掺硅粉及粉煤灰的水泥胶砂抗腐蚀性能研究

通过试验研究硫酸盐溶液侵蚀前后水泥胶砂的强度、质量损失率和中性化深度,揭示了掺矿粉及粉煤灰的水泥胶砂抗腐蚀性能。试验表明：在硫酸盐侵蚀环境下,随粉煤灰掺量增加水泥胶砂的质量损失率总体减小,随硅粉掺量增加则表现出先减小后增大的变化趋势,单掺粉煤灰或硅粉的掺量越高则中性化深度越大,掺10%粉煤灰或5%硅粉时对改善抗腐蚀性能最优;按最优掺量混掺硅粉和粉煤灰时则抗腐蚀性能的超叠加效应不明显,其中胶凝材料组成是决定掺加掺合料水泥砂浆抗腐蚀性能的主要因素。     

水泥-黄土注浆充填材料的试验研究

采空区危害巨大,目前主要采用注浆充填方式进行处置。水泥-粉煤灰浆液在采空区治理中得到了广泛的应用,但在一些采空区治理工程中,由于缺乏粉煤灰,需要寻找其他低成本的注浆材料。水泥-黄土浆液具有就地取材、工艺简单等优势,是替代水泥-粉煤灰浆液的首选。本文以陕西泾阳、甘肃兰州、山西吕梁黄土为研究对象,通过大量水泥-黄土浆液黏度、结石率、凝结时间、结石体强度等性质的试验,研究了水泥掺量、水固比、黄土类型、水玻璃掺量等因素对水泥-黄土浆液性质及其结石体强度的影响。试验结果表明:随黄土掺量的增加,结石体强度、浆体流动性降低,而凝结时间延长; 水泥-黄土浆液结石体早期强度较低,而后期强度增长较大; 黄土的地域性分布,造成水泥-黄土浆液性质差异较大,黄土的粒径越粗,结石体的强度越高; 与离石黄土浆液相比,马兰黄土浆液性能稳定,强度较高,更适宜于采空区充填注浆; 水玻璃的掺入,使浆液黏度增大,结石率提高,凝结时间缩短,强度减小。本研究成果为采空区注浆设计和施工提供了新的思路。     

水泥-黄土注浆充填材料的试验研究

采空区危害巨大,目前主要采用注浆充填方式进行处置。水泥-粉煤灰浆液在采空区治理中得到了广泛的应用,但在一些采空区治理工程中,由于缺乏粉煤灰,需要寻找其他低成本的注浆材料。水泥-黄土浆液具有就地取材、工艺简单等优势,是替代水泥-粉煤灰浆液的首选。本文以陕西泾阳、甘肃兰州、山西吕梁黄土为研究对象,通过大量水泥-黄土浆液黏度、结石率、凝结时间、结石体强度等性质的试验,研究了水泥掺量、水固比、黄土类型、水玻璃掺量等因素对水泥-黄土浆液性质及其结石体强度的影响。试验结果表明:随黄土掺量的增加,结石体强度、浆体流动性降低,而凝结时间延长;水泥-黄土浆液结石体早期强度较低,而后期强度增长较大;黄土的地域性分布,造成水泥-黄土浆液性质差异较大,黄土的粒径越粗,结石体的强度越高;与离石黄土浆液相比,马兰黄土浆液性能稳定,强度较高,更适宜于采空区充填注浆;水玻璃的掺入,使浆液黏度增大,结石率提高,凝结时间缩短,强度减小。本研究成果为采空区注浆设计和施工提供了新的思路。     

陕北采煤沉陷区黄土基注浆材料性能试验及配比优选

注浆法是采煤沉陷区的主要治理方法，浆材对注浆效果和成本影响很大。以陕北地区黄土-水泥-添加剂混合浆液为研究对象，采用单因素及正交试验对黄土浆液的黏度、凝胶时间、结石率及28 d单轴无侧限抗压强度进行试验研究，对各指标的影响因素及变化规律进行分析，同时，建立黄土基浆液的GA-BPNN预测模型，通过GA多目标全局寻优，优选出一定强度下成本最低的浆液配比。试验结果表明:黄土水泥浆液与陕北地区普遍采用的水泥粉煤灰浆液性能相近，成本大幅降低，黄土基注浆材料密度及结石率受水固比影响最为明显，黏度主要受水固比及黄土（水泥）掺量影响，28 d强度主要受黄土（水泥）掺量影响；采用GA-BPNN构建模型预测的黄土基注浆材料性能预测值与期望值相对误差为0.74%~1.83%，预测结果精度高，可满足实际应用需求。移动阅读      

纤维硅灰水泥石强度与浆液抗冲刷特性

针对隧道突水灾害防治对注浆材料的特殊要求,在水泥浆中加入外掺剂改善其力学特性与抗冲刷特性。通过测试不同水灰比、纤维掺量、硅灰掺量下水泥石的抗压与抗折强度,得出各水灰比下的强度最佳配合比,并测试最佳配合比下浆液的流动性与抗冲刷特性。试验发现,纤维与硅灰的掺入能够显著提高水泥石的强度,且对浆液的流动度影响不大;低流速下纤维硅灰水泥浆的抗冲刷特性较纯水泥浆改善显著,但流速较高时其抗冲刷特性仍较差。基于此,在纤维硅灰水泥浆中再掺入可再分散性乳胶粉进一步改善浆液抗冲刷特性。试验结果表明,可再分散性乳胶粉能明显改善浆液抗冲刷特性,即使在较高流速（0.6 m/s）下,其浆液留存率仍达到60%以上。研究结果为隧道突水灾害防治与动水注浆浆液选择提供了参考。     

油页岩原位注浆封闭浆液配方研究

油页岩在原位开采过程中,开采井与周围环境相通,原位产生的油气容易渗入周围地层形成环境污染,目前尚没有一种经济性较好的原位封闭技术来解决该难题。本文基于注浆封闭原理,通过试验探究,提出采用无污染且造价低的超细水泥注浆配方来对开采区进行封闭。经过系列配方的优化选择,最终确定优化的配方是水灰比为0.8,微硅粉掺量为6%,膨润土掺量为2%,聚羧酸减水剂掺量为0.4%,此时浆液的性能基本达到工程要求。     

高活性粉煤灰注浆材料性能和应用

高活性粉煤灰注浆材料是以工业废料－粉煤灰为主体,配合其它具有胶凝增强和提高早期强度的外掺料,以及能改善浆液性能使之满足注浆施工作业要求的外加剂,经特殊加工而成的一种新型注浆材料。该材料与普通硅酸盐水泥用于注浆工程相比有流动性好、凝结时间适当、抗压强度较高、结石率高的特点,经在静压注浆和高压旋喷注浆工程中的初步应用,取得了较好的效果。     

极软岩巷道锚注加固注浆材料研究与应用

锚注加固是一种理想的改善软岩巷道的围岩承载性能的措施。在实验室对粉煤灰-水泥锚注加固注浆材料的流动性、析水性及抗压强度进行了试验研究,找出了注浆材料的适宜配比,即粉煤灰掺量在20 %以下,水灰比为0.65～0.70,并在新集三矿极软岩巷道修复加固中进行了应用。     

“711”型速凝剂用于钻孔护壁堵漏

我队为了解决钻孔坍塌、掉块,漏水、涌水问题,对“711”型水泥速凝剂进行了护壁堵漏的试验研究工作。现介绍于下。一配比试验在水灰比为0.4的水泥浆中掺入2.5～3.5％(重量比)的“711”速凝剂可在10分钟内凝固,早期强度有提高,28天强度为不掺速凝剂水泥强度的85％。影响凝固时间及强度的主要因素是: 1.掺量当水灰比不变时,“711”的掺量少,初凝时间长,结石体强度高;“711”掺量多,初凝时间短,但掺量不宜过多,以免影响水泥的后期强度,甚至会延长其凝固时间。“711”的适宜掺量应为水泥重量的2.5～3.5％。 2.水灰比“711”的掺量一定时,水灰比大,初凝时间长,结石体强度低;水灰     

砾石土层中注浆扩散参数的研究

采用注浆模拟试验与数值分析等研究方法,探讨了砾石土层中注浆的注浆量、浆液扩散半径及注浆形成的结石体抗压强度等参数预测计算模型,并设计试验对其进行了验证。试验结果表明,砾石土层中注浆的注浆量、浆液扩散半径及结石体的抗压强度等参数预测计算模型计算的注浆量、浆液扩散半径与注浆结石体抗压强度的理论值与试验实测值间虽分别有10%、5%、10%左右的差异,但均相差不大,因此,可用来预测砾石土层实际注浆工程中的注浆量、浆液扩散半径及注浆形成的结石体的抗压强度等参数。研究成果不仅可为砾石土层实际注浆工程实践提供理论支撑,还可为砾石土诱发的滑坡、泥石流等灾害的防灾减灾提供技术参考。     

Portland Cement Stabilization of Soil–Bentonite for Vertical Cutoff Walls Against Diesel Oil Contaminant

The objective of this study was to evaluate the effect of water-cement ratio and cement content on the hydraulic behavior of soil–cement–bentonite (SCB) and soil–bentonite (SB) mixtures permeated with water and diesel oil, to assist with the design of vertical cutoff walls constructed with those mixtures. The experimental program included unconfined compression tests, hydraulic conductivity tests and X-ray diffraction analysis. The test results indicated changes in hydraulic conductivity take place due to the variation of the water-cement ratio and permeant fluid. The hydraulic conductivity of the SB mixtures permeated with diesel oil was higher than the hydraulic conductivity of the same samples permeated with water. X-ray diffraction analyses suggest that this might be due to the decrease in double layer thickness and increase of seepage pore space imparted by diesel oil permeation. Conversely, Portland cement addition increased the hydraulic conductivity of the SCB specimens permeated with water, whereas subsequent diesel oil permeation reduced the hydraulic conductivity of the SCB specimens; this might be due to the relatively lower impact imparted by diesel permeation on the double layer characteristics of the bentonite stabilized with Portland cement.     

污水浸泡对水泥土强度和电阻率特性影响的试验研究

为了揭示污水对水泥土的影响规律,并尝试采用电阻率法作为描述强度和污染特征的手段,把粉质黏土和两种水泥（普通硅酸盐水泥、矿渣硅酸盐水泥）制作的水泥土试块分别浸泡在3种液体（自来水、生活污水、造纸厂污水）中模拟环境侵蚀。首先对比分析了污水对土体液塑限的影响,其次研究了龄期、水泥类型、污水类型等对水泥土抗压强度和电阻率的影响,考察了电阻率和抗压强度的关系。结果表明：污染后土样的液限、塑限均增大,塑性指数减小;水泥土抗压强度和电阻率均随龄期增加而增长;污水均降低了水泥土的抗压强度和电阻率,但是矿渣硅酸盐水泥土的抗压强度和电阻率均高于普通硅酸盐水泥土,说明在污水环境中,矿渣水泥对水泥土有一定的抗劣化能力;在不同的龄期、水泥类型、污水类型下,水泥土电阻率均与抗压强度呈现出一致的变化规律,二者线性相关。     

水泥稳定再生沥青路面/红土混合物用于软土改良的效果评估

评估了水泥稳定再生沥青路面（RAP）/边缘红土混合物作为碎石桩骨料替代传统采石场骨料的潜力,研究了混合材料在不同RAP置换率和有效约束压力下的不排水剪切强度变化。RAP置换率分别为10%、30%和50%（按干重计）,普通硅酸盐水泥含量分别为1%和3%。很明显,RAP的置换增加了大颗粒,同时减少了细小颗粒,因此增加了压实度。在低于先期固结压力的有效应力下,RAP−土颗粒混合物表现出与孔隙压力降低相关的应变硬化性能。当RAP置换率增加时,水泥稳定的RAP−土颗粒混合物应力−应变曲线的应变软化性能减弱。胶结作用提高了黏聚力,而内摩擦角未产生明显的变化。水泥稳定的RAP−土颗粒混合物的强度和刚度主要取决于胶结强度和RAP置换率。抗剪强度随着非稳定和水泥稳定的RAP−土颗粒混合物的RAP置换率增加而提高,而水泥稳定的RAP−土颗粒混合物的刚度由于沥青黏结剂的高能量吸收而下降。     

矿渣−粉煤灰地聚合物固化砂土力学特性研究

硅酸盐水泥作为常规的土壤固化剂存在高能耗、高排放等问题,研究人员一直在寻求一种更加经济环保的水泥代替品。使用基于高炉矿渣（ground granulated blast-furnace slag,简称 GGBS）、粉煤灰（ fly ash,简称 FA）的地聚合物对砂土进行加固,通过调整激发剂的种类和配比、矿渣与粉煤灰比例、水灰比和养护条件等,研究不同因素对地聚合物固化砂土力学性能的影响。通过无侧限抗压强度（unconfined compressive strength,简称 UCS）测试、电子计算机断层扫描（ computed tomography,简称 CT ）分析、扫描电子显微镜（scanning electron microscope,简称 SEM）对试样进行了深入研究。结果表明：基于 GGBS-FA 的地聚合物可有效地提高砂土的力学性能;复合激发剂的加固效果优于单组分激发剂;低温不会明显降低地聚合物固化砂土的最终力学性能,仅延缓了地质聚合反应和结构的形成;碱性环境对地聚合物固化砂土的强度有促进作用;酸性环境及长时间暴露在空气中,会降低地聚合物固化砂土的强度。     

寒区水泥固化土力学性能影响因素分析

为了在北方寒区推广和应用水泥固化土建造保暖性房屋和设施农业,采用内蒙古黄河灌区周边典型的粉质土,利用普通硅酸盐水泥固化土体,配制水泥固化土,采用静力机械压实法和人工分层击实法分别制作了Φ50mm×H50mm和Φ39.1mm×H80mm两种不同规格的试件,并进行了无侧限抗压强度室内试验,研究了不同水泥掺入比、不同养护龄期、不同规格及成型方法对水泥固化土无侧限抗压强度的影响,得出了不同试验条件下水泥固化土的强度变化规律.试验结果表明:强度均随水泥掺入比及龄期的增大而增大,三者之间较好地满足空间平面模型,偏回归分析表明,水泥掺入比较龄期对强度的影响贡献更大,两种规格试件的强度之间较好地满足对数关系;不同规格及成型方法的试件对水泥固化土强度的影响规律不同,Φ39.1mm×H80mm试件存在一个临界水泥掺入比与临界养护龄期,当超过这个值时,其强度增长率减小.     

Influence of grain size gradation of sand impurities on strength behaviour of cement-treated clay

In nature, soils are often composed of varying amounts of clay, silt and sand. Variation of the percentage of these compositions can affect the final strength of the soils when stabilised with cement. In this study, focus was placed on clayey soils with different gradation of sand impurities up to 40% in mass. An extensive study of such clayey soils treated with cement was investigated. For the results, it is noted that water:cement ratio was a major influence of strength development of cement-treated clayey soils. In contrast, the soil:cement ratio was found to have minor effects on the strength development. The presence of sand impurities has a significant reduction on the strength development of the cement-treated clayey soil mixture due to more free water available for hydration. The use of free-water:cement ratio is adopted which was shown to be capable of adjusting for such change in amount of free water and water holding capacity of the clay which is determined with Atterberg’s liquid limit tests. The effects of gradation (fine, coarse and well-graded) of the sand impurities were found to affect strength development minimally, owing to similarities in their liquid limits when mixed with clay. Ordinary Portland cement (OPC)-treated clayey soils produced a more rapid gain in strength but lower final strength at 28 days of curing as compared with Portland blast furnace cement (PBFC). This is found to be persistent for different gradation of sand impurities. A linear correlation can be established based on the log of the unconfined compressive strengths developed at different curing age, with slopes of these linear trends found to be similar for PBFC and OPC-treated clayey soil specimens. Finally, a strength prediction model comprising of these findings is developed. The parameters adopted in this model coincide with values proposed by past studies, thereby validating the robustness of the model. The practical benefits from this study offer a quality control scheme to forecast long-term performance of cement-treated clayey soils as well as optimise cement dosage in cement stabilisation to produce a more cost-effective and less environmental-invasive usage of the technology in geotechnical applications.

     

砂土EPS颗粒混合轻质土的物理力学特性

对以砂土为原料土、以水泥为固化材料的EPS颗粒混合轻质土进行了一系列室内试验。结果表明：压实条件和含水率对其密度和强度有很大的影响,存在适宜压实次数和最优含水率;对施工含水率对其应力-应变关系的影响进行了分析,得到在水灰比一定的情况下强度与水泥的添加量的线性关系。     

Examination of the jarosite–alunite precipitate addition in the raw meal for the production of Portland and sulfoaluminate-based cement clinkers

The aim of the present research work was to investigate the possibility of adding a jarosite–alunite chemical precipitate, a waste product of a new hydrometallurgical process developed to treat economically low grade nickel oxides ores, in the raw meal for the production of Portland cement clinker. The precipitate was also tested in the production of non-expansive, sulfoaluminate-based cement clinker, as a substitute for gypsum because of its high sulfate content. For the Portland clinker, two samples of raw meals prepared, one with ordinary raw materials (reference sample) and another with 1% jarosite–alunite precipitate. Both raw meals were sintered at 1450 °C. For the sulfoaluminate-based clinker, one raw meal contained 20% gypsum (reference sample) whereas the other contained 11% of the precipitate. Both raw meals were sintered at 1300 °C. The results of chemical and mineralogical analyses as well as the microscopic examination showed that the use of the jarosite–alunite precipitate did not affect the mineralogical characteristics of the so produced Portland cement clinker. In the case of sulfoaluminate-based cement clinker, there was confirmed the formation of the sulfoaluminate phase (C₄A₃S¯), the most typical phase of this cement type.     

海水侵蚀环境下混凝土力学性能退化模型

基于混凝土干湿循环试验和混凝土细观力学,对混凝土在海水侵蚀环境下力学性能的变化进行了研究。混凝土干湿循环试验方面,采用加速腐蚀试验。对混凝土试件和根据混凝土配比制成的砂浆试件进行0、10、20、30、40、50次干湿循环,利用大型混凝土静、动三轴试验系统,检测了海水侵蚀作用对混凝土抗压强度、抗拉强度、弹性模量及应力-应变关系的影响。依据混凝土细观力学理论,对混凝土试块进行了细观数值模拟,考虑了混凝土各组成相的非均匀性、材料性质按照Weibull分布来赋值。同时,为反映海水侵蚀作用对混凝土的影响,砂浆的强度和弹性模量均以砂浆干湿循环试验所得结果为准,最后建立了混凝土随干湿循环次数变化的抗压强度折减模型,抗拉强度折减模型和弹性模量的折减模型。     

Utilization of Silica Fume to Maximize the Filler and Pozzolanic Effects of Stabilized Soil with Cement

Silica fume is identified as a pozzolan and supplementary cementitious material that can utilize to improve the mechanical properties of stabilized soil with cement. Silica fume wherein mixes with cemented soil in a proper dosage, it is susceptible to induce pozzolanic effect in cemented soil due to its fineness and high content of SiO₂ and Al₂O₃. The pozzolanic effect is vital to ensure ongoing strength of stabilized soil with cement. Up to now, stabilization of clay with cement and silica fume is not completely explored. This paper investigates: (i) the capability of utilizing the silica fume as a supplementary material for cement to maximize the filler and pozzolanic effects of compacted and stabilized soil (ii) the mechanical properties of compacted and stabilized clay with various proportions of cement and silica fume. For this purpose, a total of 120 untreated and stabilized soil admixtures were prepared by replacing ordinary Portland cement with silica fume. The influence of partial replacement of cement with silica fume on the bearing capacity, shear and compressive strength of compacted and stabilized soil was investigated. To achieve such aims, the stabilized soil specimens were examined in laboratory under direct shear, unconfined compression and California bearing ratio tests. Based on the findings of this paper the 28-day UCS of the stabilized soil with 2% partial substitution of cement with silica fume is almost 3.5-fold greater than that of the untreated. It was found that the optimum mix design for the stabilized soil is 6% cement and 2% silica fume. In conclusion, a notable discovery is that the partial substitution of cement with 2% silica fume in the optimum mix design significantly refined the pore spaces as a result of pozzolanic activity and filler effect of silica fume.