Geochronological and geochemical constraints on the petrogenesis of high-K granite from the Suffi abad area, Sanandaj-Sirjan Zone, NW Iran

The Sanandaj-Sirjan Zone (SSZ) trends northwestward in western Iran on the Precambrian to Paleozoic basement and exposes abundant I-type granitoids and calc-alkaline volcanic rocks that were most active during the Late Jurassic to Upper Cretaceous. The petrogenesis of the granitoids and associated volcanic rocks has been widely related to Neotethyan subduction beneath the Iranian plate. We report a geochronological and geochemical study of the Suffi abad granite (SLG) body that crops outs southeast of Sanandaj within the SSZ and is mainly composed of K-feldspar + quartz + plagioclase ± hornblende. The SLG, which shows a high-K calc-alkaline affinity, has LA-ICPMS zircon U–Pb ages ranging between 149 ± 2 and 144 ± 3 Ma and initial ⁸⁷Sr/⁸⁶Sr of ∼0.7024–0.7069 and ¹⁴³Nd/¹⁴⁴Nd of ∼0.5125–0.5127. These value correspond to an ?_Nd (145 Ma) of +1.5 and +4.9, suggesting that the SLG originated from the juvenile crust or depleted mantle with a young T_DM (650–900 Ma) over the subduction zone beneath the SSZ. Zircon saturation temperatures suggest that crystallization of the zircons, or emplacement of the host magmas, occurred at 560–750 °C, consistent with an intergrowth texture of K-feldspar and quartz that implies crystallization around the K-feldspar-quartz eutectic at lower temperatures. Overall, geochemical data suggest that crystallization of the hornblende and plagioclase played a role in magma differentiation. These data allow us to conclude that the high-K SLG did not originate directly from the juvenile mantle source as do most I-type, calc-alkaline granitoids, but more likely was produced from the partial melting of pre-existing I-type granitoids in the upper continental crust under low pressure conditions.     

Age,petrologic significance and provenance analysis of the Hamedan low-pressure migmatites; Sanandaj-Sirjan Zone,west Iran

ABSTRACT

Meta-pelitic rocks with interlayers of meta-psammites within the inner thermal aureole of the Alvand plutonic complex (Sanandaj-Sirjan Zone (SaSZ), western Iran) underwent partial melting; generating various types of migmatites. The mesosome of the Hamedan migmatites is classified into two groups: (1) cordierite-rich and Al-silicate-poor mesosomes and (2) cordierite-poor, Al-silicate-rich groups. Leucosomes are also variable, ranging from plagioclase-rich to K-feldspar-rich leucosomes. Mineral-chemical studies and thermobarometric estimations indicate temperature and pressure of 640–700°C and 3–5 kbar, respectively, for the formation of mesosomes. U–Pb zircon geochronology on 214 grains from the mesosome of migmatites indicates ages of 160–180 Ma (ca ~170 Ma) for zircon metamorphic rims and variable ages of 190–2590 Ma for the inherited detrital zircon cores. Inherited core ages show various age populations, but age populations at 200–600 Ma are more frequent. The age populations of the detrital zircons clarify that the provenance of the younger zircon grains (200–500 Ma) was more likely the Iranian plate, whereas the older grains (600 Ma to >2.5 Ga) may be sourced from both northern Gondwana (such as Arabian-Nubian Shield) and the neighbouring, old cratons like as Africa. We suggest that magmatic activities, especially mafic plutonism at ~167 Ma, are the main triggers for the heat source of metamorphism, partial melting, and migmatization. In contrast to a presumed idea for a Cretaceous regional metamorphic event in the NW parts of the SaSZ, this study attests that the metamorphism should be older and can be associated with Jurassic magmatic pulses.     

Isotope geochemistry of Jeongok basalts,northernmost South Korea: Implications for the enriched mantle end-member component

South Korea separates two mantle source domains for Late Cenozoic intraplate volcanism in East Asia: depleted mid-ocean-ridge basalt (MORB) mantle-enriched mantle type 1 (DMM-EM1) in the north and DMM-EM2 in the south. We determined geochemical compositions, including Sr, Nd, Pb, and Hf isotopes for the Jeongok trachybasalts (∼0.51 to 0.15 Ma K–Ar ages) from northernmost South Korea, to better constrain the origin and distribution of the enriched mantle components. The Jeongok basalts exhibit light rare earth element (LREE)-enriched patterns ([La/Yb]_N = 9.2–11.6). The (La/Yb)_N ratios are lower than that of typical oceanic island basalt (OIB). On a primitive mantle-normalized incompatible element plot, the Jeongok samples show OIB-like enrichment in highly incompatible elements. However, they are depleted in moderately incompatible elements (e.g., La, Nd, Zr, Hf, etc.) compared with the OIB and exhibit positive anomalies in K and Pb. These anomalies are also prime characteristics of the Wudalianchi basalts, extreme EM1 end-member volcanics in northeast China. We have compared the geochemistry of the Jeongok basalts with those of available Late Cenozoic intraplate volcanic rocks from East Asia (from north to south, Wudalianchi, Mt. Baekdu and Baengnyeong for DMM-EM1, and Jeju for DMM-EM2). The mantle source for the Jeongok volcanics contains an EM1 component. The contribution of the EM1 component to East Asian volcanism increases toward the north, from Baengnyeong through Jeongok to Mt. Baekdu and finally to Wudalianchi. Modeling of trace element data suggests that the Jeongok basalts may have been generated by mixing of a Wudalianchi-like melt (EM1 end-member) and a melt that originated from a depleted mantle source, with some addition of the lithospheric mantle beneath the Jeongok area. In Nd–Hf isotope space, the most enriched EM1-component-bearing Jeongok sample shows elevation of ¹⁷⁶Hf/¹⁷⁷Hf at a given ¹⁴³Nd/¹⁴⁴Nd compared with OIB. Recycled pelagic sediments may explain the EM1-end-member component of northeastern Asian volcanism, possibly from the mantle transition zone.     

华北克拉通北部古-中元古代富碱侵入岩的Nd、Sr、Pb同位素地球化学：岩石圈地幔富集的证据

华北克拉通北部古-中元古代富碱侵入岩主要分布在燕辽三叉裂堑系和辽吉拗拉谷中及附近,为一套高碱高钾的基性-中性岩,以正长岩类为主。本文通过开展系统的 Nd、Sr、Pb 同位素研究,发现所有岩体岩石均以高负ε_(Nd)(t)为特征,ε_(Nd)(t)=-3.4～-7.5,平均值为～4.8,这与研究区古-中元古代基性-超基性岩石的 Nd 同位素特征(ε_(Nd)(t)=-4～-8) 一致,与燕辽裂堑系发育的偏碱性火山岩 Nd 同位素特征(ε_(Nd)(t)=-4.3～-8.9)也比较相似,表明它们的物质来源相似,都与富集地幔有关。Sr 同位素初始比值(~(87)St/~(86)Sr)_i比较低,主要变化在0.7028～0.7053之间,平均值为0.7041。钾长石铅同位素组成普遍较低,~(206)Pb/~(204)Pb、~(207)pb/~(204)Pb、~(208)Pb/~(204)Pb 比值变化范围(梁屯-矿洞沟岩体除外)分别为14.500～15.70l、14.887～15.150和34.178～36.537,平均值分别为14.968、14.984和35.057。在ε_(Nd)(t)-ε_(Sr)(t)图解上,所有岩体的投影点均在地幔演化趋势线附近,比较接近 EMI 型富集地幔端员,暗示它们的物质来源与 EMI 型富集地幔有关;钾长石 Pb 同位素模式图也说明这些岩体物质来源与地幔和下地壳有关。通过两端员混合模拟,揭示了岩浆演化过程中存在少量的下地壳物质混染,平均约14%左右。从2.5Ga 左右开始华北克拉通岩石圈地幔的亏损程度逐渐变小,在2.2Ga 左右局部呈现富集性特征,1.85Ga时整个岩石圈地幔已经完全转变为富集性,之后富集程度越来越高。推测早期俯冲携带的壳源物质以及后期地幔流体的交代作用可能是岩石圈地幔逐渐转变为富集性的原因。     

Petrology and geochemistry of the granitoid complex of Boroujerd, Sanandaj-Sirjan Zone, Western Iran

The Middle Jurassic Boroujerd Granitoid Complex of the Sanandaj-Sirjan Zone (with a U–Pb zircon age of 169–172 Ma) was emplaced in an active continental margin setting. This complex consists of three main units: an elongate NW–SE extending granodioritic unit (SiO₂ = 58–71 wt%), which is widespread throughout the area, a quartz-dioritic unit (SiO₂ = 52–63 wt%), exposed as small stocks within the granodioritic body, and a monzogranitic unit (SiO₂ = 70–75 wt%), widely scattered as separate small outcrops through the southern part of the area. A series of NW trending aplites and pegmatites are present in the granodioritic unit and its aureole.Geochemically this complex is metaluminous to slightly peraluminous, typical of I-type granites. It belongs to high-K calc-alkaline series and displays the geochemical characteristics typical of volcanic arc granites related to an active continental margin (e.g. significant Nb, Ti, P and Sr depletion). Isotopic data (Sr_i = 0.7062–0.7074 and εNd_t = −3.02 to −3.62) are consistent with a crustal protolith. In addition, fractional crystallization may have played an important role in the formation of the whole spectrum of the granitoid types that occur in the Boroujerd area.     

Na depletion in modern adakites via melt / rock reaction within the sub-arc mantle

Interaction between slab-derived melt and mantle peridotite and the role of slab melt as a metasomatizing agent in the sub-arc mantle is being increasingly recognized. Adakite, the slab melt erupted on the surface, usually exhibits anomalously high MgO, CaO, Cr and Ni contents that indicate interaction with mantle peridotitite. Here we note that Cenozoic adakites have Na₂O contents below 5.8 wt.% with ∼95% samples lower than 5.0 wt.%, and are generally depleted in this component relative to experimental basalt partial melts (mostly beyond 5.0 wt.% and up to 9.0 wt.% Na₂O) produced under 1.5-3.0 GPa conditions that are most relevant to adakite production. We interpret the adakite Na depletion to be also a consequence of the melt / rock reaction that takes place within the hot mantle wedge. During ascent and reaction with mantle peridotite, primary adakite melts gain mantle components MgO, CaO, Cr and Ni but lose Na₂O, SiO₂ and perhaps K₂O to the mantle, leading to Na-rich mantle metasomatism. Selective assimilation of predominately mantle clinopyroxene, some spinel and minor olivine at high T/P has been considered to be an important process in producing high-Mg adakites from primary low-Mg slab melts [Killian, R., Stern, C. R., 2002. Constraints on the interaction between slab melts and the mantle wedge from adakitic glass in peridotite xenoliths. Eur. J. Mineral. 14, 25-36]. In such a process, Na depletion in the assimilated melt is the result of dilution due to the increase in melt mass. Phase relationships in the reaction system siliceous melt + peridotite and quantitative calculation suggest that assimilation of mantle clinopyroxene, olivine and spinel and fractional crystallization of sodic amphibole and orthopyroxene, under conditions of moderate T/P and increasing melt mass, is also an important process that modifies the composition of adakites and causes the Na depletion.     

南菲律宾地区类埃达克岩和富铌玄武质熔岩的成因

埃达克岩（adakite)最初 是指由消减板片玄武岩物质熔融形成的富硅、富钠、高Sr/Y和La/Yb比值的弧火山熔岩。它通常产在会聚带，这个部位的年轻的、因而仍然是热的大洋板片正在发生俯冲消减。富铌的岛弦玄武央进则是吕等到高碱的镁铁质熔岩，它们相对于正常的岛弦玄武岩含有较多的高场强元素（HFSE）。这些玄武岩通常与埃达克央共生， 这一组合是直被用于论证他们的高HFSE含量是因为他们的地幔源区受到板片来源的熔体的交代。先前的区域研究结果表明，南菲律宾是埃达克岩和富铌岛孤玄武岩的一个典型产地。然而最近的详细研究显示，尽管该地区的一些岛弧火山岩是类埃达克岩的，但是它们很可能是来自地幔楔的母岩浆的分异作用的产物，而这里的地幔楔主要是受沉积来源的成分交代的，此外，菲律宾南部最典型的富铌熔岩中HFSE的富集，也很有可能是起因于似乎是西太平洋边缘特有的富集地幔组分的熔融。这些结果提出了如下问题：南菲律宾是否存在真正的板片来源的熔体？这里的富铌岛弧 熔岩是否起因于地幔楔被这种熔体交代？     

Tectono-metamorphic evolution of the Neyriz metamorphic complex, Quri-Kor-e-Sefid area (Sanandaj-Sirjan Zone, SW Iran)

The Neyriz region includes outcrops of metamorphic rocks that are thrust over the Neotethyan ophiolites. These rocks are affected by a major deformational event, the result of which includes a shearing polyphase foliation present in gneissic core domes, overprinted by a crenulation cleavage. These fundamental structures developed contemporaneously with a medium-pressure metamorphism which is characterized by the syn-kinematic crystallization of kyanite and the beginning of anatexis, followed by the development of retrometamorphic mineral parageneses. The major deformation phase in the area occurred during the Early-Cimmerian orogeny in the Late Triassic. Following the orogeny, the gneiss domes started to rise into the upper levels of the crust. From the geodynamic point of view, after the Mid-Permian the studied area was situated at southern passive margin of the Iranian plate; the central Iranian microcontinent at that time was separated by the Neotethys ocean from the Gondwanian supercontinent. After the Late Triassic the region became an active margin associated with an accretionary prism. The margin was finally involved in an orogenic wedge after the closure of the Neotethyan oceanic basin in the Late Mesozoic. Closure of the basin resulted in a major thrusting of the metamorphic rocks of the southern Iranian margin over the Neotethyan ophiolites.     

Metasomatic Stages and Scapolitization Effects on Chemical Composition of Pasveh Pluton,NW Iran

Pasveh gabbros are mafic component of a plutonic complex in the northwest Sanandaj-Sirjan Zone.These cumulative rocks are composed of plagioclase and calcic clinopyroxene(Cpx) ,which yield unusually high CaO(>19 wt.%) in whole-rock chemistry.Petrographical and geochemical data suggest that Pasveh gabbros can be divided into two groups:free scapolite and scapolite-bearing gabbros.The second group has higher Na2O,K2O,and P2O5 relative to free scapolite ones and is enriched in LIL(large ion lithophile) and HFS...     

Early Cretaceous sedimentary provenance and structural evolution of the central Sanandaj–Sirjan Zone,Iran: implications for palaeogeographic reconstructions of the northern Neo-Tethyan margin

ABSTRACT

The Early Cretaceous was an important epoch in the evolution of the Earth system in which major tectonic episodes occurred, especially along the Alpine–Himalayan belt. The paucity of reliable palaeogeographic data from the central segment of this geological puzzle, however, hampers the reconstruction of a panoramic view of its Early Cretaceous palaeogeography and geodynamic setting. Here we present multidisciplinary provenance data from Lower Cretaceous strata of the overriding plate of the Neo-Tethyan subduction zone (the Sanandaj–Sirjan Zone; SSZ, of central Iran), including structural, basin-fill evolution, petrographic and geochemical analyses. Sandstone provenance analysis of Lower Cretaceous red beds suggests the occurrence of sub-mature litho-quartzose sandstones attributed to an active continental arc margin in convergent setting predominantly derived from plutonic, quartzose sedimentary and metamorphic rocks exposed in the central SSZ. Weathering indices indicate moderate chemical weathering in the source area which may be related to close source-to-sink relationships or arid climate. Our palaeogeographic reconstructions and original geological mapping indicate that the erosion of uplifted basement rocks exposed in horst blocks provided the sediment sources for the syn-extensional deposition of uppermost Jurassic–lowermost Cretaceous conglomerates and Lower Cretaceous siliciclastic red beds within a continental retro-arc basin during initiation of the ‘Neo-Tethys 2?. The polyphase tectonic reactivation along the principal fault of the study area controlled the syn- and post-extensional tectonostratigraphic evolution that reflect the corresponding mechanical decoupling/coupling along the northern Neo-Tethyan plate margin.     

从大陆火山岩视角了解深部地幔化学储库的属性

洋岛玄武岩（OIB）在同位素组成上的显著变化表明深部地幔在化学上是高度不均一的,存在EM1、EM2和HIMU等地幔端元。现有OIB的地球化学证据支持EM1、EM2和HIMU源区多存在再循环地壳物质,因此对地幔端元属性的精准约束是探讨壳幔物质循环和地球深部过程的关键。基于近年来来自OIB的Mg、Fe、Zn等金属稳定同位素和橄榄石斑晶元素地球化学方面的观察,本文在重新梳理不同地幔端元在成因上的联系和区别的基础上,把EM1和EM2归类为残余型富集储库（residual-type enriched reservoir）、HIMU归为交代型富集储库（metasomatic-type enriched reservoir）。相对于OIB,大陆幔源火山岩的熔融程度普遍要低得多,更有利于保存富集组分的地球化学信息。另外,洋岛玄武岩主要分布在南半球,大陆火山岩主要分布于北半球,后者可以弥补前者在空间上代表性不足的缺陷。因此,大陆火山岩有潜力成为观察深部地幔储库的新视角。

     

Petrogenesis of the Neogene alkaline volcanics with implications for post-collisional lithospheric thinning of the Eastern Pontides, NE Turkey

Whole-rock geochemistry, Sr–Nd–Pb isotopes and K–Ar data are reported for alkaline samples collected from the Neogene alkaline volcanics (NAVs) in the Eastern Pontides, northeastern Turkey, in order to investigate their source and petrogenesis and geodynamic evaluation of the region. The NAVs were made of three groups that comprise of basanite–tephrite (feldspar-free; Group A), tephrite–tephriphonolite (feldspar and feldspathoid-bearing; Group B) and alkaline basalt–rhyolite (feldspathoid-free; Group C) series. These rocks cover a broad compositional range from silica-undersaturated to silica-oversaturated types, almost all of which are potassic in character. They show enrichment of LREE and LILE and depletion of HFSE, without a Eu anomaly in most of the mafic samples. Textural features and calculated pressures based on the Cpx-barometer in each series indicate that the alkaline magma equilibrated at shallow crustal depths under a pressure of about 3–4.5 kbar and approximating a crystallization depth of 9–14 km. The NAVs are slightly depleted in isotopic composition, with respect to ⁸⁷Sr/⁸⁶Sr (ranging from 0.705018 to 0.705643) and ¹⁴³Nd/¹⁴⁴Nd (ranging from 0.512662 to 0.512714) that indicate young Nd model ages (0.51–059 Ga). This may indicate that the parent melts tapped a homogeneous and young lithospheric mantle source which was metasomatized by subduction-derived sediments during the Late Mesozoic. Pb isotopic compositions (²⁰⁶Pb/²⁰⁴Pb = 18.85–18.95; ²⁰⁷Pb/²⁰⁴Pb = 15.60–15.74; ²⁰⁸Pb/²⁰⁴Pb = 38.82–39.25) may also be consistent with a model for an enriched subcontinental lithospheric mantle source. Lithospheric thinning and resultant upwelling of asthenosphere induced by lithospheric delamination may have favoured partial melting of chemically enriched, young lithospheric mantle beneath the Eastern Pontides. Then, the melt subsequently underwent a fractional crystallization process along with or without minor amounts of crustal assimilation, generating a wide variety of rock types in a post-collision extensional regime in the Eastern Pontides during the Neogene.     

地幔热柱多级演化及其幔枝构造成矿控矿——以胶西北郭家店幔枝构造为例

文章简要介绍了幔枝构造成矿理论,探讨了幔枝构造的特征、单元划分、断裂构造体系以及成矿控矿作用。在燕山运动晚期,华北东部地区进入了以伸展构造为主的地幔热柱演化阶段,在胶西北地区形成了莱阳地幔亚热柱及其外围郭家店、栖蓬、牟乳等幔枝构造。其中,郭家店幔枝构造于燕山运动晚期发生强烈的构造活动,总体形成了以焦家断裂为主的拆离带和与其相交的以三山岛断裂为反向铲状断裂的构造体系,同时控制着玲珑、焦家、三山岛等一系列大型—超大型矿床的形成。在众多成矿控矿因素中,区域性断裂构造是重要的主导性因素,既为成矿流体的运移提供了通道,又为成矿储矿提供了有利空间。深源含矿流体可通过地幔热柱→地幔亚热柱→幔枝构造→有利构造扩容带,即脆韧性-韧脆性剪切带、侵入岩体的内外接触带、密集的构造裂隙带、各种脉岩与围岩的接触带等有利构造部位集聚成矿。近年来在胶西北深部勘查发现,浅部沿断裂展布的若干个大—中型金矿在其深部的成矿蚀变构造带可能是连为一体的,一起组合成为超大型金矿。     

Charnockite genesis across the Archaean–Proterozoic terrane boundary in the South Indian Granulite Terrain: Constraints from major–trace element geochemistry and Sr–Nd isotopic systematics

Major, trace element compositions and Sr–Nd isotopic characteristics of charnockitic gneisses from the Southern Granulite Terrain (SGT), South India are presented. The study region encompasses the central segment of the Cauvery Shear Zone system (CSZ) and regions within the Madurai Block (MB) immediately south of it (designated here as the CSZ/MB and MB domains). Differences in the compositions and source characteristics between charnockitic rocks of the CSZ vis-à-vis those of the CSZ/MB and MB regions are highlighted. Foremost, the charnockites and enderbites of the CSZ show highly fractionated REE patterns with positive Eu-anomalies, depleted HREE, Y and near chondritic εNd₀ and initial-⁸⁷Sr/⁸⁶Sr at ca. 2.5 Ga, consistent with hydrous partial melting of amphibolitic crust with residual garnet and hornblende for the parental melts. By contrast, modeled at ca. 1.8 Ga and 0.8 Ga, the CSZ/MB and MB charnockitic rocks, which show a wider range of Ti and P, relatively lower degree of HREE depletion, commonly negative Eu-anomalies and undepleted Y, present clear evidence for involvement of Archaean crustal components in sources of their magmatic protoliths. There is also evidence for significant intracrustal melting processes within a thickened crust at elevated temperatures between 800 and 1000 °C. Implications to the controversial Archaean–Neoproterozoic terrane boundary problem of the SGT are discussed.     

An investigation into the fault patterns in the Chadegan region, west Iran: Evidence for dextral brittle transpressional tectonics in the Sanandaj-Sirjan Zone

The NW-SE trending Sanandaj-Sirjan Zone (SSZ) is the internal part of the Zagros continental collision zone, which mainly consists of metamorphic rocks deformed in a dextral transpressional zone. This dextral transpression is attributed to brittle deformation related to late Cenozoic Arabia-Eurasia oblique continental collision. Major NW-trending faults, including the Dalan, Garmdareh, Yasechah, Sheida, and Ben faults, are reverse faults with a dextral strike-slip component. These faults were displaced by NW-trending synthetic and NE-trending antithetic faults. There are also E-trending thrusts and N-trending normal faults developing in directions that are, respectively, almost normal and parallel to the major shortening direction. The NW-trending Ben, Yasechah, and Sheida faults are NE-dipping faults, and the Dalan and Garmdareh faults are SW-dipping faults. These faults indicate the presence of a transpressive flower structure zone that probably led to the exhumation of Jurassic high-grade metamorphic rocks, such as eclogite, in the central part of the study area.     

Hypogene Zn carbonate ores in the Angouran deposit,NW Iran

The world-class Angouran nonsulfide Zn–Pb deposit is one of the major Zn producers in Iran, with resources estimated at about 18 Mt at 28% Zn, mainly in the form of the Zn carbonate smithsonite. This study aims to characterize these carbonate ores by means of their mineralogy and geochemistry, which has also been extended to the host rocks of mineralization and other local carbonate rock types, including the prominent travertines in the Angouran district, as well as to the local spring waters. Petrographical, chemical, and stable isotope (O, H, C, Sr) data indicate that the genesis of the Zn carbonate ores at Angouran is fairly distinct from that of other “classical” nonsulfide Zn deposits that formed entirely by supergene processes. Mineralization occurred during two successive stages, with the zinc being derived from a preexisting sulfide ore body. A first, main stage of Zn carbonates (stage I carbonate ore) is associated with both preexisting and subordinate newly formed sulfides, whereas a second stage is characterized by supergene carbonates (Zn and minor Pb) coexisting with oxides and hydroxides (stage II carbonate ore). The coprecipitation of smithsonite with galena, pyrite and arsenopyrite, as well as the absence of Fe- and Mn-oxides/hydroxides and of any discernible oxidation or dissolution of the sphalerite-rich primary sulfide ore, shows that the fluids responsible for the main, stage I carbonate ores were relatively reduced and close to neutral to slightly basic pH with high fCO₂. Smithsonite δ¹⁸O_VSMOW values from stage I carbonate ore range from 18.3 to 23.6‰, while those of stage II carbonate ore show a much smaller range between 24.3 and 24.9‰. The δ¹³C values are fairly constant in smithsonite of stage I carbonate ore (3.2–6.0‰) but show a considerable spread towards lower δ¹³C_VPDB values (4.6 to −11.2‰) in stage II carbonate ore. This suggests a hypogene formation of stage I carbonate ore at Angouran from low-temperature hydrothermal fluids, probably mobilized during the waning stages of Tertiary–Quaternary volcanic activity in an environment characterized by abundant travertine systems throughout the whole region. Conversely, stage II carbonate ore is unambiguously related to supergene weathering, as evidenced by the absence of sulfides, the presence of Fe-Mn-oxides and arsenates, and by high δ¹⁸O values found in smithsonite II. The variable, but still relatively heavy carbon isotope values of supergene smithsonite II, suggests only a very minor contribution by organic soil carbon, as is generally the case in supergene nonsulfide deposits.     

Structures and microstructures related to steady-state mantle flow in the Neyriz ophiolite, Iran

Structural analysis in the well-exposed and well-preserved Neyriz ophiolite suggests that it is a relatively undisturbed piece of oceanic lithosphere. Detailed structural mapping of high-T deformation mantle flow revealed the presence of three elliptical shaped diapirs trending NW–SE. These diapirs are characterized by vertical mantle foliations associated with vertical plunging stretching lineations, which progressively incline toward parallelism with the gently NE-dipping Moho. The NW–SE direction of asthenospheric upwelling of diapirs is parallel with the orientations of the vertical sheeted dike complex. This suggests that the Neyriz ophiolite was created by two NW–SE palaeo-ridge axes. These palaeo-ridges are classified as fast-spreading ridges. These ridges are segmented by a dextral palaeo-transform fracture zone. This is consistent with fast-spreading ridges. Comparison between the Neyriz and Oman ophiolites reveals that they show similar characteristics. Most of the Oman palaeo-ridge systems are oriented NW–SE and NNW–SE. They also display similar sheeted dike complex orientations and crustal thickness variations. These two ophiolites originally were part of the Neo-Tethyan oceanic lithosphere and afterwards were separated by the Oman line during continental collision of the Iranian micro-continent and Afro-Arabian continent.     

华北克拉通中部古元古代高Mg低Ti-P镁铁质岩墙的富集地幔源区——锆石Hf同位素的制约

华北克拉通中部是古元古代岩墙群最为发育的地区。以镁铁质成分为主的岩墙群可以分为变质的和不变质的两类。不变质岩墙群是在1780～1760Ma之间大约20Ma时间内形成的,是华北克拉通古元古代最晚期铗铁质岩浆活动的产物。不变质岩墙又可以细分成高Mg-Ti低P、低Mg高Ti-P和高Mg低Ti-P等3组。本文报道了采自丰镇附近高Mg低Ti-P岩墙样品的锆石U-Pb年龄和Hf同位素组成分析结果。新获得的SHRIMP锆石U-Pb年龄为1769±4Ma,与其它不变质岩墙的锆石、斜锆石U-Pb年龄和~(40)At/~(39)Ar年龄的范围相同。高Mg低Ti-P岩墙的锆石ε_(Hf)(t)值的变化范围在-6.4～ 0.4之间,平均值为-2.2,略高于时代相近的花岗质岩石。由于镁铁质岩浆在上升、侵位和结晶过程中几乎没有受到地壳物质混染,因而锆石ε_(Hf)(t)值可以代表镁铁质岩浆的富集的岩石圈地幔源区的特征。文献资料显示,高Mg低Ti-P岩墙的岩石圈地幔源区的~(87)Sr/~(86)Sr初始比值为0.7040～0.7050,平均值为0.7046,ε_(Nd)(t)值为-5.6～-2.8,平均值为-4.4。     

华北克拉通中部古元古代高Mg低Ti-P镁铁质岩墙的富晶集地幔源区——锆石Hf同位素的制约

华北克拉通中部是古元古代岩墙群最为发育的地区.以镁铁质成分为主的岩墙群可以分为变质的和不变质的两类.不变质岩墙群是在1780～1760 Ma之间大约20 Ma时间内形成的,是华北克拉通古元古代最晚期镁铁质岩浆活动的产物.不变质岩墙又可以细分成高Mg-Ti低P、低Mg高Ti-P和高Mg低Ti-P等3组.本文报道了采自丰镇附近高Mg低Ti-P岩墙样品的锆石U-Pb年龄和Hf同位素组成分析结果.新获得的SHRIMP锆石U-Pb年龄为1769±4 Ma,与其它不变质岩墙的锆石、斜锆石U-Pb年龄和^40Ar/^39Ar年龄的范围相同.高Mg低Ti-P岩墙的锆石εHf（t）值的变化范围在-6.4～＋0.4之间,平均值为-2.2,略高于时代相近的花岗质岩石.由于镁铁质岩浆在上升、侵位和结晶过程中几乎没有受到地壳物质混染,因而锆石εHf（t）值可以代表镁铁质岩浆的富集的岩石圈地幔源区的特征.文献资料显示,高Mg低Ti-P岩墙的岩石圈地幔源区的87Sr/86Sr初始比值为0.7040～0.7050,平均值为0.7046,εNd（t）值为-5.6～-2.8,平均值为-4.4.     

Triassic Nb-enriched basalts, magnesian andesites, and adakites of the Qiangtang terrane (Central Tibet): evidence for metasomatism by slab-derived melts in the mantle wedge

New chronological, geochemical, and isotopic data are reported for Triassic (219–236 Ma) adakite-magnesian andesite-Nb-enriched basaltic rock associations from the Tuotuohe area, central Qiangtang terrane. The adakites and magnesian andesites are characterized by high Sr/Y (25–45), La/Yb (14–42) and Na₂O/K₂O (12–49) ratios, high Al₂O₃ (15.34–18.28 wt%) and moderate to high Sr concentrations (220–498 ppm) and ε_ND (t) (+0.86 to +1.21) values. Low enrichments of Th, Rb relative to Nb, and subequal normalized Nb and La contents, and enrichments of light rare earth elements combine to distinguish a group of Nb-enriched basaltic rocks (NEBs). They have positive ε_ND (t) (+2.57 to +5.16) values. Positive correlations between Th, La and Nb and an absence of negative Nb anomalies on mantle normalized plots indicate the NEBs are products of a mantle source metasomatized by a slab melt rather than by hydrous fluids. A continuous compositional variation between adakites and magnesian andesites confirms slab melt interaction with mantle peridotite. The spatial association of the NEBs with adakites and magnesian andesites define an “adakitic metasomatic volcanic series” recognized in many demonstrably subduction-related environments (e.g., Mindanao arc, Philippines; Kamchatka arc, Russia; and southern Baja California arc, Mexico). The age of the Touhuohe suite, and its correlation with Triassic NEB to the north indicates that volcanism derived from subduction-modified mantle was abundant prior to 220 Ma in the central Qiangtang terrane.