The Mesozoic–Cenozoic structural framework of the Bay of Kiel area, western Baltic Sea

A dense grid of multichannel high-resolution seismic sections from the Bay of Kiel in the western Baltic Sea has been interpreted in order to reveal the Mesozoic and Cenozoic geological evolution of the northern part of the North German Basin. The overall geological evolution of the study area can be separated into four distinct periods. During the Triassic and the Early Jurassic, E–W extension and the deposition of clastic sediments initiated the movement of the underlying Zechstein evaporites. The deposition ceased during the Middle Jurassic, when the entire area was uplifted as a result of the Mid North Sea Doming. The uplift resulted in a pronounced erosion of Upper Triassic and Lower Jurassic strata. This event is marked by a clear angular unconformity on all the seismic sections. The region remained an area of non-deposition until the end of the Early Cretaceous, when the sedimentation resumed in the area. Throughout the Late Cretaceous the sedimentation took place under tectonic quiescence. Reactivated salt movement is observed at the Cretaceous Cenozoic transition as a result of the change from an extensional to compressional regional stress field. The vertical salt movement influenced the Cenozoic sedimentation and resulted in thin-skinned faulting.     

Intense pyrite formation under low-sulfate conditions in the Achterwasser lagoon, SW Baltic Sea

In comparison to similar low-sulfate coastal environments with anoxic-sulfidic sediments, the Achterwasser lagoon, which is part of the Oder estuary in the SW Baltic Sea, reveals unexpectedly high pyrite concentrations of up to 7.5 wt%. Pyrite occurs mainly as framboidal grains variable in size with diameters between 1 and 20 μm. Pyritization is not uniform down to the investigated sediment depth of 50 cm. The consumption of reactive-Fe is most efficient in the upper 20 cm of the sediment column, leading to degrees of pyritization (DOP) as high as 80 to 95%.Sediment accumulation in the Achterwasser takes place in high productivity waters. The content of organic carbon reaches values of up to 10 wt%, indicating that pyrite formation is not limited by the availability of organic matter. Although dissolved sulfate concentration is relatively low (<2 mmol/L) in the Achterwasser, the presence of H₂S in the pore water suggests that sulfate is unlikely to limit pyrite authigenesis. The lack of free Fe(II) in the pore waters combined with the possibility of a very efficient transformation of Fe-monosulfides to pyrite near the sediment/water interface suggests that pyrite formation is rather controlled by (i) the availability of reactive-Fe, which limits the FeS formation, and by (ii) the availability of an oxidant, which limits the transformation of FeS into pyrite. The ultimate source for reactive-Fe is the river Oder, which provides a high portion of reactive-Fe (∼65% of the total-Fe) in the form of suspended particulate matter. The surficial sediments of the Achterwasser are reduced, but are subject to oxidation from the overlying water by resuspension. Oxidation of the sediments produces sulfur species with oxidation states intermediate between sulfide and sulfate (e.g., thiosulfate and polysulfides), which transform FeS to FeS₂ at a significant rate. This process of FeS-recycling is suggested to be responsible for the formation of pyrite in high concentrations near the sediment surface, with DOP values between 80 and 95% even under low sulfate conditions.A postdepositional sulfidization takes place in the deeper part of the sediment column, at ∼22 cm depth, where the downward diffusion of H₂S is balanced by the upward migration of Fe(II). The vertical fluctuation of the diffusion front intensifies the pyritization of sediments. We suggest that the processes described may occur preferentially in shallow water lagoons with average net-sedimentation rates close to zero. Such environments are prone to surficial sediment resuspension, initiating oxidation of Fe-sulfides near the sediment/water interface. Subsequent FeS₂ formation as well as postdepositional sulfidization leads to a major pyrite spike at depth within the sediment profile.     

Late Pleistocene and early Holocene drainage events in the eastern Fehmarn Belt and Mecklenburg Bight,SW Baltic Sea

The Fehmarn Belt is a key area for the Late Pleistocene and Holocene development of the Baltic Sea as it was a passage for marine and fresh water during its different stages. The pre‐Holocene geological development of this area is presented based on the analysis of seismic profiles and sedimentary gravity cores. Late Pleistocene varve sediments of the initial Baltic Ice Lake were identified. An exceptionally thick varve layer, overlain by a section of thinner varves with convolute bedding in turn covered by undisturbed varves with decreasing thicknesses is found in the Fehmarn Belt. This succession, along with a change in varve geochemistry, represents a rapid ice‐sheet withdrawal and increasingly distal sedimentation in front of the ice margin. Two erosional unconformities are observed in the eastern Mecklenburg Bight, one marking the top of the initial Baltic Ice Lake deposits and the second one indicating the end of the final Baltic Ice Lake. These unconformities join in Fehmarn Belt, where deposits of the final Baltic Ice Lake are missing due to an erosional hiatus related to a lake‐level drop during its final drainage. After this lake‐level drop, a lowstand environment represented by river deposits developed. These deposits are covered by lake marls of Yoldia age. Tilting of the early glacial lake sediments indicates a period of vertical movements prior to the onset of the Holocene. Deposits of the earliest stages of the Baltic Sea have been exposed by ongoing erosion in the Fehmarn Belt at the transition to the Mecklenburg Bight.     

Scaling the Baltic Sea environment

The Baltic Sea environment has since the early 1970s passed through several phases of spatial objectification in which the ostensibly well-defined semi-enclosed sea has been framed and reframed as a geographical object for intergovernmental environmental politics. Based on a historical analysis of this development, this article suggests that environmental politics critically depend on the delineation of relatively bounded spaces that identify and situate particular environmental concerns as spatial objects for politics. These spaces are not simply determined by ‘nature’ or some environmental-scientific logic, but should rather be seen as temporal outcomes of scale framing processes, processes that are accentuated by contemporary conceptions of the environment (or nature) in terms of multi-scalar ecosystems. This has implications for how an environmental concern is perceived and politically addressed.     

Biogenic components of the Baltic Sea sediments

The contents of biogenic components in 1511 samples of the Baltic Sea sediments (depth range 0–5 cm) are studied, and maps of their distribution are compiled. The sediments contain < 13.03% C_org, < 1.33% N, < 9.0% SiO_2am, < 5.0% CaCO₃, and < 1.45% P. The maximum and elevated contents of components are found in the mud of the sea deeps. The more fraction < 0.01 mm the sediments contain, the higher are the contents of components. Four facies types of carbonaceous mud, precursors of shales, have been recognized: (1) shallow-water (lagoon) lime sapropel, (2) carbonaceous mud of the shallow-water Gulf of Finland, (3) carbonaceous mud of the middle-depth Baltic Sea, and (4) laminated carbonaceous metal-bearing mud. The latter type of mud is strongly enriched in manganese and ore-forming trace elements, which points to its formation in the stagnant environment. In composition the Baltic Sea mud is similar to petroliferous mudstones of the Bazhenov Formation in West Siberia and to ancient black shales.     

Seismic evidence of Caledonian deformed crust and uppermost mantle structures in the northern part of the Trans-European Suture Zone, SW Baltic Sea

Collisional structures from the closure of the Tornquist Ocean and subsequent amalgamation of Avalonia and Baltica during the Caledonian Orogeny in the northern part of the Trans-European Suture Zone (TESZ) in the SW Baltic Sea are investigated. A grid of marine reflection seismic lines was gathered in 1996 during the DEKORP-BASIN '96 campaign, shooting with an airgun array of 52 l total volume and recording with a digital streamer of up to 2.1 km length. The detailed reflection seismic analysis is mainly based on post-stack migrated sections of this survey, but one profile has also been processed by a pre-stack depth migration algorithm. The data provides well-constrained images of upper crustal reflectivity and lower crustal/uppermost mantle reflections. In the area of the Caledonian suture, a reflection pattern is observed with opposing dips in the upper crust and the uppermost mantle. Detailed analysis of dipping reflections in the upper crust provides evidence for two different sets of reflections, which are separated by the O-horizon, the main decollement of the Caledonian deformation complex. S-dipping reflections beneath the sub-Permian discontinuity and above the O-horizon are interpreted as Caledonian thrust structures. Beneath the O-horizon, SW-dipping reflections in the upper crust are interpreted as ductile shear zones and crustal deformation features that evolved during the Sveconorwegian Orogeny. The Caledonian deformation complex is subdivided into (1) S-dipping foreland thrusts in the north, (2) the S-dipping suture itself that shows increased reflectivity, and (3) apparently NE-dipping downfaulted sedimentary horizons south of the Avalonia–Baltica suture, which may have been reactivated during Mesozoic normal faulting. The reflection Moho at 28–35 km depth appears to truncate a N-dipping mantle structure, which may represent remnant structures from Tornquist Ocean closure or late-collisional compressional shear planes in the upper mantle. A contour map of these mantle reflections indicates a consistent northward dip, which is steepest where there is strong bending of the Caledonian deformation front. The thin-skinned character of the Caledonian deformation complex and the fact that N-dipping mantle reflections do not truncate the Moho indicate that the Baltica crust was not mechanically involved in the Caledonian collision and, therefore, escaped deformation in this area.     

Ferromanganese ore process in the Baltic Sea

In depressions of the Baltic Sea, where the bottom is periodically marked by stagnation, silt contains as much as 5% Mn (up to 17% in some layers) and 9–10% C_org. Silt in such depressions is laminated. The marine sediment sequence is stratified due to the influx of oceanic water into sea: the upper layers are oxic, while the lower (near-bottom) layers are hydrosulfuric. Boundary between them is represented by the transitional O₂-H₂S layer. This zone (redox barrier) is marked by drastic variation in Eh. Zone below this barrier is characterized by the accumulation of huge amounts of the dissolved manganese (Mn²⁺) and iron (Fe²⁺), which diffuse from the hydrosulfuric layer into the oxic layer under the influence of gradient and precipitated as suspeusion with as much as 15% Fe and 45% Mn. When fresh oxygenated saline water is transported to depressions, the hydrosulfuric setting gives way to oxic one and the dissolved elements are transformed into the particulate phases as hydroxides and geologically instantly precipitated at the bottom. After 5–10 yr, the setting changes; hydrogen sulfide is again delivered to water column from the bottom. This is accompanied by supply of the dissolved Mn²⁺ and Fe²⁺ previously accumulated as gel-type sediment at the bottom. Thus, the cycle of elements is repeated. The latter, however, is not completely dissolved. Some portion remains at the bottom as black rhodochrosite microlayers (laminas) that contain as much as 29% Mn. The black laminas accumulated during aeration include remains of bottom foraminifers. In addition, the bottom comprises pale diatom laminas and brownish gray varieties composed of clayey and organic substances. Bulk samples of the laminated silt contain as much as 12.9% Mn or 26.9% MnCO₃. Depressions in the Baltic Sea represent a unique site of the Earth marked by accumulation of the carbonate-manganiferous sediments at present. We believe that Oligocene manganese carbonate-oxide ores described by N.M. Strakhov and coauthors were accumulated in the same manner. Compositions of manganiferous sediments in the Baltic region and some ancient ores in Europe are compared. The author studied five stages of Mn accumulation and sediment transformation into ores.     

Strike-slip tectonics within the SW Baltic Sea and its relationship to the inversion of the Mid-Polish Trough—evidence from high-resolution seismic data

The SW Baltic Sea occupies an area where crustal-scale regional tectonic zones of different age merge and overlap, creating a complex tectonic pattern. This pattern influenced the evolution of the Mesozoic sedimentary basin in this area. We present an interpretation of new high-resolution seismic data from the SW Baltic Sea which provided new information both on modes of the Late Cretaceous inversion of this part of the Danish–Polish Mesozoic basin system as well as on relationship between tectonic processes and syn-tectonic depositional systems. Within the Bornholm–Dar owo Fault Zone, located between the Koszalin Fault and Christiansø Block, both strike-slip and reverse faulting took place during the inversion-related activity. The faulting was related to reactivation of extensional pre-Permian fault system. Syn-tectonic sedimentary features include a prominent, generally S- and SE-directed, progradational depositional system with the major source area provided by uplifted basement blocks, in particular by the Bornholm Block. Sediment progradation was enhanced by downfaulting along a strike-slip fault zone and related expansion of accommodation space. Closer to the Christiansø Block, some syn-tectonic deposition also took place and resulted in subtle thickness changes within the hinge zones of inversion-related growth folds. Lack of significant sediment supply from the inverted and uplifted offshore part of the Mid-Polish Trough suggests that in this area NW–SE-located marginal trough parallel to the inversion axis of the Mid-Polish Trough did not form, and that uplifted Bornholm Block played by far more prominent role for development of syn-inversion depositional successions.     

Structural framework of the Bashkirian anticlinorium, SW Urals

The Bashkirian anticlinorium of the southwestern Urals shows a much more complex structural architecture and tectonic evolution than previously known. Pre-Uralian Proterozoic extensional and compressional structures controlled significantly the Uralian tectonic convergence. A long-lasting Proterozoic rift process created extensional basement structures and a Riphean basin topography which influenced the formation of the western fold-and-thrust-belt with inversion structures during the Uralian deformation. A complete orogenic cycle during Cadomian times, including terrane accretion at the eastern margin of the East European platform, resulted in a high-level Cadomian basement complex, which controlled the onset of Uralian deformation, and resulted in intense imbrication and tectonic stacking in the subjacent footwall of the Main Uralian fault. The Uralian orogenic evolution can be subdivided into three deformation stages with differently oriented stress regimes. Tectonic convergence started in the Late Devonian with ophiolite obduction, tectonic accretion of basin and slope units and early flysch deposits (Zilair flysch). The accretionary complex prograded from the SE to the NW. Continuous NW/SE-directed convergence resulted finally in the formation of an early orogenic wedge thrusting the Cadomian basement complex onto the East European platform. The main tectonic shortening was connected with these two stages and, although not well constrained, appears to be of Late Devonian to Carboniferous age. In the Permian a final stage of E–W compression is observed throughout the SW Urals. In the west the fold-and-thrust-belt prograded to the west with reactivation of former extensional structures and minor shortening. In the east this phase was related to intense back thrusting. The East European platform was subducted beneath the Magnitogorsk magmatic arc during the Late Paleozoic collision. The thick and cold East European platform reacted as a stable rigid block which resulted in a narrow zone of intense crustal shortening, tectonic stacking and high strain at its eastern margin. Whereas the first orogenic wedge is of thick-skinned type with the involvement of crystalline basement, even the later west-directed wedge is not typically thin-skinned as the depth of the basal detachment appears below 15 km and the involvement of Archean basement can be assumed.     

Evidence of the final drainage of the Baltic Ice Lake and the brackish phase of the Yoldia Sea in glacial varves from the Baltic Sea

A clay-varve chronology based on 14 cross-correlated varve graphs from the Baltic Sea and a mean varve thickness curve has been constructed. This chronology is correlated with the Swedish Time Scale and covers the time span 11530 to 10250 varve years BP. Two cores have been analysed for grain size, chemistry, content of diatoms and changes in colour by digital colour analysis. The final drainage of the Baltic Ice Lake is dated to c . 10800 varve years BP and registered in the cores analysed as a decrease in the content of clay. This event can be correlated with atmospheric Δ14 C content and might have resulted in an increase in these values recorded between 11565 and 11545 years BP. The results of the correlation between the varve chronology from the Baltic Sea, the Greenland GRIP ice core and the atmospheric Δ14 C record indicate that c . 760 years are missing in the Swedish Time Scale in the part younger than c. 10250 varve years BP. A change in colour from a brownish to grey varved glacial clay recorded c . 10770 varve years BP is found to be the result of oxygen deficiency due to an increase in the rate of sedimentation in the early Preboreal. The first brackish influence is recorded c . 10540 varve years BP in the northwestern Baltic Sea and some 90 years later in the eastern Gotland Basin.     

Uronic and other organic acids in Baltic Sea and Black Sea sediments

Organic acids were released from marine sediments by acid hydrolysis. Ion-exchange chromatography and GC-MS were used to separate and identify the acids. The major compounds detected were galacturonic, glucuronic, mannuronic, 4-O-methylglucuronic, cellobiouronic, guluronic, glyceric, glycolic, lactic and erythronic acids. Numerous biouronic (sugar-uronic acid compounds) and aldonic acids were also found. The low abundance of uronic acids characteristic of terrigenous plants and the similarity of the biouronic composition to that of marine algae indicate a marine algal source for the acids in the sediment. Results from the Black Sea are compared with those from the Baltic Sea and several diagenetic transformations are discussed.     

Iodine-129 enrichment in sediment of the Baltic Sea

Sediments are an excellent archive for evaluation of time-series environmental contamination of water systems. Measurements of ultra-trace radioactive species, such as ¹²⁹I, provide information for both chronologic calibration and anthropogenic emissions during the nuclear era. Here data are presented on ¹²⁹I and other chemical parameters from two sediment cores collected in the Baltic Sea during 1997. The sediment sections have a relatively uniform grain size (clay–mud) and cover a period of about 50 a. Distribution of ¹²⁹I in the sediment strongly relates to the liquid release records from the nuclear reprocessing facilities at Sellafield and La Hague. However, syn- and post-depositional alteration of organic matter at the sediment–water interface and within the sediment column may have contributed to slightly obliterating the anthropogenic ¹²⁹I signals. Indication of Chernobyl-derived ¹²⁹I occurs in the sediment profile, but is apparently overridden by the overwhelming flux from the nuclear reprocessing facilities. Although the record did not cover the pre-nuclear era (before 1945) sections, the ultra sensitive ¹²⁹I profile provides a potential tool for relative dating and monitoring sources of water and sediment to the region.     

Seismicity and seismotectonic implications in the southern Baltic Sea area

An updated list of earthquakes and earthquake parameters (location, homogenized magnitude, macroseismic data) for the southern Baltic Sea area reveals activity north of the sea, whereas there are very few epicentres in the sea itself and in the region south of it. This is the first study to combine seismological data for the whole region to cover also the sea. Macroseismic data for the 1930 earthquake were reinvestigated leading to an intensity of V–VI (MM or MSK scale), a radius of perceptibility of 135 km and an unusually big focal depth of about 40 km. It is difficult to correlate individual earthquakes with specific faults, but some seismotectonic relations are suggested, e.g. for the Tornquist zone, the predominant structure of the region. Only few reliable focal-mechanism solutions exist. Possible seismogenic processes (ridge push, isostasy, etc) are discussed.     

Time-dependent modeling of the Baltic entrance area. 2. Water and salt exchange of the Baltic Sea

A time-dependent model for stratification and circulation within the Baltic entrance area (Gustafsson 2000) is tested against observed salinities for the period 1961–1993. Although the Baltic Sea is one of the largest estuarine systems on earth, this model could be applicable to smaller estuarine systems and embayments with tidal exchange. The seasonal cycle of freshwater flux across the sill area does not follow the seasonal cycle of freshwater supply to the Baltic Sea. The seasonal variation of the flux is a combined effect of the seasonal variation in freshwater supply, in Baltic mean sea level, and in dispersion of salt across the sills. The seasonal variation in dispersion of salt is due to the seasonal cycle of sea level variability. The model is used to predict the inflow of high saline water to the Baltic Sea. The resulting inflow time-series is consistent with variations in the deep-water salinity and temperature in the deeper parts of the Baltic Sea. A comparison with previous estimates of the magnitude of major Baltic inflows shows that the model is able to reproduce the characteristics fairly well although the magnitude of the flows of water and salt appears lower than other estimates. It is shown that a climatic change that increases the wind mixing does not significantly change the major inflows. Both increased amplitudes of sea level variations in the Kattegat and decreased freshwater supply to the Baltic Sea substantially increase the magnitude of the inflows. It is shown that deep-water renewal in the Baltic Sea is obstructed during years with high freshwater supply even if the sea level forcing is favorable to a major inflow.     

Disturbed radiometric ages and their bearing on interregional correlations in the SW Baltic Shield

Rb---Sr whole-rock and zircon U---Pb isotopic work is reported from the northern part of the region between the Mylonite and Protogine Zones in the southern Baltic Shield. Three age determinations on polymetamorphic gneissic granites were carried out. Two of these yielded U---Pb upper-intercept ages of 1650 and 1675 Ma, respectively, which is approximately one hundred Ma less than expected from the combined field evidence and earlier isotopic age determinations. Although the new discordias appear well defined, various criteria suggest that the U---Pb isotope system was disturbed. Thus, the Rb---Sr system had been opened, but nevertheless the Rb---Sr errorchrones are consistent with the U---Pb upper-intercept ages, and an abraded zircon fraction suggests an older age than the unabraded fractions. The third U---Pb age determination resulted in a poorly constrained discordia. Its upper intercept ranges between 1575 and 1605 Ma, depending on the number of fractions considered.

This paper tests a three-stage model, where the intrusion age is set identical to the 1780 Ma intrusion age of the undeformed assumed protolith. The first two analysed rocks are consistent with a model suggesting intrusion at 1780 Ma followed by partial opening of the isotopic systems early (1200 Ma) and late (950 Ma) during the Sveconorwegian orogeny. An abraded fraction together with the time of the suggested last opening of the system 950 Ma ago defines a two-point discordia with an upper-intercept age of 1745 Ma. This age is in close agreement with the assumed intrusion age. The isotope data from the third gneissic granite cannot be fitted to this simple model.

It is concluded that the analysed rocks could belong to the granitoids of the Transscandinavian Igneous Belt, but if they do, they were reworked during the Sveconorwegian orogeny. As a corollary, it follows that the regions separated by the northern part of the Protogine Zone largely had a common pre-Sveconorwegain geological history. Another important implication is that the intrusion ages in the area between the Mylonite and Protogine Zones are older than those of the Trans-Labrador Batholith in Canada.