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1.
A statistical downscaling model, based on the outputs of general circulation models (GCMs) as predictors, was proposed to simulate the daily precipitations in the Shih‐Men reservoir catchment in Taiwan. The structure of the proposed downscaling model is composed of two parts: classification and regression. Predictors of classification and regression models were selected from the large‐scale weather variables in the National Centers for Environmental Prediction (NECP) reanalysis data based on statistical tests. Discriminant analysis and support vector regression (SVR) were applied to build the classification and regression models. The outputs of five atmosphere‐ocean GCMs, which are reported to have properly considered tropical cyclone information and East Asian Monsoon modelling, were used for projecting future precipitations. Data from four grids covering Taiwan were used for developing the downscaling model. The potential of the downscaling models in simulating local precipitations was evaluated, and downscaling results reveal that the proposed downscaling model can reproduce local daily precipitations from large‐scale weather variables. Projected local precipitations under two emission scenarios show that the precipitations in the study area tend to decrease. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   

2.
Many downscaling techniques have been developed in the past few years for projection of station‐scale hydrological variables from large‐scale atmospheric variables simulated by general circulation models (GCMs) to assess the hydrological impacts of climate change. This article compares the performances of three downscaling methods, viz. conditional random field (CRF), K‐nearest neighbour (KNN) and support vector machine (SVM) methods in downscaling precipitation in the Punjab region of India, belonging to the monsoon regime. The CRF model is a recently developed method for downscaling hydrological variables in a probabilistic framework, while the SVM model is a popular machine learning tool useful in terms of its ability to generalize and capture nonlinear relationships between predictors and predictand. The KNN model is an analogue‐type method that queries days similar to a given feature vector from the training data and classifies future days by random sampling from a weighted set of K closest training examples. The models are applied for downscaling monsoon (June to September) daily precipitation at six locations in Punjab. Model performances with respect to reproduction of various statistics such as dry and wet spell length distributions, daily rainfall distribution, and intersite correlations are examined. It is found that the CRF and KNN models perform slightly better than the SVM model in reproducing most daily rainfall statistics. These models are then used to project future precipitation at the six locations. Output from the Canadian global climate model (CGCM3) GCM for three scenarios, viz. A1B, A2, and B1 is used for projection of future precipitation. The projections show a change in probability density functions of daily rainfall amount and changes in the wet and dry spell distributions of daily precipitation. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

3.
In this study, the applicability of the statistical downscaling model (SDSM) in downscaling precipitation in the Yangtze River basin, China was investigated. The investigation includes the calibration of the SDSM model by using large-scale atmospheric variables encompassing NCEP/NCAR reanalysis data, the validation of the model using independent period of the NCEP/NCAR reanalysis data and the general circulation model (GCM) outputs of scenarios A2 and B2 of the HadCM3 model, and the prediction of the future regional precipitation scenarios. Selected as climate variables for downscaling were measured daily precipitation data (1961–2000) from 136 weather stations in the Yangtze River basin. The results showed that: (1) there existed good relationship between the observed and simulated precipitation during the calibration period of 1961–1990 as well as the validation period of 1991–2000. And the results of simulated monthly and seasonal precipitation were better than that of daily. The average R 2 values between the simulated and observed monthly and seasonal precipitation for the validation period were 0.78 and 0.91 respectively for the whole basin, which showed that the SDSM had a good applicability on simulating precipitation in the Yangtze River basin. (2) Under both scenarios A2 and B2, during the prediction period of 2010–2099, the change of annual mean precipitation in the Yangtze River basin would present a trend of deficit precipitation in 2020s; insignificant changes in the 2050s; and a surplus of precipitation in the 2080s as compared to the mean values of the base period. The annual mean precipitation would increase by about 15.29% under scenario A2 and increase by about 5.33% under scenario B2 in the 2080s. The winter and autumn might be the more distinct seasons with more predicted changes of precipitation than in other seasons. And (3) there would be distinctive spatial distribution differences for the change of annual mean precipitation in the river basin, but the most of Yangtze River basin would be dominated by the increasing trend.  相似文献   

4.
With increasing uncertainties associated with climate change, precipitation characteristics pattern are receiving much attention these days. This paper investigated the impact of climate change on precipitation in the Kansabati basin, India. Trend and persistence of projected precipitation based on annual, wet and dry periods were studied using global climate model (GCM) and scenario uncertainty. A downscaling method based on Bayesian neural network was applied to project precipitation generated from six GCMs using two scenarios (A2 and B2). The precipitation values for any of three time periods (dry, wet and annual) do not show significant increasing or decreasing trends during 2001–2050 time period. There is likely an increasing trend in precipitation for annual and wet periods during 2051–2100 based on A2 scenario and a decreasing trend in dry period precipitation based on B2 scenario. Persistence during dry period precipitation among stations varies drastically based on historical data with the highest persistence towards north‐west part of the basin. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献   

5.
This paper investigates three categories of models that are derived from the equilibrium temperature concept to estimate water temperatures in the Loire River in France and the sensitivity to changes in hydrology and climate. We test the models' individual performances for simulating water temperatures and assess the variability of the thermal responses under the extreme changing climate scenarios that are projected for 2081–2100. We attempt to identify the most reliable models for studying the impact of climate change on river temperature (Tw). Six models are based on a linear relationship between air temperatures (Ta) and equilibrium temperatures (Te), six depend on a logistic relationship, and six rely on the closure of heat budgets. For each category, three approaches that account for the river's thermal exchange coefficient are tested. In addition to air temperatures, an index of day length is incorporated to compute equilibrium temperatures. Each model is analysed in terms of its ability to simulate the seasonal patterns of river temperatures and heat peaks. We found that including the day length as a covariate in regression‐based approaches improves the performance in comparison with classical approaches that use only Ta. Moreover, the regression‐based models that rely on the logistic relationship between Te and Ta exhibit root mean square errors comparable (0.90 °C) with those obtained with a classical five‐term heat budget model (0.82 °C), despite a small number of required forcing variables. In contrast, the regressive models that are based on a linear relationship Te = f(Ta) fail to simulate the heat peaks and are not advisable for climate change studies. The regression‐based approaches that are based on a logistic relationship and the heat balance approaches generate notably similar responses to the projected climate changes scenarios. This similarity suggests that sophisticated thermal models are not preferable to cruder ones, which are less time‐consuming and require fewer input data. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   

6.
This paper assesses linear regression‐based methods in downscaling daily precipitation from the general circulation model (GCM) scale to a regional climate model (RCM) scale (45‐ and 15‐km grids) and down to a station scale across North America. Traditional downscaling experiments (linking reanalysis/dynamical model predictors to station precipitation) as well as nontraditional experiments such as predicting dynamic model precipitation from larger‐scale dynamic model predictors or downscaling dynamic model precipitation from predictors at the same scale are conducted. The latter experiments were performed to address predictability limit and scale issues. The results showed that the downscaling of daily precipitation occurrence was rarely successful at all scales, although results did constantly improve with the increased resolution of climate models. The explained variances for downscaled precipitation amounts at the station scales were low, and they became progressively better when using predictors from a higher‐resolution climate model, thus showing a clear advantage in using predictors from RCMs driven by reanalysis at its boundaries, instead of directly using reanalysis data. The low percentage of explained variances resulted in considerable underestimation of daily precipitation mean and standard deviation. Although downscaling GCM precipitation from GCM predictors (or RCM precipitation from RCM predictors) cannot really be considered downscaling, as there is no change in scale, the exercise yields interesting information as to the limit in predictive ability at the station scale. This was especially clear at the GCM scale, where the inability of downscaling GCM precipitation from GCM predictors demonstrates that GCM precipitation‐generating processes are largely at the subgrid scale (especially so for convective events), thus indicating that downscaling precipitation at the station scale from GCM scale is unlikely to be successful. Although results became better at the RCM scale, the results indicate that, overall, regression‐based approaches did not perform well in downscaling precipitation over North America. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

7.
An ensemble of stochastic daily rainfall projections has been generated for 30 stations across south‐eastern Australia using the downscaling nonhomogeneous hidden Markov model, which was driven by atmospheric predictors from four climate models for three IPCC emissions scenarios (A1B, A2, and B1) and for two periods (2046–2065 and 2081–2100). The results indicate that the annual rainfall is projected to decrease for both periods for all scenarios and climate models, with the exception of a few scenarios of no statistically significant changes. However, there is a seasonal difference: two downscaled GCMs consistently project a decline of summer rainfall, and two an increase. In contrast, all four downscaled GCMs show a decrease of winter rainfall. Because winter rainfall accounts for two‐thirds of the annual rainfall and produces the majority of streamflow for this region, this decrease in winter rainfall would cause additional water availability concerns in the southern Murray–Darling basin, given that water shortage is already a critical problem in the region. In addition, the annual maximum daily rainfall is projected to intensify in the future, particularly by the end of the 21st century; the maximum length of consecutive dry days is projected to increase, and correspondingly, the maximum length of consecutive wet days is projected to decrease. These changes in daily sequencing, combined with fewer events of reduced amount, could lead to drier catchment soil profiles and further reduce runoff potential and, hence, also have streamflow and water availability implications. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   

8.
Continuous temperature measurements at 11 stream sites in small lowland streams of North Zealand, Denmark over a year showed much higher summer temperatures and lower winter temperatures along the course of the stream with artificial lakes than in the stream without lakes. The influence of lakes was even more prominent in the comparisons of colder lake inlets and warmer outlets and led to the decline of cold‐water and oxygen‐demanding brown trout. Seasonal and daily temperature variations were, as anticipated, dampened by forest cover, groundwater input, input from sewage plants and high downstream discharges. Seasonal variations in daily water temperature could be predicted with high accuracy at all sites by a linear air‐water regression model (r2: 0·903–0·947). The predictions improved in all instances (r2: 0·927–0·964) by a non‐linear logistic regression according to which water temperatures do not fall below freezing and they increase less steeply than air temperatures at high temperatures because of enhanced heat loss from the stream by evaporation and back radiation. The predictions improved slightly (r2: 0·933–0·969) by a multiple regression model which, in addition to air temperature as the main predictor, included solar radiation at un‐shaded sites, relative humidity, precipitation and discharge. Application of the non‐linear logistic model for a warming scenario of 4–5 °C higher air temperatures in Denmark in 2070‐2100 yielded predictions of temperatures rising 1·6–3·0 °C during winter and summer and 4·4–6·0 °C during spring in un‐shaded streams with low groundwater input. Groundwater‐fed springs are expected to follow the increase of mean air temperatures for the region. Great caution should be exercised in these temperature projections because global and regional climate scenarios remain open to discussion. Copyright © 2006 John Wiley & Sons, Ltd.  相似文献   

9.
Skilful and reliable precipitation data are essential for seasonal hydrologic forecasting and generation of hydrological data. Although output from dynamic downscaling methods is used for hydrological application, the existence of systematic errors in dynamically downscaled data adversely affects the skill of hydrologic forecasting. This study evaluates the precipitation data derived by dynamically downscaling the global atmospheric reanalysis data by propagating them through three hydrological models. Hydrological models are calibrated for 28 watersheds located across the southeastern United States that is minimally affected by human intervention. Calibrated hydrological models are forced with five different types of datasets: global atmospheric reanalysis (National Centers for Environmental Prediction/Department of Energy Global Reanalysis and European Centre for Medium‐Range Weather Forecasts 40‐year Reanalysis) at their native resolution; dynamically downscaled global atmospheric reanalysis at 10‐km grid resolution; stochastically generated data from weather generator; bias‐corrected dynamically downscaled; and bias‐corrected global reanalysis. The reanalysis products are considered as surrogates for large‐scale observations. Our study indicates that over the 28 watersheds in the southeastern United States, the simulated hydrological response to the bias‐corrected dynamically downscaled data is superior to the other four meteorological datasets. In comparison with synthetically generated meteorological forcing (from weather generator), the dynamically downscaled data from global atmospheric reanalysis result in more realistic hydrological simulations. Therefore, we conclude that dynamical downscaling of global reanalysis, which offers data for sufficient number of years (in this case 22 years), although resource intensive, is relatively more useful than other sources of meteorological data with comparable period in simulating realistic hydrological response at watershed scales. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

10.
In this study, we used the statistical downscaling model (SDSM) to estimate mean and extreme precipitation indices under present and future climate conditions for Shikoku, Japan. Specifically, we considered the following mean and extreme precipitation indices: mean daily precipitation, R10 (number of days with precipitation >10 mm/day), R5d (annual maximum precipitation accumulated over 5 days), maximum dry-spell length (MaDSL), and maximum wet-spell length (MaWSL). Initially, we calibrated the SDSM model using the National Center for environmental prediction (NCEP) reanalysis dataset and daily time series of precipitation for ten locations in Shikoku which were acquired from the surface weather observation point dataset. Subsequently, we used the validated SDSM, using data from NCEP and outputs form general circulation models (GCM), to predict future precipitation indices. Specifically, the HadCM3 GCM was run under the special report on emissions scenarios (SRES) A2 and B2 scenarios, and the CGCM3 GCM was run under the SRES A2 and A1B scenarios. The results showed that: (1) the SDSM can reasonably be used to simulate mean and extreme precipitation indices in the Shikoku region; (2) the values of annual R10 were predicated to decrease in the future in northern Shikoku under all climate scenarios; conversely, the values of annual R10 were predicted to increase in the future in the range of 0–15 % in southern and western Shikoku. The values of annual MaDSL were predicted to increase in northern Shikoku, and the values of annual MaWSL were predicted to decrease in northeastern Shikoku; (3) the spatial variation of precipitation indices indicated the potential for an increased occurrence of drought across northeastern Shikoku and an increased occurrence of flood events in the southwestern part of Shikoku, especially under the A2 and A1B scenarios; (4) characteristics of future precipitation may differ between the northern and southern sides of the Shikoku Mountains. Regional variations in extreme precipitation indices were not notably evident in the B2 scenario compared to the other scenarios.  相似文献   

11.
Climate change would significantly affect many hydrologic systems, which in turn would affect the water availability, runoff, and the flow in rivers. This study evaluates the impacts of possible future climate change scenarios on the hydrology of the catchment area of the Tunga–Bhadra River, upstream of the Tungabhadra dam. The Hydrologic Engineering Center's Hydrologic Modeling System version 3.4 (HEC‐HMS 3.4) is used for the hydrological modelling of the study area. Linear‐regression‐based Statistical DownScaling Model version 4.2 (SDSM 4.2) is used to downscale the daily maximum and minimum temperature, and daily precipitation in the four sub‐basins of the study area. The large‐scale climate variables for the A2 and B2 scenarios obtained from the Hadley Centre Coupled Model version 3 are used. After model calibration and testing of the downscaling procedure, the hydrological model is run for the three future periods: 2011–2040, 2041–2070, and 2071–2099. The impacts of climate change on the basin hydrology are assessed by comparing the present and future streamflow and the evapotranspiration estimates. Results of the water balance study suggest increasing precipitation and runoff and decreasing actual evapotranspiration losses over the sub‐basins in the study area. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   

12.
利用降尺度方法对CMIP5全球气候模式进行空间降尺度并以此研究鄱阳湖流域未来气候时空变化趋势,能够为流域生态环境保护提供数据、技术和理论上的支持.通过简化原始网络结构,在网络首部添加插值层,采用反卷积算法作为上采样算法对传统U-Net网络进行改进,建立基于深度学习的气候模式空间降尺度模型(DLDM).以1965-200...  相似文献   

13.
Many impact studies require climate change information at a finer resolution than that provided by general circulation models (GCMs). Therefore the outputs from GCMs have to be downscaled to obtain the finer resolution climate change scenarios. In this study, an automated statistical downscaling (ASD) regression-based approach is proposed for predicting the daily precipitation of 138 main meteorological stations in the Yangtze River basin for 2010–2099 by statistical downscaling of the outputs of general circulation model (HadCM3) under A2 and B2 scenarios. After that, the spatial–temporal changes of the amount and the extremes of predicted precipitation in the Yangtze River basin are investigated by Mann–Kendall trend test and spatial interpolation. The results showed that: (1) the amount and the change pattern of precipitation could be reasonably simulated by ASD; (2) the predicted annual precipitation will decrease in all sub-catchments during 2020s, while increase in all sub-catchments of the Yangtze River Basin during 2050s and during 2080s, respectively, under A2 scenario. However, they have mix-trend in each sub-catchment of Yangtze River basin during 2020s, but increase in all sub-catchments during 2050s and 2080s, except for Hanjiang River region during 2080s, as far as B2 scenario is concerned; and (3) the significant increasing trend of the precipitation intensity and maximum precipitation are mainly occurred in the northwest upper part and the middle part of the Yangtze River basin for the whole year and summer under both climate change scenarios and the middle of 2040–2060 can be regarded as the starting point for pattern change of precipitation maxima.  相似文献   

14.
Sujana Dhar  Asis Mazumdar 《水文研究》2009,23(16):2394-2406
India is a large developing country with nearly two‐thirds of the population depending directly on the climate‐sensitive sectors such as agriculture, fisheries and forests. A very well‐calibrated Soil and Water Assessment Tool (R2 = 0·9968, NSE = 0·91) was exercised over the Kangsabati river watershed in Bankura district of West Bengal, India, for a year including monsoon and non‐monsoon period in order to evaluate projected parameters for agricultural activities. Evapotranspiration, transmission losses, potential evapotranspiration and lateral flow to reach are evaluated from the years 2041–2050 in order to generate a picture for sustainable development of the river basin and its inhabitants. The projected climate change under various scenarios is likely to have implications on food production, water supply, biodiversity and livelihoods. India has a significant stake in scientific advancement as well as an international understanding to promote mitigation and adaptation. This requires improved scientific understanding, capacity building, networking and broad consultation processes. This paper is a commitment towards the planning, management and development of the water resources of the Kangsabati river by presenting detailed future scenarios of the Kangsabati river basin over the mentioned time period. The major findings of this paper were that of all the chosen projected parameters, transmission losses, soil water content, potential evapotranspiration, evapotranspiration and lateral flow to reach, display an increasing trend over the time period of years 2041–2050. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献   

15.
Five downscaling techniques, namely the statistical downscaling model, the automated statistical downscaling method, the change factor (CF) method, the advanced CF method, the Weather generator (LarsWG5) method, are applied to the upstream basin of the Huaihe River. Changes in regional climate scenarios and hydrology variables are compared in future periods to investigate the uncertainty associated with the downscaling techniques. Paired-sample T test is applied to evaluation the significant of the difference of the means between the observed data and the downscaled data in the future. The Xinanjiang rainfall–runoff model is employed to simulate the rainfall–runoff relation. The results demonstrate that the downscaling techniques utilized herein predict an increased tendency in the future. The increases range of maximum temperature (Tmax) is between 3.7 and 4.7 °C until the time period of 2070–2099 (2080s). While, the increases range of minimum temperature (Tmin) is between 2.8 and 4.9 °C until 2080s. The research presented herein determined that there is an increase predicted for the peaks over threshold (discussed in the paper) and a decrease predicted for the peaks below the threshold (discussed in the paper) in the future, which illustrates that the temperature would rise gradually in the future. Precipitation changes are not as obvious as temperatures changes and tend to be influence by the season. Most downscaling techniques predict increases, and others indict decreases. The annual mean precipitation range changes between 3.2 and 53.3 %, and moreover, these changes vary from season to season.  相似文献   

16.
Integrated dynamic water and chloride balance models with a catchment‐scale hydrological model (PRMS) are used to investigate the response of a terminal tropical lake, Lake Abiyata, to climate variability and water use practices in its catchment. The hydrological model is used to investigate the response of the catchment to different climate and land‐use change scenarios that are incorporated into the lake model. Lake depth–area–volume relationships were established from lake bathymetries. Missing data in the time series were filled using statistical regression techniques. Based on mean monthly data, the lake water balance model produced a good agreement between the simulated and observed levels of Lake Abiyata for the period 1968–83. From 1984 onwards the simulated lake level is overestimated with respect to the observed one, while the chloride concentration is largely underestimated. This discrepancy is attributed to human use of water from the influent rivers or directly from the lake. The simulated lake level and chloride concentration are in better agreement with observed values (r2 = 0·96) when human water use for irrigation and salt exploitation are included in the model. A comparison of the simulation with and without human consumption indicates that climate variability controls the interannual fluctuations and that the human water use affects the equilibrium of the system by strongly reducing the lake level. Sensitivity analysis based on a mean climatic year showed that, after prolonged mean climatic conditions, Lake Abiyata reacts more rapidly to an abrupt shift to wetter conditions than to dry conditions. This study shows the significant sensitivity of the level and salinity of the terminal Lake Abiyata to small changes in climate or land use, making it a very good ‘recorder’ of environmental changes that may occur in the catchment at different time scales. Copyright © 2004 John Wiley & Sons, Ltd.  相似文献   

17.
This research investigates the potential impacts of climate change on stormwater quantity and quality generated by urban residential areas on an event basis in the rainy season. An urban residential stormwater drainage area in southeast Calgary, Alberta, Canada is the focus of future climate projections from general circulation models (GCMs). A regression‐based statistical downscaling tool was employed to conduct spatial downscaling of daily precipitation and daily mean temperature using projection outputs from the coupled GCM. Projected changes in precipitation and temperature were applied to current climate scenarios to generate future climate scenarios. Artificial neural networks (ANNs) developed for modelling stormwater runoff quantity and quality used projected climate scenarios as network inputs. The hydrological response to climate change was investigated through stormwater runoff volume and peak flow, while the water quality responses were investigated through the event mean value (EMV) of five parameters: turbidity, conductivity, water temperature, dissolved oxygen (DO) and pH. First flush (FF) effects were also noted. Under future climate scenarios, the EMVs of turbidity increased in all storms except for three events of short duration. The EMVs of conductivity were found to decline in small and frequent storms (return period < 5 years); but conductivity EMVs were observed to increase in intensive events (return period ≥ 5 years). In general, an increasing EMV was observed for water temperature, whereas a decreasing trend was found for DO EMV. No clear trend was found in the EMV of pH. In addition, projected future climate scenarios do not produce a stronger FF effect on dissolved solids and suspended solids compared to that produced by the current climate scenario. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   

18.
《水文研究》2017,31(1):35-50
A methodology based on long‐term dynamical downscaling to analyse climate change effects on watershed‐scale precipitation during a historical period is proposed in this study. The reliability and applicability of the methodology were investigated based on the long‐term dynamical downscaling results. For an application of the proposed methodology, two study watersheds in Northern California were selected: the Upper Feather River watershed and the Yuba River watershed. Then, precipitation was reconstructed at 3‐km spatial resolution and hourly intervals over the study watersheds for 141 water years from 1 October 1871 to 30 September 2012 by dynamically downscaling a long‐term atmospheric reanalysis dataset, 20th century global reanalysis version 2 by means of a regional climate model. The reconstructed precipitation was compared against observed precipitation, in order to assess the applicability of the proposed methodology for the reconstruction of watershed‐scale precipitation and to validate this methodology. The validation shows that the reconstructed precipitation is in good agreement with observation data. Moreover, the differences between the reconstructed precipitation and the corresponding observations do not significantly change through the historical period. After the validation, climate change analysis was conducted based on the reconstructed precipitation. Through this analysis, it was found that basin‐average precipitation has increased significantly over both of the study watersheds during the historical period. An upward trend in monthly basin‐average precipitation is not significant in wet months except February while it is significant in dry months of the year. Furthermore, peak values of basin‐average precipitation are also on an upward trend over the study watersheds. The upward trend in peak basin‐average precipitation is more significant during a shorter duration. Copyright © 2016 John Wiley & Sons, Ltd.  相似文献   

19.
Jew Das 《水文科学杂志》2018,63(7):1020-1046
In this study, classification- and regression-based statistical downscaling is used to project the monthly monsoon streamflow over the Wainganga basin, India, using 40 global climate model (GCM) outputs and four representative concentration pathways (RCP) scenarios. Support vector machine (SVM) and relevance vector machine (RVM) are considered to perform downscaling. The RVM outperforms SVM and is used to simulate future projections of monsoon flows for different periods. In addition, variability in water availability with uncertainty and change point (CP) detection are accomplished by flow–duration curve and Bayesian analysis, respectively. It is observed from the results that the upper extremes of monsoon flows are highly sensitive to increases in temperature and show a continuous decreasing trend. Medium and low flows are increasing in future projections for all the scenarios, and high uncertainty is noticed in the case of low flows. An early CP is detected in the case of high emissions scenarios.  相似文献   

20.
Pesticide sorption on to the soil has a significant role in deciding the fate and behavior of pesticides in soil and aquatic environment. The present study investigates the adsorption of monocrotophos (MCP) and dichlorvos (DDVP) on the three soils of Malwa region of Punjab, India under different conditions. Batch adsorption experiments were preformed in replicates using 2 g of air‐dried soil and varying concentrations of pesticides and 20 mL of 0.01 M CaCl2 as background electrolyte. The results revealed high adsorption of MCP and DDVP in soil B with kf‐values 0.1261 and 0.0498 and n‐values 2.7345 and 1.831, respectively. The adsorption isotherms obtained were analyzed and the data was subjected to classical Langmuir, Freundlich, and Temkin models. The experimental data best fitted to the logarithm form of Freundlich and Temkin model. Kinetics analyses were performed using pseudo‐first order, pseudo‐second order, and intraparticle diffusion models. The regression results showed that the experimental data fitted very well with the pseudo‐second order kinetic model as correlation coefficient value is very closer to 1 and also followed the intraparticle diffusion model, whereas, diffusion is not only the rate controlling step. The percentages desorption with tap and distilled water is 32–64% for MCP and 25–48% for DDVP.  相似文献   

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