Photometry of pluto in the last decade and before: evidence for volatile transport?

Photometric observations of Pluto in the BVR filter system were obtained in 1999 and in 1990-1993, and observations in the 0.89-μm methane absorption band were obtained in 2000. Our 1999 observations yield lightcurve amplitudes of 0.30 ± 0.01, 0.26 ± 0.01, and 0.21 ± 0.02 and geometric albedos of 0.44 ± 0.04, 0.52 ± 0.03, and 0.58 ± 0.02 in the B, V, and R filters, respectively. The low-albedo hemisphere of Pluto is slightly redder than the higher albedo hemisphere. A comparison of our results and those from previous epochs shows that the lightcurve of Pluto changes substantially through time. We developed a model that fully accounts for changes in the lightcurve caused by changes in the viewing geometry between the Earth, Pluto, and the Sun. We find that the observed changes in the amplitude of Pluto’s lightcurve can be explained by viewing geometry rather than by volatile transport. We also discovered a measurable decrease since 1992 of ∼0.03 magnitudes in the amplitude of Pluto’s lightcurve, as the model predicts. Pluto’s geometric albedo does not appear to be currently increasing, as our model predicts, although given the uncertainties in both the model and the measurements of geometric albedo, this result is not firm evidence for volatile transport. The maximum of methane-absorption lightcurve occurs near the minimum of the BVR lightcurves. This result suggests that methane is more abundant in the brightest regions of Pluto. Pluto’s phase coefficient exhibits a color dependence, ranging from 0.037 ± 0.01 in the B filter to 0.032 ± 0.01 in the R filter. Pluto’s phase curve is most like those of the bright, recently resurfaced satellites Triton and Europa. Although Pluto shows no strong evidence for volatile transport now (unlike Triton), it is important to continue to observe Pluto as it moves away from perihelion.     

The effect of Nix and Hydra on the putative Pluto–Charon dust cloud

Impact-generated dust clouds around airless bodies have been observed or suggested to be present throughout the solar system, including around the Martian, Galilean and Saturnian satellites. Simulations have assessed Pluto and Charon as sources of a possible dust cloud or torus and found that such a cloud would be dominated by Charon-produced ejecta and would have an optical depth of τ≈10⁻¹¹. These simulations were conducted before the discovery of two additional, small satellites of Pluto, Nix and Hydra. These small moons may yield impact-generated dust in excess of their larger counterparts due to their lower escape velocities, despite their smaller cross sections. In this paper, we extend a previous model of the Pluto–Charon dust cloud to include Nix and Hydra, both as sinks for Pluto- and Charon-generated dust and as sources of impact-generated dust. We find that Nix- and Hydra-generated dust grains outlive Pluto and Charon dust grains significantly and are the dominant contributors of dust in the Pluto–Charon system. Furthermore, we estimate the net geometric optical depth of grains between 0.1 and to be on the order of 10⁻⁷.     

Spatial and Compositional Constraints on Non-ice Components and H2O on Pluto's Surface

We present four new near-infrared spectra of Pluto, measured separately from its satellite Charon during four HST/NICMOS observations in 1998, timed to sample four evenly spaced longitudes on Pluto. Being free of contamination by telluric absorptions or by Charon light, the new data are particularly valuable for studies of Pluto's continuum absorption. Previous studies of the major volatile species indicate the existence of at least three distinct terrains on Pluto's surface: N₂-rich, CH₄-rich, and volatile-depleted. The new data provide evidence that each of these three terrains has distinct near-infrared continuum absorption features. CH₄-rich regions appear to show reddish continuum absorption through the near-infrared spectral range. N₂-rich regions have very little continuum absorption. Visually dark, volatile-depleted regions exhibit intermediate continuum albedos with a bluish continuum slope. By analogy with Triton, we expected that careful spectral modeling would reveal strong evidence for the existence of H₂O ice on Pluto's surface, but we found only very weak evidence for its existence in the volatile-depleted regions. These data require H₂O ice to play a much less prominent role on Pluto's surface than it does on Triton's.     

The Temperature-Dependent Spectrum of Methane Ice I between 0.7 and 5 μm and Opportunities for Near-Infrared Remote Thermometry

New infrared absorption coefficient spectra of pure methane ice I were measured at temperatures between 30 and 90 K, over wavelengths from 0.7 to 5 μm, along with spectra of methane ice II at 20 K and liquid methane at 93 K. The spectra were derived from transmission measurements through monocrystalline samples grown in a series of closed cells having interior dimensions ranging from 100 μm to 1 cm. The thicker samples permitted measurement of extremely weak absorption bands, with absorption coefficients as small as 0.003 cm⁻¹. We report 14 new absorption bands, which we tentatively assign to specific vibrational transitions. Two of the new bands are attributed to CH₃D. Measurements of the weaker CH₄ bands are particularly needed for interpreting spectral observations of Pluto and Triton, where a number of weak CH₄-ice absorption bands have been observed. The data presented in this paper complement studies of spectral transmission by thin films of methane ice, which are most suitable for measuring the stronger absorption bands. Temperature-dependent spectral features revealed by the new data offer the opportunity to determine CH₄-ice temperatures remotely, via near-infrared reflectance spectroscopy. This approach could prove particularly valuable for future spacecraft exploration of Pluto.     

NN detectability in Pluto’s atmosphere

Based on the vapor pressure behavior of Pluto’s surface ices, Pluto’s atmosphere is expected to be predominantly composed of N₂ gas. Measurement of the N₂ isotopologue ¹⁵N/¹⁴N ratio within Pluto’s atmosphere would provide important clues to the evolution of Pluto’s atmosphere from the time of formation to its present state. The most straightforward way of determining the N₂ isotopologue ¹⁵N/¹⁴N ratio in Pluto’s atmosphere is via spectroscopic observation of the ¹⁴N¹⁵N gas species. Recent calculations of the 80–100 nm absorption behavior of the ¹⁴N₂ and ¹⁴N¹⁵N isotopologues by Heays et al. (Heays, A.N. et al. [2011]. J. Chem. Phys. 135, 244301), Lewis et al. (Lewis, B.R., Heays, A.N., Gibson, S.T., Lefebvre-Brion, H., Lefebvre, R. [2008]. J. Chem. Phys. 129, 164306); Lewis et al. (Lewis, B.R., Gibson, S.T., Zhang, W., Lefebvre-Brion, H., Robbe, J.-M. [2005]. J. Chem. Phys. 122, 144302), and Haverd et al. (Haverd, V.E., Lewis, B.R., Gibson, S.T., Stark, G. [2005]. J. Chem. Phys. 123, 214304) show that the peak magnitudes of the ¹⁴N₂ and ¹⁴N¹⁵N absorption bandhead cross-sections are similar, but the locations of the bandhead peaks are offset in wavelength by ∼0.05–0.1 nm. These offsets make the segregation of the ¹⁴N₂ and ¹⁴N¹⁵N absorption signatures possible. We use the most recent N₂ isotopologue absorption cross-section calculations and the atmospheric density profiles resulting from photochemical models developed by Krasnopolsky and Cruickshank (Krasnopolsky, V.A., Cruickshank, D.P. [1999]. J. Geophys. Res. 104, 21979–21996) to predict the level of solar light that will be transmitted through Pluto’s atmosphere as a function of altitude during a Pluto solar occultation. We characterize the detectability of the isotopic absorption signature per altitude assuming ¹⁴N¹⁵N concentrations ranging from 0.1% to 2% of the ¹⁴N₂ density and instrumental spectral resolutions ranging from 0.01 to 0.3 nm. Our simulations indicate that optical depth of unity is attained in the key ¹⁴N¹⁵N absorption bands located between 85 and 90 nm at altitudes ∼1100–1600 km above Pluto’s surface. Additionally, an ¹⁴N¹⁵N isotope absorption depth ∼4–15% is predicted for observations obtained at these altitudes at a spectral resolution of ∼0.2–0.3 nm, if the N₂ isotopologue ¹⁵N/¹⁴N percent ratio is comparable to the 0.37–0.6% ratio observed at Earth, Titan and Mars. If we presume that the predicted absorption depth must be at least 25% greater than the expected observational uncertainty, then it follows that a statistically significant detection of these signatures and constraint of the N₂ isotopologue ¹⁴N/¹⁵N ratio within Pluto’s atmosphere will be possible if the attainable observational signal-to noise (S/N) ratio is ?9. The New Horizons (NH) Mission will be able to obtain high S/N, 0.27–0.35 nm full-width half-max 80–100 nm spectral observations of Pluto using the Alice spectrograph. Based on the NH/Alice specifications we have simulated 0.3 nm spectral resolution solar occultation spectra for the 1100–1600 km altitude range, assuming 30 s integration times. These simulations indicate that NH/Alice will obtain spectral observations within this altitude range with a S/N ratio ∼25–50, and should be able to reliably detect the ¹⁴N¹⁵N gas absorption signature between 85 and 90 nm if the ¹⁴N¹⁵N concentration is ∼0.3% or greater. This, additionally, implies that the non-detection of the ¹⁴N¹⁵N species in the 1100–1600 km range by NH/Alice may be used to reliably establish an upper limit to the N₂ isotopologue ¹⁵N/¹⁴N ratio within Pluto’s atmosphere. Similar results may be derived from 0.2 to 0.3 nm spectral resolution observations of any other N₂-rich Solar System or exoplanet atmosphere, provided the observations are attained with similar S/N levels.     

Does pluto have a substantial atmosphere?

The presence of CH₄ ice on Pluto implies that Pluto may have a substantial atmosphere consisting of heavy gases. Without such an atmosphere, sublimation of the CH₄ ice would be so rapid on a cosmogonic time scale that either such an atmosphere would soon develop through the exposure of gases trapped in the CH₄ ice or else the surface CH₄ ice would soon be all sublimated away as other, more stable, ices became exposed. If such stable ices were present from the beginning, the existence of CH₄ frosts would also imply that Pluto's present atmosphere contains a remnant of its primordial atmosphere.     

An investigation of Pluto’s troposphere using stellar occultation light curves and an atmospheric radiative-conductive-convective model

We use a radiative-conductive-convective model to assess the height of Pluto’s troposphere, as well as surface pressure and surface radius, from stellar occultation data from the years 1988, 2002, and 2006. The height of the troposphere, if it exists, is less than 1 km for all years analyzed. Pluto has at most a planetary boundary layer and not a troposphere. As in previous analyses of Pluto occultation light curves, we find that the surface pressure is increasing with time, assuming that latitude and longitude variations in Pluto’s atmosphere are negligible. The surface pressure is found to be slightly higher ( μbar in 1988,  μbar in 2002, and 18.5 ± 4.7 μbar in 2006) than in our previous analyses with the troposphere excluded. The surface radius is determined to be . Comparison of the minimum reduced chi-squared values between the best-fit radiative-conductive-convective (i.e., troposphere-included) model and best-fit radiative-conductive (i.e., troposphere-excluded) shows that the troposphere-included model is only a slightly better fit to the data for all 3 years. Uncertainties in the small-scale physical processes of Pluto’s lower atmosphere and consequently the functional form of the model troposphere lend more confidence to the troposphere-excluded results.     

ESO-Large Program on TNOs: Near-infrared spectroscopy with SINFONI

We present in this work the observations performed with SINFONI in the framework of a new ESO-Large Program (2006-2008) on Trans-Neptunian Objects (TNOs) and Centaurs. We obtained 21 near-infrared (1.49 to 2.4 microns) spectra of high quality, including 4 spectra of objects never observed before. We search for the presence of features due to ices, particularly water ice. Eris is the only object showing deep methane ice absorption bands. The spectra of 4 objects are featureless, and 6 others show clearly the presence of water ice. For 7 objects, the detections are more ambiguous, but absorption bands could be embedded in the noise. The 3 remaining spectra are too noisy to draw any reliable conclusion. The possible amount of water ice on each object's surface has been computed. The analysis shows that some objects present strong compositional heterogeneities over the surface (e.g. Chariklo), while some others are completely homogeneous (e.g. Quaoar).     

Buoyancy waves in Pluto’s high atmosphere: Implications for stellar occultations

We apply scintillation theory to stellar signal fluctuations in the high-resolution, high signal/noise, dual-wavelength data from the MMT observation of the 2007 March 18 occultation of P445.3 by Pluto. A well-defined high wavenumber cutoff in the fluctuations is consistent with viscous-thermal dissipation of buoyancy waves (internal gravity waves) in Pluto’s high atmosphere, and provides strong evidence that the underlying density fluctuations are governed by the gravity-wave dispersion relation.     

Ejecta exchange and satellite color evolution in the Pluto system, with implications for KBOs and asteroids with satellites

In this Note, I present first-order scaling calculations to examine the efficacy of impacts by Kuiper Belt debris in causing regolith exchange between objects in the Pluto system. It is found that ejecta can escape Nix and Hydra with sufficient velocity to reach one another, as well as Charon, and even Pluto. The degree of ejecta exchanged between Nix and Hydra is sufficient to cover these bodies with much more material than is required for photometrically change. In specific, Nix and Hydra may have exchanged as up to 10s of meters of regolith, and may have covered Charon to depths up to 14 cm with their ejecta. Pluto is likely unaffected by most Nix and Hydra ejecta by virtue of a combination of dynamical shielding from Charon and Pluto's own annual atmospheric frost deposition cycle. As a result of ejecta exchange between Nix, Hydra, and Charon, these bodies are expected to evolve their colors, albedos, and other photometric properties to be self similar. These are testable predictions of this model, as is the prediction that Nix and Hydra will have diameters near 50 km, owing to having a Charon-like albedo induced by ejecta exchange. As I discuss, this ejecta exchange process can also be effective in many KBOs and asteroids with satellites, and may be the reason that very many KBO and asteroid satellite systems have like colors.     

Near-infrared spectral monitoring of Triton with IRTF/SpeX II: Spatial distribution and evolution of ices

This report arises from an ongoing program to monitor Neptune’s largest moon Triton spectroscopically in the 0.8 to 2.4 μm range using IRTF/SpeX. Our objective is to search for changes on Triton’s surface as witnessed by changes in the infrared absorption bands of its surface ices N₂,CH₄,H₂O, CO, and CO₂. We have recorded infrared spectra of Triton on 53 nights over the ten apparitions from 2000 to 2009. The data generally confirm our previously reported diurnal spectral variations of the ice absorption bands (Grundy and Young, 2004). Nitrogen ice shows a large amplitude variation, with much stronger absorption on Triton’s Neptune-facing hemisphere. We present evidence for seasonal evolution of Triton’s N₂ ice: the 2.15 μm absorption band appears to be diminishing, especially on the Neptune-facing hemisphere. Although it is mostly dissolved in N₂ ice, Triton’s CH₄ ice shows a very different longitudinal variation from the N₂ ice, challenging assumptions of how the two ices behave. Unlike Triton’s CH₄ ice, the CO ice does exhibit longitudinal variation very similar to the N₂ ice, implying that CO and N₂ condense and sublimate together, maintaining a consistent mixing ratio. Absorptions by H₂O and CO₂ ices show negligible variation as Triton rotates, implying very uniform and/or high latitude spatial distributions for those two non-volatile ices.     

Ultraviolet spectroscopy of Asteroid (4) Vesta

We report a comprehensive review of the UV–visible spectrum and rotational lightcurve of Vesta combining new observations by Hubble Space Telescope and Swift Gamma-ray Burst Observatory with archival International Ultraviolet Explorer observations. The geometric albedos of Vesta from 220 nm to 953 nm are derived by carefully comparing these observations from various instruments at different times and observing geometries. Vesta has a rotationally averaged geometric albedo of 0.09 at 250 nm, 0.14 at 300 nm, 0.26 at 373 nm, 0.38 at 673 nm, and 0.30 at 950 nm. The linear spectral slope as measured between 240 and 320 nm in the ultraviolet displays a sharp minimum near a sub-Earth longitude of 20°, and maximum in the eastern hemisphere. This is consistent with the longitudinal distribution of the spectral slope in the visible wavelength. The photometric uncertainty in the ultraviolet is ∼20%, and in the visible wavelengths it is better than 10%. The amplitude of Vesta’s rotational lightcurves is ∼10% throughout the range of wavelengths we observed, but is smaller at 950 nm (∼6%) near the 1-μm band center. Contrary to earlier reports, we found no evidence for any difference between the phasing of the ultraviolet and visible/near-infrared lightcurves with respect to sub-Earth longitude. Vesta’s average spectrum between 220 and 950 nm can well be described by measured reflectance spectra of fine particle howardite-like materials of basaltic achondrite meteorites. Combining this with the in-phase behavior of the ultraviolet, visible, and near-infrared lightcurves, and the spectral slopes with respect to the rotational phase, we conclude that there is no global ultraviolet/visible reversal on Vesta. Consequently, this implies a lack of global space weathering on Vesta, as previously inferred from visible–near-infrared data.     

Constraints on bulk composition,seasonal variation,and global dynamics of Pluto's atmosphere

Cosmic abundance, vapor pressure, and molecular weight considerations restrict the likely gas candidates for Pluto's atmosphere to Ne, N₂, CO, O₂, and Ar, in addition to the already detected CH₄. The vapor pressures and cosmic abundances of these gases indicate that all except Ne should be saturated in Pluto's atmosphere. The vapor pressure of Ne is so high that the existence of solid or liquid Ne on Pluto's surface is very unlikely; cosmic abundance arguments imply that Ne cannot attain saturation in Pluto's atmosphere. At both perihelion, N₂ should dominate the saturated gases. CO₂ should have the next highest mixing ratio, followed by O₂ and Ar. CH₄ should have the smallest mixing ratio. Because vapor pressures of these gases vary with temperature at diverse rates, the bulk and constituent mixing ratios of Pluto's atmosphere should vary with season. Between perihelion and aphelion, the column abundance of CH₄ may change by a factor of 260 while that of N₂ changes by only a factor of 52. The potential seasonal variation of Pluto's atmosphere was investigated by considering the behavior of these gases when individually mixed with CH₄. The effects of diurnal and latitudinal variation of insolation and eclipses on the atmosphere also were investigated. Seasonal effects are shown to dominate. It was shown that the atmospheric bulk may not be a minimum near aphelion but rather at intermediate distances from the Sun during summer/winter inadequate ice deposits may allow the atmosphere to collapse by freezing out over winter latitudes. If the atmosphere does not collapse, its weight is sufficient to keep it distributed uniformly around Pluto's surface. In this case, the atmosphere tends to regulate the surface temperature to a seasonally dependent value which is uniform over the globe.Finally, the likely global circulation regimes for each model atmosphere as a function of temperature were investigated and it was concluded that if CH₄, O₂, or CO dominates the atmosphere, Pluto will exhibit cyclic variations between an axially symmetric circulation system at perihelion and a baroclinic wave regime at aphelion. However, if N₂ dominates, as is likely, the wave regime should hold continuously. If the atmosphere collapses to a thin halo during summer/winter seasons, only a weak, symmetric circulation should occur.     

Radiation Products in Processed Ices Relevant to Edgeworth-Kuiper-Belt Objects

Near the inner edge of the Edgeworth-Kuiper Belt (EKB) are Pluto and Charon, which are known to have N₂- and H₂O-dominated surface ices, respectively. Such non-polar and polar ices, and perhaps mixtures of them, also may be present on other trans-Neptunian objects. Pluto, Charon, and all EKB objects reside in a weak, but constant UV-photon and energetic ion radiation environment that drives chemical reactions in their surface ices. Effects of photon and ion processing include changes in ice composition, volatility, spectra, and albedo, and these have been studied in a number of laboratories. This paper focuses on ice processing by ion irradiation and is aimed at understanding the volatiles, ions, and residues that may exist on outer solar system objects. We summarize radiation chemical products of N₂-rich and H₂O-rich ices containing CO or CH₄, including possible volatiles such as alcohols, acids, and bases. Less-volatile products that could accumulate on EKB objects are observed to form in the laboratory from acid-base reactions, reactions promoted by warming, or reactions due to radiation processing of a relatively pure ice (e.g., CO → C₃O₂). New IR spectra are reported for the 1–5 mu;m region, along with band strengths for the stronger features of carbon suboxide, carbonic acid, the ammonium and cyanate ions, polyoxymethylene, and ethylene glycol. These six materials are possible contributors to EKB surfaces, and will be of interest to observers and future missions.     

The ultraviolet reflectance of Enceladus: Implications for surface composition

The reflectance of Saturn’s moon Enceladus has been measured at far ultraviolet (FUV) wavelengths (115-190 nm) by Cassini’s Ultraviolet Imaging Spectrograph (UVIS). At visible and near infrared (VNIR) wavelengths Enceladus’ reflectance spectrum is very bright, consistent with a surface composed primarily of H₂O ice. At FUV wavelengths, however, Enceladus is surprisingly dark - darker than would be expected for pure water ice. Previous analyses have focused on the VNIR spectrum, comparing it to pure water ice (Cruikshank, D.P., Owen, T.C., Dalle Ore, C., Geballe, T.R., Roush, T.L., de Bergh, C., Sandford, S.A., Poulet, F., Benedix, G.K., Emery, J.P. [2005] Icarus, 175, 268-283) or pure water ice plus a small amount of NH₃ (Emery, J.P., Burr, D.M., Cruikshank, D.P., Brown, R.H., Dalton, J.B. [2005] Astron. Astrophys., 435, 353-362) or NH₃ hydrate (Verbiscer, A.J., Peterson, D.E., Skrutskie, M.F., Cushing, M., Helfenstein, P., Nelson, M.J., Smith, J.D., Wilson, J.C. [2006] Icarus, 182, 211-223). We compare Enceladus’ FUV spectrum to existing laboratory measurements of the reflectance spectra of candidate species, and to spectral models. We find that the low FUV reflectance of Enceladus can be explained by the presence of a small amount of NH₃ and a small amount of a tholin in addition to H₂O ice on the surface. The presence of these three species (H₂O, NH₃, and a tholin) appears to satisfy not only the low FUV reflectance and spectral shape, but also the middle-ultraviolet to visible wavelength brightness and spectral shape. We expect that ammonia in the Enceladus plume is transported across the surface to provide a global coating.     

Image tube spectra of pluto and triton from 6800 to 9000 Å

To search for a possible atmosphere on Pluto and Triton, spectra of these objects as well as comparison stars were obtained with a three-stage Varo image tube for the spectral region from 6800 to 9000 Å. Ratio spectra indicate an absorption feature near 8900 Å, although the steeply diminishing response of the image tube at that wavelength casts some doubt on the reality of this feature. The feature appears more definitive in the spectrum of Pluto and less certain in the spectrum of Triton. The absorption was analyzed using our recently determined band-model parameters for methane. Under the assumption of a pressure higher than 0.01 atm an abundance of 3 m-amagat was determined. For pressures limited by the methane abundance itself, an abundance of 50 m-amagat and a pressure of 10^?3 atm was derived (using g = 0.20 g⊕ for both Pluto and Triton). This pressure is close to the pressure that can be expected from the equilibrium vapor pressure of a methane frost. If the absorption at 8900 Å is spurious, our analysis will be applicable as an upper limit for the presence of methane gas on Pluto or Triton.     

A dust cloud around Pluto and Charon

We suggest that Pluto and Charon are immersed in a tenuous dust cloud. The cloud consists of ejecta from Pluto and—especially—Charon, released from their surfaces by impacts of micrometeoroids originating from Edgeworth-Kuiper belt objects. The motion of the ejected grains is dominated by the gravity of Pluto and Charon, which determines a pear-shape of the densest part of the cloud. While the production rates of escaping particles from both sides are comparable, the lifetimes of the Charon particles inside the Hill sphere of Pluto-Charon with respect to the Sun are much longer than of the Pluto ejecta, so that the cloud is composed predominantly of Charon grains. The dust cloud is dense enough to be detected with an in situ dust detector onboard a future space mission to Pluto. The cloud's maximum optical depth of τ≈3×10⁻¹¹ is, however, too low to allow remote sensing observations.     

Composition of Titan''s surface from Cassini VIMS

Titan's bulk density along with Solar System formation models indicates considerable water as well as silicates as its major constituents. This satellite's dense atmosphere of nitrogen with methane is unique. Deposits or even oceans of organic compounds have been suggested to exist on Titan's solid surface due to UV-induced photochemistry in the atmosphere. Thus, the composition of the surface is a major piece of evidence needed to determine Titan's history. However, studies of the surface are hindered by the thick, absorbing, hazy and in some places cloudy atmosphere. Ground-based telescope investigations of the integral disk of Titan attempted to observe the surface albedo in spectral windows between methane absorptions by calculating and removing the haze effects. Their results were reported to be consistent with water ice on the surface that is contaminated with a small amount of dark material, perhaps organic material like tholin. We analyze here the recent Cassini Mission's visual and infrared mapping spectrometer (VIMS) observations that resolve regions on Titan. VIMS is able to see surface features and shows that there are spectral and therefore likely compositional units. By several methods, spectral albedo estimates within methane absorption windows between 0.75 and 5 μm were obtained for different surface units using VIMS image cubes from the Cassini-Huygens Titan T_a encounter. Of the spots studied, there appears to be two compositional classes present that are associated with the lower albedo and the higher albedo materials, with some variety among the brighter regions. These were compared with spectra of several different candidate materials. Our results show that the spectrum of water ice contaminated with a darker material matches the reflectance of the lower albedo Titan regions if the spectral slope from 2.71 to 2.79 μm in the poorly understood 2.8-μm methane window is ignored. The spectra for brighter regions are not matched by the spectrum of water ice or unoxidized tholin, in pure form or in mixtures with sufficient ice or tholin present to allow the water ice or tholin spectral features to be discerned. We find that the 2.8-μm methane absorption window is complex and seems to consist of two weak subwindows at 2.7 and 2.8 μm that have unknown opacities. A ratio image at these two wavelengths reveals an anomalous region on Titan that has a reflectance unlike any material so far identified, but it is unclear how much the reflectances in these two subwindows pertain to the surface.     

Pluto's light curve in 1933-1934

The Pluto-Charon system has complex photometric variations on all time scales; due to rotational modulations of dark markings across the surface, the changing orientation of the system as viewed from Earth, occultations and eclipses between Pluto and Charon, as well as the sublimation and condensation of frosts on the surface. The earliest useable light curve for Pluto is from 1953 to 1955 when Pluto was 35 AU from the Sun. Earlier data on Pluto has the potential to reveal properties of the surface at a greater heliocentric distance with nearly identical illumination and viewing geometry. We are reporting on a new accurate photographic light curve of Pluto for 1933-1934 when the heliocentric distance was 40 AU. We used 43 B-band and V-band images of Pluto on 32 plates taken on 15 nights from 19 March 1933 to 10 March 1934. Most of these plates were taken with the Mount Wilson 60″ and 100″ telescopes, but 7 of the plates (now at the Harvard College Observatory) were taken with the 12″ and 16″ Metcalf doublets at Oak Ridge. The plates were measured with an iris diaphragm photometer, which has an average one-sigma photometric error on these plates of 0.08 mag as measured by the repeatability of constant comparison stars. The modern B and V magnitudes for the comparison stars were measured with the Lowell Observatory Hall 1.1-m telescope. The magnitudes in the plate's photographic system were converted to the Johnson B- and V-system after correction with color terms, even though they are small in size. We find that the average B-band mean opposition magnitude of Pluto in 1933-1934 was 15.73±0.01, and we see a roughly sinusoidal modulation on the rotational period (6.38 days) with a peak-to-peak amplitude of 0.11±0.03 mag. With this, we show that Pluto darkened by 5% from 1933-1934 to 1953-1955. This darkening from 1933-1934 to 1953-1955 cannot be due to changing viewing geometry (as both epochs had identical sub-Earth latitudes), so our observations must record a real albedo change over the southern hemisphere. The later darkening trend from 1954 to the 1980's has been explained by changing viewing geometry (as more of the darker northern hemisphere comes into view). Thus, we now have strong evidence for albedo changes on the surface of Pluto, and these are most easily explained by the systematic sublimation of frosts from the sunward pole that led to a drop in the mean surface albedo.