Geochemical characteristics, Ar–Ar ages and original tectonic setting of the Band-e-Zeyarat/Dar Anar ophiolite, Makran accretionary prism, S.E. Iran

The Makran accretionary prism in southeastern Iran contains extensive Mesozoic zones of melange and large intact ophiolites, representing remnants of the Tethys oceanic crust that was subducted beneath Eurasia. To the north of the Makran accretionary prism lies the Jaz Murian depression which is a subduction-related back-arc basin. The Band-e-Zeyarat/Dar Anar ophiolite is one of the ophiolite complexes; it is located on the west side of the Makran accretionary prism and Jaz Murian depression, and is bounded by two major fault systems. The principal rock units of this complex are a gabbro sequence which includes low- and high-level gabbros, an extensive sheeted diabase dike sequence, late intrusive rocks which consist largely of trondhjemites and diorites, and volcanic rocks which are largely pillow basalts interbedded with pelagic sedimentary rocks, including radiolarian chert. Chondrite- and primitive-mantle-normalized incompatible trace element data and age-corrected Nd, Pb, and Sr isotopic data indicate that the Band-e-Zeyarat/Dar Anar ophiolite was derived from a midocean ridge basalt-like mantle source. The isotopic data also reveal that the source for basalts was Indian-Ocean-type mantle. Based on the rare earth element (REE) data and small isotopic range, all the rocks from the Band-e-Zeyarat/Dar Anar ophiolite are cogenetic and were derived by fractionation from melts with a composition similar to average E-MORB; fractionation was controlled by the removal of clinopyroxene, hornblende and plagioclase. Three ⁴⁰Ar–³⁹Ar plateau ages of 140.7±2.2, 142.9±3.5 and 141.7±1.0 Ma, and five previously published K–Ar ages ranging from 121±4 to 146±5 Ma for the hornblende gabbros suggest that rocks from this ophiolite were formed during the Late Jurassic–Early Cretaceous. Plate reconstructions suggest that the rocks of this complex appear to be approximately contemporaneous with the Masirah ophiolite which has crystallization age of (150 Ma). Like Masirah, the rocks from the Band-e-Zeyarat/Dar Anar ophiolite complex represent southern Tethyan ocean crust that was formed distinctly earlier than crust preserved in the 90–100 Ma Bitlis-Zagros ophiolites (including the Samail ophiolite).     

New radiometric dating of the dykes from the Hurd Peninsula, Livingston Island, South Shetland Islands

Fifteen new K–Ar ages in the range of 79–31 Ma are partially confirmed by three ⁴⁰Ar/³⁹Ar plateaus and isochron data of 64.9±0.4, 55.5±0.1 and 52.8±0.6 Ma. The new geochronological data reveal a much more detailed picture of the subduction imprint in the Hurd Peninsula. Using cutting relationships, the dyke emplacement history is divided into four episodes. The Late Cretaceous–Paleocene dykes in the range of 80–60 Ma are related to the main magmatism in Livingston Island and most likely reflect the final stages of subduction of the proto-Pacific oceanic crust. The Early Eocene dykes (56–52 Ma) fill the gap in volcanic activity 70–50 Ma ago. They are the only magmatic event manifested at this time in the region. The 45–42 Ma dykes may be related to the intrusion of the Barnard Point tonalite. Three samples of Oligocene age appear to represent the last igneous activities on the Hurd Peninsula prior to the opening of the Bransfield Strait.     

K-Ar ages of the metamorphic sole of the Semail Ophiolite: implications for ophiolite cooling history

K–Ar ages have been determined on micas and hornblendes in the basal metamorphic sequence and in metamorphic rocks squeezed into the mantle sequence of the Semail Ophiolite. The hornblende ages of 99±0.5 and 102±0.8 Ma and the 90 Ma ages of coexisting micas from the high-grade metamorphic portion of the sequence are interpreted as cooling stages following the peak of metamorphism (T 800–850° C, P 6.5–9 kbar). The new pressure estimates are based on findings of kyanite in garnet-amphibolite and cordierite in quartzitic rocks. These data indicate a cooling rate of 10–30° C/Ma. The oldest mica ages of 95±1 Ma are observed in the lowest-grade greenschists. These also largely represent cooling ages, but might in part also include formation ages. The pattern of the muscovite ages across the metamorphic sole indicates that the cooling front moved from the low-grade metamorphic zone, through the high-grade rocks and into the base of the overlying ophiolite. Radiometric ages of hornblendes (92.3±0.5 and 94.8±0.6 Ma) indicate that the crustal gabbro sequence cooled below 500° C later than the base of the ophiolite sequence. Metamorphism of the sole rocks occurred during subduction of oceanic sediments and volcanic or gabbroic rocks as they progressively came into contact with hotter zones at the base of the overriding plate. The peak of metamorphism must have been contemporaneous with the main magmatism in the Semail Ophiolite. One of the dated muscovites yields an age of 81.3±0.8 Ma, but this is related to discrete deformation zones that were active during late-stage emplacement of the ophiolite.     

Proterozoic–Paleozoic development of the basement of the Central Andes (18–26°S) — a mobile belt of the South American craton

The Late Precambrian–Early Paleozoic metamorphic basement forms a volumetrically important part of the Andean crust. We investigated its evolution in order to subdivide the area between 18 and 26°S into crustal domains by means of petrological and age data (Sm–Nd isochrons, K–Ar). The metamorphic crystallization ages and t_DM ages are not consistent with growth of the Pacific margin north of the Argentine Precordillera by accretion of exotic terranes, but favor a model of a mobile belt of the Pampean Cycle. Peak metamorphic conditions in all scattered outcrop areas between 18 and 26°S are similar and reached the upper amphibolite facies conditions indicated by mineral paragensis and the occurrence of migmatite. Sm–Nd mineral isochrons yielded 525±10, 505±6 and 509±1 Ma for the Chilean Coast Range, the Chilean Precordillera and the Argentine Puna, and 442±9 and 412±18 Ma for the Sierras Pampeanas. Conventional K–Ar cooling age data of amphibole and mica cluster around 400 Ma, but are frequently reset by Late Paleozoic and Jurassic magmatism. Final exhumation of the Early Paleozoic orogen is confirmed by Devonian erosional unconformities. Sm–Nd depleted mantle model ages of felsic rocks from the metamorphic basement range from 1.4 to 2.2 Ga, in northern Chile the average is 1.65±0.16 Ga (1σ; n=12), average t_DM of both gneiss and metabasite in NW Argentina is 1.76±0.4 Ga (1σ; n=22), and the isotopic composition excludes major addition of juvenile mantle derived material during the Early Paleozoic metamorphic and magmatic cycle. These new data indicate a largely similar development of the metamorphic basement south of the Arequipa Massif at 18°S and north of the Argentine Precordillera at 28°S. Variations of metamorphic grade and of ages of peak metamorphism are of local importance. The protolith was derived from Early to Middle Proterozoic cratonic areas, similar to the Proterozoic rocks from the Arequipa Massif, which had undergone Grenvillian metamorphism at ca. 1.0 Ga.     

K–Ar ages of meteorites: Clues to parent-body thermal histories

Whereas most radiometric chronometers give formation ages of individual meteorites >4.5 Ga ago, the K–Ar chronometer rarely gives times of meteorite formation. Instead, K–Ar ages obtained by the ³⁹Ar–⁴⁰Ar technique span the entire age of the solar system and typically measure the diverse thermal histories of meteorites or their parent objects, as produced by internal parent body metamorphism or impact heating. This paper briefly explains the Ar–Ar dating technique. It then reviews Ar–Ar ages of several different types of meteorites, representing at least 16 different parent bodies, and discusses the likely thermal histories these ages represent. Ar–Ar ages of ordinary (H, L, and LL) chondrites, R chondrites, and enstatite meteorites yield cooling times following internal parent body metamorphism extending over ∼200 Ma after parent body formation, consistent with parent bodies of ∼100 km diameter. For a suite of H-chondrites, Ar–Ar and U–Pb ages anti-correlate with the degree of metamorphism, consistent with increasing metamorphic temperatures and longer cooling times at greater depths within the parent body. In contrast, acapulcoites–lodranites, although metamorphosed to higher temperatures than chondrites, give Ar–Ar ages which cluster tightly at ∼4.51 Ga. Ar–Ar ages of silicate from IAB iron meteorites give a continual distribution across ∼4.53–4.32 Ga, whereas silicate from IIE iron meteorites give Ar–Ar ages of either ∼4.5 Ga or ∼3.7 Ga. Both of these parent bodies suffered early, intense collisional heating and mixing. Comparison of Ar–Ar and I–Xe ages for silicate from three other iron meteorites also suggests very early collisional heating and mixing. Most mesosiderites show Ar–Ar ages of ∼3.9 Ga, and their significantly sloped age spectra and Ar diffusion properties, as well as Ni diffusion profiles in metal, indicate very deep burial after collisional mixing and cooling at a very slow rate of ∼0.2 °C/Ma. Ar–Ar ages of a large number of brecciated eucrites range over ∼3.4–4.1 Ga, similar to ages of many lunar highland rocks. These ages on both bodies were reset by large impact heating events, possibly initiated by movements of the giant planets. Many impact-heated chondrites show impact-reset Ar–Ar ages of either >3.5 Ga or <1.0 Ga, and generally only chondrites show these younger ages. The younger ages may represent orbital evolution times in the asteroid belt prior to ejection into Earth-crossing orbits. Among martian meteorites, Ar–Ar ages of nakhlites are similar to ages obtained from other radiometric chronometers, but apparent Ar–Ar ages of younger shergottites are almost always older than igneous crystallization ages, because of the presence of excess (parentless) ⁴⁰Ar. This excess ⁴⁰Ar derives from shock-implanted martian atmosphere or from radiogenic ⁴⁰Ar inherited from the melt. Differences between meteorite ages obtained from other chronometers (e.g., I–Xe and U–Pb) and the oldest measured Ar–Ar ages are consistent with previous suggestions that the ⁴⁰K decay parameters in common use are incorrect and that the K–Ar age of a 4500 Ma meteorite should be possibly increased, but by no more than ∼20 Ma.     

Precise 40Ar/39Ar ages from the metamorphic sole of the Mersin ophiolite (southern Turkey)

The Mersin ophiolite is located on the southern flank of the E–W-trending central Tauride belt in Turkey. It is one of the Late Cretaceous Neotethyan oceanic lithospheric remnants. The Mersin ophiolite formed in a suprasubduction zone tectonic setting in southern Turkey at the beginning of the Late Cretaceous. The Mersin ophiolite is one of the best examples in Turkey in order to study reconstruction of ophiolite emplacement along the Alpine–Himalayan orogenic belt. ⁴⁰Ar/³⁹Ar incremental-heating measurements were performed on seven obduction-related subophiolitic metamorphic rocks. Hornblende separates yielded isochron ages ranging from 96.0±0.7 Ma to 91.6±0.3 Ma (all errors ±1σ). Five of the seven hornblende age determinations are indistinguishable at the 95% confidence level and have a weighted mean age of 92.6±0.2 (2σ) Ma. We interpret these ages as the date of cooling below 500°C. Intraoceanic thrusting occurred (∼4 Ma) soon after formation of oceanic crust. The sole was crosscut by microgabbro–diabase dikes less than 3 m.y. later. The final obduction onto the Tauride platform occurred during the Late Cretaceous–Early Paleocene. Our new high-precision ages constrain intraoceanic thrusting for a single ophiolite (Mersin) in the Tauride belt.     

Transition from subduction- to exhumation-related fabrics in glaucophane-bearing eclogites, Oman: evidence from relative fabric chronology and Ar/Ar ages

Controversy over the age of peak metamorphism and therefore the tectonic evolution of the Arabian margin relates to the polydeformed and polymetamorphosed nature of glaucophane-bearing eclogites from the Saih Hatat window beneath the allochthonous Samail ophiolite in NE Oman. These eclogites contain relicts of earlier fabrics, structures and metamorphic assemblages and provide a record of change from subduction to exhumation. The eclogites are part of a mafic layer that was disrupted into boudins up to 0.5 km in length within a lower plate shear zone (As Sifah shear zone). The megaboudins not only preserve the relicts of the highest grade of metamorphism but also an early ENE-trending lineation and sheathlike isoclines enveloped by the flat-lying schistosity. The boudin-bearing layer is isoclinally folded with calc-schist, mafic schist and quartz–mica schist, where the regional folds have axes parallel to the NE-trending stretching lineation (a-type folds). Textural evidence suggests multiple growth events for garnet and clinopyroxene, requiring polymetamorphism of the mafic layers that formed the eclogite megaboudins. The surrounding calc-schist and quartz–mica schist are both intensely deformed with transposition foliation containing an NE-trending lineation in phengite and asymmetric shear indicators such as C′-type shear bands and asymmetric pressure shadows around garnets, that give top-to-the-NE sense of shear. Although consistent ENE-trending lineations in all the boudins suggest that they have largely acted as passive, nonrotating rigid bodies, the presence of NE-vergent asymmetric mesofolds, extensive dynamic recrystallisation, multiple generations of phengites and a range of ⁴⁰Ar–³⁹Ar apparent ages within the megaboudins suggest, however, that they have not acted entirely passively during the later deformation. Phengites isolated from the high-P/low-T fabrics show groupings in ⁴⁰Ar–³⁹Ar apparent ages interpreted as distinct metamorphic/cooling intervals at 140–135, 120–98 and 92–80 Ma. Microstructural relations suggest that age groupings younger than 100 Ma reflect phengite growth during exhumation with the top-to-the-NE shearing. The older ages (120–110 Ma) from fabrics that give top-to-the-S shear sense may reflect growth during the subduction phase. The combination of groupings of apparent argon ages older than the crystallisation age of the Samail Ophiolite, the suggestion of different geothermal gradients, and superposed metamorphism suggest that the eclogites and garnet blueschists formed as a result of underthrusting along a break that was not directly related to the metamorphic sole of the ophiolite. The glaucophane–eclogites are interpreted as having formed at different times under varying pressure–temperature conditions during underthrusting with variations in the rate of underthrusting, allowing thermal equilibration and/or rapid cooling at different crustal levels.     

Dating the geologic history of Oman’s Semail ophiolite: insights from U-Pb geochronology

Eclogites from the deepest structural levels beneath the Semail ophiolite, Oman, record the subduction and later exhumation of the Arabian continental margin. Published ages for this high pressure event reveal large discrepancies between the crystallisation ages of certain eclogite-facies minerals and apparent cooling ages of micas. We present precise U-Pb zircon (78.95 ± 0.13 Ma) and rutile (79.6 ± 1.1 Ma) ages for the eclogites, as well as new U-Pb zircon ages for trondhjemites from the Semail ophiolite (95.3 ± 0.2 Ma) and amphibolites from the metamorphic sole (94.48 ± 0.23 Ma). The new eclogite ages reinforce published U-Pb zircon and Rb-Sr mineral-whole rock isochron ages, yet are inconsistent with published interpretations of older ⁴⁰Ar/³⁹Ar phengite and Sm-Nd garnet dates. We show that the available U-Pb and Rb-Sr ages, which are in tight agreement, fit better with the available geological evidence, and suggest that peak metamorphism of the continental margin occurred during the later stages of ophiolite emplacement.     

990 and 1100 Ma Grenvillian tectonothermal events in the northern Oaxacan Complex, southern Mexico: roots of an orogen

Inliers of 1.0–1.3 Ga rocks occur throughout Mexico and form the basement of the Oaxaquia microcontinent. In the northern part of the largest inlier in southern Mexico, rocks of the Oaxacan Complex consist of the following structural sequence of units (from bottom to top), which protolith ages are: (1) Huitzo unit: a 1012±12 Ma anorthosite–mangerite–charnockite–granite (AMCG) suite; (2) El Catrı́n unit: ≥1350 Ma orthogneiss migmatized at 1106±6 Ma; and (3) El Marquez unit: ≥1140 Ma para- and orthogneisses. These rocks were affected by two major tectonothermal events that are dated using U–Pb isotopic analyses of zircon: (a) the 1106±6 Ma Olmecan event produced a migmatitic or metamorphic differentiation banding folded by isoclinal folds; and (b) the 1004–978±3 Ma Zapotecan event produced at least two sets of structures: (Z1) recumbent, isoclinal, Class 1C/3 folds with gently NW-plunging fold axes that are parallel to mineral and stretched quartz lineations under granulite facies metamorphism; and (Z2) tight, upright, subhorizontal WNW- to NNE-trending folds accompanied by development of brown hornblende at upper amphibolite facies metamorphic conditions. Cooling through 500 °C at 977±12 Ma is documented by ⁴⁰Ar/³⁹Ar analyses of hornblende. Fold mechanisms operating in the northern Oaxacan Complex under Zapotecan granulite facies metamorphism include flexural and tangential–longitudinal strain accompanied by intense flattening and stretching parallel to the fold axes. Subsequent Phanerozoic deformation includes thrusting and upright folding under lower-grade metamorphic conditions. The Zapotecan event is widespread throughout Oaxaquia, and took crustal rocks to a depth of 25–30 km by orogenic crustal thickening, and is here designated as Zapotecan Orogeny. Modern analogues for Zapotecan granulite facies metamorphism and deformation occur in middle to lower crustal portion of subduction and collisional orogens. Contemporaneous tectonothermal events took place throughout Oaxaquia, and in various parts of the Genvillian orogen in Laurentia and Amazonia.     

Formation, subduction, and exhumation of Penninic oceanic crust in the Eastern Alps: time constraints from Ar/Ar geochronology

New ⁴⁰Ar/³⁹Ar geochronology places time constraints on several stages of the evolution of the Penninic realm in the Eastern Alps. A 186±2 Ma age for seafloor hydrothermal metamorphic biotite from the Reckner Ophiolite Complex of the Pennine–Austroalpine transition suggests that Penninic ocean spreading occurred in the Eastern Alps as early as the Toarcian (late Early Jurassic). A 57±3 Ma amphibole from the Penninic subduction–accretion Rechnitz Complex dates high-pressure metamorphism and records a snapshot in the evolution of the Penninic accretionary wedge. High-pressure amphibole, phengite, and phengite+paragonite mixtures from the Penninic Eclogite Zone of the Tauern Window document exhumation through ≤15 kbar and >500 °C at 42 Ma to 10 kbar and 400 °C at 39 Ma. The Tauern Eclogite Zone pressure–temperature path shows isothermal decompression at mantle depths and rapid cooling in the crust, suggesting rapid exhumation. Assuming exhumation rates slower or equal to high-pressure–ultrahigh-pressure terrains in the Western Alps, Tauern Eclogite Zone peak pressures were reached not long before our high-pressure amphibole age, probably at ≤45 Ma, in accordance with dates from the Western Alps. A late-stage thermal overprint, common to the entire Penninic thrust system, occurred within the Tauern Eclogite Zone rocks at 35 Ma. The high-pressure peak and switch from burial to exhumation of the Tauern Eclogite Zone is likely to date slab breakoff in the Alpine orogen. This is in contrast to the long-lasting and foreland-propagating Franciscan-style subduction–accretion processes that are recorded in the Rechnitz Complex.     

The metamorphic complex of Beloretzk, SW Urals, Russia — a terrane with a polyphase Meso- to Neoproterozoic thermo-dynamic evolution

An integrated geological study of the tectono-metamorphic evolution of the metamorphic complex of Beloretzk (MCB) which is part of the eastern Bashkirian mega-anticlinorium (BMA), SW Urals, Russia shows that the main lithological units are Neoproterozoic (Riphean and Vendian age) siliciclastic to carbonate successions. Granitic, syenitic and mafic intrusions together with subaerial equivalents comprise the Neo- and Mesoproterozoic magmatic rocks. The metamorphic grade ranges from diagenetic and very low grade in the western BMA to high-grade in the MCB. The N–S trending Zuratkul fault marks the change in metamorphic grade and structural evolution between the central and eastern BMA. Structural data, Pb/Pb-single zircon ages, ⁴⁰Ar/³⁹Ar cooling ages and the provenance signature of Riphean and Vendian siliciclastic rocks in the western BMA give evidence of Mesoproterozoic (Grenvillian) rifting, deformation and eclogite-facies metamorphism in the MCB and a Neoproterozoic (Cadomian) orogenic event in the SW Urals. Three pre-Ordovician deformation phases can be identified in the MCB. The first SSE-vergent, isoclinal folding phase (D₁) is younger than the intrusion of mafic dykes (Pb/Pb-single zircon: 1350 Ma) and older than the eclogite-facies metamorphism. High P/low T eclogite-facies metamorphism is bracketed by D₁ and the intrusion of the Achmerovo granite (Pb/Pb-single zircon: ≤970 Ma). An extensional, sinistral, top-down-to-NW directed shearing (D₂) is correlated with the first exhumation of the MCB. E-vergent folding and thrusting (D₃) occurred at retrograde greenschist-facies metamorphic conditions. The tremolite ⁴⁰Ar/³⁹Ar cooling age (718±5 Ma) of amphibolitic eclogite and muscovite ⁴⁰Ar/³⁹Ar cooling ages (about 550 Ma) of mica schists indicate that a maximum temperature of 500±50 °C was not reached during the Neoproterozoic orogeny. The style and timing of the Neoproterozoic orogeny show similarities to the Cadomian-aged Timan Range NW of the Polar Urals. Geochronological and thermochronological data together with the abrupt change in structural style and metamorphism east of the Zuratkul fault, suggest that the MCB is exotic with respect to the SE-margin of the East European Platform. Thus, the MCB is named the ‘Beloretzk Terrane’. Recognition of the ‘Beloretzk Terrane’ and the Neoproterozoic orogeny at the eastern margin of Baltica has important implications for Neoproterozoic plate reconstruction and suggests that the eastern margin of Baltica might have lain close to the Avalonian–Cadomian belt.     

39Ar−40Ar dating of multiply zoned amphibole generations (Malenco, Italian Alps)

Mafic rocks of a Permian crust to mantle section in Val Malenco (Italy) display a multi-stage evolution: pre-Alpine exhumation to the ocean floor, followed by burial and re-exhumation during Alpine convergence. Four prominent generations of amphiboles were formed during these stages. On the basis of microstructural investigations combined with electron microprobe analyses two amphibole generations can be assigned to the pre-Alpine decompression and two to the Alpine metamorphic P–T evolution. The different amphiboles have distinct Na^M4, Ca, K and Cl contents according to different P–T conditions and fluid chemistry. Analysing these mixed amphiboles by the ³⁹Ar−⁴⁰Ar stepwise heating technique yielded very complex age spectra. However, by correlating amphibole compositions directly obtained from the electron microprobe with the components deduced from the release of Ar isotopes during stepwise heating, obtained ages were consistent with the geological history deduced from field and petrological studies. The two generations of pre-Alpine amphiboles gave distinguishable Triassic to Late Jurassic/Early Cretaceous ages (≈225 and 130–140 Ma respectively). High-Na^M4 amphiboles have higher isotopic ages than low-Na^M4 ones, in agreement with their decompressional evolution. The exhumation of the Permian crust to mantle section is represented by the former age. The latter age concerns Cl-dominated amphibole related to an Early Cretaceous oceanic stage. For the early Alpine, pressure-dominated metamorphism we obtained a Late Cretaceous age (83–91 Ma). The later, temperature-dominated overprint is significantly younger, as indicated by ³⁹Ar−⁴⁰Ar ages of 67–73 Ma. These Late Cretaceous ages favour an Adriatic origin for the Malenco unit. Our data show that ³⁹Ar−⁴⁰Ar dating combined with detailed microprobe analysis can exploit the potential to relate conditions of amphibole formation to their respective ages. Received: 1 March 1999 / Accepted: 18 August 2000     

Late Cenozoic transpressional ductile deformation north of the Nazca–South America–Antarctica triple junction

The southern Andes plate boundary zone records a protracted history of bulk transpressional deformation during the Cenozoic, which has been causally related to either oblique subduction or ridge collision. However, few structural and chronological studies of regional deformation are available to support one hypothesis or the other. We address along- and across-strike variations in the nature and timing of plate boundary deformation to better understand the Cenozoic tectonics of the southern Andes.Two east–west structural transects were mapped at Puyuhuapi and Aysén, immediately north of the Nazca–South America–Antarctica triple junction. At Puyuhuapi (44°S), north–south striking, high-angle contractional and strike-slip ductile shear zones developed from plutons coexist with moderately dipping dextral-oblique shear zones in the wallrocks. In Aysén (45–46°), top to the southwest, oblique thrusting predominates to the west of the Cenozoic magmatic arc, whereas dextral strike-slip shear zones develop within it.New ⁴⁰Ar–³⁹Ar data from mylonites and undeformed rocks from the two transects suggest that dextral strike-slip, oblique-slip and contractional deformation occurred at nearly the same time but within different structural domains along and across the orogen. Similar ages were obtained on both high strain pelitic schists with dextral strike-slip kinematics (4.4±0.3 Ma, laser on muscovite–biotite aggregates, Aysén transect, 45°S) and on mylonitic plutonic rocks with contractional deformation (3.8±0.2 to 4.2±0.2 Ma, fine-grained, recrystallized biotite, Puyuhuapi transect). Oblique-slip, dextral reverse kinematics of uncertain age is documented at the Canal Costa shear zone (45°S) and at the Queulat shear zone at 44°S. Published dates for the undeformed protholiths suggest both shear zones are likely Late Miocene or Pliocene, coeval with contractional and strike-slip shear zones farther north. Coeval strike-slip, oblique-slip and contractional deformation on ductile shear zones of the southern Andes suggest different degrees of along- and across-strike deformation partitioning of bulk transpressional deformation.The long-term dextral transpressional regime appears to be driven by oblique subduction. The short-term deformation is in turn controlled by ridge collision from 6 Ma to present day. This is indicated by most deformation ages and by a southward increase in the contractional component of deformation. Oblique-slip to contractional shear zones at both western and eastern margins of the Miocene belt of the Patagonian batholith define a large-scale pop-up structure by which deeper levels of the crust have been differentially exhumed since the Pliocene at a rate in excess of 1.7 mm/year.     

Crustal architecture above the high-pressure belt of the Grenville Province in the Manicouagan area: new structural, petrologic and U–Pb age constraints

Recent U–Pb age determinations and P–T estimates allow us to characterize the different levels of a formerly thickened crust, and provide further constraints on the make up and tectono-thermal evolution of the Grenville Province in the Manicouagan area. An important tectonic element, the Manicouagan Imbricate zone (MIZ), consists of mainly 1.65, 1.48 and 1.17 Ga igneous rocks metamorphosed under 1400–1800 MPa and 800–900 °C at 1.05–1.03 Ga, during the Ottawan episode of the Grenvillian orogenic cycle, coevally with intrusion of gabbro dykes in shear zones. The MIZ has been interpreted as representing thermally weakened deep levels of thickened crust extruded towards the NW over a parautochthonous crustal-scale ramp. Mantle-derived melts are considered as in part responsible for the high metamorphic temperatures that were registered.New data show that mid-crustal levels structurally above the MIZ are represented by the Gabriel Complex of the Berthé terrane, that consists of migmatite with boudins of 1136±15 Ma gabbro and rafts of anatectic metapelite with an inherited monazite age at 1478±30 Ma. These rocks were metamorphosed at about the same time as the MIZ (metamorphic zircon in gabbro: 1046±2 Ma; single grains of monazite in anatectic metapelite: 1053±2 Ma) and under the same T range (800–900 °C) but at lower P conditions (1000–1100 MPa). They are mainly exposed in an antiformal culmination above a high-strain zone, which has tectonic lenses of high P–T rocks from the MIZ and is intruded by synmetamorphic gabbroic rocks. This zone is interpreted as part of the hangingwall of the MIZ during extrusion. A gap of 400 MPa in metamorphic pressures between the tectonic lenses and the country rocks, together with the broad similarity in metamorphic ages, are consistent with rapid tectonic transport of the high P–T rocks over a ramp prior to the incorporation of the mafic lenses in the hangingwall.Between the antiformal culmination of the Gabriel Complex and the MIZ 1.48 Ga old granulites of the Hart Jaune terrane are exposed. They are intruded by unmetamorphosed 1228±3 Ma gabbro sills and 1166±1 Ma anorthosite. Hart Jaune Terrane represents relatively high crustal levels that truncate the MIZ-Gabriel Complex contact and are preserved in a synformal structure.Farther south, the Gabriel Complex is overlain by the Banded Complex, a composite unit including 1403+32/−25 Ma granodiorite and 1238+16/−13−1202+40/−25 Ma granite. This unit has been metamorphosed under relatively low-P (800 MPa) granulite-facies conditions. Metamorphic U–Pb data, limited to zircon lower intercept ages (971±38 Ma and 996±27 Ma) and a titanite (990±5 Ma) age, are interpreted to postdate the metamorphic peak.The general configuration of units along the section is consistent with extrusion of the MIZ during shortening and, finally, normal displacement along discrete shear zones.     

Postcollisional flow of aqueous fluid within ultrahigh-pressure eclogite in the Dabie orogen

A combined study of chronometric dating and oxygen isotope analysis for minerals from vein and host eclogite as well as regional country-rock gneiss in the Dabie orogen provides a direct constraint on timing of fluid flow in this orogen formed by continental collision. Oxygen isotope ratios of vein minerals are significantly lower than those of the host eclogite, but comparable with those of the regional gneiss. This suggests the veining fluid came from the regional gneiss (i.e. exhumed slab itself) rather than the host eclogite. While zircon U–Pb and phengite Ar–Ar dating yields ages of 214 to 222 Ma for the eclogite and gneiss, the vein gives a quartz–muscovite Rb–Sr isochron age of 181 Ma and a muscovite K–Ar age of 179 Ma. Thus the veining postdates the Triassic ultrahigh pressure metamorphic event, witnessing postcollisional fluid flow after the orogenic cycle of continental collision.     

Generation of Late Cretaceous silicic rocks in SE China: Age, major element and numerical simulation constraints

Rhyolite-dominating bimodal volcanic suites (rhyolite/basalt), mafic dikes and A-type granites distribute from N Zhejiang to S Fujian over 800 km in the Southeast Coast Magmatic Belt (SCMB) – the Late Yanshanian (LY) orogenic belt in SE China. Data of ⁴⁰Ar/³⁹Ar and K–Ar whole-rock ages and LA-ICPMS U–Pb zircon ages indicate that rhyolitic volcanism (101–72 Ma) is contemporaneous with the A-type granitic intrusions (100–90 Ma) and mafic dike injections (94–77 Ma). This time span is used to define the upper volcanic series in Zhejiang–Fujian areas. One striking feature of rhyolites in the SCMB is that many are strongly peraluminous (SP) and others, mostly restrict in Fujian, are peralkaline to mildly peraluminous (P-MP) and chemically resemble A-type granites. The SP character is unique among well-known large rhyolite provinces worldwide. Based on experimental works for a common thermal regime and inherited zircon age information, we suggest that SP and P-MP rhyolites represent low pressure melting of the felsic (quartzofeldspathic) granite (±metapelite) and the accompanied granodioritic, tonalitic and trondhjemitic member of the core complex assemblage, respectively, to account for the decreasing aluminosity. They could have also been contaminated by young igneous rocks, and ancient crust to a lesser degree, during ascent to the surface. Plate subduction and lithosphere extension processes, respectively, are numerically simulated for the magma generation of these rhyolites using the mafic underplating model. Results suggest that the most effective controlling factor to generate SP and associated P-MP (A-type) magmas during 95–80 Ma is thinning of the lithosphere thickness with a high exhumation rate. Under this circumstance, the core complex assemblage can be uplifted to lower level of the crust and match the constraint of experimental works.     

Age of emplacement of the schistes lustres nappe, Alpine Corsica

Structural studies in the Schistes lustrés nappe west of Bastia, Corsica, demonstrate the existence of a tectonic mélange in which km-scale blocks and smaller lozenges of basement granite gneiss, thick-layered marble and dismembered Mesozoic ophiolite are enveloped in a matrix of calc-schist and blueschist. The main (S₁) foliation is developed in both block and matrix and is concordant with lithologie contacts. Blueschist facies metamorphism was syn-kinematic with the main foliation.The S₁ in the Schistes lustrés was refolded about ENE-WSW trending, tight similar and monoclinal fold axes (F₂). These second folds verge to the southeast and show km-scale axial culminations and depressions that are reflected by topography and residual Bouguer gravity anomalies.Parautochthonous Hercynian basement (Tenda-Corte complex) beneath the western edge of the Schistes lustrés nappe contains a mylonitic foliation which is concordant with the main foliation in the Schistes lustrés. The intensity of deformation in the basement decreases away from this contact and undeformed granites are found 3 km to the west.Whole rock samples of the deformed basement immediately beneath the Schistes lustrés yield an Rb-Sr isochron diagram (n = 4) which has an age of 105 ± 8 Ma (1σ) and initial ratio of 0.7228 ± 0.0005 (1σ). This result is more precise than our preliminary age and initial ratio estimate of 98 ± 14 and 0.7296 ± 0.0068, respectively (Cohen et al., 1979). It is similar to a recently published mid-Cretaceous (90 Ma) ⁴⁰Ar-³⁹Ar age from glaucophane mineral separates. We interpret this date as the age of a metamorphic overprint related to the emplacement of the Schistes lustrés nappe and associated ophiolites, the formation of the main foliation and blueschist facies metamorphism.These results indicate that the mid-Cretaceous blueschist facies metamorphism documented in the Western Alps formerly extended farther south of its present terminus. The data are consistent with mid-Cretaceous obduction of Tethyan oceanic crust onto the present-day eastern continental margin of Corsica. We postulate that during Eocene—early Oligocene time a polarity flip occurred outboard of the obducted crust and a new, southfacing subduction zone developed. This change in polarity was responsible for the development of southeast-vergent second folds and for the resetting of ⁴⁰Ar−³⁹Ar and K-Ar geochronologic clocks described in the literature.     

He–Ar and Nd–Sr isotopic compositions of late Pleistocene felsic plutonic back arc basin rocks from Ulleungdo volcanic island, South Korea: Implications for the genesis of young plutonic rocks in a back arc basin

We report analyses of noble gases and Nd–Sr isotopes in mineral separates and whole rocks of late Pleistocene (< 0.2 Ma) monzonites from Ulleungdo, South Korea, a volcanic island within the back arc basin of the Japan island arc. A Rb–Sr mineral isochron age for the monzonites is 0.12 ± 0.01 Ma. K–Ar biotite ages from the same samples gave relatively concordant ages of 0.19 ± 0.01and 0.22 ± 0.01 Ma. ⁴⁰Ar/³⁹Ar yields a similar age of 0.29 ± 0.09 Ma. Geochemical characteristics of the felsic plutonic rocks, which are silica oversaturated alkali felsic rocks (av., 12.5 wt% in K₂O + Na₂O), are similar to those of 30 alkali volcanics from Ulleungdo in terms of concentrations of major, trace and REE elements. The initial Nd–Sr isotopic ratios of the monzonites (⁸⁷Sr/⁸⁶Sr = 0.70454–0.71264, ¹⁴³Nd/¹⁴⁴Nd = 0.512528–0.512577) are comparable with those of the alkali volcanics (⁸⁷Sr/⁸⁶Sr = 0.70466–0.70892, ¹⁴³Nd/¹⁴⁴Nd = 0.512521–0.512615) erupted in Stage 3 of Ulleungdo volcanism (0.24–0.47 Ma). The high initial ⁸⁷Sr/⁸⁶Sr values of the monzonites imply that seawater and crustally contaminated pre-existing trachytes may have been melted or assimilated during differentiation of the alkali basaltic magma.A mantle helium component (³He/⁴He ratio of up to 6.5 RA) associated with excess argon was found in the monzonites. Feldspar and biotite have preferentially lost helium during slow cooling at depth and/or during their transportation to the surface in a hot host magma. The source magma noble gas isotopic features are well preserved in fluid inclusions in hornblende, and indicate that the magma may be directly derived from subcontinental lithospheric mantle metasomatized by an ancient subduction process, or may have formed as a mixture of MORB-like mantle and crustal components. The radiometric ages, geochemical and Nd–Sr isotopic signatures of the Ulleungdo monzonites as well as the presence of mantle-derived helium and argon, suggests that these felsic plutonic rocks evolved from alkali basaltic magma that formed by partial melting of subcontinental lithospheric mantle beneath the back arc basin located along the active continental margin of the southeastern part of the Eurasian plate.     

Geochronological, isotopic, and geochemical data from Permo-Triassic granitic gneisses and granitoids of the Colombian Central Andes

New U–Pb SHRIMP ages in zircon, Ar–Ar ages in micas and amphiboles, Nd–Sr isotopes, and major and REE geochemical analyses in granitic gneisses and granitic stocks of the Central Cordillera of Colombia indicate the presence of a collisional orogeny in Permo-Triassic times in the Northern Andes related to the construction of the Pangea supercontinent. The collision is recorded by metamorphic U–Pb SHRIMP ages in inherited zircons around 280 Ma and magmatic U–Pb SHRIMP ages in neoformed zircons around 250 Ma within syntectonic crustal granitic gneisses. Magmatic U–Pb SHRIMP and Ar–Ar Triassic ages around 228 Ma in granitic stocks indicate the presence of late tectonic magmatism related to orogenic collapse and the beginning of the breakup of the supercontinent. During this period, the Central Cordillera of Colombia would have been located between the southern United States and northern Venezuela, in the leading edge of the Gondwana supercontinent.     

Conflicting structural and geochronological data from the Ibituruna quartz-syenite (SE Brazil): Effect of protracted “hot” orogeny and slow cooling rate?

The Ibituruna quartz-syenite was emplaced as a sill in the Ribeira-Araçuaí Neoproterozoic belt (Southeastern Brazil) during the last stages of the Gondwana supercontinent amalgamation. We have measured the Anisotropy of Magnetic Susceptibility (AMS) in samples from the Ibituruna sill to unravel its magnetic fabric that is regarded as a proxy for its magmatic fabric. A large magnetic anisotropy, dominantly due to magnetite, and a consistent magnetic fabric have been determined over the entire Ibituruna massif. The magmatic foliation and lineation are strikingly parallel to the solid-state mylonitic foliation and lineation measured in the country-rock. Altogether, these observations suggest that the Ibituruna sill was emplaced during the high temperature (~ 750 °C) regional deformation and was deformed before full solidification coherently with its country-rock. Unexpectedly, geochronological data suggest a rather different conclusion. LA-ICP-MS and SHRIMP ages of zircons from the Ibituruna quartz-syenite are in the range 530–535 Ma and LA-ICP-MS ages of zircons and monazites from synkinematic leucocratic veins in the country-rocks suggest a crystallization at ~ 570–580 Ma, i.e., an HT deformation > 35My older than the emplacement of the Ibituruna quartz-syenite. Conclusions from the structural and the geochronological studies are therefore conflicting. A possible explanation arises from ⁴⁰Ar–³⁹Ar thermochronology. We have dated amphiboles from the quartz-syenite, and amphiboles and biotites from the country-rock. Together with the ages of monazites and zircons in the country-rock, ⁴⁰Ar–³⁹Ar mineral ages suggest a very low cooling rate: < 3 °C/My between 570 and ~ 500 Ma and ~ 5 °C/My between 500 and 460 Ma. Assuming a protracted regional deformation consistent over tens of My, under such stable thermal conditions the fabric and microstructure of deformed rocks may remain almost unchanged even if they underwent and recorded strain pulses separated by long periods of time. This may be a characteristic of slow cooling “hot orogens” that rocks deformed at significantly different periods during the orogeny, but under roughly unchanged temperature conditions, may display almost indiscernible microstructure and fabric.