The influence of flow discharge variations on the morphodynamics of a diffluence–confluence unit on a large river

Bifurcations are key geomorphological nodes in anabranching and braided fluvial channels, controlling local bed morphology, the routing of sediment and water, and ultimately defining the stability of their associated diffluence–confluence unit. Recently, numerical modelling of bifurcations has focused on the relationship between flow conditions and the partitioning of sediment between the bifurcate channels. Herein, we report on field observations spanning September 2013 to July 2014 of the three‐dimensional flow structure, bed morphological change and partitioning of both flow discharge and suspended sediment through a large diffluence–confluence unit on the Mekong River, Cambodia, across a range of flow stages (from 13 500 to 27 000 m³ s^?1). Analysis of discharge and sediment load throughout the diffluence–confluence unit reveals that during the highest flows (Q = 27 000 m³ s^?1), the downstream island complex is a net sink of sediment (losing 2600 ± 2000 kg s^?1 between the diffluence and confluence), whereas during the rising limb (Q = 19 500 m³ s^?1) and falling limb flows (Q = 13 500 m³ s^?1) the sediment balance is in quasi‐equilibrium. We show that the discharge asymmetry of the bifurcation varies with discharge and highlight that the influence of upstream curvature‐induced water surface slope and bed morphological change may be first‐order controls on bifurcation configuration. Comparison of our field data to existing bifurcation stability diagrams reveals that during lower (rising and falling limb) flow the bifurcation may be classified as unstable, yet transitions to a stable condition at high flows. However, over the long term (1959–2013) aerial imagery reveals the diffluence–confluence unit to be fairly stable. We propose, therefore, that the long‐term stability of the bifurcation, as well as the larger channel planform and morphology of the diffluence–confluence unit, may be controlled by the dominant sediment transport regime of the system. © 2017 The Authors. Earth Surface Processes and Landforms published by John Wiley & Sons Ltd.     

Factors controlling the chemical evolution of travertine‐depositing rivers of the Barkly karst,northern Australia

Groundwaters feeding travertine‐depositing rivers of the northeastern segment of the Barkly karst (NW Queensland, Australia) are of comparable chemical composition, allowing a detailed investigation of how the rate of downstream chemical evolution varies from river to river. The discharge, pH, temperature, conductivity and major‐ion concentrations of five rivers were determined by standard field and laboratory techniques. The results show that each river experiences similar patterns of downstream chemical evolution, with CO₂ outgassing driving the waters to high levels of calcite supersaturation, which in turn leads to widespread calcium carbonate deposition. However, the rate at which the waters evolve, measured as the loss of CaCO₃ per kilometre, varies from river to river, and depends primarily upon discharge at the time of sampling and stream gradient. For example, Louie Creek (Q = 0·11 m³ s^?1) and Carl Creek (Q = 0·50 m³ s^?1) have identical stream gradients, but the loss of CaCO₃ per kilometre for Louie Creek is twice that of Carl Creek. The Gregory River (Q = 3·07 m³ s^?1), O'Shanassy River (Q = 0·57 m³ s^?1) and Lawn Hill Creek (Q = 0·72 m³ s^?1) have very similar gradients, but the rate of hydrochemical evolution of the Gregory River is significantly less than either of the other two systems. The results have major implications for travertine deposition: the stream reach required for waters to evolve to critical levels of calcite supersaturation will, all others things being equal, increase with increasing discharge, and the length of reach over which travertine is deposited will also increase with increasing discharge. This implies that fossil travertine deposits preserved well downstream of modern deposition limits are likely to have been formed under higher discharge regimes. Copyright © 2002 John Wiley & Sons, Ltd.     

The effect of El Niño Southern Oscillation cycles on the decadal scale suspended sediment behavior of a coastal dry‐summer subtropical catchment

Rivers display temporal dependence in suspended sediment–water discharge relationships. Although most work has focused on multi‐decadal trends, river sediment behavior often displays sub‐decadal scale fluctuations that have received little attention. The objectives of this study were to identify inter‐annual to decadal scale fluctuations in the suspended sediment–discharge relationship of a dry‐summer subtropical river, infer the mechanisms behind these fluctuations, and examine the role of El Niño Southern Oscillation climate cycles. The Salinas River (California) is a moderate sized (11 000 km²), coastal dry‐summer subtropical catchment with a mean discharge (Q_mean) of 11.6 m³ s^?1. This watershed is located at the northern most extent of the Pacific coastal North America region that experiences increased storm frequency during El Niño years. Event to inter‐annual scale suspended sediment behavior in this system was known to be influenced by antecedent hydrologic conditions, whereby previous hydrologic activity regulates the suspended sediment concentration–water discharge relationship. Fine and sand suspended sediment in the lower Salinas River exhibited persistent, decadal scale periods of positive and negative discharge corrected concentrations. The decadal scale variability in suspended sediment behavior was influenced by inter‐annual to decadal scale fluctuations in hydrologic characteristics, including: elapsed time since small (~0.1 × Q_mean), and moderate (~10 × Q_mean) threshold discharge values, the number of preceding days that low/no flow occurred, and annual water yield. El Niño climatic activity was found to have little effect on decadal‐scale fluctuations in the fine suspended sediment–discharge relationship due to low or no effect on the frequency of moderate to low discharge magnitudes, annual precipitation, and water yield. However, sand concentrations generally increased in El Niño years due to the increased frequency of moderate to high magnitude discharge events, which generally increase sand supply. Copyright © 2014 John Wiley & Sons, Ltd.     

Assessing regional‐scale spatio‐temporal patterns of groundwater–surface water interactions using a coupled SWAT‐MODFLOW model

Interaction between groundwater and surface water in watersheds has significant impacts on water management and water rights, nutrient loading from aquifers to streams, and in‐stream flow requirements for aquatic species. Of particular importance are the spatial patterns of these interactions. This study explores the spatio‐temporal patterns of groundwater discharge to a river system in a semi‐arid region, with methods applied to the Sprague River Watershed (4100 km²) within the Upper Klamath Basin in Oregon, USA. Patterns of groundwater–surface water interaction are explored throughout the watershed during the 1970–2003 time period using a coupled SWAT‐MODFLOW model tested against streamflow, groundwater level and field‐estimated reach‐specific groundwater discharge rates. Daily time steps and coupling are used, with groundwater discharge rates calculated for each model computational point along the stream. Model results also are averaged by month and by year to determine seasonal and decadal trends in groundwater discharge rates. Results show high spatial variability in groundwater discharge, with several locations showing no groundwater/surface water interaction. Average annual groundwater discharge is 20.5 m³/s, with maximum and minimum rates occurring in September–October and March–April, respectively. Annual average rates increase by approximately 0.02 m³/s per year over the 34‐year period, negligible compared with the average annual rate, although 70% of the stream network experiences an increase in groundwater discharge rate between 1970 and 2003. Results can assist with water management, identifying potential locations of heavy nutrient mass loading from the aquifer to streams and ecological assessment and planning focused on locations of high groundwater discharge. Copyright © 2016 John Wiley & Sons, Ltd.     

Role of bedrock groundwater in the rainfall–runoff process in a small headwater catchment underlain by volcanic rock

The role of bedrock groundwater in rainfall–runoff processes is poorly understood. Hydrometric, tracer and subsurface water potential observations were conducted to study the role of bedrock groundwater and subsurface flow in the rainfall–runoff process in a small headwater catchment in Shiranui, Kumamoto prefecture, south‐west Japan. The catchment bedrock consists of a strongly weathered, fractured andesite layer and a relatively fresh continuous layer. Major chemical constituents and stable isotopic ratios of δ¹⁸O and δD were analysed for spring water, rainwater, soil water and bedrock groundwater. Temporal and spatial variation in SiO₂ showed that stream flow under the base flow condition was maintained by bedrock groundwater. Time series of three components of the rainstorm hydrograph (rainwater, soil water and bedrock groundwater) separated by end member mixing analysis showed that each component fluctuated during rainstorm, and their patterns and magnitudes differed between events. During a typical mid‐magnitude storm event, a delayed secondary runoff peak with 1·0 l s⁻¹ was caused by increase in the bedrock groundwater component, whereas during a large rainstorm event the bedrock groundwater component increased to ≈ 2·5 l s⁻¹. This research shows that the contribution of bedrock groundwater and soil water depends strongly on the location of the groundwater table, i.e. whether or not it rises above the soil–bedrock interface. Copyright © 2010 John Wiley & Sons, Ltd.     

Five‐Year Soil Respiration Reflected Soil Quality Evolution in Different Forest and Grassland Vegetation Types in the Eastern Loess Plateau of China

Soil CO₂ efflux in forest and grassland over 5 years from 2005 to 2009 in a semiarid mountain area of the Loess plateau, China, was measured. The aim was to compare the soil respiration and its annual and inter‐annual responses to the changes in soil temperature and soil water content between the two vegetation types for observing soil quality evolution. The differences among the five study years were the annual precipitation (320.1, 370.5, 508.8, 341.6, and 567.4 mm in 2005–2009, respectively) and annual distribution. The results showed that the seasonal change of soil respiration in both vegetation types was similar and controlled by soil temperature and soil water content. The mean soil respiration across 5 years in the forest (3.78 ± 2.68 µmol CO₂ m^?2 s^?1) was less than that in the grassland (4.04 ± 3.06 µmol CO₂ m^?2 s^?1), and the difference was significant. The drought soil in summer depressed soil respiration substantially. The Q₁₀ value across 5‐year measurements was 2.89 and 2.94 for forest and grassland. When soil water content was between wilting point (WP) and field capacity (FC), the Q₁₀ in both types increased with increasing soil water content, and when soil water content dropped to below WP, soil respiration and the Q₁₀ decreased substantially. Although an exponential model was well fitted to predict the annual mean soil respiration for each single year data, it overestimated and underestimated soil respiration, respectively, in drought conditions and after rain for short periods of time during the year. The two‐variable models including temperature and water content variables could be well used to predict soil respiration for both types in all weather conditions. The models proposed are useful for understanding and predicting potential changes in the eastern part of Loess plateau in response to climate change.     

Modelling the effects of land‐use change on water and salt delivery from a catchment affected by dryland salinity in south‐east Australia

A comprehensive framework for the assessment of water and salt balance for large catchments affected by dryland salinity is applied to the Boorowa River catchment (1550 km²), located in south‐eastern Australia. The framework comprised two models, each focusing on a different aspect and operating on a different scale. A quasi‐physical semi‐distributed model CATSALT was used to estimate runoff and salt fluxes from different source areas within the catchment. The effects of land use, climate, topography, soils and geology are included. A groundwater model FLOWTUBE was used to estimate the long‐term effects of land‐use change on groundwater discharge. Unlike conventional salinity studies that focus on groundwater alone, this study makes use of a new approach to explore surface and groundwater interactions with salt stores and the stream. Land‐use change scenarios based on increased perennial pasture and tree‐cover content of the vegetation, aimed at high leakage and saline discharge areas, are investigated. Likely downstream impacts of the reduction in flow and salt export are estimated. The water balance model was able to simulate both the daily observed stream flow and salt load at the catchment outlet for high and low flow conditions satisfactorily. Mean leakage rate of about 23·2 mm year^?1 under current land use for the Boorowa catchment was estimated. The corresponding mean runoff and salt export from the catchment were 89 382 ML year^?1 and 38 938 t year^?1, respectively. Investigation of various land‐use change scenarios indicates that changing annual pastures and cropping areas to perennial pastures is not likely to result in substantial improvement of water quality in the Boorowa River. A land‐use change of about 20% tree‐cover, specifically targeting high recharge and the saline discharge areas, would be needed to decrease stream salinity by 150 µS cm^?1 from its current level. Stream salinity reductions of about 20 µS cm^?1 in the main Lachlan River downstream of the confluence of the Boorowa River is predicted. The FLOWTUBE modelling within the Boorowa River catchment indicated that discharge areas under increased recharge conditions could re‐equilibrate in around 20 years for the catchment, and around 15 years for individual hillslopes. Copyright © 2004 John Wiley & Sons, Ltd.     

A tracer‐based assessment of hydrological pathways at different spatial scales in a mesoscale Scottish catchment

Geochemically based hydrograph separation techniques were used in a preliminary assessment to infer how runoff processes change with landscape characteristics and spatial scale (1–233 km²) within a mesoscale catchment in upland Scotland. A two‐component end‐member mixing analysis (EMMA) used Gran alkalinity as an assumed conservative tracer. Analysis indicated that, at all scales investigated, acidic overland flow and shallow subsurface storm flows from the peaty soils covering the catchment headwaters dominated storm runoff generation. The estimated groundwater contribution to annual runoff varied from 30% in the smallest (ca 1 km²) peat‐dominated headwater catchment with limited groundwater storage, to >60% in larger catchments (>30 km²) with greater coverage of more freely draining soils and more extensive aquifers in alluvium and other drift. This simple approach offers a useful, integrated conceptualization of the hydrological functioning in a mesoscale catchment, which can be tested and further refined by focused modelling and process‐based research. However, even as it stands, the simple conceptualization of system behaviour will have significant utility as a tool for communicating hydrological issues in a range of planning and management decisions. Copyright © 2002 John Wiley & Sons, Ltd.     

Diffusive equilibrium in thin films provides evidence of suppression of hyporheic exchange and large‐scale nitrate transformation in a groundwater‐fed river

The hyporheic zone of riverbed sediments has the potential to attenuate nitrate from upwelling, polluted groundwater. However, the coarse‐scale (5–10 cm) measurement of nitrogen biogeochemistry in the hyporheic zone can often mask fine‐scale (<1 cm) biogeochemical patterns, especially in near‐surface sediments, leading to incomplete or inaccurate representation of the capacity of the hyporheic zone to transform upwelling NO₃^?. In this study, we utilised diffusive equilibrium in thin‐films samplers to capture high resolution (cm‐scale) vertical concentration profiles of NO₃^?, SO₄^2?, Fe and Mn in the upper 15 cm of armoured and permeable riverbed sediments. The goal was to test whether nitrate attenuation was occurring in a sub‐reach characterised by strong vertical (upwelling) water fluxes. The vertical concentration profiles obtained from diffusive equilibrium in thin‐films samplers indicate considerable cm‐scale variability in NO₃^? (4.4 ± 2.9 mg N/L), SO₄^2? (9.9 ± 3.1 mg/l) and dissolved Fe (1.6 ± 2.1 mg/l) and Mn (0.2 ± 0.2 mg/l). However, the overall trend suggests the absence of substantial net chemical transformations and surface‐subsurface water mixing in the shallow sediments of our sub‐reach under baseflow conditions. The significance of this is that upwelling NO₃^?‐rich groundwater does not appear to be attenuated in the riverbed sediments at <15 cm depth as might occur where hyporheic exchange flows deliver organic matter to the sediments for metabolic processes. It would appear that the chemical patterns observed in the shallow sediments of our sub‐reach are not controlled exclusively by redox processes and/or hyporheic exchange flows. Deeper‐seated groundwater fluxes and hydro‐stratigraphy may be additional important drivers of chemical patterns in the shallow sediments of our study sub‐reach. © 2015 The Authors. Hydrological Processes Published by John Wiley & Sons Ltd.     

Groundwater isoscapes in a montane headwater catchment show dominance of well‐mixed storage

We conducted an integrated groundwater–surface water monitoring programme in a 3.2‐km² experimental catchment in the Scottish Highlands by sampling all springs, seepages, and wells in six, spatially extensive synoptic surveys over a 2‐year period. The catchment has been glaciated, with steep hillslopes and a flat valley bottom. There is around 70% glacial drift cover in lower areas. The solid geology, which outcrops at higher elevations, is granite and metamorphic schist. The springs and seepages generally occur at the contact between the solid geology and drift or at breaks of slopes in the valley bottom. Samples were analysed for stable isotopes, Gran alkalinity and electrical conductivity. Despite the surveys encompassing markedly different antecedent conditions, the isotopic composition of groundwater at each location exhibited limited temporal variability, resulting in a remarkable persistence of spatial patterns indicating well‐mixed shallow, groundwater stores. Moreover, line‐conditioned excess values derived from the isotope data indicated no evidence of fractionation affecting the groundwater, which suggests that most recharge occurs in winter. The alkalinity and electrical conductivity of groundwater reflected geological differences in the catchment, being highest where more weatherable calcareous rocks outcrop at higher altitudes in the catchment. Springs draining these areas also had the most variable isotope composition, which indicated that they have shorter residence times than the drift covered part of the catchment. The study showed that even in geologically heterogeneous upland catchments, groundwater can be characterized by a consistent isotopic composition, reflecting rapid mixing in the recharge zone. Our work, thus, emphasizes the critical role of groundwater in upland catchments and provides tracer data that can help constrain quantitative groundwater models.     

Storage,properties and seasonal variations in fine‐grained bed sediment within the main channel and headwaters of the River Sanginjoki,Finland

Lowland catchments in Finland are intensively managed, promoting erosion and sedimentation that negatively affects aquatic environments. This study quantified fine‐grained bed sediment in the main channel and upstream headwaters of the River Sanginjoki (399.93 km²) catchment, Northern Finland, using remobilization sediment sampling during the ice‐free period (May 2010–December 2011). Average bed sediment storage in river was 1332 g m^?2. Storage and seasonal variations were greater in small headwater areas (total bed sediment storage mean 1527 g m^?2, range 122–6700 g m^?2 at individual sites; storage of organic sediment: mean 414 g m^?2, range 27–3159 g m^?2) than in the main channel (total bed sediment storage: mean 1137 g m^?2, range 61–4945 g m^?2); storage of organic sediment: mean 329 g m^?2, range 13–1938 g m^?2). Average reach‐specific bed sediment storage increased from downstream to upstream tributaries. In main channel reaches, mean specific storage was 8.73 t km^?1, and mean specific storage of organic sediment 2.45 t km^?1, whereas in tributaries, it was 126.94 and 34.05 t km^?1, respectively. Total fine‐grained bed sediment storage averaged 563 t in the main channel and 6831 t in the catchment. The proportion of mean organic matter at individual sites was 15–47% and organic carbon 4–455 g C m^?2, with both being highest in small headwater tributaries. Main channel bed sediment storage comprised 52% of mean annual suspended sediment flux and stored organic carbon comprised 7% of mean annual total organic carbon load. This indicates the importance of small headwater brooks for temporary within‐catchment storage of bed sediment and organic carbon and the significance of fine‐grained sediment stored in channels for the suspended sediment budget of boreal lowland rivers. Copyright © 2013 John Wiley & Sons, Ltd.     

River–aquifer interactions in a semi‐arid environment stressed by groundwater abstraction

Rivers and aquifers are, in many cases, a connected resource and as such the interactions between them need to be understood and quantified for the resource to be managed appropriately. The objective of this paper is to advance the understanding of river–aquifer interactions processes in semi‐arid environments stressed by groundwater abstraction. This is performed using data from a specific catchment where records of precipitation, evapotranspiration, river flow, groundwater levels and groundwater abstraction are analysed using basic statistics, hydrograph analysis and a simple mathematical model to determine the processes causing the spatial and temporal changes in river–aquifer interactions. This combined approach provides a novel but simple methodology to analyse river–aquifer interactions, which can be applied to catchments worldwide. The analysis revealed that the groundwater levels have declined (~ 3 m) since the onset of groundwater abstraction. The decline is predominantly due to the abstraction rather than climatic changes (r = 0.84 for the relationship between groundwater abstraction and groundwater levels; r = 0.92 for the relationship between decline in groundwater levels and magnitude of seasonal drawdown). It is then demonstrated that, since the onset of abstraction, the river has changed from being gaining to losing during low‐flow periods, defined as periods with flow less than 0.5, 1.0 or 1.5 GL/day (1 GL/day = 1 × 10⁶ m³/day). If defined as < 1.0 GL/day, low‐flow periods constitute approximately 65% of the river flows; the periods where the river is losing at low‐flow conditions are thus significant. Importantly, there was a significant delay (> 10 years) between the onset of groundwater abstraction and the changeover from gaining to losing conditions. Finally, a relationship between the groundwater gradient towards the river and the river flow at low‐flow is demonstrated. The results have important implications for water management as well as water ecology and quality. Copyright © 2012 John Wiley & Sons, Ltd.     

Mining lakes as groundwater‐dominated hydrological systems: assessment of the water balance of Mining Lake Plessa 117 (Lusatia,Germany) using stable isotopes

In the present study, the stable isotopes δ¹⁸O and δ²H were used for assessment of the water balance in a heterogeneously structured catchment area in the Lusatian Lignite Mining District, in particular, for estimation of the annual groundwater inflow and outflow (I_GW and O_GW) of Mining Lake Plessa 117. The application of stable isotopes was possible since the water exchange in the catchment area had reached steady‐state conditions after the abandonment of mining activities in 1968 and the filling of the voids and aquifers by re‐rising groundwater in the years thereafter. Diverging slopes of the Evaporation Line and the Global Meteoric Water Line manifested as evaporation from the lake catchment area. The calculated isotope water balance was compared with the commonly used surface water balance, which is unable to differentiate between I_GW and O_GW, and with a local groundwater model. The groundwater model calculated an I_GW of about 811 000 m³ yr^?1 and an O_GW close to zero, whereas the isotope water balance showed fluxes of about 914 000 and 140 000 m³ yr^?1, respectively. Considering the contribution of the groundwater inflow to the total annual input into the lake (ΔI_T) and the mean residence time (τ), where the groundwater model and the isotope water balance calculated 42 and 47% for ΔI_T and 4·3 and 3·9 years for τ, respectively, it was shown that both water balance calculation methods led to comparable results despite the differences in I_GW and O_GW. Copyright © 2008 John Wiley & Sons, Ltd.     

Identification of groundwater recharge sources and processes in a heterogeneous alluvial aquifer: results from multi‐level monitoring of hydrochemistry and environmental isotopes in a riverside agricultural area in Korea

We evaluated sources and pathways of groundwater recharge for a heterogeneous alluvial aquifer beneath an agricultural field, based on multi‐level monitoring of hydrochemistry and environmental isotopes of a riverside groundwater system at Buyeo, Korea. Two distinct groundwater zones were identified with depth: (1) a shallow oxic groundwater zone, characterized by elevated concentrations of NO₃^? and (2) a deeper (>10–14 m from the ground surface) sub‐oxic groundwater zone with high concentrations of dissolved Fe, silica, and HCO₃^?, but little nitrate. The change of redox zones occurred at a depth where the aquifer sediments change from an upper sandy stratum to a silty stratum with mud caps. The δ¹⁸O and δ²H values of groundwater were also different between the two zones. Hydrochemical and δ¹⁸O? δ²H data of oxic groundwater are similar to those of soil water. This illustrates that recharge of oxic groundwater mainly occurs through direct infiltration of rain and irrigation water in the sandy soil area where vegetable cropping with abundant fertilizer use is predominant. Oxic groundwater is therefore severely contaminated by agrochemical pollutants such as nitrate. In contrast, deeper sub‐oxic groundwater contains only small amounts of dissolved oxygen (DO) and NO₃^?. The ³H contents and elevated silica concentrations in sub‐oxic groundwater indicate a somewhat longer mean residence time of groundwater within this part of the aquifer. Sub‐oxic groundwater was also characterized by higher δ¹⁸O and δ²H values and lower d‐excess values, indicating significant evaporation during recharge. We suggest that recharge of sub‐oxic groundwater occurs in the areas of paddy rice fields where standing irrigation and rain water are affected by strong evaporation, and that reducing conditions develop during subsequent sub‐surface infiltration. This study illustrates the existence of two groundwater bodies with different recharge processes within an alluvial aquifer. Copyright © 2009 John Wiley & Sons, Ltd.     

Prediction of groundwater‐induced flooding in a chalk aquifer for future climate change scenarios

Current climate change models for the southeast UK predict changing rainfall patterns, with increased incidence of extreme events. The chalk aquifer in the UK and northern France is susceptible to groundwater‐induced flooding under such conditions. In this methodological study we apply a frequency domain analysis approach to the chalk aquifer to derive a transfer function between effective rainfall and groundwater level from 7 years of monitoring data from the North Heath Barn site, near Brighton. The derived transfer function was calibrated and validated against monitoring data and then used to predict groundwater level for rainfall models for high, medium and low emission scenarios from the UKCP09 database. The derived transfer function is most closely comparable to the linear aquifer model, despite evidence for both matrix and fracture or karst water flow in the chalk, with transmissivity and unconfined storativity at the catchment scale of 1548 m² day^?1 and 1.6 × 10^?2. The application of the transfer function to UKCP09 rainfall data suggests that groundwater‐induced flooding may be about four times more frequent by 2040–2069 compared with 1961–1990 and seven times more frequent by 2070–2099. The model data also suggest an increase in the duration of groundwater minima relative to the reference period. Compared to deterministic modelling which requires detailed knowledge of aquifer heterogeneity and processes, the transfer function approach, although with limitations, is simpler, incorporating these factors into the analysis through frequency and phase coefficients, and thus may have the potential for groundwater risk assessment in other areas. Copyright © 2015 John Wiley & Sons, Ltd.     

Multi‐decadal water table manipulation alters peatland hydraulic structure and moisture retention

A peatland complex disturbed by berm construction in the 1950s was used to examine the long‐term impact of water table (WT) manipulation on peatland hydraulic properties and moisture retention at three adjacent sites with increasing depth to WT (WET, INTermediate reference and DRY). Saturated hydraulic conductivity (K_s) was found to decrease with depth by several orders of magnitude over a depth of 1–1.5 m at all sites. The depth dependence of WT response to rainfall was similar across sites: WT response increased from 1 : 1 at the surface, to 5 : 1 at 50 cm depth. While surface specific yield (S_y) values were similar across all sites, it decreased with depth at a rate of 0.014 cm^?1 in hollows and 0.007 cm^?1 in hummocks. Bulk density (ρ_b) exhibited similar depth‐dependent trends as S_y and explains a high amount of variance (r² > 0.69) in moisture retention across a range of pore water pressures (?15 to ?500 cm H₂O). Because of higher ρ_b, hollow peat had greater moisture retention, where site effects were minimal. However, the estimated residual water content for surface Sphagnum samples, while on average lower in hummocks (0.082 m³ m^?3) versus hollows (0.087 m³ m^?3), increased from WET (0.058 m³ m^?3) to INT (0.088 m³ m^?3) to DRY (0.108 m³ m^?3) which has important implications for moisture stress under conditions of persistent WT drawdown. Given the potential importance of microtopographic succession for altering peatland hydraulic structure, our findings point to the need for a better understanding of what controls the relative height and proportional coverage of hummocks in relation to long‐term disturbance‐response dynamics. Copyright © 2014 John Wiley & Sons, Ltd.     

Landscape influence on small‐scale water temperature variations in a moorland catchment

We monitored temperatures in stream water, groundwater and riparian wetland surface water over 18 months in a 3.2‐km² moorland catchment in the Scottish Highlands. The stream occupies a glaciated valley, aligned east–west. It has three main headwater tributaries with a large north facing catchment, a south facing catchment and the smallest east facing headwater. The lower catchment sampling locations begin after the convalescence of all three headwaters. Much of the stream network is fringed by riparian peatlands. Stream temperatures are mainly regulated by energy exchanges at the air–water interface. However, they are also influenced by inflows from the saturated riparian zone, where surface water source areas are strongly connected with the stream network. Consequently, the spatial distribution of stream temperatures exhibits limited variability. Nevertheless, there are significant summer differences between the headwaters, despite their close proximity to each other. This is consistent with aspect (and incident radiation), given the south and east facing headwaters having higher temperatures. The largest, north‐facing sub‐catchment shows lower summer diurnal temperature variability, suggesting that lower radiation inputs dampen temperature extremes. Whilst stream water temperature regimes in the lower catchment exhibit little change along a 1‐km reach, they are similar to those in the largest headwater; probably reflecting size and comparable catchment aspect and hydrological flow paths. Our results suggest that different parts of the channel network and its connected wetlands have contrasting sensitivity to higher summer temperatures. This may be important in land management strategies designed to mitigate the impacts of projected climatic warming. Copyright © 2015 John Wiley & Sons, Ltd.     

Total waterborne carbon export and DOC composition from ten nested subarctic peatland catchments—importance of peatland cover,groundwater influence,and inter‐annual variability of precipitation patterns

Waterborne carbon (C) export from terrestrial ecosystems is a potentially important flux for the net catchment C balance and links the biogeochemical C cycling of terrestrial ecosystems to their downstream aquatic ecosystems. We have monitored hydrology and stream chemistry over 3 years in ten nested catchments (0.6–15.1 km²) with variable peatland cover (0%–22%) and groundwater influence in subarctic Sweden. Total waterborne C export, including dissolved and particulate organic carbon (DOC and POC) and dissolved inorganic carbon (DIC), ranged between 2.8 and 7.3 g m^–2 year^–1, representing ~10%–30% of catchment net ecosystem exchange of CO₂. Several characteristics of catchment waterborne C export were affected by interacting effects of peatland cover and groundwater influence, including magnitude and timing, partitioning into DOC, POC, and DIC and chemical composition of the exported DOC. Waterborne C export was greater during the wetter years, equivalent to an average change in export of ~2 g m^–2 year^–1 per 100 mm of precipitation. Wetter years led to a greater relative increase in DIC export than DOC export due to an inferred relative shift in dominance from shallow organic flow pathways to groundwater sources. Indices of DOC composition (SUVA₂₅₄ and a₂₅₀/a₃₆₅) indicated that DOC aromaticity and average molecular weight increased with catchment peatland cover and decreased with increased groundwater influence. Our results provide examples on how waterborne C export and DOC composition might be affected by climate change. Copyright © 2012 John Wiley & Sons, Ltd.     

Transfer of carbon dioxide and methane through the soil‐water‐atmosphere system at Mer Bleue peatland,Canada

Surface waters associated with peatlands, supersaturated with CO₂ and CH₄ with respect to the atmosphere, act as important pathways linking a large and potentially unstable global repository of C to the atmosphere. Understanding the drivers and mechanisms which control C release from peatland systems to the atmosphere will contribute to better management and modelling of terrestrial C pools. We used non‐dispersive infra‐red (NDIR) CO₂ sensors to continuously measure gas concentrations in a beaver pond at Mer Bleue peatland (Canada); measurements were made between July and August 2007. Concentrations of CO₂ in the surface water (10 cm) reached 13 mg C l^?1 (epCO₂ 72), and 26 mg C l^?1 (epCO₂ 133) at depth (60 cm). The study also showed large diurnal fluctuations in dissolved CO₂ which ranged in amplitude from ～1·6 mg C l^?1 at 10 cm to ～0·2 mg C l^?1 at 60 cm depth. CH₄ concentration and supersaturation (epCH₄) measured using headspace analysis averaged 1·47 mg C l^?1 and 3252, respectively; diurnal cycling was also evident in CH₄ concentrations. Mean estimated evasion rates of CO₂ and CH₄ over the summer period were 44·92 ± 7·86 and 0·44 ± 0·25 µg C m^?2s^?1, respectively. Open water at Mer Bleue is a significant summer hotspot for greenhouse gas emissions within the catchment. Our results suggest that CO₂ concentrations during the summer in beaver ponds at Mer Bleue are strongly influenced by biological processes within the water column involving aquatic plants and algae (in situ photosynthesis and respiration). In terms of carbon cycling, soil‐stream connectivity at this time of year is therefore relatively weak. Copyright © 2008 John Wiley & Sons, Ltd.     

Estimation of submarine groundwater discharge in the Il‐Gwang watershed using water budget analysis and 222Rn mass balance

Submarine groundwater discharges (SGD) were investigated in a marine watershed in south‐eastern Korea using water budget analysis and a ²²²Rn mass balance model. Multi‐layered TOPMODEL added hydrological assumption was used to estimate groundwater components in the water budget analysis. Field observations of soil moisture, rainfall, runoff and groundwater fluctuations were used for calibration and validation of the hydrologic model. Based on observed hydrological data and terrain analyses, parameters for the hydrologic model were delineated and used to describe several hydrologic responses in the watershed. SGD estimations by ²²²Rn mass balance method were also performed at Il‐Gwang bay in July, 2010, and May, June, July and Nov. 2011. The estimated groundwater through hydrologic modeling and water balance analysis was 1.3x10⁶ m³/year, which rapidly increased during typhoon season due to heavy rainfall and permeable geologic structure. The estimated groundwater was approximately 3.7–27.1% of SGD as evaluated by ²²²Rn mass balance method ranges 3.44 and 17.45 m³m^?2year^?1. Even though SGD is predominantly influenced by tide fluctuation, the head gradient (difference) from hydrologic processes associated with heavy rainfalls can also have extra significant influences. Comprehensive understanding of SGD evaluation can be improved through a simultaneous application of both these approaches. Copyright © 2013 John Wiley & Sons, Ltd.