基于石笋记录的晚全新世太平洋东西两岸季风区气候事件对比研究

研究晚全新世季风气候演变有助于进一步认识与预测未来季风区气候变化。太平洋东西两岸是全球季风集中分布的地区,已经有大量的古气候记录发表,但是缺乏对各个季风区气候突变事件以及整体变化趋势的对比研究。针对这一问题,选取亚洲季风区、印澳季风区、北美季风区、南美季风区11个洞穴石笋δ18O和1个湖泊Ti含量,对比研究各个记录在3.5~0.5 ka B.P.期间指示的夏季风变化特征。通过对比发现四大季风区的石笋δ18O在晚全新世整体上呈现偏正趋势,指示夏季风减弱;2次重要的气候突变事件1.5 ka B.P.和2.7 ka B.P.弱夏季风事件在各个季风区内均有表现;同时也记录了一系列十年际-百年际尺度的弱夏季风事件,表明太平洋东西两岸和南北半球的夏季风都有减弱的趋势,这与先前研究认为的南北半球呈现"see-saw"模式表现出不一样的特征。晚全新世以来ENSO（El Niño-Southern Oscillation）活动的增强对太平洋东西两岸南北半球夏季风减弱具有重要影响。在El Niño事件发生时,Walker环流减弱,而且它的上升支向东移动远离西太平洋暖池,西太平洋副热带高压增强并向西移动,导致亚洲夏季风减弱。Walker环流的东移也会使得印度尼西亚-太平洋暖池（Indo-Pacific Warm Pool,简称IPWP）海温下降,热带季节内震荡减弱致使印澳夏季风减弱;此外,El Niño事件发生时,赤道东太平洋海水温度上升导致东西太平洋海水温度梯度减弱,在此状态下南美季风区低空急流（Low Level Jet,简称LLJ）减弱,导致南美夏季风减弱;同时,北美洲加勒比海低空急流增强,使得该季风区下沉气流增强,导致北美夏季风减弱。我们的研究表明,在晚全新世ENSO活动增强的状态下,太平洋东西两岸南北半球夏季风变化可能都呈现减弱趋势。     

贵州荔波1.5万年以来石笋高分辨率古气候环境记录

通过对董哥洞石笋进行高精度的 TIMS- U系测年和 C、O同位素分析,建立了贵州省荔波地区 15 470 a以来高分辨率的古气候变化时间序列.研究结果表明,荔波地区 15 470 a以来石笋记录的冷暖事件所反映出的古季风变化,大致可分为 4个气候变化阶段 : (1) 15 470～ 11 350 a期间的晚更新世晚期-- Heinrich (H1)事件和新仙女木 (YD)事件期间,反映本阶段东亚冬季风强盛, 气温降低, 有效大气降水相对减少, 表现为干旱寒冷的气候环境; (2) 11 350～ 9 190 a期间的早全新世--干热期,反映东亚夏季风相对增强,气温升高,有效降水相对较少,表现为干热的气候环境; (3) 9 190～ 3 320 a期间的中全新世--稳定的气候适宜期,反映东亚夏季风相对强盛,气温升高,有效降水相对较大,表现为温暖湿润的气候环境; (4) 3 320～ 130 a期间的晚全新世降温期,反映本阶段东亚夏季风明显减弱,东亚冬季风相对增强,有效降水相对增大,而气候变化的波动频率却在增加 ,越至现代冷温变化时间渐趋缩短.石笋的 C、O同位素记录所揭示的末次冰期最后的 2次冷事件,其冷谷年龄分别为: (15 440± 130) a(H1事件 )和 (11 910± 70) a(YD事件),同时,还确定了终止点Ⅰ的界线年龄为 (11 350± 70) a,并证实了末次冰期在中国南方东亚季风气候区也存在有与北大西洋 H1事件和 YD事件相对应的冷事件.荔波地区的古季风环流变化,反映了东亚夏季风由弱-变强-再逐渐变弱的趋势,有效大气降水由少-增多-变少-再增多,气温由低-变高-再次变低的变化趋势,显示了与北极地区存在着古气候的遥相关关系.     

山东半岛全新世近岸泥质区沉积过程与沉积记录*

中国东部陆架边缘海发育多个全新世泥质区,是研究古海洋和古气候的理想区域。本研究从现代沉积过程和全新世沉积记录的视角,对山东半岛近岸泥质区的前人研究结果进行总结梳理,为后续相关研究提供参考。山东半岛近岸泥质区位于山东半岛沿岸,主要是来自黄河的沉积物在沿岸流、上升流、潮汐等相互作用下沉积而成,呈现独特的“Ω”形沉积模式。山东半岛近岸泥质区形成于全新世,物质来源主要是黄河,近岸侵蚀和当地小河流也贡献一定的物质来源。山东半岛近岸泥质区的形成和演化与古海洋条件、海平面升降、内陆古气候演变等多种因素有关,蕴藏着丰富的环境演化信息。山东半岛近岸泥质区沉积能够快速记录东亚季风的演变,其较高的沉积速率为研究黄河流域的古气候和古生态演化提供高分辨率的材料,可为预测未来全球变化背景下黄河流域的发展趋势提供参考。虽然前人对现代沉积过程进行了大量工作,但仍需加强现代观测和数值模拟等方面的工作,为更好地重建研究区的沉积动力过程提供数据和理论支撑。此外,该区在长时间尺度上的沉积物和有机质的沉积过程对古海洋和古气候的响应机制也亟待开展研究。     

Tracking Paleozoic evolution of the South Korean Peninsula from detrital zircon records: Implications for the tectonic history of East Asia

The southern part of the Korean Peninsula preserves important records of the Paleozoic evolutionary history of East Asia. Here we present SHRIMP U–Pb ages of detrital zircon grains from Paleozoic metasedimentary successions (Okcheon and Joseon Supergroups, Yeoncheon Group, Taean Formation, and Pyeongan Supergroup) that are incorporated into the major Phanerozoic mountain belts (Okcheon and Hongseong-Imjingang Belts) in South Korea, providing new insights for provenances and paleotectonic evolution of the South Korean Peninsula during Paleozoic time. The zircon ages from our samples display two distinct spectra patterns in their presence/absence of Neoproterozoic and/or Paleozoic populations. Our results, together with the available data from the Korean Peninsula, suggest that: (1) the Early to Middle Paleozoic successions in the Okcheon Belt were deposited in continental margin setting(s) formed by Neoproterozoic intracratonic rifting, (2) the Middle Paleozoic metasedimentary rocks in the Imjingang belt can be interpreted as molasse and flysch sediments along an active continental margin, (3) the Late Paleozoic to Early Triassic Taean Formation along the western Gyeonggi Massif represents a syn- to post-collision deltaic complex of a remnant oceanic basin, and (4) the Late Paleozoic to possibly Early Triassic Pyeongan Supergroup in the Okcheon Belt might represent a wedge-top and/or foreland basin. The spatial and temporal discrepancy between the South Korean Peninsula and the Central China Orogenic Belt during Paleozoic might reflect lateral variations in crustal evolution history along the East Asian continental margin during the Paleo-Tethyan Ocean closure.     

Stable carbon and oxygen isotopic evidence for late Pleistocene to middle Holocene climatic fluctuations in the interior of southern Africa

Stable carbon and oxygen isotope analyses of ungulate grazers from four archaeological sites located in different environs within the Caledon River Valley have provided a relatively well‐dated proxy palaeoenvironmental and palaeoclimatic sequence for the period between 16 000 and 6000 calendar (cal.) yr BP. Within the overall trend towards hot mid‐Holocene temperatures and a summer rainfall pattern, stable carbon isotope results show that there were three periods when growth season temperatures were cool enough for C₃ grasses to be present: 16 000–14 000; 10 200–9600, and 8400–8000 cal. yr BP. Similar trends were recorded in stable oxygen isotope values, reflecting shifts in either temperature or available moisture. Although having a similar pattern to that of the lower altitude site, sites situated in foothills and montane portions of the valley consistently maintained lower temperatures until the mid‐Holocene altithermal. At this time growth season temperatures warmed sufficiently for a 100% C₄ grassland to expand in altitude from the warmer low lying localities. In relation to present understanding of synoptic and global climatic patterning, these findings suggest that the early to middle Holocene transition was not a gradual warming trend, but rather it was marked by a series of climatic fluctuations. Of particular note is the possible global, rather than regional, occurrence of the 8200 cal. yr BP ‘event’. Copyright © 2002 John Wiley & Sons, Ltd.     

Strontium isotopic equilibration during metamorphism of tillites from the Ogcheon Belt,South Korea

The NE/SW trending Ogcheon Belt formed during the Mesozoic by deformation and metamorphism of a sedimentary sequence which includes tillite formations of late Precambrian or Lower Palaeozoic age. In this study Rb-Sr isotopic data are reported from cm-scale sampling of clasts and matrix in these tillites, which underwent metamorphism at grades ranging from the biotite zone to the kyanite zone. Sr-isotopic disequilibrium between clasts and matrix persists up to the highest grade but in four out of five rocks the matrix samples approximate to isochrons (MSWD's<12). The mechanism for this selective isotopic equilibration is considered to be related to the metamorphic reactions in the matrix, which were probably accompanied by a substantial fluid flow. The matrix isochrons for three of the rocks, together with separated white micas from associated schists, suggest that metamorphism took place in the Trias, approximately 200 Myr ago. Metamorphism was followed by slow cooling and biotite closure temperatures were not reached until 190-150 Myr. — These results suggest that where high fluid/rock ratios can be demonstrated on independent petrological grounds, the analysis of small-scale whole-rock samples may allow effective Rb/Sr dating of metamorphism.     

Peatland GDGT records of Holocene climatic and biogeochemical responses to the Asian Monsoon

Branched and isoprenoidal glycerol dialkyl glycerol tetraether (GDGT) membrane lipids have been widely used to reconstruct past climate and environmental change. They are not, however, widely applied to peat deposits and the controls on their distributions in peats remain unclear. Here, we present a high resolution record of branched and isoprenoid GDGT concentrations and distributions from a peat core from the Tibetan Plateau that spans the last 13 kyr, a period characterised by distinct dry and wet periods in the region. The lowest concentrations of total branched glycerol dialkyl glycerol tetraethers (brGDGTs) occurred during a presumably dry interval in the mid-Holocene, suggesting that brGDGTs-producing bacteria are less productive under such conditions, perhaps reflecting their putative anaerobic ecology. The mean annual air temperature (MAT) estimates derived from the methylation index of brGDGTs and cyclisation ratio of brGDGTs (MBT′/CBT) are higher than present mean annual temperature in the region and closer to summer temperatures, perhaps due to seasonal production of brGDGTs. The downcore distributions of isoprenoidal and branched GDGTs are dominated by GDGT-0 and brGDGT II, respectively. The high fractional abundances of GDGT-0 in warm and especially wet intervals suggest that these conditions are favourable for some groups of methanogenic archaea. The mid-Holocene dry interval is associated with an increase in the fractional and absolute abundance of crenarchaeol, which could be indicative of enhanced ammonia-oxidising archaeal-mediated nitrogen cycling under these conditions. Taken together, variations of GDGT concentrations in peats appear to document the response of microbial processes to climate change and variations in the biogeochemical environment.     

High-resolution isotope records of early Holocene rapid climate change from two coeval stalagmites of Katerloch Cave,Austria

Two coeval stalagmites from Katerloch Cave show pronounced intervals of low δ¹⁸O values around 8.2, 9.1, and 10.0 kyr (all ages are reported before the year 2000 AD) and represent an inorganic U–Th dated climate archive from the southeast of the European Alps, a region where only very few well-dated climate records exist. The O isotope curves, providing near-annual resolution, allow a direct comparison to the Greenland ice core records, as temperature was the primary factor controlling the O isotopic composition of Katerloch speleothems.The 8.2 kyr climate anomaly lasted about one century, from 8196 to 8100 yr, with a maximum amplitude of 1.1‰ at 8175 yr. The event is characterized by a rapid onset and a more gradual demise and U–Th data as well as annual lamina counting support a rapid climate change towards cooler conditions within 10–20 yr. There is no strong evidence that the 8.2 kyr anomaly was superimposed on a pronounced longer-term cooling episode, nor do the new data support two separate cooling events within the 8.2 kyr event as reported by other studies. Our record also shows a distinct climate anomaly around 9.1 kyr, which lasted 70–110 yr and showed a maximum amplitude of 1.0‰, i.e. it had a similar duration and amplitude as the (central) 8.2 kyr event. Compared to the 8.2 kyr event, the 9.1 kyr anomaly shows a more symmetrical structure, but onset and demise still occurred within a few decades only. The different progression of the 8.2 (asymmetrical) and 9.1 kyr anomaly (symmetrical) suggests a fundamental difference in the trigger and/or the response of the climate system. Moreover, both stalagmites show evidence of a climate anomaly around 10.0 kyr, which was of comparable magnitude to the two subsequent events.Using a well constrained modern calibration between air temperature and δ¹⁸O of precipitation for the study area and cave monitoring data (confirming speleothem deposition in Katerloch reflecting cave air temperature), a maximum cooling by ca 3 °C can be inferred at 8.2 and 9.1 kyr, which is similar to other estimates, e.g., from Lake Ammersee north of the Alps. The O isotopic composition of meteoric precipitation, however, is a complex tracer of the hydrological cycle and these temperature estimates do not take into account additional effects such as changes in the source area or synoptic shifts. Apart from that, the relative thickness of the seasonally controlled lamina types in the Katerloch stalagmites remains rather constant across the intervals comprising the isotopic anomalies, i.e. the stalagmite petrography argues against major shifts in seasonality during the early Holocene climate excursions.     

Elemental and isotopic carbon and nitrogen records of organic matter accumulation in a Holocene permafrost peat sequence in the East European Russian Arctic

A peat deposit from the East European Russian Arctic, spanning nearly 10 000 years, was investigated to study soil organic matter degradation using analyses of bulk elemental and stable isotopic compositions and plant macrofossil remains. The peat accumulated initially in a wet fen that was transformed into a peat plateau bog following aggradation of permafrost in the late Holocene (～2500 cal a BP). Total organic carbon and total nitrogen (N) concentrations are higher in the fen peat than in the moss‐dominated bog peat layers. Layers in the sequence that have lower concentrations of total hydrogen (H) are associated with degraded vascular plant residues. C/N and H/C atomic ratios indicate better preservation of organic matter in peat material dominated by bryophytes as opposed to vascular plants. The presence of permafrost in the peat plateau stage and water‐saturated conditions at the bottom of the fen stage appear to lead to better preservation of organic plant material. δ¹⁵N values suggest N isotopic fractionation was driven primarily by microbial decomposition whereas differences in δ¹³C values appear to reflect mainly changes in plant assemblages. Positive shifts in both δ¹⁵N and δ¹³C values coincide with a local change to drier conditions as a result of the onset of permafrost and frost heave of the peat surface. This pattern suggests that permafrost aggradation not only resulted in changes in vegetation but also aerated the underlying fen peat, which enhanced microbial denitrification, causing the observed ¹⁵N‐enrichment. Copyright © 2012 John Wiley & Sons, Ltd.     

Paleoclimate reconstruction in the Levant region from the geochemistry of a Holocene stalagmite from the Jeita cave, Lebanon

Dated oxygen and carbon isotopic profiles from a Holocene stalagmite (11.9–1.1 ka) from the Jeita cave, Lebanon, are compared to variations in crystallographic habit, stalagmite diameter and growth rate. The profiles show generally high δ¹⁸O and δ¹³C values during the late-glacial period, low values during the early Holocene, and again high values after 5.8 ka. On the basis of the good correlation between the morphological and crystallographic aspect of the stalagmite and its isotopic records, as well as the isotopic response of speleothems from central and northern Israel, we relate high δ¹⁸O and δ¹³C values to drier conditions. Between 6.5 and 5.8 ka an increase in isotopic values, a decrease in growth rate and stalagmite diameter suggest a transition from wet conditions in the early Holocene towards drier conditions in the mid-Holocene. The transition occurred in two steps, first a progressive change to drier conditions started at 6.5 ka but was interrupted by a short ( 100 years) return to wetter conditions, followed by an equally rapid (< 200 years) change to drier conditions.     

Oxygen and carbon isotopic systematics of aragonite speleothems and water in Furong Cave, Chongqing, China

To understand oxygen and carbon stable isotopic characteristics of aragonite stalagmites and evaluate their applicability to paleoclimate, the isotopic compositions of active and fossil aragonite speleothems and water samples from an in situ multi-year (October 2005-July 2010) monitoring program in Furong Cave located in Chongqing of China have been examined. The observations during October 2005-June 2007 show that the meteoric water is well mixed in the overlying 300-500-m bedrock aquifer, reflected by relatively constant δ¹⁸O, ±0.11-0.14‰ (1σ), of drip waters in the cave, which represents the annual status of rainfall water. Active cave aragonite speleothems are at oxygen isotopic equilibrium with drip water and their δ¹⁸O values capture the surface-water oxygen isotopic signal. Aragonite-to-calcite transformation since the last glaciation is not noticeable in Furong stalagmites. Our multi-year field experiment approves that aragonite stalagmite δ¹⁸O records in this cave are suitable for paleoclimate reconstruction. With high U, 0.5-7.2 ppm, and low Th, 20-1270 ppt, the Furong aragonite stalagmites provide very precise chronology (as good as ±20s yrs (2σ)) of the climatic variations since the last deglaciation. The synchroneity of Chinese stalagmite δ¹⁸O records at the transition into the Bølling-Allerød (t-BA) and the Younger Dryas from Furong, Hulu and Dongge Caves supports the fidelity of the reconstructed East Asian monsoon evolution. However, the Furong record shows that the cold Older Dryas (OD) occurred at 14.0 thousand years ago, agreeing with Greenland ice core δ¹⁸O records but ∼200 yrs younger than that in the Hulu record. The OD age discrepancy between Chinese caves can be attributable to different regionally climatic/environmental conditions or chronological uncertainty of stalagmite proxy records, which is limited by changes in growth rate and subsampling intervals in absolute dating. Seasonal dissolved inorganic carbon δ¹³C variations of 2-3‰ in the drip water and 5-7‰ in the pool and spring waters are likely attributed to variable degrees of CO₂ degassing in winter and summer. The variable δ¹³C values of active deposits from −11‰ to 0‰ could be caused by kinetically mediated CO₂ degassing processes. The complicated nature of pre-deposition kinetic isotopic fractionation processes for carbon isotopes in speleothems at Furong Cave require further study before they can be interpreted in a paleoclimatic or paleoenvironmental context.     

Carbon and oxygen isotope records and paleoclimate reconstruction (140–250 ka B.P.) from a stalagmite of Shuinan Cave, Guilin, China

The time sequence of paleoclimatic changes from 245.2 to 147.9 ka B.P. has been established by high precision U-series dating by Thermal Ionization Mass Spectrometry and the analysis of the oxygen isotopes from a stalagmite of Shuinan Cave in Guilin. The oxygen isotope pattern is divided into three main intervals. The top part of the stalagmite (interval C) displays mainly relatively heavy oxygen isotopes, mostly −7 to −5‰_VPDB, but at a depth of 86.5 cm below the top, there is a sharp change to values lighter than −8 ‰. This boundary, dated at 192.6 ±3.9 ka B.P. is correlated with the boundary between marine oxygen isotope stages 6 and 7. The underlying interval B has δ¹⁸O values consistently between −7.5 and −8.5‰ until 271 cm depth when there is a sharp rise in δ¹⁸O values towards values as heavy as −5‰. The upper position of this change is dated at 242.5±6.4 ka B.P. and is correlated with the boundary between marine isotope stages 7 and 8. Carbon isotope values lie between −8.5 and −11‰ and are not uniquely high or low in the three intervals, but also show rapid changes at the boundaries between intervals in the same sense as the shifts in δ¹⁸O. The pronounced shifts in δ¹⁸O are attributed to changes in the paleo-monsoon intensity which reflect major reorganizations of the climate system, but some regional characteristics are also present. The results are also consistent with previous studies of climate proxies from loess-palaesol sequences in northern China. These characteristics show that paleo-climate evolution since the late stage of the middle Pleistocene Epoch in the Guilin area not only follows the global characteristics, but also has the strong district or regional patterns.     

小冰期十年际尺度亚洲季风变化的四川黑竹沟洞石笋记录

基于四川省黑竹沟洞一支石笋（编号：EB1）高精度²³⁰Th年龄和氧同位素数据,建立小冰期时期（1375~1810A.D.）气候变化时间序列。该序列δ¹⁸O值变化范围为-10.37‰~-8.58‰,敏感响应于区域气候变化过程。高分辨率δ¹⁸O变化序列能清晰地捕捉到10年际尺度振荡旋回。该石笋记录根据δ¹⁸O值变化可分为4个阶段：1375~1540A.D.和1680~1780A.D.时段,δ¹⁸O值整体偏负,指示季风增强时期;1540~1680A.D.和1780~1810A.D.时段,δ¹⁸O值整体偏正,处于弱季风阶段。与贵州董哥洞、甘肃万象洞和印度Jhumar洞石笋记录对比发现在小冰期时期δ¹⁸O变化特征具有一定的相似性,表明上述区域降水可能共同受控于印度季风水汽输送影响,反映了区域性夏季风经向环流及其降水变化特征。通过EB1石笋记录与北半球温度曲线的对比发现,两者在百年尺度上同相位变化,可能指示北高纬气候的控制作用。而该石笋与秘鲁东北部Cascayunga洞石笋记录的进一步对比结果显示亚洲季风与南半球季风记录呈反相位关系,证实了ITCZ位置的南北移动在半球间能量传递和交换过程中的重要作用。功率谱分析结果显示小冰期季风波动具有显著的25a和9a周期旋回,接近太阳黑子22a和11a周期频率,表明太阳活动变化可能是小冰期十年际尺度亚洲季风波动的重要驱动因素。

     

Late-glacial and Holocene vegetation and climatic history of the Cass Basin, central South Island, New Zealand

Lithology, pollen, macrofossils, and stable carbon isotopes from an intermontane basin bog site in southern New Zealand provide a detailed late-glacial and early Holocene vegetation and climate record. Glacial retreat occurred before 17,000 cal yr B.P., and tundra-like grassland–shrubland occupied the basin shortly after. Between 16,500 and 14,600 cal yr B.P., a minor regional expansion of forest patches occurred in response to warming, but the basin remained in shrubland. Forest retreated between 14,600 and 13,600 cal yr B.P., at about the time of the Antarctic Cold Reversal. At 13,600 cal yr B.P., a steady progression from shrubland to tall podocarp forest began as the climate ameliorated. Tall, temperate podocarp trees replaced stress-tolerant shrubs and trees between 12,800 and 11,300 cal yr B.P., indicating sustained warming during the Younger Dryas Chronozone (YDC). Stable isotopes suggest increasing atmospheric humidity from 11,800 to 9300 cal yr B.P. Mild (annual temperatures at least 1°C higher than present), and moist conditions prevailed from 11,000 to 10,350 cal yr B.P. Cooler, more variable conditions followed, and podocarp forest was completely replaced by montane Nothofagus forest at around 7500 cal yr B.P. with the onset of the modern climate regime. The Cass Basin late-glacial climate record closely matches the Antarctic ice core records and is in approximate antiphase with the North Atlantic.     

Paleoenvironmental records of water level and climatic changes from the middle to late Holocene at a Lake Erie coastal wetland, Ontario, Canada

Pollen and diatom assemblages, and peat stratigraphies, from a coastal wetland on the northern shore of Lake Erie were used to analyze water level and climatic changes since the middle Holocene and their effects on wetland plant communities. Peat deposition began 4700 cal yr B.P. during the Nipissing II transgression, which was driven by isostatic rebound. At that time, a diatom-rich wild rice marsh existed at the site. Water level dropped at the end of the Nipissing rise at least 2 m within 200 yr, leading to the development of shallower-water plant communities and an environment too dry for most diatoms to persist. The sharp decline in water level was probably driven primarily by outlet incision, but climate likely played some role. The paleoecological records provide evidence for post-Nipissing century-scale transgressions occurring around 2300, 1160, 700 and 450 cal yr B.P. The chronology for these transgressions correlates with other studies from the region and implies climatic forcing. Peat inception in shallow sloughs across part of the study area around 700 cal yr B.P. coincides with the Little Ice Age. These records, considered alongside others from the region, suggest that the Little Ice Age may have resulted in a wetter climate across the eastern Great Lakes region.     

海南岛沙老岸礁区滨珊瑚氧、碳同位素对气候的记录

通过对海南岛沙老岸礁中正在连续生长的澄黄滨珊瑚骨骼进行氧，碳同位素的测定，对9年生长的珊瑚骨骼依次分析了352个样品，平均每旬有1－2个控制样品，以此来分析珊瑚生长期间的气候变化。首先分析出每年雨季和旱季的差别，得到雨季和旱季曲线的特征，并得出雨季在每年夏季，旱季在每年的秋冬季，表明海南岛礁区是典型的季风气候区。同时将珊瑚骨骼的氧同位素分析数值与相关记录的气温资料做比较，它们的相关系数为0．97和0．79，并得出以氧同位素分析数值求气温的公式。     

Mineralogy and geochemistry of the Au-Ag ore deposits of the South Korean Peninsula

Pyrite and arsenopyrite are the predominant ore minerals in the Korean Au-Ag deposits of this study. The X _Ni ^py , X _Co ^py , X _Ni ^apy , and X _Co ^apy values range between 100 and 3,000 ppm, 200 and 6,000 ppm, 200 and 8,200 ppm, and 100 and 10,200 ppm, respectively. Most X _Ni ^py /X _Co ^py values fall in the field lower than values varying 0.16–1.30. Arsenopyrite also tends to prefer cobalt rather than nickel showing X _Ni ^apy /X _Co ^apy values between 0.20 and 1.40. The concentrations of minor elements in ores and gangue minerals vary 1–55 ppm Au and 1–1,120 ppm Ag for the former and 4–57 ppm Ni and 2–45 ppm Co for the latter. The Au/Ag ratio in ore has a good correlation to the Ni/Co ratio of arsenopyrite to gangue. The (Ni/Co)_py-(Ni/Co)_gangue and (Ni/Co)_apy-(Ni/Co)_gangue diagrams revealed that the values from the Korean Au-Ag deposits plot in the field lower than 900 °C which is the lowermost temperature determined by previous partitioning experiments.     

全新世早期石笋灰度序列记录的气候环境信息分析——以重庆羊口洞石笋为例

以采自重庆南川地区金佛山羊口洞中一支石笋YK719为研究对象,利用精确的230Th测年数据、δ18O数据和灰度数据重建了重庆地区早全新世古气候变化序列。将石笋YK719灰度序列和δ18O记录进行对比后发现,在弱季风时段,石笋δ18O值偏重,石笋灰度值较高,灰度序列表现出“谷”构造;反之亦然。分析显示羊口洞石笋灰度序列与树轮Δ14C数据、太阳黑子数据具有较高的相关性,说明太阳活动是驱动石笋灰度序列变化的一个重要因素。太阳活动可能通过温度和季风降水两方面来影响石笋灰度的变化:温度升高促使土壤微生物活动量增加,土壤中可溶性有机碳和CO2含量增加,从而形成较为纯净的方解石沉积物,石笋颜色暗而透明,反之,石笋表现为不透明乳白色;北大西洋浮冰变化在早全新世可能通过季风－欧亚大陆雪盖耦合来间接地影响亚洲季风降水变化,从而影响石笋灰度的变化。      

Scottish early Holocene vegetation dynamics based on pollen and tephra records from Inverlair and Loch Etteridge,Inverness-shire

This paper presents the results of an investigation of early Holocene cryptotephra layers recovered from sediments in two kettle-hole basins at Inverlair (Glen Spean) and Loch Etteridge (Glen Fernisdale). Electron probe micro-analysis (EPMA) of shards from two cryptotephra layers revealed that the uppermost layer in both sequences has a composition similar to the An Druim tephra, first reported from a site in Northern Scotland. We present evidence that distinguishes the An Druim from the chemically very similar early Holocene Ashik tephra. The lowermost layer at Inverlair matches the composition of the Askja-S tephra found in the Faroe Islands, Ireland, Sweden, Germany and Switzerland. This is the first published record of the Askja-S tephra from mainland Scotland. As at other sites, the Askja-S seems to mark a short-lived climatic deterioration, most likely the Pre-Boreal Oscillation: at Inverlair it occurs just above an oscillation represented by a reduction in LOI values and in the abundance of Betula pollen, and by a peak in Juniperus pollen. The lowermost layer at Loch Etteridge has a Katla-type chemistry and extends through the upper part of the Loch Lomond (Younger Dryas/GS-1) Stadial to the Stadial/Holocene transition; it may represent a composite layer which merges the Vedde and Abernethy tephras. One of the key conclusions is that the glacial-melt deposits in the vicinity of Inverlair (kames and kame terraces) were ice-free by c. 10.83 ka (the age of the Askja-S), providing a limiting age on the disappearance of LLR ice in Glen Spean.