Origin of the fumarolic fluids of Vulcano Island,Italy and implications for volcanic surveillance

Variations in D and ¹⁸O values with H₂O contents and outlet temperatures indicate that the fumaroles of La Fossa crater have discharged mixtures of magmatic water and marine hydrothermal water, since 1979. The contribution of meteoric water was low in the period 1979–1982 and very low afterwards. The ¹⁸O values of the marine-hydrothermal component of +5 to +7.2 are due to isotopic exchange with the ¹⁸O-rich silicates of the rocks under high-temperature and low-permeability conditions. The ¹⁸O value of the magmatic end-member is generally +3.5 to +4.3, although values as high as +5.5 to +6.5 were reached in the summer of 1988, when magma degassing appears to have extended into the core of the magma body. The D values of the end-member were close to -20, typical of andesitic waters. Both the isotopic values and chemical data strongly support a dry model, consisting of a central magmatic gas column and a surrounding hydrothermal envelope, in which marine hydrothermal brines move along limited fracture zones to undergo total evaporation on approaching the conduits of magmatic fluids. The vents at the eastern and western boundaries of the fumarolic field are fed by fluids whose pressure is governed by the coexistence of vapor, liquid and halite, giving rise to a high risk of phreato magmatic explosions, should magma penetrate into these wet environments. Most La Fossa eruptions were triggered by an initial hydrothermal blast and continued with a series of phreatomagmatic explosions. The fluids discharged by the Forgia Vecchia fumaroles are mixed with meteoric water, which is largely evaporated, although subordinate loss of condensed steam may be responsible for scrubbing most of the acidic gas species. The temperatures and pressures, and the risk of a sudden pressure increase, are low. A boiling hydrothermal aquifer at 230° C is present underneath the Baia di Levante beach. This area has a minor risk of hydrothermal explosions.     

Comparison between Pollutant Concentration in the Samples of Fog and Rime Water Collected at Mt. Milešovka

The article aims at showing the differences in concentration of pollutants that are contained in the samples of fog and/or low cloud water in comparison with the water from rime. The results follow from the fog and rime measurements made at Mt. Mileovka (eské Stedohoí Mountains). They are compared with the results of other studies that also report the differences in fog and rime chemistry.     

The gross features of the lithosphere-asthenosphere system in Europe from seismic surface waves and body waves

Long-period recordings of dispersive Rayleigh waves along numerous station lines, or profiles, in Europe have for the first time permitted a uniform inversion of these observations based on a new method of phase velocity regionalization.Regional dispersion relations obtained by this method have then been subjected to a complete inversion procedure commonly known as the hedgehog method. The results are presented in a map outlining the thickness of the lower lithosphere (lid) and the shear (S) velocities in both the lid and the asthenosphere channel.A comparison of these results with the minimum compressional (P) wave velocities in the asthenosphere and their corresponding depths provides an estimate of theV _p /V _s ratio for the asthenosphere in the European area.Contribution No. 314, Institute of Geophysics, ETH-Zürich, Switzerland.     

A method of searching for radial velocity anomalies in the lower mantle using interfering signals

Radial velocity anomalies in the lower mantle that give rise to triplications in the travel-time curve for short-periodP waves will produce arrivals havingdT/d values that differe by roughly 0.2–0.5 s/deg. The first two arrivals associated with such triplications will be separated by less than one second over a distance range of 4°–10° they may not, therefore, be separable visually on single seismograms, so that their presence can only be inferred from some measurable property that depends on their mutual interference. If there are lateral variations in the regions of anomalous velocity gradients, the interfering signals will also have different azimuths of arrival. Using two synthetic wavelets we have investigated the effect of interference on bothdT/d and azimuth measurements at the Yellowknife Array. We found that if the interfering pulses have a dominant frequencyv, there is a range of time separations (0.30/v0.55/v) over which the measureddT/d and azimuth values may fluctuate by much more than the differences indT/d and azimuth between the interfering signals. We have evaluated the following empirically defined functions for three different primary signals, and for three different relative amplitudes of the interfering signals:f (t), the drift function, which expresses how the measured slownesses,p, and azimuths, , differ from the slownesses and azimuths of the primary wavelets; f(), the range function, which describes the behaviour of the upper and lower bounds ofp and as a function of the difference in arrival times of the signals, andf , studied the properties of these functions, and have outlined how these properties provide criteria based on the numerical and statistical characteristics of the arrival vectors, and on the waveform of the signal that will enable small radial velocity anomalies to be more clearly delineated.Contribution No. 863 from the Earth Physics Branch.     

Channel overflows of the Pōhue Bay flow,Mauna Loa,Hawai'i: examples of the contrast between surface and interior lava

A number of overflows from a large lava channel and tube system on the southwest rift zone of Mauna Loa were studied. Initial overflows were very low viscosity gas-rich phoehoe evidenced by flow-unit aspect ratios and vesicle sizes and contents. Calculated volumetric flow-rates in the channel range between 80 and 890 m³/s, and those of the overflows between 35 and 110 m³/s. After traveling tens to hundreds of meters the tops of these sheet-like overflows were disrupted into a surface composed of clinker and phoehoe fragments. After these 'a' overflows came to rest, lava from the interiors was able to break out on to the surface as phoehoe. The surface structure of a lava flow records the interaction between the differential shear rate (usually correlated with the volumetric flow-rate) and viscosity-induced resistance to flow. However, the interior of a flow, being better insulated, may react differently or record a later set of emplacement conditions. Clefts of toothpaste lava occurring within fields of clinker on proximal-type 'a' flows also record different shear rates during different times of flow emplacement. The interplay between viscosity and shear rate determines the final morphological lava type, and although no specific portion of lava ever makes a transition from 'a' back to phoehoe, parts of a flow can appear to do so.     

A Local Least-Squares Modification of Stokes’ Formula

The combination of Stokes formula and an Earth Gravity Model (EGM) for geoid determination has become a standard procedure. However, the way of modifying Stokes formula vary from author to author, and numerous methods of modification exist. Most methods are deterministic, with the primary goal of reducing the truncation bias committed by limiting the area of Stokes integration around the computation point, but there are also some stochastic methods with the explicit goal to reduce the global mean square error of the geoid height estimator stemming from the truncation bias as well as the random errors of the EGM and the gravity data. The latter estimators are thus, at least from a theoretical point of view, optimal in a global mean sense, but in a local sense they may be far from optimality.Here we take advantage of the error variance-covariance matrices of the EGM and the terrestrial gravity data to derive the modification parameters of Stokes kernel in a local least-squares sense. The solution is given for the unbiased type of modification of Stokes formula of Sjöberg (1991).     

Community preparedness for lava flows from Mauna Loa and Hualālai volcanoes,Kona, Hawai‘i

Lava flows from Mauna Loa and Huallai volcanoes are a major volcanic hazard that could impact the western portion of the island of Hawaii (e.g., Kona). The most recent eruptions of these two volcanoes to affect Kona occurred in a.d. 1950 and ca. 1800, respectively. In contrast, in eastern Hawaii, eruptions of neighboring Klauea volcano have occurred frequently since 1955, and therefore have been the focus for hazard mitigation. Official preparedness and response measures are therefore modeled on typical eruptions of Klauea.The combinations of short-lived precursory activity (e.g., volcanic tremor) at Mauna Loa, the potential for fast-moving lava flows, and the proximity of Kona communities to potential vents represent significant emergency management concerns in Kona. Less is known about past eruptions of Huallai, but similar concerns exist. Future lava flows present an increased threat to personal safety because of the short times that may be available for responding.Mitigation must address not only the specific characteristics of volcanic hazards in Kona, but also the manner in which the hazards relate to the communities likely to be affected. This paper describes the first steps in developing effective mitigation plans: measuring the current state of peoples knowledge of eruption parameters and the implications for their safety. We present results of a questionnaire survey administered to 462 high school students and adults in Kona. The rationale for this study was the long lapsed time since the last Kona eruption, and the high population growth and expansion of infrastructure over this time interval. Anticipated future growth in social and economic infrastructure in this area provides additional justification for this work.The residents of Kona have received little or no specific information about how to react to future volcanic eruptions or warnings, and short-term preparedness levels are low. Respondents appear uncertain about how to respond to threatening lava flows and overestimate the minimum time available to react, suggesting that personal risk levels are unnecessarily high. A successful volcanic warning plan in Kona must be tailored to meet the unique situation there.     

Integral Equations for Kinematic Dynamo Models

A new technique for the treatment of the kinematic dynamo problem is presented. The method is applicable when the dynamo is surrounded by a medium of finite conductivity and is based on a reformulation of the induction equation and boundary conditions at infinity into an integral equation. We show that the integral operator involved here is compact in the case of homogeneous conductivity, which is important for both mathematical and numerical treatment. A lower bound for the norm of then yields a necessary condition for the generation of magnetic fields by kinematic dynamos. Numerical results are presented for some simple ²-dynamo models. The far-field asymptotics for stationary and time-dependent field modes are discussed.     

Tectonosedimentary Evolution of the Cheb Basin (NW Bohemia,Czech Republic) between Late Oligocene and Pliocene: A Preliminary Note

A working model of tectono-sedimentary evolution is proposed for the Cheb Basin, a polyhistory sedimentary basin formed between the late Oligocene and Pliocene by reactivation of basement fracture systems in the northwestern part of the Bohemian Massif. The basin is located at the intersection of the Ohe (Eger) Graben structural domain, characterized by dominance of NE-striking graben systems in present-day geology, and the NW-striking Cheb-Domalice Graben, a major strike-slip – dominated structure in Western Bohemia. The first significant depositional episode in the Cheb Basin coincides with the deposition of late Oligocene-Miocene clastics in the whole extensional system of the Ohe Graben, controlled by E-W – trending depocenters. The main structural feature of the Cheb Basin region at that time was a palaeohigh caused by a NW- trending accommodation zone separating minor E-W – trending depocentres. The second, late Pliocene, episode of sedimentation occurred under a very different kinematic regime than the Oligo-Miocene rift basin evolution. During this time, the present-day structure of the Cheb Basin and the Cheb-Domalice Graben formed as a consequence of sinistral displacement on the Mariánské Lázn Fault Zone. Reactivation of this strike-slip fault zone led to the formation of a horsetail splay of oblique-extensional faults at the northern termination of the Mariánské Lázn Fault Zone, which contained the present-day Cheb Basin.     

Mean Field Dynamos with Algebraic and Dynamic α-Quenchings

Calculations for mean field dynamo models (in both full spheres and spherical shells), with both algebraic and dynamic -quenchings, show qualitative as well as quantitative differences and similarities in the dynamical behaviour of these models. We summarise and enhance recent results with extra examples. Overall, the effect of using a dynamic appears to be complicated and is affected by the region of parameter space examined.     

Tilt Observations in the Normal Mode Frequency Band at the Geodynamic Observatory Cueva de los Verdes,Lanzarote

We have conducted observations with the aid of a seismo-tiltmeter station, which is based on the Ostrovsky pendulum and installed at the Geodynamic Observatory Cueva de los Verdes at Lanzarote Island since 1995. In this station the signal is separated into two frequency bands – tidal tilts (from 0 to 5 mHz) and ground oscillations in the frequency range of free Earths normal modes (from 0.2 to 5 mHz). The later band, called accelerometer channel, has additional amplification. We analyzed the background records in the frequency range of Earths free oscillations from August 2000 to September 2001, as well as, Earths normal modes after strong earthquakes. We found several distinctive persistent peaks in the spectra of background oscillations. Both amplitudes of distinguished peaks and noises have seasonal variations. We found that spectra of background oscillations are different in the frequency interval between 1.4 and 2.5 mHz for North- South and East-West components.     

Lagrangian Solution of Dynamo Equations and Path Integrals

We discuss an explicit solution of the Cauchy problem for induction equation and suggest its generalization for equations of ²-dynamo. These solutions are based on concepts of multiplicative, Wiener path, and stochastic integrals. Obtained explicit solution can be useful as a tool in investigations of a dynamo with fluctuating helicity.     

A statistical study of the upstream intermediate ion boundary in the Earth’s foreshock

A statistical investigation of the location of onset of intermediate and gyrating ion populations in the Earths foreshock is presented based on Fixed Voltage Analyzer data from ISEE 1. This study reveals the existence of a spatial boundary for intermediate and gyrating ion populations that coincides with the reported ULF wave boundary. This boundary position in the Earths foreshock depends strongly upon the magnetic cone angle _BX and appears well defined for relatively large cone angles, though not for small cone angles. As reported in a previous study of the ULF wave boundary, the position of the intermediate-gyrating ion boundary is not compatible with a fixed growth rate of the waves resulting from the interaction between a uniform beam and the ambient plasma. The present work examines the momentum associated with protons which travel along this boundary, and we show that the variation of the boundary position (or equivalently, the associated particle momentum) with the cone angle is related to classical acceleration mechanisms at the bow shock surface. The same functional behavior as a function of the cone angle is obtained for the momentum predicted by an acceleration model and for the particle momentum associated with the boundary. However, the model predicts systematically larger values of the momentum than the observation related values by a constant amount; we suggest that this difference may be due to some momentum exchange between the incident solar-wind population and the backstreaming particles through a wave-particle interaction resulting from a beam plasma instability.     

Critical remarks on the use of medieval eclipse records for the determination of long-term changes in the Earth's rotation

The use of some Arabic medieval solar and lunar eclipse records for the determination of secular changes in the Earth's rotation is critically reviewed. The published results derived from these data suggest a non-uniform decrease in the Earth's rotation rate over the last 27 cy. There is, however, up to this day no sound physical explanation for the deduced non-tidal oscillations, with an apparent period of about 1500 yr and a semi-amplitude of some 4 ms in the l.o.d., which overlayed to a constant secular tidal change in the Earth's rotation rate produce a net non-uniform deceleration of the Earth's rotation. In this paper we discuss a set of observations, which were executed by professional Arabic astronomers. We show by our analysis the way in which the non-uniform deceleration of the Earth's rotation was constructed. A correct reading of the Arabic medieval observations shows that they do not contradict a secular constant decrease in the Earth's rotation rate of nearly -4.6 10-22 rad s-2. This value is in accordance with other similar ones derived from ancient eclipse records and from satellite tracking data.     

Quasilinear heating of electrons in the earth's plasmasphere

In the framework of a quasilinear theory we examine the interaction between thermal electrons and ion-cyclotron waves (ICW) in the outer plasmasphere of the earth. For this type of wave-particle interaction, a simplification of the quasilinear diffusion integral in a magneto-active plasma under plasmaspheric conditions is given. Under the assumption of a Maxwellian distribution of electrons we have calculated the collision frequency and the heating source as the electrons are scattered by ICW. The obtained values of intrinsic parameters of the outer plasmasphere may exceed greatly, accordingly, the Coulomb frequency of collisions and the heating source due to suprathermal electrons. ICW-heating causes the ionosphereward thermal flux to increase, and this must lead to an increase in electron temperature in lower-lying plasmaspheric regions and in the subauroral ionosphere. A quantitative estimation of the electron temperature for the hot zone, made in this paper, is consistent with available experimental data.     

Modeling Atmospheric Chemistry: Interactions between Gas-Phase Species and Liquid Cloud/Aerosol Particles

For detailed modeling of atmospheric chemistry it is necessary to consider aqueous-phase reactions in cloud droplets and deliquesced aerosol particles. Often, the gas-phase concentration is in equilibrium with the aqueous phase. Then Henrys law can be used to describe the distribution between the phases provided that the Henrys law coefficient is known. In some cases, thermodynamic equilibrium will not be reached and it is necessary to use kinetic expressions of the rates involved. These rates depend on diffusion constants, accommodation coefficients, Henrys law coefficients, particle size distributions, and several other parameters. This review describes how these processes can be treated in computer modeling and how the necessary data can be obtained. Even though it is written primarily for use in modeling atmospheric chemistry, some parts will also be useful for waste water and pesticide control and in other areas where the distribution of chemicals between the aqueous and the gas phase is important.     

A daily rainfall occurrence process

A model for the periodic (annual cycle), discrete rainfall occurrence process is presented. Using this model the probabilistic properties of the process in -day intervals can be investigated. In such an interval the rainfall occurrence process is approximated by some stationary processa _t ,tIN. The processa _t ,tIN is described by the distributions of the lengths of wet and dry sequences. It is assumed that the lengths of successive wet and dry sequences are independent. For this process the distribution of the number of wet days in -day intervals is calculated. The model is fitted to 50-year rainfall data from Wroclaw, Poland. Rainfall amounts of 0.1, 1.0 and 2.0 mm are considered as thresholds defining a wet day. To estimate the distribution of the length of wet and dry sequences the family of Pascal distribution is chosen.     

A deep geophysical study in the Baikal region

Experimental data show that in East Siberia resistivity curves, irrespective of their trends, are affected by galvanic (local) distortions. The preliminary step of the magnetotelluric data processing is to obtain a steady shape of resistivity curves reflecting a true deep section. For this purpose statistical averaging and different criteria of impedance rejecting were used. The available MTS curves were normalized by level to the global magnetovariation curves. Two-dimensional modelling was performed from several sublatitudinal profiles crossing the Baikal rift zone. Three-dimensional models based on two-dimensional modelling and on induction vector distribution have been computed via programs of M. N. Yudin. Following other researchers, two conductive layers are distinguished: i) the mid- and low crustal and ii) the mantle one, with the layer surface uplifted from 100–110 km depth in the southern Baikal rift zone to 60–70 km northeastwards along the eastern Baikal coast. The top of this layer seems to correspond to the asthenospheric roof. The asthenosphere deepening in southern BRZ is likely to be related to a decrease in the asthenospheric bulge width and an increase in the rate of lithospheric thickening with mantle degasing. The origin and evolution of the Baikal rift is considered, proceeding from the model of passive rifting with regard to a long-existing lithospheric inhomogeneity between the Siberian platform and the Sayan-Baikal folded area.     

Hawaiian magma-reservoir processes as inferred from the petrology of gabbro xenoliths in basalt,Kahoolawe Island

Gabbro xenoliths in a tholeiitic lava of Kahoolawe Island, Hawaii, a 1.3–1.4 Ma shield volcano, are 1–3 cm in size and comprised of plagioclase, clinopyroxene, and orthopyroxene. Gabbro textures — while intergranular and in part subophitic-are open due to 28–48 vol.% of vesicular basalt occupying xenolith space. Vesicles in and around the xenoliths are lined or filled with rhyolitic glass (segregation vesicles). The host is evolved tholeiite (MgO 6.1 wt%) with phenocrysts, microphenocrysts, and glomerocrysts of olivine, clinopyroxene, orthopyroxene, and plagioclase, and megacrysts (1 cm) of plagioclase. The Sr-isotope ratio of one xenolith is 0.70489; the host basalt ratio is 0.70460. Xenolith isotope composition, grain resorption, and clinopyroxene (Fs_12.5–15Wo_38–35.5), orthopyroxene (Fs_19.5–24Wo_4.1), and plagioclase (An_68–65Or_0.8–1.2) compositions suggest that these gabbros crystallized from Kahoolawe tholeiitic magma of essentially the same composition as the host basalt, but pre-dating the magma represented by the host. Based on the absence of intergranular Fe–Ti oxide phases from the pl+cpx+opx assemblages, and the open, vuggy textures, we envision crystallization on a reservoir roof at temperatures >1100°C. Entrainment of gabbro assemblages and plagioclase megacrysts from a roof mush/suspension zone occurred during convection associated with replenishment of the magma reservoir. These open-textured gabbro xenoliths are therefore not fragments of preexisting coarse-grained bodies such as sills or segregation veins. Rhyolitic glass in vesicles represents a gas-effervescence filtration process that forced fractionated residual liquids from the groundmass into voids associated with the xenoliths.Sirrine Environmental Consultants, Fremont, CA 94538