Roughness length and drag coefficient at two MONTBLEX-90 tower stations

Using MONTBLEX-90 mean velocity data, roughness lengths and drag coefficients are estimated at Jodhpur and Kharagpur. At Jodhpur, since the surface is not uniform the roughness length is estimated separately in three different subsectors within the range of prevailing wind directions and averages to 1.23 cm in the sector between 200° and 230° which is relatively flat with no obstacles on the ground. At Kharagpur, where the terrain is more nearly homogeneous, the average value (for all prevailing wind directions) is 1.94 cm. The drag coefficient C_D at Jodhpur shows variation both with the roughness subsector and with wind speed, the average over all directions increasing rapidly as themean wind speed Ū₁₀ at 10m height drops according to the power lawC _D = 0.05 Ū ₁₀ ^t-1.09 in trie range 0.5 < Ū₁₀ < 7 m s⁻¹. At Kharagpur, the drag coefficient is smaller than at Jodhpur by nearly 50% for the same range of wind speeds (> 3 ms⁻¹).     

Estimation of drag coefficient over the western desert sector of the Indian summer monsoon trough

In the estimation of momentum fluxes over land surfaces by the bulk aerodynamic method, no unique value of the drag coefficient (C _D) is found in the literature. The drag coefficient is generally estimated from special observations at different parts of the world. In this study an attempt is made to estimate drag coefficient over the western desert sector of India using data sets of Monsoon Trough Boundary Layer Experiment (MONTBLEX) during the summer monsoon season of 1990. For this purpose, the fast and slow response data sets obtained simultaneously from a 30 m high micro-meteorological tower at Jodhpur are used. All the observations used in this study are confined to a wind speed regime of 2.5–9.0 ms⁻¹. A comparison of momentum fluxes computed by eddy correlation (direct estimation) with profile and bulk aerodynamic (C _D = 3.9 × 10⁻³, Garratt, 1977) methods revealed that though the nature of variation of the fluxes by all these methods is almost similar, both the indirect methods give an under-estimated value of the fluxes. The drag coefficient is estimated as a function of wind speed and surface stability by a multiple regression approach. An average value of the estimated drag coefficient is found to be of the order of 5.43 × 10⁻³. The estimated value ofC _D is validated with a set of independent observations and found to be quite satisfactory. The recomputed momentum fluxes by bulk aerodynamic method using the estimated drag coefficient are in close agreement with the directly estimated fluxes.     

Sensitivity of high-resolution tropical cyclone intensity forecasts to surface flux parameterization

Surface flux parameterization schemes used in current dynamic models are primarily based upon measurements at low and moderate wind speeds. Recent studies show that these parameterization schemes may be incorrect at high wind speeds (e.g., tropical cyclone forecasts). Five high-resolution numerical model experiments are designed to assess the sensitivity of tropical cyclone intensity forecasts to changes in the surface flux parameterization. The sensitivity experiments are conducted by running 48 h forecasts of the Coupled Ocean/Atmosphere Mesoscale Prediction System (COAMPS) for six selected tropical cyclones with individual modifications to surface flux calculation that include: (1) limiting the surface stress for wind speeds greater than 33 m s⁻¹, or 64 knots (kt); (2) computing the stress at the top of the model bottom grid layer (MBGL) by averaging results from surface layer similarity and turbulence mixing parameterization for wind speeds greater than 33 m s⁻¹; (3) increasing the roughness lengths for heat and moisture transfer by a factor of ten; (4) setting the roughness lengths for heat and moisture transfer to 1/10 of the momentum roughness length; and (5) cooling the sea surface temperature (SST) by a prescribed rate at high winds. Averaged responses for the six storms to these sensitivity tests show that: (i) the limit on surface stress at high winds significantly increases the cyclone intensity in 48 h forecasts; (ii) the averaged surface layer stress at high winds increases the cyclone intensity but to a much lesser degree than limiting the surface stress; (iii) large increases in the roughness lengths for heat and moisture transfer are needed to significantly impact the intensity forecast; (iv) the different roughness length formula for surface transfer coefficients notably increases C _h/C _d ratio from 0.59 to 0.79 for 25 m s⁻¹ and 0.41 to 0.75 for 50 m s⁻¹ that significantly increases the predicted cyclone intensity; and (v) cooling of the SST by −5.8°C in 48 h reduces the maximum surface wind speed by −32 kt, or 16.5 m s⁻¹, at 48 h forecast. These results suggest that a surface flux parameterization scheme suitable for tropical cyclone intensity forecast must correctly model the leveling-off character of surface stress and C _h/C _d ratio at high winds. All modifications to surface flux calculation have little influence on 48 h track forecasts, even though they may significantly impact the intensity forecasts.

Determination of efficiency of Vaseline slide and Wilson and Cooke sediment traps by wind tunnel experiments

The trap efficiency of a catcher in wind erosion measurements plays a significant role, and in many cases suspension trap efficiencies at high wind velocities are still unknown. The sediment trap efficiency generally changes with particles size and with wind speed. In this study, the efficiency of Vaseline Slide (VS) and Modified Wilson and Cooke (MWAC) catchers were determined with different sand particle sizes (<50, <75, 50–75, 200–400, and 400–500 μm) at a fixed wind speed (13.3 ms⁻¹) and with different soil textures at different wind velocities (10.3, 12.3, and 14.3 ms⁻¹) in the wind tunnel of the International Center for Eremology (ICE), Ghent University, Belgium. The traps were placed at different heights (4, 6.5, 13, 20, 120, and 192 cm for VS and 1.5, 3, 5, 8, 11, and 30 cm for MWAC) to catch saltating and suspended sediments in a 12-m long, 1.2-m wide and 3.2-m high working section of the wind tunnel. In the sand particle experiments, the efficiency of the VS catcher was 92% for particles smaller than 50 μm and decreased with increasing particles size, falling to 2.2% for 400–500 μm particle size at 13.4 ms⁻¹. However, the MWAC’s efficiency was 0% for particles smaller than 50 μm and increased with increasing particle size to 69.5% at 400–500 μm. In the experiments with different soil textures, the efficiency of each catcher significantly changed with soil and with wind speed. It also considerably varied with the catchers: for instance, for sand (S), the MWAC efficiency was very high (67.4, 113.4, and 90.5% at 10.3, 12.3, and 14.4 ms⁻¹, respectively) while the efficiency of VS was relatively very low (5.2, 4.4, and 1.9% at 10.3, 12.3, and 14.4 ms⁻¹, respectively). Results indicated that the efficiency depends critically on the particle size, type of catcher, and wind speed, and these could be helpful to increase the robustness of wind erosion measurements.     

Growing season evapotranspiration from Tamarix ramosissima stands under extreme arid conditions in northwest China

Given the increasing threat of water shortages in the extremely arid regions (rainfall<50 mm year⁻¹) of northwestern China, growing season evapotranspiration (ET) associated with native species such as Tamarix ramosissima is of particular interest. Consequently, this study sought to evaluate the accuracy of daily ET estimates using Bowen ratio data, as well as measuring seasonal ET and development of an energy balance for a stand of T. ramosissima. Bowen ratio apparatus measurements of ET were carried out on a stand of T. ramosissima in a 2.04 km² field, which are all covered with T. ramosissima near Erdaoqiao, Ejina Province, Inner Mongolia Autonomous Region, China. Soil moisture content and green area index were also monitored. Daily ET could be accurately estimated from Bowen ratio data on a continuous basis over the 153-day growing season. The mean daily T. ramosissima ET over this period was 1.62 mm day⁻¹, for a seasonal total of 248.20 mm. In this extremely arid locale, the great majority of available energy dissipated over the growing season was a result of sensible rather than latent heat fluxes. While the heat storage term was the main source of energy at night and a considerable sink of energy during the daytime, the magnitude of the daily mean soil heat flux was small. Such a determination of temporal and ecosystem-specific ET patterns allows an improved prediction of ET in the desert riparian zone.     

The value ofC efor the Arabian Sea during summer monsoon

We estimate, from the moisture budget the bulk aerodynamic coefficient for latent heat flux (C _e) during the monsoon season over the central Arabian Sea. The average value ofC _eunder active monsoon conditions was found to be 2.25 × 10⁻³ which is nearly 60% higher than those previously used.     

Excess heat capacity and entropy of mixing along the chlorapatite–fluorapatite binary join

The heat capacity at constant pressure, C _p, of chlorapatite [Ca₅(PO₄)₃Cl – ClAp], and fluorapatite [Ca₅(PO₄)₃F – FAp], as well as of 12 compositions along the chlorapatite–fluorapatite join have been measured using relaxation calorimetry [heat capacity option of the physical properties measurement system (PPMS)] and differential scanning calorimetry (DSC) in the temperature range 5–764 K. The chlor-fluorapatites were synthesized at 1,375–1,220°C from Ca₃(PO₄)₂ using the CaF₂–CaCl₂ flux method. Most of the chlor-fluorapatite compositions could be measured directly as single crystals using the PPMS such that they were attached to the sample platform of the calorimeter by a crystal face. However, the crystals were too small for the crystal face to be polished. In such cases, where the sample coupling was not optimal, an empirical procedure was developed to smoothly connect the PPMS to the DSC heat capacities around ambient T. The heat capacity of the end-members above 298 K can be represented by the polynomials: C _p^ClAp = 613.21 − 2,313.90T ^−0.5 − 1.87964 × 10⁷ T ⁻² + 2.79925 × 10⁹ T ⁻³ and C _p^FAp = 681.24 − 4,621.73 × T ^−0.5 − 6.38134 × 10⁶ T ⁻² + 7.38088 × 10⁸ T ⁻³ (units, J mol⁻¹ K⁻¹). Their standard third-law entropy, derived from the low-temperature heat capacity measurements, is S° = 400.6 ± 1.6 J mol⁻¹ K⁻¹ for chlorapatite and S° = 383.2 ± 1.5 J mol⁻¹ K⁻¹ for fluorapatite. Positive excess heat capacities of mixing, ΔC _p^ex, occur in the chlorapatite–fluorapatite solid solution around 80 K (and to a lesser degree at 200 K) and are asymmetrically distributed over the join reaching a maximum of 1.3 ± 0.3 J mol⁻¹ K⁻¹ for F-rich compositions. They are significant at these conditions exceeding the 2σ-uncertainty of the data. The excess entropy of mixing, ΔS ^ex, at 298 K reaches positive values of 3–4 J mol⁻¹ K⁻¹ in the F-rich portion of the binary, is, however, not significantly different from zero across the join within its 2σ-uncertainty.     

A study of turbulent characteristics of atmospheric boundary layer over monsoon trough region using Kytoon and Doppler sodar

As a part of the MONTBLEX-90 observational programme, Kytoon and Doppler sodar observations were taken at Kharagpur. These data are analysed to study the turbulent characteristics of the atmospheric boundary layer in terms of stability, temperature structure function (C _T ² ) and velocity structure function (C _v ² ).C _T ² follows aZ ^−4/3 law on most of the days, whereas the variation ofC _V ² is not systematic.C _V ² andC _T ² values are found to vary between 10⁻⁵−10⁻¹ m^4/3s⁻² and 10⁻⁵−10⁻²°C² m^−2/3 respectively.     

Low-temperature thermodynamic properties of disordered zeolites of the natrolite group

 The heat capacity of paranatrolite and tetranatrolite with a disordered distribution of Al and Si atoms has been measured in the temperature range of 6–309 K using the adiabatic calorimetry technique. The composition of the samples is represented with the formula (Na_1.90K_0.22Ca_0.06)[Al_2.24Si_2.76O₁₀]·nH₂O, where n=3.10 for paranatrolite and n=2.31 for tetranatrolite. For both zeolites, thermodynamic functions (vibrational entropy, enthalpy, and free energy function) have been calculated. At T=298.15 K, the values of the heat capacity and entropy are 425.1 ± 0.8 and 419.1 ±0.8 J K⁻¹ mol⁻¹ for paranatrolite and 381.0 ± 0.7 and 383.2 ± 0.7 J K⁻¹ mol⁻¹ for tetranatrolite. Thermodynamic functions for tetranatrolite and paranatrolite with compositions corrected for the amount of extraframework cations and water molecules have also been calculated. The calculation for tetranatrolite with two water molecules and two extraframework cations per formula yields: C _p (298.15)=359.1 J K⁻¹ mol⁻¹, S(298.15) −S(0)=362.8 J K⁻¹ mol⁻¹. Comparing these values with the literature data for the (Al,Si)-ordered natrolite, we can conclude that the order in tetrahedral atoms does not affect the heat capacity. The analysis of derivatives dC/dT for natrolite, paranatrolite, and tetranatrolite has indicated that the water- cations subsystem within the highly hydrated zeolite may become unstable at temperatures above 200 K. Received: 30 July 2001 / Accepted: 15 November 2001     

Estimation of surface heat flux and inversion height with a Doppler acoustic sounder

In this paper, acoustic sounder (sodar) derived vertical velocity variance (σ _w ² ) and inversion height (Z _i) are used to compute the surface heat flux during the convective activity in the morning hours. The surface heat flux computed by these methods is found to be of the same order of magnitude as that obtained from tower measurements. Inversion heights derived from sodar reflectivity profiles averaged for an hour are compared with those obtained from the σ _w ² /Z profile. Variation of σ _w ² in the mixed layer is discussed. The data were collected during the Monsoon Trough Boundary Layer Experiment 1990 at Kharagpur. The analysis is made for four days which represent the pre-monsoon, onset, active and relatively weak phases of the summer monsoon 1990. The interaction of the ABL with the monsoon activity is studied in terms of the variation of inversion height, vertical velocity variance and surface heat flux as monsoon progresses from June to August.     

Heat capacity of γ-Fe2SiO4 between 5 and 303 K and derived thermodynamic properties

A multi-anvil device was used to synthesize 24 mg of pure γ-Fe₂SiO₄ crystals at 8.5 GPa and 1,273 K. The low-temperature heat capacity (C _p) of γ-Fe₂SiO₄ was measured between 5 and 303 K using the heat capacity option of a physical properties measurement system. The measured heat capacity data show a broad λ-transition at 11.8 K. The difference in the C _p between fayalite and γ-Fe₂SiO₄ is reduced as the temperature increases in the range of 50–300 K. The gap in C _p data between 300 and 350 K of γ-Fe₂SiO₄ is an impediment to calculation of a precise C _p equation above 298 K that can be used for phase equilibrium calculations at high temperatures and high pressures. The C _p and entropy of γ-Fe₂SiO₄ at standard temperature and pressure (S°₂₉₈) are 131.1 ± 0.6 and 140.2 ± 0.4 J mol⁻¹ K⁻¹, respectively. The Gibbs free energy at standard pressure and temperature (ΔG° _f,298) is calculated to be −1,369.3 ± 2.7 J mol⁻¹ based on the new entropy data. The phase boundary for the fayalite–γ-Fe₂SiO₄ transition at 298 K based on current thermodynamic data is located at 2.4 ± 0.6 GPa with a slope of 25.4 bars/K, consistent with extrapolated results of previous experimental studies.     

Seasonal variability of deep ocean particle fluxes and particle composition in the north open sea of Prydz Bay

Time-series Mark VII sediment trap was deployed at 72°58.55′E, 62°28.63°S (north of the Prydz Bay, Antarctica) during the cruise of CHINARE-15 in cooperation with University of Marine of America. Seasonal variability of deep ocean particle fluxes and biogenic components were investigated in order to reveal the fluxes and biogeochemistry of sinking particles in the deep ocean. The results show that the total mass flux of sinking particles at a water depth of 1000 m ranges from 13.00 to 334.59 mg⋅d⁻¹⋅m⁻²). A marked seasonal variability exists in the fluxes of all particle components reflecting the seasonal changes in upper water productivity. Biogenic material was a significant component and biogenic silica represented more than 80% of the biogenic matter, reflecting a diatom dominated system, but a lithogenic fraction is always present. The fact that the POC dominated over particulate inorganic carbon (as CaCO₃) and C_inorg/C_org was always greater than 1, indicate a net removal of CO₂ from surface water by biological activity. __________ Translated from Acta Oceanologica Sinica, 2006, 5: 49–55 [译自:海洋 学报]     

Heat capacity,entropy, and phase equilibria of dmitryivanovite

The heat capacity (C _p ) of dmitryivanovite synthesized with a cubic press was measured in the temperature range of 5–664 K using the heat capacity option of a physical properties measurement system and a differential scanning calorimeter. The entropy of dmitryivanovite at standard temperature and pressure (STP) was calculated to be 110.1 ± 1.6 J mol⁻¹ K⁻¹ from the measured C _p data. With the help of new phase equilibrium experiments done at 1.5 GPa, the phase transition boundary between krotite and dmitryivanovite was best represented by the equation: P (GPa) = −2.1825 + 0.0025 T (K). From the temperature intercept of this phase boundary and other available thermodynamic data for krotite and dmitryivanovite, the enthalpy of formation and Gibbs free energy of formation of dmitryivanovite at STP were calculated to be −2326.7 ± 2.1 and −2,208.1 ± 2.1 kJ mol⁻¹, respectively. It is also inferred that dmitryivanovite is the stable CaAl₂O₄ phase at STP and has a wide stability field at high pressures whereas the stability field of krotite is located at high temperatures and relatively low pressures. This conclusion is consistent with natural occurrences (in Ca–Al-rich inclusions) of dmitryivanovite and krotite, where the former is interpreted as the shock metamorphic product of originally present krotite.     

Heat capacity and thermodynamic functions of xenotime YPO<Subscript>4</Subscript>(c) at 0–1600 K

The heat capacity of xenotime YPO₄(c) was measured by adiabatic calorimetry at 4.78–348.07 K. Our experimental and literature data on H ⁰(T)-H ⁰(298.15 K) of Y orthophosphate were utilized to derive the C _p ⁰(T) function of xenotime at 0–1600 K, which was then used to calculate the values of thermodynamic functions: entropy, enthalpy change, and reduced Gibbs energy. These functions assume the following values at 298.15 K: C _p ⁰ (298.15 K) = 99.27 ± 0.02 J K⁻¹ mol⁻¹, S ⁰(298.15 K) = 93.86 ± 0.08 J K⁻¹ mol⁻¹, H ⁰(298.15 K) − H ⁰(0) = 15.944 ± 0.005 kJ mol⁻¹, Φ⁰(298.15 K) = 40.38 ± 0.08 J K⁻¹ mol⁻¹. The value of the free energy of formation Δ _f G ⁰(YPO₄, 298.15 K) is −1867.9 ± 1.7 kJ mol⁻¹.     

Heat capacity and thermodynamic properties of GdPO<Subscript>4</Subscript> in the temperature range 0–1600 K

The heat capacity of gadolinium orthophosphate (GdPO₄) measured in the temperature range 11.15–344.11 K by adiabatic calorimetry and available literature data were used to calculate its thermodynamic functions at 0–1600 K. At 298.15 K, these functions are as follows: C _p ⁰(298.15 K) = 101.85 ± 0.05 J K⁻¹ mol⁻¹, S ⁰(298.15 K) = 123.82 ± 0.18 J K⁻¹ mol⁻¹, H ⁰(298.15 K)–H ⁰(0) = 17.250 ± 0.012 kJ mol⁻¹, and Φ ⁰(298.15 K) = 65.97 ± 0.18 J K⁻¹ mol⁻¹ The calculated Gibbs free energy of formation from the elements of GdPO₄ is Δ _f G ⁰ (298.15 K) = −1844.3 ± 4.7 kJ mol⁻¹.     

Convective crystal dissolution

The effect of free and forced convection on crystal dissolution is examined both theoretically and experimentally. Well-established relationships for heat and mass transfer are applied to obtain approximate expressions for the dissolution velocity and the associated thickness of the compositional boundary layer. These expressions are found to be in good agreement with experimental observations of the dissolution of quartz crystals in basalt and NaCl crystal in water. When applied to light felsic crystals in basaltic magmas, the expressions predict that forced convection will produce a boundary layer thickness of about 100 μm and a dissolution velocity of order 10⁻⁶ cm s⁻¹. These velocities are too slow for xenocrysts to be dissolved significantly during magma ascent in dykes, but are sufficient for cm-size crystals to dissolve in the interior of a convecting magma chamber. Larger crystals are likely to accumulate at the chamber's roof, where free convection is predicted to dissolve them at velocities of order 10⁻⁷ cm s⁻¹. In an Appendix, the dissolution of the chamber's walls is also considered, and a velocity of order 10⁻⁸cm s⁻¹ is predicted. Editorial responsibility: T.L. Grove     

Carbon dioxide,water vapor,and heat fluxes over agricultural crop field in an arid oasis of Northwest China,as determined by eddy covariance

Fluxes of carbon dioxide, water vapor, and heat were measured above crop canopy using the eddy covariance method during the 2008 maize growing season, over an agricultural field within an oasis located in the middle reaches of Heihe River basin, northwest China. The values for friction velocity, the Monin–Obukhov stability parameter, and energy balance closure indicated that the eddy covariance system at this study site provided reliable flux estimates. Results from measurements showed that the mean sensible heat flux was 70 W m⁻² with a maximum value of 164 W m⁻² (May) and a minimum value of 45 W m⁻² (July) during the maize growing season. In contrast, the mean latent heat was 278 W m⁻² with a maximum value of 383 W m⁻² (July) and minimum of 101 W m⁻² (May). The mean downward soil heat flux was 55 W m⁻² with a maximum value of 127 W m⁻² (May) and minimum of 49 W m⁻² (July). The magnitude of mean daytime net CO₂ uptake was −11.50 μmol m⁻² s⁻¹ with a maximum value of −28.32 μmol m⁻² s⁻¹ (18 and 19 July) and a minimum values of −0.32 μmol m⁻² s⁻¹ (18 and 19 May). Correlation was observed between daytime half-hourly carbon dioxide flux and canopy conductance. In addition, the relationship between carbon dioxide flux and photosynthetically active radiation for selected days during different stages of maize growing season indicated the carbon dioxide flux uptake by the canopy was controlled by actual photosynthetic activity related to the variation of green leaf area index for the different growing stages.     

Thermodynamic mixing behavior of synthetic Ca-Tschermak–diopside pyroxene solid solutions: I. Volume and heat capacity of mixing

The unite cell parameters and heat capacities of a series of synthetic clinopyroxenes on the join Ca-Tschermak (CaTs)−diopside (Di) were measured using X-ray powder diffraction and calorimetric methods, respectively. The volume of mixing at 298 K shows a negative asymmetric deviation from ideality. A two-parameter Margules fit to the data yields W _CaTs−Di ^V = −0.29 ± 0.11 cm³ mol⁻¹ and W _Di−CaTs ^V = −1.14 ± 0.14 cm³ mol⁻¹. Heat capacities were determined between 5 and 923 K by heat-pulse at 5−302 K and differential-scanning calorimetry at 143−923 K. The precision of the low and high temperature C _p data is better than ±1%. Polynomials of the form C _p = a + bT ^−1/2 + cT ⁻² + dT ⁻³ were fitted to the C _p data in the temperature range between 250 and 925 K. Thermal entropy values [S ₂₉₈ − S ₀] and [S ₉₀₀ −S ₀] as well as enthalpies [H ₂₉₈ − H ₀] and [H ₉₀₀ − H ₀] were calculated for all members of the solid solution series. No significant deviation from ideal mixing behavior was observed.     

Evaporation and energy balance estimates over a large inland lake in the Tibet-Himalaya

The process of evaporation from the lake surface is one of the main mechanisms in the energy and water budgets of the lake hydrologic cycle, and an essential component of the water balance especially for inland lakes. In this study, using routine meteorological data as input, a one-layer potential evaporation model was employed to simulate evaporation and energy fluxes over Lake Yamdrok Yumco, the largest high-elevation inland lake in the mountain area of the Tibet-Himalaya in China. Then, the calculation results were compared with the measured values from a big pan evaporator of 20 m² near the lake. The results show that the average annual input radiation flux R ^↓ is 128.2 W m⁻², the lake storage heat flux G is 19.4 W m⁻², the sensible heat flux H is 20.4 W m⁻² and the latent heat flux lE is 107.8 W m⁻². The R ^↓ and G exhibit similar seasonal variations. The lE reaches a maximum in October, lagging nearly 4 months behind the R ^↓ and the G, which indicates the large heat capacity of the lake. The simulated annual evaporation ranges from 1,113.2 to 1,429.1 mm and its mean value is 1,252.5 mm during 1961–2005. The simulated annual evaporation is in good agreement with the measured value, and the measured average lake temperature is as expected when compared with the measured lake surface temperature.     

Variation in surface turbulence and the gas transfer velocity over a tidal cycle in a macro-tidal estuary

The gradient flux technique, which measures the gas transfer velocity (k), and new observational techniques that probe turbulence in the aqueous surface boundary layers were conducted over a tidal cycle in the Plum Island Sound, Massachusetts. Efforts were aimed at testing new methods in an estuarine system and to determine if turbulence created by tidal velocity can be responsible for the short-term variability ink. Measurements were made during a low wind day, at a site with tidal excursions of 2.7 m and a range in tidal velocity of nearly 1 m s⁻¹. Estimates ofk using the gradient flux technique were made simultaneously with the Controlled Flux Technique (CFT), infrared imagery, and high-resolution turbulence measurements, which measure the surface renewal rate, turbulent scales, and the turbulent dissipation rate, respectively. All measurements were conducted from a small mobile catamaran that minimizes air- and water-side flow distortions. Infrared imagery showed considerable variability in the turbulent scales that affect air-water gas exchange. These measurements were consistent with variation in the surface renewal rate (range 0.02 to 2 s⁻¹), the turbulent dissipation rate (range 10⁻⁷ to 10⁻⁵ W kg⁻¹), andk (range 2.2 to 12.0 cm hr⁻¹). During this low wind day, all variables were shown to correlate with tidal speed. Taken collectively our results indicate the promise of these methods for determining short-term variability in gas transfer and near surface turbulence in estuaries and demonstrate that turbulent transport associated with tidal velocity is a potentially important factor with respect to gas exchange in coastal systems.