苏北高压变质带绿片岩中石榴石内文石包裹体的发现

苏北高压变质带位于苏鲁超高压变质带东南缘,露头多为绿片岩相的中—晚元古代云台岩群,典型的蓝片岩仅见于灌云县杨集的钻孔岩心中。本文通过拉曼光谱研究,在连云港地区的绿片岩内石榴石中发现文石(CaCO3)包裹体。文石呈细小包裹体残留于细粒半自形石榴石斑晶中。这些石榴石作为低扩散的刚性矿物,经历了多期变质变形作用,变质反应证据保存在石榴石的成分环带及包体矿物组合中。文石包裹体的存在证明苏北高压变质带北部的、即本区出露的这套岩系是早期经历了高压变质作用、晚期又叠加了绿片岩相变质作用的高压变质地体。     

Petrology and P–T evolution of garnet peridotites from central Sulawesi, Indonesia

Alpine‐type orogenic garnet‐bearing peridotites, associated with quartzo‐feldspathic gneisses of a 140–115 Ma high‐pressure/ultra‐high‐pressure metamorphic (HP‐UHPM) terrane, occur in two regions of the Indonesian island of Sulawesi. Both exposures are located within NW–SE‐trending strike–slip fault zones. Garnet lherzolite occurs as <10 m wide fault slices juxtaposed against Miocene granite in the left‐lateral Palu‐Koro (P‐K) fault valley, and as 10–30 m wide, fault‐bounded outcrops juxtaposed against gabbros and peridotites of the East Sulawesi ophiolite within the right‐lateral Ampana fault in the Bongka river (BR) valley. Six evolutionary stages of recrystallization can be recognized in the peridotites from both localities. Stage I, the precursor spinel lherzolite assemblage, is characterized by Ol+Cpx+Opx±Prg‐Amp ± Spl±Rt±Phl, as inclusions within garnet cores. Stage II, the main garnet lherzolite assemblage, consists of coarse‐grained Ol+Opx+Cpx+Grt; whereas finer‐grained, neoblastic Ol+Opx+Grt+Cpx±Spl±Prg‐Amp±Phl constitutes stage III. Stages IV and V are manifest as kelyphites of fibrous Opx+Cpx+Spl in inner coronas, and Opx+Spl+Prg‐Amp±Ep in outer coronas around garnet, respectively. The final (greenschist facies) retrogressive stage VI is accompanied by recrystallization of Serp+Chl±Mag±Tr±Ni sulphides±Tlc±Cal. P–T conditions of the hydrated precursor spinel lherzolite stage I were probably about 750 °C at 15–20 kbar. P–T determinations of the peak stage IIc (from core compositions) display considerable variation for samples derived from different outcrops, with clustering at 26–38 kbar, 1025–1210 °C (P‐K & BR); 19–21 kbar, 1070–1090 °C (P‐K), and 40–48 kbar, 1205–1290 °C (BR). Stage IIr (derived from rim compositions) generally records decompression of around 4–12 kbar accompanied by cooling of 50–240 °C from the IIc peak stage. Stage III, which post‐dates a phase of ductile deformation, yielded 22±2 kbar at 750±25 °C (P‐K) and 16±2 kbar at 730±40 °C (BR). The granulite–amphibolite–greenschist decompression sequence reflects uplift to upper crustal levels from conditions of 647–862 °C at P=15 kbar (stage IV), through 580–635 °C at P=10–12 kbar (stage V) to 350–400 °C at P=4–7 kbar (stage VI), respectively, and is identical to the sequence recorded in associated granulite, gneiss and eclogite. Sulawesi garnet peridotites are interpreted to represent minor components of the extensive HP‐UHP (peak P >28 kbar, peak T of c. 760 °C) metamorphic basement terrane, which was recrystallized and uplifted in a N‐dipping continental collision zone at the southern Sundaland margin in the mid‐Cretaceous. The low‐T , low‐P and metasomatized spinel lherzolite precursor to the garnet lherzolite probably represents mantle wedge rocks that were dragged down parallel to the slab–wedge interface in a subduction/collision zone by induced corner flow. Ductile tectonic incorporation into the underthrust continental crust from various depths along the interface probably occurred during the exhumation stage, and the garnet peridotites were subsequently uplifted within the HP‐UHPM nappe, suffering a similar decompression history to that experienced by the regional schists and gneisses. Final exhumation from upper crustal levels was clearly facilitated by entrainment in Neogene granitic plutons, and/or Oligocene trans‐tension in deep‐seated strike–slip fault zones.     

Prograde eclogite in the Gföhl Nappe, Czech Republic: new evidence on Variscan high-pressure metamorphism

A layer of relict, high-temperature, prograde eclogite has been discovered within felsic granulite of the Gföhl Nappe, which is the uppermost tectonic unit in the Moldanubian Zone of the Bohemian Massif, the easternmost of the European Variscan massifs. Pressure-temperature conditions for eclogite (≥890  °C, 18.0  kbar) and felsic granulite ( c . 1000  °C, 16  kbar) place early metamorphism of the polymetamorphic Gföhl crustal rocks within the eclogite facies, and preservation of prograde compositional zoning in small garnet grains in high-temperature eclogite requires very rapid heating, as well as cooling. Mantle-derived garnet and spinel–garnet peridotites are associated with the high temperature-high pressure crustal rocks in the Gföhl Nappe, and this distinctive lithological suite appears to be unique among European Phanerozoic orogenic belts, implying that tectonic processes during the late stages in evolution of the Variscan belt were different from those in the Caledonian and Alpine belts. The unusually high temperatures and pressures in Gföhl crustal rocks, mineralogical evidence for rapid heating and cooling, juxtaposition of lithospheric and asthenospheric mantle with crustal rocks, and widespread production of late-stage granites indicate that culmination of the Variscan Orogeny may have been driven by lithospheric delamination and asthenospheric upwelling.     

Petrogenesis of the garnet peridotite and garnet-free peridotite of the Zhimafang ultramafic body in the Sulu ultrahigh-pressure metamorphic belt, eastern China

The CCSD‐PP1 drillhole penetrated a 110‐m‐thick sequence of the Zhimafang ultramafic body in the Sulu ultrahigh‐pressure (UHP) metamorphic belt, east China. The sequence consists of interlayered garnet‐bearing (Grt) and garnet‐free (GF) peridotite. Eleven layers of Grt‐peridotite, ranging from 1.2 to 9.5 m in thickness, have an aggregate thickness of 54.49 m, whereas eight layers of GF‐peridotite, ranging from 2.2 to 14.2 m in thickness, have a total thickness of 57.53 m. The boundaries between the two rock types are gradational. The Grt‐peridotites have slightly higher contents of Al₂O₃, CaO and SiO₂, and lower Mg^#s (0.90–0.92) than the GF‐peridotites (Mg^#s 0.91–0.93). Both contain low TiO₂ (<0.05 wt%) and have higher modal abundances of enstatite (average 10 vol.%) than diopside (1–5 vol.%), typical of depleted‐type upper mantle. The diopside in these rocks has high and relatively uniform Mg^# members (0.93–0.95), but highly variable Al₂O₃ (0.2–2.3 wt%), Na₂O (0.5–2.5 wt%) and Cr₂O₃ (0.38–2.09 wt%). Enstatite (En_92?93) contains very low Al₂O₃ (0–0.3 wt%). Both porphyroblastic and equigranular garnet are present. The equigranular varieties are zoned, from core to rim in Cr₂O₃ (3.4–4.2 wt%), MgO (18.4–17.5 wt%) and Al₂O₃ (21.1–20.1 wt%). Titania is very low in all the garnet, mostly <0.05 wt%. Chromite or chromium (Cr)‐spinel occur both in the Grt‐ and GF‐peridotite, and are characterized by high contents of Cr₂O₃ (49–58 wt%) and FeO (24–43 wt%), similar to that in iron‐rich Alpine‐type peridotites. Based on the bulk‐rock MgO–FeO compositions, the Zhimafang Grt‐peridotite probably underwent 20–30% partial melting, whereas the GF‐peridotite may have undergone as much as 35–40% partial melting, suggesting that the two rock types owe their differences to different degrees of partial melting rather than to pressure differences during metamorphism.     

利用石榴橄榄岩重建大陆俯冲带的古动力学环境及其演化过程

本文提出一种对于造山带石榴橄榄岩的简单概念分类模型。该模型将造山带石榴橄榄岩划分为地幔楔型和俯冲带型两种类型,根据所记录温压条件及P-T轨迹的差异,地幔楔型石榴橄榄岩进而被划分为A-D四个亚类,分别对应不同厚度的克拉通型岩石圈地幔及普通大陆岩石圈地幔环境中冷的/古老的/稳定的地幔环境及与之对应的相对热的/年轻的/活动地幔环境。我们选择研究程度较高的斯堪的纳维亚加里东期造山带及我国柴北缘造山带中出露的石榴橄榄岩来检验该模型的适用性。出露于挪威西片麻岩地区的Mg-Cr型及Fe-Ti型石榴橄榄岩分别属于地幔楔型的A亚类(来自于古老的/冷的/厚的/亏损的克拉通岩石圈地幔)及壳源俯冲带石榴橄榄岩,而来自Seve,Troms和Linds地体的石榴橄榄岩则属于地幔楔型的C亚类(来自于古老的/冷的/薄的/亏损的大陆岩石圈地幔)后经历俯冲过程变为俯冲带石榴橄榄岩。对我国柴北缘超高压带绿梁山石榴橄榄岩的检验结果相对复杂。前人的研究表明绿梁山石榴橄榄岩存在三种不同的成因方式,对应分类模型中的:1)D亚类橄榄岩(阿拉斯加型岩浆岩堆晶体);2)壳源俯冲带型石榴橄榄岩;3)A亚类来自克拉通岩石圈地幔的太古代石榴橄榄岩。检验结果表明,该分类模型能较好的解释斯堪的纳维亚加里东期造山带中的石榴橄榄岩的出露规律,岩石学及矿物学特征及不同期次矿物之间的年代学关系,但对于我国绿梁山石榴橄榄岩的成因分类仍需进一步研究。假设该分类模型能适用于大多研究程度较高的造山带石榴橄榄岩,起到决定性作用的两个分类参数为地幔楔形成初期的平均温度(T)及造山带岩石圈地幔的厚度(P)。熔融作用发生的时间及深度同样是区分不同类型石榴橄榄岩的重要因素。     

Petrochemical constraints for dual origin of garnet peridotites from the Dabie-Sulu UHP terrane, eastern-central China

Garnet peridotites occur as lenses, blocks or layers within granulite–amphibolite facies gneiss in the Dabie-Sulu ultra-high-pressure (UHP) terrane and contain coesite-bearing eclogite. Two distinct types of garnet peridotite were identified based on mode of occurrence and petrochemical characteristics. Type A mantle-derived peridotites originated from either: (1) the mantle wedge above a subduction zone, (2) the footwall mantle of the subducted slab, or (3) were ancient mantle fragments emplaced at crustal depths prior to UHP metamorphism, whereas type B crustal peridotite and pyroxenite are a portion of mafic–ultramafic complexes that were intruded into the continental crust as magmas prior to subduction. Most type A peridotites were derived from a depleted mantle and exhibit petrochemical characteristics of mantle rocks; however, Sr and Nd isotope compositions of some peridotites have been modified by crustal contamination during subduction and/or exhumation. Type B peridotite and pyroxenite show cumulate structure, and some have experienced crustal metasomatism and contamination documented by high ⁸⁷Sr/⁸⁶Sr ratios (0.707–0.708), low ε_Nd( t ) values (−6 to −9) and low δ¹⁸O values of minerals (+2.92 to +4.52). Garnet peridotites of both types experienced multi-stage recrystallization; some of them record prograde histories. High- P–T  estimates (760–970 °C and 4.0–6.5±0.2 GPa) of peak metamorphism indicate that both mantle-derived and crustal ultramafic rocks were subducted to profound depths >100 km (the deepest may be ≥180–200 km) and experienced UHP metamorphism in a subduction zone with an extremely low geothermal gradient of <5 °C km⁻¹.     

Remnants of premetamorphic fluid and oxygen isotopic signatures in eclogites and garnet clinopyroxenite from the Dabie-Sulu terranes, eastern China

A combined oxygen‐isotope and fluid‐inclusion study has been carried out on high‐ and ultrahigh‐pressure metamorphic (HP/UHPM) eclogites and garnet clinopyroxenite from the Dabie‐Sulu terranes in eastern China. Coesite‐bearing eclogites/garnet clinopyroxenite and quartz eclogites have a wide range in whole‐rock δ¹⁸O_VSMOW, from 0 to 11‰. The high‐T oxygen‐isotope fractionations preserved between quartz and garnet preclude significant retrograde isotope exchange during exhumation, and the wide range in whole‐rock oxygen‐isotope composition is thought to be a presubduction signature of the precursors. Aqueous fluids with variable salinities and gas species (N₂‐, CO₂‐, or CH₄‐rich), are trapped as primary inclusions in garnet, omphacite and epidote, and in quartz blebs enclosed within eclogitic minerals. In high‐δ¹⁸O HP/UHPM rocks from Hujialin and Shima, high‐salinity brine and/or N₂ inclusions occur in garnet porphyroblasts, which also contain inclusions of coesite, Cl‐rich blue amphibole and dolomite. In contrast, in low‐δ¹⁸O eclogites from Qinglongshan and Huangzhen, the Cl concentrations in amphibole are very low, < 0.2 wt.%, and low‐salinity aqueous inclusions occur in quartz inclusions in epidote porphyroblasts and in epidote cores. These low‐salinity fluid inclusions are believed to be remnants of meteoric water, although the fluid composition was modified during pre‐ and syn‐peak HP/UHPM. Eclogites at Houshuichegou and Hetang contain CH₄‐rich fluid inclusions, coexisting with high‐salinity brine inclusions. Methane was probably formed under the influence of CO₂‐rich aqueous fluids during serpentinisation of mantle‐derived peridotites prior to or during plate subduction. Remnants of premetamorphic low‐ to high‐salinity aqueous fluid with minor N₂ and/or other gas species preserved in the Dabie‐Sulu HP/UHPM eclogites and garnet clinopyroxenite indicate a great diversity of initial fluid composition in the precursors, implying very limited fluid–rock interaction during syn‐ and post‐peak HP/UHPM.     

苏鲁-大别山超高压变质带迟家店和碧溪岭石榴二辉橄榄岩橄榄石组构

大别山碧溪岭和山东荣成分别发育壳源和幔源的石榴二辉橄榄岩.它们在扬子板块向华北板块的俯冲过程中与俯冲板片一起经历了超高压变质作用.这两种原岩来源不同的石榴橄榄岩中的橄榄石具有相似的结晶学优选方位（LPO）：[100]轴主极密垂直于面理面,[010]轴主极密平行于线理,这种橄榄石结晶学优选方位明显不同于高温地幔橄榄岩包体中的橄榄石组构,也不同于最近在超高压变质地体中发现的水导致的橄榄石组构.我们认为碧溪岭和荣成石榴二辉橄榄岩中的这种橄榄石组构可能是在相对较干的超高压变质条件下形成的.本研究为大陆深俯冲超高压变质石榴橄榄岩橄榄石组构特征提供了第一手资料.     

Deep subduction of mantle-derived garnet peridotites from the Su-Lu UHP metamorphic terrane in China

Garnet peridotites from the southern Su‐Lu ultra‐high‐pressure metamorphic (UHPM) terrane, eastern China, contain porphyroblastic garnet with aligned inclusions comprising a low‐P–T mineral assemblage (chlorite, hornblende, Na‐gedrite, Na‐phlogopite, talc, spinel and pyrite). Orthopyroxene porphyroblasts show fine exsolution lamellae of clinopyroxene and minor chromite. A clinopyroxene inclusion in garnet shows some orthopyroxene exsolution lamellae. Both the rims of porphyroblastic pyroxene and garnet and the matrix pyroxene and garnet crystallized at the expense of olivine. This is interpreted as a result of metasomatism of the peridotites by an SiO₂‐rich melt at UHP conditions. A chromian garnet further overgrew on the rims of the garnet. The X_Mg values (Mg/(Mg+Fe)) of porphyroblastic garnet decrease from core to rim and vary in different peridotite samples, while the compositions of both the porphyroblastic and the matrix pyroxene are similar in terms of Ca–Mg–Fe. The Mg‐rich cores of porphyroblastic garnet and orthopyroxene record high temperatures and pressures (c. 1000 °C, ≥5.1 GPa), whereas the matrix minerals, including the rims of porphyroblasts, record much lower P–T (c. 4.2 GPa, c. 760 °C). Sm–Nd data give apparent isochron ages of c. 380 Ma and negative ε_Nd(0) values (c.?9). These dates are considered meaningless due to isotopic disequilibrium between garnet cores and the rest of the rocks. The isotopic disequilibrium was probably caused by metasomatism of the peridotites by melt/fluids derived from the coevally subducted crustal materials. On the other hand, the Rb–Sr isotopic systems of phlogopite and clinopyroxene appear to have reached equilibrium and record a cooling age of c. 205 Ma. It is suggested that the garnet peridotites were originally emplaced into a low‐P–T environment prior to the c. 220 Ma continental collision, during which they were subducted together with crustal rocks to mantle depth and subjected to UHP metamorphism. An important corollary is that at least some of the coevally subducted crustal rocks in the Su‐Lu terrane have been subjected to peak metamorphism at P–T conditions much higher than presently estimated (≥2.7 GPa, ≤800 °C).     

南苏鲁超高压变质带东海地区富钛榴辉岩及金红石矿的成因

苏鲁超高压变质带南部的东海地区有富Fe—Ti的钛铁矿榴辉岩和富Ti的金红石榴辉岩。富Fe—Ti榴辉岩的次要矿物主要由钛铁矿和钛磁铁矿组成,可舍少量金红石,具有很低的Si02（38．0％-42．3％）、Na20＋K20（0．48％～2．13％）和Zr、Nb、Ta、Ba、1Kb、REE含量,很高的FeO（18．24％-25．33％）、V和Co含量,并具有不同程度的LREE亏损、明显的正Eu异常;富Ti金红石榴辉岩舍有丰富的金红石和磷灰石,SiO2含量范围（38．0％-54．8％）较宽,FeO含量较低,P2O5含量较高（可达4．1％）,而X-TiO2与P205含量具正相关性。相对于原始地慢岩．富Ti金红石榴辉岩具有Rb、Th、K、Nb、Pr、Nd、Eu、Ti、Lu的负异常和Ba、Sr、Zr的正异常．并具相对较高的IKEE含量,LREE富集和HREE亏损的1KEE分配型式。岩石学和地球化学特征揭示,Fe—Ti榴辉岩的原岩是变质的Fe—Ti辉长岩,是基性岩浆强烈分离结晶作用形成的超基性-基性-中酸性层状侵入体的特征组成部分。     

羌塘地区榴辉岩中矿物出溶体及其成因机制探讨

西藏羌塘地区榴辉岩石榴子石和磷灰石中均发育矿物出溶体,结合电子探针和扫描电镜分析及能谱分析,确定了石榴子石中的出溶体有金红石、石英和角闪石,指示其可能经历了高压/超高压变质作用。本研究在磷灰石中发现了金红石出溶,并认为其可能是在高压/超高压条件下元素相互置换的结果,置换方式为Ti~(4+)(Fe~(2+)、Si~(4+))=2Ca~(2+),这些出溶体的形成为榴辉岩曾经历高压/超高压变质作用提供了矿物学证据。     

The Luliangshan garnet peridotite massif of the North Qaidam UHPM belt, NW China - a review of its origin and metamorphic evolution

The Luliangshan garnet peridotite massif is an ultramafic complex in the North Qaidam UHPM belt, NW China. The strongly layered complex comprising garnet-bearing dunite, garnet-harzburgite, garnet-lherzolite and garnet-pyroxenite and garnet-free dunite, occurs together with eclogite embedded in various continental gneisses. The geological setting, the internal structure, bulk-composition, rare earth elements, isotopic and mineral composition data show that the garnet peridotite derives from a middle Ordovician Alaskan-type layered sub-arc cumulate intrusion of ascending mantle wedge melts. An abyssal peridotite protolith can be excluded. During the Ordovician-Silurian continental collision, thickening and foundering, the Luliangshan peridotite complex was exposed to ultrahigh pressures (UHP) reaching 5.5 GPa possibly >6 GPa at temperatures of 900 °C (perhaps up to 1000 °C) corresponding to a depth of ∼200 km. The extreme pressure conditions have been derived from thermobarometry using mineral compositions of the garnet peridotite assemblages, but they are supported by a wealth of decompression-induced mineral exsolutions in UHP minerals and by diamond inclusion in zircon. The Luliangshan garnet peridotite has experienced four stages of retrograde overprint during exhumation that lasted into the Devonian: (i) decompression-induced unmixing of the UHP minerals; (ii) garnet kelyphitisation; (iii) amphibole overprinting and (iv) serpentinization. Hydrous minerals occurring within peak metamorphic assemblage represent pseudo-inclusions, that is reaction products of reactions related to various stages of decompression and cooling rather than prograde inclusions during porphyroblast growth.     

On the mechanism of resorption zoning in metamorphic garnet

Abstract An analytical electron microscope study of almandine garnet from a metamorphosed Al–Fe‐rich rock revealed detailed composition profiles and defect microstructures of resorption zoning along fluid‐infiltrated veins and even into the garnet/ilmenite (inclusion) interface. This indicates a limited volume diffusion for the cations in substitution (mainly Ca and Fe) and an interface‐controlled partition for the extension of a composition‐invariant margin. A corrugated interface between the Ca‐rich margin/zone and the almandine garnet core is characterized by dislocation arrays and recovery texture further suggesting a resorption process facilitated by diffusion‐induced recrystallization, diffusion‐induced dislocation migration and diffusion–induced grain boundary migration. Integrated microstructural and chemical studies are essential for understanding the underlying mechanisms of processes such as garnet zoning and its modification. Without this understanding, it will not be possible to reliably use garnet compositions for thermobarometry and other applications that rely on garnet chemical information.     

Deformation-enhanced metamorphic reactions and the rheology of high-pressure shear zones, Western Gneiss Region, Norway

Microstructural and petrological analysis of samples with increasing strain in high‐pressure (HP) shear zones from the Haram garnet corona gabbro give insights into the deformation mechanisms of minerals, rheological properties of the shear zone and the role of deformation in enhancing metamorphic reactions. Scanning electron microscopy with electron backscattering diffraction (SEM–EBSD), compositional mapping and petrographic analysis were used to evaluate the nature of deformation in both reactants and products associated with eclogitization. Plagioclase with a shape‐preferred orientation that occurs in the interior part of layers in the mylonitic sample deformed by intracrystalline glide on the (0 0 1)[1 0 0] slip system. In omphacite, crystallographic preferred orientations indicate slip on (1 0 0)[0 0 1] and (1 1 0)[0 0 1] during deformation. Fine‐grained garnet deformed by diffusion creep and grain‐boundary sliding. Ilmenite deformed by dislocation glide on the basal and, at higher strains, prism planes in the a direction. Relationships among the minerals present and petrological analysis indicate that deformation and metamorphism in the shear zones began at 500–650 °C and 0.5–1.4 GPa and continued during prograde metamorphism to ultra‐high‐pressure (UHP) conditions. Both products and reactants show evidence of syn‐ and post‐kinematic growth indicating that prograde reactions continued after strain was partitioned away. The restriction of post‐kinematic growth to narrow regions at the interface of garnet and plagioclase and preservation of earlier syn‐kinematic microstructures in older parts layers that were involved in reactions during deformation show that diffusion distances were significantly shortened when strain was partitioned away, demonstrating that deformation played an important role in enhancing metamorphic reactions. Two important consequences of deformation observed in these shear zones are: (i) the homogenization of chemical composition gradients occurred by mixing and grain‐boundary migration and (ii) composition changes in zoned metamorphic garnet by lengthening diffusion distances. The application of experimental flow laws to the main phases present in nearly monomineralic layers yield upper limits for stresses of 100–150 MPa and lower limits for strain rates of 10^?12 to 10^?13 s^?1 as deformation conditions for the shear zones in the Haram gabbro that were produced during subduction of the Baltica craton and resulted in the production of HP and UHP metamorphic rocks.     

山东荣成高钙石榴辉石岩的地球化学特征及其成因

在苏鲁超高压变质带荣成蓝晶石榴辉岩中, 发现一具有特殊结构和地球化学特征的石榴辉石岩.该石榴辉石岩以包裹体的形式赋存于强烈退变的蓝晶石榴辉岩中.岩相学观测表明该岩石的主要结构为石榴石呈薄带、项链状相互连接的网状结构, 分割由辉石和石榴石、钛铁氧化物等出溶片晶组成的区域.全岩地球化学分析表明, 和邻近的蓝晶石榴辉岩相比, 该岩石具有(1) 相对低的SiO₂ (42.5%~43.1%), 异常高的CaO (21.4%~21.9%)和CaO/Al₂O₃比值(1.46~1.64); (2) 较高的TiO₂ (1.77%~1.89%)、V (359~419μg/g)、Nb (~8μg/g)、Y (17.7~23.1μg/g)和Zr (~150μg/g); (3) LREE富集和微弱的Eu负异常; (4) 较低的Cr、Ni和Co.上述地球化学特征表明荣成辉石岩的原岩形成于经过橄榄石分离结晶作用的超基性岩浆或经历了Na和K亏损过程的高钙基性岩浆.这2种过程都要求较高的温压条件, 压力 > 15×105kPa, 温度 > 1300 ℃, 这和荣成辉石岩的原岩的初始稳定条件的温压估算相一致.该研究结果表明在苏鲁超高压变质带中, 一些超高压变质岩的母岩形成于高温部分熔融或岩浆演化作用, 明显不同于大多数榴辉岩或片麻岩的原岩形成环境.      

Jadeite–garnet glaucophane schists in the Bizan area,Sambagawa metamorphic belt,eastern Shikoku,Japan: significance and extent of eclogite facies metamorphism

Eclogite facies metamorphic rocks have been discovered from the Bizan area of eastern Shikoku, Sambagawa metamorphic belt. The eclogitic jadeite–garnet glaucophane schists occur as lenticular or sheet‐like bodies in the pelitic schist matrix, with the peak mineral assemblage of garnet + glaucophane + jadeite + phengite + quartz. The jadeitic clinopyroxene (X_Jd 0.46–0.75) is found exclusively as inclusions in porphyroblastic garnet. The eclogite metamorphism is characterized by prograde development from epidote–blueschist to eclogite facies. Metamorphic P–T conditions estimated using pseudosection modelling are 580–600 °C and 18–20 kbar for eclogite facies. Compared with common mafic eclogites, the jadeite–garnet glaucophane schists have low CaO (4.4–4.5 wt%) and MgO (2.1–2.3 wt%) bulk‐rock compositions. The P–T– pseudosections show that low X_Ca bulk‐rock compositions favour the appearance of jadeite instead of omphacite under eclogite facies conditions. This is a unique example of low X_Ca bulk‐rock composition triggered to form jadeite at eclogite facies conditions. Two significant types of eclogitic metamorphism have been distinguished in the Sambagawa metamorphic belt, that is, a low‐T type and subsequent high‐T type eclogitic metamorphic events. The jadeite–garnet glaucophane schists experienced low‐T type eclogite facies metamorphism, and the P–T path is similar to lawsonite‐bearing eclogites recently reported from the Kotsu area in eastern Shikoku. During subduction of the oceanic plate (Izanagi plate), the hangingwall cooled gradually, and the geothermal gradient along the subduction zone progressively decreased and formed low‐T type eclogitic metamorphic rocks. A subsequent warm subduction event associated with an approaching spreading ridge caused the high‐T type eclogitic metamorphism within a single subduction zone.     

拉萨地块林芝杂岩体含十字石石榴角闪岩的岩石学和变质过程研究

在拉萨地块林芝杂岩体中新发现的石榴角闪岩矿物组合为石榴子石、角闪石、十字石、绿泥石、斜长石、钠云母以及少量的钛铁矿和磷灰石。石榴角闪岩中石榴石核部富锰(Xsps=0.12~0.15)贫铁(Xalm=0.45~0.50)而石榴子石边部相对贫锰(Xsps=0.01~0.03)富铁(Xalm=0.60~0.65),表明石榴子石的核部和边部分别形成于变质作用两个不同阶段。从核部到边部,镁铝榴石升高而钙铝榴石降低,表现为进变质环带特征,这表明石榴子石核部形成于进变质过程。生长在不同的变质阶段的角闪石具有不同的成分特征,作为变质基性岩中罕见的富铝矿物,十字石的结构特征记录了不同变质阶段的信息,结合石榴石的成分和结构特征,为相平衡模拟研究其P-T演化过程提供了可能。我们利用Perplex相图模拟软件在Mn-NCKMASHO体系中模拟出该石榴角闪岩的视剖面图,利用石榴子石边部镁铝榴石和钙铝榴石含量等值线确定出石榴角闪岩峰期温压为:610~630oC,12×105~13×105k Pa,对应峰期矿物组合为石榴子石,角闪石,十字石和白云母。同时结合十字石保存的退变信息得到该石榴角闪岩经历了一个顺时针的变质演化轨迹。     

A recalibration of the garnet-olivine geothermometer and a new geobarometer for garnet peridotites and garnet-olivine-plagioclase-bearing granulites

The garnet-olivine Fe-Mg exchange geothermometer and the garnet-olivine-plagioclase geobarometer have been simultaneously calibrated using reversed experimental data based on the model reactions and between 900 and 1500 °C at 9.1–95.0 kbar and between 4.7 and 7.0 kbar at 750–1050 °C, respectively. The resulting garnet-olivine thermometer reproduces experimental temperatures mostly within ±75 °C and the garnet-olivine-plagioclase barometer reproduces experimental pressures well within ±0.19 kbar. These new thermobarometers use the same garnet and olivine activity models and are thermodynamically consistent. Application of these thermobarometers to garnet peridotites from mantle xenoliths, orogenic garnet peridotites over the world and the Adirondack olivine-bearing metagabbros yielded reasonable P–T results. The present garnet-olivine thermometer can be used to measure medium-high-grade to ultrahigh-grade, low-pressure to ultrahigh–high-pressure garnet peridotites and metagabbros, whereas the garnet-olivine-plagioclase barometer has limited application to garnet-olivine-plagioclase-bearing granulites.     

A TEM study of the oriented orthopyroxene and forsterite inclusions in garnet from Otrøy garnet peridotite,WGR, Norway: new insights on crystallographic characteristics and growth energetics of exsolved pyroxene in relict majoritic garnet

Regularly oriented orthopyroxene (opx) and forsterite (fo) inclusions occur as opx + rutile (rt) or fo + rt inclusion domains in garnet (grt) from Otrøy peridotite. Electron diffraction characterization shows that forsterite inclusions do not have any specific crystallographic orientation relationships (COR) with the garnet host. In contrast, orthopyroxene inclusions have two sets of COR, that is, COR‐I: <111>_grt//<001>_opx and {110}_grt～//～{100}_opx (～13° off) and COR‐II: <111>_grt//<011>_opx and {110}_grt～//～{100}_opx (～14° off), in four garnet grains analysed. Both variants of orthopyroxene have a blade‐like habit with one pair of broad crystal faces parallel/sub‐parallel to {110}_grt plane and the long axis of the crystal, <001>_opx for COR‐I and <011>_opx for COR‐II, along <111>_grt direction. Whereas the lack of specific COR between forsterite and garnet, along with the presence of abundant infiltrating trails/veinlets decorated by fo + rt at garnet edges, provide compelling evidence for the formation of forsterite inclusions in garnet through the sequential cleaving–infiltrating–precipitating–healing process at low temperatures, the origin of the epitaxial orthopyroxene inclusions in garnet is not so obvious. In this connection, the reported COR, the crystal habit and the crystal growth energetics of the exsolved orthopyroxene in relict majoritic garnet were reviewed/clarified. The exsolved orthopyroxene in a relict majoritic garnet follows COR‐III: {112}_grt//{100}_opx and <111>_grt//<001>_opx. Based on the detailed trace analysis on published SEM images, these exsolved orthopyroxene inclusions are shown to have the crystal habit with one pair of broad crystal faces parallel to {112}_grt//{100}_opx and the long crystal axis along <111>_grt//<001>_opx. Such a crystal habit can be rationalized by the differences in oxygen sub‐lattices of both structures and represents the energetically favoured crystal shape of orthopyroxene inclusions in garnet formed by solid‐state exsolution mechanism. Considering the very different COR, crystal habit, as well as crystal growth direction, the orthopyroxene inclusions in garnet of the present sample most likely had been formed by mechanism(s) other than solid‐state exsolution, regardless of their regularly oriented appearance in garnet and the COR specification between orthopyroxene and garnet. In fact, the crystallographic characteristics of orthopyroxene and the similar chemical compositions of garnet at opx + rt inclusion domains, fo + rt inclusion domains/trails and garnet rim suggest that the orthopyroxene inclusions in the garnet are most likely formed by similar cleaving‐infiltration process as forsterite inclusions, though probably at an earlier stage of metamorphism. This work demonstrates that the oriented inclusions in host minerals, with or without specific COR, can arise from mechanism(s) other than solid‐state exsolution. Caution is thus needed in the interpretation of such COR, so that an erroneous identification of exhumation from UHP depths would not be made.     

大别—苏鲁区UHP变质岩构造学及流变学演化

在大别—苏鲁区的30个关键位置,对UHP/HP变质岩进行详细构造解析、大比例尺(1∶10000)制图并在区域尺度上进行观察和对比,以便揭示它们的构造几何学、变形条件和流变学演化。初步的研究结果指出,广泛出露的UHP/HP榴辉岩相岩石形成一个巨大的UHP/HP变质带,提供了一个观察中朝与扬子克拉通之间三叠纪大陆深俯冲-碰撞带过程的窗口。观察的显微构造及组构指出,UHP/HP变质带内岩石变形机制,无论是在榴辉岩相阶段还是在榴辉岩相后阶段,都是以塑性流变为主,其力学行为和组构特征都受组成矿物的强度、强度差等流变学特征,以及变形物理环境如压力、温度、应变速率、差异应力和流体含量等的制约。在俯冲/碰撞带内的变形分解作用于岩石圈不同层次及不同的构造阶段都曾发生,而且,在不同尺度上,应变局部化形成具高应变的剪切带网络,且一般显示典型的布丁-基质或碎斑-基质构造及流变学型式。根据构造、岩石、变质作用及地质年代学资料,借助于岩石圈流变学基本原理,提出一个大别—苏鲁区UHP/HP变质岩石流变学演化的工作模式,它涉及早期扬子与中朝克拉通间三叠纪(~250~230Ma)大陆深俯冲/碰撞、UHP/HP变质岩形成,相继深埋岩石的多期折返。特别强调UHP/HP岩石向地壳表层的折返,主要是构造过程,地面侵蚀作用是次要的。