Ice‐free conditions in Sweden during Marine Oxygen Isotope Stage 3?

Wohlfarth, B. 2010: Ice‐free conditions in Sweden during Marine Oxygen Isotope Stage 3? Boreas, 10.1111/j.1502‐3885.2009.00137.x. ISSN 0300‐9483 Published and unpublished ¹⁴C dates for Sweden older than the Last Glacial Maximum ice advance were evaluated. Acceptable ¹⁴C dates indicate that age ranges for interstadial organic material in northern and central Sweden are between c. 60 and c. 35 cal. kyr BP and for similar deposits in southern Sweden are between c. 40 and c. 25 cal. kyr BP, which is in good agreement with recently derived Optical Stimulated Luminescence ages. ¹⁴C dates on mammoth remains show a larger scatter, possibly as a result of incomplete laboratory pretreatment. A possible scenario based on calibrated ¹⁴C dates from interstadial deposits is that central and northern Sweden was ice‐free during the early and middle part of Marine Oxygen Isotope Stage 3 and that southern Sweden remained ice‐free until c. 25 cal. kyr BP. A first ice advance into northern and central Sweden might have occurred as late as around 35 cal. kyr BP, more or less coeval with the Last Glacial Maximum ice advance onto the Norwegian shelf. To test the conclusions drawn here, new multi‐proxy and high‐resolution investigations of several key sites in north, central and south Sweden are required.     

Groundwater flow patterns in the San Luis Valley,Colorado, USA revisited: an evaluation of solute and isotopic data

Groundwater systems in the San Luis Valley, Colorado, USA have been re-evaluated by an analysis of solute and isotopic data. Existing stream, spring, and groundwater samples have been augmented with 154 solute and isotopic samples. Based on geochemical stratification, three groundwater regimes have been identified within 1,200 m of the surface: unconfined, upper active confined, and lower active confined with maximum TDS concentrations of 35,000, 3,500 and 600 mg/L, respectively. The elevated TDS of northern valley unconfined and upper active confined systems result from mineral dissolution, ion exchange and methanogenesis of organic and evaporate lake sediments deposited in an ancient lake, herein designated as Lake Sipapu. Chemical evolutions along flow paths were modeled with NETPATH. Groundwater ages, and δ¹³C, δ²H and δ¹⁸O compositions and distributions, suggest that mountain front recharge is the principle recharge mechanism for the upper and lower confined aquifers with travel times in the northern valley of more than 20,000 and 30,000 ¹⁴C years, respectively. Southern valley confined aquifer travel times are 5,000 ¹⁴C years or less. The unconfined aquifer contains appreciable modern recharge water and the contribution of confined aquifer water to the unconfined aquifer does not exceed 20%.     

Chronostratigraphic studies of sediments in the Negev desert, using amino acid epimerization analysis of land snail shells

The chronostratigraphy of mostly Holocene sediments in the Northern Negev desert of Israel was studied through amino acid epimerization analysis (alloisoleucine/isoleucine ratio, A/I) of individual land snail shells and ¹⁴C analysis of bulk samples of land snail shells contained within the sediments. Analysis of 31 deposits shows a very strong correlation between A/I and ¹⁴C age. A/I analyses indicate that age mixtures occur within all colluvial and in some fluvial deposits. Consequently, radiocarbon dates of bulk samples, which give an average age, overestimate the time of deposition. Sedimentation rates were generally rapid in both fluvial and colluvial deposits. Colluviation shows a maximum in the early Holocene and decreases progressively thereafter, in accordance with the change in average rainfall. Accumulation of fluvial sediments shows a distinct mid-Holocene maximum and apparently relates to the interaction between variation in rainfall, extent of bedrock exposure, and vegetation density. Late Holocene fluvial deposition may relate to agricultural activity. The understanding of the chronology of sedimentation is dependent on an integrated approach employing amino acid epimerization analysis to study age variation within a layer and ¹⁴C analyses for establishment of an absolute chronology.     

Using environmental isotopes to evaluate the renewable capacity of a typical karst groundwater system in northern China

The karst groundwater in northern China is an important source of water supply. Its capacity for self-renewal is a key factor affecting its sustainable use. The Pingyi–Feixian karst aquifer in central and southern Shandong Province is a typical karst water source, contributing 54% to the total groundwater taken from the region. In this study, 25 groups of water samples were collected from the Pingyi–Feixian karst aquifer in November 2013. The compositions of isotopes of tritium (³H), carbon-13 (¹³C), and carbon-14 (¹⁴C) were measured. As indicated by the tritium values between 7.1 and 12.2 TU, the Pingyi–Feixian karst groundwater is primarily originated from both historical atmospheric precipitation and modern precipitation. The ¹⁴C ages corrected by δ¹³C were between 146 and 5403 years. Specifically, the shallow groundwater is younger than deep groundwater. Groundwater age tends to increase along the flow path. The ages of the groundwater in recharge area were between 146 and 1348 years, while the ages of deep groundwater in flowing area were generally between 2000 and 4000 years. The ages of the groundwater in discharge area with little anthropic exploitation were larger than 4500 years, whereas these with large amounts of exploitation were less than 1500 years. The shallower the groundwater, the stronger its capacity for renewal. The renewable capacity of karst groundwater in discharge area was significantly affected by anthropic exploitation. The karst groundwater in the areas with less exploitation showed the weakest capacity, whereas that in the area with intensive exploitation was much older and had a stronger renewable capacity.     

Testing the 14C ages and conservative behavior of dissolved 14C in a carbonate aquifer in Yucca Flat,Nevada (USA), using 36Cl from groundwater and packrat middens

Corrected groundwater ¹⁴C ages from the carbonate aquifer in Yucca Flat at the former Nevada Test Site (now the Nevada National Security Site), USA, were evaluated by comparing temporal variations of groundwater ³⁶Cl/Cl estimated with these ¹⁴C ages with published records of meteoric ³⁶Cl/Cl variations preserved in packrat middens (piles of plant fragments, fecal matter and urine). Good agreement between these records indicates that the groundwater ¹⁴C ages are reasonable and that ¹⁴C is moving with chloride without sorbing to the carbonate rock matrix or fracture coatings, despite opposing evidence from laboratory experiments. The groundwater ¹⁴C ages are consistent with other hydrologic evidence that indicates significant basin infiltration ceased 8,000 to 10,000 years ago, and that recharge to the carbonate aquifer is from paleowater draining through overlying tuff confining units along major faults. This interpretation is supported by the relative age differences as well as hydraulic head differences between the alluvial and volcanic aquifers and the carbonate aquifer. The carbonate aquifer ¹⁴C ages suggest that groundwater velocities throughout much of Yucca Flat are about 2 m/yr, consistent with the long-held conceptual model that blocking ridges of low-permeability rock hydrologically isolate the carbonate aquifer in Yucca Flat from the outlying regional carbonate flow system.     

The central Australian groundwater discharge zone: Evolution of associated calcrete and gypcrete deposits

The groundwater discharge zone of central Australia is marked by a chain of playas extending 500 km from Lake Hopkins in Western Australia through Lake Neale, Lake Amadeus and numerous smaller playas to the Finke River in the Northern Territory. This great valley is devoid of surface drainage, and the playas and their associated landforms and chemical sediments are a result of groundwater transmission, and discharge from a large regional flow system. The valley contains extensive groundwater calcrete deposits, which are commonly silicified. The playas contain gypsum and glauberite deposits resulting from the evaporative concentration of discharging groundwater to 250 g/1total dissolved solids. Thin gypcrete crusts have developed on the playa margins and islands as a result of induration of bordering gypsum dunes. Diagenetic changes in the calcrete and gypcrete are caused by dissolution and reprecipitation through groundwater movement.

Calcrete and gypcrete samples from playas near Curtin Springs, NT, dated by electron spin resonance (ESR) — calibrated by ¹⁴C dates on calcrete and the uranium content of gypcrete — are mostly in the range 8000–16 000 years BP, and are evidence of groundwater discharge conditions similar to those of the present day. Calcrete in the vadose zone, above the present water‐table, gives ESR dates in the range 22 000–27 000 years BP suggesting episodes of high intensity rainfall at that time. Phreatic calcrete, below the water‐table, with ages in the range 34 000–75 000 years BP, provides evidence of older episodes of calcretization.

The ESR and ¹⁴C dates for the chemical sediments suggest that this groundwater flow system has been an important feature in the region for much of the Late Quaternary. Although there are problems with the interpretation of ESR dating for chemical sediments with diagenetic alteration, the technique shows promise as a dating tool.     

Chronology of the shell bar section and a discussion on the ages of the Late Pleistocene lacustrine deposits in the paleolake Qarhan, Qaidam basin

Shell bar, composed of abundant fossil shells of Corbicula fluminea müller and Corbicula largillierti philippi and located at the southeastern end (36°30′N, 96°12′E) of the paleolake Quarhan, is one of the most prominent features in the Qaidam basin. It is the highest site where such species of fossil shells have been found in the Late Pleistocene age. A 2.6-m-thick fresh profile was manually excavated to determine the formation ages and the scope of the high paleolake levels. Accelerator mass spectrometry (AMS), conventional radiocarbon dating, and sector inductively coupled plasma-mass spectroscopy ²³⁰Th methods were used to investigate the reliability and accuracy of dating results in different laboratories. Ages of various components (e.g. acid residual and acid soluble fraction of the organic matter) from the same sample were determined. Age differences of a variety of materials (e.g. organic matter, fossil shells, and salt crystals), and age differences at the same sampling position were evaluated. Dating shows that the AMS ages given by alkali residue and acid soluble fractions vary greatly, e.g., from 124.5 cm upwards. The dates given by the acid soluble fraction were normal. Down the column, the dates show a reverse pattern and those of alkali residues, especially the lower part of the section, show an unstable pattern. These imply that organic matter had been influenced by two separate processes. One possible explanation is that the alkali residual fraction most likely had been contaminated by dead carbon-bearing reworked material because the study section is located near the edge of the paleolake and could have been easily influenced by old eroded deposits. Another is that the acid soluble fraction could have been contaminated by upward-flowing groundwater containing soluble organic matter. The amount of this soluble organic material should be very small because the strongest age reversal is in the lower part, where the TOC content remains low, meaning that the change of soluble organic fraction alters neither TOC content nor the δ ¹³C dramatically. It is concluded that a uniform mega-paleolake developed in the Qaidam basin in the northeastern Tibetan plateau between 39.7 and 17.5 ¹⁴C kaB.P. During the period when the high paleolake level of Qarhan was formed, the huge paleolake covered a vast area with dramatic lake level fluctuations. It is found that the ages determined may be influenced by either radioactive ¹⁴C variations of repeated deposition or content variations in the atmosphere. The ages given by fossil shells are 15–18 ka older than those given by organic matter. The large differences between the ages of fossil shells and organic matter might have resulted from the large water areas and huge water volume and the special location of the high-elevation Qaidam basin. This study also shows the reliability and accuracy of the ²³⁰Th dating method on the salt crystals but further study is needed to determine whether this method could be applied to the study area. __________ Translated from Quaternary Sciences, 2007, 27(4): 511–521 [译自: 第四纪研究]     

Late Quaternary sea level and environmental changes from relic carbonate deposits of the western margin of India

Relic carbonate deposits along the western margin of India occur as dolomite crusts, aragonite sands (pelletal / oolitic) and aragonite-cemented limestones, oyster shells, corals, encrusted coralline algal and foraminiferal-dominated nodules. The petrology and mineralogy of the deposits indicate that except for aragonite sands and foraminiferal nodules, the others were formed in shallow marine conditions and serve as sea level indicators. Radiocarbon dates were measured for 62 relic deposits covering the entire margin. The age of these deposits on the continental shelf off Cape Comorin and Mangalore, between 110 and 18 m depth, ranges between 12, 610¹⁴C yr BP and 6,390¹⁴C yr BP. On the northwestern margin of India, especially on the carbonate platform (between 64 and 100 m), the age ranges from 17,250 to 6,730¹⁴C yr BP. The relic deposits of the Gulf of Kachchh at depths between 35 and 25 m are dated at 12,550–9,630¹⁴C yr BP. The age vs. depth plot of the relic deposits further indicates that the Gulf of Kachchh was inundated much early, atleast by 15 ka, after the Last Glacial Maximum, and was subjected to uplift and subsidence during the Holocene. The carbonate platform subsided during the early Holocene. Some of the relic deposits between Cape Comorin and Mangalore plot on or, closely follow the glacio-eustatic sea level curve. Despite abundant siliciclastic flux discharged by the Narmada and Tapti during the early Holocene, the platform off these rivers is largely devoid of this flux and carbonate sedimentation continued until 6,700¹⁴C yr BP. We suggest that the river-derived sediment flux diverted southwards under the influence of the SW monsoon current and, thereby, increased the turbidity on the shelf and slope southeast of the carbonate platform and facilitated the formation of deeper water foraminiferal nodules off Vengurla-Goa.     

Chronologies of sedimentary changes in the south Bohai Sea,China: constraints from luminescence and radiocarbon dating

The alternation of terrestrial and marine deposits is an indicator of past environmental and sea‐level changes. The age of deposition is usually dated by means of radiocarbon. However, radiocarbon dates of molluscan shells from coastal areas may be complicated by various sources of carbon, and problematic for deposits of 40–50 ka or older. Herein, we apply the Optically Stimulated Luminescence (OSL) dating method to date samples from terrestrial and marine/coastal sediments extracted from three cores in the south Bohai Sea, China. Multiple‐ and single‐aliquot regenerative‐dose procedures using OSL signals from fine‐silt (4–11 μm), coarse‐silt (38–63 μm) and fine‐sand (63–90 or 90–125 μm) quartz were employed to determine the equivalent dose (D _e). The results showed that: (i) OSL ages from quartz of different grain sizes and different protocols are consistent with each other; (ii) for Holocene samples, most of the radiocarbon dates agree well with OSL ages; (iii) for pre‐Holocene samples, radiocarbon dates cluster at 40–50 ¹⁴ C ka BP, whereas OSL ages are in stratigraphic order from 11 ka to 176 ka. Because of the self‐consistency of the quartz OSL ages, the stratigraphic agreement in the three cores, and the clustering of the radiocarbon dates, we suggest that the quartz OSL ages are more reliable with respect to dating the samples from the south Bohai Sea. Finally, the four marine strata identified in the south Bohai Sea are likely to have formed during the Holocene, Marine Isotopic Stage (MIS) 3–5, MIS 6 and probably MIS 7, respectively.     

Sea Level Changes in the Last Several Thousand Years, Penghu Islands, Taiwan Strait

Holocene shore-face and beach-face deposits form plains <5 m above present sea level along Taiwan Strait. We measured the¹⁴C ages of detrital mollusk shells and coral in such deposits at the Penghu Islands. Twelve carbonate samples—mainly from the largest island, Makung—were dated. Age measurements for two coral samples and one mollusk sample from the same outcrop imply that the¹⁴C ages of mollusk shells give the best approximation of depositional age. The highest Holocene relative sea level in the Penghu Islands occurred about 4700 years ago with a height about 2.4 m above the present sea level. Thereafter, relative sea level appreciably fell without detectable fluctuations to its recent position. Our sea level data are consistent with other studies from the central and western Pacific, except for the timing of peak sea level position. This variation may reflect local crustal response to hydroisostatic effects on the continental shelf.     

Development of climatic and vegetation conditions and the geochemical and isotopic composition in the Franconian Albvorland aquifer system

The impact of climatic and vegetation conditions over the past 15 Ka on the chemical composition and ¹⁴C dating of groundwater from the Franconian Albvorland aquifer system is discussed. Seven groundwaters over a flow distance of 25.5 km are investigated. Groundwater dating is made by ¹⁴C of dissolved inorganic carbon (DIC) and aqueous fulvic acid as well as ¹⁸O. ¹⁴C dating via fulvic acid gives groundwater ages consistent with climatic and vegetation records and variations in the groundwater composition. No correction for geochemical processes is required, since under these geochemical conditions fulvic acid remains stable over this time period and flow-distance. On the other hand, ¹⁴C dating via DIC requires correction of the ¹⁴C value due to perturbation by different geochemical processes. Up to a groundwater flow distance of approximately 17 km and an age of about 10 Ka, the ¹⁴C dating by DIC shows considerable dependence on the ¹⁴C-correction model applied. Beyond this groundwater age, ¹⁴C-DIC dating results in an overestimation by two to three ¹⁴C half-lives (T_1/2=5730 a). This deviation may result from different groundwater recharge conditions at the end of the past glaciation and geochemical processes acting on DIC that cannot be adequately characterized. The present study has implications for humic substance mediated transport of pollutants in natural aquatic systems over long time periods.     

Evidence of probable paleotsunami deposits on Kho Khao Island, Phang Nga Province, Thailand

The 2004 tsunami deposits and probable paleotsunami deposits were studied at the southern Kho Khao Island, on Andaman Sea coast of Thailand. The 2004 tsunami laid down about 8?cm of fining upward medium sand and locally about 40?cm of massive coarse sand with common mud clasts. The sediments were characterized by the presence of marine foraminiferal assemblage; however, already after 5?years many of carbonate foraminiferal tests were partly or completely dissolved. The probable paleotsunami deposits form layer about 1?m thick. It consists of massive very coarse sand with common big shells and mud clasts. Its composition suggests a marine origin and the presence of mud clasts, and similarity to the 2004 tsunami deposits suggests that the layer was left by paleotsunami, which took place probably during the late Holocene, even though two shells within the layer gave ¹⁴C ages of 40,000?years or more.     

Dating megafaunal extinction on the Pleistocene Darling Downs,eastern Australia: the promise and pitfalls of dating as a test of extinction hypotheses

A key to understanding Late Pleistocene megafaunal extinction dynamics is knowledge of megafaunal ecological response(s) to long-term environmental perturbations. Strategically, that requires targeting fossil deposits that accumulated during glacial and interglacial intervals both before and after human arrival, with subsequent palaeoecological models underpinned by robust and reliable chronologies. Late Pleistocene vertebrate fossil localities from the Darling Downs, eastern Australia, provide stratigraphically-intact, abundant megafaunal sequences, which allows for testing of anthropogenic versus climate change megafauna extinction hypotheses. Each stratigraphic unit at site QML796, Kings Creek Catchment, was previously shown to have had similar sampling potential, and the basal units contain both small-sized taxa (e.g., land snails, frogs, bandicoots, rodents) and megafauna. Importantly, sequential faunal horizons show stepwise decrease in taxonomic diversity with the loss of some, but not all, megafauna in the geographically-small palaeocatchment. The purpose of this paper is to present the results of our intensive, multidisciplinary dating study of the deposits (>40 dates). Dating by means of accelerator mass spectrometry (AMS) ¹⁴C (targeting bone, freshwater molluscs, and charcoal) and thermal ionisation mass spectrometry U/Th (targeting teeth and freshwater molluscs) do not agree with each other and, in the case of AMS ¹⁴C dating, lack internal consistency. Scanning electron microscopy and rare earth element analyses demonstrate that the dated molluscs are diagenetically altered and contain aragonite cements that incorporated secondary young C, suggesting that such dates should be regarded as minimum ages. AMS ¹⁴C dated charcoals provide ages that occur out of stratigraphic order, and cluster in the upper chronological limits of the technique (～40–48 ka). Again, we suggest that such results should be regarded as suspicious and only minimum ages. Subsequent OSL and U/Th (teeth) dating provide complimentary results and demonstrate that the faunal sequences actually span ～120–83 ka, thus occurring beyond the AMS ¹⁴C dating window. Importantly, the dates suggest that the local decline in biological diversity was initiated ～75,000 years before the colonisation of humans on the continent. Collectively, the data are most parsimoniously consistent with a pre-human climate change model for local habitat change and megafauna extinction, but not with a nearly simultaneous extinction of megafauna as required by the human-induced blitzkrieg extinction hypothesis. This study demonstrates the problems inherent in dating deposits that lie near the chronological limits of the radiocarbon dating technique, and highlights the need to cross-check previously-dated archaeological and megafauna deposits within the timeframe of earliest human colonisation and latest megafaunal survival.     

Constraining groundwater flow,residence times,inter-aquifer mixing,and aquifer properties using environmental isotopes in the southeast Murray Basin,Australia

Environmental isotopes (particularly δ¹⁸O, δ²H, and δ¹³C values, ⁸⁷Sr/⁸⁶Sr ratios, and a¹⁴C) constrain geochemical processes, recharge distribution and rates, and inter-aquifer mixing in the Riverine Province of the southern Murray Basin. Due to methanogenesis and the variable δ¹³C values of matrix calcite, δ¹³C values are highly variable and it is difficult to correct ¹⁴C ages using δ¹³C values alone. In catchments where δ¹³C values, ⁸⁷Sr/⁸⁶Sr ratios, and major ion geochemistry yield similar a¹⁴C corrections, ∼15% of the C is derived from the aquifer matrix in the silicate-dominated aquifers, and this value may be used to correct ages in other catchments. Most groundwater has a¹⁴C above background (∼2 pMC) implying that residence times are <30 ka. Catchments containing saline groundwater generally record older ¹⁴C ages compared to catchments that contain lower salinity groundwater, which is consistent with evapotranspiration being the major hydrogeochemical process. However, some low salinity groundwater in the west of the Riverine Province has residence times of >30 ka probably resulting from episodic recharge during infrequent high rainfall episodes. Mixing between shallower and deeper groundwater results in ¹⁴C ages being poorly correlated with distance from the basin margins in many catchments; however, groundwater flow in palaeovalleys where the deeper Calivil–Renmark Formation is coarser grained and has high hydraulic conductivities is considerably more simple with little inter-aquifer mixing. Despite the range of ages, δ¹⁸O and δ²H values of groundwater in the Riverine Province do not preserve a record of changing climate; this is probably due to the absence of extreme climatic variations, such as glaciations, and the fact that the area is not significantly impacted by monsoonal systems.     

Radiocarbon dating of dissolved inorganic carbon in groundwater from confined parts of the Upper Floridan aquifer, Florida, USA

Geochemical reaction models were evaluated to improve radiocarbon dating of dissolved inorganic carbon (DIC) in groundwater from confined parts of the Upper Floridan aquifer in central and northeastern Florida, USA. The predominant geochemical reactions affecting the ¹⁴C activity of DIC include (1) dissolution of dolomite and anhydrite with calcite precipitation (dedolomitization), (2) sulfate reduction accompanying microbial degradation of organic carbon, (3) recrystallization of calcite (isotopic exchange), and (4) mixing of fresh water with as much as 7% saline water in some coastal areas. The calculated cumulative net mineral transfers are negligibly small in upgradient parts of the aquifer and increase significantly in downgradient parts of the aquifer, reflecting, at least in part, upward leakage from the Lower Floridan aquifer and circulation that contacted middle confining units in the Floridan aquifer system. The adjusted radiocarbon ages are independent of flow path and represent travel times of water from the recharge area to the sample point in the aquifer. Downgradient from Polk City (adjusted age 1.7 ka) and Keystone Heights (adjusted age 0.4 ka), 14 of the 22 waters have adjusted ¹⁴C ages of 20–30 ka, indicating that most of the fresh-water resource in the Upper Floridan aquifer today was recharged during the last glacial period. All of the paleowaters are enriched in ¹⁸O and ²H relative to modern infiltration, with maximum enrichment in δ¹⁸O of approximately 2.0‰. Electronic Publication     

Glacial advances constrained by Be exposure dating of bedrock landslides, Kyrgyz Tien Shan

Numerous large landslide deposits occur in the Tien Shan, a tectonically active intraplate orogen in Central Asia. Yet their significance in Quaternary landscape evolution and natural hazard assessment remains unresolved due to the lack of "absolute" age constraints. Here we present the first ¹⁰Be exposure ages for three prominent (> 10⁷ m³) bedrock landslides that blocked major rivers and formed lakes, two of which subsequently breached, in the northern Kyrgyz Tien Shan. Three ¹⁰Be ages reveal that one landslide in the Alamyedin River occurred at 11–15 ka, which is consistent with two ¹⁴C ages of gastropod shells from reworked loess capping the landslide. One large landslide in Aksu River is among the oldest documented in semi-arid continental interiors, with a ¹⁰Be age of 63–67 ka. The Ukok River landslide deposit(s) yielded variable ¹⁰Be ages, which may result from multiple landslides, and inheritance of ¹⁰Be. Two ¹⁰Be ages of 8.2 and 5.9 ka suggest that one major landslide occurred in the early to mid-Holocene, followed by at least one other event between 1.5 and 0.4 ka. Judging from the regional glacial chronology, all three landslides have occurred between major regional glacial advances. Whereas Alamyedin and Ukok can be considered as postglacial in this context, Aksu is of interglacial age. None of the landslide deposits show traces of glacial erosion, hence their locations and ¹⁰Be ages mark maximum extents and minimum ages of glacial advances, respectively. Using toe-to-headwall altitude ratios of 0.4–0.5, we reconstruct minimum equilibrium-line altitudes that exceed previous estimates by as much as 400 m along the moister northern fringe of the Tien Shan. Our data show that deposits from large landslides can provide valuable spatio-temporal constraints for glacial advances in landscapes where moraines and glacial deposits have low preservation potential.     

In situ feldspar dissolution rates in an aquifer

In situ silicate dissolution rates within the saturated Navajo sandstone, at Black Mesa, Arizona were determined from elemental fluxes in the aquifer. The mass transfer between groundwater and mineral matrix along flow paths was calculated from inverse mass balance modeling. The reaction time is bound by ¹⁴C-based travel time. BET surface areas were measured with N₂ gas adsorption. Dissolution rates for K-feldspar and plagioclase are 10⁻¹⁹ and 10⁻¹⁶ mol (feldspar) m⁻² s⁻¹, respectively, which are ∼10⁵ times slower than laboratory experiment-derived rates under similar pH and temperature but at far from equilibrium conditions. The rates obtained in this study are consistent with the slower field rates found in numerous watershed and soil profile studies. However, these rates are from saturated aquifers, overcoming some concerns on estimated rates from unsaturated systems. The Navajo sandstone is a quartz-sandstone with a relatively simple and well-studied hydrogeology, groundwater geochemistry, and lithology, a large number of groundwater analyses and ¹⁴C groundwater ages, groundwater residence times up to ∼37 ky, groundwater pH from ∼8 to 10, and temperature from ∼15 to 35°C.     

Associated terrestrial and marine fossils in the late-glacial Presumpscot Formation, southern Maine, USA, and the marine reservoir effect on radiocarbon ages

Excavations in the late-glacial Presumpscot Formation at Portland, Maine, uncovered tree remains and other terrestrial organics associated with marine invertebrate shells in a landslide deposit. Buds of Populus balsamifera (balsam poplar) occurred with twigs of Picea glauca (white spruce) in the Presumpscot clay. Tree rings in Picea logs indicate that the trees all died during winter dormancy in the same year. Ring widths show patterns of variation indicating responses to environmental changes. Fossil mosses and insects represent a variety of species and wet to dry microsites. The late-glacial environment at the site was similar to that of today's Maine coast. Radiocarbon ages of 14 tree samples are 11,907 ± 31 to 11,650 ± 50 ¹⁴C yr BP. Wiggle matching of dated tree-ring segments to radiocarbon calibration data sets dates the landslide occurrence at ca. 13,520 + 95/−20 cal yr BP. Ages of shells juxtaposed with the logs are 12,850 ± 65 ¹⁴C yr BP (Mytilus edulis) and 12,800 ± 55 ¹⁴C yr BP (Balanus sp.), indicating a marine reservoir age of about 1000 yr. Using this value to correct previously published radiocarbon ages reduces the discrepancy between the Maine deglaciation chronology and the varve-based chronology elsewhere in New England.     

Optical dating of tsunami-laid sand from an Oregon coastal lake

Optical ages for five samples of tsunami-laid sand from an Oregon coastal lake were determined using an infrared optical-dating method on K-feldspar separates and, as a test of accuracy, compared to ages determined by AMS ¹⁴C dating of detrital plant fragments found in the same beds. Two optical ages were about 20% younger than calibrated ¹⁴C ages of about 3.1 and 4.3 ka. Correction of the optical ages using measured anomalous fading rates brings them into agreement with the ¹⁴C ages. The approach used holds significant promise for improving the accuracy of infrared optical-dating methods.Luminescence data for the other three samples result in optical age limits much greater than the ¹⁴C ages. These data provide a textbook demonstration of the correlation between scatter in the luminescence intensity of individual sample aliquots and their normalization values that is expected when the samples contain sand grains not adequately exposed to daylight just prior to or during deposition and burial. Thus, the data for these three samples suggest that the tsunamis eroded young and old sand deposits before dropping the sand in the lake.     

Radiocarbon dates from the East China sea and their geological implications

Radiocarbon analysis plays an important role in studying the Quaternary geologic history of the East China Sea. More than 200 ¹⁴C dates have been published in various Chinese publications. The continental shelf of the East China Sea is one of the few large continental shelves in the world. Many low-lying flats and deltaic plains lie along the coast making it a favorable site for sea-level studies. Radiocarbon data from Neolithic sites, chenier ramparts, peaty deposits, and submarine sediments converge to suggest that oscillations of sea level have occurred: they also suggest that the lowest glacial sea levels probably occurred between 22,000 and 19,000 yr B.P. Calculation of the volume of the Yangtze River Delta, together with ¹⁴C dates, indicates that more than 89% of the solid particles carried by the river were deposited in the delta. Due to the sedimentary load, the crust beneath the delta has subsided isostatically and tilted seaward. Marine shells provide many acceptable ¹⁴C dates, but because they are easily transported, most samples from the continental shelf cannot be directly related to the history of sea-level changes.