Vertical profiling of SO2 and SO above Venus’ clouds by SPICAV/SOIR solar occultations

New measurements of sulfur dioxide (SO₂) and monoxide (SO) in the atmosphere of Venus by SPICAV/SOIR instrument onboard Venus Express orbiter provide ample statistics to study the behavior of these gases above Venus’ clouds. The instrument (a set of three spectrometers) is capable to sound atmospheric structure above the clouds in several observation modes (nadir, solar and stellar occultations) either in the UV or in the near IR spectral ranges. We present the results from solar occultations in the absorption ranges of SO₂ (190–230 nm, and at 4 μm) and SO (190–230 nm). The dioxide was detected by the SOIR spectrometer at the altitudes of 65–80 km in the IR and by the SPICAV spectrometer at 85–105 km in the UV. The monoxide’s absorption was measured only by SPICAV at 85–105 km. We analyzed 39 sessions of solar occultation, where boresights of both spectrometers are oriented identically, to provide complete vertical profiling of SO₂ of the Venus’ mesosphere (65–105 km). Here we report the first firm detection and measurements of two SO₂ layers. In the lower layer SO₂ mixing ratio is within 0.02–0.5 ppmv. The upper layer, also conceivable from microwave measurements by Sandor et al. (Sandor, B.J., Todd Clancy, R., Moriarty-Schieven, G., Mills, F.P. [2010]. Icarus 208, 49–60) is characterized by SO₂ increasing with the altitude from 0.05 to 2 ppmv, and the [SO₂]/[SO] ratio varying from 1 to 5. The presence of the high-altitude SO_x species could be explained by H₂SO₄ photodissociation under somewhat warmer temperature conditions in Venus mesosphere. At 90–100 km the content of the sulfur dioxide correlates with temperature increasing from 0.1 ppmv at 165–170 K to 0.5–1 ppmv at 190–192 K. It supports the hypothesis of SO₂ production by the evaporation of H₂SO₄ from droplets and its subsequent photolysis at around 100 km.     

Venus Monitoring Camera for Venus Express

The Venus Express mission will focus on a global investigation of the Venus atmosphere and plasma environment, while additionally measuring some surface properties from orbit. The instruments PFS and SPICAV inherited from the Mars Express mission and VIRTIS from Rosetta form a powerful spectrometric and spectro-imaging payload suite. Venus Monitoring Camera (VMC)—a miniature wide-angle camera with 17.5° field of view—was specifically designed and built to complement these experiments and provide imaging context for the whole mission. VMC will take images of Venus in four narrow band filters (365, 513, 965, and 1000 nm) all sharing one CCD. Spatial resolution on the cloud tops will range from 0.2 km/px at pericentre to 45 km/px at apocentre when the full Venus disc will be in the field of view. VMC will fulfill the following science goals: (1) study of the distribution and nature of the unknown UV absorber; (2) determination of the wind field at the cloud tops (70 km) by tracking the UV features; (3) thermal mapping of the surface in the 1 μm transparency “window” on the night side; (4) determination of the global wind field in the main cloud deck (50 km) by tracking near-IR features; (5) study of the lapse rate and H₂O content in the lower 6–10 km; (6) mapping O₂ night-glow and its variability.     

Atomic oxygen on the Venus nightside: Global distribution deduced from airglow mapping

The Visible and Infra-Red Thermal Imaging Spectrometer (VIRTIS) instrument on board the Venus Express spacecraft has measured the O₂(a¹Δ) nightglow distribution at 1.27 μm in the Venus mesosphere for more than two years. Nadir observations have been used to create a statistical map of the emission on Venus nightside. It appears that the statistical 1.6 MR maximum of the emission is located around the antisolar point. Limb observations provide information on the altitude and on the shape of the emission layer. We combine nadir observations essentially covering the southern hemisphere, corrected for the thermal emission of the lower atmosphere, with limb profiles of the northern hemisphere to generate a global map of the Venus nightside emission at 1.27 μm. Given all the O₂(a¹Δ) intensity profiles, O₂(a¹Δ) and O density profiles have been calculated and three-dimensional maps of metastable molecular and atomic oxygen densities have been generated. This global O density nightside distribution improves that available from the VTS3 model, which was based on measurements made above 145 km. The O₂(a¹Δ) hemispheric average density is 2.1 × 10⁹ cm^?3, with a maximum value of 6.5 × 10⁹ cm^?3 at 99.2 km. The O density profiles have been derived from the nightglow data using CO₂ profiles from the empirical VTS3 model or from SPICAV stellar occultations. The O hemispheric average density is 1.9 × 10¹¹ cm^?3 in both cases, with a mean altitude of the peak located at 106.1 km and 103.4 km, respectively. These results tend to confirm the modeled values of 2.8 × 10¹¹ cm^?3 at 104 km and 2.0 × 10¹¹ cm^?3 at 110 km obtained by Brecht et al. [Brecht, A., Bougher, S.W., Gérard, J.-C., Parkinson, C.D., Rafkin, S., Foster, B., 2011a. J. Geophys. Res., in press] and Krasnopolsky [Krasnopolsky, V.A., 2010. Icarus 207, 17–27], respectively. Comparing the oxygen density map derived from the O₂(a¹Δ) nightglow observations, it appears that the morphology is very different and that the densities obtained in this study are about three times higher than those predicted by the VTS3 model.     

Scientific goals for the observation of Venus by VIRTIS on ESA/Venus express mission

The Visible and Infrared Thermal Imaging Spectrometer (VIRTIS) on board the ESA/Venus Express mission has technical specifications well suited for many science objectives of Venus exploration. VIRTIS will both comprehensively explore a plethora of atmospheric properties and processes and map optical properties of the surface through its three channels, VIRTIS-M-vis (imaging spectrometer in the 0.3–1 μm range), VIRTIS-M-IR (imaging spectrometer in the 1–5 μm range) and VIRTIS-H (aperture high-resolution spectrometer in the 2–5 μm range). The atmospheric composition below the clouds will be repeatedly measured in the night side infrared windows over a wide range of latitudes and longitudes, thereby providing information on Venus's chemical cycles. In particular, CO, H₂O, OCS and SO₂ can be studied. The cloud structure will be repeatedly mapped from the brightness contrasts in the near-infrared night side windows, providing new insights into Venusian meteorology. The global circulation and local dynamics of Venus will be extensively studied from infrared and visible spectral images. The thermal structure above the clouds will be retrieved in the night side using the 4.3 μm fundamental band of CO₂. The surface of Venus is detectable in the short-wave infrared windows on the night side at 1.01, 1.10 and 1.18 μm, providing constraints on surface properties and the extent of active volcanism. Many more tentative studies are also possible, such as lightning detection, the composition of volcanic emissions, and mesospheric wave propagation.     

Ground-based near-infrared observations of water vapour in the Venus troposphere

We present a study of water vapour in the Venus troposphere obtained by modelling specific water vapour absorption bands within the 1.18 μm window. We compare the results with the normal technique of obtaining the abundance by matching the peak of the 1.18 μm window. Ground-based infrared imaging spectroscopy of the night side of Venus was obtained with the Anglo-Australian Telescope and IRIS2 instrument with a spectral resolving power of R ～ 2400. The spectra have been fitted with modelled spectra simulated using the radiative transfer model VSTAR. We find a best fit abundance of 31 ppmv (?6 +9 ppmv), which is in agreement with recent results by Bézard et al. (Bézard, B., Fedorova, A., Bertaux, J.-L., Rodin, A., Korablev, O. [2011]. Icarus, 216, 173–183) using VEX/SPICAV (R ～ 1700) and contrary to prior results by Bézard et al. (Bézard, B., de Bergh, C., Crisp, D., Maillard, J.P. [1990]. Nature, 345, 508–511) of 44 ppmv (±9 ppmv) using VEX/VIRTIS-M (R ～ 200) data analyses. Comparison studies are made between water vapour abundances determined from the peak of the 1.18 μm window and abundances determined from different water vapour absorption features within the near infrared window. We find that water vapour abundances determined over the peak of the 1. 18 μm window results in plots with less scatter than those of the individual water vapour features and that analyses conducted over some individual water vapour features are more sensitive to variation in water vapour than those over the peak of the 1. 18 μm window. No evidence for horizontal spatial variations across the night side of the disk are found within the limits of our data with the exception of a possible small decrease in water vapour from the equator to the north pole. We present spectral ratios that show water vapour absorption from within the lowest 4 km of the Venus atmosphere only, and discuss the possible existence of a decreasing water vapour concentration towards the surface.     

The solar wind interaction with Venus through the eyes of the Pioneer Venus Orbiter

Venus has no internal magnetic dynamo and thus its ionosphere and hot oxygen exosphere dominate the interaction with the solar wind. The solar wind at 0.72 AU has a dynamic pressure that ranges from 4.5 nPa (at solar max) to 6.6 nPa (at solar min), and its flow past the planet produces a shock of typical magnetosonic Mach number 5 at the subsolar point. At solar maximum the pressure in the ionospheric plasma is sufficient to hold off the solar wind at an altitude of 400 km above the surface at the subsolar point, and 1000 km above the terminators. The deflection of the solar wind occurs through the formation of a magnetic barrier on the inner edge of the magnetosheath, or shocked solar wind. Under typical solar wind conditions the time scale for diffusion of the magnetic field into the ionosphere is so long that the ionosphere remains field free and the barrier deflects almost all the incoming solar wind. Any neutral atoms of the hot oxygen exosphere that reach the altitude of the magnetosheath are accelerated by the electric field of the flowing magnetized plasma and swept along cycloidal paths in the antisolar direction. This pickup process, while important for the loss of the Venus atmosphere, plays a minor role in the deceleration and deflection of the solar wind. Like at magnetized planets, the Venus shock and magnetosheath generate hot electrons and ions that flow back along magnetic field lines into the solar wind to form a foreshock. A magnetic tail is created by the magnetic flux that is slowed in the interaction and becomes mass-loaded with thermal ions.The structure of the ionosphere is very much dependent on solar activity and the dynamic pressure of the solar wind. At solar maximum under typical solar wind conditions, the ionosphere is unmagnetized except for the presence of thin magnetic flux ropes. The ionospheric plasma flows freely to the nightside forming a well-developed night ionosphere. When the solar wind pressure dominates over the ionospheric pressure the ionosphere becomes completely magnetized, the flow to the nightside diminishes, and the night ionosphere weakens. Even at solar maximum the night ionosphere has a very irregular density structure. The electromagnetic environment of Venus has not been well surveyed. At ELF and VLF frequencies there is noise generated in the foreshock and shock. At low altitude in the night ionosphere noise, presumably generated by lightning, can be detected. This paper reviews the plasma environment at Venus and the physics of the solar wind interaction on the threshold of a new series of Venus exploration missions.     

New wind measurements in Venus’ lower mesosphere from visible spectroscopy

The dynamics of Venus’ mesosphere (70–110 km) is characterized by the superposition of two different wind regimes: (1) Venus’ retrograde superrotation; (2) a sub-solar to anti-solar (SS–AS) flow pattern, driven by solar EUV heating on the sunlit hemisphere. Here, we report on new ground-based velocity measurements in the lower part of the mesosphere. We took advantage of two essentially symmetric Venus elongations in 2001 and 2002 to perform high-resolution Doppler spectroscopy (R=120,000) in ¹²C¹⁶O₂ visible lines of the 5ν₃ band and in a few solar Fraunhofer lines near 8700 Å. These measurements, mapped over several points on Venus’ illuminated hemisphere, probe the region of cloud tops. More precisely, the solar Fraunhofer lines sample levels a few kilometers below the UV features (i.e. near ∼67 km), while the CO₂ lines probe an altitude higher by about 7 km. The wind field over Venus’ disk is retrieved with an rms uncertainty of 15–25 m s⁻¹ on individual measurements. Kinematical fit to a one- or two-component circulation model indicates the dominance of the zonal retrograde flow with a mean equatorial velocity of ∼75 m s⁻¹, exhibiting very strong day-to-day variations (±65 m s⁻¹). Results are very consistent for the two kinds of lines, suggesting a negligible vertical wind shear over 67–74 km. The SS–AS flow is not detected in single-day observations, but combining the results from all data suggests that this component may invade the lower mesosphere with a ∼40 m s⁻¹ velocity.     

The abundance and vertical distribution of the unknown ultraviolet absorber in the venusian atmosphere from analysis of Venus Monitoring Camera images

Observations of Venus using the ultraviolet filter of the Venus Monitoring Camera (VMC) on ESA’s Venus Express Spacecraft (VEX) provide the best opportunity for study of the spatial and temporal distribution of the venusian unknown ultraviolet absorber since the Pioneer Venus (PV) mission. We compare the results of two sets of 125 radiative transfer models of the upper atmosphere of Venus to each pixel in a subset of VMC UV channel images. We use a quantitative best fit criterion based upon the notion that the distribution of the unknown absorber should be independent of the illumination and observing geometry. We use the product of the cosines of the incidence and emission angles and search for absorber distributions that are uncorrelated with this geometric parameter, finding that two models can describe the vertical distribution of the unknown absorber. One model is a well-mixed vertical profile above a pressure level of roughly 120 mb (～63 km). This is consistent with the altitude of photochemical formation of sulfuric acid. The second model describes it as a thin layer of pure UV absorber at a pressure level roughly around 24 mb (～71 km) and this altitude is consistent with the top of upper cloud deck. We find that the average abundance of unknown absorber in the equatorial region is 0.21 ± 0.04 optical depth and it decreases in the polar region to 0.08 ± 0.05 optical depth at 365 nm.     

Latitudinal distribution of HDO abundance above Venus’ clouds by ground-based 2.3 μm spectroscopy

The abundance of HDO above the clouds in the dayside atmosphere of Venus was measured by ground-based 2.3 μm spectroscopy over 4 days. This is the first HDO observation above the clouds in this wavelength region corresponding to a new height region. The latitudinal distributions found show no clearly defined structure. The disk-averaged mixing ratio is 0.22 ± 0.03 ppm for a representative height region of 62–67 km. This is consistent with measurements found in previous studies. Based on previous H₂O measurements, the HDO/H₂O ratio is found to be 140 ± 20 times larger than the telluric ratio. This lies between the ratios of 120 ± 40 and 240 ± 25, respectively, reported for the 30–40 km region by ground-based nightside spectroscopy and for the 80–100 km region by solar occultation measurement on board the Venus Express.     

Observation of DCl and upper limit to NH3 on Venus

To search for DCl in the Venus atmosphere, a spectrum near the D³⁵Cl (1–0) R4 line at 2141.54 cm^?1 was observed using the CSHELL spectrograph at NASA IRTF. Least square fitting to the spectrum by a synthetic spectrum results in a DCl mixing ratio of 17.8 ± 6.8 ppb. Comparing to the HCl abundance of 400 ± 30 ppb (Krasnopolsky [2010a] Icarus, 208, 314–322), the DCl/HCl ratio is equal to 280 ± 110 times the terrestrial D/H = 1.56 × 10^?4. This ratio is similar to that of HDO/H₂O = 240 ± 25 times the terrestrial HDO/H₂O from the VEX/SOIR occultations at 70–110 km. Photochemistry in the Venus mesosphere converts H from HCl to that in H₂O with a rate of 1.9 × 10⁹ cm^?2 s^?1 (Krasnopolsky [2012] Icarus, 218, 230–246). The conversion involves photolysis of HCl; therefore, the photochemistry tends to enrich D/H in HCl and deplete in H₂O. Formation of the sulfuric acid clouds may affect HDO/H₂O as well. The enriched HCl moves down by mixing to the lower atmosphere where thermodynamic equilibriums for H₂ and HCl near the surface correspond to D/H = 0.71 and 0.74 times that in H₂O, respectively. Time to establish these equilibriums is estimated at ～3 years and comparable to the mixing time in the lower atmosphere. Therefore, the enriched HCl from the mesosphere gives D back to H₂O near the surface. Comparison of chemical and mixing times favors a constant HDO/H₂O up to ～100 km and DCl/HCl equal to D/H in H₂O times 0.74.Ammonia is an abundant form of nitrogen in the reducing environments. Thermodynamic equilibriums with N₂ and NO near the surface of Venus give its mixing ratio of 10^?14 and 6 × 10^?7, respectively. A spectrum of Venus near the NH₃ line at 4481.11 cm^?1 was observed at NASA IRTF and resulted in a two-sigma upper limit of 6 ppb for NH₃ above the Venus clouds. This is an improvement of the previous upper limit by a factor of 5. If ammonia exists at the ppb level or less in the lower atmosphere, it quickly dissociates in the mesosphere and weakly affects its photochemistry.     

First ever in situ observations of Venus’ polar upper atmosphere density using the tracking data of the Venus Express Atmospheric Drag Experiment (VExADE)

On its highly elliptical 24 h orbit around Venus, the Venus Express (VEX) spacecraft briefly reaches a periapsis altitude of nominally 250 km. Recently, however, dedicated and intense radio tracking campaigns have taken place in August 2008, October 2009, February and April 2010, for which the periapsis altitude was lowered to the 186–176 km altitude range in order to be able to probe the upper atmosphere of Venus above the North Pole for the first time ever in situ. As the spacecraft experiences atmospheric drag, its trajectory is measurably perturbed during the periapsis pass, allowing us to infer total atmospheric mass density at the periapsis altitude. A Precise Orbit Determination (POD) of the VEX motion is performed through an iterative least-squares fitting process to the Doppler tracking data, acquired by the VEX radioscience experiment (VeRa). The drag acceleration is modelled using an initial atmospheric density model (VTS3 model, Hedin, A.E., Niemann, H.B., Kasprzak, W.T., Seiff, A. [1983]. J. Geophys. Res. 88, 73–83). A scale factor of the drag acceleration is estimated for each periapsis pass, which scales Hedin’s density model in order to best fit the radio tracking data. Reliable density scale factors have been obtained for 10 passes mainly from the second (October 2009) and third (April 2010) VExADE campaigns, which indicate a lower density by a factor of about 1.8 than Hedin’s model predicts. These first ever in situ polar density measurements at solar minimum have allowed us to construct a diffusive equilibrium density model for Venus’ thermosphere, constrained in the lower thermosphere primarily by SPICAV-SOIR measurements and above 175 km by the VExADE drag measurements (Müller-Wodarg et al., in preparation). The preliminary results of the VExADE campaigns show that it is possible to obtain with the POD technique reliable estimates of Venus’ upper atmosphere densities at an altitude of around 175 km. Future VExADE campaigns will benefit from the planned further lowering of VEX pericenter altitude to below 170 km.     

Dynamical properties of the Venus mesosphere from the radio-occultation experiment VeRa onboard Venus Express

The dynamics of Venus’ mesosphere (60–100 km altitude) was investigated using data acquired by the radio-occultation experiment VeRa on board Venus Express. VeRa provides vertical profiles of density, temperature and pressure between 40 and 90 km of altitude with a vertical resolution of few hundred meters of both the Northern and Southern hemisphere. Pressure and temperature vertical profiles were used to derive zonal winds by applying an approximation of the Navier–Stokes equation, the cyclostrophic balance, which applies well on slowly rotating planets with fast zonal winds, like Venus and Titan. The main features of the retrieved winds are a midlatitude jet with a maximum speed up to 140 ± 15 m s^?1 which extends between 20°S and 50°S latitude at 70 km altitude and a decrease of wind speed with increasing height above the jet. Cyclostrophic winds show satisfactory agreement with the cloud-tracked winds derived from the Venus Monitoring Camera (VMC/VEx) UV images, although a disagreement is observed at the equator and near the pole due to the breakdown of the cyclostrophic approximation. Knowledge of both temperature and wind fields allowed us to study the stability of the atmosphere with respect to convection and turbulence. The Richardson number Ri was evaluated from zonal field of measured temperatures and thermal winds. The atmosphere is characterised by a low value of Richardson number from ～45 km up to ～60 km altitude at all latitudes that corresponds to the lower and middle cloud layer indicating an almost adiabatic atmosphere. A high value of Richardson number was found in the region of the midlatitude jet indicating a highly stable atmosphere. The necessary condition for barotropic instability was verified: it is satisfied on the poleward side of the midlatitude jet, indicating the possible presence of wave instability.     

Water vapor near the cloud tops of Venus from Venus Express/VIRTIS dayside data

Observations of the dayside of Venus performed by the high spectral resolution channel (–H) of the Visible and Infrared Thermal Imaging Spectrometer (VIRTIS) on board the ESA Venus Express mission have been used to measure the altitude of the cloud tops and the water vapor abundance around this level with a spatial resolution ranging from 100 to 10 km. CO₂ and H₂O bands between 2.48 and 2.60 μm are analyzed to determine the cloud top altitude and water vapor abundance near this level. At low latitudes (±40°) mean water vapor abundance is equal to 3 ± 1 ppm and the corresponding cloud top altitude at 2.5 μm is equal to 69.5 ± 2 km. Poleward from middle latitudes the cloud top altitude gradually decreases down to 64 km, while the average H₂O abundance reaches its maximum of 5 ppm at 80° of latitude with a large scatter from 1 to 15 ppm. The calculated mass percentage of the sulfuric acid solution in cloud droplets of mode 2 (～1 μm) particles is in the range 75–83%, being in even more narrow interval of 80–83% in low latitudes. No systematic correlation of the dark UV markings with the cloud top altitude or water vapor has been observed.     

Mineral reaction buffering of Venus’ atmosphere: A thermochemical constraint and implications for Venus-like planets

The equilibrium suggested as a buffer for CO₂ in the Venus atmosphere, CaCO₃ + SiO₂ = CaSiO₃ + CO₂, cannot act as a buffer at the Venus surface/troposphere – the pressure–temperature slope of the equilibrium and that of the atmosphere (dry adiabat with significant greenhouse heating) do not provide buffering capacity (if indeed CaCO₃ were present). Instead, perturbations to T or P(CO₂) can produce catastrophic expansion or collapse of the atmosphere. This instability can be generalized to all devolatilization reactions that produce a radiatively active gas in a planetary atmosphere dominated by such gases, and gives a simple thermochemical criterion for whether a reaction could buffer such an atmosphere. Simple decarbonation reactions fail this criterion, suggesting that the abundance of CO₂ in a CO₂-dominated atmosphere cannot be buffered by chemical reactions with the surface; a similar conclusion holds for the abundance of H₂O in an H₂O-dominated (steam) atmosphere. Buffering of minor gases is more likely; a mineral buffer equilibrium for SO₂ proposed for Venus, FeS₂ + CO₂ = Fe₃O₄ + SO₂ + CO, passes the thermochemical criterion, as does a reaction involving Ca sulfate. These inferences can be generalized to atmospheres in ‘moist’ adiabatic equilibria, and to extrasolar Venus-like planets, and will help in interpreting the compositions of their atmospheres.     

Atomic oxygen distributions in the Venus thermosphere: Comparisons between Venus Express observations and global model simulations

Nightglow emissions provide insight into the global thermospheric circulation, specifically in the transition region (～70–120 km). The O₂ IR nightglow statistical map created from Venus Express (VEx) Visible and InfraRed Thermal Imaging Spectrometer (VIRTIS) observations has been used to deduce a three-dimensional atomic oxygen density map. In this study, the National Center of Atmospheric Research (NCAR) Venus Thermospheric General Circulation Model (VTGCM) is utilized to provide a self-consistent global view of the atomic oxygen density distribution. More specifically, the VTGCM reproduces a 2D nightside atomic oxygen density map and vertical profiles across the nightside, which are compared to the VEx atomic oxygen density map. Both the simulated map and vertical profiles are in close agreement with VEx observations within a ～30° contour of the anti-solar point. The quality of agreement decreases past ～30°. This discrepancy implies the employment of Rayleigh friction within the VTGCM may be an over-simplification for representing wave drag effects on the local time variation of global winds. Nevertheless, the simulated atomic oxygen vertical profiles are comparable with the VEx profiles above 90 km, which is consistent with similar O₂ (¹Δ) IR nightglow intensities. The VTGCM simulations demonstrate the importance of low altitude trace species as a loss for atomic oxygen below 95 km. The agreement between simulations and observations provides confidence in the validity of the simulated mean global thermospheric circulation pattern in the lower thermosphere.     

The planetary fourier spectrometer (PFS) onboard the European Venus Express mission

The planetary fourier spectrometer (PFS) for the Venus Express mission is an infrared spectrometer optimized for atmospheric studies. This instrument has a short wavelength (SW) channel that covers the spectral range from 1700 to 11400 cm⁻¹ (0.9–5.5 μm) and a long wavelength (LW) channel that covers 250–1700 cm⁻¹ (5.5–45 μm). Both channels have a uniform spectral resolution of 1.3 cm⁻¹. The instrument field of view FOV is about 1.6 ° (FWHM) for the short wavelength channel and 2.8 ° for the LW channel which corresponds to a spatial resolution of 7 and 12 km when Venus is observed from an altitude of 250 km. PFS can provide unique data necessary to improve our knowledge not only of the atmospheric properties but also surface properties (temperature) and the surface-atmosphere interaction (volcanic activity).PFS works primarily around the pericentre of the orbit, only occasionally observing Venus from larger distances. Each measurements takes 4.5 s, with a repetition time of 11.5 s. By working roughly 1.5 h around pericentre, a total of 460 measurements per orbit will be acquired plus 60 for calibrations. PFS is able to take measurements at all local times, enabling the retrieval of atmospheric vertical temperature profiles on both the day and the night side.The PFS measures a host of atmospheric and surface phenomena on Venus. These include the:(1) thermal surface flux at several wavelengths near 1 μm, with concurrent constraints on surface temperature and emissivity (indicative of composition); (2) the abundances of several highly-diagnostic trace molecular species; (3) atmospheric temperatures from 55 to 100 km altitude; (4) cloud opacities and cloud-tracked winds in the lower-level cloud layers near 50-km altitudes; (5) cloud top pressures of the uppermost haze/cloud region near 70–80 km altitude; and (6) oxygen airglow near the 100 km level. All of these will be observed repeatedly during the 500-day nominal mission of Venus Express to yield an increased understanding of meteorological, dynamical, photochemical, and thermo-chemical processes in the Venus atmosphere. Additionally, PFS will search for and characterize current volcanic activity through spatial and temporal anomalies in both the surface thermal flux and the abundances of volcanic trace species in the lower atmosphere.Measurement of the 15 μm CO₂ band is very important. Its profile gives, by means of a complex temperature profile retrieval technique, the vertical pressure-temperature relation, basis of the global atmospheric study.PFS is made of four modules called O, E, P and S being, respectively, the interferometer and proximity electronics, the digital control unit, the power supply and the pointing device.     

Rotation period of Venus estimated from Venus Express VIRTIS images and Magellan altimetry

The 1.02 μm wavelength thermal emission of the nightside of Venus is strongly anti-correlated to the elevation of the surface. The VIRTIS instrument on Venus Express has mapped this emission and therefore gives evidence for the orientation of Venus between 2006 and 2008. The Magellan mission provided a global altimetry data set recorded between 1990 and 1992. Comparison of these two data sets reveals a deviation in longitude indicating that the rotation of the planet is not fully described by the orientation model recommended by the IAU. This deviation is sufficiently large to affect estimates of surface emissivity from infrared imaging. A revised period of rotation of Venus of 243.023 ± 0.002 d aligns the two data sets. This period of rotation agrees with pre-Magellan estimates but is significantly different from the commonly accepted value of 243.0185 ± 0.0001 d estimated from Magellan radar images. It is possible that this discrepancy stems from a length of day variation with the value of 243.023 ± 0.002 d representing the average of the rotation period over 16 years.     

The distribution of carbon monoxide in the lower atmosphere of Venus

We have obtained spatially resolved near-infrared spectroscopy of the Venus nightside on 15 nights over three observing seasons. We use the depth of the CO absorption band at 2.3 μm to map the two-dimensional distribution of CO across both hemispheres. Radiative transfer models are used to relate the measured CO band depth to the volume mixing ratio of CO. The results confirm previous investigations in showing a general trend of increased CO abundances at around 60° latitude north and south as compared with the equatorial regions. Observations taken over a few nights generally show very similar CO distributions, but significant changes are apparent over longer periods. In past studies it has been assumed that the CO latitudinal variation occurs near 35 km altitude, at which K-band sensitivity to CO is greatest. By modeling the detailed spectrum of the excess CO at high latitudes we show that it occurs at altitudes around 45 km, much higher than has previously been assumed, and that there cannot be significant contribution from levels of 36 km or lower. We suggest that this is most likely due to downwelling of CO-rich gas from the upper atmosphere at these latitudes, with the CO being removed by around 40 km through chemical processes such as the reaction with SO₃.     

Sulfur chemistry in the middle atmosphere of Venus

Venus Express measurements of the vertical profiles of SO and SO₂ in the middle atmosphere of Venus provide an opportunity to revisit the sulfur chemistry above the middle cloud tops (～58 km). A one dimensional photochemistry-diffusion model is used to simulate the behavior of the whole chemical system including oxygen-, hydrogen-, chlorine-, sulfur-, and nitrogen-bearing species. A sulfur source is required to explain the SO₂ inversion layer above 80 km. The evaporation of the aerosols composed of sulfuric acid (model A) or polysulfur (model B) above 90 km could provide the sulfur source. Measurements of SO₃ and SO (a¹Δ → X³Σ^-) emission at 1.7 μm may be the key to distinguish between the two models.     

Studying methane and other trace species in the Mars atmosphere using a SOIR instrument

Solar Occultation in the InfraRed (SOIR) is one of three spectrometers of the SPICAV/SOIR instrument suite (Bertaux et al., 2007b) on board the Venus Express orbiter (VEX). VEX has been in orbit around Venus since April 2006 and to date SOIR has carried out over 674 measurements. Pre-launch and in-orbit performance analyses allow us to predict what SOIR would be capable of at Mars. SOIR spectra through the Martian atmosphere have been simulated with ASIMUT, a line-by-line (LBL) radiative transfer code also used for the retrieval of vertical profiles of atmospheric constituents of Venus (Vandaele et al., 2008, Bertaux et al., 2007a). The code takes into account the temperature and pressure vertical profiles as well as those of the atmospheric species, but also the instrument function and the overlapping of the diffraction orders of the echelle grating. We will show these spectra and the detection limits of species that could be studied using a SOIR spectrometer making solar occultation or nadir measurements in Mars orbit.