Adsorption of Two Taste and Odor Compounds IPMP and IBMP by Granular Activated Carbon in Water

Granular activated carbon (GAC) adsorption of two representative taste and odor (T & O) compounds, 2‐isopropyl‐3‐methoxy pyrazine (IPMP), and 2‐isobutyl‐3‐methoxy pyrazine (IBMP), in drinking water was investigated. Results show that the modified Freundlich equation best fit the experimental data during the adsorption isotherm tests, and the pseudo first‐order kinetics and intra‐particle diffusion kinetics well described the adsorption kinetics pattern. The calculated thermodynamic parameters (ΔH⁰, ΔS⁰, and ΔG⁰) indicated a spontaneous and endothermic adsorption process. Factors affecting the treatment efficiency were carefully evaluated. Acidic and alkaline conditions both favored GAC adsorption of IPMP and IBMP, especially the former. With the GAC dosage increasing, the first order adsorption rates increased, while the intra‐particle adsorption rates decreased. Within 12 h, 200 mg/L GAC could remove >90% of 150 µg/L IPMP and IBMP via adsorption at pH 3–11. Therefore, GAC is a promising treatment technology to control the T & O compounds associated water pollution.     

Transient three‐dimensional‐patterned ripples appear during deformation of a two‐dimensional ripple field under wave‐induced oscillatory flow

Wave‐flume experiments on the process of deformation of pre‐existing two‐dimensional ripples revealed that one of two distinct types of three‐dimensional patterned ripple, the rhombic or the barrel type, emerged in the early stages of the experimental runs. Rhombic‐type ripples were characterized by a staggered pattern of similar‐sized mounds, whereas the barrel‐type ripples had a barrel‐like plan shape arranged in echelons. The former ripples were formed under strongly asymmetrical flow conditions with large excursion distances of water particle motion near the pre‐existing rippled bed, whereas the latter were formed under relatively symmetrical flow conditions with small excursion distances. The emergence of both types of ripples was also highly dependent on sediment grain size. Copyright © 2009 John Wiley & Sons, Ltd.     

Wavefield interpolation in 3D large‐step Fourier wavefield extrapolation

Extrapolating wavefields and imaging at each depth during three‐dimensional recursive wave‐equation migration is a time‐consuming endeavor. For efficiency, most commercial techniques extrapolate wavefields through thick slabs followed by wavefield interpolation within each thick slab. In this article, we develop this strategy by associating more efficient interpolators with a Fourier‐transform‐related wavefield extrapolation method. First, we formulate a three‐dimensional first‐order separation‐of‐variables screen propagator for large‐step wavefield extrapolation, which allows for wide‐angle propagations in highly contrasting media. This propagator significantly improves the performance of the split‐step Fourier method in dealing with significant lateral heterogeneities at the cost of only one more fast Fourier transform in each thick slab. We then extend the two‐dimensional Kirchhoff and Born–Kirchhoff local wavefield interpolators to three‐dimensional cases for each slab. The three‐dimensional Kirchhoff interpolator is based on the traditional Kirchhoff formula and applies to moderate lateral velocity variations, whereas the three‐dimensional Born–Kirchhoff interpolator is derived from the Lippmann–Schwinger integral equation under the Born approximation and is adapted to highly laterally varying media. Numerical examples on the three‐dimensional salt model of the Society of Exploration Geophysicists/European Association of Geoscientists demonstrate that three‐dimensional first‐order separation‐of‐variables screen propagator Born–Kirchhoff depth migration using thick‐slab wavefield extrapolation plus thin‐slab interpolation tolerates a considerable depth‐step size of up to 72 ms, eventually resulting in an efficiency improvement of nearly 80% without obvious loss of imaging accuracy. Although the proposed three‐dimensional interpolators are presented with one‐way Fourier extrapolation methods, they can be extended for applications to general migration methods.     

Determination of radionuclides in water at uranium mining remediation – a comparison of analytical methods

The corporate purpose of Wismut GmbH is to decommission its former mining holdings and to rehabilitate the landscape and the environment. Sample taking and analysing the value of contaminants are necessary steps for the remediation of waste rock piles, the recycling of contaminated areas, controlled flooding of uranium mines. Main emphasis lies on the determination of heavy metals and radionuclides of natural decay chains of U‐238 and U‐235. Yearly about 60 000…70 000 determinations of radionuclides in waters were done. Facing this high output of determinations it is a permanent task for laboratory and quality management to ask: Are the results of different methods comparable to each other? Is there a preferred analytical technology? Which matrix influences exist? and What about the analytical costs? Answers to these important questions are given in this report. Summarizing our investigations done in the last few years it is possible to say that – by using different analytical methods the results of radionuclides in water samples (surface or groundwater) are comparable, – a not negligible influence of Ra‐223, Ra‐224 and Ra‐228 may exist by using the DIN 38404 C18 method to determine Ra‐226, – a preferred method cannot be defined, – the choice of the analytical method should include analytical questions (the sample matrix, the occurrence of other disturbing radionuclides, the necessary detection limit) and economical questions (costs, other parameters to be determined).     

Influence of Culture Conditions on Poly‐3‐Hydroxybutyrate Production by a Newly Isolated Bacillus cereus Y23

Polyhydroxyalkanoates (PHAs), environmental friendly polyesters, can be produced by a wide range of microorganisms in nutrient‐limiting conditions. In the present study a new bacterial strain, able to produce high quantities of poly‐3‐hydroxybutyrate (PHB), is isolated from contaminated soil. The isolate is characterized and identified as Bacillus cereus Y23, based on morphological, physiological characteristics, and 16S ribosomal RNA gene sequences. PHB production is evaluated using different carbon and nitrogen sources and nutritional and culture conditions are optimized. The highest PHB production of 5.12 g L^?1 was obtained in growth medium containing fructose and ammonium sulfate at a C/N ratio of 30, 0.3% yeast extract, 4.5 g L^?1 phosphate solution, pH 7, inoculum size of 0.3%, and agitation rate of 150 rpm after 48 h of incubation at 32 °C. The PHB production decrement can be attributed to the intracellular utilization of the polymer during the stationary phase of the cellular growth and to the sporulation process. The presence of the main functional groups of PHB polymer is verified by Fourier‐transform infrared analysis. At optimum conditions, B. cereus Y23 turned out to be a good candidate for industrial production of PHB since it accumulates up to 67.9% of its dry weight.     

Evaluating hydrologic effects of spatial and temporal patterns of forest canopy change using numerical modelling

Although hydrologic responses to land cover changes are often studied using a paired watershed approach, it is not feasible to assess the hydrological effects of many different patterns of land cover alteration by empirical studies alone. An alternative is to use well validated, spatially explicit, physically based numerical models to estimate watershed storage and flux dynamics. The objectives of this study were to assess the sensitivity of watershed flow regimes to several spatial and temporal patterns of forest harvest and recovery in a snow‐dominated mountain watershed. The Distributed Hydrology Soil‐Vegetation Model (DHSVM) was parameterized using 1998–2007 climate data for the 28‐km² Mica Creek Experimental Watershed (MCEW), a headwater catchment in the inland Pacific Northwest. The modelling experiment indicated that clear‐cutting the entire watershed would increase runoff volume by 79% and 5^th percentile flows by 68%. Hydrologic recovery resulting from forest regeneration after clear‐cut harvesting is expected to take up to 25 years to return to baseline conditions, and 50 years to fully recover to preharvest conditions. A more realistic harvesting scenario where the watershed was gradually harvested in a series of clear‐cut blocks allowing for subsequent regeneration to occur was also assessed. This approach reduced the magnitude of hydrologic alteration. Analysis of several other scenarios, defined by aspect, elevation, and distance to the stream network, revealed that flow regime was more sensitive to the amount of alteration rather than pattern and landscape position of disturbance. Copyright © 2015 John Wiley & Sons, Ltd.     

Degradation of Reactive Brilliant Red X‐3B Dye by Microwave Electrodeless UV Irradiation

Degradations of reactive brilliant red X‐3B solution by both conventional UV irradiation and microwave electrodeless UV irradiation were investigated. Degradation processes were studied by UV–VIS spectrophotometry, total organic carbon (TOC), high performance capillary electrophoresis (HPCE), conductivity, pH value, and ion chromatography. The results of color removal (%) and TOC removal (%) showed that the degradation by microwave electrodeless UV irradiation was more effective than by conventional UV irradiation. The results of UV–VIS absorption spectra and HPCE analyses indicated that the degradation of reactive brilliant red X‐3B was occurred at the conjugation system first, the benzene ring and the naphthalene ring later. The reactive brilliant red X‐3B was cleaved into some new small compounds and eventually most of the organic substances were mineralized to CO₂ and H₂O. The results of the conductivity analysis suggested that the degradation has mainly occurred in the first 40 min of reaction. The pH value of reactive brilliant red X‐3B solution was decreased first and then was increased. The results of inorganic anions analysis hinted that many of the N, Cl, and S elements from reactive brilliant red X‐3B were still attached in organic molecules.     

Field isotope investigations and numerical simulation of lake hydrodynamics

A three‐dimensional, numerical free‐surface‐flow simulation model is developed to investigate hydrodynamics of a lake and the predictive capabilities of the numerical model are validated by comparing them with field results obtained from Lake Naini, Uttar Pradesh, using environmental isotope (δ¹⁸O, δD and ³H) techniques. This has been carried out in order to understand the hydrodynamics of a lake (i.e. circulations, mixing and transport of water within the lake). Copyright © 2002 John Wiley & Sons, Ltd.     

Regional seismic responses of shallow basins incorporating site‐city interaction analyses on high‐rise building clusters

This study assesses the 3D amplification effects in shallow basins and quantifies the effects of site‐city interaction (SCI) on high‐rise buildings. A regional‐scale 3D spectral element simulation is conducted on the Tuen Mun‐Yuen Long basin, which contains multiple subbasins with heterogeneous and nonlinear soil profiles, while 3D city models with various building layouts are fully integrated into the basin model for our SCI study. We found a good correlation between spectral amplification factors and soil depths. Site response is significantly amplified at basin edges and centers due to surface waves generated at basin edges and the focusing effects stemming from 3D basin geometry. Transfer functions of 3D basins can be up to fourfold at fundamental frequencies as compared to 1D response, and further amplifications occur at high frequencies due to surface waves. In the SCI simulations, we observe wave trapping in the open space amid buildings resulting in energy concentration and up to twofold PGA amplifications. The wave trapping effect diminishes as the space between buildings increase beyond their range of influence (～100 m). The SCI analyses show that destructive kinetic energy in superstructures increases 28% in one horizontal direction but decreases 22% in the other. Our study concluded that, 1D site response analysis can significantly underestimate the seismic demand in shallow basins. Site‐city interaction of high‐rise buildings increases the short‐period spectra of ground motions, leading to an increase in their story accelerations by up to 50% and to a substantial decrease in the seismic safety of short structures in their vicinity.     

Eliminating 3D pre‐stack migration artefacts by 6D filtering

State‐of‐the‐art 3D seismic acquisition geometries have poor sampling along at least one dimension. This results in coherent migration noise that always contaminates pre‐stack migrated data, including high‐fold surveys, if prior‐to‐migration interpolation was not applied. We present a method for effective noise suppression in migrated gathers, competing with data interpolation before pre‐stack migration. The proposed technique is based on a dip decomposition of common‐offset volumes and a semblance‐type measure computation via offset for all constant‐dip gathers. Thus the processing engages six dimensions: offset, inline, crossline, depth, inline dip, and crossline dip. To reduce computational costs, we apply a two‐pass (4D in each pass) noise suppression: inline processing and then crossline processing (or vice versa). Synthetic and real‐data examples verify that the technique preserves signal amplitudes, including amplitude‐versus‐offset dependence, and that faults are not smeared.     

Probabilistic evaluation of seismic performance of 3‐story 3D one‐ and two‐way steel moment‐frame structures

This paper presents the results of a probabilistic evaluation of the seismic performance of 3D steel moment‐frame structures. Two types of framing system are considered: one‐way frames typical of construction in the United States and two‐way frames typical of construction in Japan. For each framing system, four types of beam–column connections are considered: pre‐Northridge welded‐flange bolted‐web, post‐Northridge welded‐flange welded‐web, reduced‐beam‐section, and bolted‐flange‐plate connections. A suite of earthquake ground motions is used to compute the annual probability of exceedence (APE) for a series of drift demand levels and for member plastic‐rotation capacity. Results are compared for the different framing systems and connection details. It is found that the two‐way frames, which have a larger initial stiffness and strength than the one‐way frames for the same beam and column volumes, have a smaller APE for small drift demands for which members exhibit no or minimal yielding, but have a larger APE for large drift demands for which members exhibit large plastic rotations. However, the one‐way frames, which typically comprise a few seismic frames with large‐sized members that have relatively small rotation capacities, may have a larger APE for member failure. The probabilistic approach presented in this study may be used to determine the most appropriate frame configuration to meet an owner's performance objectives. Copyright © 2008 John Wiley & Sons, Ltd.     

Offset‐variable density improves acoustic full‐waveform inversion: a shallow marine case study

We have previously applied three‐dimensional acoustic, anisotropic, full‐waveform inversion to a shallow‐water, wide‐angle, ocean‐bottom‐cable dataset to obtain a high‐resolution velocity model. This velocity model produced an improved match between synthetic and field data, better flattening of common‐image gathers, a closer fit to well logs, and an improvement in the pre‐stack depth‐migrated image. Nevertheless, close examination reveals that there is a systematic mismatch between the observed and predicted data from this full‐waveform inversion model, with the predicted data being consistently delayed in time. We demonstrate that this mismatch cannot be produced by systematic errors in the starting model, by errors in the assumed source wavelet, by incomplete convergence, or by the use of an insufficiently fine finite‐difference mesh. Throughout these tests, the mismatch is remarkably robust with the significant exception that we do not see an analogous mismatch when inverting synthetic acoustic data. We suspect therefore that the mismatch arises because of inadequacies in the physics that are used during inversion. For ocean‐bottom‐cable data in shallow water at low frequency, apparent observed arrival times, in wide‐angle turning‐ray data, result from the characteristics of the detailed interference pattern between primary refractions, surface ghosts, and a large suite of wide‐angle multiple reflected and/or multiple refracted arrivals. In these circumstances, the dynamics of individual arrivals can strongly influence the apparent arrival times of the resultant compound waveforms. In acoustic full‐waveform inversion, we do not normally know the density of the seabed, and we do not properly account for finite shear velocity, finite attenuation, and fine‐scale anisotropy variation, all of which can influence the relative amplitudes of different interfering arrivals, which in their turn influence the apparent kinematics. Here, we demonstrate that the introduction of a non‐physical offset‐variable water density during acoustic full‐waveform inversion of this ocean‐bottom‐cable field dataset can compensate efficiently and heuristically for these inaccuracies. This approach improves the travel‐time match and consequently increases both the accuracy and resolution of the final velocity model that is obtained using purely acoustic full‐waveform inversion at minimal additional cost.     

Formative conditions and sedimentary structures of sandy 3D antidunes: an application of the gravel step‐pool model to fine‐grained sand in an experimental flume

Antidunes and their sedimentary structures can be useful in reconstructing paleo‐hydraulic conditions, especially for large discharge events. However, three‐dimensional (3D) antidunes in sand‐sized sediments have not yet been studied extensively, as compared to either two‐dimensional (2D) antidunes or antidunes in gravel‐sized sediments. In this study, we estimated formative conditions of gravel step‐pool morphologies and applied them to the formation of 3D antidunes over a sand bed. Formative conditions are expressed in terms of a relationship between the water discharge per unit width and the bed slope. Flume experiments demonstrated that 3D mound‐like antidune configurations and their associated internal sedimentary structures could be preserved. Internal sedimentary structures were characterized by shallow lens‐like structures whose bases were erosional. Although gently‐dipping concave‐upward lamination was dominant, convex‐upward lamination was occasionally observed. The dimensions of lenticular lamina‐sets can be used to estimate antidune geometry. Thus if 3D antidunes can be interpreted in the stratigraphic record, it is possible to estimate the paleo‐hydraulic parameters such as water discharge and bed slope more precisely than previously. Copyright © 2010 John Wiley & Sons, Ltd.     

Impacts of forest structure on precipitation interception and run‐off generation in a semiarid region in northern China

Water resource scarcity and uneven distribution are 2 major environmental issues in China today. Forest structure is a dominant factor that influences hydrological processes, but the specific interactions remain uncertain due to the predominant use of individual or 1‐dimensional forest structure metrics in previous studies. In this study, forest structures in 8 run‐off plots on Mount Miaofeng in north China were parameterized by metrics of different dimensionalities. The relation between canopy interception and forest structure, shrub/litter interception, and forest structure as well as run‐off and forest structure were analysed by regression method and validated by leave‐one‐out cross test. The results showed that canopy interception rates ranged from less than 0.10 all the way to 0.80, affected by forest structure and precipitation, with interception rate decreasing logarithmically as precipitation increased. Forests with a larger canopy area (CA), leaf area index (LAI), and higher average height (H) had a narrow range of canopy interception rates, and forest with larger value of diameters at breath height (DBH), H, LAI, vertical heterogeneity coefficient (T), and structure complexity index (SCI) had higher interception rates. Forests with higher value of DBH, H, and horizontal heterogeneity coefficient (R) had higher shrub/litter interception rates on the forest floor. The run‐off coefficient was only significantly associated with LAI, T, and SCI. The validation test indicated that regression analysis of canopy interception rates and shrub interception are reliable and SCI is a key factor to influence the run‐off coefficient. However, the regression results of litter interception have a relatively large error. According to the results, to reduce the risks of the landslides and floods, forest managers should complicate the canopy and preserve trees with thicker stems and larger canopies. By contrast, to obtain more water resource from run‐off in arid regions, forest managers should harvest trees with large canopies and construct complex vertical structures by intermediate cutting.     

Exploring the effect of data assimilation by WRF‐3DVar for numerical rainfall prediction with different types of storm events

The mesoscale Numerical Weather Prediction (NWP) model is gaining popularity among the hydrometeorological community in providing high‐resolution rainfall forecasts at the catchment scale. Although the performance of the model has been verified in capturing the physical processes of severe storm events, the modelling accuracy is negatively affected by significant errors in the initial conditions used to drive the model. Several meteorological investigations have shown that the assimilation of real‐time observations, especially the radar data can help improve the accuracy of the rainfall predictions given by mesoscale NWP models. The aim of this study is to investigate the effect of data assimilation for hydrological applications at the catchment scale. Radar reflectivity together with surface and upper‐air meteorological observations is assimilated into the Weather Research and Forecasting (WRF) model using the three‐dimensional variational data‐assimilation technique. Improvement of the rainfall accumulation and its temporal variation after data assimilation is examined for four storm events in the Brue catchment (135.2 km²) located in southwest England. The storm events are selected with different rainfall distributions in space and time. It is found that the rainfall improvement is most obvious for the events with one‐dimensional evenness in either space or time. The effect of data assimilation is even more significant in the innermost domain which has the finest spatial resolution. However, for the events with two‐dimensional unevenness of rainfall, i.e. the rainfall is concentrated in a small area and in a short time period, the effect of data assimilation is not ideal. WRF fails in capturing the whole process of the highly convective storm with densely concentrated rainfall in a small area and a short time period. A shortened assimilation time interval together with more efficient utilisation of the weather radar data might help improve the effectiveness of data assimilation in such cases. Copyright © 2012 John Wiley & Sons, Ltd.     

An analytical study on three‐dimensional versus two‐dimensional water table‐induced flow patterns in a Tóthian basin

Although it has been increasingly acknowledged that groundwater flow pattern is complicated in the three‐dimensional (3‐D) domain, two‐dimensional (2‐D) water table‐induced flow models are still widely used to delineate basin‐scale groundwater circulation. However, the validity of 2‐D cross‐sectional flow field induced by water table has been seldom examined. Here, we derive the analytical solution of 3‐D water table‐induced hydraulic head in a Tóthian basin and then examine the validity of 2‐D cross‐sectional models by comparing the flow fields of selected cross sections calculated by the 2‐D cross‐sectional model with those by the 3‐D model, which represents the “true” cases. For cross sections in the recharge or discharge area of the 3‐D basin, even if head difference is not significant, the 2‐D cross‐sectional models result in flow patterns absolutely different from the true ones. For the cross section following the principal direction of groundwater flow, although 2‐D cross‐sectional models would overestimate the penetrating depth of local flow systems and underestimate the recharge/discharge flux, the flow pattern from the cross‐sectional model is similar to the true one and could be close enough to the true one by adjusting the decay exponent and anisotropy ratio of permeability. Consequently, to determine whether a 2‐D cross‐sectional model is applicable, a comparison of hydraulic head difference between 2‐D and 3‐D solutions is not enough. Instead, the similarity of flow pattern should be considered to determine whether a cross‐sectional model is applicable. This study improves understanding of groundwater flow induced by more natural water table undulations in the 3‐D domain and the limitations of 2‐D models accounting for cross‐sectional water table undulation only.