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1.
Organic nitrates are secondary atmospheric pollutants that play a key role in ozone and aerosol production. This study focused on the simulation of organic nitrates through a box model coupled with RACM2(Regional Atmospheric Chemistry Mechanism, version 2), based on data from the PRIDE-PRD2006 campaign in Backgarden, China. Our study found that an overestimation of organic nitrate production rate was generated by the model. Furthermore, the effective production ratio(α_(eff)) of organic nitrates was around 0.033 after optimizing its chemical production module. The chemical impacts of organic nitrates on ozone production were related to VOC-OH reactivity and αeff. We found that VOC-OH reactivity was positively related to α_(eff),resulting in the suppression of ozone production caused by organic nitrates, which showed that P(O_x=O_3+NO_2) increased initially and subsequently decreased with VOC-OH reactivity. These results highlight the importance of organic nitrate's impact on ozone production in strategies to control ozone pollution, specifically regarding the reduction of low-molecular-weight VOCs in the Pearl River Delta.  相似文献   

2.
An intensive field campaign was conducted in Chongqing during the summer of 2015 to explore the formation mechanisms of ozone pollution. The sources of ozone, the local production rates, and the controlling factors, as well as key species of volatile organic compounds(VOCs), were quantified by integrating a local ozone budget analysis, calculations of the relative incremental reactivity, and an empirical kinetic model approach. It was found that the potential for rapid local ozone formation exists in Chongqing. During ozone pollution episodes, the ozone production rates were found to be high at the upwind station Nan Quan, the urban station Chao Zhan, and the downwind station Jin-Yun Shan. The average local ozone production rate was 30×10~(-9) V/V h~(-1) and the daily integration of the produced ozone was greater than 180×10~(-9) V/V. High ozone concentrations were associated with urban and downwind air masses. At most sites, the local ozone production was VOC-limited and the key species were aromatics and alkene, which originated mainly from vehicles and solvent usage. In addition, the air masses at the northwestern rural sites were NO_x-limited and the local ozone production rates were significantly higher during the pollution episodes due to the increased NOx concentrations. In summary, the ozone abatement strategies of Chongqing should be focused on the mitigation of VOCs. Nevertheless, a reduction in NO_x is also beneficial for reducing the regional ozone peak values in Chongqing and the surrounding areas.  相似文献   

3.
The effect of seawater on vertical ground motions is studied via a theoretical method and then actual offshore ground motion records are analyzed using a statistical method. A theoretical analysis of the effect of seawater on incident plane P and SV waves at ocean bottom indicate that on one hand, the affected frequency range of vertical ground motions is prominent due to P wave resonance in the water layer if the impedance ratio between the seawater and the underlying medium is large, but it is greatly suppressed if the impedance ratio is small; on the other hand, for the ocean bottom interface model selected herein, vertical ground motions consisting of mostly P waves are more easily affected by seawater than those dominated by SV waves. The statistical analysis of engineering parameters of offshore ground motion records indicate that:(1) Under the infl uence of softer surface soil at the seafl oor, both horizontal and vertical spectral accelerations of offshore motions are exaggerated at long period components, which leads to the peak spectral values moving to a longer period.(2) The spectral ratios(V/H) of offshore ground motions are much smaller than onshore ground motions near the P wave resonant frequencies in the water layer; and as the period becomes larger, the effect of seawater becomes smaller, which leads to a similar V/H at intermediate periods(near 2 s). These results are consistent with the conclusions of Boore and Smith(1999), but the V/H of offshore motion may be smaller than the onshore ground motions at longer periods(more than 5 s).  相似文献   

4.
The spatial distribution of clouds and their seasonal variations, and the three-dimensional(3D) cloud structures over East Asia have been analyzed with the CALIPSO-GOCCP data during the period from 2007 to 2012. The results show that there is a large cloud fraction greater than 0.7 over southern China, and the largest cloud fraction appears in southwest China. Besides, a large cloud fraction occurs over the southeast of the Tibetan Plateau. The total and high cloud fractions show notable variations with seasons, while the middle and low cloud fractions vary a little. As for cloud vertical structure, significant differences of the cloud vertical distributions are observed between over land and ocean. Cloud fractions and the height of the maximum cloud fractions decline gradually with the increasing latitude, except for the vertical-latitude profiles over the Tibetan Plateau regions. The longitude-vertical cross sections show similar patterns from the longitude 70° E to 140° E, except the profiles with large cloud fractions over the Tibetan Plateau. From the horizontal distribution patterns and vertical structures of the clouds over East Asia, it is concluded that the huge terrain of the Tibetan Plateau has significant impacts on the cloud formation over the Tibetan Plateau region and the areas to the east. At last, the clouds from the CALIPSO-GOCCP observations are compared to those from the ERA-Interim reanalysis data. The results indicate that the ERA-Interim reanalysis data provide reasonable spatial distribution patterns and the vertical structures in terms of the total cloud fraction over East Asia. However, the total cloud fraction was underestimated about 20% by the ERA-Interim reanalysis data over most parts of East Asia, especially over the neighboring areas east of the Tibetan Plateau. Additionally, the ERA-interim reanalysis data overestimate the cloud fractions at each level in the vertical direction.  相似文献   

5.
In the study of the application of MODIS satellite remote sensing data to earthquake prediction, the paper puts forward for the first time a quantitative method to estimate the ratio for the pixels with abnormal brightness temperature (BT) increase and a preliminary scheme for cloud removal. The principle is that, firstly, the cloudless data observed by the same satellite at the same period of time but in different days (usually 1 day to 3 days) are mosaiced to get high ratio of clear sky, and then the BT variation curve and mean square difference (MSD) of each pixel are calculated with the data from the covered area to determine daily whether the BT data of the day is normal or not at a certain pixel by using double the MSD as the criterion. The ratio for the pixels with abnormal BT increase can be calculated by dividing the total number of abnormal pixels with the total pixels of the whole area. Analysis on a series of recent earthquakes in the Taiwan area shows that the ratio for pixels with abnormal BT increase, which normally undulates around zero, has a sudden enhancement 1 day to 20 days before medium-strong earthquakes. It is expected that a new method for identifying earthquake auspice could be found through special studies in regions with frequent seismic activity by analyzing the change of the ratio for the pixels with abnormal BT increase from MODIS satellite remote sensing infrared (IR) information from which the effect of clouds has been removed to a certain extent.  相似文献   

6.
The gravity field and crustal thickness of Venus   总被引:1,自引:0,他引:1  
The gravity and topography of Venus obtained from observations of the Magellan mission, as well as the gravity and topography from our numerical mantle convection model, are discussed in this paper. We used the hypothesis that the geoid of degrees 2–40 is produced by sublithospheric mantle density anomalies that are associated with dynamical process within the mantle. We obtained the model dynamical admittance(the geoid topography ratio based on a convection model) by a numerical simulation of the Venusian mantle convection, and used it to correct the dynamical effect in the calculation of crustal thickness. After deducting the dynamical effect, the thickness of the Venusian crust is presented. The results show that the gravity and topography are strongly correlated with the Venusian mantle convection and the Venusian crust has a significant influence on the topography. The Venusian crustal thickness varies from 28 to 70 km. Ishtar Terra, and Ovda Regio and Thetis Regio in western Aphrodite Terra have the highest crustal thickness(larger than 50 km). The high topography of these areas is thought to be supported by crustal compensation and our results are consistent with the hypothesis that these areas are remnants of ancient continents. The crustal thickness in the Beta, Themis, Dione, Eistla, Bell, and Lada regiones is thin and shows less correlation with the topography, especially in the Atla and Imdr regiones in the eastern part of Aphrodite Terra. This is consistent with the hypothesis that these highlands are mainly supported by mantle plumes. Compared with the crustal thickness calculated with the dynamical effect, our results are more consistent with the crust evolution and internal dynamical process of Venus.  相似文献   

7.
The dynamic shear modulus ratio and damping ratio of sandy gravel are important parameters for the seismic response analysis of valley geomorphic sites,which have an important impact on the determination of design ground motion parameters. In this paper,the dynamic triaxial test of sandy gravels has been performed based on the project of the Shangluo Seismic Microzonation. Combined with the other results of sandy gravel,the recommended results of slightly dense,medium dense and dense sandy gravel were obtained. By building the typical site model,the influence of the dynamic shear modulus ratio and the damping ratio uncertainty on the seismic response of the site is studied. The results show that the uncertainty of the average of the dynamic shear modulus ratio and the damping ratio ± 1 times the standard deviation has little effect on the peak acceleration of the sandy gravel site,and the rationality of the grouping and statistical results is explained. Under different probability levels,the change in the shear modulus ratio and damping ratio leads to a significant difference in the high frequency response spectrum.The response spectrum of 0. 04-0. 1s ranges from about 20%,but it has little effect on the long period spectrum of more than 1. 0s. The study of dynamic shear modulus ratio and damping ratio of sandy gravel has the ability to improve the reliability of the designing ground motion parameters.  相似文献   

8.
Forest NPP estimation based on MODIS data under cloudless condition   总被引:3,自引:0,他引:3  
Based on light-use efficiency model, an MODIS-derived daily net primary production (NPP) model was developed. In this model, a new model for the fraction of photosynthetically active radiation absorbed by vegetation (FPAR) is developed based on leaf area index (LAI) and albedo parameters, and a pho- tosynthetically active radiation (PAR) is calculated from the combination of Bird's model with aerosol optical thickness and water vapor derived from cloud free MODIS images. These two models are inte- grated into our predicted NPP model, whose most parameters are retrieved from MODIS data. In order to validate our NPP model, the observed NPP in the Qianyanzhou station and the Changbai Mountains station are used to compare with our predicted NPP, showing that they are in good agreement. The NASA NPP products also have been downloaded and compared with the measurements, which shows that the NASA NPP products underestimated NPP in the Qianyanzhou station but overestimated in the Changbai Mountains station in 2004.  相似文献   

9.
Three kinds of the widely-used cloudiness parameterizations are compared with data produced from the cloud-resolving model(CRM) simulations of the tropical cloud system. The investigated schemes include those based on relative humidity(RH), the semi-empirical scheme using cloud condensate as a predictor, and the statistical scheme based on probability distribution functions(PDFs). Results show that all three schemes are successful in reproducing the timing of cloud generation, except for the RH-based scheme, in which low-level clouds are artificially simulated during cloudless days. In contrast, the low-level clouds are well simulated in the semi-empirical and PDF-based statistical schemes, both of which are close to the CRM explicit simulations. In addition to the Gaussian PDF, two alternative PDFs are also explored to investigate the impact of different PDFs on cloud parameterizations. All the PDF-based parameterizations are found to be inaccurate for high cloud simulations, in either the magnitude or the structure. The primary reason is that the investigated PDFs are symmetrically assumed, yet the skewness factors in deep convective cloud regimes are highly significant, indicating the symmetrical assumption is not well satisfied in those regimes. Results imply the need to seek a skewed PDF in statistical schemes so that it can yield better performance in high cloud simulations.  相似文献   

10.
Expression of strain and rotation tensor in geodetic coordinates   总被引:1,自引:0,他引:1  
In this paper, unit moving trihedron is first constructed for a point on the surface of a revolution ellipsoid. Via translation, the origin of the trihedron coincides with that of Cartesian coordinates established at the center of the ellipsoid, and then through two coordinate rotations, the trihedron completely coincides with the Cartesian coordi-nates. Transformation formulae between the moving trihedron and unit Cartesian coordinate frameworks as well as transformation of point displacement between two unit coordinate frameworks are presented. Based on the above transformation formulae between two different coordinate frameworks, due to the fact that the displacement and moving trihedron of the point are both functions of the geodetic coordinates, components in the corresponding axis for differential of displacement vector and geodetic curves arc differential at the point in geodetic system can be obtained through complicated derivation. Displacement gradient matrix at the point in geodetic system is also given. Finally, expressions of strain and rotation tensor in geodetic coordinates are presented. Geometric meanings of the rotation tensor are explained in detail. The intrinsic relationship between strain tensors of sphere and ellip-soid are also discussed.  相似文献   

11.
Pyrolysis of lignite in closed systems was conducted at temperatures from 400 to 700℃ and pressure from 1 to 3 GPa in order to investigate the evolutive characteristics of aromatics and the effects of pressure and temperature on the maturation of organic matter under the extreme conditions. The total yield of liquid hydrocarbons decreased with increasing pressure and the aromatics shows more mature with increasing temperature at a given pressure. The data indicate that high pressure significantly suppresses the thermal evolution of geological organic matter especially at lower temperature, but favors the cyclization, polymerization and aromatization of pyrolysate. The pressure effect on maturation of organic matter is nonlinear. Therefore, it can be inferred that sediment organic-matters in the subducted slab could be retained in the deep lithosphere, and the results are also significant for understanding the accumulation and preservation of petroleum in deep reservoirs.  相似文献   

12.
The Shenhu area on the northern continental slope of the South China Sea (SCS) is one of the promising fields for gas hydrate exploitation. The hydrate-bearing layer at drilling site SH2 is overlain and underlain by permeable zones of mobile water. In this study a vertical well was configured with a perforated Interval I for producing gas and a coiled Interval II for heating sediment. The hydrate is dissociated by a small depressurization at Interval I and a thermal stimulation at Interval II. The numerical simulations indicate that the thermal stimulation has a significant effect on gas release from the hydrates in the production duration and improves the gas production in the late period. The gas released by thermal stimulation cannot be produced as quickly as the production gets operated because of the hard pathway for fluids to flow in the sediments. The gas production is enhanced due to the heating for 7242 m 3 in the whole production. Increasing heating temperature at Interval II can improve gas production and restrain water output, and advance the arrival time of the gas flow from the zone at Interval II. The absolute criterion and relative criterion suggest that the thermal stimulation in the production schemes is pronounced for releasing gas from the hydrate deposit, but the production efficiency of gas is limited by the sediment of low permeability. The study provides an insight into the production potential of the hydrate accumulations by thermal stimulation with depressurization in two wells, and a basis for analyzing economic feasibility of gas production from the area.  相似文献   

13.
This paper deals with the response features of AR (apparent ratio of seismic wave velocities to the changes of TR (true ratio of wave velocities) in the horizontal layered model by mathematical modeling. The results show that: (1) the response features of AR are associated with the parameters of the structure and its dynamic changes, and the relative position between the hypocenters and the monitoring networks, showing complicated patterns strongly related to the concrete paths of propagation of seismic waves from the source to the receiver in the observatories of the network; (2) the depth of the seismic source would have important influence on the response features of AR, especially the capacity to carry the anomalous information in the condition of the earth media, being in the anomalous state would be greater for those earthquakes which occur inside the anomalous layers than those underneath the anomalous layers; (3) the response features of AR are clearly related to the changes of TR (true ratio of wave velocities) instead of changes of wave velocities themselves, i.e. the response could be small as the changes in TR is small even in the case of large changes in the wave velocities. It is suggested that more attention must be paid to all these features in combination with detailed investigation of the velocity structure of the earth media in the study region and best fitting of precise hypocenter locations when one wants to obtain the reliable precursors from the changes in AR.  相似文献   

14.
Ultrahigh-pressure (UHP) eclogites often show strong plastic deformation and anisotropy of seismic properties. We report in this paper the seismic velocity and anisotropy of eclogite calculated from the crystallographic preferred orientations (CPOs) of constituent minerals (garnet, omphacite, quartz and rutile) and single crystal elastic properties. We also compared the calculated results with the measured results in similar eclogites. Our results suggest that (1) Except that garnet is a seismically quasi-isotropic mineral, omphacite, quartz, coesite and rutile all have strong seismic anisotropies (AVp = 23.0%―40.9%, Max. AVs = 18.5%―47.1%). They are the major sources for anisotropy in eclogite. The average seismic velocities are fast in garnet and rutile, moderate in omphacite and coesite, and slow in quartz. (2) The deformed eclogites have the maximum Vp (8.33―8.75 km/s) approximately parallel to foliation and lineation, the minimum Vp (8.25―8.62 km/s) approximately normal to foliation and lineation and the Vp anisotropies of 1.0―1.7%. Their Vs are 4.93―4.97 km/s. The corresponding maximum anisotropies (0.73%―1.78%) of Vs are at 45° to both foliation and lineation and the minimum anisotropies at positions normal to lineation on the foliation plane. The Vs1 polarization planes are approximately parallel to foliation. The mean Vp and Vs of eclogite under UHP peak metamorphism conditions (P = 3―5 GPa, T = 900―1100℃) are estimated to be 3.4%―7.2% and 6.3%―12.1% higher than those at ambient pressure and temperature conditions, respectively. (3) Omphacite component dominates the anisotropy of eclogite while garnet component reduces the anisotropy and increases the seismic velocities. Quartz component has a small effect on the anisotropy but reduces the seismic velocities of eclogite. The effect of rutile component is negligible on seismic properties of eclogite due to its trivial volume fraction. (4) The increase of volume fraction of omphacite in eclogite will reduce the seismic velocities and increase the anisotropy. Omphacitite has seismic velocities reduced by 6%―8% and anisotropies increased to 3%―4% compared to those of garnetite. Our results suggest that the seismic properties calculated with single crystal elastic properties and CPOs are equivalent to those measured in laboratory. Moreover, it provides insights into the mineral physical interpretations of eclogite seismic properties.  相似文献   

15.
On the basis of information from the project "Land-surface Processes and their Experimental Study on the Chinese Loess Plateau", we analyzed differences in land-surface water and heat processes during the main dry and wet periods of the semiarid grassland growing season in Yuzhong County, as well as the influences of these environmental factors. Studies have shown that there are significant differences in changes of land-surface temperature and humidity during dry and wet periods. Daily average normalized temperature has an overall vertical distribution of "forward tilting" and "backward tilting" during dry and wet periods, respectively. During the dry period, shallow soil above 20-cm depth is the active temperature layer. The heat transfer rate in soil is obviously different during dry and wet periods. During the dry period, the ratio of sensible heat flux to net radiation(H/Rn) and the value of latent heat flux to net radiation(LE/Rn) have a linear relationship with 5-cm soil temperature; during the wet period, these have a nonlinear relationship with 5-cm soil temperature, and soil temperature of 16°C is the critical temperature for changes in the land-surface water and heat exchange trend on a daily scale. During the dry period, H/Rn and LE/Rn have a linear relationship with soil water content. During the wet period, these have a nonlinear relationship with 5-cm soil water content, and 0.21 m3 m?3 is the critical point for changes in the land-surface water and heat exchange trend at daily scale. During the dry period, for vapor pressure deficit less than 0.7 k Pa, H/Rn rises with increased vapor pressure deficit, whereas LE/Rn decreases with that increase. When that deficit is greater than 0.7 k Pa, both H/Rn and LE/Rn tend to be constant. During the wet period, H/Rn increases with the vapor pressure deficit, whereas LE/Rn decreases. The above characteristics directly reflect the effect of differences in land-surface environmental factors during land-surface water and heat exchange processes, and indirectly reflect the influences of cloud precipitation processes on those processes.  相似文献   

16.
《国际泥沙研究》2016,(2):120-130
Siltation,a phenomenon resulted from the presence of fine particles in an aqueous environment,dominated by silt and clay,is a known and common environmental issue worldwide.The accumulation of fine sediments engenders murky water with low oxygen levels,which leads to the death of aquatic life.Thus,investigating the physical and mechanical properties of fine sediment by rheological methods has expanded.Rheology is the science of deformation and flow of matter in stress.This survey investigates the rheological behavior of six samples of soil as the fine particles structure(D 63 μm) from different regions of Malaysia by using a rotational rheometer with a parallel-plate measuring(using two sizes:25 mm and 50 mm) device to explore the flow and viscoelastic properties of fine particles.The samples were examined in two rheological curve and amplitude sweep test methods to investigate the effect of water content ratio,texture,and structure of patticles on rheological properties.It was found that the content of fine sand,clay,and silt had an effect on the stiffness,structural stability,and shear behavior.Thus,the pseudoplastic and viscoelastic behaviot are respectively shown.Moreover,the amount of fine sediments present in water i.e.the concentration of these particles,has a direct effect on the rheological curve.A reduction in viscosity of samples with higher concentrations of water has been observed.As a consequence,a considerable quantity of fine sediments are distributed within the water body and remain suspended over the time.As a result,the sedimentation rate slows down.It needs to be asserted that the stotage modulus G′,loss modulus G″,and yield point can vary depending on particle type.The G′ and G″were instigated for samples(70%and 45%concentrations) that demonstrated viscoelastic characteristics using the same rotational rheometer with a parallel-plate measuring device.  相似文献   

17.
Approximately 80% of the road network in Brazil is unpaved and shows evidences of a high erosion potential. In the semi-arid Caatinga Biome in the northeast of the country, a monitoring programme has been done for two years in order to analyze runoff and sediment production from unpaved rural road-ways and from embankments. Sediment production ranged from 0.30 to 0.92 Mg/ha yr, higher than in undisturbed areas, but generally lower than that reported for unpaved roads in other regions. However, this is a semi-arid area with low rainfall and runoff and, hence, with a limited hydrological connectivity and sediment production. Sediment production on an embankment with no vegetation was around ten times higher than on an embankment with vegetation. On the road surface, annual sediment production (normalized for gradient) in a section with traffic was three times higher than for a road surface without traffic. In addition, events that occurred after roadway maintenance activities generated peaks of sedi-ment concentration of over 5000 mg/L. These results suggest that sediment production from roads and embankments with bare surfaces is at least one order of magnitude higher than in undisturbed catch-ment areas. Maintenance activity and vehicle traffic contribute to an increase in sediment availability and impact on the sediment concentration, but less intensely on sediment loads, which depend on the runoff magnitude of the events occurring after roadway maintenance. It was also found that the natural vegetation of the semi-arid region potentially captures sediment on roadway embankments;thereby playing an important role in breaking connectivity between the sediment flow from unpaved roads and the natural drainage system of the catchment.  相似文献   

18.
Based on the finite element numerical algorithm,the coseismic displacements of the Wenchuan MS8.0 earthquake are calculated with the rupture slip vectors derived by Ji and Hayes as well as Nishimura and Yaji.Except in a narrow strip around the rupture zone,the coseismic displacements are consistent with those from GPS observation and InSAR interpretation.Numerical results show that rupture slip vectors and elastic properties have profound influences on the surface coseismic deformation.Results from models with different elastic parameters indicate that:①in homogeneous elastic medium,the surface displacements are weakly dependent on Poisson's ratio and independent of the elastic modulus;②in horizontally homogeneous medium with a weak zone at its middle,the thickness of the weak zone plays a significant role on calculating the surface displacements;③in horizontally and vertically heterogeneous medium,the surface displacements depend on both Poisson's ratio and elastic modulus.Calculations of coseismic deformation should take account of the spatial variation of the elastic properties.The misfit of the numerical results with that from the GPS observations in the narrow strip around the rupture zone suggests that a much more complicated rupture model of the Wenchuan earthquake needs to be established in future study.  相似文献   

19.
Tuned mass dampers(TMDs) have been widely used in recent years to mitigate structural vibration.However,the damping mechanisms employed in the TMDs are mostly based on viscous dampers,which have several well-known disadvantages,such as oil leakage and difficult adjustment of damping ratio for an operating TMD.Alternatively,eddy current damping(ECD) that does not require any contact with the main structure is a potential solution.This paper discusses the design,analysis,manufacture and testing of a large-scale horizontal TMD based on ECD.First,the theoretical model of ECD is formulated,then one large-scale horizontal TMD using ECD is constructed,and finally performance tests of the TMD are conducted.The test results show that the proposed TMD has a very low intrinsic damping ratio,while the damping ratio due to ECD is the dominant damping source,which can be as large as 15% in a proper configuration.In addition,the damping ratios estimated with the theoretical model are roughly consistent with those identified from the test results,and the source of this error is investigated.Moreover,it is demonstrated that the damping ratio in the proposed TMD can be easily adjusted by varying the air gap between permanent magnets and conductive plates.In view of practical applications,possible improvements and feasibility considerations for the proposed TMD are then discussed.It is confirmed that the proposed TMD with ECD is reliable and feasible for use in structural vibration control.  相似文献   

20.
This research on the attenuation features of intensity in the Yunnan region has been conducted by using intensity isoseismals of 127 earthquakes, and the following three conclusions have been put forward : ( 1 ) The average ratio value of long axis to short axis of innermost isoseismals in the Yunnan region is larger than that of eastern China and smaller than that of western China.The velocity of intensity attenuation varies in different directions; (2) The zoning feature of intensity attenuation in the Yunnan region is obvious; (3) In Northwest China and North China, the ratios of long axis to short axis of low-magnitude isoseismals are larger than those of high magnitude ones. Compared with that phenomenon, the ratios in the Yunnan region are more complicated. Finally, some relevant questions are discussed.  相似文献   

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