Cadmium,zinc, copper,and barium in foraminifera tests

The concentrations of cadmium, zinc, copper and barium have been determined on 2-mg samples of single-species foraminifera populations. Cleaning techniques were tested using North Atlantic core tops, and followed by a detailed downcore study for the last 30,000 years in South Atlantic core V22-174. Raw foram tests cleaned by crushing followed by ultrasonic removal of fine-grained material, and dissolved in a pH 5.5 acetate buffer, contain appreciable amounts of trace elements associated with ferromanganese and alumino-silicate contaminants. A reductive/complexing cleaning treatment reduces ferromanganese contamination by 1–2 orders of magnitude. Acetate buffers at pH 5.5 complex iron and raise the solubility of ferromanganese oxides; these buffers are unsuitable for separating carbonate lattice-bound trace elements from the fraction associated with ferromanganese phases. Improved mechanical and ultrasonic reductive cleaning combined with a mild dissolution in distilled water under 1 atm.P_CO2 reduces contaminant levels another order of magnitude. The Cd and Zn concentrations (order 10^?8 mole Cd/mole Ca and 10^?5 mole Zn/mole Ca) of species with low surface area show an increase with decreasing isotopic temperatures. This increase is consistent with the increasing concentrations of these metals from low values in surface waters to higher values at depth. The variance of Cd and Zn over the last 30,000 years in the central South Atlantic is consistent with the probable variability of the dissolved trace elements at the calcification levels of the species analyzed. Cu and Ba are irreproducible and probably sensitive to residual contaminant phases. The trace element content of the tests differs from levels observed in a recent coprecipitation study. Foraminifera may be a significant vector in zinc cycling in the ocean.     

Deterministic signals in precipitation in Arkansas,Louisiana, and Mississippi

Evidence for a signal near 19 years is found in 51 out of 65 rain gauge records in the tri-state region of Arkansas, Louisiana, and Mississippi, While another term with period 10 to 11 years is found in 39 instances. These are identified as the 18.6-year luni-solarM _n and solar cycleS _c signals in climate variability. In terms of both amplitude and phase the luni-solar wave trains are highly nonstationary; in particular, the waves commonly change phase by 180°. Examples of theM _n andS _c terms in corn yield for Arkansas and Missouri are presented, and the implications for economic science briefly discussed.     

2006年台湾屏东海外7.2级地震前福建漳州汰内井水氡异常分析

通过对福建华安县汰内井2005年以来的水氡测值进行分析,提取了中期及短期异常,认为这些异常与2006年12月26日台湾屏东海外7.2级地震有关。     

Streamflow generation in semi-arid,glacier-covered,montane catchments in the upper Shule River,Qilian Mountains,northeastern Tibetan plateau

Streamflow generation was investigated using isotopic and geochemical tracers in semiarid, glacier-covered, montane catchments in the upper Shule River, northeastern Tibetan Plateau. Samples from stream water, precipitation, glacier meltwater, and groundwater were collected at the Suli and Gahe catchments along the Shule River, with an area of 1908 and 4210 km², respectively. The samples were analysed for stable isotopes of water and major ions. Results of diagnostic tools of mixing models showed that Ca²⁺, Mg²⁺ and Cl⁻, along with δ¹⁸O and δ²H, behaved conservatively as a result of mixing of three endmembers. The three endmembers identified by the mixing analysis were surface runoff directly from precipitation, groundwater, and glacier meltwater. Streamflow was dominated by groundwater, accounting for 59% and 60% of streamflow on average in the Suli and Gahe catchments, respectively, with minimum groundwater contribution in July (47% and 50%) and maximum contribution in October (69% and 70%). The contributions of surface runoff were slightly higher in the Suli catchment (25%) than in the Gahe catchment (19%). However, the contributions of glacier meltwater were higher in the Gahe catchment (21%) compared to the Suli catchment (17%), as a result of a higher percentage of glacier covered area in the Gahe catchment. This difference followed well the non-linear power–law trend of many glacier-covered catchments around the world. As glacier retreat continues in the future, the reduction of streamflow in glacier-covered upper Shule catchment likely will be accelerated and possibly elsewhere in the Tibetan Plateau. This study suggests that it is critical to define the turning point of an accelerated reduction in glacier meltwater for glacier-covered catchments around the world in order to better assess and manage water resources.     

Deccan plume,lithosphere rifting,and volcanism in Kutch,India

Kutch (northwest India) experienced lithospheric thinning due to rifting and tholeiitic and alkalic volcanism related to the Deccan Traps K/T boundary event. Alkalic lavas, containing mantle xenoliths, form plug-like bodies that are aligned along broadly east–west rift faults. The mantle xenoliths are dominantly spinel wehrlite with fewer spinel lherzolite. Wehrlites are inferred to have formed by reaction between transient carbonatite melts and lherzolite forming the lithosphere. The alkalic lavas are primitive (Mg# = 64–72) relative to the tholeiites (Mg# = 38–54), and are enriched in incompatible trace elements. Isotope and trace element compositions of the tholeiites are similar to what are believed to be the crustally contaminated Deccan tholeiites from elsewhere in India. In terms of Hf, Nd, Sr, and Pb isotope ratios, all except two alkalic basalts plot in a tight cluster that largely overlap the Indian Ridge basalts and only slightly overlap the field of Reunion lavas. This suggests that the alkalic magmas came largely from the asthenosphere mixed with Reunion-like source that welled up beneath the rifted lithosphere. The two alkalic outliers have an affinity toward Group I kimberlites and may have come from an old enriched (metasomatized) asthenosphere. We present a new model for the metasomatism and rifting of the Kutch lithosphere, and magma generation from a CO₂-rich lherzolite mantle. In this model the earliest melts are carbonatite, which locally metasomatized the lithosphere. Further partial melting of CO₂-rich lherzolite at about 2–2.5 GPa from a mixed source of asthenosphere and Reunion-like plume material produced the alkalic melts. Such melts ascended along deep lithospheric rift faults, while devolatilizing and exploding their way up through the lithosphere. Tholeiites may have been generated from the main plume head further south of Kutch.     

Geophysical-Archaeological Survey in Lake Tequesquitengo,Morelos, Mexico

In August 2009, a marine geophysical survey was conducted in Lake Tequesquitengo (located in the state of Morelos, Mexico) to delineate the extent of the remains of a small town that has been submerged since the mid 19th century. The survey consists of the acquisition and mapping of magnetic, single beam bathymetric and side-scan sonar data. A dual receiver marine GPS navigation system was used to position the boat during the survey. Except for the larger structural remains that are visible on the side scan sonar images, the magnetic anomaly map proved to be most useful in delineating the extent of the town. These anomalies exhibit short wavelength components in the area surrounding a submerged church, with the shortest wavelength components being confined to the area immediately east of the church. These short wavelength components are only observed near the church; therefore, we propose that they delineate the buried remnants of the submerged town.     

Arsenic, cadmium, lead and mercury in canned sardines commercially available in eastern Kentucky, USA

Seventeen samples of canned sardines, originating from six countries and sold in eastern Kentucky, USA, were analyzed in composites of 3-4 fish each for total arsenic (As), cadmium (Cd) and lead (Pb) by graphite furnace atomic absorption spectrophotometry (AAS) and for mercury (Hg) by thermal decomposition amalgamation and AAS. Results in μg/g wet: As 0.49-1.87 (mean: 1.06), Cd < 0.01-0.07 (0.03), Pb < 0.06-0.27 (0.11), Hg ND < 0.09. Values fall generally within readings reported by others, but no internationally agreed upon guidelines have yet been set for As or Cd in canned or fresh fish. The incidence of cancers and cardiovascular diseases associated with As ingestion is extraordinarily high here. With the role of food-borne As in human illness presently under scrutiny and its maximum allowable limits in fish being reviewed, more studies of this nature are recommended, especially considering the potential importance of small pelagic fishes as future seafood of choice.     

Microbial carbonates in Holocene beachrocks,Shuiweiling, Luhuitou Peninsula,Hainan Island

Two research methods, geomicrobiology and carbonate sedimentology, were adopted to study the microbial carbonates in the beachrocks, Shuiweiling, Luhuitou, Sanya City, Hainan Island. The results indicate that microbial carbonates occur in Shuiweiling beachrocks and cements related to microbial activitives are common. Microbial carbonates were mainly developed on the surfaces of coral skeletons and within the coral (fragments and shivers) skeletal cavities,and rarely grew in interspaces formed by coral and other biological detritus. The growth morphologies of microbial carbonates are various, including stromatolitic lamination, thin crusts, dome-like, and microbialites. Microbial carbonates commonly trap fine-sized bioclasts, contain tubular filaments, and show laminated growth striation. Microbial carbonates within the coral skeletal cavities are generally stromatolitic cone-shaped, with a random growth direction along the bearing of trend of cavities, showing distinct growth laminae and recognizable growth phases. It is a special growth pattern of crypt microbial carbonates. Microbial cements occur mainly in shape of needle cement, calcified filaments, microborings, and calcified framboidal spheres. The needle cement is the most common type. These microbial cements indicate that microbial activities and microbial carbonates played an important role in beachrock formation in which carbonates were dominant components and the climate of tropical ocean monsoon was influential. Such microbial carbonates and microbial cementation have not been reported here from beachrocks along the northern shorelines of the South China Sea. The results support a clear microbial origin for certain carbonate cements in beachrocks, confirm that microbial carbonates are a significant contributor to carbonate sedimentation, and widen the knowledge of beachrocks from a new field.     

云南洱海现代沉积研究

洱海是位于云南省境内较大的但相对较浅的断陷湖泊（水深小于２０ｍ）。根据１９９０－１９９３年对该湖现代沉积的研究,结果表明,湖泊沉积物主要是来自西部相对高２０００ｍ以上的山地,东部为低矮石灰岩山地,物源较少,南北两条入湖河流亦是重要的物源供应区。湖区沉积物主要是由粉砂质粘土组成,来自山地的粗碎屑物质则大量的堆积于此地,三角洲、扇三角洲及滨湖地带,沉积速度在过去１３０００年中平均为０．２ｃｍａ＾－１,     

Complexity,magnetic field topology,criticality, and metastability in magnetotail dynamics

Recently, it has been shown that certain features of magnetotail dynamics in response to solar wind changes may resemble the behavior of a complex system near a dynamical critical state (Chang, Phys. Plasmas 6 (1999) 4137; Consolini and Chang, Space Sci. Rev. 95 (2001) 309), and of topological phase transitions (Chang, Phys. Scr. (2001), 80). Moreover, the impulsive part of the magnetotail response seems to be well described by cellular automata and other simulation models displaying criticality.Here, the relevance of the magnetic field topological disorder will be discussed in connection with observed complexity and near-criticality, showing how the impulsive character of the magnetotail response could be viewed as fluctuation-induced topological transitions among metastable configurations of magnetic field topology.     

Eutrophication and hypoxia in four streams discharging in Guanabara Bay, RJ, Brazil, a case study

Four streams in the city of São Gonçalo, were sampled to evaluate their potential as sources of nutrients to Guanabara Bay aiming to contribute with the government program to decrease the levels of pollution in this area. Imbuaçu, Guaxindiba, Marimbondo and Brandoas streams were sampled in 2007, 2008 and 2009. The streams revealed to be hipereutrophic with severe limitation of primary production by nitrogen, as shown by the N/P molar ratio. Phosphate levels were abnormally high varying between 4.35 and 130.82 μM, whereas nitrate and nitrite ranged from 0.06 to 54.05 μM and from 0.28 to 19.23 μM, respectively. The streams also presented severe hypoxia and anoxia, with oxygen values varying from non-detected to 3.72 ml l⁻¹. Heavy loads of particulate suspended material were recorded in the studied streams, ranging between 6.00 and 400.00 mg l⁻¹. The streams were considered inexorable sources of nutrients, enhancing the severe eutrophication process in Guanabara Bay.     

Nutrient flux, uptake, and transformation in a spring-fed stream in the Missouri Ozarks, USA

We examined nutrient flux, uptake, and transformation along a spring-fed stream in the Ozark region of Missouri, USA, over the year 2006. Water in Mill Creek originates from several springs, with a single spring contributing over 90% of the stream discharge during much of the year of study. Soluble reactive phosphate concentrations were usually low (<10 μg L⁻¹) along Mill Creek, but peaked during high discharge. Concentrations of dissolved inorganic nitrogen (DIN) were relatively high in the spring water, mainly as nitrate, but usually declined across a small pond and the 10-km length of Mill Creek. During low flows in summer and early autumn, the stream removed over 300 μg L⁻¹ of DIN over its 10-km length, or about 80% of the initial amount. DIN retention along the stream, as a percentage of the DIN upstream, was related mainly to discharge, with higher flows having much higher DIN concentrations. The net uptake rate of DIN uptake was 0.91 μg m⁻² s⁻¹ in the stream during summer baseflow. The uptake rate declined downstream for different reaches and was closely related to DIN concentration. In experimental channels, uptake by epilithic algae was one significant sink for nitrate-N in Mill Creek. In 2006, inorganic nutrient export during a single day after a spring storm was similar to export during 40–100 days of low flow conditions in summer and early autumn. Our results suggest that significant nutrient retention can occur during baseflow periods via biological uptake, whereas substantial export occurs during high flow conditions.     

Macroalgal mats in Langstone Harbour,Hampshire, England

The spread of green algae over mudflats in Langstone Harbour has been caused by increased discharges of both treated and untreated sewage effluent. The decline in some species of estuarine birds may be a secondary effect of the blanketing of the muds by algae, but Soulsby et al. concluded that the evidence for a causal link was inconclusive. This note examines the points they put forward in support of this.     

A once-molten,coarse-grained,Ca-rich inclusion in Allende

A compact, spheroidal Type B inclusion in Allende contains melilite laths that project radially inward from the inclusion edge which show interference growth textures. The combined textural and chemical features of this object cannot be explained by independent vapor-solid condensation of grains in space, followed by random aggregation of these grains into an inclusion. Rather, it probably formed from a once-molten droplet that crystallized in response to radiative cooling from its outer surface. The crystallization sequence in this and another similar inclusion in which oxygen isotopes have been measured is: melilite-spinel-anorthite-fassaite. This sequence supports the idea that oxygen isotopic heterogeneities in coarse-grained inclusions were formed after complete solidification of these objects by partial exchange with a less¹⁶O-rich gas, and not during or before a melting event.     

Turbulence,entrainment, and mixing in cloud dynamics

The various models that have been proposed for describing the dynamical development of small cumuli are discussed in terms of how well they predict the observed distribution of liquid water. The entrainment concept is examined and shown to involve contradictions when applied to growing blobs. An alternative process is offered in which the dominating factor in the cloud dynamics is the mixing in of drier overlying air down through the cloud until temporary static equilibrium is established. Consideration of the mixing process and calculations of the required dilution show this process can lead to the observed liquid water distributions.     

Porosity, permeability, and fluid flow in the Yellowstone geothermal system, Wyoming

Cores from two of 13 U.S. Geological Survey research holes at Yellowstone National Park (Y-5 and Y-8) were evaluated to characterize lithology, texture, alteration, and the degree and nature of fracturing and veining. Porosity and matrix permeability measurements and petrographic examination of the cores were used to evaluate the effects of lithology and hydrothermal alteration on porosity and permeability. The intervals studied in these two core holes span the conductive zone and the upper portion of the convective geothermal reservoir. Variations in porosity and matrix permeability observed in the Y-5 and Y-8 cores are primarily controlled by lithology. Y-8 intersects three distinct lithologies: volcaniclastic sandstone, perlitic rhyolitic lava, and non-welded pumiceous ash-flow tuff. The sandstone typically has high permeability and porosity, and the tuff has very high porosity and moderate permeability, while the perlitic lava has very low porosity and is essentially impermeable. Hydrothermal self-sealing appears to have generated localized permeability barriers within the reservoir. Changes in pressure and temperature in Y-8 correspond to a zone of silicification in the volcaniclastic sandstone just above the contact with the perlitic rhyolite; this silicification has significantly reduced porosity and permeability. In rocks with inherently low matrix permeability (such as densely welded ash-flow tuff), fluid flow is controlled by the fracture network. The Y-5 core hole penetrates a thick intracaldera section of the 0.6-Ma Lava Creek ash-flow tuff. In this core, the degree of welding appears to be responsible for most of the variations in porosity, matrix permeability, and the frequency of fractures and veins. Fractures are most abundant within the more densely welded sections of the tuff. However, the most prominent zones of fracturing and mineralization are associated with hydrothermal breccias within densely welded portions of the tuff. These breccia zones represent transient conduits of high fluid flow that formed by the explosive release of overpressure in the underlying geothermal reservoir and that were subsequently sealed by supersaturated geothermal fluids. In addition to this fracture sealing, hydrothermal alteration at Yellowstone appears generally to reduce matrix permeability and focus flow along fractures, where multiple pulses of fluid flow and self-sealing have occurred.     

Chalcophile elements (Hg,Cd, Pb,As) in Lake Umbozero,Murmansk province

Lake Umbozero (the second largest in the area and the deepest in Murmansk province) was studied with the aim to establish the biogeochemical features of the distribution of chalcophile elements (Hg, Cd, Pb, As) in water, bottom sediments, and whitefish organs and tissues. Lake Umbozero is subject to the effect of emissions and effluents of mining-and-metallurgical plants in Murmansk province, as well as airborne anthropogenic pollution of global character. Surface and near-bed peaks were recorded in the distribution of Pb and Cd in water mass. Those peaks can be due to phytoplankton development in surface layers and the precipitation of dead organisms and mechanical suspension into bed layers. The mean Pb and Cd concentrations in Umbozero water mass exceed the mean for lake water in taiga zone. Water body pollution manifests itself in an increase in concentrations of elements, such as heavy metals, in the surface layers of bottom sediments. The largest contamination factors were recorded for Cd and Pb. Lake pollution by highly toxic chalcophile elements also caused their accumulation in whitefish organs and tissues: the biological accumulation coefficient is >1 for Cd in kidneys (5.8) and for Hg in kidneys, liver, and muscles (3.6, 3.3, and 2.2, respectively).