新疆北部中二叠统烃源岩有机质与沉积环境的关系

依据地表剖面烃源岩地球化学分析资料,结合部分井下样品分析数据对新疆北部准噶尔、吐哈及伊犁盆地中二叠统碳酸盐岩类、泥岩类烃源岩的元素地球化学和有机地球化学特征进行了系统分析.研究认为烃源岩的轻稀土元素富集程度较高,重稀土元素相对较低,Ce/Ce*具有较明显的正异常,反映出烃源岩的沉积环境总体为还原环境.多项地球化学分析证实,沉积水体的元素地球化学特征及古盐度等环境条件与烃源岩有机相关系密切.研究结果表明,烃源岩的植烷优势主要是在还原条件的沉积环境下释放出大量的植烷所致,伽马腊烷、β-胡萝卜烷等生物标志化合物的检出表征诸盆地烃源岩沉积时具有一定的盐度条件.还原程度高的沉积相带是原始有机质沉积的良好场所,沉积有机质能及时沉积、保存,烃源岩大多有机质丰度高、类型好;反之,则明显变差.     

Influence of sedimentary environments on mechanical properties of clastic rocks

The sedimentary environments are the intrinsic factor controlling the mechanical properties of clastic rocks. Examining the relationship between rock sedimentary environments and rock mechanical properties gives a better understanding of rock deformation and failure mechanisms. In this study, more than 55 samples in coal measures were taken from seven different lithologic formations in eastern China. Using the optical microscope the sedimentary characteristics, such as components of clastic rocks and sizes of clastic grains were quantitatively tested and analyzed. The corresponding mechanical parameters were tested using the servo-controlled testing system. Different lithologic attributes in the sedimentary rocks sampled different stress–strain behaviors and failure characteristics under different confining pressures, mainly due to different compositions and textures. Results demonstrate that clastic rocks have the linear best-fit for Mohr-Coulomb failure criterion. The elastic moduli in clastic rocks are highly dependent upon confining pressures, unlike hard rocks. The envelope lines of the mechanical properties versus the contents of quartz, detritus of the grain diameter of more than 0.03 mm, and grain size in clastic rocks are given. The compressive strength or elastic modulus and the grain diameter have a non-monotonic relation and demonstrate the “grain-diameter softening” effect.     

Influence of sedimentary environments on sulfur isotope ratios in clastic rocks: a review

Strata-bound sulfide deposits associated with clastic, marine sedimentary rocks, and not associated with volcanic rocks, display distributions of S³⁴ values gradational between two extreme types: 1. a flat distribution ranging from S³⁴ of seawater sulfate to values about 25 lower; and 2. a narrow distribution around value S³⁴ (sulfide)=S³⁴ (seawater sulfate) –50, and skewed to heavier values. S³⁴ (seawater sulfate) is estimated from contemporaneous evaporites. There is a systematic relation between the type of S³⁴ distribution and the type of depositional environment. Type 1 occurs in shallow marine or brackish-water environments; type 2 occurs characteristically in deep, euxinic basins. These distributions can be accounted for by a model involving bacterial reduction of seawater sulfate in systems which range from fully-closed batches of sulfate (type 1) to fully open systems in which fresh sulfate is introduced as reduction proceeds (type 2). The difference in the characteristic distributions requires that the magnitude of the sulfate-sulfide kinetic isotope effect on reduction be different in the two cases. This difference has already been suggested by the conflict between S³⁴ data for modern marine sediments and laboratory experiments. The difference in isotope effects can be accounted for by Rees' (1973) model of steady-state sulfate reduction: low nutrient supply and undisturbed, stationary bacterial populations in the open system settings tend to generate larger fractionations.

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Zusammenfassung Schichtgebundene Sulfid-Lagerstätten in Begleitung von klastischen, marinen Sedimentgesteinen ohne Beteiligung vulkanischer Gesteine zeigen kontinuierliche Verteilungen der S³⁴-Werte zwischen zwei Extremtypen: 1. Eine flache Verteilung im Bereich von S³⁴-Werten des Seewasser-Sulfats bis zu Werten, die etwa 25 niedriger liegen. 2. Eine eng begrenzte Verteilung um den S³⁴ (Sulfid)-Wert=S³⁴ (Seewasser-Sulfat) –50 und asymmetrischer Verteilungskurve mit stärkerer Besetzung bei den schwereren Werten. Das S³⁴ (Seewasser-Sulfat) wird von gleichaltrigen Evaporiten abgeleitet. Es besteht eine systematische Beziehung zwischen der Art der S³⁴-Verteilung und dem Milieu des Ablagerungsraumes. Typ 1 tritt im marinen Flachwasser oder in brackischer Umgebung auf. Typ 2 ist charakteristisch für tiefe euxinische Becken. Diese Verteilungen können erklärt werden mit Hilfe eines Modells mit bakterieller Reduktion von Meerwasser-Sulfat in Systemen, die von völlig abgeschlossenen Sulfat-Mengen (Typ 1) bis zu völlig offenen Systemen reichen, in die bei fortschreitender Reduktion frisches Sulfat zugeführt wird (Typ 2). Der Unterschied in den charakteristischen Verteilungen setzt voraus, daß die Stärke der kinetischen Sulfat-Sulfid-Isotopen-Wirkung auf die Reduktion in beiden Fällen verschieden ist. Dieser Unterschied wurde bereits wegen der Widersprüche zwischen den verschiedenen S³⁴-Werten heutiger mariner Sedimente und Laborexperimente vermutet. Der Unterschied in der Isotopen-Wirkung kann durch das Modell von Rees (1973) für kontinuierlich ablaufende Sulfat-Reduktion erklärt werden. Geringes Nahrungsangebot und ungestörte, gleichbleibende Bakterien-Populationen in offenen Systemen neigen zur Erzeugung stärkerer Fraktionierungen.

     

Hydrocarbon source rocks in sedimentary basins of continental margins in the Middle-Late Paleozoic

The second half of the Paleozoic was marked by amalgamation of large continental blocks. The collision between the Laurentia and Baltica continents in the Devonian culminated in the formation of Laurussia. This event was followed by accretion of the Siberian and Kazakhstan continental blocks after the closure of the Uralian marine basin in the terminal Carboniferous-initial Permian. These processes were responsible for the formation of the Pangea supercontinent at the end of the Permian Period. They were accompanied by climate changes reflected in the alternation of warming and cooling epochs. One of these cooling epochs was terminated by large-scale glaciation of Gondwana at the end of the Carboniferous Period. Nevertheless, the most significant process, which drastically changed the existing paleogeographic situation, was colonization of continents by plants and animals, and, thus, accumulation of coaliferous formations in them. The lacustrine and sea basins also accumulated humic and mixed humic/sapropel organic matter (OM) in addition to pure sapropelic sediments.     

北疆阿尔泰南缘泥盆系浅变质碎屑沉积岩地球化学特征及其形成环境

对于北疆阿尔泰地区泥盆纪所处的大地构造环境,目前仍旧存在不同观点.前人基于阿尔泰南缘泥盆纪火山岩地球化学研究,分别提出了活动大陆边缘和被动大陆边缘裂谷等不同构造观点.阿尔泰造山带南缘的泥盆纪浅变质碎屑沉积岩地球化学研究表明,该套浅变质碎屑沉积岩原岩主要为泥质或砂质沉积岩.尽管不同岩性样品主量元素含量不同,但其化学蚀变指数(CIA)小于75,成分变异指数(ICY)接近或小于1.0,斜长石蚀变指数(PIA)平均70,说明其源区物质比较新鲜,成熟度相对较低,化学风化作用较弱.同样,不同岩性样品微量元素含量差别较大,但表生过程中不活泼的微量元素比值却比较一致,轻稀土(LREE)中度富集(LaN/YbN=2.88～9.90),重稀土(HREE)比较平坦,并伴有明显的Eu负异常(Eu/Eu*=0.45～0.89).绝大多数样品具有高的La/Sc(1～3)、La/Y(0.5～1)和Ti/Zr(10～35),以及较低的Sc/Cr(0.1～0.3)比值,类似于大陆岛弧相关环境碎屑沉积物.在La-Th-Sc和Th-Sc-Zr/10构造环境判别图解中,除一千枚岩样品外,其他所有样品均落入大陆岛弧区.以上地球化学特征明显不同于大洋岛弧和被动陆缘沉积物,说明该套浅变质碎屑沉积岩可能沉积于活动大陆边缘的大陆岛弧相关环境,为认识阿尔泰造山带泥盆纪岛弧增生构造演化过程提供了一个重要证据.     

贵州瓮安地区上震旦统碳同位素特征

贵州瓮安磷矿上震旦统碳同位素组成显示，δ１３Ｃ值在垂向地层序列中的变化有明显的规律性。陡山沱组底部白云岩δ１３Ｃ为负值，向上碳同位素值发生显著正飘移，然后，除在陡山沱组中部δ１３Ｃ值有所下降外，δ１３Ｃ值基本上保持在＋２‰左右，一直持续到灯影组。瓮安地区上震旦统碳同位素剖面表现出与湖北峡东及世界其它地区同期碳同位素剖面极大的相似性，显示它们反映了末元古代海水碳同位素值的长期变化趋势。     

松辽盆地白垩系泉头组碎屑沉积岩岩石地球化学特征及其地质意义

松辽盆地庆安地区白垩系泉头组碎屑沉积岩主要由砂岩、泥岩和粉砂岩类组成。通过对白垩系泉头组碎屑沉积岩岩石样品的岩石化学分析表明 :主元素化学分类结果主要为长石砂岩、页岩 ,少量岩屑砂岩和硬砂岩 ;稀土元素分布模式显示其明显富集轻稀土及Eu负异常 ,并与NASC和PAAS稀土分布模式相似 ;碎屑沉积岩与上地壳的微量元素含量比值曲线显示为平坦型 ,这说明沉积岩是在活动性较弱的构造背景下缓慢沉积 ,具有被动大陆边缘和活动大陆边缘沉积物的特点。松辽盆地庆安地区白垩系泉头组碎屑沉积岩物质来源于张广才岭海西期花岗岩 ,后者的物源来自于上地壳。     

沉积盆地成岩作用系统及其时空属性

含油气盆地的勘探开发对认识沉积成岩作用和储层发育规律提出了很高的要求。然而,迄今为止沉积学家和石油工程师还很难如认识沉积过程及其结构那样认识盆地尺度或宏观尺度上成岩作用的时空分带。为此,本文探讨了成岩作用类型的时空属性和主控因素等理论问题,提出了成岩系统分级（类）的有关准则,试图以此探索成岩作用时空分布与演变研究的新思路。结合中国东、西部有关中-新生代沉积盆地实例分析,阐述了盆地域（尺度）、层序域、亚层序域、层内域等成岩作用系统的客观存在,并对盆地域、层序域成岩作用系统动力学研究的思路和方法作了进一步阐释。在盆地尺度上成岩作用的时空分布主要与盆地大地构造位置及其控制的温压场、物源、剥蚀-搬运气候背景、埋藏历史、水文体制叠置方式密切关联：层序域成岩作用系统的时空分异则主要取决于埋藏深度、层序结构与宏观物理-化学障、沉积体系（配置）、水文体制。研究认为,成岩系统的层次分析是认识不同类型沉积盆地成岩结构的重要基础,而对于确定的盆地类型而言,盆地尺度水文体制与流体-岩石相互作用研究是解析成岩作用时空属性的关键。成岩系统研究目前还面临许多关键问题亟待解决,如成岩系统及其边界奈件的划分;成岩作用系统关键要素及其制约机制的厘定;盆地尺度上精细构造演化和温压历史恢复;盆地流体属性和活动期次的准确鉴别;盆地尺度上成岩作用数值模拟和动力学过程研究。     

Source rocks in sedimentary basins of continental margins in the early paleozoic

During the Paleozoic, epochs with the relatively cold climate alternated with epochs marked by significant warming. Moreover, cooling epochs were characterized by the substantial sea level fall, while warming was accompanied by its rapid rise. In many basins located at margins of Laurentia, Baltica, and the North China continental block, such an alternation is reflected in the structure of sedimentary sequences and the lateral/vertical distribution of reservoirs, confining beds, and source rocks. Despite the fact that sediments with high concentrations of sapropelic OM accumulated in different periods, their distribution areas on continents and their margins became highly reduced during cold epochs, when these sediments filled mostly rift troughs and foreland basins. After the colonization of land by higher plant communities in the Carboniferous and Permian sediments deposited during cold epochs, the humic material became an important constituent of OM in the source rock sequences.     

Nd Isotopic Composition and Material Source of Pre—and Post—Sinian Sedimentary Rocks in Xiushui Area,Jiangxi Province

Reported in this paper are the Nd isotopic compositions of the pre-Sinian and Sinian-Cambrian sedimentary rocks in the Xiushui area,Jiangxi Province.Significant differences are noticed between them in their Nd isotopic dompositions.As for the pre-Sinian lightly metmorphozed sedimentary rocks,^143Nd/^144Nd=0.512000-0.512214,CNd(T)=-8.04-9.99,and TDM=18332426Ma are suggested for the Sinian-Cambrian sedimentary rocks .These differences would reflect the diversity of material source for the sedimentary rocks deposited before and after the Sinian period.Mantle material ap-pears to have been involved in the formation of the pre-Sinian sedimentary rocks while the post-Sinian sedimentary rocks are composed mainly of recycled detritus from the continental crust.     

Geochemistry of fine-grained clastic sedimentary rocks of the Neoproterozoic Ikorongo Group, NE Tanzania: Implications for provenance and source rock weathering

The Neoproterozoic Ikorongo Group, which lies unconformably on the late Archaean Nyanzian Supergroup of the Tanzania Craton, is comprised of conglomerates, quartzites, shales, siltstones, red sandstones with rare flagstones and gritstones and is regionally subdivided into four litho-stratigraphic units namely the Makobo, Kinenge, Sumuji and Masati Formations.We report geochemical data for the mudrocks (i.e., shales and siltstones) from the Ikorongo basin in an attempt to constrain their provenance and source rock weathering. These mudrocks are compositionally similar to PAAS and PS indicating derivation from mixed mafic–felsic sources. However, the siltstones show depletion in the transition elements (Cr, Ni, Cu, Sc and V) and attest to a more felsic protolith than those for PAAS and PS. The Chemical Index of Alteration (CIA: 52–82) reveal a moderately weathered protolith for the mudrocks. The consistent REE patterns with LREE-enriched and HREE-depleted patterns ((La/Yb)_CN = 7.3–38.3) coupled with negative Eu anomalies (Eu/Eu* = 0.71 on average), which characteristics are similar to the average PAAS and PS, illustrate cratonic sources that formed by intra-crustal differentiation.Geochemical considerations and palaeocurrent indications suggest that the provenance of the Ikorongo Group include high-Mg basaltic-andesites, dacites, rhyolites and granitoids from the Neoarchaean Musoma-Mara Greenstone Belt to the north of the Ikorongo basin. Mass balance calculations suggest relative contributions of 47%, 42% and 11% from granitoids, high-magnesium basaltic-andesites and dacites, respectively to the detritus that formed the shales. Corresponding contributions to the siltstones detritus are 53%, 43% and 4%.     

The genesis of calcite in carbonate rocks of the sedimentary basins: Evidence from the stable carbon and oxygen isotopes composition

The distributions of stable carbon and oxygen isotopes in modern and ancient limestones of various types were studied. Carbonate samples from modern sediments were collected in the Black and Barents Seas. Ancient carbonates were represented by Upper Jurassic (Kimmeridgian-Tithonian) limestones from the central part of the West Siberian basin. Carbonate samples include remains of modern and Upper Jurassic fauna, carbonate crust from sediments of the Black Sea, carbonate tube from sediments of the Barents Sea, and Upper Jurassic limestone from the carbonate layer found at top of Abalak, bottom of Bazhenov deposits in the central part of the West Siberian basin. According to the results of the isotope analysis and comparison with modern carbonates, Upper Jurassic limestones of the West Siberian basin belong to the group of methane-derived carbonates and precipitated as a result of anaerobic oxidation of methane (AOM). Fractures in limestones are filled with secondary calcite.     

Analysis of sedimentary facies and depositional environments of Paleogene sequence of Cambay basin,India

A study on the sedimentary facies characterization and depositional environment interpretations for the K#Field (K-Oil Field) in Cambay petroleum basin of western onshore, India was conducted based on the sub-surface data from drilled wells, including well logs, borehole images, cores and the regional knowledge of the basin. In this work, an effort is made to integrate the current data from seismics and well logging, to study and analyze its depositional environments and establish the petroleum systems. The study regions for the present work are K45 and K48 blocks. The target strata includes 2 oil-bearing formations of Paleogene, which is about 3600 ft; they are M#Fm (M-Formation) of the Eocene and N#Fm (N-Formation) of Oligocene, subdivided into 11 zones. The sediment fill is mostly of Tertiary. The research attempts to decipher the oil - depositional source correlation problems of the basin. Sedimentary models were established referring to the core analysis, core photographs and well logs. Reservoir and heterogeneity study included reservoir lithology features, physical properties and pore structure features.Well facies analysis of oil well WELL-0297 and WELL-0129 was done and the results were analyzed for further drilling of new wells for oil and gas exploration. The study found that the Eocene, Oligocene, Miocene and Paleogene are fluviatile facies sand and mud interbed sediment with the thickness 2000-4000 ft, which are main oil-bearing formations in these areas. Studies concluded that the fluvial reservoirs of the K#Field are characterized by large variations from laterally extensive bodies with good interconnectedness and high net-to-gross ratios, multi-storey ribbon bodies with poor interconnections and low net-to-gross ratios.     

川东南—黔中及其周边地区下组合烃源岩元素地球化学特征及沉积环境意义

笔者采用ICP-MS测试分析技术,对川东南-黔中及其周边地区震旦-志留纪地层28件样品进行了B、V、Ni、Sr、Ba、Th、U等指示沉积环境的敏感微量元素做了系统测试分析,采用GB/T14506.28-93硅酸盐岩石化学分析方法和X射线荧光光谱法测定主要元素和微量元素含量,并探讨了Sr/Ba、V/Ni、V/(V+Ni)、Sr/Ca、Ca/Mg、Th/U比值与沉积环境的对应关系.分析结果表明,本区下组合沉积环境主要为半深海、深海及浅海滞流环境.元素空间分布的差异性反映了沉积环境的区域性变化.     

湘西晚前寒武纪层状硅质岩的热水沉积地球化学标志及其环境意义

湘西晚前寒武纪层状硅质岩化学成分纯净,硅质矿物平均含量９５％以上。岩石富Ｆｅ、Ｍｎ,相对贫Ａｌ、Ｔｉ、Ｍｇ,富含Ｂａ、Ａｓ、Ｓｂ、Ａｇ、Ｕ等微量元素。Ｆｅ／Ｔｉ、（Ｆｅ＋Ｍｎ）／Ｔｉ、Ａｌ／（Ａｌ＋Ｆｅ＋Ｍｎ）、Ｕ／Ｔｈ比值及ＡｌＦｅＭｎ、ＦｅＭｎ（Ｎｉ＋Ｃｏ＋Ｃｕ）三角图均表明岩石为热水来源沉积岩。稀土元素总量低,Ｃｅ负异常,重稀土相对富集,显示主要为热水沉积作用的产物。δ３０Ｓｉ、δ１８Ｏ值及岩石的形成温度清楚地表明组成岩石的二氧化硅来源于热水。岩石的ＭｎＯ／ＴｉＯ２、δＣｅ及δ３０Ｓｉ值分析表明硅质岩沉积于大陆边缘斜坡半深海至大洋盆地深海环境中     

鄂尔多斯盆地延长组长1段烃源岩有机地球化学特征

鄂尔多斯盆地三叠系延长组长1段发育一套深湖相浊积岩及数层暗色泥岩。根据实测的有机碳含量、可溶有机质及族组分含量、有机元素和同位素等数据可知,该泥岩为一套较好—好的烃源岩。镜质体反射率及生物标志化合物成熟度指标显示,该段烃源岩有机质处于低成熟到成熟阶段。该套烃源岩的发现为陕北地区寻找新的油气勘探目标提供了依据。     

广西南部凭祥中三叠世沉积盆地构造环境——来自岩相学和碎屑岩地球化学的证据

岩相学特征表明,广西凭祥盆地砾岩可分为颗粒支撑和基质支撑2种,砾石成分主要为生物碎屑灰岩,其次为砂岩和泥岩。盆地砂岩主要由成分成熟度和结构成熟度较低的亚岩屑(杂)砂岩和岩屑(杂)砂岩组成,物源区为碰撞造山带或再旋回造山带。碎屑岩地球化学特征表明,凭祥中三叠世盆地中的砂岩和泥岩样品SiO2含量为61.71%~74.85%,接近于上地壳的平均值。具有高的K2O/Na2O值(6.50~0.51)和高的TFe2O3+MgO含量(7.29%~10.31%),TFe2O3/K2O值为2.05%~5.54%,矿物稳定性较差。稀土元素标准化配分曲线呈现出轻稀土元素富集、重稀土元素平坦和明显的Eu、Ce负异常特征,类似于上地壳和典型的太古宙页岩,具有海相沉积的特征。砂岩风化蚀变指数CIA高(71~88),Th/U值为3.68~9.53,表明砂岩和泥岩经历了较强的风化作用。砂岩物源区判别图表明,凭祥盆地物源与酸性岛弧具明显的亲缘性,增生楔和活动陆缘是主要的物源区。这些特征综合表明,凭祥盆地是一个伴随古特提斯分支洋盆闭合、经强烈构造改造的残余弧前盆地。     

Distribution of major hydrocarbon source rocks in the major oil-gas-bearing basins in China

The distribution characteristics of major hydrocarbon source rocks in the major oil-gas-bearing basins in China were discussed in this paper, and differences between the East and the West basins in tectonic setting, age, lithology, sedimentary environment, and hydrocarbon generation feature and potential were also studied. Considering the Lieiliang Mountains-Dalou Mountains as the boundary, source rocks in the East basins are distributed mainly in three NNE-trend subsiding belts, and those in the West basins are distributed in the north and south of the Tianshan Mountains and Qilian Mountains. They are mainly NWW trending and can be divided into four basin groups.     

Provenance and weathering history of Mesoproterozoic clastic sedimentary rocks from the basal Gulcheru Formation,Cuddapah Basin

Geochemical analysis for the Mesoproterozoic clastic sedimentary rocks of the basal Gulcheru Formation of the Cuddapah Basin in the Gugudu-Dadithota-Parnapalle-Palkonda region (extending atleast 40 km) have been performed to highlight their provenance and weathering history. The low K₂O/Al₂O₃ ratios of the representative samples points to the recycled nature of sediments and illite clay in the sediments indicate an overall cold climate (low chemical weathering degree). All the provenance diagrams indicate a mixed source of the Gulcheru sediments with felsic dominancy and Upper continental crust (UCC) signature.     

低勘探程度盆地烃源岩早期预测方法研究

低勘探领域(深层、深水和新区)是今后油气勘探的重要方向,而有没有有效烃源岩将决定该领域是否具有勘探价值,因此烃源岩评价是低勘探领域早期评价的关键。由于少井条件下烃源岩的评价参数几乎均未知,因此,低勘探程度与烃源岩早期评价是一对矛盾。针对低勘探领域的资料条件,探讨了在层序地层框架基础上的多项烃源岩参数的早期预测及综合评价方法。主要包括4个方面,即(1)层序地层格架分析法确定主力烃源岩层段;(2)地震速度岩性分析法确定烃源岩厚度;(3)烃源岩镜质体反射率地震预测法估算烃源岩成熟度;(4)烃源岩综合评价。本方法充分利用层序地层学方法和地球物理技术,实现了低勘探程度与烃源岩早期评价之间矛盾的转化,成为低勘探领域烃源岩早期预测的一种新方法。