Benthic microbial abundance and activities in an intensively trawled ecosystem (Thermaikos Gulf, Aegean Sea)

Abundance of benthic bacteria, heterotrophic nanoflagellates and ciliates, extracellular enzymatic activities, bacterial C production, C mineralisation and sediment community oxygen consumption rates were measured in the Thermaikos Gulf (Northeastern Mediterranean), before (September 2001), and during intense trawling activities (October 2001 and February 2002). The biochemical composition of sedimentary organic matter has revealed that bottom trawling had an effect on the trophic state of Thermaikos Gulf. Changes on the benthic microbial food web were also recorded, during the three sampling seasons. Even though trawling-induced sediment resuspension did not alter significantly the abundance of the microbial components, with the exception of the most impacted station, it determined changes regarding their relative importance. Thus, the ratios of bacterium to nanoflagellates and ciliate to nanoflagellates abundance increased in the trawled stations, causing a sudden increase in bacterial C production, in comparison to the non-trawled station. Four months later, the effects of trawling on the microbial food web were less evident, masked possibly by the drastic decrease in the water temperature. The results of the present work suggest that bottom trawling induces alteration of the sedimentological variables and can be considered as a factor affecting the function of the microbial food web in marine coastal ecosystems. These alterations cause faster mobilisation of organic C buried in the sediment and increase nutrient concentrations and availability in the system, thus inducing an effect that could lead to coastal eutrophication.     

Carbon remineralization in the Amazon–Guianas tropical mobile mudbelt: A sedimentary incinerator

The Amazon River spawns a vast mobile mudbelt extending ∼1600 km from the equator to the Orinoco delta. Deposits along the Amazon–Guianas coastline are characterized by some of the highest C_org remineralization rates reported for estuarine, deltaic, or shelf deposits, however, paradoxically, except where stabilized by mangroves or intertidal algal mats, they are usually suboxic and nonsulfidic. A combination of tides, wind-driven waves, and coastal currents forms massive fluid muds and mobile surface sediment layers ∼0.5–2 m thick which are dynamically refluxed and frequently reoxidized. Overall, the seabed functions as a periodically mixed batch reactor, efficiently remineralizing organic matter in a gigantic sedimentary incinerator of global importance. Amazon River material entering the head of this dynamic dispersal system carries an initial terrestrial sedimentary C_org loading of ∼ 0.7 mg C m⁻² particle surface area. Total C_org loading is lowered to ∼ 0.2 mg C m⁻² in the proximal delta topset, ∼60–70% of which remains of terrestrial origin. Loading decreases further to 0.12–0.14 mg C m⁻² (∼60% terrestrial) in mudbanks ∼600 km downdrift along French Guiana, values comparable to those found in the oligotrophic deepsea. DOC/ΣCO₂ ratios in pore waters of French Guiana mudbanks indicate that >90% of metabolized organic substrates are completely oxidized. Within the Amazon delta topset at the head of the dispersal system, both terrestrial and marine organic matter contribute substantially to early diagenetic remineralization, although reactive marine substrate dominates (∼60–70%). The conditional rate constant for terrestrial C_org in the delta topset is ∼0.2 a⁻¹. As sedimentary C_org is depleted during transit, marine sources become virtually the exclusive substrate for remineralization except very near the mangrove shoreline. The δ¹³C and Δ¹⁴C values of pore water ΣCO₂ in mudbanks demonstrate that the primary source of remineralized organic matter within ∼1 km of shore is a small quantity of bomb signature marine plankton (+80‰). Thus, fresh marine organic material is constantly entrained into mobile deposits and increasingly drives early diagenetic reactions along the transit path. Relatively refractory terrestrial C_org is lost more slowly but steadily during sedimentary refluxing and suboxic diagenesis. Amazon Fan deposits formed during low sea level stand largely bypassed this suboxic sedimentary incinerator and stored material with up to ∼3X the modern high stand inner shelf C_org load (Keil et al., 1997b. Proceedings of the Ocean Drilling Program, Scientific Results. Vol. 155. pp. 531–537). Sedimentary dynamics, including frequency and magnitude of remobilization, and the nature of dispersal systems are clearly key controls on diagenetic processes, biogeochemical cycling, and global C storage along the continental margins.     

Shifting environmental baselines in the Red Sea

The Red Sea is among the world’s top marine biodiversity hotspots. We re-examined coastal ecosystems at sites surveyed during the 1980s using the same methodology. Coral cover increased significantly towards the north, mirroring the reverse pattern for mangroves and other sedimentary ecosystems. Latitudinal patterns are broadly consistent across both surveys and with results from independent studies. Coral cover showed greatest change, declining significantly from a median score of 4 (1000–9999 m²) to 2 (10–99 m²) per quadrat in 2010/11. This may partly reflect impact from coastal construction, which was evident at 40% of sites and has significantly increased in magnitude over 30 years. Beach oil has significantly declined, but shore debris has increased significantly. Although substantial, levels are lower than at some remote ocean atolls. While earlier reports have suggested that the Red Sea is generally healthy, shifting environmental baselines are evident from the current study.     

Impact of natural (storm) and anthropogenic (trawling) sediment resuspension on particulate organic matter in coastal environments

In order to assess the impact of natural and anthropogenic sediment resuspension on quantity, biochemical composition and bioavailability of particulate organic matter (POM), two field investigations were carried out in two shallow coastal areas of the Mediterranean Sea. In the Gulf of Lions, we investigated the impact of a storm resuspension of sediment, whereas in the Thermaikos Gulf we investigated the impact of bottom trawling.Resuspension in the Gulf of Lions determined the increase of sedimentation rates, modified the composition of the organic fraction of settling particles and decreased the labile fraction of POM, as indicated by a drop in the enzymatically hydrolysable amino acid fraction. The increase in the refractory fraction, following short-term storm-induced resuspension, increased also the contribution of glycine and decreased the contribution of aspartic acid contents to the total amino acid pools.Trawling activities in Thermaikos Gulf determined a significant increase in suspended POM concentrations and important changes in its biochemical composition. After trawling, the protein to carbohydrate ratio decreased (as a result of a major input of sedimentary carbohydrates at the water–sediment interface) and the fraction of enzymatically hydrolysable biopolymeric C decreased by ≈30%, thus reducing the bioavailability of resuspended organic particles. Results of the present study indicate that changes in suspended POM, induced by storms and trawling activities, can have similar consequences on benthic systems and on food webs. In fact, the potential benefit of increased organic particle concentration for suspension feeders, is depressed by the shift of suspended food particles towards a more refractory composition.     

Nature of decadal-scale sediment accumulation on the western shelf of the Mississippi River delta

Sediment delivered to coastal systems by rivers (15×10⁹ tons) plays a key role in the global carbon and nutrient cycles, as deltas and continental shelves are considered to be the main repositories of organic matter in marine sediments. The Mississippi River, delivering more than 60% of the total dissolved and suspended materials from the conterminous US, dominates coastal and margin processes in the northern Gulf of Mexico. Draining approximately 41% of the conterminous US, the Mississippi and Atchafalaya river system deliver approximately 2×10⁸ tons of suspended matter to the northern Gulf shelf each year. Unlike previous work, this study provides a comprehensive evaluation of sediment accumulation covering majority of the shelf (<150 m water depth) west of the Mississippi Delta from 92 cores collected throughout the last 15 years. This provides a unique and invaluable data set of the spatial and modern temporal variations of the sediment accumulation in this dynamic coastal environment.Three types of ²¹⁰Pb profiles were observed from short cores (15–45 cm) collected on the shelf. Proximal to Southwest Pass in 30–100 m water depths, non-steady-state profiles were observed indicating rapid accumulation. Sediment accumulation rates in this area are typically >2.5 cm yr⁻¹ (>1.8 g cm⁻² yr⁻¹). Kasten cores (∼200 cm in length) collected near Southwest Pass also indicate rapid deposition (>4 cm yr⁻¹; >3 g cm⁻² yr⁻¹) on a longer timescale than that captured in the box cores. Near shore (<20 m), profiles are dominated by sediments reworked by waves and currents with no accumulation (the exception is an area just south of Barataria Bay where accumulation occurs). The remainder of the shelf (distal of Southwest Pass) is dominated by steady-state accumulation beneath a ∼10-cm thick mixed layer. Sediment accumulation rates for the distal shelf are typically <0.7 cm yr⁻¹ (<0.5 g cm⁻² yr⁻¹). A preliminary sediment budget based on the distribution of ²¹⁰Pb accumulation rates indicates that 40–50% of the sediment delivered by the river is transported out of the study region. Sediment is moved to distal regions of the shelf/slope through two different mechanisms. Along-isobath sediment movement occurs by normal resuspension processes west of the delta, whereas delivery of sediments south and southwest of the delta may be also be influenced by mass movement events on varying timescales.     

Optical dating of clastic deposits generated by an extreme marine coastal flood: The 1755 tsunami deposits in the Algarve (Portugal)

Identification of past tsunamis is important for risk assessment and management of coastal areas. Obtaining accurate and precise ages of sediments originating from such extreme marine coastal floods is crucial for a reliable estimation of the recurrence interval of these often devastating events. We present here the results of quartz optical dating and ¹⁴C dating of two sites (Boca do Rio and Martinhal) on the Algarve coast (southern Portugal). These sites contain deposits of the great tsunami of November 1, 1755. The sections were described using sedimentological techniques; at both sites tsunami-laid sands and gravels were identified, intercalated between estuarine muds. Quartz luminescence ages from these sedimentary successions were derived using standard SAR-OSL dating using multi-grain sub-samples. A multiple sampling strategy was employed with several samples taken from the AD 1755 tsunami deposit and from the sediments bracketing the tsunami layer. Our SAR-OSL protocol was shown to be appropriate using dose recovery measurements (measured/given dose ratio of 1.004 ± 0.007, n = 165). The several OSL ages from the 1755 tsunamigenic deposits are internally reproducible but yield age overestimates of between 20 and 125% (60–310 years respectively); this is in agreement with values reported in the literature for similar deposits. The age overestimation of the tsunami-laid sands is presumably due to the rapid erosion and deposition of older sediments, with insufficient light exposure for complete bleaching during the tsunami event itself. The absence of significant bleaching during the tsunami is also suggested by the shape of the dose distributions based on sub-samples made up of only about 100 grains. Analysis of the distributions with the minimum-age model seems to yield the expected age for two of the three distributions. It is important to note that age offsets of a few tens of years to a few hundred years rapidly become insignificant when dating older (>1 to few ka) tsunami layers.     

Fine-sediment transport associated with cold-front passages on the shallow shelf,Gulf of Mexico

The eastern part of the chenier plain of the Louisiana coast has been prograding seaward over the last few decades while much of the rest of the Louisiana coast is experiencing high erosion rates. The source of sediment is the Atchafalaya River, which has been delivering sediment to the coastal ocean since the 1940s. Researchers have suggested that the repeated passage of cold fronts during winter and early spring plays an important role in delivering sediment to the coast. A sediment-transport study on the Atchafalaya coast was conducted between October 1997 and March 2001, which included several field experiments in early March, the period of high discharge from the Atchafalaya and frequent cold-front activity. A combination of shipboard profiling and time-series measurements from a bottom tripod and array of wave sensors on the inner shelf has resulted in a data set that illustrates the mechanism of onshore transport. For a cold-front passage sampled in 2001, during pre-front conditions, sediment is resuspended and mixed throughout the water column, with transport rates onshore and to the west of 53 and 184 g s⁻¹ m⁻¹, respectively. Post-front conditions also result in onshore transport due to onshore flow (upwelling) in the lower meter of the water column and formation of a high-concentration bottom layer. Post-front onshore transport rates are 32 g s⁻¹ m⁻¹ and most of the transport occurs in the bottom meter of the water column. The repeated cycling of cold-front passages leads to a positive feedback with transport onshore during both pre- and post-front conditions, and effective attenuation of wave energy over the muddy inner shelf inhibits erosion at the coast. Thus, the chenier-plain coast is experiencing high progradation rates (up to 29 m yr⁻¹), while most of the Gulf coast is eroding.     

Late Miocene to present-day exhumation and uplift of the Internal Zone of the Rif chain: Insights from low temperature thermochronometry and basin analysis

Located on the margin of the west Alboran basin, the Gibraltar Arc (Betic-Rif mountain belt) displays post-Pliocene vertical movements evidenced by uplifted marine sedimentary basins and marine terraces. Quantification of vertical movements is an important clue to understand the origin of present-day relief generation in the Betic-Rif mountain chain together with the causes of the Messinian Salinity Crisis. In this paper, we present the results of a pluridisciplinary study combining an analysis of low temperature thermochronology and Pliocene basins evolution to constrain the exhumation history and surface uplift of internals units of the Rif belt (Northern Morocco). The mean (U-Th)/He apatite ages obtained from 11 samples are comprised between 14.1 and 17.8 Ma and display a wide dispersion, which could be explained by a great variability of apatite chemistries in the analyzed samples. No correlations between altitude and age have been found along altitudinal profile suggesting a rapid exhumation during this period. Thermal modeling using our (U-Th)/He apatite ages and geochronological data previously obtained in the same area (⁴⁰Ar/³⁹Ar and K/Ar data on biotite, zircon and apatite fission track) allow us to propose a cooling history. The rocks suffered a rapid cooling at 60–100 °C/Ma between 22.5 and 19 Ma, then cooled to temperatures around 40 °C between 19 and 18 Ma. They were re-heated at around 110 °C between 18 and 15 Ma then rapidly cooled and exhumed to reach the surface temperature at around 13 Ma. The re-heating could be related to a renewal in thrusting and burying of the inner zones. Between 15 and 13 Ma the cooling resumed at a rate of 50 °C/Ma indicating an exhumation rate of 0.8 mm/y considering an average 40 °C/km geothermal gradient. This exhumation may be linked to the extension in the Alboran Sea. Otherwise biostratigraphic and sedimentological analysis of Pliocene basins of the internal Rif provided informations on the more recent events and vertical movements. Pliocene deposits of the Rifian coast represent the passive infilling of palaeo-rias between 5.33 and 3.8 Ma. The whole coastal area was uplifted at slow average rates (0.01–0.03 mm/y) in relation with a northeastward tilting of 0.2–0.3° since the Lower-Pliocene. A late Pliocene to present extensional tectonics associated to uplift has been identified all along the coastal ranges of the Internal Zone of the Rif chain. This extension was coeval with the major late Pliocene to Pleistocene extensional episode of the Alboran Sea and appears to be still active nowadays. No significant late Messinian uplift was evidenced, thus calling into question the geodynamic models relating the closure of the marine gateways and the MSC to slab roll back.     

Temporal and spatial complexity in post-glacial sedimentation on the tectonically active,Poverty Bay continental margin of New Zealand

On the eastern Raukumara Ranges of the New Zealand East Coast, active tectonics, vigorous weather systems, and human colonisation have combined to cause widespread erosion of the mudstone- and sandstone-dominated hinterland. The Waipaoa River sedimentary dispersal system is an example that has responded to environmental change, and is now New Zealand's second largest river in terms of suspended sediment discharge. This paper presents new sediment accumulation rates for the continental shelf and slope that span century to post-glacial time scales. These data are derived from radiochemical tracer, palynological, tephrostratigraphic, and seismic methods. We hypothesise on the temporal and spatial complexity of post-glacial sedimentation across the margin and identify the broad extent of sediment dispersal from the Waipaoa system. The ∼15 km³ Poverty Bay mid-shelf basin lies adjacent to the mouth of the Waipaoa River, reaching a maximum thickness of ∼45 m. A post-glacial mud lobe of an additional ∼3 km³ extends through the Poverty Gap and out onto the uppermost slope, attaining 40 m thickness in a structurally controlled sub-basin. Here, an offset in the last-glacial erosion surface indicates that deposition was sympathetic with fault activity and the creation of accommodation space, implying that sedimentation was not supply limited. Contrary to classical shelf sedimentation models, the highest modern accumulation rate of 1 cm y⁻¹ occurs on the outer-shelf sediment lobe, approximately ∼2 times the rate recorded at the mid-shelf basin depocentre, and ∼10 times faster than the excess ²¹⁰Pb rates estimated from the slope. Pollen records from slope cores fingerprint Polynesian then European settlement, and broaden the spatial extent of post-settlement sedimentation initially documented from the Poverty Bay mid-shelf. Changes in sub-millennial sedimentation infer a 2–3-times increase in post-settlement accumulation on the shelf but a smaller 1–2 times increase on the slope. Over longer time scales, seismic evidence infers slower but steady sedimentation since the last transgression, and that significant cross-shelf sediment pathways pre-date the increase in sedimentation resulting from colonisation and deforestation. From a summation of coastal bedload, shelf and slope sediment mass accumulation, the total sediment budget for the Holocene is ∼1 Mt y⁻¹. Under modern conditions a larger proportion of the Waipaoa sediment dispersal system likely extends onto the slope and beyond.     

Stepwise atmospheric carbon-isotope excursion during the Toarcian Oceanic Anoxic Event (Early Jurassic,Polish Basin)

During the Mesozoic (250–64 Ma) intervals of about 0.5 Myr were subject to severe environmental changes, including high sea-surface temperature and very low oxygen content of marine water. These Oceanic Anoxic Events, or OAEs, occurred simultaneously with profound disturbance to the carbon cycle. The carbon-isotope anomaly in the Early Jurassic that marks the Toarcian Oceanic Anoxic Event (T-OAE) at ~ 182 Ma is characterized in marine sections by a series of dramatic steps towards lighter values. Herein we present new carbon-isotope data from terrestrial organic matter (phytoclast separates), collected through a Late Pliensbachian–Middle Toarcian coastal and marginal marine succession in the Polish Basin, a setting where hinterland climate and sea-level change are well recorded. The results show that the shift to light carbon-isotope values in the woody organic matter, and therefore also in atmospheric carbon dioxide, similarly occurred in major steps. The steps are here correlated with those identified from marine organic matter, where they have previously been attributed to 100 kyr eccentricity forcing of climate. The results provide strong support for orbitally and climatically controlled release of isotopically light carbon from gas hydrates into the ocean–atmosphere system in a series of rapid bursts. Additionally, a link between the carbon-isotope steps and shoreline movements can be demonstrated. Individual peaks of the negative excursion are mostly associated with facies indicative of sea-level rise (flooding surfaces). However, at the same time inferred higher atmospheric carbon-dioxide content may be expected to have resulted in increased rainfall and temperature, leading to accelerated weathering and erosion, and consequently increased sediment supply, progradation and regression, causing some mismatches between isotope shifts and inferred sea-level changes. Enhanced abundance of megaspores derived from hydrophilic plant groups, and marked increase in kaolinite, are coincident with the overall development of the negative isotope excursion. The combined data suggest that each 100-kyr cycle in carbon-isotope values was characterized by increasingly severe palaeoclimatic change, culminating in extremely hot and humid conditions co-incident with the peak of the final most negative carbon-isotope excursion. The chemostratigraphic correlation allows very precise dating of the Late Pliensbachian–Middle Toarcian coastal and marginal marine sedimentary succession in the Polish Basin.     

Quantities,composition, and sources of beach debris in Korea from the results of nationwide monitoring

This study assessed the levels of marine debris pollution and identified its main sources in Korea. The surveys were bimonthly conducted by NGO leaders and volunteers on 20 beaches from March 2008 to November 2009. The quantities of marine debris were estimated at 480.9 (±267.7) count ⋅ 100 m⁻¹ for number, 86.5 (±78.6) kg ⋅ 100 m⁻¹ for weight, and 0.48 (±0.38) m³ ⋅ 100 m⁻¹ for volume. The level of marine debris pollution on the Korean beaches was comparable to that in the coastal areas of the North Atlantic ocean and South Africa. Plastics and styrofoam occupied the majority of debris composition in terms of number (66.7%) and volume (62.3%). The main sources of debris were fishing activities including commercial fisheries and marine aquaculture (51.3%). Especially styrofoam buoy from aquaculture was the biggest contributor to marine debris pollution on these beaches.     

40Ar/39Ar temporal framework for the Alleret maar lacustrine sequence (French Massif-Central): Volcanological and paleoclimatic implications

The Alleret maar (Massif Central, France) is part of the few Western European early middle Pleistocene lacustrine sequences. In the AL3 core several new ash layers were recovered in the 10 first meters of the sedimentary filling. We obtained three ⁴⁰Ar/³⁹Ar ages, which range from 683 ± 5 ka (MSWD: 1.2, n = 17) to 722 ± 6 ka (MSWD: 3.2, n = 18). All the studied ash layers belong to the Super-Besse eruptive cycle of the Sancy volcano. Based on the chronostratigraphy that we have derived we estimate that the age of the main eruption could correspond to the Sancy volcano caldera formation at 725 ka close to the end of MIS 18 and that the Super-Besse explosive episode duration lasted only about 40 ka. The time framework we build evidences that the Alleret lacustrine sequence represents a time interval of probably 180 ka spanning from MIS 18 to MIS 14. This sequence offers the first well constrained comparison between terrestrial environmental history and that preserved in marine sediments during the Mid-Pleistocene Revolution.     

Dominance patterns in macroalgal and phytoplankton biomass under different nutrient loads in subtropical coastal lagoons of the SE Gulf of California

Nine macroalgal blooms were studied in five coastal lagoons of the SE Gulf of California. The nutrient loads from point and diffuse sources were estimated in the proximity of the macroalgal blooms. Chlorophyll a and macroalgal biomass were measured during the dry, rainy and cold seasons. Shrimp farms were the main point source of nitrogen and phosphorus loads for the lagoons. High biomasses were found during the dry season for phytoplankton at site 6 (791.7 ± 34.6 mg m⁻²) and during the rainy season for macroalgae at site 4 (296.0 ± 82.4 g m⁻²). Depending on the season, the phytoplankton biomass ranged between 40.0 and 791.7 mg m⁻² and the macroalgal biomass between 1 and 296.0 g m⁻². The bulk biomass (phytoplankton + macroalgal) displayed the same tendency as the nutrient loads entering the coastal lagoons. Phytoplankton and macroalgal biomass presented a significant correlation with the atomic N:P ratio.     

An evaluation of the toxicity and bioaccumulation of thallium in the coastal marine environment using the macroalga,Ulva lactuca

Thallium(I) has been added to cultures of the marine macroalga, Ulva lactuca, for a period of 48 h and the accumulation of the metal and its effects on the photochemical efficiency of photosystem II (PS II) measured. Thallium elicited a measurable toxic response above concentrations of 10 μg L⁻¹ in both coastal seawater (salinity 33) and estuarine water (salinity 20). The accumulation of Tl was defined by a linear relationship with aqueous Tl and accumulation factors of about 900 mL g⁻¹ in both media. Thallium accumulated by U. lactuca that was resistant to an EDTA extraction and, by operational definition, internalised, exceeded 90% in both cases. Accumulation and toxicity of Tl in the presence of a ∼10⁵-fold excess of its biogeochemical analogue, potassium, suggests that Tl has a high intrinsic phytotoxicity and that its mode of action involves permeation of the cell membrane as Tl⁺ through NaCl–KCl co-transporter sites rather than (or in addition to) transport through K⁺ ion channels.     

Dinoflagellate cysts in recent marine sediments from Thermaikos Gulf, Greece: Effects of resuspension events on vertical cyst distribution

A qualitative and semi-quantitative study of recent dinoflagellate cysts has been undertaken in the NW part of Aegean Sea, Thermaikos Gulf (Eastern Mediteranean), before (September 2001), during (October 2001) and after 120 days (February 2002) of intensive trawling activities. This is the first survey of recent dinoflagellate cysts from Greek marine coastal environments. Sediment samples were collected with a corer and the vertical distribution of the cysts was studied at five different layers, from 0 to 10 cm. Dinoflagellate cysts were both abundant and diverse. Cysts were found over the whole sampling area and periods, with concentrations ranging between 247–3202 cysts cm⁻³. Thirty-six cyst types were encountered, of which 32 were identified to species level, representing 12 genera. It seems that significant local resuspension, related to the onset of the trawling period and stirring up of the sediment, contributed to mixing of the upper layers, resulting to more homogenous cyst profiles in the sediment. Viable cysts constituted 16–60% of the total cyst abundance. The abundance peaks of viable cysts within the subsurface sediment layers, observed during the undisturbed period, disappeared during October. In February, the reduction of cyst concentration was associated to a loss of viable cysts, whilst the ratio of viable/empty cysts ranged between 0.30 and 0.67. The abundance of the different dinoflagellate species, in their active form, was monitored in order to detect any relationship between the concentration of cysts in the top 10 cm of sediment and blooms of algae in the water column. Cysts of potentially toxic species, causing Paralitic Shellfish Poisoning (PSP), such as Alexandrium cf. tamarense, A. cf. affine, A. cf. minutum, as well as Gymnodinium catenatum, were detected in the cyst survey.     

Steroid markers to assess sewage and other sources of organic contaminants in surface sediments of Cienfuegos Bay,Cuba

Analyses of faecal steroids in coastal sediments from Cienfuegos Bay Cuba indicate chronic sewage contamination at the main outfalls from the city, where concentrations of coprostanol up to 5400 ng g⁻¹ (dry wt) were measured. In contrast, steroid concentrations and compositions from sites from the south part of the Bay are characteristic of uncontaminated sewage environments. The levels of coprostanol in the Cienfuegos sediments compares to the lower to mid-range of concentrations reported for coastal sediments on a world-wide basis, with sedimentary levels markedly below those previously reported for heavily impacted sites. This study delivers baseline data for further investigation of the effectiveness of the proposed sewerage plan promoted by the GEF project in Cienfuegos. Investigations on the correlations between faecal steroids and other organic contaminants confirmed that the major source of petroleum hydrocarbons within the bay was associated with the sewage effluents from the Cienfuegos city.     

Crustal velocity structure in the southern edge of the Central Alborz (Iran)

Inversion of local earthquake travel times and joint inversion of receiver functions and Rayleigh wave group velocity measurements were used to derive a simple model for the velocity crustal structure beneath the southern edge of the Central Alborz (Iran), including the seismically active area around the megacity of Tehran. The P and S travel times from 115 well-located earthquakes recorded by a dense local seismic network, operated from June to November 2006, were inverted to determine a 1D velocity model of the upper crust. The limited range of earthquake depths (between 2 km and 26 km) prevents us determining any velocity interfaces deeper than 25 km. The velocity of the lower crust and the depth of the Moho were found by joint inversion of receiver functions and Rayleigh wave group velocity data. The resulting P-wave velocity model comprises an upper crust with 3 km and 4 km thick sedimentary layers with P wave velocities (V_p) of ～5.4 and ～5.8 km s^?1, respectively, above 9 km and 8 km thick layers of upper crystalline crust (V_p ～6.1 and ～6.25 km s^?1 respectively). The lower crystalline crust is ～34 km thick (V_p ～ 6.40 km s^?1). The total crustal thickness beneath this part of the Central Alborz is 58 ± 2 km.     

Glaciation,erosion, and landscape evolution of Iceland

Stratigraphic and sedimentological studies indicate that Iceland has experienced over 20 glaciations during the last 4–5 Myr, in reasonable agreement with the number of glaciations reconstructed from the ∂¹⁸O record in deep-sea sediment. The pattern of glacial erosion was to a large part controlled by constructive volcanic processes resulting in increased topographic relief after 2.5 Myr. Between 2.5 and 0.5 Ma valleys up to 400 m deep were excavated into the Tertiary basalts of eastern and south Iceland with an average erosion rate of 10–20 cm ka⁻¹. During the last 0.5 million years rates of erosion increased to 50–175 cm ka⁻¹, with an additional 200 to over 1000 m of valley excavation. Previous estimates of the rate of landscape erosion during the Holocene vary widely, from 5 to 70,000 cm ka⁻¹. We present new studies that define the rates of landscape denudation during the major part of the Holocene (the last 10,200 years): one based on the Iceland shelf sediment record, the other from the sediment record in the glacier-fed lake, Hvítárvatn. Both studies indicate average Holocene erosion rates of about 5 cm ka⁻¹ similar to our erosion rate estimate for 4–5 Ma old strata that has not been subjected to regional glaciation.     

Toxicities of antifouling biocide Irgarol 1051 and its major degraded product to marine primary producers

Irgarol 1051 (2-methythiol-4-tert-butylamino-6-cyclopropylamino-s-triazine) is an algaecide commonly used in antifouling paints. It undergoes photodegradation which yields M1 (2-methylthio-4-tert-butylamino-6-amino-s-triazine) as its major and most stable degradant. Elevated levels of both Irgarol and M1 have been detected in coastal waters worldwide; however, ecotoxicity effects of M1 to various marine autotrophs such as cyanobacteria are still largely unknown. This study firstly examined and compared the 96 h toxicities of Irgarol and M1 to the cyanobacterium Chroococcus minor and two marine diatom species, Skeletonema costatum and Thalassiosira pseudonana. Our results suggested that Irgarol was consistently more toxic to all of the three species than M1 (96 h EC50 values: C. minor, 7.71 μg L⁻¹ Irgarol vs. >200 μg L⁻¹ M1; S. costatum, 0.29 μg L⁻¹ Irgarol vs. 11.32 μg L⁻¹ M1; and T. pseudonana, 0.41 μg L⁻¹ Irgarol vs. 16.50 μg L⁻¹ M1). Secondly, we conducted a meta-analysis of currently available data on toxicities of Irgarol and M1 to both freshwater and marine primary producers based on species sensitivity distributions (SSDs). Interestingly, freshwater autotrophs are more sensitive to Irgarol than their marine counterparts. For marine autotrophs, microalgae are generally more sensitive to Irgarol than macroalgae and cyanobacteria. With very limited available data on M1 (i.e. five species), M1 might be less toxic than Irgarol; nonetheless this finding warrants further confirmation with additional data on other autotrophic species.     

Environmental behavior of organotin compounds in the coastal environment of Xiamen,China

In 2006, organotins pollution were investigated in the coastal environment of Xiamen, China. Six species of organotin compounds including tributyltin, triphenyltin and their degradation compounds were quantified in the dissolved and particulate phases of the water, and in the sediment using GC-FPD. The concentrations of organotin compounds ranged from 2.2 to 160 ng (Sn) L⁻¹ dissolved in the water, 0.14–6.7 ng (Sn) L⁻¹ in suspended particulate matter and nd ∼ 26 ng (Sn) g⁻¹ (dry weight) in the sediment. The highest concentration of total organotin or tributyltin in water was found in a shipyard and at a station near the inlet of the harbor, indicating fresh inputs of antifouling paints to Xiamen’s coastal environment. Organotin speciation was performed on sediment cores to investigate contamination trends over the past ten years in the harbor. The results of ²¹⁰Pb dating indicated that Xiamen western harbor suffered contamination during 2000. The environmental behavior of organotins such as the enhancement of the microlayer, partitioning between water/suspended particulate matter and between water/sediment are also discussed in this paper.