Understanding the dynamics and contamination of an urban aquifer system using groundwater age (14C, 3H,CFCs) and chemistry

The quality of the groundwater supplying drinking water to the Guadalajara metropolitan area has deteriorated due to both endogenic and exogenic processes. Previous studies of this complex neotectonic volcanic environment suggest that the sources of contamination here are underground fluids derived from an active volcanic center and surface wastewater derived from regional land‐use intensification. This study uses isotopic, gaseous, and chemical signatures to more comprehensively characterize this groundwater flow and its contamination paths. Groundwater is mainly recharged at the La Primavera Caldera to the west and is discharged into the Santiago River to the east. The exception to this trend is the Toluquilla area, where groundwater most likely represents rainfall originating from outside the basin limits. Evaporation affects groundwater in these areas, especially waters that have been affected by recycling below urban areas in the Atejamac area and by intensive agricultural activity in the Toluquilla area. Additionally, we present evidence that groundwater flow through alluvial sediments and tuffs in deeper wells mixes with a lower aquifer unit in basaltic‐andesitic rocks, which are in contact with hydrothermal fluids. Groundwater ages range from postbomb in the western and northwestern regions of the study area (i.e., the Atemajac aquifer unit) to Late Pleistocene in the southern and southeastern regions (i.e., the Toluquilla aquifer unit). Recently recharged water records little mixing and is located mostly in or near the La Primavera volcanic system. As groundwater undergoes gravitational flow towards discharge areas, it mixes with older water components. Chloride and sodium concentrations above natural background levels are primarily related to volcanic activity, nitrate is associated with human activities, and sulfate originates from both anthropogenic sources and water–rock interactions. Nitrate originating from land‐use activities (such as sewers, septic tanks, landfills, and agricultural fields) that is introduced into the deeper part of the groundwater system is expected to travel with the groundwater to the discharge areas because oxidizing conditions will prevent microbial reduction. See Supplementary Information.     

Coastal aquifer response to extreme storm events in Emilia‐Romagna,Italy

With global warming and sea level rise, many coastal systems will experience increased levels of inundation and storm flooding, especially along sandy lowland coastal areas, such as the Northern Adriatic coast (Italy). Understanding how extreme events may directly affect groundwater hydrology in shallow unconfined coastal aquifers is important to assess coastal vulnerability and quantify freshwater resources. This study investigates shallow coastal aquifer response to storm events. The transitory and permanent effects of storm waves are evaluated through the real time monitoring of groundwater and soil parameters, in order to characterize both the saturated and unsaturated portions of the coastal aquifer of Ravenna and Ferrara (southern Po Delta, Italy). Results highlight a general increase in hydraulic head and soil moisture, along with a decrease in groundwater salinity and pore water salinity due to rainfall infiltration during the 2 days storm event. The only exceptions are represented by the observation wells in proximity to the coastline (within 100 m), which recorded a temporary increase in soil and water salinity caused by the exceptional high waves, which persist on top of the dune crest during the storm event. This generates a saline plume that infiltrates through the vadose zone down to the saturated portion of the aquifer causing a temporary disappearance of the freshwater lens generally present, although limited in size, below the coastal dunes. Despite the high hydraulic conductivity, the aquifer system does not quickly recover the pre‐storm equilibrium and the storm effects are evident in groundwater and soil parameters after 10 days past the storm overwash recess.     

Wellbore‐Wall Compression Effects on Monitored Groundwater Levels and Qualities

The effects of wellbore‐wall compression from rough excavation on monitored groundwater levels and qualities under natural hydraulic gradient conditions were investigated in a shallow clayey Andisol aquifer. Nine wellbores reaching the underlying aquitard at about 2.6‐m depth were constructed by dynamic cone penetrometry to mimic rough wellbore construction. Five of these were constructed under wet aquifer soil conditions and the remaining four under dry conditions. A 15‐month period monitoring showed that the groundwater levels in the wellbores constructed under wet conditions responded significantly in retard of, and in narrower ranges than, those constructed under dry conditions. The wellbore‐wall hydraulic conductivities at the former wellbores were calculated to be more than one to two orders of magnitude lower than those at the latter ones. Furthermore, remarkable nitrate removal attributable to the occurrence of a heterotrophic denitrification was observed in one of the former wellbores. In contrast, the groundwater levels and qualities in the latter wellbores appeared to be generally similar to those monitored in the conventional soil coring and augering‐derived wellbores. Our results suggest that the wellbore‐wall compression induced by rough excavation under wet and soft aquifer soil conditions leads to a substantial decrease in the wellbore‐wall hydraulic conductivity, which in turn can lead to unreliable groundwater levels and qualities. This problem can occur in clayey Andisols whenever the aquifer soil is wet; however, the problem can be largely avoided by constructing the wellbore under dry and hard aquifer soil conditions.     

Applying the HPT‐GWS for Hydrostratigraphy,Water Quality and Aquifer Recharge Investigations

The primary objective of this study was to evaluate use of the hydraulic profiling tool‐groundwater sampler (HPT‐GWS) log data as an indicator of water quality (level of dissolved ionic species) in an alluvial aquifer. The HPT‐GWS probe is designed for direct push advancement into unconsolidated formations. The system provides both injection pressure logs and electrical conductivity (EC) logs, and groundwater may be sampled at multiple depths as the probe is advanced (profiling). The combination of these three capabilities in one probe has not previously been available. During field work it was observed that when HPT corrected pressure (P_c) indicates a consistent aquifer unit then bulk formation EC can be used as an indicator of water quality. A high correlation coefficient (R ² = 0.93) was observed between groundwater specific conductance and bulk formation EC in the sands and gravels of the alluvial aquifer studied. These results indicate that groundwater specific conductance is exerting a controlling influence on the bulk formation EC of the coarse‐grained unit at this site, and probably many similar sites, consistent with Archie's Law. This simple relationship enables the use of the EC and P_c logs, with targeted water samples and a minimum of core samples, to rapidly assess groundwater quality over extended areas at high vertical resolution. This method was used to identify both a brine impacted zone at the base of the aquifer investigated and a groundwater recharge lens developing below storm water holding ponds in the upper portion of the same aquifer. Sample results for trace level, naturally occurring elements (As, Ba, U) further demonstrate the use of this system to sample for low level groundwater contamination.     

Assessing the Transport of Pharmaceutical Compounds in a Layered Aquifer Discharging to a Stream

A groundwater plume containing high concentrations of pharmaceutical compounds, mainly sulfonamides, barbiturates, and ethyl urethane, in addition to chlorinated ethenes and benzene was investigated. The contamination originating from a former pharmaceutical industry discharges into a multilayered aquifer system and a downgradient stream. In this study, geological and hydrogeological data were integrated into a numerical flow model to examine identified trends using statistical approaches, including principal component analysis and hierarchal cluster analysis. A joint interpretation of the groundwater flow paths and contaminant concentrations in the different compartments (i.e., groundwater and hyporheic zone) provided insight on the transport processes of the different contaminant plumes to the stream. The analysis of historical groundwater concentrations of pharmaceutical compounds at the site suggested these compounds are slowly degrading. The pharmaceutical compounds migrate in both a deep semiconfined aquifer, as well as in the shallow unconfined aquifer, and enter the stream along a 2-km stretch. This contrasted with the chlorinated ethenes, which mainly discharge to the stream as a focused plume from the unconfined aquifer. The integrated approach developed here, combining groundwater flow modeling and statistical analyses of the contaminant concentration data collected in groundwater and the hyporheic zone, lead to an improved understanding of the observed distribution of contaminants in the unconfined and semiconfined aquifers, and thus to their discharge to the stream. This approach is particularly relevant for large and long-lasting contaminant sources and plumes, such as abandoned landfills and industrial production sites, where field investigations may be very expensive.     

Assessing “Urban Karst” Effects from Groundwater–Storm Sewer System Interaction in a Till Aquitard

Storm sewer systems and their associated utility trenches may strongly influence the effects of urbanization on a groundwater system. This study was undertaken to identify the causes of district-wide basement infiltration in an aquitard system. It comprised widespread continuous monitoring of utility trench wells and dye tracing from storm sewer system exfiltration tests. The results indicate that a major effect of urbanization on shallow groundwater is related to storm sewer system exfiltration, which is marked by a characteristic pattern of head variations in the aquitard unrelated to distributed surface infiltration. The aquitard constrains flow from storm sewer system exfiltration to the utility trench, creating an urban flow path for groundwater discharge. Temporary buildup of water levels in the utility trench drives relatively high-velocity flow through the permeable sewer bedding material of the utility trench to a separate foundation drainage collector system, ultimately causing a severe “urban karst” effect that produces system surcharging and widespread basement water infiltration. The main conditions causing the “urban karst” are the large hydraulic conductivity ratio between the utility trench material and the aquitard, and the shallow depth and low gradient of the storm sewer system imposed by a very flat drainage basin.     

Use of an Artificial Sweetener to Identify Sources of Groundwater Nitrate Contamination

The artificial sweetener acesulfame (ACE) is a potentially useful tracer of waste water contamination in groundwater. In this study, ACE concentrations were measured in waste water and impacted groundwater at 12 septic system sites in Ontario, Canada. All samples of septic tank effluent (n = 37) had ACE >6 µg/L, all samples of groundwater from the proximal plume zones (n = 93) had ACE >1 µg/L and, almost all samples from the distal plume zones had ACE >2 µg/L. Mean mass ratios of total inorganic nitrogen/ACE at the 12 sites ranged from 680 to 3500 for the tank and proximal plume samples. At five sites, decreasing ratio values in the distal zones indicated nitrogen attenuation. These ratios were applied to three aquifers in Canada that are nitrate‐stressed and an urban stream where septic systems are present nearby to estimate the amount of waste water nitrate contamination. At the three aquifer locations that are agricultural, low ACE values (<0.02‐0.15 µg/L) indicated that waste water contributed <15% of the nitrate in most samples. In groundwater discharging to the urban stream, much higher ACE values (0.2‐11 µg/L) indicated that waste water was the likely source of >50% of the nitrate in most samples. This study confirms that ACE is a powerful tracer and demonstrates its use as a diagnostic tool for establishing whether waste water is a significant contributor to groundwater contamination or not.     

Tetrachloroethene Release and Degradation During Combined ERH and Sodium Persulfate Oxidation

Electrical resistance heating (ERH) is a thermal treatment technology that involves passing electrical current through soil to increase subsurface temperatures. In addition to volatizing and recovering contaminant mass in the gas phase, heating the subsurface has the potential to decompose contaminants by increasing the rate of degradation reactions. Prior laboratory studies using convective heating demonstrated that the rate of tetrachloroethene (PCE) degradation was not sufficient to cause substantial in situ PCE mass destruction. However, similar experiments have not been performed using ERH, which has the potential to degrade PCE in reaction with the heating electrodes and electrochemically. Thus, the objective of this study was to determine the extent of PCE degradation during thermal treatment of PCE‐contaminated soil using a bench‐scale ERH system. The contaminated soil, a silty clay loam, was collected from a single borehole at a former dry cleaning facility prior to undergoing ERH treatment. After 30 days of ERH, 52% of the initial PCE mass was recovered, potentially indicating that 48% of the PCE was degraded during ERH. Although potential degradation products such as carbon dioxide were observed, their presence was attributed to the degradation of soil organic carbon and carbonates rather than PCE destruction. A second ERH experiment was conducted to assess the potential benefit of adding the heat‐activated oxidant, sodium‐persulfate, during treatment. After 19 days of ERH and three persulfate injections, 93% of the initial PCE was recovered, with 3% PCE destruction based on chloride evolution. However, the difference in mass recovery between the first and second experiments could have been due to differences in the initial mass of PCE, even though soil from the same core was used in both experiments. The results of this work suggest that the majority of mass recovered during ERH of the PCE‐contaminated soil at the former dry cleaning facility will be due to volatilization and gas phase extraction rather than abiotic degradation, even with the addition of sodium persulfate.     

Monitoring In Situ Biodegradation of MTBE Using Multiple Rounds of Compound‐Specific Stable Carbon Isotope Analysis

At a large industrial facility, methyl tert‐butyl ether (MTBE) was released to the subsurface and dispersed into the light, non‐aqueous phase liquids (LNAPL), in the first aquifer, with the LNAPL serving as a continuous source of MTBE in groundwater. Compound‐specific isotope analysis was conducted on both MTBE and tert‐butyl alcohol (TBA) in groundwater samples collected in 2008, 2011, and 2013 from wells located along and off the center line of the MTBE plume. The study demonstrated the onset and progress of biodegradation of MTBE between 2008 and 2013. The TBA observed in 2008 appears to be derived only in part from MTBE transformation while a significant portion of TBA might be contributed directly from LNAPL sources. In 2011 to 2013, the dominant source of TBA in the mid‐gradient plume was MTBE transformation. A contribution of an offsite LNAPL source, in particular to the down‐gradient area of the plume, is possible but could not be unequivocally confirmed. The time series provided direct evidence for MTBE biodegradation, but also a valuable insight on the sources of TBA.     

Application of multivariate statistical procedures to the hydrochemical study of a coastal aquifer: an example from Crete,Greece

A variety of multivariate statistical procedures were applied to three separate sets of quantitative analytical data from a coastal aquifer located in Malia, Crete (Greece), in order to identify the major hydrochemical processes affecting the groundwater quality and to investigate the evolution of groundwater composition in three different sampling periods. Two of them were carried out on October 2001 and September 2002 at the end of the dry season and the third on April 2002 at the end of the wet period. Two factors were found that explained major hydrochemical processes in the aquifer. These factors reveal the existence of an intensive intrusion of seawater and mechanisms of nitrate contamination of groundwater. Bivariate plots of the scores of the two main factors showed that the seawater intrusion and nitrate pollution processes are maintained through three surveys and that the process of nitrate pollution increases from the first to the second dry survey. Q‐mode factor analysis and discriminant analysis of the three sampling periods clearly showed a seasonal variation of the whole chemistry of groundwater samples. This seasonal variation can be attributed to the freshwater recharge and seawater intrusion that affect the groundwater quality of the Malia aquifer. The results of trend surface analysis are in agreement with those of factor analysis. Moreover, the fourth‐order trend surfaces of EC, Cl^? and NO₃^? showed that the salinization process is more intensive during the first dry period and the spatial variation of NO₃^? maxima plumes are strongly affected by the flow regime of the Malia aquifer. Copyright © 2007 John Wiley & Sons, Ltd.     

Arsenic Cycling in Hydrocarbon Plumes: Secondary Effects of Natural Attenuation

Monitored natural attenuation is widely applied as a remediation strategy at hydrocarbon spill sites. Natural attenuation relies on biodegradation of hydrocarbons coupled with reduction of electron acceptors, including solid phase ferric iron (Fe(III)). Because arsenic (As) adsorbs to Fe‐hydroxides, a potential secondary effect of natural attenuation of hydrocarbons coupled with Fe(III) reduction is a release of naturally occurring As to groundwater. At a crude‐oil‐contaminated aquifer near Bemidji, Minnesota, anaerobic biodegradation of hydrocarbons coupled to Fe(III) reduction has been well documented. We collected groundwater samples at the site annually from 2009 to 2013 to examine if As is released to groundwater and, if so, to document relationships between As and Fe inside and outside of the dissolved hydrocarbon plume. Arsenic concentrations in groundwater in the plume reached 230 µg/L, whereas groundwater outside the plume contained less than 5 µg/L As. Combined with previous data from the Bemidji site, our results suggest that (1) naturally occurring As is associated with Fe‐hydroxides present in the glacially derived aquifer sediments; (2) introduction of hydrocarbons results in reduction of Fe‐hydroxides, releasing As and Fe to groundwater; (3) at the leading edge of the plume, As and Fe are removed from groundwater and retained on sediments; and (4) downgradient from the plume, patterns of As and Fe in groundwater are similar to background. We develop a conceptual model of secondary As release due to natural attenuation of hydrocarbons that can be applied to other sites where an influx of biodegradable organic carbon promotes Fe(III) reduction.     

Hydrological processes of a rainforest headwater swamp from natural chemical tracing in Nsimi watershed,Cameroon

The hydrological role of a headwater swamp in a tropical rainforest is studied using chloride mass balance (CMB) and end‐member mixing analysis. There are three main contributions to streamflow: (1) the hillside bedrock aquifer, (2) overland flow from the swamp during storm events and (3) groundwater flow from the swamp aquifer. Before rainfall events of the wet season, the pre‐event water comprises a mix of 80% of bedrock aquifer and 20% of swamp aquifer. During storms, the relative contribution of overland flow increases according to the rainfall intensity and the initial saturation rate of the pre‐event water reservoirs. The yearly contribution of overland flow from the swamp to the stream is about 31%. The relationship between the swamp and the stream fluctuates with space and time. Generally, the swamp is drained by the stream; however, at the end of long dry seasons, after the first rains, indirect recharge occurs from the stream to the swamp with a hydraulic gradient inversion in the swamp aquifer. The net contribution of the swamp aquifer to the stream is only 4%, which is much lower than the hillside aquifer contribution of about 65%. Recharge on the swamp being very low, these results suggest that, except for a few storms at the end of the dry season, the Nsimi swamp does not contribute to flood attenuation. Evapotranspiration is higher on the hillside than in the swamp. Nevertheless, depletion of water stored within the swamp is dominated by evaporation rather than by its contribution to streamflow. The export of solutes through swamp groundwater flow below the weir is low (<7%). Nevertheless, the swamp is the most active area of weathering in the watershed. Copyright © 2011 John Wiley & Sons, Ltd.     

Numerical modelling of stream–aquifer interaction: Quantifying the impact of transient streambed permeability and aquifer heterogeneity

Stream–aquifer interaction plays a vital role in the water cycle, and a proper study of this interaction is needed for understanding groundwater recharge, contaminants migration, and for managing surface water and groundwater resources. A model‐based investigation of a field experiment in a riparian zone of the Schwarzbach river, a tributary of the Rhine River in Germany, was conducted to understand stream–aquifer interaction under alternative gaining and losing streamflow conditions. An equivalent streambed permeability, estimated by inverting aquifer responses to flood waves, shows that streambed permeability increased during infiltration of stream water to aquifer and decreased during exfiltration. Aquifer permeability realizations generated by multiple‐point geostatistics exhibit a high degree of heterogeneity and anisotropy. A coupled surface water groundwater flow model was developed incorporating the time‐varying streambed permeability and heterogeneous aquifer permeability realizations. The model was able to reproduce varying pressure heads at two observation wells near the stream over a period of 55 days. A Monte Carlo analysis was also carried out to simulate groundwater flow, its age distribution, and the release of a hypothetical wastewater plume into the aquifer from the stream. Results of this uncertainty analysis suggest (a) stream–aquifer exchange flux during the infiltration periods was constrained by aquifer permeability; (b) during exfiltration, this flux was constrained by the reduced streambed permeability; (c) the effect of temporally variable streambed permeability and aquifer heterogeneity were found important to improve the accurate capture of the uncertainty; and (d) probabilistic infiltration paths in the aquifer reveal that such pathways and the associated prediction of the extent of the contaminant plume are highly dependent on aquifer heterogeneity.     

Performance Assessments of a Novel Well Design for Reducing Exposure to Bedrock‐Derived Arsenic

Arsenic in groundwater is a serious problem in New England, particularly for domestic well owners drawing water from bedrock aquifers. The overlying glacial aquifer generally has waters with low arsenic concentrations but is less used because of frequent loss of well water during dry periods and the vulnerability to surface‐sourced bacterial contamination. An alternative, novel design for shallow wells in glacial aquifers is intended to draw water primarily from unconsolidated glacial deposits, while being resistant to drought conditions and surface contamination. Its use could greatly reduce exposure to arsenic through drinking water for domestic use. Hypothetical numerical models were used to investigate the potential hydraulic performance of the new well design in reducing arsenic exposure. The aquifer system was divided into two parts, an upper section representing the glacial sediments and a lower section representing the bedrock. The location of the well, recharge conditions, and hydraulic properties were systematically varied in a series of simulations and the potential for arsenic contamination was quantified by analyzing groundwater flow paths to the well. The greatest risk of arsenic contamination occurred when the hydraulic conductivity of the bedrock aquifer was high, or where there was upward flow from the bedrock aquifer because of the position of the well in the flow system.     

A radiomagnetotelluric survey on an oil-contaminated area near the Brazi Refinery, Romania

Scalar radiomagnetotelluric measurements were carried out on a contaminated test area close to the Brazi Refinery in Romania in order to detect and to monitor a 1 m thick oil layer expected at 5 m depth. Radio transmitters broadcasting in a frequency range from 10 kHz to 300 kHz were selected to observe the apparent resistivity and the phase data associated with the E‐ and B‐polarizations. They were located parallel and perpendicular to the assumed strike direction of the contamination plume. The data were interpreted by a 2D inversion technique from which the conductivity structure of the area was derived. The 2D inversion models of all profiles on the contaminated area show a poor‐conductivity zone above the groundwater table which could be associated with the oil contamination. A first attempt was also made to monitor the contaminated layer: the radiomagnetotelluric measurements were repeated on the same profiles a year later, but this time in a dry period, not in a rainy one. The 2D inversion results of the measurements in the dry period indicate that the high‐resistivity layer moved closer to the surface. Additional reference measurements were then carried out on a non‐contaminated area situated at a distance from the refinery, in the opposite direction to the flow of the groundwater. These reference measurements were used for the derivation of the unperturbed geology and they were also compared with the measurements of the contaminated test area. There is a significant difference in the frequency dependences of the apparent resistivities of the reference and contaminated areas, which could indicate a contamination at shallow depth. The 2D inversion results show the increase of resistivity at a depth of about 5 m beneath the contaminated area where the oil contamination is expected according to the information from the boreholes.     

Thermal DNAPL Source Zone Treatment Impact on a CVOC Plume

The tetrachloroethene (PCE) source zone at a site in Endicott, New York had caused a dissolved PCE plume. This plume was commingled with a petroleum hydrocarbon plume from an upgradient source of fuel oil. The plume required a system for hydraulic containment, using extraction wells located about 360 m downgradient of the source. The source area was remediated using in situ thermal desorption (ISTD). Approximately 1406 kilograms (kg) of PCE was removed in addition to 4082 kg of commingled petroleum‐related compounds. The ISTD treatment reduced the PCE mass discharge into the plume from an estimated 57 kg/year to 0.07 kg/year, essentially removing the source term. In the 5 years following the completion of the thermal treatment in early 2010, the PCE plume has collapsed, and the concentration of degradation products in the PCE‐series plume area has declined by two to three orders of magnitude. Anaerobic dechlorination is the suspected dominant mechanism, assisted by the presence of a fuel oil smear zone and a petroleum hydrocarbon plume from a separate source area upgradient of the PCE source. Based on the post‐thermal treatment groundwater monitoring data, the hydraulic containment system was reduced in 2014 and discontinued in early 2015.     

Numerical Modeling of Methane Leakage from a Faulty Natural Gas Well into Fractured Tight Formations

Horizontal drilling and hydraulic fracturing have enabled hydrocarbon recovery from unconventional reservoirs, but led to natural gas contamination of shallow groundwaters. We describe and apply numerical models of gas‐phase migration associated with leaking natural gas wells. Three leakage scenarios are simulated: (1) high‐pressure natural gas pulse released into a fractured aquifer; (2) continuous slow leakage into a tilted fractured formation; and (3) continuous slow leakage into an unfractured aquifer with fluvial channels, to facilitate a generalized evaluation of natural gas transport from faulty natural gas wells. High‐pressure pulses of gas leakage into sparsely fractured media are needed to produce the extensive and rapid lateral spreading of free gas previously observed in field studies. Transport in fractures explains how methane can travel vastly different distances and directions laterally away from a leaking well, which leads to variable levels of methane contamination in nearby groundwater wells. Lower rates of methane leakage (≤1 Mcf/day) produce shorter length scales of gas transport than determined by the high‐pressure scenario or field studies, unless aquifers have low vertical permeabilities (≤1 millidarcy) and fractures and bedding planes have sufficient tilt (～10°) to allow a lateral buoyancy component. Similarly, in fractured rock aquifers or where permeability is controlled by channelized fluvial deposits, lateral flow is not sufficiently developed to explain fast‐developing gas contamination (0‐3 months) or large length scales (～1 km) documented in field studies. Thus, current efforts to evaluate the frequency, mechanism, and impacts of natural gas leakage from faulty natural gas wells likely underestimate contributions from small‐volume, low‐pressure leakage events.     

Groundwater,salt and contaminant transport in a coastal aquifer system with a low-permeability layer in the intertidal zone

Low-permeability layer (LPL), formed by natural deposit or artificial reclamation and commonly found below the intertidal zone of coastal groundwater system, can retard the ingress of seawater and contaminants, and shorten the travel time of the land-sourced contaminant to the marine environment compared with a homogenous sandy coastal aquifer. However, there is limited understanding on how an intertidal LPL, a condition occurred in a coastal aquifer at Moreton Bay, Australia, influences the groundwater and contaminant transport across the shallow beach aquifer system. We characterized the aquifer hydrological parameters, monitored the in situ groundwater heads, and constructed a 2-D numerical model to analyses the cross-shore hydrological processes in this stratified system. The calibrated model suggests that in the lower aquifer, the inland-source fresh groundwater flowed horizontally towards the sea, upwelled along the freshwater–saltwater interface, and exited the aquifer at the shore below the LPL. Whereas in the upper aquifer, the tidally driven seawater circulation formed a barrier that prevented fresh groundwater from horizontal transport and discharge to the beach above the LPL, thereby directing its leakage to the lower aquifer. A contaminant represented by a conservative tracer was ‘released’ the upper aquifer in the model and results showed that the spreading extent of the contaminant plume, the maximum rate of contaminant discharge to the ocean, and its plume length decreased compared with a simulation case in a homogenous sandy aquifer. Sensitivity analysis was also conducted to investigate the characteristics of the LPL, including its continuity and hydraulic conductivity, which were found to vary along the beach at Moreton Bay. The result shows that with a lower hydraulic conductivity and continuous layer of LPL reduced the groundwater exchange and contaminant transport between upper and lower aquifer. The findings from the combined field and modelling investigations on the impact of an intertidal LPL on coastal aquifer systems highlight its significant implications to alter the groundwater and mass transport across the land–ocean interface.     

Adsorbed and Bound Residues in Fulvic Acid Fractions of a Contaminated Groundwater – Isolation:, Chromatographic and Spectroscopic Characterization

Humic substances (HS) were isolated from two contaminated groundwater samples (B22 and B53) from a site of a former gas facility. The isolation yielded almost only the fulvic acid fractions (FA). For characterization spectroscopic (UV, fluorescence) and chromatographic techniques (hydrophobic interaction chromatography – HIC as well as size-exclusion chromatography – SEC) were applied. The sample designated B22 FA was collected from the contamination plume whereas the sample B53 FA was collected downstream. Distinct differences were exhibited by these samples. The UV and fluorescence spectra as well as the HIC and SEC chromatograms of the B53 FA sample resemble those of the FA fraction obtained from natural water (groundwater, bog). The HIC and SEC chromatograms reveal the presence of organic compounds in B22 FA which can be derived from coal tar contaminants or their metabolites. Some of the compounds can be extracted from the FA fraction with non-polar organic solvents indicating adsorptive forces between the contaminants and the FA fraction.     

Groundwater recharge through an alluvial fan in the Atacama Desert,northern Chile: mechanisms,magnitudes and causes

The Chacarilla fan in the Atacama Desert is one of several formed in the Late Miocene at the foot of the Pre‐Andean Cordillera overlying the large, complex, Pampa Tamarugal aquifer contained in the continental clastic sediments of the fore‐arc basin. The Pampa Tamarugal aquifer is a strategic source of water for northern Chile but there is continuing doubt over the resource magnitude and recharge. During January 2000 a 1 in 4 year storm in the Andes delivered a 34 million m³ flash flood to the fan apex where c. 70% percolated to the underlying aquifers. Groundwater recharge through the fan is calculated to be a minimum of 200 l/s or 6% of the long‐term catchment rainfall. These figures are supported by hydrochemical data that suggest that recharge may be 9% of long‐term rainfall. Isotopic data suggest groundwater less than 50 years old is transmitted westward through the permeable sheetflood sediments of the fan overlying the main aquifer. Analysis of this and other events shows that the hydrological system is non‐linear with positive feedback. The magnitude of groundwater recharge is dependent on climatic variations, antecedent soil moisture storage and changes in channel characteristics. Long‐term declines in groundwater level may partly result from climatic fluctuations and the causes of such fluctuations are discussed. Copyright © 2002 John Wiley & Sons, Ltd.