首页 | 本学科首页   官方微博 | 高级检索  
相似文献
 共查询到20条相似文献,搜索用时 31 毫秒
1.
The 3.2 km-thick late Precambrian Kongsfjord Formation Submarine Fan shows well-developed middle-fan facies-associations. Channel deposits are characterised by discrete packets of coarse-grained, medium to thick-bedded, amalgamated sandstone turbidites and other mass-flow deposits, generally 10 to 30 m thick. Individual beds, or packets of beds, wedge out and channel bases cut down by up to 11 m over a lateral distance of 150 m. Channel deposits often comprise a thinning-and-fining-upward sequence although they vary greatly in clarity. Interchannel deposits occur as packets, tens of centimetres to 25 m thick, of thin and very thin bedded Bouma Tcde siltstones and mudstones. Palaeocurrents within interchannel deposits commonly diverge from those of adjacent channel sandstones. Within the interchannel deposits, isolated beds or packets of beds occur that are both thicker bedded and coarser grained than the surrounding beds; these unusual deposits are sheet-like or fill small channels, and are interpreted as crevasse splays, lobes and channels. Packets, up to a few metres thick, of laterally discontinuous siltstone turbidites occur immediately above some of the channel sandstones, rarely below, and in some cases within interchannel deposits. These siltstones are thin to medium-bedded, show Bouma Tcd, with Tc often as climbing-ripple lamination, and commonly show soft-sediment deformation as slides, slumps, liquefaction and fluidisation structures. Palaeoflow within these packets, compared to adjacent channel sandstones, diverges by up to 90°, and in some cases channel sandstones are seen to pass laterally into these deposits with a swing in palaeocurrents from parallel to the inferred channel axis, to perpendicular to it. These deposits are thought to be levees. Channel-margin deposits are most distinctive, and they are recognised by extreme lateral wedging of channel sandstones, with concomitant thinning and fining of individual beds and their amalgamation towards the channel axis. Sliding and slumping of channel margin deposits is common. Throughout the Kongsfjord Formation Submarine Fan, channel sandstone palaeocurrents suggest a sediment-transport direction to the NE quadrant, although some channels funnelled sediment towards the southeast.  相似文献   

2.
This paper describes recent proglacial lacustrine sediments exposed by the drainage of a small (probably never more than 0·03 km2) ice-dammed lake basin at Leirbreen, central Jotunheimen, Norway. The dominant facies include ripple-laminated, massive and horizontally-stratified sands, massive and horizontally-laminated silts, and irregularly-laminated fine sands and silts. The major control on lake circulation and the nature and distribution of these facies was an underflow driven by a subglacial meltwater stream which formed the major lake input. Although much of the sedimentary sequence indicates a pulsatory input, the proximal character of this small lake prevented the development of classic varved silts. Compressional deformation of shoreline sediments was due to winter lake ice push. Other deformational processes included the grounding of icebergs, water escape and syn-sedimentary downslope collapse. Observations from an adjacent small ice-marginal lake at Leirbreen provide support for several of the inferences drawn from the sediments of the former ice-dammed lake.  相似文献   

3.
Drift deposits exposed in a large open cut are described. The basal member of the sequence consists of bedded sandy gravels, and these are overlain by a grey silty sand containing abundant striated pebbles and boulders. The uppermost deposit consists of a brown poorly sorted drift containing silty and sandy lenses. Analysis of the texture, index properties and densities of the sediments, together with the shape, lithology and fabric of the contained pebbles suggests that the basal gravels were deposited by subglacial meltwater, the grey drift is a lodgement till, and the uppermost brown rubbly drift was formed by solifluction of the till, with the addition of frost shattered sandstone from the hilltop above. It is suggested that the glacigenic sediments are of Devensian age, and the solifluction layer Late Devensian.  相似文献   

4.
The Lower Cretaceous Britannia Formation (North Sea) includes an assemblage of sandstone beds interpreted here to be the deposits of turbidity currents, debris flows and a spectrum of intermediate flow types termed slurry flows. The term ‘slurry flow’ is used here to refer to watery flows transitional between turbidity currents, in which particles are supported primarily by flow turbulence, and debris flows, in which particles are supported by flow strength. Thick, clean, dish‐structured sandstones and associated thin‐bedded sandstones showing Bouma Tb–e divisions were deposited by high‐ and low‐density turbidity currents respectively. Debris flow deposits are marked by deformed, intraformational mudstone and sandstone masses suspended within a sand‐rich mudstone matrix. Most Britannia slurry‐flow deposits contain 10–35% detrital mud matrix and are grain supported. Individual beds vary in thickness from a few centimetres to over 30 m. Seven sedimentary structure division types are recognized in slurry‐flow beds: (M1) current structured and massive divisions; (M2) banded units; (M3) wispy laminated sandstone; (M4) dish‐structured divisions; (M5) fine‐grained, microbanded to flat‐laminated units; (M6) foundered and mixed layers that were originally laminated to microbanded; and (M7) vertically water‐escape structured divisions. Water‐escape structures are abundant in slurry‐flow deposits, including a variety of vertical to subvertical pipe‐ and sheet‐like fluid‐escape conduits, dish structures and load structures. Structuring of Britannia slurry‐flow beds suggests that most flows began deposition as turbidity currents: fully turbulent flows characterized by turbulent grain suspension and, commonly, bed‐load transport and deposition (M1). Mud was apparently transported largely as hydrodynamically silt‐ to sand‐sized grains. As the flows waned, both mud and mineral grains settled, increasing near‐bed grain concentration and flow density. Low‐density mud grains settling into the denser near‐bed layers were trapped because of their reduced settling velocities, whereas denser quartz and feldspar continued settling to the bed. The result of this kinetic sieving was an increasing mud content and particle concentration in the near‐bed layers. Disaggregation of mud grains in the near‐bed zone as a result of intense shear and abrasion against rigid mineral grains caused a rapid increase in effective clay surface area and, hence, near‐bed cohesion, shear resistance and viscosity. Eventually, turbulence was suppressed in a layer immediately adjacent to the bed, which was transformed into a cohesion‐dominated viscous sublayer. The banding and lamination in M2 are thought to reflect the formation, evolution and deposition of such cohesion‐dominated sublayers. More rapid fallout from suspension in less muddy flows resulted in the development of thin, short‐lived viscous sublayers to form wispy laminated divisions (M3) and, in the least muddy flows with the highest suspended‐load fallout rates, direct suspension sedimentation formed dish‐structured M4 divisions. Markov chain analysis indicates that these divisions are stacked to form a range of bed types: (I) dish‐structured beds; (II) dish‐structured and wispy laminated beds; (III) banded, wispy laminated and/or dish‐structured beds; (IV) predominantly banded beds; and (V) thickly banded and mixed slurried beds. These different bed types form mainly in response to the varying mud contents of the depositing flows and the influence of mud on suspended‐load fallout rates. The Britannia sandstones provide a remarkable and perhaps unique window on the mechanics of sediment‐gravity flows transitional between turbidity currents and debris flows and the textures and structuring of their deposits.  相似文献   

5.
The most extensive Jurassic marine transgression in North America reached its maximum limits during the Oxfordian Age. At this time, siliciclastic sediments were being brought into the North American seaway from an uplifted zone to the west. Within this setting, complexes of sand ridges and coquinoid sands layers were deposited. Coquinoid sandstones appear to fill erosional scours and were interpreted as channel fills. Re-evaluation of these features in the light of recently discovered attributes of modern shelf sediments and processes has produced a revised model of coquinoid sand deposition in this setting. Coquinoid sandstones which fill ‘channel-like’ scours in the Oxfordian (Upper Jurassic) rocks of central Wyoming and south-central Montana, appear to have formed through the migration of sand waves across the crests of inner shelf sand ridges during periods of storm and tidal flow. Erosion in the zone of flow reattachment in the troughs between sand waves resulted in the development of shell lags. Migration of these scour zones as the sand waves advanced resulted in the deposition of sheet-like coquinoid sandstone bodies. Sand waves crossing the ridge crest tended to migrate more slowly and to be overstepped by later sand waves. Sand wave troughs thus buried have channel-like geometries with apparent epsilon bedding.  相似文献   

6.
阐述了砂质碎屑流沉积特征、研究现状及其与其他深海碎屑沉积的区别 ,认为西藏特提斯喜马拉雅上侏罗统 -下白垩统深海沉积背景下的块状砂岩具有砂质碎屑流沉积性质 ,指出深海相中的块状砂岩可以预测。  相似文献   

7.
Late Pleistocene age terrace deposits are exposed in the narrow cliffed coastal plain of Bahia Coyote, Baja California Sur, resting unconformably on the lagoonal-shallow water volcaniclastics of the early Miocene Cerro Colorado Member of the El Cien Formation. The terrace is dissected by widely spaced arroyos and partically covered by alluvial fans in the inner and central areas. The marine deposits vary in thickness from 0.5 to 10 m and were laid down in pre-existing erosional channels and depressions in the Pleistocene landscape. The sequence begins with a cobble conglomerate with oyster shells, overlain by poorly bedded molluscan-rich bioclastic sands and coral rubble, beds of massive Porites in growth position and coral-rhodolith sands and marls. Beach sands and gravels and coastal dunes cap the sequence.Samples of Porites panamensis selected for U/Th dating are well-preserved aragonite (>95%). Preliminary results yield U/Th ages of 109–209 ka but the corals have initial δ 234U values in excess of modern seawater values. This indicates open-system behavior and uncertainty associated with the ages. A corrected age for the top of the massive Porites unit suggests that the corals grew during the last interglacial, marine isotope stage (MIS) 5e sea level high stand.Assuming global sea level during MIS 5e was ca. 4–5 m above present-day sea level (McCulloch and Esat, 2000) and the growth position of the corals was 1–5 m below sea level, the terraces have been uplifted between 12 and 25 m (12–15 cm/kyr). This is consistent with other terrace-based uplift rates for the central Baja California peninsula, north of the La Paz fault.  相似文献   

8.
重力流沉积:理论研究与野外识别   总被引:10,自引:3,他引:10  
重力流沉积是(半)深海和深湖环境中一种重要的沉积现象,因此准确识别重力流沉积对恢复古代沉积环境具有重要意义。从沉积物重力流的基本理论出发,介绍四类重力流沉积的特点和野外鉴别特征。碎屑流沉积表现为颗粒大小混杂,底面平坦,板条状砾石平行层面排列;超高密度流沉积的砂岩呈厚层状或块状,砂岩内部经常出现较大砾石或泥岩碎片,泄水构...  相似文献   

9.
For the characterization of sediments, Computer Controlled Scanning Electron Microscopy (CCSEM) is a powerful method in obtaining chemical data on individual mineral grains and modal analysis of the heavy mineral fraction of sediment samples. Here we show how the CCSEM method can be used to evaluate ilmenite ore grade as well as a tool to investigate the source of heavy mineral deposits.The heavy mineral rich deposits in beach sands around the town of Chavara in SW India are characterized by ilmenite with elevated TiO2 contents, often exceeding 60 wt.%. In order to determine the origin of these high-TiO2 ilmenite deposits, we collected a series of beach sediment samples (22) from a c. 800 km long stretch of coastline from northern Kerala state to well within the Tamil Nadu state. A set (7) of river sediments was also taken, roughly covering the catchment area to the beach samples. The data show that the sediments in the Chavara high-Ti ilmenite deposit are distinguished by minor elements in ilmenite, garnet chemistry and heavy mineral assemblage: Chavara ilmenite has high MgO and low MnO contents; garnets have low grossular components and the heavy mineral assemblage is dominated by sillimanite–kyanite in addition to ilmenite. These features correlate with basement geology in the hinterland, and with sediments from rivers, draining the basement. Based on these observations we conclude that high-Ti ilmenite from Chavara beaches originates in the khondalite belt of high-grade metasediments. Our study demonstrates rapid mineral analyses in sediments by CCSEM to be efficient in the characterization of mineral compositions and assemblages in sediments, in the identification of possible source regions and thus ultimately in exploration for industrial mineral resources.  相似文献   

10.
在详细野外剖面工作的基础上,通过岩性特征、沉积构造及沉积序列等的系统观察研究,发现济源盆地下侏罗统鞍腰组重力流沉积由滑塌沉积、砂质碎屑流沉积和浊流沉积构成。滑塌沉积以砂岩和泥岩的混杂、岩层的滑动变形以及泥岩呈碎块被卷入砂岩层中为特征;砂质碎屑流沉积常呈厚层块状,颗粒分选和磨圆较差,杂基较多,可见漂浮于层内的石灰岩砾石;常见的浊流沉积分为2种类型: 具有明显正粒序结构的浊流沉积和砂泥岩薄互层的浊流沉积,可用鲍马序列来描述。鞍腰组重力流沉积可划分为3个沉积序列: 序列A记录了滑塌沉积→砂质碎屑流沉积→浊流沉积→深湖沉积的转换过程;序列B表现为砂质碎屑流与浊流沉积的叠覆;序列C由浊流及湖泊沉积构成,并经历了由序列A→序列B→序列C的沉积演化过程。重力流的形成受秦岭造山带于早侏罗世沿三门峡—鲁山—舞阳断裂发生逆冲推覆作用的控制,其沉积演化指示了秦岭造山带造山作用由强到弱的过程。  相似文献   

11.
During the deposition of the Chang-7 (Ch-7) and Chang-6 (Ch-6) units in the Upper Triassic, gravity flows were developed widely in a deep lake in the southwestern Ordos Basin, China. Based on cores, outcrops, well-logs and well-testing data, this paper documents the sedimentary characteristics of the gravity-flow deposits and constructs a depositional model. Gravity-flow deposits in the study area comprise seven lithofacies types, which are categorised into four groups: slides and slumps, debris-flow-dominated lithofacies, turbidity-current-dominated lithofacies, and deep-water mudstone-dominated lithofacies. The seven lithofacies form two sedimentary entities: sub-lacustrine fan and the slump olistolith, made up of three and two lithofacies associations, respectively. Lithofacies association 1 is a channel–levee complex with fining-/thinning-upward sequences whose main part is characterised by sandy debris flow-dominated, thick-bedded massive sandstones. Lithofacies association 2 represents distributary channelised lobes of sub-lacustrine fans, which can be further subdivided into distributary channel, channel lateral margin and inter-channel. Lithofacies association 3 is marked by non-channelised lobes of sub-lacustrine fans, including sheet-like turbidites and deep-lake mudstones. Lithofacies association 4 is represented by proximal lobes of slump olistolith, consisting of slides and slumps. Lithofacies association 5 is marked by distal lobes of slump olistolith, comprising tongue-shaped debris flow lobes and turbidite lobes. It is characterised by sandy debris flow, muddy debris flow-dominated sandstone and sandstone with classic Bouma sequences. Several factors caused the generation of gravity flows in the Ordos Basin, including sediment supply, terrain slope and external triggers, such as volcanisms, earthquakes and seasonal floods. The sediment supply of sub-lacustrine fan was most likely from seasonal floods with a high net-to-gross and incised channels. Triggered by volcanisms and earthquakes, the slump olistolith is deposited by the slumping and secondary transport of unconsolidated sediments in the delta front or prodelta with a low net-to-gross and no incised channels.  相似文献   

12.
Chert spheroids are distinctive, early‐diagenetic features that occur in bedded siliceous deposits spanning the Phanerozoic. These features are distinct in structure and genesis from similar, concentrically banded ‘wood‐grain’ or ‘onion‐skin’ chert nodules from carbonate successions. In the Miocene Monterey Formation of California (USA), chert spheroids are irregular, concentrically banded nodules, which formed by a unique version of brittle differential compaction that results from the contrasting physical properties of chert and diatomite. During shortening, there is brittle fracture of diatomite around, and horizontally away from, the convex surface of strain‐resistant chert nodules. Unlike most older siliceous deposits, the Monterey Formation still preserves all stages of silica diagenesis, thus retaining textural, mineralogical and geochemical features key to unravelling the origin of chert spheroids and other enigmatic chert structures. Chert spheroids found in opal‐A diatomite form individual nodules composed of alternating bands of impure opal‐CT chert and pure opal‐CT or chalcedony. With increased burial diagenesis, surrounding diatomite transforms to bedded porcelanite or chert, and spheroids no longer form discrete nodules, yet still display characteristic concentric bands of pure and impure microcrystalline quartz and chalcedony. Petrographic observations show that the purer silica bands are composed of void‐filling cement that precipitated in curved dilational fractures, and do not reflect geochemical growth‐banding in the manner of Liesegang phenomena invoked to explain concentrically banded chert nodules in limestone. Chertification of bedded siliceous sediment can occur more shallowly (< 100 m) and rapidly (< 1 Myr) than the bulk silica phase transitions forming porcelanite or siliceous shale in the Monterey Formation and other hemipelagic/pelagic siliceous deposits. Early diagenesis is indicated by physical properties, deformational style and oxygen‐isotopic composition of chert spheroids. Early‐formed cherts formed by pore‐filling impregnation of the purest primary diatomaceous beds, along permeable fractures and in calcareous–siliceous strata.  相似文献   

13.
In glacial sedimentology there has been a recent improvement in the understanding of both progressive and polyphase deformation of glacigenic sequences, and the role played by water during these complex deformation histories. However, the processes occurring during the detachment and transport of sediment blocks during ice-marginal glaciotectonic thrusting remain poorly understood. This lack of understanding is addressed in detail through a macro- and microscale study of the deformation structures in the glacigenic sequence exposed at Hayberries, Teesdale, County Durham (UK), where esker sands and gravels and associated tills truncate and overlie a sequence of rhythmically bedded glacilacustrine sands, silts and clays. Thrusts within the glacilacustrine and glacifluvial sediments appear to be relatively sharp, planar structures. However, orientated thin sections reveal that these bedding-parallel detachments are marked by a thin layer of massive to foliated sand. The geometry of both meso and small-scale folds and sense of displacement on the thrusts is consistent with both brittle and ductile structures having formed in response to ice-push from the N/NW. Detailed analysis of the thin sections reveals that initial folding and thrusting was followed by the liquefaction and injection of a massive, matrix poor sand along the propagating thrust. Evidence for liquefaction and injection (sand-filled veins) increases towards the NW consistent with fluid flow and sediment injection accompanying SE-directed ice-push. These results suggest that the introduction of pressurised meltwater and sediment along the thrusts during deformation may facilitate decoupling and displacement along these detachments by thrust gliding.  相似文献   

14.
The Otekura Formation (Early Jurassic, Pseudaucella zone) at Sandy Bay comprises part of a 10+ km thick, regressive, forearc shelf and slope sequence, the Hokonui facies belt of the Rangitata Geosyncline. The Otekura Formation is dominantly fine grained, being mostly mudstone, silty mudstone and siltstone. The sediments are volcanogenic throughout. The upper 150 m of the formation contains two 20 m thick, channelized bodies of medium-thick bedded sandy flysch, each associated with thin bedded muddy flysch interpreted as overbank turbidites. Directional indicators within the channel sequence indicate emplacement from the south-southwest. In contrast, rare turbidites that occur below the channel sequence, within the background mudstone sediment, were emplaced from the east, i.e. at right angles to the channelized flows. The immediately overlying Omaru Formation contains more abundant macrofossils, intraclastic conglomerates, and appreciable amounts of traction-emplaced cross-bedded sand. Bioturbated calcareous siltstones with an in situ molluscan fauna follow (Boatlanding Formation), and are of shelf origin. The Omaru Formation is therefore interpreted as a shelf-slope break deposit, and the Otekura Formation as an upper slope facies. Reconnaissance studies indicate that the Otekura Formation is underlain by several kilometres of dominantly fine grained, deep water slope sediments, containing occasional sand and conglomerate filled channels similar to those here described in detail from the Otekura Formation. Such channels are inferred to form when a mass-transported sand, derived from failure higher on the slope, ploughs erosively into the sea floor. After their incision, the channels served for a short time as conduits for downslope transport of sediment, the redeposited deposits of which are found filling each channel. Both channel fills at Sandy Bay are capped by thin-bedded turbidites inferred to have overspilled from similar channels nearby on the slope.  相似文献   

15.
Chalcopyrite-rich bedded and vein mineralization at Kapunda occurs in two locally developed dolosiltstone units within a sequence of generally darker-coloured, finer-grained calcmudstones and siltstones. The Mine Series accumulated in shallow water to supratidal, sabkha-like environments; there is no evidence for igneous activity in the region. Isotope data for bedded sulphides are characteristic of biological sulphate reduction in a restricted basin. It is likely that iron sulphides were produced initially, and that copper was introduced subsequently in mildly oxidizing, highly saline groundwaters, the influence of which is seen in the 13C-18O correlation for dolomite in the mineralized siltstones. Isotopic data support derivation of the veins from their host sediments, and this appears to have occurred before lithification.  相似文献   

16.
The Late Westphalian to Artinskian glaciomarine deposits of the Karoo and Kalahari basins of southern Africa consist of massive and stratified diamictite, mudrock with ice-rafted material, sandstone, silty rhythmite, shale and subordinate conglomerate forming a cyclic succession recognizable across both basins. A complete cycle comprises a resistant basal unit of apparently massive diamictite overlain by softer, bedded stratified diamictite, sandstone and mudrock with a total thickness of as much as 350 m. Four major cycles are observed each separated by bounding surfaces. Lateral facies changes are present in some cycles. The massive diamictites formed as aprons and fans in front of the ice-grounding line, whereas the stratified diamictites represent more distal debris-flow fans. The sandstones originated in different environments as turbidite sands, small subaqueous outwash channel sands and delta front sands. The rhythmites and mudrock represent blanket deposits derived from turbid meltwater plumes. Cycles represent deglaciation sequences which formed during ice retreat phases caused by eustatic changes in the Karoo and Kalahari basins. Evidence for shorter-term fluctuation of the ice margin is present within the major advance-retreat cycles. Hardly any sediment was deposited during lowstand ice sheet expansion, whereas a deglaciation sequence was laid down during a sea-level rise and ice margin retreat with the volume of meltwater and sediment input depending on temporary stillstands of the ice margin during the retreat phase. The duration of the cycles is between 9 and 11 Ma suggesting major global tectono-eustatic events. Smaller cycles probably linked to orbital forcing were superimposed on the longer-term events. A sequence stratigraphic approach using the stacking of deglaciation sequences with the ice margin advance phases forming bounding surfaces, can be a tool in the framework analysis of ancient glaciomarine basin fills.  相似文献   

17.
位于三江地区的云南鲁春铜铅锌矿床和鲁春火山岩有密切的关系.鲁春火山岩锆石U-Pb年龄为270.0±4.6Ma.稀土和微量元素分布图显示该火山岩相对富集轻稀土元素、强烈亏损Na、Ta、和Ti,表明该火山岩具有岛弧火山岩的地球化学特点,反映了该火山岩形成于早二叠世晚期金沙江洋盆消减阶段的岛弧构造环境.鲁春铜铅锌矿床矿石具有条带状、层状构造等沉积作用的特点;矿石的不活泼元素比值和矿区火山岩相近,表明鲁春铜铅锌矿床经历了海西期火山喷流沉积成矿作用.  相似文献   

18.
The large-scale (i.e. bar-scale) structure of channel deposits of the braided, low-sinuosity Calamus River, Nebraska, is described using ground-penetrating radar (GPR) profiles combined with vibracores. Basal erosion surfaces are generally overlain by medium-scale, trough-cross-stratified (sets 3–25 cm thick), very coarse to medium sands, that are associated with relatively high amplitude, discontinuous GPR reflectors. Overlying deposits are bioturbated, small-scale cross-stratified (sets <3 cm thick) and vegetation-rich, fine to very-fine sands, that are associated with low-amplitude discontinuous reflectors. Near-surface peat and turf have no associated GPR reflectors. In along-stream profiles through braid and point bars, most GPR reflectors dip downstream at up to 2° relative to the basal erosion surface, but some reflectors in the upstream parts of bars are parallel to the basal erosion surface or dip upstream. In cross-stream profiles through bars, GPR reflectors are either approximately parallel to bar surfaces or have low-angle inclinations (up to 6°) towards cut banks of adjacent curved channels. Basal erosion surfaces become deeper towards cut banks of curved channels. These structures can be explained by lateral and downstream growth of bars combined with vertical accretion. Convex upwards forms up to 0·5 m high, several metres across and tens of metres long represent episodic accretion of unit bars (scroll bars and bar heads). Stratal patterns in channel fills record a complicated history of erosion and deposition during filling, including migration of relatively small bars. A revised facies model for this type of sandy, braided river has been constructed based on this new information on large-scale bedding structure.  相似文献   

19.
The early diagenetic environment of intertidal sandy sediments (sands) and muddy sediments (muds) is described and compared from two cores taken from an unpolluted part of the Manukau Harbour, New Zealand. Extraction techniques characterized the form of the trace elements (Fe, Mn, S, C, Pb, Zn, Cu) at different depths in the sediment. Dissolved forms of Fe, Mn, and S were measured in interstitial water. Nonresidual metal concentrations, humic acid, FeS, and FeS2 are an order of magnitude higher in the muds than in the sands because of dilution by unreactive sand particles. Muds contain a larger proportion of metals in the mobile fractions; exchangeable (Mn), carbonate (Mn, Fe, Zn), and easily-reducible oxide (Fe, Mn, Zn, Pb). This is due to greater surface area (for Mn adsorption); the favorable conditions for MnCO3, FeCO3, and FeS precipitation; and higher concentrations of easily reducible iron oxide and humic acid. Therefore, compared to the sands, muds are more important as reservoirs for toxic metals, both in terms of quantity and availability. At either site there was very little difference between the forms of Zn, Pb or Cu identified by sequential extraction as sediments changed from oxic to anoxic conditions. One reason for this is that the amounts and proportions of some of the important components that bind metals, viz., amorphous iron hydrous oxides, humic acids, and FeS2, do not change much. Other components that do change with redox conditions, for example, manganese phases and FeS, are only minor components of the sediment. Redox conditions, then, have relatively little effect on trace-metal partitioning in the sediment matrix of these unpolluted sediments.  相似文献   

20.
The Changba Pb-Zn SEDEX deposit occurs in the Middle Devonian sequence of the Anjiaca Formation of the Western Qinling Hercynian Orogen in the Gansu Province, China. The Changba-II orebody is hosted in biotite quartz schist and is the largest of 143 stratiform orebodies that are hosted either in biotite quartz schist or marble. The Changba-II comprises two types of mineralization: a bedded facies and an underlying breccia lens. The bedded section exhibits three sulfide sub-facies zoned from bottom to top: 1) banded sphalerite intercalated with quartz albitite; 2) interbedded massive pyrite and sphalerite ore; and 3) banded sphalerite ore intercalated with banded baritite. Major metallic minerals are sphalerite, pyrite, galena, with minor arsenopyrite, pyrrhotite, boulangerite, and rare chalcopyrite. The bedded sulfides are underlain by a lens of brecciated and albitized biotite-quartz schists cemented by sulfides and tourmaline.Massive and bedded sulfide 34S values range from 8.1 to 29.3, whereas barite 34S values range from 20.8 to 31.5. Disseminated pyrite in footwall schists has 34S values ranging from 8.1 to 10.6, and increase to values ranging from 11.1 to 14.7 in the hangingwall. The lower 34S values for massive and bedded sulfides are interpreted to be derived from progressive bacterial sulfate reduction (BSR) of Devonian seawater in a sulfate-restricted sub-basin. The higher 34S values for massive and bedded sulfides could be a product of quantitative BSR but this is incompatible with barite being more abundant above the bedded sulfides. Instead, it is more likely that thermochemical sulfate reduction of seawater sulfate or of evaporite was the source of heavy hydrothermal sulfur. Heavy hydrothermal sulfur was injected into a sulfate-restricted sub-basin where it mixed with low 34S BSR sulfide to form the massive and bedded sulfides. The REE patterns of sulfide layers and associated quartz albitite and baritite are similar to those of the host biotite quartz schists, suggesting that the hydrothermal fluids leached REE from the underlying rocks. Pb isotope ratios in galena form an array between the Upper Crust and the Mantle reservoir curves, which indicates that the lead is derived from upper crustal rocks comprising mafic igneous units. The Sr87/Sr86 ratio of 0.7101 for carbonate within the sulfide layers also suggests that Sr is derived from the mixing of Sr leached from upper crustal rocks with Middle Devonian seawater Sr. A Rb-Sr isochron age of 389.4 ± 6.4 Ma for sulfide layers and the interbedded hydrothermal sediments is consistent with the age of host Mid-Devonian strata. Ar39/Ar40 plateau age at 352.8 ± 3.5 Ma and Ar39-Ar40 isochron age of 346.6 ± 6.4 Ma for albite in the quartz albitite intercalated with sulfide layers indicate either albite formation after the sulfides or thermal resetting of the Rb-Sr system at about 350 Ma, the age of collision between the North China and Yangtze cratons.Editorial handling: E. Frimmel  相似文献   

设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号