Concentrations of PCBs,BHCs and DDTs residues in seaweeds of the east coast of Sicily

The levels of PCBs, DDT and BHC residues have been determined in thalli of 12 species of marine algae harvested along the east coast of Sicily. The results are discussed in comparison with those obtained earlier with animal species sampled in the same area.     

Observations and Impacts from the 2010 Chilean and 2011 Japanese Tsunamis in California (USA)

The coast of California was significantly impacted by two recent teletsunami events, one originating off the coast of Chile on February 27, 2010 and the other off Japan on March 11, 2011. These tsunamis caused extensive inundation and damage along the coast of their respective source regions. For the 2010 tsunami, the NOAA West Coast/Alaska Tsunami Warning Center issued a state-wide Tsunami Advisory based on forecasted tsunami amplitudes ranging from 0.18 to 1.43 m with the highest amplitudes predicted for central and southern California. For the 2011 tsunami, a Tsunami Warning was issued north of Point Conception and a Tsunami Advisory south of that location, with forecasted amplitudes ranging from 0.3 to 2.5 m, the highest expected for Crescent City. Because both teletsunamis arrived during low tide, the potential for significant inundation of dry land was greatly reduced during both events. However, both events created rapid water-level fluctuations and strong currents within harbors and along beaches, causing extensive damage in a number of harbors and challenging emergency managers in coastal jurisdictions. Field personnel were deployed prior to each tsunami to observe and measure physical effects at the coast. Post-event survey teams and questionnaires were used to gather information from both a physical effects and emergency response perspective. During the 2010 tsunami, a maximum tsunami amplitude of 1.2 m was observed at Pismo Beach, and over $3-million worth of damage to boats and docks occurred in nearly a dozen harbors, most significantly in Santa Cruz, Ventura, Mission Bay, and northern Shelter Island in San Diego Bay. During the 2011 tsunami, the maximum amplitude was measured at 2.47 m in Crescent City Harbor with over $50-million in damage to two dozen harbors. Those most significantly affected were Crescent City, Noyo River, Santa Cruz, Moss Landing, and southern Shelter Island. During both events, people on docks and near the ocean became at risk to injury with one fatality occurring during the 2011 tsunami at the mouth of the Klamath River. Evaluations of maximum forecasted tsunami amplitudes indicate that the average percent error was 38 and 28 % for the 2010 and 2011 events, respectively. Due to these recent events, the California tsunami program is developing products that will help: (1) the maritime community better understand tsunami hazards within their harbors, as well as if and where boats should go offshore to be safe, and (2) emergency managers develop evacuation plans for relatively small “Warning” level events where extensive evacuation is not required. Because tsunami-induced currents were responsible for most of the damage in these two events, modeled current velocity estimates should be incorporated into future forecast products from the warning centers.     

A new type of primitive baleen whale (Cetacea; Mysticeti) from Kyushu, Japan

Abstract An important and relatively complete fossil mysticete cetacean specimen was collected from the Oligocene age Ashiya Group in Kyushu, Japan. The specimen includes a complete skull, with the anterior part of the vertebral column, several ribs, and the left pectoral limb. It provides significant information about the early evolution of cetotheres and transitional steps from the Archaeoceti to Mysticeti. Several features of the specimen, such as the anterior position of the nasal opening and large mandibular foramen, are primitive, but others are derived, such as the wide maxilla, broad supraorbital process of the frontal, occipital shield overhanging the temporal fossae, and the flat articulation of the distal end of the humerus. This animal, therefore, has a mixture of primitive and derived characters. It represents a stage of evolution in mysticetes that has been previously unrecognized.     

Levels of persistent organic pollutants and residual pattern of DDTs in small cetaceans from the coast of São Paulo, Brazil

The State of São Paulo is the most developed area in Brazil and was impacted by persistent organic pollutants for several decades. This study investigated organochlorines in five species of small cetaceans (Pontoporia blainvillei, Stenella frontalis, Sotalia guianensis, Tursiops truncatus and Steno bredanensis) found dead along the coast of São Paulo between 1997 and 2003. DDTs (15.9 μg g⁻¹ lipid; mean for all pooled individuals) and PCBs (8.08 μg g⁻¹) exhibited the highest concentrations in the animals, reflecting large amounts formerly used in Brazil. Lower levels of mirex (0.149 μg g⁻¹), HCB (0.051 μg g⁻¹), CHLs (0.008 μg g⁻¹) and HCHs (0.007 μg g⁻¹) were detected in all species. Residual pattern of DDTs in dolphins suggests that o,p′-DDT is more recalcitrant than p,p′-DDT in the body of the animals and/or the environment. In contrast to p,p′-DDT, residues of o,p′-DDT seem to be preferentially converted into o,p′-DDD rather than o,p′-DDE.     

Organochlorine contamination (PCBs, DDTs, HCB, HCHs) in sediments from Cienfuegos bay, Cuba

The spatial distribution of various organochlorinated compounds, e.g. PCBs, DDTs, HCB and HCHs, were investigated in sediments from Cienfuegos bay, Cuba. Their concentrations appeared to be relatively low by global standards and only sediments receiving the impact from the residual waters of the city and thermoelectrical power approached the sediment quality guidelines for PCBs and DDTs. Relatively higher ΣDDT concentrations and high DDT/DDE + DDD ratios in two sites near the outfalls of the city indicated a current DDT usage, probably linked to public health emergencies. These results contribute to the sparse regional database for organochlorinated compounds in the Caribbean marine environment.     

A new fossil kentriodontid dolphin (Cetacea; Kentriodontidae) from the Middle Miocene Takinoue Formation, Hokkaido, Japan

Abstract Kentriodon hobetsu , a new species, is described from a partial skull from the Middle Miocene Takinoue Formation, in Hokkaido, Japan. The holotype skull includes the base of the rostrum and a fairly well preserved braincase. The new species is distinguished clearly from previously described species of Kentriodon Kellogg, 1927, by the shape of the anterior margin of the pterygoid sinus fossa, the large premaxilla, rounded facial margin, and lesser development of rugosities and processes. This new record of Kentriodon , the first named kentriodontid dolphin from the western North Pacific, extends the geographic range of the genus significantly.     

Classification and distribution of Oligocene Aetiocetidae (Mammalia; Cetacea; Mysticeti) from western North America and Japan

Abstract Fossil whales in the very rare, primitive, extinct cetacean family Aetiocetidae are small, relict, toothed mysticetes that persisted into Late Oligocene time after more highly derived baleen-bearing mysticetes had already evolved. No known aetiocetid could be ancestral to baleen-bearing mysticetes, but aetiocetid morphology is in many ways intermediate between archaeocetes and baleen-bearing mysticetes, demonstrating the probable transitional steps passed through in the evolution of baleen-bearing mysticetes. Their discovery indicates that mysticetes evolved from Archaeocetes, and supports theories of the monophyly of Cetacea. Late Oligocene aetiocetids have been found on both sides of the North Pacific Ocean: on Vancouver Island, British Columbia, Canada; in Oregon and Washington, USA; in Baja California Sur, México; and the islands of Kyushu and Hokkaido, Japan. The most primitive North American aetiocetid, Chonecetus sookensis Russell, 1968, is from the early Late Oligocene Hesquiat Formation on Vancouver Island, British Columbia, Canada. A more derived, Late Oligocene species, Chonecetus goedertorum Barnes and Furusawa, new species, from the Late Oligocene Pysht Formation, Olympic Peninsula, Washington, has the primitive placental mammalian tooth count of 11/11. The type genus of the family, Aetiocetus Emlong, 1966, has as its type species, A. cotylalveus Emlong, 1966, known only from the Late Oligocene Yaquina Formation on the coast of Oregon. It has 11 upper teeth on each side of the rostrum. A more derived species, Aetiocetus weltoni Barnes and Kimura, new species, from a higher stratigraphic level in the Yaquina Formation, has a more posteriorly positioned cranial vertex and a tooth count of 11/12. We describe four new species of aetiocetids in three genera from the Late Oligocene Morawan Formation near Ashoro, Hokkaido, Japan. The most primitive, Ashorocetus eguchii Barnes and Kimura, new genus and species, has a primitive stage of cranial telescoping, and is closely related to Chonecetus Russell, 1968. Another, Morawanocetus yabukii Kimura and Barnes, new genus and species, in some ways intermediate between Chonecetus and Aetiocetus, has a suite of unique derived characters, including a much foreshortened brain case. The third, Aetiocetus tomitai Kimura and Barnes, new species, is the most primitive species of Aetiocetus yet discovered. The fourth, Aetiocetus polydentatus Sawamura, new species, the most derived species of Aetiocetus known, has a highly telescoped cranium, homodonty, polydonty and a dental count of 13–14/14–15. The fossil record now indicates considerable diversity in the family, with several different contemporaneous lineages in three new subfamilies: Chonecetinae, Morawanocetinae and Aetiocetinae. Aetiocetids are not known outside the North Pacific. Many Recent mysticetes are essentially cosmopolitan, and aetiocetids might have also been relatively widely dispersed. We suspect that with time their remains will be found around other ocean basins also. If so, then they may be potentially useful in trans-oceanic geological correlations.     

A new species of Middle Miocene sperm whale of the genus Scaldicetus (Cetacea; Physeteridae) from Shiga-mura, Japan

Abstract A nearly complete skeleton of a fossil sperm whale from the Middle Miocene age Bessho Formation at Shiga-mura, Nagano Prefecture, the most complete fossil physeterid skeleton found in Japan, is here named Scaldicetus shigensis, new species. Its abruptly tapered rostrum, deep supracranial basin, and high occipital crest are typical of physeterids. Large teeth with crenulate enamel on conical crowns, present in both the palate and mandible, are consistent with the genus Scaldicetus du Bus, 1867, a genus originally based on fossils discovered in the Antwerp Basin, Belgium. Scaldicetus shigensis is relatively primitive, having a relatively long, slender rostrum, large zygomatic arches, large tympanic bullae, prominent occipital condyles, low tooth count and a sloping occipital shield that is deeply emarginated laterally by large temporal fossae. The probable mandibular tooth count is 12, only one more than the primitive eutherian mammalian dentition. Despite its abundant primitive characters, Scaldicetus shigensis has very asymmetrical external nares, comparable to the living sperm whale, Physeter catodon, and is in this way more derived than most of the contemporaneous fossil physeterids. At a time when other sperm whales were more highly evolved, Scaldicetus shigensis retained a primitive occipital shield, large tympanic bullae, and low tooth count, as in primitive Oligocene odontocetes such as Agorophiidae. It was a relict form in Middle Miocene time, and provides an indication of a primitive stage of sperm whale evolution heretofore undocumented. Fossils from elsewhere previously referred to as Scaldicetus, largely on the basis of tooth characters, range in age from Early Miocene to Plio-Pleistocene time. Cranial material that would clarify relationships is lacking for most of these, and this time range seems too long for a cetacean genus. Because of this simplistic approach to identifications, Scaldicetus is probably a grade taxon, not a natural biological grouping. However, the tooth morphology of Scaldicetus shigensis is correct for the genus Scaldicetus, so we provisionally assign it to this genus. Redefinition of the genus Scaldicetus and revision of the Physeteridae are beyond the scope of the present study.     

Monitoring of heavy metals in wild mussels (Mytilus galloprovincialis) from the Spanish North-Atlantic coast

Concentrations of five heavy metals (Hg, Cd, Pb, Cu and Zn) were determined in tissues of wild mussels (Mytilus galloprovincialis) collected at 41 stations located on the Spanish Atlantic and Northern coasts to assess the levels and spatial distribution of metals in the environment. This study, performed in 2005, constituted a contribution to the last international OSPAR pollution monitoring survey. A pool of mussel soft tissue was prepared using 50 or more individuals, representing the size range present at the sampling points. Quantification was carried out after a nitric acid digestion by atomic absorption spectrometry, AAS (Cd and Pb by electrothermal AAS; Cu and Zn by flame AAS; and total mercury by the cold vapour technique). The quality of the chemical analyses was assessed by interlaboratory exercises carried out on a regular basis. In general, the levels of the metals were higher for the Northern region than for the Atlantic one (except for a sampling site close to Vigo, one of the main Galician industrial areas). Some Galician sampling points (Atlantic coast, NW of Spain) located far from human inputs showed high Cd concentrations, which were attributed to the annual upwelling processes in this region. The levels of Cu increased from Northwest to East, whereas Zn concentrations were very homogeneous throughout the two studied geographical regions. These results were confirmed using multivariate studies (PCA and cluster analysis), as well as international ‘background assessment concentrations’ criteria.     

Polychlorinated biphenyls and chlorinated pesticides in harbor seals (Phoca vitulina concolor) from the northwestern Atlantic coast

Concentrations of polychlorinated biphenyls (PCBs), dichlorodiphenyltrichloroethane (DDT) and its metabolites, chlordane-related compounds (CHLs), mirex, hexachlorocyclohexane isomers (HCHs), dieldrin, and hexachlorobenzene (HCB) were determined in blubber of harbor seals (Phoca vitulina concolor) from the northwestern Atlantic coast. PCBs, DDTs, and CHLs were the major persistent organochlorines in harbor seal blubber, while mirex, HCHs, dieldrin, and HCB were minor contaminants. Highest concentrations were found in the adult males, followed by the pups, yearlings, adult females, and fetuses. DDT and PCB concentrations have declined from the high levels reported in the early 1970s, but no declines were observed in our samples over the ten-year period 1991-2001. DDT/PCB ratios were indicative of a more rapid decline of DDTs than PCBs, while ratios of p,p'-DDE/DDT were indicative of a metabolic "weathering" of DDT. The population appears to be susceptible to disease outbreaks, as evidenced by a recurrence of viral epizootics since the late 1970s. The PCB burdens in these seals are similar to levels reported in seals from polluted regions of Europe and Asia, and exceed the estimated threshold levels for adverse reproductive and immune system effects in the species.     

Evaporation from shallow groundwater in closed basins in the Chilean Altiplano

Abstract

The hydrological cycle in arid and semi-arid climates is highly controlled by evaporation. The correct quantification of this process is essential for improving the accuracy of water balance estimates, especially in closed basins. The objective of this paper is to characterize evaporation rates from shallow groundwater using the chamber approach in six closed basins in the Altiplano of northern Chile. Measurements were made at 49 locations with water-table depths ranging from 0.09 m to 3.3 m. Estimated daily evaporation rates appeared to be strongly related to groundwater depth and soil texture. In particular, the highest rates were recorded in areas with high groundwater tables and coarse-grained soils. Evaporation curves were derived by fitting exponential and power relationships as functions of the groundwater depths that we proposed to use in the study area. An application of these curves for the Salar de Pedernales basin produced an estimated evaporation flow of 530 L s^-1, using the average curve.

Citation Johnson, E., Yáñez, J., Ortiz, C. & Muñoz, J. (2010) Evaporation from shallow groundwater in closed basins in the Chilean Altiplano. Hydrol. Sci. J. 55(4), 624–635.