Petrochemistry of quaternary pumiceous pyroclastic products in southern Guadeloupe (F.W.I.)

Pumiceous pyroclastic products are present as flows and falls at several stages of the evolution of the southern Guadeloupe volcanic island. An understanding of this volcanism had to rely on detailed petrochemical data of these products to complement similar data for effusive rocks so as to yield complete stratigraphical coverage. On the other hand most pumiceous rocks are more or less conspicuousily banded suggesting that mixing phenomena occurred to different degrees in their genesis. Three major classes of pumiceous products are found: (1) the Axial Chain deposits (2.0–0.5 My) are characterized by An90, 75-55 + En55 + Wo42En37 + Usp35-37 ± Fo68 ± Hble, SiO₂ 60%, SiO₂/Th 35.6, and La/Th 3.9. Banded samples have components that differ in evolution indices by about 50%; (2) the Bouillante Chaine pyroclastics (0.3–0.1 My) consist of scattered deposits with variable mineralogical and geochemical compositions that seem to have erupted from a number of small eruptive centers. Qz-dacitic pumice is common with An90, 70-45 + En66-56 + Usp32-38 + Ilm94 + Hble ± Wo40-42En40-42, SiO₂ 62%, SiO₂/Th 22.9, and La/Th >4. Mixed pumice samples have highly contrasted evolution indices differing by up to 120%; (3) the Pintade pumice flows and falls correspond to the major pyroclastic event (approx. 10 km³) in the southern Basse Terre area. They are characterized by An85-70 + En66-56 + Usp32-37 ± Wo42En42, SiO₂/Th 18.7-22?6, and La/Th 3.0-4.0. Banded pumice lumps are scarce and show slight compositional contrasts; differences in evolution indices do not exceed 38%. Axial and Bouillante chain pyroclastics and Grande Découverte volcano pumice respectively, form two different families in trace element plots. Minor elements in pyroxenes also are distinctive. These trends are similar to those obtained for effusive rocks and define comagmatic series. Major and trace element data for the separated components of inhomogeneous pumice in each formation always plot in the corresponding series. These chemical discriminants can be used to attribute samples of unknown provenance to a given volcanic ensemble. An inverse relationship between differences in evolution indices in inhomegeneous pumice and the volume of any single eruptive sequence is noted. This is an indication that pumiceous pyroclastic rocks were erupted from a zoned magma chamber. We favor an interpretation where zonation is produced by influx of less envolved magma in superficial differentiated chambers which is a direct cause for eruption.     

Geochemistry and origin of basaltic lavas from Society Islands,French Polynesia (south central Pacific Ocean)

The Society Islands of French Polynesia (south-central Pacific Ocean) are formed predominatly by basaltic lavas of alkaline affinities. These intraplate rocks are either Ne- or Hy-normative. Ne-normative basaltic lavas are lower in Si and heavy rare earth elements and higher in Ti, V and Sr than Hy-normative. The differences are attributed to the contrasting behaviour of amphibole during melting of the upper mantle, which, in turn, may be related to the variation in the depth of melting. Compared to pyrolite, the upper mantle source of the lavas was enriched in incompatible elements.     

Volcan ceboruco: A major composite volcano of the mexican volcanic belt

Ceboruco is a major composite volcano at the western end of the Mexican Volcanic Belt, near the junction between the North American and Pacific plates. The volcano is built from successive eruptions of andesite lavas and pyroclastic rocks, and major eruptions during its history have resulted in the formation of two concentric calderas. The youngest volcanic activity has included the extrusion of dacites within the inner caldera and a voluminous flank eruption of andesite during 1870–72. Fumarolic activity persists to the present day. Chemical analyses show that the lavas are of cale-alkaline type and rangs from andesite (SiO₂=58–61%) to acid dacite (SiO₂=68%) in composition. The rate of increase of K₂O relative to SiO is greater than that in volcanic rocks from the Mexican Volcanic Belt as a whole. This indicates that simple models based on the application of such relationships may not be adequate to explain the petrogenesis of calc-alkaline lavas.     

Major-element petrochemistry of some extrusive rocks from the volcanically active Mariana Islands

Volcanic rocks from six of the currently or recently active volcances of the Mariana Island are show little variation in major element abundances. SiO₂ content averages 51.5 wt.%. The flows are high in Al₂O (mean 17.7 wt.%) and Fe oxides (mean 10.1 wt.% calculated as FeO only), and moderate in MgO content (mean 4.7 wt.%), Na₂O (mean 2.7 wt.%), and K₂O (mean 0.7 wt.%). Only the rocks from Farallon de Pajaros, the northernmost of the Mariana Islands, deviate slightly from the average of the analyses. Three analyses from this island are slightly higher in SiO₂ (about 54 wt.%) and Al₂O₃, and are lower in total Fe oxides and MgO. According to preferred classification, the lavas of the Mariana Islands can be termed mela-andesites, high-alumina basalts, or calc-alkaline (orogenic) basalts. The K₂O values (mean 0.7 wt.%) obtained from lavas of the Mariana Islands are significantly higher than the K₂O values (about 0.33 wt.%) from volcanics of the Izu chain to the north. Inasmuch as the substantial scatter in location of earthquake foci beneath both arcs prevents accurate delineation of the upper boundary of the Benioff zone, it presently cannot be determined whether this discrepancy in K₂O values reflects a difference in depth from the volcanic are to the dipping seismic zone or relates to other phenomena. The older volcanic islands within the Mariana-Bonin island chain apparently defined an island arc system during Eocene to Miocene time. This indicates that the present plane of convergence between the Pacific plate and the Philippine Sea plate has defined the convergence between these plates since Eocene time.     

Petrology of tholeiitic lavas from Tanna Island (New Hebrides): Importance of cumulative processes in Island arc magmatism

Tanna, one of the southernmost islands of the New Hebrides volcanic arc, is made of Late Pliocene to Recent island arc tholeiitic basalts and andesites, with SiO₂ contents ranging from 45 to 57%. These lavas are highly porphyritic (30–50% in volume): phenocrysts of plagioclase are the most abundant, together with olivine and clinopyroxene. The groundmass contain plagioclase, augite, olivine, magnetite and glass; pigeonite, tridymite, sanidine and, rarely, biotite may also occur. The olivines and clinopyroxenes show an iron enrichment from the cores of phenocrysts to their rims and the groundmass crystals, but their compositional variations are not correlated with the Mg/Fe ratio of bulk host rocks, the most Fe-rich compositions being found in Mg-rich lavas. Plagioclase compositions range from An₉₅ to An₆₀ in the basalts and An₆₀ to An₅₀ in the andesites, but, within each group, they are not correlated with SiO₂ or Na₂O contents of host lavas. Consequently, the bulk major element compositions of Tanna volcanic rocks cannot be considered as primarily controlled by crystal separation from successive liquids. The oxyde-SiO₂ variations diagrams, and the modal compositions and mineral chemistry show that crystal accumulation is the predominant mechanism accounting for bulk rock compositions. However, this does not exclude fractional crystallization: the variation of the calculated groundmass mineralogy strongly suggest the occurrence of crystal removal mainly clinopyroxene and magnetite.     

Significance of basic and ultramafic rock inclusions in the basalts of Canary Islands

This paper deals with the mineralogical, textural and chemical features of the dunite, peridotite, pyroxenite and gabbroic inclusions present in the Quaternary basalts of the Canary Islands. The mineralogical composition, structure and texture of the inclusions show that most of them have been formed as crystal cumulates from a nonalkaline basaltic magma in the earlier stages of its fractional crystallization. There are no co-genetic relationships between the inclusions and the host basalts, since the latter have a very strong alkaline-olivine character, although there are also some types with tholciitic aflinities. The study of the data leads to the conclusion that these inclusions can be considered as xenoliths from the basic and ultrabasic complexes that form the substratum and which outcrop in some of the Canary Islands. Attention is called to the fact that in many other volcanic zones of the world there has been a previous emplacement of basic and ultramafic layered complexes and is the question opened whether the association between stratiform-complexes and active basaltic volcanism is more frequent than has been assumed up to now.     

Variation trends in basaltic rocks of the canary islands

More than two hundred new analyses of basaltic rocks from the Canary Islands are presented. The available data show that the earlier successions have similar variation trends throughout the archipelago; these trends represent all the intermediate types between basic differentiates (oceanites, ankaramites) and more salic differentiates (trachy-basalts, hawaiites). In the more recent volcanic series, the study shows that there is a magmatic diversification with different variation trends in the Eastern than in the Central Canary Islands. In the latter the alkaline character becomes stronger in the successive periods of volcanic activity which have been established in each island. In the Eastern islands the basaltic evolution is, on the contrary, towards basaltic rocks with tholeiitic affinities.     

Geology and tectonic setting of the Mule Creek caldera,New Mexico,U.S.A.

The 10-km diameter Mule Creek caldera is the youngest felsic eruptive center in the Mogollon-Datil volcanic field of southwestern New Mexico. The caldera forms a topographic basin surrounded by a raised rim. The caldera wall is well displayed on the south and west sides of the structure where it dips 20–30 degrees toward the center of the basin. Mudflow breccia fills the caldera and is banked up against the caldera wall. Post-caldera porphyritic quartz latite domes and flows crop out along the ring-fracture zone. The caldera is superimposed upon an older volcanic complex of flow-banded rhyolite and porphyritic andesite lava. The Mule Creek caldera probably originated by explosive eruption of about 10 km³ of pumice and ash, in part preserved in the matrix of the mudflow breccia. Periods of explosive volcanism during the deposition of mudflow breccia are documented by tuffaceous beds interbedded with the breccia. A thin rhyolite ash-flow sheet originated in the caldera and overlies the mudflow breccia. The youngest felsic rocks around the caldera are (1) domes and flows of crystal-rich porphyritic quartz latite of variable mineralogy, interpreted as a defluidized magma, and (2) widespread crystal-poor, flow-banded rhyolite, dated at 18.6 m.y., which is not directly related to the caldera sequence. The Mule Creek caldera and other volcanic features farther south represent the only documented overlap of felsic volcanism with early stages of Basin-Range tectonism in the Mogollon-Datil field.     

Voluminous acid volcanism in the Busheveld Complex: A review of the Rooiberg Felsite

The 2.1 b.y. old Rooiberg Felsite roofs and is intruded by the mafic layered rocks and granites of the Bushveld Complex. The felsite unit, which locally exceeds 5 km in thickness and may represent an originally erupted volume of more than 300,000 km³, is dominated by rhyolitic to dacitic lavas with minor pyroclastic and sedimentary rock types. Volcanic rocks of more mafic composition occur towards the base of the sequence. The Rooiberg episode essentially terminated the volcanic activity in the Transvaal basin and heralded the emplacement of the Bushveld Complex. Despite the close spatial and temporal relationships between the Rooiberg Felsite and the Bushveld Complex, the precise nature of the petrogenetic link is obscure. Chemical analyses of felsite have been variously interpreted to suggest cyclic differentiation along a comagmatic trend or to demonstrate anomalous enrichment in SiO₂. Several characteristics delineate the Rooiberg Felsite as a possibly unique occurrence of rhyolitic magmatism, notably the immense volume of the unit, the marked preponderance of lavas over pyroclastic types, and the unusually great thickness and lateral extent of the flows. The thesis that the Rooiberg Felsite represents a shock-produced, meteorite-impact melt cannot be supported on the available evidence.     

Geochemistry and petrogenesis of the kilimanjaro volcanic rocks of the Amboseli area,Kenya

The paper summarizes the geochemical and petrogenetic aspects of an investigation of late Tertiary to Recent volcanic rocks in the Amboseli area of southern Kenya. A study of chemical variations in the Amboseli and Kilimanjaro lavas distinguishes a mildly alkaline series (alkali olivine basalts, trachybasalts/trachyandesites, trachytes, rhomb porphyries and phonolites) from a strongly alkaline series embracing subordinate nephelinitic, phonolitic and tephritic lavas. The two series probably evolved independently from a source in the mantle. A comparison of Kilimanjaro with other East African volcanoes shows that the focus of strongly alkaline volcanicity moved from eastern Uganda and western Kenya to northern Tanzania at the end of Miocene times. The Pliocene to Recent centres near the Kenya-Tanzania border show evidence of decreasing alkalinity from a western zone of nephelinite-phonolite volcanoes to an eastern region in which central volcanoes are characterized by the association of strongly and mildly alkaline suites.     

Explosive felsic volcanism on El Hierro (Canary Islands)

The Canary Islands consist of seven basaltic shield volcanoes whose submerged portion is much more voluminous than the subaerial part of each island. Like so many other volcanic oceanic islands, the indicative deposits of explosive felsic volcanism are not a common feature on the Canary archipelago. Hitherto, they have only been documented from the central islands of Gran Canaria and Tenerife, which are the largest volcanic complexes of the islands. On the other Canary Islands, the presence of felsic rocks is mostly restricted to intrusions and a few lava flows, generally within the succession in the oldest parts of individual islands. In this paper, we present a detailed stratigraphic, lithological and sedimentological study of a significant felsic pumice deposit on the island of El Hierro, referred here as the Malpaso Member, which represents the only explosive episode of felsic volcanism found on the Canary Islands (outside of Gran Canaria and Tenerife). The products of the eruption indicate a single eruptive event and cover an area of about 15 km². This work provides a detailed stratigraphic and chronological framework for El Hierro, and four subunits are identified within the member on the basis of lithological and granulometric characteristics. The results of this study demonstrate the importance of an explosive eruption in a setting where the activity is typified by effusive basaltic events. Given the style and the spatial distribution of the Malpaso eruption and its products, a future event with similar characteristics could have a serious impact on the population, infrastructure and economy of the island of El Hierro.     

Boninite as a possible calc-alkalic primary magma

Boninite is an unusual, plagioclase-free magnesian andesite, occurring as vesicular pillow lavas and hyaloclastites, accompanied by andesites and dacites in Chichi-jima, Bonin Islands. The Bonin Islands belong to the Izu-Mariana arc and consist of dominant volcanic rocks and subordinate sedimentary rocks of late Oligocene-early Miocene age. The chemistry of boninite is characterized by high contents of MgO. Cr and Ni similar to primitive basalts, but apparently in ill accord with its relatively high SiO₂ content of ? 55%. The relation of SiO₂ to total FeO/MgO ratio indicates that boninite belongs to the cale-alkalic rock suite. The mineralogy of boninite consists of olivine (Fo87-90), orthopyroxene (En87-90), clinopyroxene (Wo38-35En37-44Fs25-21), hydrous glass and Cr-spinel, Experimental studies show that the magma of boninite composition could be in equilibrium with upper mantle peridotite at pressures less than 17 kb and temperatures of 1200–1050°C under high P_H2_O. It is suggested that boninite is a sea-floor quenched product (900°C) of a direct partial melt of the upper mantle. Related andesites and dacites are considered to be probably fractional crystallization products from the same magma.     

Eruption of Piip Crater (Kamchatka)

In autumn of 1966 on the northern slope of Kliuchevskoy volcano a chain of new adventive craters broke out at the height of about 2200 m. Eighty-four hours before the beginning of the eruption a swarm of preliminary volcanic earthquakes had appeared. The number of preliminary shocks was 457 with total energy of 4 × 10¹⁷ erg. With the beginning of the lava flow the earthquakes stopped and a continuous volcanic tremor appeared. The total energy of volcanic tremor amounts to 10¹⁶ erg. During the eruption numerous explosive earthquakes with the energy of 10¹⁵–10¹⁶ erg were recorded and besides the microbarograph of the Volcanostation recorded 393 explosions with an energy more than 10¹³ erg and their total energy was equal to 10¹⁷ erg. All together it has been formed 8 explosive craters and the lowest 9th crater was effusive. The slag cone was formed round this effusive crater, the lava effusion of basaltic-andesite composition (52,5% SiO₂) tooke place from the lava boccas at the cone base and from the crater. The lava flow covered a distance of 10 km along the valley of the Sopochnoy river and descended to a height of about 800 m. The lava flow velocity at the outflow reached 800 m/hr, the lava temperature was 1050°C. The effused lava volume amounts to 0.1 km³. The eruption stopped on December 25–26, 1966.     

Geochronology of Gran Canaria,Canary Islands: Age of shield building volcanism and other magmatic phases

Forty-six new K-Ar age determinations are presented on whole rock samples and mineral separates from volcanic and subvolcanic rocks of Gran Canaria. The main subaerial shield building basaltic volcanism with estimated volume of about 1000 km³ was confined to the interval about 13.7 m.y. to 13.5 m.y. ago in the middle Miocene. Substantial volume (～100 km³) of silicic volcanics (trachyte and peralkaline rhyolite) were erupted with no detectable time break following the basaltic volcanism, essentially contemporaneous with formation of a large collapse caldera at 13.4±0.3 m.y. ago. Trachytic to phonolitic volcanism continued intermittently in the waning states of activity until about 9 m.y. ago. Following a long hiatus there was resurgence of volcanism with eruption of about 100 km³ of basanitic to hauyne phonolitic rocks of the Roque Nublo Group between about 4.4 m.y. and 3.4 m.y. ago in the Pliocene. After a hiatus of less than 1.0 m.y., olivine nephelinite magmas were erupted and this activity continued intermittently until relatively recent times, the younger eruptives being mainly basanitic in composition. The volume of volcanic products in this phase probably does not exceed 10 km³. Thus the volume of all the resurgent volcanism comprises less than 10 percent of the subaerially exposed part of Gran Canaria. The results show that the subaerial main shield building phase of volcanism in Gran Canaria, consisting of mildly alkali to transitional basalts, occurred over a time interval that was less than 0.5 m.y. Magmatic evolution on Gran Canaria appears to be similar to that found on other basaltic volcanoes in oceanic regions. Thus volcanoes in the Hawaiian, Marquesas and Society Islands all were built by basaltic lavas in similar short-lived episodes of volcanism. In some Hawaiian volcanoes, a resurgent phase of volcanism of strongly undersaturated basalts of small volume is recognized following a long hiatus, again similar to that found on Gran Canaria. The relatively large volume of silicic lavas erupted in Gran Canaria immediately following the main basaltic shield building phase is, however, not matched in the Pacific volcanoes mentioned.     

Liparitic volcanism of some regional volcanic structures in Kazakhstan,Middle Asia and Caucasus

Liparitic volcanism is a typical feature of the orogenic phase giving rise to the Kazakhstan, Middle Asia and Caucasus folded systems. The main characteristics of the liparitic volcanism common to these three regions are the following:

1. Geo-structural zonation of the volcanic structures.
2. Dismembered Moho surface within the volcanic structures.
3. Synchronous, yet independent evolution of liparitic and andesitic volcanisms.
4. Ignimbritic character of the liparitic volcanism.
5. Lateral petrochemical zonation with some features common to the liparitic and andesitic rock series.

Geo-structural and petrochemical zonations are likely governed in the regions studied by a deep-seated plutonic body.     

Geochemistry of the volcanics of central Mexico

The Tertiary and Recent volcanics of Mexico occur in two provinces. The Cordillera Province is made up of about 1700 m of ignimbrite sheets overlain and intercalated in the upper part by olivine basalt and basaltic andesite. The Rio Lerma Province extends transversely across Mexico and in the Valley of Mexico the lavas consist mainly of andesite and dacite, 68 % of those analysed having 62 | 4.7 % SiO₂. A total of 108 chemical analyses were made for the major elements, 90 of these including determinations of Cr, Ni, Cu, Zn, Rb, Sr, Ba, Th and Pb for two areas, the Valley of Mexico in the Rio Lerma Province and the Guadalajara region which lies at the intersection of the two provinces. Computer constructions of normative components in the basalt tetrahedron and other projections support an origin of partial melting of tholeiitic to pyrolitic material for the production of andesite. The Guadalajara lavas have consistently higher K/SiO₂ and K/Rb ratios and lower Mg/SiO₂ ratio than the Valley of Mexico rocks suggesting generation at greater depth.     

The drift of zooplankton in a lake-outlet (Glatt) in a day-night-rhythm depending from the water level

To give an indication on the influence of the dynamics and behavior of lake plankton on the seston composition in the outlet, four 24-hour sampling sessions were made in the Greifensee (situated near Zürich, Switzerland) and its outlet (River Glatt). The most important crustacean species studied wereEudiaptomus gracilis, Cyclops abyssorum, Cyclops vicinus, Mesocyclops leuckarti andDaphnia spp.Leptodora kindtii was found during one sampling only. No evidence of shore avoidance was found. The vertical migration in the lake especially in the upper layer (0–6 m) is believed to have an influence on the amount of plankton which is flushed into the outlet. Although the composition and concentration of the plankton at the deepest point of the lake have been known, no accurate predictions on the quality of the plankton close to shore or in the outlet were possible.     

Petrology of volcanic rocks from anjouan,comores archipelago

Anjouan is an extinct and substantially denuded volcanic island, belonging to the Comores Archipelago, a chain of volcanic islands in the northern Mozambique Channel. Volcanism was probably controlled by a complex regional stress pattern, closely implicated with the recent geotectonic evolution of East Africa and the western Indian Ocean. On Anjouan a lengthy period of shield construction was succeeded by fissure-controlled eruptions forming three extended peninsulas to the north, south and west. A ‘rejuvenescent’ phase of activity erupted lavas on to an erosional surface formed during a period of quiescence following build-up of the main volcanic edifice. Lavas of the shield-building stage comprise ankaramites, oceanites and olivine basalts, with minor development of hawaiites and trachytes. The fissure controlled eruptions are also mainly basaltic although generally more alkaline, while rejuvenescent lavas comprise basanites and a significant proportion of derivatives following a trend towards phonolite. Coarse-grained xenoliths are found in lavas of the latter two phases, while a gabbroic intrusion (the ‘Tatinga Intrusion’) is exposed in the centrally-situated Cirque de Bambao in the vicinity of N’Tingui (1595 m). The main chemical trends and petrographic characteristics of the Anjouan lavas are related to the eruptive sequence.