Understanding the origin and fate of nitrate in groundwater of semi-arid environments

Though nitrate enrichment in groundwater is a worldwide phenomenon and mainly related to human impact, processes leading to nitrate enrichment in scarcely inhabited semi-arid regions are not yet well understood. In those regions, elevated nitrate concentrations put additional pressure on the scarce water resources, as they pose a serious health risk. This study applies a multidisciplinary approach (hydrogeology, isotope hydrology, and geochemistry) to understand the origin and fate of nitrate in groundwater of the semi-arid Kalahari of Botswana. Our investigations suggest that nitrate in groundwater of the study area is of natural origin, leached from a pool in the unsaturated zone that was actively involved in the soil nitrogen cycle. The presence of active (minor) recharge was found, showing that nitrate may be transported into the groundwater under the present conditions. Yet, slow travel times of replenishing water and the low recharge amounts render the thick unsaturated zone into a long-term reservoir for nitrate. Being only little influenced by reactive processes, nitrate has a high persistency in the observed groundwater system. Concentration increases induced by the present land-use do not yet appear to affect the groundwater quality but may within decades.     

张掖盆地地下水硝酸盐污染与人体健康风险评价

地下水是张掖盆地的重要水资源,其硝酸盐污染尚未得到足够重视。对张掖盆地2004、2015年地下水硝酸盐浓度进行了系统分析,并采用美国环境保护署（USEPA）推荐的健康风险评价模型评估了地下水硝酸盐的健康风险。结果表明：自2004年以来张掖盆地地下水硝酸盐污染日趋严重。2015年硝酸盐浓度最高已达到283.32 mg·L^-1,17.61%的采样点硝酸盐氮浓度超过GB5749-2006《生活饮用水卫生标准》中饮用地下水限量值（20 mg·L^-1）。研究区人群经皮肤接触途径摄入硝酸盐的健康风险在可接受水平,而饮水摄入硝酸盐的健康风险较高,总风险中饮水途径引起健康风险的贡献率占99.40%,远大于皮肤接触途径。儿童经饮水摄入和皮肤接触两种途径的健康风险均显著高于成人,分别为成人的1.544倍和1.039倍。32.39%的采样点地下水硝酸盐对儿童的健康风险超出了可接受水平,14.79%的采样点地下水硝酸盐对成人的健康风险不可接受。甘州区城区、临泽县北部边缘及高台县城区周围硝酸盐浓度最高,这些区域内所有人群都面临硝酸盐引发的高健康风险,其余区域硝酸盐引发的健康风险相对较低。     

The 3D simulation and optimized management model of groundwater systems based on eco-environmental water demand

Through the study of mutual process between groundwater systems and eco-environmental water demand, the eco-environmental water demand is brought into groundwater systems model as the important water consumption item and unification of groundwater’s economic, environmental and ecological functions were taken into account. Based on eco-environmental water demand at Da’an in Jilin province, a three-dimensional simulation and optimized management model of groundwater systems was established. All water balance components of groundwater systems in 1998 and 1999 were simulated with this model and the best optimal exploitation scheme of groundwater systems in 2000 was determined, so that groundwater resource was efficiently utilized and good economic, ecologic and social benefits were obtained.     

The 3D simulation and optimized management model of groundwater systems based on eco-environmental water demand

Through the study of mutual process between groundwater systems and eco-environmental water demand, the eco-environmental water demand is brought into groundwater systems model as the important water consumption item and unification of groundwater’s economic, environmental and ecological functions were taken into account. Based on eco-environmental water demand at Da’an in Jilin province, a three-dimensional simulation and optimized management model of groundwater systems was established. All water balance components of groundwater systems in 1998 and 1999 were simulated with this model and the best optimal exploitation scheme of groundwater systems in 2000 was determined, so that groundwater resource was efficiently utilized and good economic, ecologic and social benefits were obtained.     

Sediment-chemistry response to land-use change and pollutant loading in a hypertrophic lake, southern Sweden

Responses to recent land-use changes and pollutant loading in the sediment of a hypertrophic lake in southern Sweden were studied by comparison of geochemical, pollen and magnetic records with historical land-use data. A chronology was constructed for the last two centuries by correlating changes in the pollen diagram to major events in the land-use history. Sediment accumulation was low (mean c. 0.2 g cm^-2 yr^-1) prior to 1800 AD, when less than 25% of the catchment was arable land. Reorganization of the agrarian system during the 19th century increased the annually tilled area by 300%, which accelerated soil erosion and substantially increased the accumulation of allochtonous matter in the lake. Since the turn of the century 90% of the catchment has been ploughed every year. The deposition of clastic matter in the lake has, however, decreased due to a gradual rerouting of the drainage system, which has reduced the effective catchment area by c. 85%.Authigenic vivianite (Fe3(PO4)2.8H2O) is a major P phase in the preindustrial non-sulphidic sediments, which suggests that the sediments at that time served as a fairly efficient sink for P. The arable expansion, increased manuring and, eventually, the introduction of artificial fertilizers during the 19th century led to a massive influx of nutrients, which elevated primary production in the lake. Subsequent development of bottom water anoxia around 1900, in combination with an additional pollutant burden of sulphate within the lake basin, led to major alterations of the biogeochemical cycles. The most critical change in the post-1900 sediments involved the cycling of Fe and P. The linkage between the lacustrine P and Fe cycles can explain that FeS formation was paralleled by a release of P from the sedimentary pool. This supply of P to the lake basin must have supplemented the nutrient supply by modern agriculture and contributed to recent hypertrophication. The bacterial sulphate reduction also affected the generation of alkalinity which supported a significant calcite precipitation in the post-1900 sediments.S is enriched 10-fold in the post-1900 sediments compared to preindustrial values. Along with the rise in S, soot particles derived from fossil fuel combustion appear in the sediments for the first time. Therefore, Bussj¨osj¨on is thought to be a good example of how a well-buffered, highly productive lake may respond to the pollution by sulphur from acid rain.     

Application of GIS for the identification and demarcation of selective heavy metal concentrations in the urban groundwater

Groundwater is the most appropriate and widely used source of drinking water, which is increasingly threatened by pollution from industrial and agricultural activities. To check the severity of the problem, 156 groundwater samples were collected from various depths (60-110 ft) of 52 different localities in Faisalabad city, the third largest metropolis in Pakistan, and analyzed for the metals (Zn, Cu, Cd, Ni, Pb, Mn and Fe) concentration in 2009. Quantification was done by using Flame Atomic Absorption Spectrophotometer technique and the results were compared with WHO standards for drinking water quality. Results showed that the levels of Cu, Mn and Fe were below the WHO standards while the concentrations of Zn, Cd, Ni and Pb were above the recommended levels of safe drinking water. Correlation analysis among the occurrence of these heavy metals revealed a highly significant and positive correlation of Mn with Zn and Fe. A significant and positive correlation of Cd was also found with Cu and groundwater depth showing that there is strong association between Cu-Cd pair and that the Cd concentration varies with depth of groundwater in the study area. Regional patterns of heavy metals occurrence were mapped using Geographical Information System (GIS) for the identification and demarcation of risk areas. The concentration maps may be used by policymakers of the city to mitigate groundwater pollution.     

巴丹吉林沙漠湖泊与地下水的补给来源及化学组成(英文)

Based on the analysis of ion chemical composition of lake water and shallow groundwater in the Badain Jaran Desert, this paper discussed the characteristics of ion chemical composition, spatial variation of lake water, and possible supply sources of lake water and groundwater in the desert areas. The results show that the pH, salinity, TDS and electrical conductivity of the lake water are greater than those of groundwater. The ion con-tents of water samples are dominated by Na+ and Cl?. Most of the higher salinity lakes are Na (K)-Cl-(SO4) type, and a few of low salinity lakes belong to the Na-(Mg)-(Ca)-Cl-(SO4)-(HCO3) type. Most of the groundwater is Na-(Ca)-(Mg)-Cl-(SO4)-(HCO3) type, attributed to subsaline lake, and only a few present the Na-Cl-SO4 type, flowing under saline lake. The pH, salinity, TDS and electrical conductivity in the southeastern lakes are relatively low, and there are slightly alkaline lakes. The pH, salinity, TDS and electrical conductivity in the northern lakes are much greater than those of the southeastern lakes, and the northern lakes are moderately alkaline and saline ones. In the southeastern part of the Badain Jaran Desert, the ion chemical characteristics of the lake water from south to north show a changing trend of sub-saline →saline→hypersaline. The changing trend of chemical compositions of ions in recent 9 years indicates that most of the ion contents have a shade of reduction in Boritaolegai, Badain, Nuoertu and Huhejilin lakes, which state clearly that the amount of fresh water supply is increasing in the 9-year period. The ion chemical composition of the lake water reveals that the flow direction of lake water is from southeast to northwest in the Badain Jaran Desert. The ion chemical composition, moisture content of sand layer water level height and hierarchical cluster analysis of the lake water and groundwater demonstrate that the lake water is mainly supplied by local rainfall and infiltration of precipitation in Yabulai Mountains and Heishantou Mountain, and the supply from the Qilian Mountains is almost impossible.     

Summer temperatures during the Medieval Warm Period and Little Ice Age inferred from varved proglacial lake sediments in southern Alaska

For the heavily glaciated mountains of southern Alaska, few high-resolution, millennial-scale proxy temperature reconstructions are available for comparison with modern temperatures or with the history of glacier fluctuations. Recent catastrophic drainage of glacier-dammed Iceberg Lake, on the northern margin of the Bagley Icefield, exposed subaerial outcrops of varved lacustrine sediments that span the period 442–1998 AD. Here, an updated chronology of varve thickness measurements is used to quantitatively reconstruct melt-season temperature anomalies. From 1958 to 1998, varve thickness has a positive and marginally significant correlation with May–June temperatures at the nearest coastal measurement stations. Varve sensitivity to temperature has changed over time, however, in response to lake level changes in 1957 and earlier. I compensate for this by log-transforming the varve thickness chronology, and also by using a 400-year-long tree-ring-based temperature proxy to reconstruct melt-season temperatures at Iceberg Lake. Regression against this longer proxy record is statistically weak, but spans the full range of occupied lake levels and varve sensitivities. Reconstructed temperature anomalies have broad confidence intervals, but nominally span 1.1°C over the last 1500+ years. Maximum temperatures occurred in the late twentieth century, with a minimum in the late sixth century. The Little Ice Age is present as three cool periods between 1350 and 1850 AD with maximum cooling around 1650 AD. A Medieval Warm Period is evident from 1000 to 1100 AD, but the temperature reconstruction suggests it was less warm than recent decades—an observation supported by independent geological evidence of recent glacier retreat that is unprecedented over the period of record. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.

巴丹吉林沙漠典型湖冰冻结-消融的空间模式差异

利用多源遥感数据解译、野外考察、原位观测等方法,分析了巴丹吉林沙漠腹地湖泊群湖冰冻结-消融空间模式及其差异的主要影响因素.结果表明:该沙漠存在4种冻结-消融空间模式,湖冰自湖岸蔓延至湖心、冻结早的区域融化晚;湖冰自湖岸蔓延至湖心、冻结早的区域融化早;湖冰自湖泊一岸扩展至另一岸、冻结早的区域融化晚;湖冰自湖泊一岸扩展至另...     

Fly-in/Fly-out and Fly-over: Mining and regional development in Western Australia

Adoption of fly-in/fly-out (FIFO) or commute work systems in the Western Australian mining industry has increased rapidly over the last decade, with metropolitan Perth becoming the main source of labour and the base for major mining supply and service companies in the state. This situation has led to increasing concern on the part of many regional authorities about the loss of local benefits through 'fly-over' effects, and implications for regional development in their smaller resource-based communities. To date, the state government has paid little attention to these issues, but, at the same time, the regions have done relatively little to help themselves. The paper explores the reasons for the growth of this work system, the nature of the regions' concerns, the measures taken to address them, and options for future action.     

Retene and resin acid concentrations in sediment profiles of a lake recovering from exposure to pulp mill effluents

The stratigraphy of resin acids (pimaric, isopimaric, sandaracopimaric, dehydroabietic and abietic acids) and base neutral compounds (retene, tetrahydroretene, dehydroabietin and fichtelite) in sediments of a lake recovering after the mill closure from exposure to effluents from sulphite pulp mill was studied. The highest concentrations of these compounds were detected 1.5 km downstream from the effluent pipe in sediment depth of 7–11 cm. This sediment layer is approximately 30 yrs old. The highest concentration of resin acids was 1100 and of retene 3300 g/g d.w. The retene concentration observed is the highest reported in the literature so far. The results imply that high concentrations of retene may be common in sediments of Finnish lakes polluted by pulp mill effluents.     

Siliceous algae-based seasonal temperature inference and indicator pollen tracking ca. 4,000 years of climate/land use dependency in the southern Austrian Alps

Diatom and chrysophyte cyst-based reconstructions of the dates of spring and autumn lake-mixing enabled us to estimate spring (ST_anom) and autumn (AT_anom) temperature anomalies as well as ice-cover of the last ca. 4,000 years in a lake sediment core (Oberer Landschitzsee, 2,076 m a.s.l.) from the southern slopes of the Austrian Central Alps. The two independently inferred temperature anomalies were significantly correlated. On average, spring and autumn temperatures were lower during the two millennia B.C than during 0–1,300 A.D. Marked spring and autumn temperature minima occurred at about 1,300 and 600 B.C. At about 1,300 A.D, ST_anom declined again. Spring-temperature anomalies during Roman and Medieval times equaled or slightly exceeded the modern values and paralleled tree-line and glacier fluctuations. The de-coupling of autumn and spring climates, which began during the Medieval period, might indicate changes in major circulation modes. It was assumed that the North-Atlantic influence, triggering winter-rain climate in the Northern Mediterranean, became weaker during Medieval times, resulting in a trend towards warmer autumns and overall more continental climate conditions in the study area. Four pulses of land use, inferred from indicator pollen, occurred during (1) the Early to Late Bronze, (2) the transition from Late Bronze to Early Iron Age (Hallstatt), (3) Late Iron Age (La Tène, Celtic time) to Roman times, and (4) during high to late Medieval times. Climate seemed to be an important, though complex, trigger of Alpine land use.