The 183-WSL fast rain rate retrieval algorithm: Part I: Retrieval design

The Water vapour Strong Lines at 183 GHz (183-WSL) fast retrieval method retrieves rain rates and classifies precipitation types for applications in nowcasting and weather monitoring. The retrieval scheme consists of two fast algorithms, over land and over ocean, that use the water vapour absorption lines at 183.31 GHz corresponding to the channels 3 (183.31 ± 1 GHz), 4 (183.31 ± 3 GHz) and 5 (183.31 ± 7 GHz) of the Advanced Microwave Sounding Unit module B (AMSU-B) and of the Microwave Humidity Sounder (MHS) flying on NOAA-15-18 and Metop-A satellite series, respectively.The method retrieves rain rates by exploiting the extinction of radiation due to rain drops following four subsequent steps. After ingesting the satellite data stream, the window channels at 89 and 150 GHz are used to compute scattering-based thresholds and the 183-WSLW module for rainfall area discrimination and precipitation type classification as stratiform or convective on the basis of the thresholds calculated for land/mixed and sea surfaces. The thresholds are based on the brightness temperature difference Δ_win = T_B89 ? T_B150 and are different over land (L) and over sea (S): cloud droplets and water vapour (Δ_win < 3 K L; Δ_win < 0 K S), stratiform rain (3 K < Δ_win < 10 K L; 0 K < Δ_win < 10 K S), and convective rain (Δ_win > 10 K L and S). The thresholds, initially empirically derived from observations, are corroborated by the simulations of the RTTOV radiative transfer model applied to 20000 ECMWF atmospheric profiles at midlatitudes and the use of data from the Nimrod radar network. A snow cover mask and a digital elevation model are used to eliminate false rain area attribution, especially over elevated terrain. A probability of detection logistic function is also applied in the transition region from no-rain to rain adjacent to the clouds to ensure continuity of the rainfall field. Finally, the last step is dedicated to the rain rate retrieval with the modules 183-WSLS (stratiform) and 183WSLC (convective), and the module 183-WSL for total rainfall intensity derivation.A comparison with rainfall retrievals from the Goddard Profiling (GPROF) TRMM 2A12 algorithm is done with good results on a stratiform and hurricane case studies. A comparison is also conducted with the MSG-based Precipitation Index (PI) and the Scattering Index (SI) for a convective-stratiform event showing good agreement with the 183-WSLC retrieval. A complete validation of the product is the subject of Part II of the paper.     

Below-cloud rain scavenging of atmospheric aerosols for aerosol deposition models

Below-cloud aerosol scavenging is generally estimated from field measurements using advanced instruments that measure changes in aerosol distributions with respect to rainfall. In this study, we discuss various scavenging mechanisms and scavenging coefficients from past laboratory and field measurements. Scavenging coefficients derived from field measurements (representing natural aerosols scavenging) are two orders higher than that of theoretical ones for smaller particles (D_p < 2 μm). Measured size-resolved scavenging coefficients can be served as a better option to the default scavenging coefficient (e.g. a constant of 10^?4 s^?1 for all size of aerosols, as used in the CALPUFF model) for representing below-cloud aerosol scavenging. We propose scavenging correction parameter (C_R) as an exponential function of size-resolved scavenging coefficients, winds and width in the downwind of the source–receptor system. For a wind speed of 3 m s^?1, C_R decrease with the width in the downwind for particles of diameters D_p < 0.1 μm but C_R does not vary much for particles in the accumulation mode (0.1 < D_p < 2 μm). For a typical urban aerosol distribution, assuming 3 m s^?1 air-flow in the source–receptor system, 10 km downwind width, 2.84 mm h^?1 of rainfall and using aerosol size dependent scavenging coefficients in the C_R, scavenging of aerosols is found to be 16% in number and 24% in volume of total aerosols. Using the default scavenging coefficient (10^?4 s^?1) in the CALPUFF model, it is found to be 64% in both number and volume of total aerosols.     

Analysis of rainfall characteristics of the Madden–Julian oscillation using TRMM satellite data

Rainfall characteristics of the Madden–Julian oscillation (MJO) are analyzed primarily using tropical rainfall measuring mission (TRMM) precipitation radar (PR), TRMM microwave imager (TMI) and lighting imaging sensor (LIS) data. Latent heating structure is also examined using latent heating data estimated with the spectral latent heating (SLH) algorithm.The zonal structure, time evolution, and characteristic stages of the MJO precipitation system are described. Stratiform rain fraction increases with the cloud activity, and the amplitude of stratiform rain variation associated with the MJO is larger than that of convective rain by a factor of 1.7. Maximum peaks of both convective rain and stratiform rain precede the minimum peak of the outgoing longwave radiation (OLR) anomaly which is often used as a proxy for the MJO convection. Stratiform rain remains longer than convective rain until ∼4000 km behind the peak of the mature phase. The stratiform rain contribution results in the top-heavy heating profile of the MJO.Associated with the MJO, there are tri-pole convective rain top heights (RTH) at 10–11, ∼7 and ∼3 km, corresponding to the dominance of afternoon showers, organized systems, and shallow convections, respectively. The stratiform rain is basically organized with convective rain, having similar but slightly lower RTH and slightly lags the convective rain maximum. It is notable that relatively moderate (∼7 km) RTH is dominant in the mature phase of the MJO, while very tall rainfall with RTH over 10 km and lightning frequency increase in the suppressed phase. The rain-yield-per flash (RPF) varies about 20–100% of the mean value of ∼2–10 × 10⁹ kg fl⁻¹ over the tropical warm ocean and that of ∼2–5 × 10⁹ kg fl⁻¹ over the equatorial Islands, between the convectively suppressed phase and the active phase of MJO, in the manner that RPF is smaller in the suppressed phase and larger in the active phase.     

A Mediterranean nocturnal heavy rainfall and tornadic event. Part I: Overview,damage survey and radar analysis

This study presents an analysis of a severe weather case that took place during the early morning of the 2nd of November 2008, when intense convective activity associated with a rapidly evolving low pressure system affected the southern coast of Catalonia (NE Spain). The synoptic framework was dominated by an upper level trough and an associated cold front extending from Gibraltar along the Mediterranean coast of the Iberian Peninsula to SE France, which moved north-eastward. South easterly winds in the north of the Balearic Islands and the coast of Catalonia favoured high values of 0–3 km storm relative helicity which combined with moderate MLCAPE values and high shear favoured the conditions for organized convection. A number of multicell storms and others exhibiting supercell features, as indicated by Doppler radar observations, clustered later in a mesoscale convective system, and moved north-eastwards across Catalonia. They produced ground-level strong damaging wind gusts, an F2 tornado, hail and heavy rainfall. Total lightning activity (intra-cloud and cloud to ground flashes) was also relevant, exhibiting several classical features such as a sudden increased rate before ground level severe damage, as discussed in a companion study. Remarkable surface observations of this event include 24 h precipitation accumulations exceeding 100 mm in four different observatories and 30 minute rainfall amounts up to 40 mm which caused local flash floods. As the convective system evolved northward later that day it also affected SE France causing large hail, ground level damaging wind gusts and heavy rainfall.     

An analysis of extreme intraseasonal rainfall events during January–March 2010 over eastern China

The precipitation over eastern China during January–March 2010 exhibited a marked intraseasonal oscillation (ISO) and a dominant period of 10-60 days. There were two active intraseasonal rainfall periods. The physical mechanisms responsible for the onset of the two rainfall events were investigated using ERA-interim data. In the first ISO event, anomalous ascending motion was triggered by vertically integrated (1000–300 hPa) warm temperature advection. In addition to southerly anomalies on the intraseasonal (10–60-day) timescale, synoptic-scale southeasterly winds helped advect warm air from the South China Sea and western Pacific into the rainfall region. In the second ISO event, anomalous convection was triggered by a convectively unstable stratification, which was caused primarily by anomalous moisture advection in the lower troposphere (1000–850 hPa) from the Bay of Bengal and the Indo-China Peninsula. Both the intraseasonal and the synoptic winds contributed to the anomalous moisture advection. Therefore, the winter intraseasonal rainfall events over East Asia in winter could be affected not only by intraseasonal activities but also by higher frequency disturbances.     

Variability of CO2 fugacity at the western edge of the tropical Atlantic Ocean from the 8°N to 38°W PIRATA buoy

Hourly data of CO₂ fugacity (fCO₂) at 8°N–38°W were analyzed from 2008 to 2011. Analyses of wind, rainfall, temperature and salinity data from the buoy indicated two distinct seasonal periods. The first period (January to July) had a mean fCO₂ of 378.9 μatm (n = 7512). During this period, in which the study area was characterized by small salinity variations, the fCO₂ is mainly controlled by sea surface temperature (SST) variations (fCO₂ = 24.4*SST-281.1, r² = 0.8). During the second period (August–December), the mean fCO₂ was 421.9 μatm (n = 11571). During these months, the region is subjected to the simultaneous action of (a) rainfall induced by the presence of the Intertropical Convergence Zone (ITCZ); (b) arrival of fresh water from the Amazon River plume that is transported to the east by the North Equatorial Countercurrent (NECC) after the retroflection of the North Brazil Current (NBC); and (c) vertical input of CO₂-rich water due to Ekman pumping. The data indicated the existence of high-frequency fCO₂ variability (periods less than 24 h). This high variability is related to two different mechanisms. In the first mechanism, fCO₂ increases are associated to rapid increases in SST and are attributed to the diurnal cycle of solar radiation. In addition, low wind speed contributes to SST rising by inhibiting vertical mixing. In the second mechanism, fCO₂ decreases are associated to SSS decreases caused by heavy rainfall.     

Influence of spatial and temporal scales on statistical analyses of rainfall variability in the River Nile basin

In this study, empirical orthogonal function was applied to analyze rainfall variability in the Nile basin based on various spatio-temporal scales. The co-occurrence of rainfall variability and the variation in selected climate indices was analyzed based on various spatio-temporal scales. From the highest to the lowest, the cumulative amount of variance explained by the first two principal components (PCs) for any selected size of the spatial domain was obtained for the annual, seasonal, and monthly rainfall series respectively. The variability in the annual rainfall of 1° × 1° spatial coverage explained by only the first PC was about 55% on average. However, this percentage reduced to about 40% on average across the study area when the size of the spatial domain was increased from 1° × 1° to 10° × 10°. The variation in climate indices was shown to explain rainfall variability more suitably at a regional than location-specific spatial scale. The magnitudes and sometimes signs of the correlation between rainfall variability and the variation in climate indices tended to vary from one time scale to another. These findings are vital in the selection of spatial and temporal scales for more considered attribution of rainfall variability across the study area.     

One year measurements of aerosol optical properties over an urban coastal site: Effect on local direct radiative forcing

We present results of direct aerosol radiative forcing over a French Mediterranean coastal zone based on one year of continuous observations of aerosol optical properties during 2005–2006. Monthly-mean aerosol optical depth at 440 nm ranged between 0.1 and 0.34, with high Angstrom coefficient (α > 1.2). The single scattering albedo (at 525 nm) estimated at the surface ranged between 0.7 and 0.8, indicating significant absorption. The presence of aerosols over the Mediterranean zone during summer decreases the shortwave radiation reaching the surface by as much as 26 ± 3.9 W m^− 2, and increases the top of the atmosphere reflected radiation by as much as 5.2 ± 1.0 W m^− 2. The shortwave atmospheric absorption translates to an atmospheric heating of 2.5 to 4.6 K day^− 1. Concerted efforts are needed for investigating the possible impact of the increase in heating rate on the maintenance of heat-waves frequently occurring over this coastal region during summer time.     

Farmer perceptions of climate change: Associations with observed temperature and precipitation trends,irrigation, and climate beliefs

How individuals perceive climate change is linked to whether individuals support climate policies and whether they alter their own climate-related behaviors, yet climate perceptions may be influenced by many factors beyond local shifts in weather. Infrastructure designed to control or regulate natural resources may serve as an important lens through which people experience climate, and thus may influence perceptions. Likewise, perceptions may be influenced by personal beliefs about climate change and whether it is human-induced. Here we examine farmer perceptions of historical climate change, how perceptions are related to observed trends in regional climate, how perceptions are related to the presence of irrigation infrastructure, and how perceptions are related to beliefs and concerns about climate change. We focus on the regions of Marlborough and Hawke’s Bay in New Zealand, where irrigation is utilized on the majority of cropland. Data are obtained through analysis of historical climate records from local weather stations, interviews (n = 20), and a farmer survey (n = 490). Across both regions, no significant historical trends in annual precipitation and summer temperatures since 1980 are observed, but winter warming trends are significant at around 0.2–0.3 °C per decade. A large fraction of farmers perceived increases in annual rainfall despite instrumental records indicating no significant trends, a finding that may be related to greater perceived water availability associated with irrigation growth. A greater fraction of farmers perceived rainfall increases in Marlborough, where irrigation growth has been most substantial. We find those classes of farmers more likely to have irrigation were also significantly more likely to perceive an increase in annual rainfall. Furthermore, we demonstrate that perceptions of changing climate – regardless of their accuracy – are correlated with increased belief in climate change and an increased concern for future climate impacts. Those farmers that believe climate change is occurring and is human induced are more likely to perceive temperature increases than farmers who believe climate change is not occurring and is not human induced. These results suggest that perceptions are influenced by a variety of personal and environmental factors, including infrastructure, which may in turn alter decisions about climate adaptation.     

Climate change impacts on ecosystems and the terrestrial carbon sink: a new assessment

Climate output from the UK Hadley Centre's HadCM2 and HadCM3 experiments for the period 1860 to 2100, with IS92a greenhouse gas forcing, together with predicted patterns of N deposition and increasing CO₂, were input (offline) to the dynamic vegetation model, Hybrid v4.1 (Friend et al., 1997; Friend and White, 1999). This model represents biogeochemical, biophysical and biogeographical processes, coupling the carbon, nitrogen and water cycles on a sub-daily timestep, simulating potential vegetation and transient changes in annual growth and competition between eight generalized plant types in response to climate.Global vegetation carbon was predicted to rise from about 600 to 800 PgC (or to 650 PgC for HadCM3) while the soil carbon pool of about 1100 PgC decreased by about 8%. By the 2080s, climate change caused a partial loss of Amazonian rainforest, C₄ grasslands and temperate forest in areas of southern Europe and eastern USA, but an expansion in the boreal forest area. These changes were accompanied by a decrease in net primary productivity (NPP) of vegetation in many tropical areas, southern Europe and eastern USA (in response to warming and a decrease in rainfall), but an increase in NPP of boreal forests. Global NPP increased from 45 to 50 PgC y⁻¹ in the 1990s to about 65 PgC y⁻¹ in the 2080s (about 58 PgC y⁻¹ for HadCM3). Global net ecosystem productivity (NEP) increased from about 1.3 PgC y⁻¹ in the 1990s to about 3.6 PgC y⁻¹ in the 2030s and then declined to zero by 2100 owing to a loss of carbon from declining forests in the tropics and at warm temperate latitudes — despite strengthening of the carbon sink at northern high latitudes. HadCM3 gave a more erratic temporal evolution of NEP than HadCM2, with a dramatic collapse in NEP in the 2050s.     

Influence of regional pollution and sandstorms on the chemical composition of cloud/fog at the summit of Mt. Taishan in northern China

Cloud/fog samples were collected during spring of 2007 in the highly polluted North China Plain in order to examine the impact of pollution and dust particles on cloud water chemistry. The volume weighted mean pH of cloud water was 3.68. The cloud acidity was shown to be associated with air mass origins. Cloud water with its air mass trajectories originating from the southern part of China was more acidic than those from northern China. Anthropogenic source and dust had obvious impact on cloud water composition as indicated by the very high mean concentrations of SO₄^2? (1331.65 μeq L^? 1), NO₃^? (772.44 μeq L^? 1), NH₄⁺ (1375.92 μeq L^? 1) and Ca²⁺ (625.81 μeq L^? 1) in the observation periods. During sandstorm days, cloud pH values were relatively high, and the concentrations of all the ions in cloud water reached unusual high levels. Significant decreases in the mass concentrations of PM_2.5 and PM₁₀ were observed during cloud events. The average scavenging ratio for PM_2.5 and PM₁₀ was 52.0% and 55.7%, respectively. Among the soluble ions in fine particles, NO₃^?, K⁺ and NH₄⁺ tend to be more easily scavenged than Ca²⁺ and Na⁺.     

Exploring the vertical extent of breaking internal wave turbulence above deep-sea topography

A mooring equipped with 200 high-resolution temperature sensors between 6 and 404 m above the bottom was moored in 1890 m water depth above a steep, about 10° slope of Mount Josephine, NE-Atlantic. The sensors have a precision of less than 0.5 mK. They are synchronized via induction every 4 h so that the 400 m range is measured to within 0.02 s, every 1 s. Thin cables and elliptical buoyancy assured vertical mooring motions to be smaller than 0.1 m under maximum 0.2 m s⁻¹ current speeds. The local bottom slope is supercritical for semidiurnal internal tides by a factor of two. Exploring a one-month record in detail, the observations show: 1/semidiurnal tidal dominance in variations of dissipation rate ε, eddy diffusivity K_z and temperature, but no significant correlation between the records of ε and total kinetic energy, 2/a variation with time over four orders of magnitude of 100-m vertically averaged ε, 3/a local minimum in density stratification between 50 and 100 m above the bottom, 4/a gradual decrease in daily or longer averaged ε and K_z by one order of magnitude over a vertical distance of 250 m, upwards from 150 m above the bottom, 5/monthly mean values of <[ε]> = 2 ± 0.5 × 10⁻⁷ m² s⁻³, <[K_z]> = 8 ± 3 × 10⁻³ m² s⁻¹ averaged over the lower 150 m above the bottom.     

Nitrate in groundwater of China: Sources and driving forces

Identifying the sources of reactive nitrogen (N) and quantifying their contributions to groundwater nitrate concentrations are critical to understanding the dynamics of groundwater nitrate contamination. Here we assessed groundwater nitrate contamination in China using literature analysis and N balance calculation in coupled human and natural systems. The source appointment via N balance was well validated by field data via literature analysis. Nitrate was detected in 96% of groundwater samples based on a common detection threshold of 0.2 mg N L^?1, and 28% of groundwater samples exceeded WHO's maximum contaminant level (10 mg N L^?1). Groundwater nitrate concentrations were the highest beneath industrial land (median: 34.6 mg N L^?1), followed by urban land (10.2 mg N L^?1), cropland (4.8 mg N L^?1), and rural human settlement (4.0 mg N L^?1), with the lowest found beneath natural land (0.8 mg N L^?1). During the period 1980–2008, total reactive N leakage to groundwater increased about 1.5 times, from 2.0 to 5.0 Tg N year^?1, in China. Despite that the contribution of cropland to the total amount of reactive N leakage to groundwater was reduced from 50 to 40% during the past three decades, cropland still was the single largest source, while the contribution from landfill rapidly increased from 10 to 34%. High reactive N leakage mainly occurred in relatively developed agricultural or urbanized regions with a large population. The amount of reactive N leakage to groundwater was mainly driven by anthropogenic factors (population, gross domestic product, urbanization rate and land use type). We constructed a high resolution map of reactive N source appointment and this could be the basis for future modeling of groundwater nitrate dynamics and for policy development on mitigation of groundwater contamination.     

The origin of sub-surface source waters define the sea–air flux of methane in the Mauritanian Upwelling,NW Africa

Concentrations and flux densities of methane were determined during a Lagrangian study of an advective filament in the permanent upwelling region off western Mauritania. Newly upwelled waters were dominated by the presence of North Atlantic Central Water and surface CH₄ concentrations of 2.2 ± 0.3 nmol L⁻¹ were largely in equilibrium with atmospheric values, with surface saturations of 101.7 ± 14%. As the upwelling filament aged and was advected offshore, CH₄ enriched South Atlantic Central Water from intermediate depths of 100–350 m was entrained into the surface mixed layer of the filament following intense mixing associated with the shelf break. Surface saturations increased to 198.9 ± 15% and flux densities increased from a mean value over the shelf of 2.0 ± 1.1 μmol m⁻² d⁻¹ to a maximum of 22.6 μmol m⁻² d⁻¹. Annual CH₄ emissions for this persistent filament were estimated at 0.77 ± 0.64 Gg which equates to a maximum of 0.35% of the global oceanic budget. This raises the known outgassing intensity of this area and highlights the importance of advecting filaments from upwelling waters as efficient vehicles for air-sea exchange.     

Collapse and recovery in a remote small island—A tale of adaptive cycles or downward spirals?

Few studies consider how social-ecological systems recover from disturbance. We consider the small semi-autonomous island of Rodrigues (Indian Ocean). Based on semi-structured interviews (n = 70), a fisher survey (n = 73), weather data and official records we build a timeline of key events. We tabulate local perceptions (5+ mentions) of changes (social, economic and natural capital) and look for signs of adaptive cycles in the island's social-ecological past. Rising human pressure and extreme weather event impacts are reported since first settlement. We propose a recent “collapse” phase catalysed in the 1970s by severe drought, based on respondents’ perceptions of still-ongoing changes in farming and fishing, water, external dependence, migration and inter-island political change. Connectivity (flows of people, goods, information, money, power) appear to have strengthed local island recovery, but degradation continued, not least due to water scarcity and a lack of shared political vision as Rodrigues became more tied into the wider world.Overall, our findings suggest social-ecological systems may get stuck in a post-collapse recovery without any new structure emerging, presuming adaptive cycles can even be detected. Data gaps and global change redefining spatial and temporal scales could mean the adaptive cycle's usefulness is limited in development policy-making contexts.     

Analysis of quantitative precipitation forecasts using the Dynamic State Index

The German Weather Service (DWD) has two non-hydrostatic operational weather prediction models with different spatial resolution and precipitation parametrisations. The coarser COSMO-EU model has a spatial resolution of 7 km, whereas the higher-resolution COSMO-DE model has a gridspace of 2.8 km and explicitly resolves deep convection. To improve the numerical weather prediction (NWP) models it is necessary to understand precipitation processes. A central goal is the statistical evaluation of precipitation forecasts with dynamic parameters. Here, the Dynamic State Index (DSI) is used as a dynamic threshold parameter. The DSI theoretically describes the change of atmospheric flow fields as deviations from a stationary adiabatic solution of the primitive equations (Névir, 2004). For seasonal area means the DSI shows a remarkably high correlation with the precipitation forecasts provided by the COSMO-DE model. This is especially the case for the summer of 2007. The same analysis has been performed with the COSMO-EU forecast data and the results were compared with those from the COSMO-DE model. Moreover, an independent precipitation analysis, with a resolution corresponding to 7 km and 2.8 km, has been compared with respect to modelled precipitation and the DSI. In addition, correlations between the DSI and modelled as well as observed precipitation as a function of the forecast time for the different grid resolutions are also presented. The results show, that after 12 h, the correlation of the persistence forecast with the DSI reaches two thirds of the initial value. Thus, the DSI offers itself as a new dynamic forecast tool for precipitation events.     

Evidence of high PM2.5 strong acidity in ammonia-rich atmosphere of Guangzhou,China: Transition in pathways of ambient ammonia to form aerosol ammonium at [NH4+]/[SO42–] = 1.5

In this study, 24-h PM_2.5 samples were collected using Harvard Honeycomb denuder/filter-pack system during different seasons in 2006 and 2007 at an urban site in Guangzhou, China. The particles collected in this study were generally acidic (average strong acidity ([H⁺]) ~ 70 nmol m^? 3). Interestingly, aerosol sulfate was not fully neutralized in the ammonia-rich atmosphere (NH₃ ~ 30 ppb) and even when NH₄⁺]/[SO₄^2?] was larger than 2. Consequently, strong acidity ([H⁺]) as high as 170 nmol m^? 3 was observed in these samples. The kinetic rate of neutralization of acidity (acidic sulfate) by ambient ammonia was significantly higher than the rate of formation of ammonium nitrate involving HNO₃ and NH₃ for [NH₄⁺]/[SO₄^2?] ≤ 1.5 and much lower for NH₄⁺]/[SO₄^2?] > 1.5. Therefore, higher nitrate principally formed via homogeneous gas phase reactions involving ammonia and nitric acid were observed for [NH₄⁺]/[SO₄^2?] > 1.5. However, little nitrate, probably formed via heterogeneous processes e.g. reaction of HNO₃ with sea salt or crustal species, was observed for [NH₄⁺]/[SO₄^2?] ≤ 1.5. These demonstrate a clear transition in the pathways of ambient ammonia to form aerosol ammonium at [NH₄⁺]/[SO₄^2?] = 1.5 and evidently explain the observed high acidity due to the unneutralized sulfate in the ammonium-rich aerosol (NH₄⁺]/[SO₄^2?] > 1.5). In fact, the measured acidity was almost similar to the excess acid defined as the acid that remains at [NH₄⁺]/[SO₄^2?] = 1.5 due to the un-neutralized fraction of sulfate ([H⁺] = 0.5[SO₄^2?]). The presence of high excess acid and ammonium nitrate significantly lowered the deliquescence relative humidity of ammonium sulfate (from 80% to 40%) in the ammonium-rich samples.     

Variability of rainfall and effective onset and length of the monsoon season over a sub-humid climatic environment

The study has analyzed the variability and trends in monthly, seasonal and annual rainfall and rainy days of four locations over different agro-ecological zones of Bihar, namely Samastipur (zone-I), Madhepura (zone-II), Sabour (zone-IIIA) and Patna (zone-IIIB). The Mann–Kendall nonparametric test was employed for detection of statistical significance and slopes of the trend lines were determined using the method of least square linear fitting. The variability and trends of onset of effective monsoon and length of monsoon period were also analyzed using the same method. The mean annual rainfall varies from 1137 mm at Patna to 1219 mm at Sabour. July is the rainiest month in all the zones followed by August. Maximum increase in annual rainfall was found at Sabour (40.1% of mean/30 years at 95% confidence level) and minimum for Patna (10.1% of mean/30 years). Significant increasing trend of rainfall during July, August and September at rates of 41.9, 83.2, and 112.7% of the mean/30 years, respectively has been noticed at Madhepura. Analysis of rainy days indicates that rainy days increased during winter and annually for all the sites. The mean effective onset of monsoon varies from 18th June at Sabour to 28th June at Patna. The trends in the date of effective onset of monsoon indicate that the date tends to be early in all the sites except Madhepura. But a significant delayed trend in the onset at a rate of 2.8% of the mean/30 years has been observed for Madhepura. The early trend of the effective onset of monsoon and increasing trends of length of monsoon season have been observed for Samastipur, Sabour and Patna.     

Impressions of the turbulence variability in a weakly stratified,flat-bottom deep-sea ‘boundary layer’

The character of turbulent overturns in a weakly stratified deep-sea is investigated in some detail using 144 high-resolution temperature sensors at 0.7 m intervals, starting 5 m above the bottom. A 9-day, 1 Hz sampled record from the 912 m depth flat-bottom (<0.5% bottom-slope) mooring site in the central-north Alboran Sea (W-Mediterranean) demonstrates an overall conservative temperature range of only 0.05 °C, a typical mean buoyancy period as large as 3 h and a 1 Hz-profile-vertically-averaged turbulence dissipation rate maximum of only 10⁻⁸ m² s⁻³. Nonetheless, this ‘boundary layer’ varies in height between <6 and >104 m above the bottom and is thus not homogeneous throughout; the temperature variations are seldom quiescent and are generally turbulent in appearance, well exceeding noise levels. The turbulence character is associated with small-scale internal waves; examples are found of both shear- and convection-driven turbulence; particular association, although not phase-locked, is found between turbulence variations and tidal rather than with inertial motions; the mean buoyancy frequency of a few times the inertial frequency implies the importance of ‘slantwise convection’ in the direction of the earth rotational vector rather than in the direction of gravity. Such convection is observed both in near-homogeneous and weakly stratified form.     

Intraurban variability of PM10 and PM2.5 in an Eastern Mediterranean city

The results of the first large scale chemical characterization of PM10 and PM2.5 at three different sites in the urban city of Beirut, Lebanon, are presented. Between May 2009 and April 2010 a total of 304 PM10 and PM2.5 samples were collected by sampling every sixth day at three different sites in Beirut. Observed mass concentrations varied between 19.7 and 521.2 μg m^? 3 for PM10 and between 8.4 and 72.2 μg m^? 3 for PM2.5, respectively. Inorganic concentrations accounted for 29.7–35.6 μg m^? 3 and 46.0–53.5 μg m^? 3 of the total mass of PM10 and PM2.5, respectively. Intra-city temporal and spatial variations were assessed based on the study of three factors: correlation coefficients (R) for PM and chemical components, coefficient of divergence (CODs), and source apportionment using positive matrix factorization (PMF). Based on R and COD of PM concentrations, the three sites appear homogeneous. However, when individual elements were compared, heterogeneity among sites was found. This latter was attributed to the variability in the percent contribution of biogenic and local anthropogenic source factors such as traffic related sources and dust resuspension. Other factors included the proximity to the Mediterranean sea, the population density and the topographical structure of the city. Hence, despite its small size (20.8 km²), one PM monitoring site does not reflect an accurate PM level in Beirut.