Petrogenesis and geodynamic implications of the Late Carboniferous felsic volcanics in the Bogda belt,Chinese Northern Tianshan

An integrated study on petrology and geochemistry has been carried out on the Late Carboniferous I-type felsic volcanics of the Liushugou Formation in the Bogda belt to constrain the late Paleozoic tectonic evolution of the Bogda belt. The felsic volcanics were dated to be 315 to 319 Ma and are composed of trachy-andesite–trachyte ignimbrites and rhyolite lavas. They are in conformable contact with high-Al basalt. The eruption of the felsic volcanics and high-Al basalt is not bimodal volcanism, but is related to bimodal magma (basaltic and rhyolitic magmas). MELTS modeling and comparison with previous basaltic melting experiments indicate that the felsic volcanics are likely produced by partial melting of hydrated mafic crust rather than fractional crystallization of high-Al basalt. It is also supported by relatively large amounts of felsic volcanics to high-Al basalts and remarkably different incompatible element ratios (e.g., Th/Zr, Nb/Zr and U/Zr) of the rocks. The Bogda felsic volcanics have positive ε_Nd(t) values (6.2–7.4), low Pb isotopes and low zircon saturation temperatures, consistent with a derivation from a juvenile crust in an arc setting. The intermediate ignimbrites display melting–mingling textures and abundant feldspar aggregates and have various δEu ratios, indicating that magma mingling and feldspar fractionation processes may have played an important role in the genesis of the ignimbrites. In contrast, the Early Permian felsic rocks in this region are of post-collisional A-type. We therefore propose that the Bogda belt was an island arc in the Late Carboniferous and then switched to a post-collisional setting in the Early Permian due to the arc–arc collision at the end of the Late Carboniferous.     

Malani Rhyolites — A Review

The late Proterozoic Malani bimodal volcanics constitute the largest suite of anorogenic acid volcanics in India. The volcanism took place during 745±10 Ma ago, succeeding the granitic activity of Abu pluton and ceased before the onset of Marwar sedimentation.On the basis of field evidences, three stages of igneous activity have been recognised. Volcanics of the first stage are mostly basalt with occasional andesite or trachybasalts. These are subsequently covered by the voluminous outpouring of peralkaline and peraluminous rhyolite, basalt, dacite and trachyte flows. The third stage ceased with the outburst of ash flow deposits.The dominant felsic volcanics are rhyolites and rhyodacites spread over an area of about 31, 000 km². The other rock types associated with rhyolite are trachytes, dacites, pitchstone, welded tuff, vitric, lithic and crystal ash, ignimbrite, obsidian, pyroclastic slates, agglomerate, volcanic breccia and volcanic conglomerates. Majority of the acid volcanics are high potassic and a few are calcalkaline or low potassic in composition.Feldspar geothermometry suggests the temperature of equilibrium to be above 650°C. Similar results were obtained by magnetite-ulvospinel geothermometry. Oxygen fugacity is estimated to be about 10⁻¹⁸ under FMQ-Ni-NiO buffer conditions.Malani volcanism was essentially under terrestrial conditions, although deposition by aqueous conditions are also indicated. The volcanic eruptions have been through fissures, shield volcanoes and central cones. The volcanism was triggered in an extensional tectonic regime of continental crust, where geotherm was raised by the repeated influx of basic magma. The initial basaltic magma was possibly generated at deeper depth by ‘hot spot’ activity. This magma while migrating upwards supplied additional heat for the partial melting of lower sialic crust resulting in the generation of felsic magma. The crustal extension has helped in the upward advancement of the felsic magma.     

西准噶尔谢米斯台地区双峰式火山岩的发现及其地质意义

西准噶尔谢米斯台地区是研究准噶尔洋盆构造演化的关键地区,新发现的双峰式火山岩为开展研究提供了直接的载体,对其物质组成特征、岩石地球化学特征和锆石U Pb年代学等进行研究,判别成因机制和大地构造环境,对恢复造山带大地构造格局有着重要的意义。本次研究获得如下认识：该套双峰式火山岩为碱性玄武岩-钙碱性流纹岩组合,流纹岩LA ICP MS锆石U Pb年龄(4318±23) Ma;玄武岩来源于俯冲流体交代的地幔部分熔融,流纹岩来源于地壳物质的部分熔融;双峰式火山岩形成于早志留世弧后盆地初始演化阶段;结合前人的研究成果,认为西准噶尔谢米斯台地区在早古生代存在完整的沟-弧-盆体系。     

Rb−Sr and Ar−Ar systematics of Malani volcanic rocks of southwest Rajasthan: Evidence for a younger post-crystallization thermal event

A new Rb−Sr age of 779±10 Ma has been obtained for a suite of andesite-daciterhyolite from the Malani Igneous Province of southwestern Rajasthan, dated earlier at 745±10 Ma by Crawford and Compston (1970). The associated basalts may be slightly younger than the felsic volcanics and have a mantle source. The felsic volcanics on the other hand were most probably derived by fractional crystallization of a crustal magma (Srivastavaet al 1989a, b).⁴⁰Ar−³⁹Ar systematics of three samples viz., a basalt, a dacite and a rhyolite show disturbed age spectra indicating a thermal event around 500–550 Ma ago. This secondary thermal event is quite wide-spread and possibly related to the Pan-African thermo-tectonic episode observed in the Himalayas and south India.     

Geology and geochemistry of archaean felsic metavolcanic rocks of the Eastern Part of the Kolar greenstone belt, Dharwar craton, India: Implications for their petrogenesis and geodynamic setting

In the Kolar greenstone belt of the Dharwar craton, felsic metavolcanics are encountered prominently in its eastern region around Surapalli and Marikoppa. These felsic volcanic rocks are essentially homogeneous and their bulk mineralogy is almost the same. They consist of phenocrysts of quartz and feldspar, set in a fine-grained quartzo-feldspathic groundmass. They are calc-alkaline rhyolite in composition, and are characterized by high SiO₂ (av. 75.74 wt.%), moderate Al₂O₃ (av. 11.84 wt.%), Na₂O (av. 3.55 wt.%), K2O (av. 3.26 wt%) contents and low Mg# (av. 6.07), Cr (av. 8 ppm), Ni (av. 8 ppm), Sr (av. 331 ppm.), Y (av. 7 ppm), Yb (av. 0.87 ppm) and Nb/Ta (av. 6.40) values, suggesting Tonalite-Trondhjemite-Granodiorite (TTG) affinity for these felsic volcanics. They are strongly fractionated [(La/Yb)_N? = 14.41–48.70] with strong LREE enrichment [(La/Sm)_N = 2.50-3.59] and strong HREE depletion [(Gd/Yb)_N = 1.34–2.77] with positive Eu anomaly. The regional geological set-up, petrographic and geochemical characteristics suggest that these felsic volcanics probably were derived by partial melting of a subducting basalt slab at shallow depth without much involvement of mantle wedge in an island arc geodynamic setting.     

Dokhan volcanics of Gabal Monqul area,North Eastern Desert,Egypt: geochemistry and petrogenesis

The Dokhan volcanics are represented by a thick stratified lava flows succession of basalt, andesite, imperial porphyry, dacite, rhyodacite, rhyolite, ignimbrites, and tuffs. These lavas are interbanded with their pyroclastics in some places including banded ash flow tuffs, lithic tuffs, crystal lapilli tuffs, and agglomerates. They are typical calc–alkaline and developed within volcanic arc environment. All rocks show moderate enrichment of most large ion lithophile elements relative to high field strength elements (HFSE). The incompatible trace elements increase from basalt through andesite to rhyolite. The felsic volcanics are characterized by moderate total rare earth elements (REE) contents (162 to 392 ppm), less fractionated patterns {(Ce/Yb)_N = (1.24 to 10.93)}, and large negative Eu anomaly {(Eu/Eu*) = (0.15 to 0.92)}. The mafic volcanics have the lowest REE contents (61 to 192 ppm) and are relatively steep {(Ce/Yb)_N = (3.2 to 8.5)}, with no negative Eu anomalies {(Eu/Eu*) = (0.88 to 1)}. The rhyolite displays larger negative Eu anomaly (Eu/Eu* = 0.28) than those of other varieties, indicating that the plagioclase was an early major fractionating phase. The mineralogical and chemical variations within volcanics are consistent with their evolution by fractional crystallization of plagioclase and clinopyroxene.     

Permo-Carboniferous volcanism in late Variscan continental basins of the Bohemian Massif (Czech Republic): geochemical characteristic

Extensive Permo-Carboniferous volcanism has been documented from the Bohemian Massif. The late Carboniferous volcanic episode started at the Duckmantian–Bolsovian boundary and continued intermittently until Westphalian D to Stephanian B producing mainly felsic and more rarely mafic volcanics in the Central Bohemian and the Sudetic basins. During the early Permian volcanic episode, after the intra-Stephanian hiatus, additional large volumes of felsic and mafic volcanics were extruded in the Sudetic basins. The volcanics of both episodes range from entirely subalkaline (calc-alkaline to tholeiitic) of convergent plate margin-like type to transitional and alkaline of within-plate character. A possible common magma could not be identified among the Carboniferous and Permian primitive magmas, but a common geochemical signature (enrichment in Th, U, REE and depletion in Nb, Sr, P, Ti) in the volcanic series of both episodes was recognized. On the other hand, volcanics of both episodes differ in intensities of Nb, Sr and P depletion and also, in part, in their isotope signatures. High ⁸⁷Sr/⁸⁶Sr (0.707–0.710) and low ε_Nd (−6.0 to −6.1) are characteristic of the Carboniferous mafic volcanics, whereas low ⁸⁷Sr/⁸⁶Sr (0.705–0.708) and higher ε_Nd ranging from −2.7 to −3.4 are typical of the Permian volcanics. Felsic volcanics of both episodes vary substantially in ⁸⁷Sr/⁸⁶Sr (0.705–0.762) and ε_Nd (−0.9 to −5.1). Different depths of magma source or heterogeneity of the Carboniferous and Permian mantle can be inferred from variation in some characteristic elements of the geochemical signature for volcanics in some basins. The Sr–Nd isotopic data with negative ε_Nd values confirm a significant crustal component in the volcanic rocks that may have been inherited from the upper mantle source and/or from assimilation of older crust during magmatic underplating and ascending of primary basic magma. Two different types of primary magma development and formation of a bimodal volcanic series have been recognized: (i) creation of a unique magma by assimilation fractional crystallization processes within shallow-level reservoirs (type Intra-Sudetic Basin) and (ii) generation and mixing of independent mafic and felsic magmas, the latter by partial melting of upper crustal material in a high-level chamber (type Krkonoše Piedmont Basin). A similar origin for the Permo-Carboniferous volcanics of the Bohemian Massif is obvious, however, their geochemical peculiarities in individual basins indicate evolution in separate crustal magma chambers.     

Geochemistry of Proterozoic volcanic and granitic rocks from the Gold Hill-Wheeler Peak area,northern New Mexico

Early Proterozoic supracrustal and plutonic rocks from the Gold Hill-Wheeler Peak area in northern New Mexico define three populations: amphibolite—diorite—tonalite, hornblendite—cumulus amphibolite and felsic volcanics and porphyries. Also present are mid-Proterozoic granites. Amphibolites are similar in Ti, Zr, Cr, Ni and REE contents to young calc-alkaline and arc basalts and diorites and tonalites are similar in composition to young andesites and to high-Al₂O₃ tonalites, respectively. Felsic volcanics resemble young felsic volcanics from mature arc systems in their immobile-element contents. Geochemical model studies suggest that the amphibolites, hornblendites, diorites and tonalites are related by progressive fractional crystallization of a hydrous parent tholeiite magma produced from partial melting of undepleted lherzolite. Amphibolites represent parent tholeiites modified by olivine removal. Hornblendite is an early solid residue comprised chiefly of hornblende, clinopyroxene, and olivine; diorite and cumulus amphibolite represent respectively residual solid (clinopyroxene, plagioclase, hornblende) and liquid, after 50% crystallization. Tonalite represents a residual liquid after 80% crystallization. Felsic volcanic rocks are produced by partial melting of a tonalite or diorite source with granulite-facies mineralogy in the lower crust. Granites have a similar origin to felsic volcanics although requiring an inhomogeneous source with the presence of residual hornblende or garnet.The calc-alkaline igneous rocks in the Gold Hill-Wheeler Peak area suggest the presence of an arc system in northern New Mexico during the Early Proterozoic. The fact that these rocks interfinger with and are overlain by mature clastic sediments favors a model in which a continental arc system is uplited, eroded and buried by cratonic sediments from the north.     

Geochemistry,mineralogy and petrogenesis of the northeast Niğde volcanics,central Anatolia,Turkey

The volcanics exposed in the northeast Niğde area are characterized by pumiceous pyroclastic rocks present as ash flows and fall deposits and by compositions ranging from dacite to rhyolite. Xenoliths found in the volcanics are basaltic andesite, andesite and dacite in composition. These rocks exhibit linear chemical variations between end‐member compositions and a continuity of trace element behaviour exists through the basaltic andesite–andesite–dacite–rhyolite compositional range. This is consistent with the fractionation of ferromagnesian minerals and plagioclase from a basaltic andesite or andesite parent. These rocks are peraluminous and show typical high‐K calc‐alkaline differentiation trends with total iron content decreasing progressively with increasing silica content. Bulk rock and mineral compositional trends and petrographic data suggest that crustal material was added to the magmas by subducted oceanic crust and is a likely contaminant of the source zone of the Niğde magmas. The chemical variations in these volcanics indicate that crystal liquid fractionation has been a dominant process in controlling the chemistry of the northeast Niğde volcanics. It is also clear, from the petrographic and chemical features, that magma mixing with disequilibrium played a significant role in the evolution of the Niğde volcanic rocks. This is shown by normal and reverse zoning in plagioclase and resorption of most of the observed minerals. The xenoliths found in the Niğde volcanics represent the deeper part of the magma reservoir which equilibrated at the higher pressures. Copyright © 2002 John Wiley & Sons, Ltd.     

Origin,age and petrogenesis of Neoproterozoic composite dikes from the Arabian‐Nubian Shield,SW Jordan

The evolution of a Pan‐African (c. 900–550 Ma) suite of composite dikes, with latite margins and rhyolite interiors, from southwest Jordan is discussed. The dikes cut the Neoproterozoic calc‐alkaline granitoids and high‐grade metamorphic rocks (c. 800–600 Ma) of the northern Arabian‐Nubian Shield in Jordan and have been dated by the Rb‐Sr isochron method at 566±7 Ma. The symmetrically distributed latite margins constitute less than one‐quarter of the whole dike thickness. The rhyolite intruded a median fracture within the latite, while the latter was still hot but completely solidified. The dikes are alkaline and bimodal in composition with a gap in SiO₂ between 61 and 74 wt%. Both end members display similar chondrite‐normalized rare earth element patterns. The rhyolites display the compositional signature of A‐type granites. The (La/Lu)_N values are 6.02 and 4.91 for latites and rhyolites, respectively, and the rhyolites show a pronounced negative Eu anomaly, in contrast to the slight negative Eu anomaly of the latites. The chemical variability (e.g. Zr/Y, Zr/Nb, K/Rb) within and between latites and rhyolites does not support a fractional crystallization relationship between the felsic and mafic members of the dikes. We interpret the magma genesis of the composite dikes as the result of intrusion of mantle‐derived mafic magma into the lower crust in an extensional tectonic regime. The mafic magma underwent extensive fractional crystallization, which supplied the necessary heat for melting of the lower crust. The products of the initial stages of partial melting (5–10%) mixed with the fractionating mafic magma and gave rise to the latite melts. Further partial melting of the lower crust (up to 30%) produced a felsic melt, which upon 50% fractional crystallization (hornblende 15%, biotite 5%, feldspars 60%, and quartz 20%) gave rise to the rhyolitic magma. Copyright © 2004 John Wiley & Sons, Ltd.     

Formation of U-depleted rhyolite from a basanite at El Hierro, Canary Islands

Phonolite and trachyte are the felsic magmas of the alkaline magma suites, which characterize the Canary Islands. The October 2011 submarine eruption off El Hierro, the westernmost island, nevertheless, produced a small volume of rhyolitic magma. The rhyolite occurred as highly vesicular, white coloured pumices enveloped in and mingled with darker coloured basanitic pumice. The basanitic pumice is relatively crystal poor with a few euhedral olivines (mostly Fo_77–79), clinopyroxenes and Fe-rich spinels, whereas very rare olivine of same composition is found together with equally rare Fe-sulphide and FeTi-rich oxides in the rhyolite. The Fe–Mg exchange equilibrium in the oxides permits to calculate an equilibrium temperature of 970–890 °C for the rhyolite, in agreement with quartz-melt equilibrium at ca. 930 °C. A striking mineralogical feature of the rhyolite is the presence of rounded to contorted grains of milky quartz, which are xenocrysts incorporated and partly dissolved into the magma. Analyses of residual volatile concentrations in the glasses show that the rhyolite melt was highly degassed, whereas the basanitic glass still has important halogen concentrations. Trace element patterns of the mafic glasses and their elevated incompatible element concentrations are typical of the western Canary Island basanites. In contrast, the trace element composition of the rhyolite shows surprisingly low concentrations for all elements except the most incompatible ones (e.g. Rb, Ba, K and Th). All other measured LILE, HFSE and REE have significantly lower concentration than the basanitic counterpart that can be explained by fractionation of accessory phases (1 % apatite, 1 % sphene and 0.1 % zircon). Surprisingly, low U concentration is presumably related to elevated oxygen fugacity in the rhyolite, causing U to be in a hexavalent state, and fluxing of F-rich gas leading to volatilization of UF₆, known to emanate at low temperature. The results suggest that a gas-rich basanitic melt remobilized a small volume of stagnant rhyolitic melt formed by incorporation of approximately 10 % quartz-rich sediment into a late differentiate of trachytic composition. Sediments at the interface of an old oceanic crust adjacent to a continental shield and younger volcanic island are likely to act as magma traps were sediment assimilation may alter the mantle-derived magma composition. Quartz assimilation thus explains the production of rhyolite magma in a volcanic island characterized by an alkaline magma series from primitive basanites to trachytes.     

Petrogenesis of Mafic Inclusions in Rhyolitic Lavas from Narugo Volcano, Northeastern Japan

Mafic inclusions present in the rhyolitic lavas of Narugo volcano,Japan, are vesiculated andesites with diktytaxitic texturesmainly composed of quenched acicular plagioclase, pyroxenes,and interstitial glass. When the mafic magma was incorporatedinto the silica-rich host magma, the cores of pyroxenes andplagioclase began to crystallize (>1000°C) in a boundarylayer between the mafic and felsic magmas. Phenocryst rim compositionsand interstitial glass compositions (average 78 wt % SiO₂) inthe mafic inclusions are the same as those of the phenocrystsand groundmass glass in the host rhyolite. This suggests thatthe host felsic melt infiltrated into the incompletely solidifiedmafic inclusion, and that the interstitial melt compositionin the inclusions became close to that of the host melt (c.850°C). Infiltration was enhanced by the vesiculation ofthe mafic magma. Finally, hybridized and density-reduced portionsof the mafic magma floated up from the boundary layer into thehost rhyolite. We conclude that the ascent of mafic magma triggeredthe eruption of the host rhyolitic magma. KEY WORDS: mafic inclusion; stratified magma chamber; magma mixing; mingling; Narugo volcano; Japan     

闽中地区马面山群东岩组变质岩形成的古构造环境研究

闽中地区马面山群东岩组地层主要为绿片岩为主的一套古火山沉积建造。其主要岩性类型包括各种成分的绿片岩、大理岩、石英片岩及变粒岩类。绿片岩显示海底火山喷发特征,变粒岩原岩为中酸性岩类。东岩组变质岩岩石化学研究表明,绿片岩的原岩应为玄武岩类。变粒岩类主要属于英安岩及流纹岩。这些特征反映东岩组具双峰式火山岩特征,形成于大陆内部张性环境。绿片岩稀土元素特征也显示和大陆拉张环境中的火山岩类稀土特征非常相似,属大陆拉斑玄武岩;微量元素分布显示出该组变质岩原岩类似于大洋岛和大陆裂谷的板内碱性玄武岩。因此闽中地区中元古代可能处于板内古裂谷环境。     

新疆北山石炭纪、二叠纪火山岩岩石化学及构造环境分析

北山地区火山岩发育,以熔岩和凝灰岩为主。空间上呈线性分布,岩性组合为玄武岩、安山岩、流纹岩。成分一般富镁、贫钾,以钙碱性系列为主。岩石指数、微量元素和稀土元素、同位素特征,均表明岩浆来源于上地幔的部分熔融。岩浆上升演化过程中遭受部分混染作用。是造山带岩浆作用产物。     

Rb-Sr Isotope Dating of Neoproterozoic (Malani Group) Magmatism from Southwest Rajasthan, India: Evidence of Younger Pan-African Thermal Event by Ar-Ar Studies

This paper reports Rb-Sr isotope ages of the Neoproterozoic volcanics, and associated granitoids of the trans-Aravalli belt of northwestern India. All these rocks along with the earlier reported 779±10 Ma old felsic volcanics from Diri, and Gurapratap Singh of Pali district, Rajasthan, constitute the Malani Group. The study indicates that different rock suites belonging to the Malani Group represent a polyphase igneous activity which spanned for about 100 Ma ranging from 780 to 680 Ma. The granitoids of the Malani Group, i.e. peraluminous Jalore type, and peralkaline Siwana type, were emplaced around 730, and 700 Ma ago, respectively. These plutonic suites represent two different magmatic episodes within a short time interval. The initial Sr ratios of these granitoids suggest lower crustal derivation of the magma. The peralkaline granitoids, and the associated peralkaline rhyolites (pantellerites) are coeval, and cogenetic. The ultrapotassic rhyolite exposed at Manihari of Pali district represents the youngest magmatic activity at 681±20 Ma, having a very high initial Sr ratio of 0.7135±0.0033. The high initial Sr ratio of these rocks may be due to incorporation of radiogenic ⁸⁷Sr from the country rock, by assimilation or fusion, into the residual fraction of the magma in the crust which gave rise to other differentiated rocks of the Group.⁴⁰Ar³⁹Ar studies of two Jalore granite samples indicate presence of post crystallisation thermal disturbance between 500550 Ma ago. The timing of this thermal overprinting on the Malani rocks is related to the widespread Pan-African thermo-tectonic event which is witnessed, and magmatically manifested in different part of the Indian shield.     

What is keratophyre?

The rock names keratophyre and quartz keratophyre are beset by confusion and ambiguity. This is due in part to the notion that these sodic rock types originated by albitization of potassic rocks (trachyte and rhyolite) and in part to the existence of two varieties of quartz keratophyre, one with and one without quartz phenocrysts. Though both types of quartz keratophyre are felsic rocks, they are often confused with keratophyre, an intermediate rock. Generally, keratophyre is not albitized trachyte but the sodic-plagioclase counterpart of trachyte. Similarly, quartz keratophyre is not albitized rhyolite but its sodic-plagioclase complement. Keratophyre is less common than quartz keratophyre and the spilite-keratophyre suite is more often a spilite-quartz keratophyre association. Keratophyre and the two types of quartz keratophyre are leucocratic sodic albite-phyric volcanics, the former intermediate and the latter felsic.     

Petrogenesis and tectonics of late Permian felsic volcanic rocks,eastern Qiangtang block,north-central Tibet: Sr and Nd isotopic evidence

The Palaeo-Tethyan tectonic evolution of central Tibet remains a topic of controversy. Two Permian to Late Triassic arc-like volcanic suites have been identified in the eastern Qiangtang (EQ) block of north-central Tibet. Three competing models have been proposed to explain the formation of these volcanic suites, with two models involving a single stage of long-lived subduction but with opposing subduction polarities, while the other model involves a two-stage subduction process. Here, we present new whole-rock geochemistry, including Sr–Nd isotope data, for late Permian felsic volcanics of the Zaduo area. These volcanics are mainly low to middle K calc-alkaline felsic tuffs and rhyolites with SiO₂ concentrations up to 73 wt.%. In primitive mantle-normalized diagrams, the volcanics are typified by large ion lithophile element enrichment and high-field-strength element (e.g. Nb, Ta, P, and Ti) depletion, with slightly negative Eu anomalies. They have initial Sr ratios (⁸⁷Sr/⁸⁶Sr) _i of 0.70319–0.70547, and ?Nd(t) values of +3.4 to +3.5, suggesting derivation by the partial melting of a depleted mantle wedge, followed by assimilation of crustal material. The available geochemical data indicate the presence of two distinctive igneous evolution trends within the Permian to Late Triassic volcanics of the EQ block, consistent with a two-stage subduction model. Permian to Early Triassic arc-like volcanics are formed during northward (present-day orientation) subduction, whereas the Late Triassic volcanics are related to southward (present-day orientation) subduction of mafic crust of the Garze–Litang Ocean.     

二连盆地北缘晚中生代火山岩Ar-Ar年代、地球化学及构造背景

中国东北二连盆地周缘分布有三组时代不同的晚中生代火山岩,其中早、中期为两套地球化学性质不同的流纹岩,晚期为玄武质火山岩。本文通过测定火山岩基质Ar-Ar同位素年龄,表明早期查干诺尔组流纹岩形成于142Ma,晚期不拉根哈达组基性火山岩形成于129Ma,可见二连盆地北缘晚中生代火山岩时代均为早白垩世。通过对主、微量元素地球化学特征和Sr-Nd-Pb同位素组成研究,以及与邻区同期满克头鄂博组英安岩和流纹岩、玛尼吐组英安岩、霍林河地区查干诺尔组英安岩、流纹岩对比,认为早期查干诺尔组流纹岩来源于新成下地壳,岩浆演化过程经历了强烈分异作用;中期流纹岩源区为中上地壳或下地壳岩浆经历了上地壳强烈同化混染作用;晚期不拉根哈达组基性火山岩则源于受俯冲洋壳流体交代的富集岩石圈地幔。结合早白垩世区域岩石圈减薄背景,本文认为研究区早白垩世火山岩形成于陆内伸展构造环境。     

Geology,geochemistry, and genesis of the hot-spring-type Sipingshan gold deposit,eastern Heilongjiang Province,Northeast China

The Sipingshan gold deposit, located in the eastern part of the Nadanhada Terrane, is hosted within cherts and silicified breccias of the Upper Cretaceous Sipingshan Formation and rhyolites of the Upper Cretaceous Datashanlinchang Formation. The orebodies are composed of gold- and pyrite-bearing cherts, silicified breccias, and quartz veins accompanied by various types of wall rock alteration, including silicification, pyritization, sericitization, chloritization, pyrophyllitization, and carbonatization. LA-ICP-MS U–Pb zircon ages determined for the ore-bearing rhyolites range between 122 ± 1.4 and 135.2 ± 1.9 million years slightly older than the metallogenic age of the Sipingshan gold deposit. The rhyolite has aluminium saturation index values ranging from 0.015 to 1.25 and shows the following features: enrichment in LILE (e.g. Rb, Pb, K, and Th); depletion of Ba, Sm, and Ti; and negative Eu anomalies. These geochemical characteristics indicate that (1) the rhyolite contains features typical of S-type granites; (2) the felsic magma likely originated through partial melting of the continental crust; and (3) plagioclase crystals were present in the partial melt residues in the magma source region, or else magma evolution involved plagioclase fractionation. The host cherts have high Al/(Al + Fe + Mn) ratios (0.23–0.81, averaging 0.60) and low Al₂O₃ and TiO₂ contents. Their North American shale-normalized REE patterns are characterized by flat REE, slightly positive Eu anomalies, no Ce anomalies, and (La/Yb)_SN ratios of 1.27–1.38, indicating that these cherts formed in a continental margin environment. In addition, the analysed cherts have low ΣREE (1.56–3.64 ppm) and Zr (9.1–13.5 ppm) contents, suggesting a hydrothermal origin. Fluid inclusions in quartz veins show elliptical to irregular shapes that range from 5 to 12 μm in size and have homogenization temperatures of 118.7–223.4°C, densities of 0.84–0.94 g/cm³, and pressures of 21.2–51.4 MPa, indicating that the hot-spring-type Sipingshan gold deposit is epithermal in origin.     

义敦岛弧带弧后区板内岩浆作用的时代及意义

通过对义敦岛弧夏囊沟一带酸性火山岩的岩石地球化学和Rb-Sr同位素研究,首次在该岛弧弧后区确立了一条板内火山岩带.这些火山岩属钾玄岩系列,以高K2O,低CaO,富Nb、Ta、Zr、Hf,贫Sr、Eu为特点,具标准的"V"型稀土元素配分型式,构造环境判别图解显示其形成于板内裂陷环境.由4个全岩样品给出的Rb-Sr等时线年龄t=189.2±5.0 Ma,相关系数R=0.999?824,ISr=0.714?578.认为火山岩的成分分异受斜长石在岩浆源区熔融残留和岩浆形成后黑云母的结晶分离双重控制.位于该带东侧弧后扩张盆地中的晚三叠世勉戈组双峰火山岩的形成年龄为213.1 Ma,说明该岛弧仅仅在24 Ma左右时限内就完成了从俯冲造弧到板内裂陷的重大转换,由此可对该岛弧带的碰撞造山过程和演化时序做出精确约束.