Radio Line Observations Of Molecular And Isotopic Species In Comet C/1995 O1 (Hale-Bopp)

We present here a review of the radio observations of the remarkable comet Hale-Bopp C/1995 O1 in which most major radio astronomical facilities have been involved. These observations started in August 1995, soon after the discovery of the comet (it was then at ∼7 AU from the sun), and well before its perihelion on April 1st, 1997; they are still going on, hopefully up to end of 1998. Extended cartographies have been obtained using multibeam receivers and on-the-fly techniques. High spatial resolution (a few ″) has been achieved with interferometers. Submillimetric observations are playing an increasing role, and high resolution (R ∼ 10⁶−10⁷) spectroscopy of cometary lines is now performed from decimetric to submillimetric wavelengths. The number of species observed at radio wavelengths now reaches ∼28,when it was ∼14 for comet C/1996 B2 Hyakutake. Most of these species are parent molecules. However, ions have been observed for the first time at radio wavelengths, and their velocities measured. Several isotopic species (involving D,¹³C,³⁴S,¹⁵N) have been sought, allowing isotopic enrichment determinations. The abundances of cometary molecules present many similarities and some differences with the abundances of interstellar molecules in regions where grain mantles are believed to be evaporated to the gas phase (hot cores, bipolar flows). They will be discussed for their implications on the origin of cometary ices and of comets themselves. This revised version was published online in July 2006 with corrections to the Cover Date.     

Comet Hale-Bopp (1995 O1)

Considerable interest has been raised by the discovery of Comet Hale-Bopp (1995 O1) and the possibility that it might become a very bright object in Spring 1997. The evidence to support either of the conflicting hypothesis (an intrinsically bright comet or a faint comet in a very large outburst) is too limited to reach solid conclusions and may remain so for some months yet. The pre-discovery observations encountered to date provide some limits to photometric models and suggest that the comet may be intrinsically bright, but do not yet permit a firm discrimination, even between extreme scenarios, due to the enormous extrapolation that must be made from the heliocentric distance at discovery, to that of perihelion.     

Comparison of the composition of the Tempel 1 ejecta to the dust in Comet C/Hale-Bopp 1995 O1 and YSO HD 100546

Spitzer Infrared Spectrograph observations of the Deep Impact experiment in July 2005 have created a new paradigm for understanding the infrared spectroscopy of primitive solar nebular (PSN) material—the ejecta spectrum is the most detailed ever observed in cometary material. Here we take the composition model for the material excavated from Comet 9P/Tempel 1's interior and successfully apply it to Infrared Space Observatory spectra of material emitted from Comet C/1995 O1 (Hale-Bopp) and the circumstellar material found around the young stellar object HD 100546. Comparison of our results with analyses of the cometary material returned by the Stardust spacecraft from Comet 81P/Wild 2, the in situ Halley flyby measurements, and the Deep Impact data return provides a fundamental cross-check for the spectral decomposition models presented here. We find similar emission signatures due to silicates, carbonates, phyllosilicates, water ice, amorphous carbon, and sulfides in the two ISO-observed systems but there are significant differences as well. Compared to Tempel 1, no Fe-rich olivines and few crystalline pyroxenes are found in Hale-Bopp and HD 100546. The YSO also lacks amorphous olivine, while being super-rich in amorphous pyroxene. All three systems show substantial emission due to polycyclic aromatic hydrocarbons. The silicate and PAH material in Hale-Bopp is clearly less processed than in Tempel 1, indicating an earlier age of formation for Hale-Bopp. The observed material around HD 100546 is located ∼13 AU from the central source, and demonstrates an unusual composition due to either a very different, non-solar starting mix of silicates or due to disk material processing during formation of the interior disk cavity and planet(s) in the system.     

Thermal model of water and CO activity of Comet C/1995 O1 (Hale-Bopp)

An investigation of the activity of Comet C/1995 O1 (Hale-Bopp) with a thermophysical nucleus model that does not rely on the existence of amorphous ice is presented. Our approach incorporates recent observations allowing to constrain important parameters that control cometary activity. The model accounts for heat conduction, heat advection, gas diffusion, sublimation, and condensation in a porous ice-dust matrix with moving boundaries. Erosion due to surface sublimation of water ice leads to a moving boundary. The movement of the boundary is modeled by applying a temperature remapping technique which allows us to account for the loss in the internal energy of the eroded surface material. These kind of problems are commonly referred to as Stefan problems. The model takes into account the diurnal rotation of the nucleus and seasonal effects due to the strong obliquity of Hale-Bopp as reported by Jorda et al. (Jorda, L., Rembor, K., Lecacheux, J., Colom, P., Colas, F., Frappa, E., Lara, L.M. [1997]. Earth Moon Planets 77, 167-180). Only bulk sublimation of water and CO ice are considered without further assumptions such as amorphous ices with certain amount of occluded CO gas. Confined and localized activity patterns are investigated following the reports of Lederer and Campins (Lederer, S.M., Campins, H. [2002]. Earth Moon Planets 90, 381-389) about the chemical heterogeneity of Hale-Bopp and of Bockelée-Morvan et al. (Bockelée-Morvan, D., Henry, F., Biver, N., Boissier, J., Colom, P., Crovisier, J., Despois, D., Moreno, R., Wink, J. [2009]. Astron. Astrophys. 505, 825-843) about a strong CO source at a latitude of 20°. The best fit to the observations of Biver et al. (Biver, N. et al. [2002]. Earth Moon Planets 90, 5-14) is obtained with a low thermal conductivity of 0.01 W m⁻¹ K⁻¹. This is in agreement with recent results of the Deep Impact mission to 9P/Tempel 1 (Groussin, O., A’Hearn, M.F., Li, J.-Y., Thomas, P.C., Sunshine, J.M., Lisse, C.M., Meech, K.J., Farnham, T.L., Feaga, L.M., Delamere, W.A. [2007]. Icarus 187, 16-25) and with previous thermal simulations (Kührt, E. [1999]. Space Sci. Rev. 90, 75-82). The water production curve matches the production rates well from −4 AU pre-perihelion to the outgoing leg while the model does not reproduce so well the water production beyond 4 AU pre-perihelion. The CO production curve is a good fit to the measurements of Biver et al. (2002) over the whole measured heliocentric range from −7 AU pre- to 15 AU post-perihelion.     

Gaseous Jets in Comet Hale-Bopp (1995 O1)

We report the identification of gas jets in comet Hale-Bopp in OH, NH, CN, C₂ and C₃. This is the first time OH and NH jets without an obvious optical dust jet counterpart have been identified in narrowband comet images. We also confirm the existence of CN jets as reported by Larson et al. (1997) and Mueller et al. (1998). Jet features can be seen in the March and April 1997 datasets, approximately a month before and after perihelion. Our results contribute to the understanding of both the chemical properties of the comet as well as the physical mechanisms necessary to produce these features. This revised version was published online in July 2006 with corrections to the Cover Date.     

Observations of the OH Radical in Comet C/1995 O1 (Hale-Bopp) with the Nançay Radio Telescope

We present OH 18-cm observations of comet Hale-Bopp (C/1995 O1) at the Nançay radio telescope. On nucleus and offset position observations allowed us to obtain both OH production rates and quenching radii. The maximum OH production rate was reached around perihelion, at about10³¹ s^-1.     

Spectroscopy of Comet Hale-Bopp in the infrared

High resolution infrared spectra of Comet C/1995 O1 (Hale-Bopp) were obtained during 2-5 March 1997 UT from the NASA Infrared Telescope Facility on Mauna Kea, Hawaii, when the comet was at r≈1.0 AU from the Sun pre-perihelion. Emission lines of CH₄, C₂H₆, HCN, C₂H₂, CH₃OH, H₂O, CO, and OH were detected. The rotational temperature of CH₄ in the inner coma was T_rot=110±20 K. Spatial profiles of CH₄, C₂H₆, and H₂O were consistent with release solely from the nucleus. The centroid of the CO emission was offset from that of the dust continuum and H₂O. Spatial profiles of the CO lines were much broader than those of the other molecules and asymmetric. We estimate the CO production rate using a simplified outflow model: constant, symmetric outflow from the peak position. A model of the excitation of CO that includes optical depth effects using an escape probability method is presented. Optical depth effects are not sufficient to explain the broad spatial extent. Using a parent+extended-source model, the broad extent of the CO lines can be explained by CO being produced mostly (∼90% on 5 March) from an extended source in the coma. The CO rotational temperature was near 100 K. Abundances relative to H₂O (in percent) were 1.1±0.3 (CH₄), 0.39±0.10 (C₂H₆), 0.18±0.04 (HCN), 0.17±0.04 (C₂H₂), 1.7±0.5 (CH₃OH), and 37-41 (CO, parent+extended source). These are roughly comparable to those obtained for other long-period comets also observed in the infrared, though CO appears to vary.     

No compelling evidence of distributed production of CO in Comet C/1995 O1 (Hale-Bopp) from millimeter interferometric data and a re-analysis of near-IR lines

Based on long-slit infrared spectroscopic observations, it has been suggested that half of the carbon monoxide present in the atmosphere of Comet C/1995 O1 (Hale-Bopp) close to perihelion was released by a distributed source in the coma, whose nature (dust or gas) remains unidentified. We re-assess the origin of CO in Hale-Bopp’s coma from millimeter interferometric data and a re-analysis of the IR lines.Simultaneous observations of the CO J(1–0) (115 GHz) and J(2–1) (230 GHz) lines were undertaken with the IRAM Plateau de Bure interferometer in single-dish and interferometric modes. The diversity of angular resolutions (from 1700 to 42,000 km diameter at the comet) is suitable to study the radial distribution of CO and detect the extended source observed in the infrared. We used excitation and radiative transfer models to simulate the single-dish and interferometric data. Various CO density distributions were considered, including 3D time-dependent hydrodynamical simulations which reproduce temporal variations caused by the presence of a CO rotating jet. The CO J(1–0) and J(2–1) observations can be consistently explained by a nuclear production of CO. Composite 50:50 nuclear/extended productions with characteristic scale lengths of CO parent L_p > 1500 km are rejected.Based on similar radiation transfer calculations, we show that the CO v = 1–0 ro-vibrational lines observed in Comet Hale-Bopp at heliocentric distances less than 1.5 AU are severely optically thick. The broad extent of the CO brightness distribution in the infrared is mainly due to optical depth effects entering in the emitted radiation. Additional factors can be found in the complex structure of the CO coma, and non-ideal slit positioning caused by the anisotropy of dust IR emission.We conclude that both CO millimeter and infrared lines do not provide compelling evidence for a distributed source of CO in Hale-Bopp’s atmosphere.     

Heliocentric evolution of the degradation of polyoxymethylene: Application to the origin of the formaldehyde (H2CO) extended source in Comet C/1995 O1 (Hale-Bopp)

The H₂CO production rates measured in Comet C/1995 O1 (Hale-Bopp) from radio wavelength observations [Biver, N., and 22 colleagues, 2002a. Earth Moon Planets 90, 5-14] showed a steep increase with decreasing heliocentric distance. We studied the heliocentric evolution of the degradation of polyoxymethylene (formaldehyde polymers: (CH₂O)_n, also called POM) into gaseous H₂CO. POM decomposition can indeed explain the H₂CO density profile measured in situ by Giotto spacecraft in the coma of Comet 1P/Halley, which is not compatible with direct release from the nucleus [Cottin, H., Bénilan, Y., Gazeau, M.-C., Raulin, F., 2004. Icarus 167, 397-416]. We show that the H₂CO production curve measured in Comet C/1995 O1 (Hale-Bopp) can be accurately reproduced by this mechanism with a few percents by mass of solid POM in grains. The steep heliocentric evolution is explained by the thermal degradation of POM at distances less than 3.5 AU. This study demonstrates that refractory organics present in cometary dust can significantly contribute to the composition of the gaseous coma. POM, or POM-like polymers, might be present in cometary grains. Other molecules, like CO and HNC, might also be produced by a similar process.     

What is the Parent of CH in the Coma of Comet C/1995 O1 (Hale-Bopp)?

The ratio of CH₄/CO in comets is an important indicator of the region of their formation. However, it is difficult to measure the quantity of CH⁺. The Giotto Ion Mass Spectrometer experiment observed a quantity of CH⁺ which seemed inconsistent with the amount of CH⁺. Thus, it was proposed that a source of the CH⁺ was a distributed source in the dust. We tested this hypothesis by observing the CH emission strength in comet Hale-Bopp as a function of dustiness. We see no strong correlation between the dust and the gas. Thus, for Hale-Bopp,dust is unlikely to be a dominant source of CH. This revised version was published online in July 2006 with corrections to the Cover Date.     

Comet Hale-Bopp (C/1995 O1): UVSTAR-FUV Spectroscopy from the Space Shuttle

We report here on unique post-perihelion (2.3 AU) measurements of Comet Hale-Bopp in the FUV-range (950–1250 Å) by means of the UVSTAR spectrometer from the space shuttle with the main purpose of searching for argon and other FUV emitters. New methods for separating the strong airglow emission at shuttle altitudes are here discussed in detail. Due to our low resolution (15 Å) and S/N ratio the possible rocket-borne detection of argon near perihelion (0.9 AU) could not be confirmed. New species as N₂ are suspected but difficult to separate from the strong airglow emission at shuttle altitudes. From the Lyα brightness (1.30± 0.08 kRy) a water production rate Q = 5.9 ± 0.4 × 10²⁹ molecules s^?1 could be derived and compared with other post-perihelion observations.     

Spectrocam-10 Thermal Infrared Observations Of The Dust In Comet C/1995 O1 Hale-Bopp

We describe 5 to 18 μm broadband images and R ∼ 100 spectra of comet Hale-Bopp taken with SpectroCam-10 on the 5 m Hale telescope during six runs between 1996 June and 1997 April. Our data show the gradual warming of dust grains as the comet approached perihelion. In June, the 10 μm silicate emission feature was already stronger than observed in any other comet, and it increased to about 3 times the continuum level near perihelion. Spectral structure attributed to a crystalline olivine grain component remained relatively constant, but other features associated with pyroxenes appeared to vary with heliocentric distance. This revised version was published online in July 2006 with corrections to the Cover Date.     

Cyanide Chemistry in Comet Hale-Bopp (C/1995 O1)

Observations of comet Hale-Bopp (C/1995 O1) have been carried out near perihelion (1997 March) at millimeter wavelengths using the NRAO 12 m telescope. The J=1-->0, 2-->1, and 3-->2 lines of HCN at 88, 177, and 265 GHz were measured in the comet as well as the J=3-->2 lines of H13CN, HC15N, and HNC. The N=2-->1 transition of CN near 226 GHz was also detected, and an upper limit was obtained for the J=2-->1 line of HCNH+. From the measurements, column densities and production rates have been estimated. A column density ratio of [HCN]/[HNC] = 7+/-1 was observed near perihelion, while it was found that [HCN]/[HCNH+] greater, similar 1. The production rates at perihelion for HCN and CN were estimated to be Q(HCN) approximately 1x1028 s-1 and Q(CN) approximately 2.6x1027 s-1, respectively, resulting in a ratio of [HCN]/[CN] approximately 3. Consequently, HCN is sufficiently abundant to be the parent molecule of CN in Hale-Bopp, and HCNH+ could be a source of HNC. Finally, carbon and nitrogen isotope ratios of 12C/13C = 109+/-22 and 14N/15N = 330+/-98 were obtained from HCN measurements, in agreement with previous values obtained from J=4-->3 data. Such ratios suggest that comet Hale-Bopp formed coevally with the solar system.     

Evolution of Dust Shells and Jets in the Inner Coma of Comet C/1995 O1 (Hale-Bopp)

Comet Hale-Bopp was observed with the 80 cm reflector + CCD at the Haute-Provence observatory (OHP) and with the 62 cm reflector + CCD at the Saint-Véran observatory (Queyras, France). The morphology of the shells was followed from their first appearence on 1997 Jan. 30, until their disappearance on May 9. These shells spread from the nucleus region with a velocity in agreement with a nuclear rotation period of about 11.33 hours. We report also a short and bright dust ejection on May 8. CN images show a long spiral jet in the tailward side invisible on continuum images. The circumnuclear structures have been followed at Saint-Véran from Apr. 5 to Apr. 11, 1997 with a high spatial resolution (200 km/pixel). We have followed the emergence of a recurrent linear polar jet. Measurements of its expansion show a constant acceleration of material with typical expansion velocity of 1 km/s. The CCD frames show the interconnection between spiral jets and the successive shells. This revised version was published online in July 2006 with corrections to the Cover Date.     

Comet Hale-Bopp in outburst: Imaging the dynamics of icy particles with HST/NICMOS

Comet Hale-Bopp was imaged at wavelengths from 1.87 to 2.22 μm by HST/NICMOS in post-perihelion observations starting on UT 1997 August 27.95. Diffraction-limited (∼02) images were obtained at high signal-to-noise (∼1500) to probe the composition and dynamics of the inner coma and also the size and activity of the nucleus. The velocities of several unusual morphological features over a 1.7 h period, indicate that a significant outburst occurred 7.4 h prior to these images while the comet was at a heliocentric distance of 2.49 AU. Similar features are also apparent after re-analysis of pre-perihelion ground-based images. The inner coma (radius ?2500 km) is dominated by an “arc” feature, which expanded and became more diffuse with time. This feature can be modeled as the bright central portion of a “jet of outburst” from a near-equatorial region of the nucleus. Less prominent, time-variable linear and circular morphologies are also apparent. The expansion rates of both the arc feature and the circular morphologies imply a common origin and also suggest a grain size distribution with two broad maxima. In addition, several static linear features extend to the edge of the field of view (21,100 km). Radial brightness profiles are highly asymmetric and only approach a ρ⁻¹ decline at distances ?15,000 km. Images in a narrow-band filter at 2.04 μm exhibit a ∼4% absorption feature relative to nearly simultaneous images at wavelengths of 2.22, 1.90, and 1.87 μm. This absorption is attributed to H₂O ice in the coma grains. The spatial distribution and expansion velocity of the absorption at 2.04 μm indicate that these grains are associated with the outburst. The constancy of the absorption feature indicates no appreciable sublimation over 1.7 h. The unresolved nucleus has a flux density consistent with a 40±10 km diameter assuming a 4% geometric albedo.     

Narrow-Band Photometry of Comet C/1995 O1 (Hale-Bopp)

Photometric observations of comet C/1995 O1 (Hale-Bopp) carried out at the Stará Lesná Observatory since February to April 1997 are analyzed and discussed. Emission band fluxes and continuum fluxes are presented, from which the total numbers of molecules in the columns of the coma encircled by diaphragms are calculated. The production rates are estimated from the conventional Haser model. We found that the photometric exponent of dust contribution two months prior perihelion was n = 5.2. The photometric exponent n of the cometary magnitude solely to the C₂ emission alone equals 3.3 and that of CN equals 2.5. These values can be explained by a fact that the maximums of production rates of the gases were reached between March 2and 12 and not at the perihelion as it is valid for dust. These results are compared with the values of 1P/Halley (1986 III) under the similar conditions, obtained with the same method and instrument. C/Hale-Bopp exhibited 4.1 times more molecules radiating the CN-emission than 1P/Halley in the same column of the coma. The continuum flux of C/Hale-Bopp was also very strong. The ratios (to 1P/Halley) are 94:1 (Cont. 484.5) and 74:1 (Cont. 365.0). The cometary colour was the same as that of the Sun. This revised version was published online in July 2006 with corrections to the Cover Date.     

Spectroscopic Monitoring of Comet C/1995 O1 (Hale-Bopp)

Earth, Moon, and Planets -     

CCD Polarimetric Imaging Of Comet Hale-Bopp (C/1995 O1)

Polarimetric observations of the light scattered by dust have been carried out at Pic-du-Midi Observatory with the 2 m telescope in June and September–October 1996, and at Haute-Provence Observatory with the 0.80 m telescope in April 1997. They cover a total number of 11 nights and a large (6.9°–47.7°) phase angle range. The spatial resolution allows to underline structures in the coma, as well in the brightness images as in the polarization maps, with a correlation between the regions of bright structures and the regions of higher polarization. A clear difference appears between the sunward and antisunward side, with higher polarization on the antisunward side. The phase angle coverage allows us to obtain a polarimetric phase curve for the whole coma and to compare it with other cometary phase curves. The degree of polarization is higher for Hale-Bopp than for the comets previously observed. This revised version was published online in July 2006 with corrections to the Cover Date.     

The composition and size distribution of the dust in the coma of Comet Hale-Bopp

We discuss the composition and size distribution of the dust in the coma of Comet Hale-Bopp. We do this using a model fit for the infrared emission measured by the Infrared Space Observatory (ISO) and the measured degree of linear polarization of scattered light at various phase angles and wavelengths. The effects of particle shape on the modeled optical properties of the dust grains are taken into account. Both the short wavelength (7-44 μm) and the long wavelength (44-120 μm) infrared spectrum are fitted using the same dust parameters, as well as the degree of linear polarization at twelve different wavelengths in the optical to near-infrared domains. We constrain our fit by forcing the abundances of the major rock forming chemical elements to be equal to those observed in meteorites. The infrared spectrum at long wavelengths reveals that large grains are needed in order to fit the spectral slope. The size and shape distribution we employ allows us to estimate the sizes of the crystalline silicates. The ratios of the strength of various forsterite features show that the crystalline silicate grains in Hale-Bopp must be submicrometer-sized. On the basis of our analysis the presence of large crystalline silicate grains in the coma can be excluded. Because of this lack of large crystalline grains combined with the fact that we do need large amorphous grains to fit the emission spectrum at long wavelengths, we need only approximately 4% of crystalline silicates by mass (forsterite and enstatite) to reproduce the observed spectral features. After correcting for possible hidden crystalline material included in large amorphous grains, our best estimate of the total mass fraction of crystalline material is ∼7.5%, which is significantly lower than deduced in previous studies in which the typical derived crystallinity is ∼20-30%. The implications of this low abundance of crystalline material on the possible origin and evolution of the comet are discussed. We conclude that the crystallinity we observe in Hale-Bopp is consistent with the production of crystalline silicates in the inner Solar System by thermal annealing and subsequent radial mixing to the comet forming region (∼30 AU).     

A Molecular Survey of Comet C/1995 O1 (Hale-Bopp) at the IRAM Telescopes

Spectroscopic observations of comet Hale-Boppwere undertaken near perihelion at millimetre wavelengths with the Institut de Radioastronomie Millimétrique (IRAM) telescopes at Plateau de Bure (France)and Pico Veleta (Spain). They resulted in the first detections of HCOOH,SO₂, NH₂CHO and HCOOCH₃ in a comet. HDO was detected through its3₁₂–2₂₁ line at 225.897 GHz,complementing the observation of the 1₀₁–0₀₀ line at 464.925 GHz at the James Clerk Maxwell Telescope (Meier et al., 1998,Science 279, 842).Several unidentified lines are present in the spectra. Observations of HC₃N, HNCO, OCS, SO, CN, CO₊, HCO₊, in addition to more ‘classical’species CO, HCN, HNC, CH₃CN, CH₃OH, H₂CO, CS and H₂S (Biveret al., this issue) permit us to make out an extensive inventory of the composition of the coma of comet Hale-Bopp at its perihelion. It presents strong analogies with gas-phase abundances measured in interstellar hot cores and bipolar flows, which are believed to reflect the composition of interstellar grains. This revised version was published online in July 2006 with corrections to the Cover Date.