Erodibility of soil and organic matter: independence of organic matter resistance to interrill erosion

The enrichment of organic matter in interrill sediment is well documented; however, the respective roles of soil organic matter (SOM) and interrill erosion processes for the enrichment are unclear. In this study, organic matter content of sediment generated on two silts with almost identical textures, but different organic matter contents and aggregations, was tested. Artificial rainfall was applied to the soils in wet, dry and crusted initial conditions to determine the effects of soil moisture and rainfall and drying history on organic matter enrichment in interrill sediment. While erosional response of the soils varied significantly, organic matter enrichment of sediment was not sensitive to initial soil conditions. However, enrichment was higher on the silt with a lower organic matter content and lower interrill erodibility. The results show that enrichment of organic matter in interrill sediment is not directly related to either SOM content or soil interrill erodibility, but is dominated by interrill erosion processes. As a consequence of the complex interaction between soil, organic matter and interrill erosion processes, erodibility of organic matter should be treated as a separate variable in erosion models. Further research on aggregate breakdown, in particular the content and fate of the organic matter in the soil fragments, is required. Copyright © 2007 John Wiley & Sons, Ltd.     

Ground Water Contamination in Kuwait Resulting from the 1991 Gulf War: A Preliminary Assessment

A large number of oil wells in Kuwait were damaged and ignited by the retreating Iraqi troops during the 1991 Gulf War. The resulting spillage of huge volumes of crude oil on the surface gave rise to oil lakes and crude oil–impregnated soil. Moreover, products of crude oil combustion had spread over a large tract of the ground surface, causing widespread contamination of soil. Hydrocarbon contamination of ground water by the infiltrating runoff water carrying the contaminants from the surface soil to the water table and/or through direct contact with the crude oil leaking through the damaged casing in the subsurface was feared. This preliminary study was carried out to investigate the extent and nature of this possible contamination of ground water. The results indicate that the shallow fresh water lenses present under the Umm Al-Aish water field and in the southeastern parts of the Raudhatain water field in North Kuwait were affected by hydrocarbon pollution. Standard methods like the determination of the contents of the total petroleum hydrocarbon by the Fourier transform infrared method and 16 polyaromatic hydrocarbons using the gas chromatography-mass spectrometry method did not work well, possibly due to the environmental degradation of the crude oil over time. The fluorescence methods and the total organic carbon and total organic matter gave better indications of the intensity and the extent of ground water pollution. The brackish water fields of South and Central Kuwait were, however, free of any indications of hydrocarbon contamination.     

鄱阳湖湿地土壤微生物活性对年际水文变化的响应

湿地自然水文节律的改变影响着湿地生态系统的稳定与安全.为探究湿地水文变化对土壤微生物活性的影响,以鄱阳湖洲滩湿地3种典型植被狗牙根（Cynodon dactylon）、南荻（Triarrhena lutarioriparia）和苔草（Carex cinerascens）下表层土壤（0~20 cm）为研究对象,对湿地土壤微生物呼吸、微生物生物量和水解酶等土壤活性特征进行连续3年的实验监测,分析年际水位变化对不同植被湿地土壤微生物活性的影响.结果表明：丰水年显著提高土壤中养分的可利用性（有机质、总磷、速效磷）,提高土壤微生物生物量、微生物熵、水解酶活性,表明丰水年有利于湿地生态系统的物质循环转化.水文条件也能通过影响湿地植被生长改变土壤养分状况,进而对植被下土壤微生物活性产生显著影响.诸多土壤理化因子中,可溶性有机碳是驱动微生物活性变化最关键的因子.进一步分析表明,由植被类型所代表的长期水文累积效应对湿地土壤理化及微生物活性的调节作用大于单纯的年际水文变化.     

Organic Contamination of Ground Water at Gas Works Park, Seattle, Washington

Gas Works Park, in Seattle, Washington, is located on the site of a coal and oil gasification plant that ceased operation in 1956. During operation, many types of wastes, including coal, tar, and oil, accumulated on-site. The park soil is currently (1986) contaminated with compounds such as polynuclear aromatic hydrocarbons, volatile organic compounds, trace metals, and cyanide. Analyses of water samples from a network of observation wells in the park indicate that these compounds are also present in the ground water.
Polynuclear aromatic hydrocarbons and volatile organic compounds were identified in ground water samples in concentrations as large as 200 mg/L. Concentrations of organic compounds were largest where ground water was in contact with a non-aqueous phase liquid in the soil. Where no non-aqueous phase liquid was present, concentrations were much smaller, even if the ground water was in contact with contaminated soils. This condition is attributed to weathering processes in which soluble, low-molecular-weight organic compounds are preferentially dissolved from the non-aqueous phase liquid into the ground water. Where no non-aqueous phase liquid is present, only stained soils containing relatively insoluble, high-molecular-weight compounds remain. Concentrations of organic contaminants in the soils may still remain large.     

Holocene dust accumulation and the formation of polycyclic cinnamon soils (luvisols) in the Chinese Loess Plateau

Chinese loess–palaeosol sequences are well known for their records of monsoonal climatic variations. However, the modern processes of dust accumulation and soil formation remain poorly understood. A high‐resolution investigation on modern soils, including the measurement of magnetic susceptibility, particle‐size distribution, total Fe, total organic carbon, CaCO₃ content, and optical stimulated luminescence (OSL) dating was carried out on the Zhouyuan loess tableland in the southern Loess Plateau. The results indicate that modern cinnamon soils (luvisols) have developed on contemporarily accumulated aeolian dust during the Holocene. The aeolian loess accumulated during the Younger Dryas was identi?ed in the top part of the Malan Loess that underlay the modern soil by OSL dating and proxy climatic data. It indicates that the Malan Loess accumulated during the last glaciation (marine isotope stages 2–4) does not serve as the parent material for the modern soils. Pedogenesis of the soils started with the increased precipitation and soil moisture that have occurred on the loess tableland since the early Holocene. Precipitation‐driven pedogenesis and organic activities are responsible for the leaching of CaCO₃, decomposition of mineral dust and the production of clay and ferromagnetic minerals. Drier intervals have interrupted soil formation several times, and therefore pro?les with multiple soils have been developed at many sites on the loess tableland. At places where soil erosion was relatively strong, either a single soil or welded soils are preserved in the Holocene pro?les. This does not necessarily mean, however, that modern soils over the plateau have been developed without interruption under a constantly warmer, moister climate. This is signi?cant for understanding the surface processes and climatic variation during the formation of the numerous palaeosols over the Loess Plateau in the Quaternary. Copyright © 2003 John Wiley & Sons, Ltd.     

Effect of organic matter on splash detachment and the processes involved

The influence of organic matter on splash detachment was investigated using soils with grass and peat treatments. The relationship between organic matter and aggregate stability to water disruption was positive for soils with grass treatment while it was negative for those with peat treatment. Organic matter from both treatments, however, reduced splash detachment by rainfall. Soils with grass did this by increasing aggregate stability while peat acted as a mulch on the soil surface. This implies that though organic matter always reduces splash detachment, different processes may be involved, depending on the form of the organic material. Because of the different processes involved, both negative and positive relationships between splash detachment and aggregate stability as reported in literature were obtained for the soils with grass and peat respectively.     

Soil organic carbon storage and soil CO_2 flux in the alpine meadow ecosystem

High-resolution sampling,measurements of organic carbon contents and 14C signatures of selected four soil profiles in the Haibei Station situated on the northeast Tibetan Plateau,and application of 14C tracing technology were conducted in an attempt to investigate the turnover times of soil organic car-bon and the soil-CO2 flux in the alpine meadow ecosystem. The results show that the organic carbon stored in the soils varies from 22.12×104 kg C hm-2 to 30.75×104 kg C hm-2 in the alpine meadow eco-systems,with an average of 26.86×104 kg C hm-2. Turnover times of organic carbon pools increase with depth from 45 a to 73 a in the surface soil horizon to hundreds of years or millennia or even longer at the deep soil horizons in the alpine meadow ecosystems. The soil-CO2 flux ranges from 103.24 g C m-2 a-1 to 254.93 gC m-2 a-1,with an average of 191.23 g C m-2 a-1. The CO2 efflux produced from microbial decomposition of organic matter varies from 73.3 g C m-2 a-1 to 181 g C m-2 a-1. More than 30% of total soil organic carbon resides in the active carbon pool and 72.8%―81.23% of total CO2 emitted from or-ganic matter decomposition results from the topsoil horizon (from 0 cm to 10 cm) for the Kobresia meadow. Responding to global warming,the storage,volume of flow and fate of the soil organic carbon in the alpine meadow ecosystem of the Tibetan Plateau will be changed,which needs further research.     

Vegetation and soil carbon storage in China

This study estimated the current vegetation and soil carbon storage in China using a biogeochemical model driven with climate, soil and vegetation data at 0.5° latitude-longitude grid spatial resolution. The results indicate that the total carbon storage in China's vegetation and soils was 13.33 Gt C and 82.65 Gt C respectively, about 3% and 4% of the global total. The nationally mean vegetation and soil carbon densities were 1.47 kg C/m2 and 9.17 kg C/m2, respectively, differing greatly in various regions affected by climate, vegetation, and soil types. They were generally higher in the warm and wet Southeast China and Southwest China than in the arid Northwest China; whereas vegetation carbon density was the highest in the warm Southeast China and Southwest China, soil carbon density was the highest in the cold Northeast China and southeastern fringe of the Qinghai-Tibetan Plateau. These spatial patterns are clearly correlated with variations in the climate that regulates plant growth and soil organi     

The distribution characteristic and its significance of compound specific isotopic composition of aromatic hydrocarbon from marine source rock and oil in the Tarim Basin,western China

Aromatic hydrocarbons are generally main distillation of crude oil and organic extract of source rocks. Bicyclic and tricyclic aromatic hydrocarbons can be purified by two-step method of chromatography on alumina. Carbon isotopic composition of individual aromatic hydrocarbons is affected not only by thermal maturity, but also by organic matter input, depositional environment, and hydrocarbon generation process based on the GC-IRMS analysis of Upper Ordovician, Lower Ordovician, and Cambrian source rocks in different areas in the Tarim Basin, western China. The subgroups of aromatic hydrocarbons as well as individual aromatic compound, such as 1-MP, 9-MP, and 2,6-DMP from Cambrian-Lower Ordovician section show more depleted 13 C distribution. The 13 C value difference between Cambrian-Lower Ordovician section and Upper Ordovician source rocks is up to 16.1‰ for subgroups and 14‰ for individual compounds. It can provide strong evidence for oil source correlation by combing the 13 C value and biomarker distribution of different oil and source rocks from different strata in the Tarim Basin. Most oils from Tazhong area have geochemical characteristics such as more negative 13C9-MP value, poor gammacerane, and abundant homohopanes, which indicate that Upper Ordovician source rock is the main source rock. In contrast, oils from Tadong area and some oils from Tazhong area have geochemical characteristics such as high 13C9-MP value, abundant gammacerane, and poor homohopanes, which suggest that the major contributor is Cambrian-Lower Ordovician source rock.     

抚仙湖流域不同农业模式砾质土壤环境质量及其氮磷流失风险评估

于2006年8月分层采集抚仙湖流域有机及传统农业农田砾质土壤,对土壤样品的机械组成、重金属含量、养分剖面积累进行测定分析;通过室内降雨模拟,对不同土壤样品氮磷流失风险进行评估.结果表明:①有机及传统农业模式下,砾质土壤机械组成发生明显变化,0-20cm土层砂粒含量明显降低:②除传统农业土壤Cd为二级标准,其他土壤重金属含量均符合国家土壤环境质量(GB/15618-1995)一级标准:③有机及传统农业模式下0-20cm土层有机质、全氮养分明显积累,但不同农业模式问无明显差异:有机农业土壤全磷、水溶性氮磷积累程度显著高于传统农业土壤;④有机农业土壤在780mm模拟降雨条件下,氮、磷流失风险更大,氮、磷流失总量分别是传统农业土壤的1.9倍、19.8倍.     

Effects of peat content,rainfall duration and aggregate size on soil crust strength

The effect of peat on crust strength was investigated using ten soils with organic matter levels ranging from 1-50 to 18-23 per cent. As peat content increased, the crust strength reduced. This occurred in spite of the inability of peat to increase the stability of soil aggregates. Peat reduced crust strength by acting as a mulch on the soil surface, thereby reducing breakdown of soil aggregates. Peat also formed a source of weakness on the soil, reducing crust formation. Using a factorial experiment involving a further seven soils with different levels of peat treatment, exposed to four rainfall durations and with two aggregate sizes, crust strength was described in terms of the direct effects and the interactions of these factors. Most of the crust strength values reduced with increasing peat content. For each soil, crust strength increased significantly with increasing rainfall duration. Crust strength was greater for the smaller aggregate size. The most significant interactions affecting crust strength were between soil and aggregate size, rainfall duration and aggregate size, and soil and rainfall duration in that order. These interactions were used to describe the effect of organic matter in form of peat on crust strength. For each soil and aggregate size, polynomial relationships were established to relate crust strength to total kinetic energy of rainfall.     

Mobilisierbarkeit von hydrophoben organischen Schadstoffen in belasteten Böden und Abfällen. Teil I: Mobilisierbarkeit von PCB,PAK und n-Alkanen durch Lösungsvermittler

Mobilization Potential of Hydrophobic Organic Compounds (HOCs) in Contaminated Soils and Waste Materials. Part I: Mobilization Potential of PCBs, PAHs, and Aliphatic Hydrocarbons in the Presence of Solubilizing Substances When using an elution procedure for organic pollutants to estimate the leaching behaviour of contamined soils and waste deposits, the influence of organic matter in solids and eluates adequately has to be considered. In batch tests with a solid/liquid ratio of 1:10, various aqueous solutions were composed, the solubilizing effect of which can be attributed to ubiquitous natural compounds (e. g., phospholipids, humic and carbonic acids). These solutions were evaluated in regard to the mobilization of PAHs, PCBs, and aliphatic hydrocarbons in soil and waste samples. The results were compared with batch tests containing sodium dodecyl sulfate (SDS), the properties and applications of which are selected and optimized in order to simulate the chemical interactions between pollutant and solubilizing substances of natural sources. Under alkaline conditions, the part of eluated pollutants was high because of the release of humic substances indigenous to the sample. Low concentrations of phospholipids and humic acid could decrease the mobility of aliphatic hydrocarbons. The extend of HOC mobilization is affected by specific interdependences between solubilizing substances and reactive matter of the samples. For most samples, 5.0 g/L concentrated SDS solution was able to simulate the most effective natural solutizer potential in regard to the mobilization of PAHs, PCBs, and aliphatic hydrocarbons within the system of batch tests. Whereas elution with pure water caused significant deviations in pollutant composition and too low yields, the use of SDS effected à good conformity. Modified in such a manner, the elution procedure can follow DIN 38414 part 4, when loss of pollutants will be minimized; e. g., centrifugation is needed to separate phases.     

Spatial variation of salt-marsh organic and inorganic deposition and organic carbon accumulation: Inferences from the Venice lagoon,Italy

Salt marshes are ubiquitous features of the tidal landscape governed by mutual feedbacks among processes of physical and biological nature. Improving our understanding of these feedbacks and of their effects on tidal geomorphological and ecological dynamics is a critical step to address issues related to salt-marsh conservation and response to changes in the environmental forcing. In particular, the spatial variation of organic and inorganic soil production processes at the marsh scale, a key piece of information to understand marsh responses to a changing climate, remains virtually unexplored. In order to characterize the relative importance of organic vs. inorganic deposition as a function of space, we collected 33 shallow soil sediment samples along three transects in the San Felice and Rigà salt marshes located in the Venice lagoon, Italy. The amount of organic matter in each sample was evaluated using Loss On Ignition (LOI), a hydrogen peroxide (H₂O₂) treatment, and a sodium hypochlorite (NaClO) treatment following the H₂O₂ treatment. The grain size distribution of the inorganic fraction was determined using laser diffraction techniques. Our study marshes exhibit a weakly concave-up profile, with maximum elevations and coarser inorganic grains along their edges. The amount of organic and inorganic matter content in the samples varies with the distance from the marsh edge and is very sensitive to the specific analysis method adopted. The use of a H₂O₂+NaClO treatment yields an organic matter density value which is more than double the value obtained from LOI. Overall, inorganic contributions to soil formation are greatest near the marsh edges, whereas organic soil production is the main contributor to soil accretion in the inner marsh. We interpret this pattern by considering that while plant biomass productivity is generally lower in the inner part of the marsh, organic soil decomposition rates are highest in the better aerated edge soils. Hence the higher inorganic soil content near the edge is due to the preferential deposition of inorganic sediment from the adjacent creek, and to the rapid decomposition of the relatively large biomass production. The higher organic matter content in the inner part of the marsh results from the small amounts of suspended sediment that makes it to the inner marsh, and to the low decomposition rate which more than compensates for the lower biomass productivity in the low-lying inner zones. Finally, the average soil organic carbon density from the LOI measurements is estimated to be 0.044 g C cm⁻³. The corresponding average carbon accumulation rate for the San Felice and Rigà salt marshes, 132 g C m⁻² yr⁻¹, highlights the considerable carbon stock and sequestration rate associated with coastal salt marshes.     

Dissolved Organic Carbon in Seepage Water – Production and Transformation during Soil Passage

Dissolved organic carbon (DOC) in seepage water can combine with organic pollutants, with Al and heavy metal ions and transport them through the soil profile with a potential to contaminate groundwater. We studied the production of DOC in aerobic decomposition experiments at 8 °C and moisture close to field capacity in soils from two sites with different microbial activities (spodic dystric Cambisols with moder (SLB) and mor‐moder (SLS) layers) using ¹³C‐depleted plants of differing decomposability (Epilobium angustifolium and Calamagrostis epigeios). Additionally, we investigated the DOC transformation during soil passage in decomposition experiments and in the field for the sites SLB and SLS. For SLS, decomposition of Epilobium resulted in a cumulative CO₂ production of 14% of the added C within 128 days. Priming effects were negligible. CO₂ production for the experiments using Calamagrostis was less with 11% for SLB and 10% for SLS. Cumulative DOC production was markedly high in the Epilobium decomposition experiment, being 25 g m^–2, out of which 11 g m^–2 were Epilobium‐derived (2% of the added C). For the Calamagrostis experiments, cumulative productions of DOC and Calamagrostis‐derived DOC (0.1% of the added C for SLS and SLB) were much less. During the soil passage, much of the DOC was removed by sorption or decomposition processes. Field studies at SLS and SLB using ¹³C natural abundance showed that ¹³C distribution of soil organic matter increased with depth, probably mainly due to a discrimination of C isotopes by decomposing microorganisms. DOC, however, showed a depletion of ¹³C from –28γ PDB to –29γ (SLB at 40 cm) or –28 to –30γ (SLS at 20 cm) with depth, owing to preferential decomposition of ¹³C‐enriched substances or preferential adsorption. This study indicates that DOC production is strongly affected by litter composition and that significant changes in DOC composition may occur during its passage through a soil depth of 40 cm.     

Biodegradation of petroleum hydrocarbons at low temperature in the presence of the dispersant Corexit 9500

Our study examined the effects of Corexit 9500 and sediment on microbial mineralization of specific aliphatic and aromatic hydrocarbons found in crude oil. We also measured gross mineralization of crude oil, dispersed crude oil and dispersant by a marine microbial consortium in the absence of sediment. When provided as carbon sources, our consortium mineralized Corexit 9500 the most rapidly, followed by fresh oil, and finally weathered oil or dispersed oil. However, mineralization in short term assays favored particular components of crude oil (2-methyl-naphthalene > dodecane > phenanthrene > hexadecane > pyrene) and was not affected by addition of nutrients or sediment (high sand, low organic carbon). Adding dispersant inhibited hexadecane and phenanthrene mineralization but did not affect dodecane and 2-methyl-naphthalene mineralization. Thus, the effect of dispersant on biodegradation of a specific hydrocarbon was not predictable by class. The results were consistent for both high and low oiling experiments and for both fresh and weathered oil. Overall, our results indicate that environmental use of Corexit 9500 could result in either increases or decreases in the toxicity of residual oil through selective microbial mineralization of hydrocarbons.     

The Eleni V oil spill: Fate and effects of the oil over the first twelve months: Part II. Biological effects

The general effects of the Eleni V oil spill on fisheries and intertidal organisms are described. There appears to have been little damage except by direct smothering. Oil hydrocarbon concentrations have been followed in a small intertidal population of mussels (Mytilus edulis) at Corton beach. Although the area became visually clean of oil, hydrocarbon concentrations in mussel flesh remained high 12 months after the spill and depuration rates in the laboratory were very slow. Shrimps (Crangon crangon) exposed to a water extract of beached Eleni V oil for 42 days showed no ill effects and little uptake of hydrocarbons. At the North Harbour site, where beached oil has not been disturbed, it appears that the fauna, used to oil contamination from other sources, has been little affected by the additional Eleni V oil.     

Geochemical characterization of soil organic matter and variability of a postglacial detrital organic supply (chaillexon lake,france)

Geochemical analysis of sedimentary organic matter in recent lacustrine sediments appears to be a useful tool in providing information concerning past environmental conditions. However, such analysis is often made without knowing the geochemical characteristics of the organic matter derived from the watershed and, more explicitly, its soils. The present work deals with (i) a geochemical investigation (Rock-Eval pyrolysis) of soil organic matter sampled in a lake watershed, and (ii) the study of the sedimentary organic matter trapped in the lake deposits. The research was conducted on Chaillexon Lake which was created by a rock collapse that dammed the palaeovalley of the Doubs River about 12 000 years ago. Since this event, the sediment trap provides a continuous palaeoclimatic record for the Postglacial period. Results obtained lead to two main conclusions. First, the variability of Rock-Eval pyrolysis values observed in soils modifies the common interpretation given to these parameters in the characterization of sedimentary organic matter. Indeed, variations in these parameters point not only to varying proportions of terrestrial and lacustrine organic matter in a lacustrine infilling but also to variations of the terrestrial supply linked with the evolution of vegetal cover in the catchment. The second conclusion is that the story of the Chaillexon lacustrine system is marked by a rather sudden soil and forest development at the Preboreal–Boreal transition (9000 BP ). Copyright © 1998 John Wiley & Sons, Ltd.     

Effects of incorporating two organic materials at varying levels on splash detachment of some soils from Borno state,Nigeria

Splash detachment by raindrops was measured using a factorial experiment involving three soils (sandy loam, clay loam and clay) and two organic materials (cow dung and groundnut haulms) applied at five levels (0, 2, 4, 6 and 8 per cent by mass). A simulated rainfall intensity of 145 mm h^?1 for 10 min duration was used for the tests. Detachment was described in terms of the direct effects and the first and second order interactions of the variables mentioned above. Results indicated that mean splash detachment was reduced significantly (P < 0·01) from 1·97 kg m^?2 in the sandy loam to 0·67 kgm^?2 in the clay soil. For each soil type, detachment was reduced significantly (P < 0.01) with increasing levels of added organic matter. Groundnut haulms produced lower values of detachment than cow dung. There were also significant interaction effects between the study variables. These interactions were used to describe the effect of added organic materials on splash detachment. For each soil type and organic material, negative exponential relationships were established to relate splash detachment to levels of added organic matter.     

Weathering of Oil in a Surficial Aquifer

The composition of crude oil in a surficial aquifer was determined in two locations at the Bemidji, MN, spill site. The abundances of 71 individual hydrocarbons varied within 16 locations sampled. Little depletion of these hydrocarbons (relative to the pipeline oil) occurred in the first 10 years after the spill, whereas losses of 25% to 85% of the total measured hydrocarbons occurred after 30 years. The C_6‐30 n‐alkanes, toluene, and o‐xylene were the most depleted hydrocarbons. Some hydrocarbons, such as the n‐C_10–24 cyclohexanes, tri‐ and tetra‐ methylbenzenes, acyclic isoprenoids, and naphthalenes were the least depleted. Benzene was detected at every sampling location 30 years after the spill. Degradation of the oil led to increases in the percent organic carbon and in the δ ¹³C of the oil. Another method of determining hydrocarbon loss was by normalizing the total measured hydrocarbon concentrations to that of the most conservative analytes. This method indicated that the total measured hydrocarbons were depleted by 47% to 77% and loss of the oil mass over 30 years was 18% to 31%. Differences in hydrocarbon depletion were related to the depth of the oil in the aquifer, local topography, amount of recharge reaching the oil, availability of electron acceptors, and the presence of less permeable soils above the oil. The results from this study indicate that once crude oil has been in the subsurface for a number of years there is no longer a “starting oil concentration” that can be used to understand processes that affect its fate and the transport of hydrocarbons in groundwater.     

Environmental effect of produced water from North Sea oil operations

Produced water from North Sea oil reservoirs contains substantial amounts (about 1g I⁻¹) of non-hydrocarbon organic matter, largely as salts of acetic, propionic and butyric acids, as well as some 20–40 mg I⁻¹ of dissolved hydrocarbons such as benzene, toluene and xylene. The non-hydrocarbon components originate in water in the oil-bearing formation. All of the organic matter can be accounted for, within analytical accuracy. The water also contains some 20–30 mg I⁻¹ of ammoniacal nitrogen and a number of inorganic components.At peak water production from production installations in the North Sea some 1−2 × 10⁵ tonnes yr⁻¹ of organic acids will be discharged in the U.K. sector of the North Sea.The ready biodegradability of the organic constituents and the low toxicity of produced water have been confirmed by direct measurement; acute toxicity is unlikely at dilutions of greater than 100 fold.Dispersion has been modelled and tested in the laboratory indicating some 1000 fold dilution within less than 50 m of the discharge.The laboratory studies are supported by field observations. Any direct deleterious effects are limited to the immediate vicinity of the discharge (within a few tens of metres).