Experiments On Buoyant Plume Dispersion In A Laboratory Convection Tank

Plume dispersion in the convective boundary layer (CBL) is investigated experimentally in a laboratory convection tank. The focusis on highly-buoyant plumes that loft near or become trapped in the CBL capping inversion and resistdownward mixing. Such plumes are defined by dimensionless buoyancy fluxes F_* 0.1, where F_* = F_b/(U w_* ² z_i), F_b is the stack buoyancy flux,U is the mean wind speed, w_* is the convective velocity scale, and z_i is the CBL depth. The aim is to obtain statistically-reliable mean (C) and root-mean-square (rms, _c) concentration fields as a function of F_* and the dimensionless distance X = w_*x/(U z_i), where x is the distance downstream of the source.The experiments reveal the following mainresults: (1) For 3 X 4and F_* 0.1, the crosswind-integrated concentration (CWIC) fields exhibit distinctly uniform profiles below z_i with a CWIC maximum aloft, in contrast to the nonuniform profiles obtained earlier by Willis and Deardorff. (2) The lateral dispersion (_y) variation with X is consistent with Taylor's theory for _* 0.1 and a buoyancy-enhanced dispersion, _y/z_i F_* ^1/3X^2/3, forF_* = 0.2 and 0.4. (3) The entrapment, the plume fraction above z_i, has a mean (E) that follows a systematic variationwith X and F_*, and a variability (_e/E) that is broad ( 0.3 to 2) near the source but subsides to 0.25 far downstream. (4) Vertical profiles of the concentration fluctuation intensity (c/C) are uniform for z < z_i and X > 1.5, but exhibit significant increases: (a) at the surface and close to the source (X 1.5), and(b) in the entrainment zone. (5) The cumulative distribution functions (CDFs) of the scaled concentration fluctuations (c/_c) separate into mixed-layer and entrainment-layer CDFs for X 2, with the mixed-layer group collapsing to a single distribution independent of z.These are the first experiments to obtain all components of the lateral and vertical dispersion parameters (rms meander, relative dispersion, total dispersion) for continuous buoyant releases in a convection tank. They also are the first tank experiments to demonstrate agreement with field observations of: (1) the scaled ground-level concentration along the plume centreline, and (2) the dimensionless lateral dispersion _y/z_i of buoyant plumes.     

An atmospheric dispersion model with continuous vertical variation of dispersion parameters

Summary A dispersion model is proposed to predict the continuous vertical variation of the dispersion parameters _y and _z in case of hot pollutant release to the atmosphere. In such a case, the plume rises far above the ground and is subject to varying levels of turbulence. The framework in this paper can be divided into three approaches: (1) determination of the eddy diffusivitiesK _y (z, _y ) andK _z (z, _z ) as functions of height above ground and plume dimensions, (2) determination of both the plume rise and its vertical velocity using a modified version of Brigg's formula, and (3) numerical solution of actual problems with buoyant plumes at each time step. The model results have been applied to a case of pollutant release from fire destruction of a chemical storehouse roof.With 15 Figures     

Variability of surface roughness and turbulence intensities at a coastal site in India

Surface-layer features with different prevailing wind directions for two distinct seasons (Southwest Monsoon and Northeast Monsoon) on the west coast of India are studied using data obtained from tower-based sensors at a site located about 500 m from the coast. Only daytime runs have been used for the present analysis. The surface boundary-layer fluxes have been estimated using the eddy correlation method. The surface roughnessz ₀ obtained using the stability-corrected wind profiles (Paulson, 1970) has been found to be low for the Southwest monsson season. For the other season,z ₀ is relatively high. The drag coefficientC _D varies with height in the NE monsoon season but not in the season with lowz ₀. This aspect is reflected in the wind profiles for the two seasons and is discussed in detail. The scaling behaviour of friction velocityu _* and the turbulence intensity of longitudinal, lateral and vertical winds _u, _v and _w, respectively) are further examined to study their dependence on fetch. Our study shows that for the non-dimensional case, _u/u_* and _v/u_* do not show any surface roughness dependence in either season. On the other hand, for _w/u_* for the season with lowz ₀, the values are seen to agree well with that of Panofskyet al. (1977) for homogeneous terrain whereas for the other season with highz ₀, the results seem to conform more to the values observed by Smedman and Högström (1983) for coastal terrain. The results are discussed in the light of observations by other investigators.     

Statistics of Surface-Layer Turbulence Over Terrain with Metre-Scale Heterogeneity

Refuge has patchy vegetation in sandy soil. During midday and at night, the surface sources and sinks for heat and moisture may thus be different. Although the Sevilleta is broad and level, its metre-scale heterogeneity could therefore violate an assumption on which Monin-Obukhov similarity theory (MOST) relies. To test the applicability of MOST in such a setting, we measured the standard deviations of vertical (_w) and longitudinal velocity (_u), temperature (_t), and humidity (_q), the temperature-humidity covariance (¯tq), and the temperature skewness (S_t). Dividing the former five quantities by the appropriate flux scales (u_*, _*, and q_*) yielded the nondimensional statistics _w/u_*, _u/u_*, _t/|t_*|, _q/|q_*|, and ¯tq/t_*q_*. _w/u_*, _t/|t_*|, and S_t have magnitudes and variations with stability similar to those reported in the literature and, thus, seem to obey MOST. Though _u/u_* is often presumed not to obey MOST, our _u/u_* data also agree with MOST scaling arguments. While _q/|q_*| has the same dependence on stability as _t/|t_*|, its magnitude is 28% larger. When we ignore ¯tq/t_*q_* values measured during sunrise and sunset transitions – when MOST is not expected to apply – this statistic has essentially the same magnitude and stability dependence as (_t/t_*)². In a flow that truly obeys MOST, (_t/t_*)², (_q/q_*)², and ¯tq/t_*q_* should all have the same functional form. That (_q/q_*)² differs from the other two suggests that the Sevilleta has an interesting surface not compatible with MOST. The sources of humidity reflect the patchiness while, despite the patchiness, the sources of heat seem uniformly distributed.     

Standard deviation of vertical two-point longitudinal velocity differences in the atmospheric boundary layer

The standard deviation of vertical two-point longitudinal velocity fluctuation differences is analyzed experimentally with eleven sets of turbulence measurements obtained at the NASA 150-m ground-winds tower site at Cape Kennedy, Florida. It is concluded that /u _*0 is proportional to (fz/u _*0)^0.22, where the coefficient of proportionality is a function of fz/u _*0 and u _*0/fL ₀. The quantities f and L₀ denote the Coriolis parameter and the surface Monin-Obukhov stability length, respectively; u _*0 is the surface friction velocity; z is the vertical distance between the two points over which the velocity difference is calculated; and zz is the mean height of the mid-point of the interval z above natural grade. The results of the analysis are valid for 20<-u _*0/fL ₀<2000.     

Incorporation of internal fluctuations in a meandering plume model of concentration fluctuations

A meandering plume model that explicitly incorporates the effects of small-scale structure in the instantaneous plume has been formulated. The model requires the specification of two physically based input parameters; namely, the meander ratio,M, which is dependent on the ratio of the meandering plume dispersion to the instantaneous relative plume dispersion and, a relative in-plume fluctuation measure,k, that is related inversely to the fluctuation intensity in relative coordinates. Simple analytical expressions for crosswind profiles of the higher moments (including the important shape parameters such as fluctuation intensity, skewness, and kurtosis) and for the concentration pdf have been derived from the model. The model has been tested against some field data sets, indicating that it can reproduce many key aspects of the observed behavior of concentration fluctuations, particularly with respect to modeling the change in shape of the concentration pdf in the crosswind direction.List of Symbols C Mean concentration in absolute coordinates - C _r Mean concentration in relative coordinates - C₀ Centerline mean concentration in absolute coordinates - C _r,0 Centerline mean concentration in relative coordinates - f Probability density function of concentration in absolute coordinates - f _c Probability density function of plume centroid position - f _r Probability density function of concentration in relative coordinates - i Absolute concentration fluctuation intensity (standard deviation to mean ratio) - i _r Relative concentration fluctuation intensity (standard deviation to mean ratio) - k Relative in-plume fluctuation measure:k=1/i _r ² - K Concentration fluctuation kurtosis - M Meander ratio of meandering plume variance to relative plume variance - S Concentration fluctuation skewness - x Downwind distance from source - y Crosswind distance from mean-plume centerline - z Vertical distance above ground - Instantaneous (random) concentration - Crosswind dispersion ofnth concentration moment about zero - _ny Mean-plume crosswind (absolute) dispersion - _y Plume centroid (meandering) dispersion in crosswind direction - _y,c Instantaneous plume crosswind (relative) dispersion - Normalized mean concentration in absolute coordinates:C/C ₀ - Particular value taken on by instantaneous concentration,      

Markov chain simulations of vertical dispersion in the neutral surface layer for surface and elevated releases

Vertical dispersion in the neutral surface layer is investigated using a Markov Chain simulation procedure. The conceptual basis of the procedure is discussed and computation procedures outlined. Wind and turbulence parameterizations appropriate to the neutral surface layer are considered with emphasis on the Lagrangian time scale. Computations for a surface release are compared with field data. Good agreement is found for the variation of surface concentration and cloud height to distances 500 m downwind of the source. The functional form of the vertical concentration profile is examined and an exponential with exponent 1.6 is found to give the best fit with simulations.For elevated releases, it is demonstrated that an initial dip of the mass mean height from the simulation can be normalized for various release heights using a non-dimensionalized downwind coordinate incorporating advective wind speed and wind shear. The vertical distribution standard deviation ( _z ), as employed in Gaussian models, shows a fair degree of independence with source height but close examination reveals an optimum source height for maximum _z at a given downwind distance,x. This source height increases with downwind distance. Also the simulations indicate that vertical wind shear is more important than vertical variation of Lagrangian time scale close to the source, with a reverse effect farther downwind.     

The Interference of Higher-Order Statistics of the Concentration Field Produced by Two Point Sources According to a Generalized Fluctuating Plume Model

The higher-order correlation functions for the concentrationfluctuations arising from a two-point-source configuration have beencalculated analytically within the context of the phenomenology of afluctuating plume model (viz., a meandering plume model that explicitlyincorporates internal fluctuations). Explicit expressions for thesecond-, third-, and fourth-order correlationfunctions between the concentrationfluctuations produced by two point sources are given in terms of the sourceseparation d and the five physically based parameters that define thegeneralized fluctuating plume model: namely, the absolute plume dispersion,_a, which determines the outer plume length scale; the relative plume dispersion, _r, which determines the inner plume length scale; the fluctuation intensity, i_r, in relative coordinates, which determines the internal concentration fluctuation level; the correlation coefficient, r,between the positions of the centroids of the two interfering plumes; and,the correlation coefficient, r^*, between the concentration fluctuationsof the two plumes in relative coordinates, which determines the degree ofinternal mixing of the two scalars. Furthermore, the form of the totalconcentration probability density function arising from the interferenceproduced by two point sources is presented. Predictions for the second-ordercorrelation function, , and for the total concentration probabilitydensity function have been compared with some new experimental data fora two-point-source configuration in grid turbulence generated in awater-channel simulation. These results are in good agreement with the dataand suggest that the analytical model for the second-order correlationfunction and the total concentration probability density function canreproduce many qualitative trends in the interaction of plumes from twosources.     

Local Similarity Relationships In The Urban Boundary Layer

To investigate turbulent structures in an urban boundary layer (UBL) with many tallbuildings, a number of non-dimensional variable groups based on turbulent observationsfrom a 325-m meteorological tower in the urban area of Beijing, China, are analyzedin the framework of local similarity. The extension of surface-layer similarity to localsimilarity in the stable and unstable boundary layer is also discussed. According to localsimilarity, dimensionless quantities of variables: e.g., velocity and temperature standarddeviations _i/u_*l (i=u,v,w) and_T/T_*l,correlation coefficients of uw and wT covariance, gradients of wind and temperature_m and _h, and dissipation rates of turbulent kinetic energy (TKE) andtemperature variance and _N can be represented as a functiononly of a local stability parameter z/, where is the local Obukhovlength and z is the height above ground. The average dissipation rates of TKE andtemperature variance are computed by using the u spectrum, and the uw and wTcospectra in the inertial subrange. The functions above were found to be in a goodagreement with observational behaviour of turbulence under unstable conditions, butthere were obvious differences in the stable air.     

Diurnal variation of horizontal wind direction fluctuations in complex terrain at Geysers,Cal.

Horizontal diffusion in the surface layer is dependent on the standard deviation of wind direction fluctuations . Diurnal variation of this parameter in complex terrain was studied for the July 1979 Geysers, Cal., experiment using data from a network of 11 short meteorological towers in the 25 km² Anderson Creek watershed Valley side slopes are roughly 20 ° and maximum terrain difference is about 1 km.Values of for wind directions sampled for one hour at a height of 10 m are about 35 ° during the daytime. They slowly decrease to about 20 ° by 8 to 10 p.m. as stability increases but wind speeds are still relatively high. After 10 p.m. the drainage flow sets in at most stations, with speeds of 1 to 2 m s^-1, and average increases to about 30° during the period 11 p.m. to 6 a.m. In general, highest values of at night are associated with lowest values of wind speed and greatest static stability. This enhancement of by the terrain suggests that horizontal diffusion at night always conforms to that expected during nearly neutral stabilities. That is, Pasquill class D diffusion applies to the horizontal component all night in complex terrain.     

Numerical simulation of particle trajectories in inhomogeneous turbulence,II: Systems with variable turbulent velocity scale

It is shown that for the purpose of trajectory simulation, the vertical velocityw _L (t) of a fluid element, which is moving in a system (such as a forest canopy, or the unstably stratified atmospheric surface layer) whose turbulent velocity scale _w is height-dependent, must be chosen from a frequency-distribution which is asymmetric aboutw _L = 0. If the gradient _w /z varies only slowly with height, correct trajectories may be obtained by adding a bias (where _L is the length scale) to a fluctuating velocity chosen from a symmetric distribution with variance _w ²(z).     

Estimation of Scalar Source/Sink Distributions in Plant Canopies Using Lagrangian Dispersion Analysis: Corrections for Atmospheric Stability and Comparison with a Multilayer Canopy Model

Source/sink distributions of heat, water vapour andCO₂ within a rice canopy were inferred using aninverse Lagrangian dispersion analysis and measuredmean profiles of temperature, specific humidity andCO₂ mixing ratio. Monin–Obukhov similarity theorywas used to account for the effects of atmosphericstability on _w(z), the standard deviation ofvertical velocity and _L(z), the Lagrangian timescale of the turbulence. Classical surface layer scaling was applied in the inertial sublayer (z > z_ruf)using the similarity parameter = (z - d)/L, where z is height above ground, d is the zero plane displacementheight for momentum, L is the Obukhov length,and z_ruf 2.3h_c, where h_c iscanopy height. A single length scale h_c, was usedfor the stability parameter 3 = h_c/L in the height range 0.25 < z/h_c < 2.5. This choice is justified by mixing layer theory, which shows that within the roughness sublayer there is one dominant turbulence length scaledetermined by the degree of inflection in the windprofile at the canopy top. In the absence of theoretical or experimental evidence for guidance,standard Monin–Obukhov similarity functions, with = h_c/L, were used to calculate the stabilitydependence of _w(z) and _L(z) in the roughness sublayer. For z/h_c < 0.25 the turbulence length and time scales are influenced by the presence of the lowersurface, and stability effects are minimal. With theseassumptions there was excellent agreement between eddycovariance flux measurements and deductions from theinverse Lagrangian analysis. Stability correctionswere particularly necessary for night time fluxes whenthe atmosphere was stably stratified.The inverse Lagrangian analysis provides a useful toolfor testing and refining multilayer canopy models usedto predict radiation absorption, energy partitioningand CO₂ exchanges within the canopy and at thesoil surface. Comparison of model predictions withsource strengths deduced from the inverse analysisgave good results. Observed discrepancies may be dueto incorrect specification of the turbulent timescales and vertical velocity fluctuations close to theground. Further investigation of turbulencecharacteristics within plant canopies is required toresolve these issues.     

The effects of orography on precipitation

In this paper, a model simulating the effects of topography and altitude on precipitation is presented. Topography has its maximum effect on precipitation when the angle which the wind makes with the slope direction approaches zero and the inclination of the slope is near 45°. The smaller the angle , the greater the influence of slope on precipitation. When <45°, the larger the inclination, the greater the influence of slope on precipitation and the less the difference in precipitation between the windward and the leeward slopes. When <45°, the reverse holds. But for in the range of 0°–45° and in the range 30°–60°, differences in precipitation on both the windward and leeward slopes are not so well marked and can be neglected in general. In condition of uniform slope inclination, precipitation on the windward slope increases with altitude at first and then decreases after attaining a height (H _m ) of maximum precipitation; alsoH _m is greater, the drier the air mass. When the terrain on the windward side is stepped in shape, it is possible that more than one height of maximum precipitation will occur.     

Boundary-layer parameterizations for applied dispersion modeling over urban areas

Many applied dispersion models require the knowledge of boundary-layer parameters such as sensible heat flux,Q _H , friction velocity,u _*, and turbulent energy components, _w and _v . Formulas are suggested for calculating these parameters over a wide variety of types of ground surfaces, based on simple observations of wind speed near the ground and fractional cloud cover, and specification of constants such as roughness length, albedo, and soil moisture availability. Observations ofu _*,Q _H , _w , and _v during field experiments in St. Louis and Indianapolis are used to test the formulas for urban sites. Relative errors of about ±20% in the predictions are seen to occur whenu _*,Q _H , _w , and _v are large. However, when these quantities are small (e.g.,u _* < 0.2 m/s), the errors in the predictions are as large as the mean value of the quantity itself.In addition, it is concluded from studies of available field data and theories that the magnitude of _w is not well-known at elevations above about 100m during the late afternoon and night. Some simple parameterizations for _w . are suggested that are consistent with the observed steady decrease in ground-level concentration in the afternoon and the sudden increase in concentration that can occur a few hours after sunset due to wind shears associated with a low-level jet, for continuous plumes emitted from moderate to tall stacks.     

Transport-Dissipation Analytical Solutions to the E-∈Turbulence Model and their Role in Predictions of the Neutral ABL

E- turbulence model predictions of the neutralatmospheric boundary layer (NABL) are reinvestigated to determine thecause for turbulence overpredictions found in previous applications. Analytical solutions to the coupled E and equations for the case of steady balance between transport and dissipation terms, the dominant balance just below the NABL top, are derived. It is found that analytical turbulence profiles laminarizeat a finite height only for values of closure parameter ratio c ₂ /_e equal toor slightly greater than one, with laminarization as z for greater . The point = 2 is additionally foundthat where analytical turbulent length scale (l) profilesmade a transition from ones ofdecreasing ( < 2) to increasing ( > 2)values with height. Numerically predicted profiles near the NABL topare consistent with analytical findings. The height-increasingvalues of l predicted throughout the NABL with standard values ofclosure parameters thus appear a consequence of 2.5(> 2), implied by these values (c ₂ = 1.92, _{= 1.3}, _{e = 1}). Comparison of numericalpredictions with DNS data shows that turbulence overpredictions obtained with standard-valued parameters are rectifiedby resetting and _e to 1.1 and 1.6, respectively, giving, with c ₂ = 1.92, 1.3, and laminarization of the NABL's cappingtransport-dissipation region at a finite height.     

Spatial Variability of Turbulent Fluxes in the Roughness Sublayer of an Even-Aged Pine Forest

The spatial variability of turbulent flow statistics in the roughness sublayer (RSL) of a uniform even-aged 14 m (= h) tall loblolly pine forest was investigated experimentally. Using seven existing walkup towers at this stand, high frequency velocity, temperature, water vapour and carbon dioxide concentrations were measured at 15.5 m above the ground surface from October 6 to 10 in 1997. These seven towers were separated by at least 100m from each other. The objective of this study was to examine whether single tower turbulence statistics measurements represent the flow properties of RSL turbulence above a uniform even-aged managed loblolly pine forest as a best-case scenario for natural forested ecosystems. From the intensive space-time series measurements, it was demonstrated that standard deviations of longitudinal and vertical velocities (_u, _w) and temperature (_T) are more planar homogeneous than their vertical flux of momentum (u_* ²) and sensible heat (H) counterparts. Also, the measured H is more horizontally homogeneous when compared to fluxes of other scalar entities such as CO₂ and water vapour. While the spatial variability in fluxes was significant (>15 %), this unique data set confirmed that single tower measurements represent the canonical structure of single-point RSL turbulence statistics, especially flux-variance relationships. Implications to extending the moving-equilibrium hypothesis for RSL flows are discussed. The spatial variability in all RSL flow variables was not constant in time and varied strongly with spatially averaged friction velocity u_*, especially when u_* was small. It is shown that flow properties derived from two-point temporal statistics such as correlation functions are more sensitive to local variability in leaf area density when compared to single point flow statistics. Specifically, that the local relationship between the reciprocal of the vertical velocity integral time scale (I_w) and the arrival frequency of organized structures (/h) predicted from a mixing-layer theory exhibited dependence on the local leaf area index. The broader implications of these findings to the measurement and modelling of RSL flows are also discussed.     

Turbulence in a Katabatic Flow

Turbulence measurements performed in a stable boundary layer over the sloping ice surface of the Vatnajökull in Iceland are described. The boundary layer, in which katabatic forces are stronger than the large-scale forces, has a structure that closely resembles that of a stable boundary layer overlying a flat land surface, although there are some important differences. In order to compare the two situations the set-up of the instruments on an ice cap in Iceland was reproduced on a flat grass surface at Cabauw, the Netherlands. Wind speed and temperature gradients were calculated and combined with flux measurements made with a sonic anemometer in order to obtain the local stability functions _m and _h as a function of the local stability parameter z/L. Unlike the situation at Cabauw, where _m was linear as a function of z/L, in the katabatically forced boundary layer, the dependence of _m on stability was found to be non-linear and related to the height of the wind maximum. Thermal stratification and the depth of the stable boundary layer however seem to be rather similar under these two different forcing conditions.Furthermore, measurements on the ice were used to construct the energy balance. These showed good agreement between observed melt and components contributing to the energy balance: net radiation (supplying 55% of the energy), sensible heat flux (30%) and latent heat flux (15%).Local sources and sinks in the turbulent kinetic energy budget are summed and indicate a reasonable balance in near-neutral conditions but not in more stable situations. The standard deviation of the velocity fluctuations _u, _v, and _w, can be scaled satisfactorily with the local friction velocity u_* and the standard deviation of the temperature fluctuation with the local temperature scale _*.     

AN EVALUATION OF DISPERSION COEFFICIENTS FOR USE IN AIR QUALITY MODELS

Standard deviations of concentration in horizontal andvertical directions i.e. y andz have been estimated by using fivedifferent schemes based on empirical(due to Pasquill and Briggs)schemes and sophisticated methods(due to Irwin, Draxler, Taylor, Hanna et al.). The fiveschemes are discussed atlength. The purpose of this study is to make use ofmeteorological observations whichare routinely available, to test all the above methods andintercompare the resultswith one another and observations so that the sensitivityof each schemeunder various atmospheric stability conditions could beassessed. It has beenfound that the existing schemes are good enough to providereasonable estimates ofdispersion coefficient (y) during highly unstableconditions (Pasquill stability classes A and B). However, thesame is not true for the case when the stability increasesfrom C to F and turbulencedecreases, specifically during stable atmospheric conditions,when the observedvalues were found to be much higher than all the existingschemes. This suggests thatwhile we continue to use the current methods of estimatingthe dispersion parameters,a rigorous search is required for methods which give predictionswhich are close-to-realityduring such conditions which are represented by lowlevels (in terms of magnitude)of atmospheric turbulence leading to higher levelsof pollution.As one of the sophisticated methods requiresthe use of v and w (standard deviationsof wind velocity fluctuation in y and z directions),these have been estimated andvalidated with observed data (field experiments conductedby EPRI at Kincaid).Statistical evaluation of v and wbased on performance measures indicate a goodperformance of the parameterisations adopted in thisstudy. In the case of w duringunstable conditions a comparison of three differentschemes with observations is made.     

Short-Term Variability of Atmospheric DMS and Its Oxidation Products at Amsterdam Island during Summer Time

A one-month experiment was performed at Amsterdam Island in January 1998, to investigate the factors controlling the short-term variations of atmospheric dimethylsulfide (DMS) and its oxidation products in the mid-latitudes remote marine atmosphere. High mixing ratios of DMS, sulfur dioxide (SO₂) and dimethylsulfoxide (DMSO) have been observed during this experiment, with mean concentrations of 395 parts per trillion by volume (pptv) (standard deviation, = 285, n = 500), 114 pptv ( = 125, n = 12) and 3 pptv ( = 1.2, n = 167), respectively. Wind speed and direction were identified as the major factors controlling atmospheric DMS levels. Changes in air temperature/air masses origin were found to strongly influence the dimethylsulfoxide (DMSO)/DMS and SO₂/DMS molar ratios, in line with recent laboratory data. Methanesulfonic acid (MSA) and non-sea-salt sulfate (nss-SO₄ ^2–) mean concentrations in aerosols during this experiment were 12.2± 6.5 pptv (1, n=47) and 59 ± 33 pptv (1, n=47), respectively. Evidence of vertical entrainment was reported following frontal passages, with injection of moisture-poor, ozone-rich air. High MSA/ nss-SO₄ ^2– molar ratios (mean 0.44) were calculated during these events. Finally following frontal passages, few spots in condensation nuclei (CN) concentration were also observed.     

Turbulence Reynolds number and the turbulent kinetic energy balance in the atmospheric surface layer

The relation between the turbulence Reynolds numberR and a Reynolds numberz* based on the friction velocity and height from the ground is established using direct measurements of the r.m.s. longitudinal velocity and turbulent energy dissipation in the atmospheric surface layer. Measurements of the relative magnitude of components of the turbulent kinetic energy budget in the stability range 0 >z/L 0.4 indicate that local balance between production and dissipation is maintained. Approximate expressions, in terms of readily measured micrometeorological quantities, are proposed for the Taylor microscale and the Kolmogorov length scale .