共查询到20条相似文献,搜索用时 31 毫秒
1.
C. M. Gibson-Poole L. Svendsen J. Underschultz M. N. Watson J. Ennis-King P. J. van Ruth E. J. Nelson R. F. Daniel Y. Cinar 《Environmental Geology》2008,54(8):1583-1606
Geological storage of CO2 in the offshore Gippsland Basin, Australia, is being investigated by the Cooperative Research Centre for Greenhouse Gas Technologies
(CO2CRC) as a possible method for storing the very large volumes of CO2 emissions from the nearby Latrobe Valley area. A storage capacity of about 50 million tonnes of CO2 per annum for a 40-year injection period is required, which will necessitate several individual storage sites to be used
both sequentially and simultaneously, but timed such that existing hydrocarbon assets will not be compromised. Detailed characterisation
focussed on the Kingfish Field area as the first site to be potentially used, in the anticipation that this oil field will
be depleted within the period 2015–2025. The potential injection targets are the interbedded sandstones of the Paleocene-Eocene
upper Latrobe Group, regionally sealed by the Lakes Entrance Formation. The research identified several features to the offshore
Gippsland Basin that make it particularly favourable for CO2 storage. These include: a complex stratigraphic architecture that provides baffles which slow vertical migration and increase
residual gas trapping and dissolution; non-reactive reservoir units that have high injectivity; a thin, suitably reactive,
lower permeability marginal reservoir just below the regional seal providing mineral trapping; several depleted oil fields
that provide storage capacity coupled with a transient production-induced flow regime that enhances containment; and long
migration pathways beneath a competent regional seal. This study has shown that the Gippsland Basin has sufficient capacity
to store very large volumes of CO2. It may provide a solution to the problem of substantially reducing greenhouse gas emissions from future coal developments
in the Latrobe Valley. 相似文献
2.
Europe’s longest-operating on-shore CO2 storage site at Ketzin, Germany: a progress report after three years of injection 总被引:3,自引:3,他引:0
S. Martens T. Kempka A. Liebscher S. Lüth F. M?ller A. Myrttinen B. Norden C. Schmidt-Hattenberger M. Zimmer M. Kühn 《Environmental Earth Sciences》2012,67(2):323-334
The Ketzin pilot site, led by the GFZ German Research Centre for Geosciences, is Europe??s longest-operating on-shore CO2 storage site with the aim of increasing the understanding of geological storage of CO2 in saline aquifers. Located near Berlin, the Ketzin pilot site is an in situ laboratory for CO2 storage in an anticlinal structure in the Northeast German Basin. Starting research within the framework of the EU project CO2SINK in 2004, Ketzin is Germany??s first CO2 storage site and fully in use since the injection began in June 2008. After 39?months of operation, about 53,000 tonnes of CO2 have been stored in 630?C650?m deep sandstone units of the Upper Triassic Stuttgart Formation. An extensive monitoring program integrates geological, geophysical and geochemical investigations at Ketzin for a comprehensive characterization of the reservoir and the CO2 migration at various scales. Integrating a unique field and laboratory data set, both static geological modeling and dynamic simulations are regularly updated. The Ketzin project successfully demonstrates CO2 storage in a saline aquifer on a research scale. The results of monitoring and modeling can be summarized as follows: (1) Since the start of the CO2 injection in June 2008, the operation has been running reliably and safely. (2) Downhole pressure data prove correlation between the injection rate and the reservoir pressure and indicates the presence of an overall dynamic equilibrium within the reservoir. (3) The extensive geochemical and geophysical monitoring program is capable of detecting CO2 on different scales and gives no indication for any leakage. (4) Numerical simulations (history matching) are in good agreement with the monitoring results. 相似文献
3.
The CO2 migrated from deeper to shallower layers may change its phase state from supercritical state to gaseous state (called phase transition). This phase transition makes both viscosity and density of CO2 experience a sharp variation, which may induce the CO2 further penetration into shallow layers. This is a critical and dangerous situation for the security of CO2 geological storage. However, the assessment of caprock sealing efficiency with a fully coupled multi-physical model is still missing on this phase transition effect. This study extends our previous fully coupled multi-physical model to include this phase transition effect. The dramatic changes of CO2 viscosity and density are incorporated into the model. The impacts of temperature and pressure on caprock sealing efficiency (expressed by CO2 penetration depth) are then numerically investigated for a caprock layer at the depth of 800 m. The changes of CO2 physical properties with gas partial pressure and formation temperature in the phase transition zone are explored. It is observed that phase transition revises the linear relationship of CO2 penetration depth and time square root as well as penetration depth. The real physical properties of CO2 in the phase transition zone are critical to the safety of CO2 sequestration. Pressure and temperature have different impact mechanisms on the security of CO2 geological storage. 相似文献
4.
Qi Fang Junwen Lv Guojian Peng Caiwu Luo Mi Li Wenfa Tan Yingfeng Luo 《Environmental Earth Sciences》2017,76(13):464
Deep brine recovery enhanced by supercritical CO2 injection is proposed to be a win–win method for the enhancement of brine production and CO2 storage capacity and security. However, the cross-flow through interlayers under different permeability conditions is not well investigated for a multi-layer aquifer system. In this work, a multi-layer aquifer system with different permeability conditions was built up to quantify the brine production yield and the leakage risk under both schemes of pure brine recovery and enhanced by supercritical CO2. Numerical simulation results show that the permeability conditions of the interlayers have a significant effect on the brine production and the leakage risk as well as the regional pressure. Brine recovery enhanced by supercritical CO2 injection can improve the brine production yield by a factor of 2–3.5 compared to the pure brine recovery. For the pure brine recovery, strong cross-flow through interlayers occurs due to the drastic and extensive pressure drop, even for the relative low permeability (k = 10?20 m2) mudstone interlayers. Brine recovery enhanced by supercritical CO2 can successfully manage the regional pressure and decrease the leakage risk, even for the relative high permeability (k = 10?17 m2) mudstone interlayers. In addition, since the leakage of brine mainly occurs in the early stage of brine production, it is possible to minimize the leakage risk by gradually decreasing the brine production pressure at the early stage. Since the leakage of CO2 occurs in the whole production period and is significantly influenced by the buoyancy force, it may be more effective by adopting horizontal wells and optimizing well placement to reduce the CO2 leakage risk. 相似文献
5.
Liwei Zhang Robert Dilmore Argha Namhata Grant Bromhal 《Computational Geosciences》2018,22(3):909-923
A numerical model was developed to investigate the potential to detect fluid migration in a (homogeneous, isotropic, with constant pressure lateral boundaries) porous and permeable interval overlying an imperfect primary seal of a geologic CO2 storage formation. The seal imperfection was modeled as a single higher-permeability zone in an otherwise low-permeability seal, with the center of that zone offset from the CO2 injection well by 1400 m. Pressure response resulting from fluid migration through the high-permeability zone was detectable up to 1650 m from the centroid of that zone at the base of the monitored interval after 30 years of CO2 injection (detection limit = 0.1 MPa pressure increase); no pressure response was detectable at the top of the monitored interval at the same point in time. CO2 saturation response could be up to 774 m from the center of the high-permeability zone at the bottom of the monitored interval, and 1103 m at the top (saturation detection limit = 0.01). More than 6% of the injected CO2, by mass, migrated out of primary containment after 130 years of site performance (including 30 years of active injection) in the case where the zone of seal imperfection had a moderately high permeability (10??17 m2 or 0.01 mD). Free-phase CO2 saturation monitoring at the top of the overlying interval provides favorable spatial coverage for detecting fluid migration across the primary seal. Improved sensitivity of detection for pressure perturbation will benefit time of detection above an imperfect seal. 相似文献
6.
Modeling geological carbon storage represents a new and substantial challenge for the subsurface geosciences. To increase understanding and make good engineering decisions, containment processes and large-scale storage operations must be simulated in a thousand-year perspective. Large differences in spatial and temporal scales make it prohibitively expensive to compute the fate of injected CO2 using traditional 3D simulators. Instead, accurate forecast can be computed using simplified models that are adapted to the specific setting of the bouyancy-driven migration of the light fluid phase. This paper presents a family of vertically integrated models for studying the combined large-scale and long-term effects of structural, residual, and solubility trapping of CO2. The models are based on an assumption of a sharp interface separating CO2 and brine and can provide a detailed inventory of the injected CO2 volumes over periods of thousands of years within reasonable computational time. To be compatible with simulation tools used in industry, the models are formulated in a black-oil framework. The models are implemented in MRST-co2lab, which is an open community software developed especially to study and optimize large-scale, long-term geological storage of CO2. The resulting simulators are fully implicit and handle input from standard geomodeling tools. 相似文献
7.
Deep saline aquifers in sedimentary basins are considered to have the greatest potential for CO2 geological storage in order to reduce carbon emissions. CO2 injected into a saline sandstone aquifer tends to migrate upwards toward the caprock because the density of the supercritical CO2 phase is lower than that of formation water. The accumulated CO2 in the upper portions of the reservoir gradually dissolves into brine, lowers pH and changes the aqueous complexation, whereby induces mineral alteration. In turn, the mineralogical composition could impose significant effects on the evolution of solution, further on the mineralized CO2. The high density of aqueous phase will then move downward due to gravity, give rise to “convective mixing,” which facilitate the transformation of CO2 from the supercritical phase to the aqueous phase and then to the solid phase. In order to determine the impacts of mineralogical compositions on trapping amounts in different mechanisms for CO2 geological storage, a 2D radial model was developed. The mineralogical composition for the base case was taken from a deep saline formation of the Ordos Basin, China. Three additional models with varying mineralogical compositions were carried out. Results indicate that the mineralogical composition had very obvious effects on different CO2 trapping mechanisms. Specific to our cases, the dissolution of chlorite provided Mg2+ and Fe2+ for the formation of secondary carbonate minerals (ankerite, siderite and magnesite). When chlorite was absent in the saline aquifer, the dominant secondary carbon sequestration mineral was dawsonite, and the amount of CO2 mineral trapping increased with an increase in the concentration of chlorite. After 3000 years, 69.08, 76.93, 83.52 and 87.24 % of the injected CO2 can be trapped in the solid (mineral) phase, 16.05, 11.86, 8.82 and 6.99 % in the aqueous phase, and 14.87, 11.21, 7.66 and 5.77 % in the gas phase for Case 1 through 4, respectively. 相似文献
8.
Craig A. Griffith David A. Dzombak Gregory V. Lowry 《Environmental Earth Sciences》2011,64(4):925-948
Capture and geological sequestration of CO2 from energy production is proposed to help mitigate climate change caused by anthropogenic emissions of CO2 and other greenhouse gases. Performance goals set by the US Department of Energy for CO2 storage permanence include retention of at least 99% of injected CO2 which requires detailed assessments of each potential storage site’s geologic system, including reservoir(s) and seal(s).
The objective of this study was to review relevant basin-wide physical and chemical characteristics of geological seals considered
for saline reservoir CO2 sequestration in the United States. Results showed that the seal strata can exhibit substantial heterogeneity in the composition,
structural, and fluid transport characteristics on a basin scale. Analysis of available field and wellbore core data reveal
several common inter-basin features of the seals, including the occurrence of quartz, dolomite, illite, calcite, and glauconite
minerals along with structural features containing fractures, faults, and salt structures. In certain localities within the
examined basins, some seal strata also serve as source rock for oil and gas production and can be subject to salt intrusions.
The regional features identified in this study can help guide modeling, laboratory, and field studies needed to assess local
seal performances within the examined basins. 相似文献
9.
One of the uncertainties in the field of carbon dioxide capture and storage (CCS) is caused by the parameterization of geochemical
models. The application of geochemical models contributes significantly to calculate the fate of the CO2 after its injection. The choice of the thermodynamic database used, the selection of the secondary mineral assemblage as
well as the option to calculate pressure dependent equilibrium constants influence the CO2 trapping potential and trapping mechanism. Scenario analyses were conducted applying a geochemical batch equilibrium model
for a virtual CO2 injection into a saline Keuper aquifer. The amount of CO2 which could be trapped in the formation water and in the form of carbonates was calculated using the model code PHREEQC.
Thereby, four thermodynamic datasets were used to calculate the thermodynamic equilibria. Furthermore, the equilibrium constants
were re-calculated with the code SUPCRT92, which also applied a pressure correction to the equilibrium constants. Varying
the thermodynamic database caused a range of 61% in the amount of trapped CO2 calculated. Simultaneously, the assemblage of secondary minerals was varied, and the potential secondary minerals dawsonite
and K-mica were included in several scenarios. The selection of the secondary mineral assemblage caused a range of 74% in
the calculated amount of trapped CO2. Correcting the equilibrium constants with respect to a pressure of 125 bars had an influence of 11% on the amount of trapped
CO2. This illustrates the need for incorporating sensitivity analyses into reaction pathway modeling. 相似文献
10.
Structural traps like anticline structures are preferred for carbon dioxide sequestration as they limit lateral spreading of CO2 and thus provide localized storage. This study, therefore, assesses strategies for maximizing storage of CO2 using as hypothetical but realistic storage site a typical anticline structure in the North German sedimentary basin. Scenario simulations are performed to investigate the effects of well number, location, spacing and alignment, using fracture pressure and containment of CO2 within the anticline as constraining factors. Scenarios are ranked by stored CO2 mass, pressure increase due to injection and CO2 immobilized by dissolution or residual trapping. It is found that pressure overlap from different injectors influences CO2 migration considerably, limiting the storable amount to about 150 Mt, which represents half of the static capacity estimate. 相似文献
11.
Carbon dioxide (CO2) has been injected in the subsurface permeable formations as a means to cut atmospheric CO2 emissions and/or enhance oil recovery (EOR). It is important to constrain the boundaries of the CO2 plume in the target formation and/or other formations hosting the CO2 migrated from the target formation. Monitoring methods and technologies to assess the CO2 plume boundaries over time within a reservoir of interest are required. Previously introduced methods and technologies on pressure monitoring to detect the extent of the CO2 plume require at least two wells, i.e. pulser and observation wells. We introduce pressure transient technique requiring single well only. Single well pressure transient testing (drawdown/buildup/injection/falloff) is widely used to determine reservoir properties and wellbore conditions. Pressure diagnostic plots are used to identify different flow regimes and determine the reservoir/well characteristics. We propose a method to determine the plume extent for a constant rate pressure transient test at a single well outside the CO2 plume. Due to the significant contrast between mobility and storativity of the CO2 and native fluids (oil or brine), the CO2 boundary causes deviation in the pressure diagnostic response from that corresponding to previously identified heterogeneities. Using the superposition principle, we develop a relationship between the deviation time and the plume boundary. We demonstrate the applicability of the proposed method using numerically generated synthetic data corresponding to homogeneous, heterogeneous, and anisotropic cases to evaluate its potential and limitations. We discuss ways to identify and overcome the potential limitations for application of the method in the field. 相似文献
12.
Herwig Marbler Kirsten P. Erickson Michael Schmidt Christof Lempp Herbert Pöllmann 《Environmental Earth Sciences》2013,69(6):1981-1998
The geochemical and geomechanical behaviour of reservoir rocks from deep saline aquifers during the injection and geological storage of CO2 is studied in laboratory experiments. A combination of geochemical and geomechanical studies was carried out on various sandstones from the North German Basin. After the mineralogical, geochemical and petrophysical characterization, a set of sandstone samples was exposed to supercritical (sc)CO2 and brine for 2–4 weeks in an autoclave system. One sample was mineralogically and geochemically characterised and then loaded in a triaxial cell under in situ pressure and temperature conditions to study the changes of the geomechanical rock properties. After treatment in the autoclaves, geochemical alterations mainly in the carbonate, but also in the sheet silicate cements as well as in single minerals of the sandstones were observed, affecting the rocks granular structure. In addition to partial solution effects during the geochemical experiments, small grains of secondary carbonate and other mineral precipitations were observed within the pore space of the treated sandstones. Results of additional geomechanical experiments with untreated samples show that the rock strength is influenced by the saturation degree, the confining pressure, the pore fluid pressure and temperature. The exposure to pure scCO2 in the autoclave system induces reduced strength parameters, modified elastic deformation behaviour and changes of the effective porosity in comparison to untreated sandstone samples. Experimental results show that the volume of pore fluid fluxing into the pore space of the sandstones clearly depends on the saturation level of the sample. 相似文献
13.
14.
Potential assessment of CO2 geological storage based on injection scenario simulation: A case study in eastern Junggar Basin
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Ma Xin Wen Dong-guang Yang Guo-dong Li Xu-feng Diao Yu-jie Dong Hai-hai Cao Wei Yin Shu-guo Zhang Yan-mei 《地下水科学与工程》2021,9(4):279-291
Carbon Capture and Storage (CCS) is one of the effective means to deal with global warming, and saline aquifer storage is considered to be the most promising storage method. Junggar Basin, located in the northern part of Xinjiang and with a large distribution area of saline aquifer, is an effective carbon storage site. Based on well logging data and 2D seismic data, a 3D heterogeneous geological model of the Cretaceous Donggou Formation reservoir near D7 well was constructed, and dynamic simulations under two scenarios of single-well injection and multi-well injection were carried out to explore the storage potential and CO2 storage mechanism of deep saline aquifer with real geological conditions in this study. The results show that within 100 km2 of the saline aquifer of Donggou Formation in the vicinity of D7 well, the theoretical static CO2 storage is 71.967 × 106 tons (P50)① , and the maximum dynamic CO2 storage is 145.295 × 106 tons (Case2). The heterogeneity of saline aquifer has a great influence on the spatial distribution of CO2 in the reservoir. The multi-well injection scenario is conducive to the efficient utilization of reservoir space and safer for storage. Based on the results from theoretical static calculation and the dynamic simulation, the effective coefficient of CO2 storage in deep saline aquifer in the eastern part of Xinjiang is recommended to be 4.9%. This study can be applied to the engineering practice of CO2 sequestration in the deep saline aquifer in Xinjiang. 相似文献
15.
W. A. Ambrose C. Breton M. H. Holtz V. Núñez-López S. D. Hovorka I. J. Duncan 《Environmental Geology》2009,57(7):1537-1551
Documenting geographic distribution and spatial linkages between CO2 sources and potential sinks in areas with significant levels of CO2 emissions is important when considering carbon-management strategies such as geologic sequestration or enhanced oil recovery
(EOR). For example, the US Gulf Coast overlies a thick succession (>6,000 m [>20,000 ft]) of highly porous and permeable sandstone
formations separated by thick, regionally extensive shale aquitards. The Gulf Coast and Permian Basin also have a large potential
for EOR, in which CO2 injected into suitable oil reservoirs could be followed by long-term storage of CO2 in nonproductive formations below reservoir intervals. For example, >6 billion barrels (Bbbl) of oil from 182 large reservoirs
is technically recoverable in the Permian Basin as a result of miscible-CO2 flooding. The Gulf Coast also contains an additional 4.5 Bbbl of oil that could be produced by using miscible CO2. Although the CO2 pipeline infrastructure is well-developed in the Permian Basin, east Texas and the Texas Gulf Coast may have a greater long-term
potential for deep, permanent storage of CO2 because of thick brine-bearing formations near both major subsurface and point sources of CO2. 相似文献
16.
CO2 is now considered as a novel heat transmission fluid to extract geothermal energy. It can achieve the goal of energy exploitation and CO2 geological sequestration. Taking Zhacanggou as research area, a “Three-spot” well pattern (one injection with two production), “wellbore–reservoir” coupled model is built, and a constant injection rate is set up. A fully coupled wellbore–reservoir simulator—T2Well—is introduced to study the flow mechanism of CO2 working as heat transmission fluid, the variance pattern of each physical field, the influence of CO2 injection rate on heat extraction and the potential and sustainability of heat resource in Guide region. The density profile variance resulting from temperature differences of two wells can help the system achieve “self-circulation” by siphon phenomenon, which is more significant in higher injection rate cases. The density of CO2 is under the effect of both pressure and temperature; moreover, it has a counter effect on temperature and pressure. The feedback makes the flow process in wellbore more complex. In low injection rate scenarios, the temperature has a dominating impact on the fluid density, while in high rate scenario, pressure plays a more important role. In most scenarios, it basically keeps stable during 30-year operation. The decline of production temperature is <5 °C. However, for some high injection rate cases (75 and 100 kg/s), due to the heat depletion in reservoir, there is a dramatic decline for production temperature and heat extraction rate. Therefore, a 50-kg/s CO2 injection rate is more suitable for “Three-spot” well pattern in Guide region. 相似文献
17.
Shib Sankar Ganguli Nimisha Vedanti Idar Akervoll V. P. Dimri 《Journal of the Geological Society of India》2016,88(3):273-280
The utilization of anthropogenic CO2 for enhanced oil recovery (EOR) can significantly extend the production life of an oil field, and help in the reduction of atmospheric emission of anthropogenic CO2 if sequestration is considered. This work summarizes the prospect of EOR and sequestration using CO2 flooding from an Indian mature oil field at Cambay basin through numerical modelling, simulation and pressure study based on limited data provided by the operator. To get an insight into CO2-EOR and safe storage process in this oil field, a conceptual sector model is developed and screening standard is proposed keeping in mind the major pay zone of the producing reservoir. To construct the geomodel, depth maps, well positions and coordinates, well data and well logs, perforation depths and distribution of petrophysical properties as well as fluid properties provided by the operator, has been considered. Based on the results from the present study, we identified that the reservoir has the potential for safe and economic geological sequestration of 15.04×106 metric ton CO2 in conjunction with a substantial increase in oil recovery of 10.4% of original oil in place. CO2-EOR and storage in this mature field has a bright application prospect since the findings of the present work could be a better input to manage the reservoir productivity, and the pressure field for significant enhancement of oil recovery followed by safe storage. 相似文献
18.
Pressure buildup limits CO2 injectivity and storage capacity and pressure loss limits the brine production capacity and security, particularly for closed and semi-closed formations. In this study, we conduct a multiwell model to examine the potential advantages of combined exhaustive brine production and complete CO2 storage in deep saline formations in the Jiangling Depression, Jianghan Basin of China. Simulation results show that the simultaneous brine extraction and CO2 storage in saline formation not only effectively regulate near-wellbore and regional pressure of storage formation, but also can significantly enhance brine production capacity and CO2 injectivity as well as storage capacity, thereby achieving maximum utilization of underground space. In addition, the combination of brine production and CO2 injection can effectively mitigate the leakage risk between the geological units. With regard to the scheme of brine production and CO2 injection, constant pressure injection is much superior to constant rate injection thanks to the mutual enhancement effect. The simultaneous brine production of nine wells and CO2 injection of four wells under the constant pressure injection scheme act best in all respects of pressure regulation, brine production efficiency, CO2 injectivity and storage capacity as well as leakage risk mitigation. Several ways to further optimize the combined strategy are investigated and the results show that increasing the injection pressure and adopting fully penetrating production wells can further significantly enhance the combined efficiency; however, there is no obvious promoting effect by shortening the well spacing and changing the well placement. 相似文献
19.
Geological sequestration of CO2 is an option for significantly reducing emissions into the atmosphere. Various hydrocarbon companies in western Canada are currently injecting acid-gas (CO2 and H2S) into deep subsurface formations. At West Stoddart, in northeast British Columbia, acid-gas has been injected since 1998 at 1600 m depth into sandstones of the Triassic Halfway Formation, which forms a regional aquifer. A comprehensive subsurface characterization was conducted of the regional and local-scale geology, reservoir characteristics, mineralogy, in situ fluid properties, and hydrogeology. Preliminary results from geochemical and numerical multi-phase flow modelling suggest that the majority of the injected acid-gas will dissolve in the formation water and remain within a radius of a few kilometres of the injection well. The experience with the acid-gas injection at West Stoddart and other operations in the Alberta Basin has shown that the process of large-scale CO2-injection into deep aquifers is technically feasible. 相似文献
20.
The discovery of Hadean to Paleoarchean zircons in a metaconglomerate from Jack Hills, Western Australia, has catalyzed intensive study of these zircons and their mineral inclusions, as they represent unique geochemical archives that can be used to unravel the geological evolution of early Earth. Here, we report the occurrence and physical properties of previously undetected CO2 inclusions that were identified in 3.36–3.47 Ga and 3.80–4.13 Ga zircon grains by confocal micro-Raman spectroscopy. Minimum P–T conditions of zircon formation were determined from the highest density of the inclusions, determined from the density-dependence of the Fermi diad splitting in the Raman spectrum and Ti-in-zircon thermometry. For both age periods, the CO2 densities and Ti-in-zircon temperatures correspond to high-grade metamorphic conditions (≥5 to ≥7 kbar/~670 to 770 °C) that are typical of mid-crustal regional metamorphism throughout Earth’s history. In addition, fully enclosed, highly disordered graphitic carbon inclusions were identified in two zircon grains from the older population that also contained CO2 inclusions. Transmission electron microscopy on one of these inclusions revealed that carbon forms a thin amorphous film on the inclusion wall, whereas the rest of the volume was probably occupied by CO2 prior to analysis. This indicates a close relationship between CO2 and the reduced carbon inclusions and, in particular that the carbon precipitated from a CO2-rich fluid, which is inconsistent with the recently proposed biogenic origin of carbon inclusions found in Hadean zircons from Jack Hills. 相似文献