Post‐Synthesis of Ti‐SBA‐15 in Supercritical CO2‐Ethanol Solution

Ti‐SBA‐15 materials with Ti incorporated into the framework of SBA‐15 and controllable Ti contents were successfully prepared via a post‐treatment route in supercritical CO₂‐ethanol solution, followed by calcination. The resultant Ti‐SBA‐15 materials were characterized by means of different techniques including X‐ray diffraction, X‐ray photoelectron spectroscopy, transmission electron microscopy, IR analysis, and N₂ sorption analysis. It was demonstrated that the resultant materials retained a structure similar to that of the parent SBA‐15, and Ti was incorporated into the framework of SBA‐15. At high Ti content, i.e, Si/Ti = 5:1, a TiO₂ phase formed and was coated onto the inner surface of SBA‐15 in addition to the incorporation of the Ti in the framework. The BET surface areas of the Ti‐SBA‐15 samples decreased with increasing Ti content. The presence of small amounts of H₂O in the reaction medium may have resulted in some TiO₂ nanoparticles being uniformly distributed in the pores of the SBA‐15 accompanying the incorporation of Ti in the SBA‐15 framework.     

Non‐linear‐Maxwell‐element‐type hysteretic control force

A simple non‐linear control law is proposed for reducing structural responses against seismic excitations. This law defines control force dynamics by one differential equation involving a non‐linear term that restrains the control force amplitude. If non‐linearity is neglected, the control force becomes the force in a Maxwell element, so it is called the non‐linear‐Maxwell‐element‐type (NMW) control force. The NMW control force vs. deformation relation plots hysteretic curves. The basic performance of an SDOF model with the NMW control force is examined for various conditions by numerical analyses. Furthermore, the control law is extended to fit an MDOF structural model, and an application example is shown. The computational results show that the NMW control force efficiently reduces structural responses. Copyright © 2000 John Wiley & Sons, Ltd.     

Evaluation of out‐of‐plane seismic performance of column‐to‐column precast concrete cladding panels in one‐storey industrial buildings

Recent earthquakes in Italy (L'Aquila 2009 and Emilia 2012) highlighted the vulnerability of precast cladding panels, typically associated with a connection system not designed to account for displacement and rotation compatibility between the panels and the supporting structure. Experimental investigations were performed in the past to investigate the in‐plane performance of cladding panels and design recommendations have been made accordingly; however, in the case of out‐of‐plane seismic loads, the load demand is commonly evaluated in the design practice by means of formulations for nonstructural components. This paper summarizes the results obtained from parametric analyses conducted to estimate the out‐of‐plane load demand in column‐to‐column cladding panels typical of one‐storey commercial and industrial buildings. Empirical equations suitable for both new and existing panels are proposed and compared with the design equations given in Eurocode 8 and ASCE 7. The paper also considers the effects of the development of plastic hinges at the column base and of the roof flexibility on the load demand in panel‐to‐column connections. The roof flexibility may generate the torsion of the panels; consequently, an analytical procedure to account for such effects is proposed. Finally, general design recommendations are made.     

Closed‐form aftershock reliability of damage‐cumulating elastic‐perfectly‐plastic systems

Major earthquakes (i.e., mainshocks) typically trigger a sequence of lower magnitude events clustered both in time and space. Recent advances of seismic hazard analysis stochastically model aftershock occurrence (given the main event) as a nonhomogeneous Poisson process with rate that decays in time as a negative power law. Risk management in the post‐event emergency phase has to deal with this short‐term seismicity. In fact, because the structural systems of interest might have suffered some damage in the mainshock, possibly worsened by damaging aftershocks, the failure risk may be large until the intensity of the sequence reduces or the structure is repaired. At the state‐of‐the‐art, the quantitative assessment of aftershock risk is aimed at building tagging, that is, to regulate occupancy. The study, on the basis of age‐dependent stochastic processes, derived closed‐form approximations for the aftershock reliability of simple nonevolutionary elastic‐perfectly‐plastic damage‐cumulating systems, conditional on different information about the structure. Results show that, in the case hypotheses apply, the developed models may represent a basis for handy tools enabling risk‐informed tagging by stakeholders and decision makers. Copyright © 2013 John Wiley & Sons, Ltd.     

Least‐squares reverse‐time migration in a matrix‐based formulation

This paper describes least‐squares reverse‐time migration. The method provides the exact adjoint operator pair for solving the linear inverse problem, thereby enhancing the convergence of gradient‐based iterative linear inversion methods. In this formulation, modified source wavelets are used to correct the source signature imprint in the predicted data. Moreover, a roughness constraint is applied to stabilise the inversion and reduce high‐wavenumber artefacts. It is also shown that least‐squares migration implicitly applies a deconvolution imaging condition. Three numerical experiments illustrate that this method is able to produce seismic reflectivity images with higher resolution, more accurate amplitudes, and fewer artefacts than conventional reverse‐time migration. The methodology is currently feasible in 2‐D and can naturally be extended to 3‐D when computational resources become more powerful.     

Out‐of‐plane effects in 2D borehole‐to‐surface resistivity tomography and applications in mineral exploration

In this paper, we discuss the effects of anomalous out‐of‐plane bodies in two‐dimensional (2D) borehole‐to‐surface electrical resistivity tomography with numerical resistivity modelling and synthetic inversion tests. The results of the two groups of synthetic resistivity model tests illustrate that anomalous bodies out of the plane of interest have an effect on two‐dimensional inversion and that the degree of influence of out‐of‐plane body on inverted images varies. The different influences are derived from two cases. One case is different resistivity models with the same electrode array, and the other case is the same resistivity model with different electrode arrays. Qualitative interpretation based on the inversion tests shows that we cannot find a reasonable electrode array to determine the best inverse solution and reveal the subsurface resistivity distribution for all types of geoelectrical models. Because of the three‐dimensional effect arising from neighbouring anomalous bodies, the qualitative interpretation of inverted images from the two‐dimensional inversion of electrical resistivity tomography data without prior information can be misleading. Two‐dimensional inversion with drilling data can decrease the three‐dimensional effect. We employed two‐ and three‐dimensional borehole‐to‐surface electrical resistivity tomography methods with a pole–pole array and a bipole–bipole array for mineral exploration at Abag Banner and Hexigten Banner in Inner Mongolia, China. Different inverse schemes were carried out for different cases. The subsurface resistivity distribution obtained from the two‐dimensional inversion of the field electrical resistivity tomography data with sufficient prior information, such as drilling data and other non‐electrical data, can better describe the actual geological situation. When there is not enough prior information to carry out constrained two‐dimensional inversion, the three‐dimensional electrical resistivity tomography survey is the better choice.     

Kinematic characteristics and the influence of reference velocities of phase‐shift‐plus‐interpolation and extended‐split‐step‐Fourier migration methods

The phase‐shift‐plus‐interpolation and extended‐split‐step‐Fourier methods are wavefield‐continuation algorithms for seismic migration imaging. These two methods can be applied to regions with complex geological structures. Based on their unified separable formulas, we show that these two methods have the same kinematic characteristics by using the theory of pseudodifferential operators. Numerical tests on a Marmousi model demonstrate this conclusion. Another important aspect of these two methods is the selection of reference velocities and we explore the influence of the selection of reference velocities by comparing the geometric progression method and the statistical method. We show that the geometric progression method is simple but does not take into account the velocity distribution while the statistical approach is relatively complex but reflects the velocity distribution.     

Full waveform inversion of SH‐ and Love‐wave data in near‐surface prospecting

We develop a two‐dimensional full waveform inversion approach for the simultaneous determination of S‐wave velocity and density models from SH ‐ and Love‐wave data. We illustrate the advantages of the SH/Love full waveform inversion with a simple synthetic example and demonstrate the method's applicability to a near‐surface dataset, recorded in the village ?achtice in Northwestern Slovakia. Goal of the survey was to map remains of historical building foundations in a highly heterogeneous subsurface. The seismic survey comprises two parallel SH‐profiles with maximum offsets of 24 m and covers a frequency range from 5 Hz to 80 Hz with high signal‐to‐noise ratio well suited for full waveform inversion. Using the Wiechert–Herglotz method, we determined a one‐dimensional gradient velocity model as a starting model for full waveform inversion. The two‐dimensional waveform inversion approach uses the global correlation norm as objective function in combination with a sequential inversion of low‐pass filtered field data. This mitigates the non‐linearity of the multi‐parameter inverse problem. Test computations show that the influence of visco‐elastic effects on the waveform inversion result is rather small. Further tests using a mono‐parameter shear modulus inversion reveal that the inversion of the density model has no significant impact on the final data fit. The final full waveform inversion S‐wave velocity and density models show a prominent low‐velocity weathering layer. Below this layer, the subsurface is highly heterogeneous. Minimum anomaly sizes correspond to approximately half of the dominant Love‐wavelength. The results demonstrate the ability of two‐dimensional SH waveform inversion to image shallow small‐scale soil structure. However, they do not show any evidence of foundation walls.     

Nested‐Scale Nutrient Flux in a Mixed‐Land‐Use Urbanizing Watershed

To improve quantitative understanding of mixed‐land‐use impacts on nutrient yields, a nested‐scale experimental watershed study design (n = 5) was applied in a 303(d), clean water act impaired urbanizing watershed of the lower Missouri River Basin, USA. From 2010 to 2013, water samples (n = 858 sample days per site) were analysed for total inorganic nitrogen (TIN‐N), nitrite (NO₂–N) nitrate (NO₃–N), ammonia (NH₃–N), and total phosphorus (TP‐P). Annual, seasonal, and monthly flow‐weighted concentrations (FWCs) and nutrient yields were estimated. Mean nutrient concentrations were highest where agricultural land use comprised 58% of the drainage area (NH₃ = 0.111 mg/l; NO₂ = 0.045 mg/l; NO₃ = 0.684 mg/l, TIN = 0.840 mg/l; TP = 0.127 mg/l). Average TP‐P increased by 15% with 20% increased urban land use area. Highly variable annual precipitation was observed during the study with highest nutrient yields during 2010 (record setting wet year) and lowest nutrient yields during 2012 (extreme drought year). Annual TIN‐N and TP‐P yields exceeded 10.3 and 2.04 kg ha^?1 yr^?1 from the agricultural dominated headwaters. Mean annual NH₃–N, NO₂–N, NO₃–N, TIN‐N, and TP‐P yields were 0.742, 0.400, 4.24, 5.38, and 0.979 kg ha^?1 yr^?1, respectively near the watershed outlet. Precipitation accounted for the majority of the explained variance in nutrient yields (R² values from 0.68 to 0.85). Nutrient yields were also dependent on annual precipitation of the preceding year (R² values from 0.87 to 0.91) thus enforcing the great complexity of variable mixed‐land‐use mediated source‐sink nutrient yield relationships. Study results better inform land managers and best management practices designed to mitigate nutrient pollution issues in mixed‐land‐use freshwater ecosystems. Copyright © 2015 John Wiley & Sons, Ltd.     

Multipathing in three‐parameter common‐image gathers from reverse‐time migration

Reverse‐time migration gives high‐quality, complete images by using full‐wave extrapolations. It is thus not subject to important limitations of other migrations that are based on high‐frequency or one‐way approximations. The cross‐correlation imaging condition in two‐dimensional pre‐stack reverse‐time migration of common‐source data explicitly sums the product of the (forward‐propagating) source and (backward‐propagating) receiver wavefields over all image times. The primary contribution at any image point travels a minimum‐time path that has only one (specular) reflection, and it usually corresponds to a local maximum amplitude. All other contributions at the same image point are various types of multipaths, including prismatic multi‐arrivals, free‐surface and internal multiples, converted waves, and all crosstalk noise, which are imaged at later times, and potentially create migration artefacts. A solution that facilitates inclusion of correctly imaged, non‐primary arrivals and removal of the related artefacts, is to save the depth versus incident angle slice at each image time (rather than automatically summing them). This results in a three‐parameter (incident angle, depth, and image time) common‐image volume that integrates, into a single unified representation, attributes that were previously computed by separate processes. The volume can be post‐processed by selecting any desired combination of primary and/or multipath data before stacking over image time. Separate images (with or without artifacts) and various projections can then be produced without having to remigrate the data, providing an efficient tool for optimization of migration images. A numerical example for a simple model shows how primary and prismatic multipath contributions merge into a single incident angle versus image time trajectory. A second example, using synthetic data from the Sigsbee2 model, shows that the contributions to subsalt images of primary and multipath (in this case, turning wave) reflections are different. The primary reflections contain most of the information in regions away from the salt, but both primary and multipath data contribute in the subsalt region.     

Estimation of element‐by‐element demand‐to‐capacity ratios in instrumented SMRF buildings using measured seismic response

This paper presents a methodology to estimate element‐by‐element demand‐to‐capacity ratios in instrumented steel moment‐resisting frames subject to earthquakes. The methodology combines a finite element model and acceleration measurements at various points throughout the building to estimate time history of displacements and internal force demands in all members. The estimated demands and their uncertainty are compared with code‐based capacity from which probabilistic bounds of demand‐to‐capacity ratios are obtained. The proposed methodology is verified using a simulated six‐story building and validated using acceleration data from California Strong Motion Instrumentation Programstation 24370 during the Northridge and Sierra Madre earthquakes.     

Two‐dimensional waveform inversion of multi‐component data in acoustic‐elastic coupled media

In order to account for the effects of elastic wave propagation in marine seismic data, we develop a waveform inversion algorithm for acoustic‐elastic media based on a frequency‐domain finite‐element modelling technique. In our algorithm we minimize residuals using the conjugate gradient method, which back‐propagates the errors using reverse time migration without directly computing the partial derivative wavefields. Unlike a purely acoustic or purely elastic inversion algorithm, the Green's function matrix for our acoustic‐elastic algorithm is asymmetric. We are nonetheless able to achieve computational efficiency using modern numerical methods. Numerical examples show that our coupled inversion algorithm produces better velocity models than a purely acoustic inversion algorithm in a wide variety of cases, including both single‐ and multi‐component data and low‐cut filtered data. We also show that our algorithm performs at least equally well on real field data gathered in the Korean continental shelf.     

Post‐processing of ensemble forecasts in low‐flow period

For water supply, navigational, ecological protection or water quality control purposes, there is a great need in knowing the likelihood of the river level falling below a certain threshold. Ensemble streamflow prediction (ESP) based on simulations of deterministic hydrologic models is widely used to assess this likelihood. Raw ESP results can be biased in both the ensemble means and the spreads. In this study, we applied a modified general linear model post‐processor (GLMPP) to correct these biases. The modified GLMPP is built on the basis of regression of simulated and observed streamflow calculated on the basis of canonical events, instead of the daily values as is carried out in the original GLMPP. We conducted the probabilistic analysis of post‐processed ESP results falling below pre‐specified low‐flow levels at seasonal time scale. Raw ESP forecasts from the 1980 to 2006 periods by four different land surface models (LSMs) in eight large river basins in the continental USA are included in the analysis. The four LSMs are Noah, Mosaic, variable infiltration capacity and Sacramento models. The major results from this study are as follows: (1) a modified GLMPP was proposed on the basis of canonical events; (2) post‐processing can improve the accuracy and reduce the uncertainty of hydrologic forecasts; (3) post‐processing can help deal with the effect of human activity; and (4) raw simulation results from different models vary greatly in different basins. However, post‐processing can always remove model biases under different conditions. Copyright © 2014 John Wiley & Sons, Ltd.     

Tracing variability of run‐off generation in mountainous permafrost of semi‐arid north‐eastern Mongolia

The headwaters of mountainous, discontinuous permafrost regions in north‐eastern Mongolia are important water resources for the semi‐arid country, but little is known about hydrological processes there. Run‐off generation on south‐facing slopes, which are devoid of permafrost, has so far been neglected and is totally unknown for areas that have been affected by recent forest fires. To fill this knowledge gap, the present study applied artificial tracers on a steppe‐vegetated south‐facing and on two north‐facing slopes, burned and unburned. Combined sprinkling and dye tracer experiments were used to visualize processes of infiltration and water fluxes in the unsaturated zone. On the unburned north‐facing slope, rapid and widespread infiltration through a wet organic layer was observed down to the permafrost. On the burned profile, rapid infiltration occurred through a combusted organic and underlying mineral layer. Stained water seeped out at the bottom of both profiles suggesting a general tendency to subsurface stormflow (SSF). Ongoing SSF could directly be studied 24 h after a high‐intensity rainfall event on a 55‐m hillslope section in the burned forest. Measurements of water temperature proved the role of the permafrost layer as a base horizon for SSF. Repeated tracer injections allowed direct insights into SSF dynamics: A first injection suggested rather slow dispersive subsurface flow paths; whereas 18 h later, a second injection traced a more preferential flow system with 20 times quicker flow velocities. We speculate that these pronounced SSF dynamics are limited to burned slopes where a thermally insulating organic layer is absent. On three south‐facing soil profiles, the applied tracer remained in the uppermost 5 cm of a silt‐rich mineral soil horizon. No signs of preferential infiltration could be found, which suggested reduced biological activity under a harsh, dry and cold climate. Instead, direct observations, distributed tracers and charcoal samples provided evidence for the occurrence of overland flow. Copyright © 2014 John Wiley & Sons, Ltd.     

Triangulation hand‐held laser‐scanning (TriHaLaS) for micro‐ and meso‐habitat surveys in streams

A novel hand‐held laser‐based stream bed survey system is presented. The system facilitates the capture of detailed 3D mapping of shallow (< 0.7 m) riverbed topography in sections approximately 4 m by 2 m. The system includes a stationary reference system, which projects three laser sheets (two at offset angles), within which a hand‐held monitoring pole is moved. The unique configuration of the light sheets intercepts with the pole as it moves within the survey area providing an exact horizontal location. Pole tilt is compensated for by an inertial measurement unit on the pole, and the height above the bed of the pole and submerged scanning laser are monitored relative to the horizontal laser sheet. Verification and application measurements demonstrate high resolution and accuracy in the horizontal (~5 mm) and vertical (~1 mm) direction. The system can be applied at sites where a free view is blocked and other optical through‐water methods fail. It is appropriate for studies on riverbed statistics and dynamics, which necessitate non‐invasive in‐situ surveys. Copyright © 2017 John Wiley & Sons, Ltd.     

Spatio‐temporal controls of snowmelt and runoff generation during rain‐on‐snow events in a mid‐latitude mountain catchment

A network of 30 standalone snow monitoring stations was used to investigate the snow cover distribution, snowmelt dynamics, and runoff generation during two rain‐on‐snow (ROS) events in a 40 km² montane catchment in the Black Forest region of southwestern Germany. A multiple linear regression analysis using elevation, aspect, and land cover as predictors for the snow water equivalent (SWE) distribution within the catchment was applied on an hourly basis for two significant ROS flood events that occurred in December 2012. The available snowmelt water, liquid precipitation, as well as the total retention storage of the snow cover were considered in order to estimate the amount of water potentially available for the runoff generation. The study provides a spatially and temporally distributed picture of how the two observed ROS floods developed in the catchment. It became evident that the retention capacity of the snow cover is a crucial mechanism during ROS. It took several hours before water was released from the snowpack during the first ROS event, while retention storage was exceeded within 1 h from the start of the second event. Elevation was the most important terrain feature. South‐facing terrain contributed more water for runoff than north‐facing slopes, and only slightly more runoff was generated at open compared to forested areas. The results highlight the importance of snowmelt together with liquid precipitation for the generation of flood runoff during ROS and the large temporal and spatial variability of the relevant processes. Copyright © 2015 John Wiley & Sons, Ltd.     

Simulating saturation‐excess surface run‐off in a semi‐distributed hydrological model

The level of complexity, and the number of parameters, to include in a hydrological model is a relatively contentious issue in hydrological modelling. However, it can be argued that explicitly representing important run‐off generation processes can improve the practical value of a model's outputs. This paper explores the benefits of including a new function into an existing semi‐distributed hydrological model (the Pitman model) that is widely used in the sub‐Saharan Africa region. The new function was designed to represent saturation‐excess surface run‐off processes at subcatchment scales and was motivated by the evidence of dambo (low topography riparian areas) type features in many sub‐Saharan river basins. The results for uncertainty versions of the model, with and without the new function, were compared for 25 catchments, which were divided up into those where evidence of dambos exists and those where there is no such evidence. The results suggest that the new function certainly improves the model results for the catchments where dambos exist, but not in situations where saturation‐excess surface run‐off is not expected to occur. The overall conclusion is therefore that the addition of the new function is justified.     

Validation of (not‐historical) large‐event near‐fault ground‐motion simulations for use in civil engineering applications

Ground‐motion simulations generated from physics‐based wave propagation models are gaining increasing interest in the engineering community for their potential to inform the performance‐based design and assessment of infrastructure residing in active seismic areas. A key prerequisite before the ground‐motion simulations can be used with confidence for application in engineering domains is their comprehensive and rigorous investigation and validation. This article provides a four‐step methodology and acceptance criteria to assess the reliability of simulated ground motions of not historical events, which includes (1) the selection of a population of real records consistent with the simulated scenarios, (2) the comparison of the distribution of Intensity Measures (IMs) from the simulated records, real records, and Ground‐Motion Prediction Equations (GMPEs), (3) the comparison of the distribution of simple proxies for building response, and (4) the comparison of the distribution of Engineering Demand Parameters (EDPs) for a realistic model of a structure. Specific focus is laid on near‐field ground motions (<10km) from large earthquakes (M_w7), for which the database of real records for potential use in engineering applications is severely limited. The methodology is demonstrated through comparison of (2490) near‐field synthetic records with 5 Hz resolution generated from the Pitarka et al (2019) kinematic rupture model with a population of (38) pulse‐like near‐field real records from multiple events and, when applicable, with NGA‐W2 GMPEs. The proposed procedure provides an effective method for informing and advancing the science needed to generate realistic ground‐motion simulations, and for building confidence in their use in engineering domains.     

Catchment area‐based evaluation of the AMC‐dependent SCS‐CN‐based rainfall–runoff models

Using a large set of rainfall–runoff data from 234 watersheds in the USA, a catchment area‐based evaluation of the modified version of the Mishra and Singh (2002a) model was performed. The model is based on the Soil Conservation Service Curve Number (SCS‐CN) methodology and incorporates the antecedent moisture in computation of direct surface runoff. Comparison with the existing SCS‐CN method showed that the modified version performed better than did the existing one on the data of all seven area‐based groups of watersheds ranging from 0·01 to 310·3 km². Copyright © 2005 John Wiley & Sons, Ltd.