Analysis of the effect of megalopolises on water quality in surface water bodies by ecological-toxicological characteristics

Data of long-term observations of Roshydromet and the studies of the authors’ studies of hydrochemical, hydrobiological, and bioassaying characteristics and appropriate publications in the areas of megalopolises—the cities of Rostov-on-Don and Novosibirsk are analyzed. Similar and distinctive characteristics of water quality by these ecological-toxicological characteristics are identified; trends in the long-term year-to-year variations in water quality are established, criteria and characteristics reflecting the effect of cities on water bodies in their territory are determined. The identity of some chemical-toxicological criteria and the characteristics of the influence of cities in southern Russia and Siberia on water bodies suggest that they can also be used in urban area in other regions. The Lower Don is used as an example to show that water pollution by metals is mostly due to wastewater discharge, while water pollution by petroleum products and sulfates has no direct relation to that.     

Changes in Hydrochemical Characteristics of Water Bodies in the Southern Aral Region

Based on the hydrochemical characteristics of water bodies in the northwestern part of the southern Aral Sea region, limnic ecosystems are shown to be liable to anthropogenic changes. The dynamics of the salinity, ionic composition, oxygen content of water, and nutrients under human impact on water bodies of the southern Aral Sea region are shown.     

Characteristics of the Ecosystems of Water Bodies Separating from Kandalaksha Bay of the White Sea

The coastal water bodies that separate from White Sea water area due to Kandalaksha coast rise are examined. The hydrological and hydrochemical characteristics of these water bodies are found to notably differ from these in the bays and straits connected with them. Extreme values of water temperature and salinity were recorded. High concentrations of oxygen (>20 mg/l) were recorded in the near-surface water layers and high concentrations of hydrogen sulfide (>90 mg/l) in bottom waters. The species composition of phyto- and zooplankton was found to be poor. The characteristics of enzymatic destruction in subsurface waters of lakes are an order of magnitude greater than those in White Sea open areas.     

Tolerance of water objects to acidification depending on their specific drainage areas—a case study of lakes and rivers in the basin of the Shuya River (Onezhskaya)

The dependence of acidification of water objects on their hydrologic characteristics is considered. An equation is derived to link the input of strong acids into lakes with their specific drainage areas. Based on the results of hydrochemical observations, the acidification of water bodies is analyzed in terms of hydrology and geochemistry.     

Present-day ecological state of water objects of the Republic of Armenia

An ecological and hydrochemical classification elaborated by the authors is used to assess the present quality of water in the most important water objects of the Republic of Armenia. This classification allowed us to determine the degree of environmental safety of each water body by ranking the water quality, ecosystem ecological stability, and the reliability of conservation of water quality during transportation. Based on the results of the ecological and hydrochemical assessment of water quality, the water bodies that require special protection and rational exploitation are distinguished, and the priority of water protection measures is established.     

Water chemistry in Onega Lake and its tributaries

The results of studies of water chemistry carried out in the water body in 1965–2009 are presented. This period features a considerable industrial and agricultural rise in the lake drainage basin, followed by a decline since the 1990s, manifesting themselves in the dynamics of some hydrochemical characteristics of water bodies. The multipurpose use of Onega Lake is shown to cause its pollution and eutrophication. The results of studies are used to evaluate the major components of the external load onto the lake and trends in variations of chemical characteristics under the effect of natural and anthropogenic factors.     

Salt pollution of surface water in oil fields of Khanty-Mansi Autonomous Area-Yugra

The article gives the results of analysis of salt pollution at deposits of Khanty-Mansi Autonomous Area-Yugra (KhMAO-Yugra) based on data of regional hydrochemical monitoring. Data of a twenty-year observation series were used to identify the most polluted water bodies and to determine deposits with the largest salt load. Correlation and regression analyses are used to assess the interrelation between technogenesis characteristics and pollution level. It was found that the current salt pollution in the area is lower than that in the 1990s, though the pollution level has increased at some deposits of the Ob–Irtysh interfluve.     

Radionuclides and microelements in natural waters in the zone of a uranium-vanadium deposit (Republic of Karelia)

The results of studies performed in the area of a uranium-vanadium deposit are used to characterize the concentration and distribution of microelements and radionuclides in water, soil, and fish. The exposure rate on the surface of the examined samples is found to be equal to 15–20 μr/h, i.e., to lie at the background level, which means that these samples are not an external radiation hazard for population. Concentrations of U and V in water somewhat greater than background values were recorded, though they are lower than MAC for fishery water bodies. The collected data show that a delicate equilibrium has formed in this territory, although the hydrochemical characteristics have not changed within the recent 40 years, and radionuclide content of water, soil, bottom sediments, and fish are at an extremely low level.     

Express Assessment of Water Toxicity Based on Bioassaying: Case Study of Surface-Water Bodies in St. Petersburg

A system of efficient on-line monitoring of the state of water in surface water bodies is developed. The expediency of using new general-purpose bioassays for the integral express evaluation of the natural-water toxic impact on living organisms is substantiated. Fundamentally new methods of bioassaying with gasteropoda from special laboratory cultures (“PRM-TESTS”) used as test organisms are presented. The results of complex hydrochemical and biological (toxicological) investigations with PRM-TESTS as applied to water bodies in St. Petersburg are discussed.__________Translated from Vodnye Resursy, Vol. 32, No. 4, 2005, pp. 425–434.Original Russian Text Copyright © 2005 by Kurilenko, Zaitseva.     

Long-Term Dynamics of Ice Phenomena—An Indicator of Global Warming in the Southern Urals

The article presents the first study of the long-term dynamics of ice phenomena in lakes of different landscape–climate zones in the Southern Urals. The overwhelming majority of lakes, whatever their typology and geographic occurrence, show a decrease in the duration of the period of ice phenomena at a longer open-water period because of the later freeze-up. The governing factor in the long-term dynamics of ice phenomena is the mean annual air temperature. The largest is the effect of the average air temperature in the freeze-up period (October–March). The morphometric, hydrological, and hydrochemical characteristics have no direct effect on the differences in the long-term dynamics of ice phenomena in individual lakes. These differences are determined by the landscape–climate zones. The difference between water bodies in urbanized landscapes and other water bodies is much greater than that between the lakes in natural landscape–climate zones.     

Concentrations,coexisting forms,and features of silicon distribution and migration in surface waters of Ukraine

The results of studying silicon concentrations and coexisting forms in surface water bodies of Ukraine with different hydrological regime, hydrophysical and hydrochemical characteristics are presented. Silicon distribution between its dissolved and suspended forms, as well as the relationship between the concentration of suspended silicon and the weight of suspended matter and its nature are discussed. The dominating form of silicon migration is shown to be its dissolved form (70.1–99.4% of its total content), while suspended form of silicon dominates in river waters with higher concentration of suspended matter of mineral origin, (56.1–81.5%). The results of studying silicon distribution between abiotic and biotic components of suspended matter, as well as between its dissolved forms with different charge signs are given. Dissolved silicon in the water bodies under study is shown to account for 93.0–99.0% of neutral fraction, where its compounds with molecular weight <0.2 kDa dominate.     

江西永平爆破的水化学效应

为了探索研究各种地震前兆现象,我国地震工作者已开始对地下水化学成分在地震发生前的变化进行观测。利用爆破作实验,是企图发现地下水化学成份在冲击力的作用下的变化,为识别地震前兆提供一定的依据。 本文着重研究江西永平铜矿前后三次爆破所取得的大量水化学观测资料,探讨爆破时水化学效应的特征,并确认爆破膨胀冲击力是使氡及水化学组分发生变化的主导因素,而各观测井孔所处的地质、水文地质条件及地球化学环境的不同,又起了加强或削弱的控制作用。为合理地选择水化学观测井孔(泉),以及研究在力的作用下水化学组分的变化特征,提供了实验依据。      

山西省4口井(泉)水化学特征与水氡映震效能研究

对山西4口水化学观测井（泉）及周边地表水进行水化学和氢氧同位素分析,利用Piper图、durov图、Na-K-Mg三角图等方法研究其水化学特征及成因,得出井（泉）水岩平衡程度、热储温度、地下水循环深度及地下水补给来源详情;分析了井（泉）水氡测项映震特征,应用水氡映震效果与水岩平衡程度、地下水循环深度表现出的特征,评价了地震监测效能。评价结果显示夏县井、奇村井优于临猗井,适于开展地震水化学观测;定襄泉应用该水化学方法评价尚存不足之处,需要探索适用于该类观测泉点的物理与化学相结合的评价方法。     

Toxicity and Accumulation of Al in the Acid Water of Small Lakes and Watercourses in Finnish Lapland

On the basis of a study of the hydrochemical regime and the status of benthic acidophobic species in the acidified watercourses and small lakes of Finnish Lapland, humic compounds are demonstrated to be the principal factors controlling both pH and the proportions of different forms of Al in water. It is found that the concentration of labile aluminum, i.e., that form of aluminum which is most toxic for aquatic organisms, increases only in acid water (pH 4.8–6.5) with a low and extremely low humic content of water (with a color of 5–60 mg Pt/l). Humic and other organic substances that fix Al in an inert or another stable form are demonstrated to be able to decrease the toxic properties of aluminum for acidophobic species and the capacity of aluminum to be accumulated in the bodies of aquatic organisms. Aluminum is shown to have no tendency to an increased rate of accumulation in the bodies of aquatic organisms that form the highest trophic level of secondary predators.     

山西奇村水汞相关性分析与与区域分布特征的研究—剖析山西奇村水汞与空白样同步的原因

为揭示山西奇村水汞与空白样测值同步的原因，对水化热水井与空白样、水化热水井与制作空白样的冷水井、制作空白样的冷水井与空白样的特征进行了分析，并对忻定盆地南部近1 000km^2不同深度、不同水温的21眼井进行了水汞测量。研究表明，测区各井具有水汞含量一致、动态变化同步的基本特征，提出水汞动态可能反映了来自大构造及深层的变化信息的看法。     

Heterogeneity in ground water–surface water interactions in the hyporheic zone of a salmonid spawning stream

Spatial and temporal variability in ground water–surface water interactions in the hyporheic zone of a salmonid spawning stream was investigated. Four locations in a 150‐m reach of the stream were studied using hydrometric and hydrochemical tracing techniques. A high degree of hydrological connectivity between the riparian hillslope and the stream channel was indicated at two locations, where hydrochemical changes and hydraulic gradients indicated that the hyporheic zone was dominated by upwelling ground water. The chemistry of ground water reflected relatively long residence times and reducing conditions with high levels of alkalinity and conductivity, low dissolved oxygen (DO) and nitrate. At the other locations, connectivity was less evident and, at most times, the hyporheic zone was dominated by downwelling stream water characterized by high DO, low alkalinity and conductivity. Substantial variability in hyporheic chemistry was evident at fine (<10 m) spatial scales and changed rapidly over the course of hydrological events. The nature of the hydrochemical response varied among locations depending on the strength of local ground water influence. It is suggested that greater emphasis on spatial and temporal heterogeneity in ground water–surface water interactions in the hyporheic zone is necessary for a consideration of hydrochemical effects on many aspects of stream ecology. For example, the survival of salmonid eggs in hyporheic gravels varied considerably among the locations studied and was shown to be associated with variation in interstitial chemistry. River restoration schemes and watershed management strategies based only on the surface expression of catchment characteristics risk excluding consideration of potentially critical subsurface processes. Copyright © 2002 John Wiley & Sons, Ltd.     

濮阳台2号井水化学动态变化原因分析

依据区域水地质、地球化学环境特征,研究了濮阳市地震台2号井水化动态的变化原因。濮阳台2号井属多层一混合型井孔,采用双含水层进行水化观测,其水化动态的变化受地下水开采的影响。     

生态补水对白洋淀流域地表水和地下水水化学特征的影响

生态补水是维持和改善白洋淀生态环境的重要途径.为研究生态补水对白洋淀水环境的影响,分别在补水前与补水后采集淀水、河水及地下水样品,分析区域地表水和地下水水化学特征.结果表明：（1）白洋淀补水前、后地表水与地下水的水化学组成中Na⁺为主要阳离子,补水后阴离子以HCO₃^-为主,淀区南部地表水电导率高;补水后地表水与地下水Ca²⁺、Mg²⁺和HCO₃^-浓度显著增加,水体电导率降低.（2）补水前地下水为Na-HCO₃型水,地表水主要为Na-Cl·SO₄及Na-Cl·HCO₃类型;补水后地表水与浅层地下水向Ca·Mg-HCO₃型演化,深层地下水水化学类型基本保持不变.（3）生态补水使白洋淀水位升高,淀区水面积增大,缓解了水资源短缺的问题;同时也使浅层地下水水化学组成发生改变,而深层地下水暂未受到影响.生态补水后,受稀释和混合作用的影响,水体Na⁺、Cl^-和SO₄^2-浓度显著下降,Ca²⁺、Mg²⁺及HCO₃^-浓度增加.在白洋淀生态补水中应"先治污,后补水",以减少补水过程中污染物向淀区的运移,还应注意区域地下水位上升过程中的阳离子交换及水岩相互作用,为合理调配生态补水及改善白洋淀生态环境提供科学依据.     

Water source characterization through spatiotemporal patterns of major,minor and trace element stream concentrations in a complex,mesoscale German catchment

The link between spatiotemporal patterns of stream water chemistry and catchment characteristics for the mesoscale Dill catchment (692 km²) in Germany is explored to assess the catchment scale controls on water quality and to characterize water sources. In order to record the spatiotemporal pattern, ‘snapshot sampling’ was applied during low, mean and high flow, including 73 nested sites throughout the catchment. Water samples were analysed for the elements Li, B, Na, Mg, Al, K, Ca, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Rb, Sr, Mo, Ba, Pb and U using inductively‐coupled‐plasma mass spectrometry, and for electric conductivity and pH. Principle component analysis and hierarchical cluster analysis were used to find typical element associations and to group water samples according to their hydrochemical fingerprints. This revealed regional hydrochemical patterns of water quality which were subsequently related to catchment attributes to draw conclusions about the controls on stream chemistry. It was found that various lithologic signals and anthropogenic point source inputs controlled the base flow hydrochemistry. During increased flows, stream waters were diluted causing additional hydrochemical variability in response to heterogeneous precipitation inputs and differences in aquifer storage capacities. The hydrochemical patterns further displayed in‐stream mixing of waters. This implied, that stream waters could be apportioned to the identified water sources throughout the catchment. The basin‐wide hydrochemical variability has the potential to outrange the tracer signatures typically inferred in studies at the hillslope scale and is able to strongly influence the complexity of the catchment output. Both have to be considered for further catchment scale tracer and modelling work. Despite the likelihood of non‐conservative behaviour, the minor and trace elements enhanced the rather qualitative discrimination of the various groundwater types, as the major cations were strongly masked by point source inputs. Copyright © 2007 John Wiley & Sons, Ltd.