Archaean to Proterozoic Crustal Evolution in the Central Zone of the Limpopo Belt (South Africa-Botswana): Constraints from Combined U-Pb and Lu-Hf Isotope Analyses of Zircon

A combined set of U–Pb and Lu–Hf in situ laser ablationICP-(MC)-MS zircon analyses were obtained from orthogneissesand granitoids in the Central Zone of the Limpopo Belt, whichcomprises the Beit Bridge and Mahalapye complexes. The resultsindicate that by combining the two isotope systems primary magmaticzircon domains can be distinguished from those formed duringlater metamorphic events, even if the distinct zircon domainsunderwent multiple Pb loss and the texture–age relationships,as obtained by cathodoluminescence images and U–Pb analyses,are ambiguous. Furthermore, the applied technique allows distinctionof zircon grains formed in juvenile magmas from those generatedby melting of older continental crust or affected by substantialcrustal contamination. The combined U–Pb and Lu–Hfdata reveal that the Sand River gneiss suite of the Beit BridgeComplex was emplaced at 3283 ± 8 Ma and formed from meltingof an older Archaean crust, which was derived from a depletedmantle source at around 3·65 Ga. The hafnium model age(T_DM^Hf) is significantly older than those obtained from zirconsfrom numerous Neoarchaean granitoids of the Beit Bridge Complex,comprising the Singelele gneiss (2647 ± 12 Ma), the Bulaigranite (2612 ± 7 Ma), the Regina gneiss (2649 ±9 Ma) and two samples of the Zanzibar gneiss (2613 ±6 Ma). These granitoids show initial Hf(t) values between +0·5 and –7·1, which correspond to initialT_DM^Hf between 3·46 and 3·01 Ga. These variableT_DM^Hf_initial and Hf(t)_initial values are interpreted to be theresult of different mixtures of reworked 3·65 Ga Palaeoarchaeancrust with juvenile magmas extracted from the depleted mantleduring the Neoarchaean at 2·65 Ga. This conclusion issupported by results obtained from the Mahalapye Complex, whichwas affected by migmatization and granite intrusions duringthe Palaeoproterozoic at 2·02–2·06 Ga. TheMokgware granite (2019 ± 9 Ma) contains zircon xenocrystswith Pb–Pb ages of 2·52–2·65 Ga and2·93 Ga and hafnium model ages of 3·0–3·4Ga, indicating that this granite is derived from remelting ofArchaean crust. In contrast, uniform T_DM^Hf_initial ages of 2·61–2·67Ga obtained from a diorite gneiss (2061 ± 6 Ma) of theMahalapye Complex indicate that its protolith may have beenformed from remelting of a Neoarchaean juvenile crust. VariableHf(t)_initial values from –3·7 to +6·3 ofzircon cores (2711 ± 11 Ma) in an adjacent leucosomealso support a model of mixing of juvenile mantle derived matterwith older crust in the Neoarchaean. KEY WORDS: Archaean; Palaeoproterozoic; Limpopo Belt; zircon, U–Pb dating; Lu–Hf isotopes; LA-ICP-MS     

Inheritance of early Archaean Pb-isotope variability from long-lived Hadean protocrust

Comparison of initial Pb-isotope signatures of several early Archaean (3.65-3.82 Ga) lithologies (orthogneisses and metasediments) and minerals (feldspar and galena) documents the existence of substantial isotopic heterogeneity in the early Archaean, particularly in the ²⁰⁷Pb/²⁰⁴Pb ratio. The magnitude of isotopic variability at 3.82-3.65 Ga requires source separation between 4.3 and 4.1 Ga, depending on the extent of U/Pb fractionation possible in the early Earth. The isotopic heterogeneity could reflect the coexistence of enriched and depleted mantle domains or the separation of a terrestrial protocrust with a ²³⁸U/²⁰⁴Pb (µ) that was ca. 20-30% higher than coeval mantle. We prefer this latter explanation because the high-µ signature is most evident in metasediments (that formed at the Earth's surface). This interpretation is strengthened by the fact that no straightforward mantle model can be constructed for these high-µ lithologies without violating bulk silicate Earth constraints. The Pb-isotope evidence for a long-lived protocrust complements similar Hf-isotope data from the Earth's oldest zircons, which also require an origin from an enriched (low Lu/Hf) environment. A model is developed in which ́.8-Ga tonalite and monzodiorite gneiss precursors (for one of which we provide zircon U-Pb data) are not mantle-derived but formed by remelting or differentiation of ancient (ca. 4.3 Ga) basaltic crust which had evolved with a higher U/Pb ratio than coeval mantle in the absence of the subduction process. With the initiation of terrestrial subduction at, we propose, ca. 3.75 Ga, most of the ́.8-Ga basaltic shell (and its differentiation products) was recycled into the mantle, because of the lack of a stabilising mantle lithosphere. We argue that the key event for preservation of all ́.8-Ga terrestrial crust was the intrusion of voluminous granitoids immediately after establishment of global subduction because of complementary creation of a lithospheric keel. Furthermore, we argue that preservation of ́.8-Ga material (in situ rocks and zircons) globally is restricted to cratons with a high U/Pb source character (North Atlantic, Slave, Zimbabwe, Yilgarn, and Wyoming), and that the Pb-isotope systematics of these provinces are ultimately explained by reworking of material that was derived from ca. 4.3 Ga (i.e. Hadean) basaltic crust.     

胶北太古宙早期锆石U-Pb定年及Hf同位素研究：华北克拉通古老陆壳增生及再循环的证据

古老陆壳物质的发现与鉴别是探索地球早期陆壳形成与演化历史的重要内容之一,锆石U-Pb年龄结合Hf同位素研究是该研究的重要手段。本文通过对胶北地体内一个长英质副片麻岩中的锆石开展系统的原位U-Pb定年和微量、稀土元素分析,获得了多个太古宙早期的锆石。根据这些锆石的阴极发光图像、Th/U比值及稀土元素球粒陨石标准化配分模式,它们具有典型岩浆锆石的特征,其中2个分析点给出了3413Ma和3400Ma(~3.4Ga)的锆石U-Pb年龄,7个分析点给出3547±19Ma(MSWD=1.16)的锆石U-Pb年龄,指示太古宙早期的陆壳岩浆事件;结合华北克拉通其它地区的类似研究结果,暗示华北克拉通可能曾经存在比现今出露面积更大的太古宙早期的古老陆壳。这些古老锆石的Hf同位素分析显示,它们的εHf(t)值在-6.19~0.95之间,平均为-2.54,两阶段Hf模式年龄在3737~4353Ma之间,平均值为~4.1Ga,远大于锆石的U-Pb年龄,指示华北克拉通存在~4.1Ga的地壳增生作用及古老陆壳(3.55Ga)的再循环。     

闽西南清流地区加里东期花岗岩锆石U-Pb年代学及Hf同位素组成研究

通过对玮埔岩体两个代表性样品进行锆石的LA-ICP-MSU-Pb测年获得的206Pb/238U加权平均年龄分别为(429.9±3.0)Ma、(446.3±4.0)Ma,证明该岩体确实不是最早认为的印支期花岗岩,而是加里东期岩体。同时对宁化岩体一个样品的锆石LA-ICP-MSU-Pb测年结果得到206Pb/238U加权平均年龄为(448.2±2.5)Ma,同样属于加里东期岩体。进一步对闽西南清流地区玮埔和宁化岩体的锆石Lu-Hf同位素组成分析表明,εHf(t)值主要集中在-0.8～-10.4之间,且Hf二阶段模式年龄(TDM2)集中在1.72～2.34Ga之间,表明其岩浆源区来自华夏地块元古代地壳物质。并结合其他己发表的相关年代学和地球化学资料,可以推断包括玮埔和宁化岩体在内的华南内陆地区加里东期花岗岩很可能是元古宙基底深熔而成的产物;其形成与陆内地壳物质叠置加厚所引起的再造作用关系紧密。     

华北克拉通南缘五佛山群沉积时代和物源区分析:碎屑锆石U-Pb年龄和Hf同位素证据

河南嵩山地区位于华北克拉通南缘,其早前寒武纪结晶基底主要由新太古代登封群表壳岩、TTG质片麻岩和古元古代嵩山群石英岩,以及新太古代-古元古代的花岗质岩石组成。五佛山群角度不整合覆盖于登封群和嵩山群之上,主要由石英砂岩组成,夹少量的粉砂质页岩和薄层灰岩,为该地区太古宙-古元古代结晶基底之上分布广泛的第一沉积盖层。探讨其沉积时代和物质来源,对揭示华北克拉通南缘前寒武纪地壳演化过程具有重要意义,并可为华北南缘前寒武纪地层框架的建立和对比提供依据。本文对五佛山群底部马鞍山组两个石英砂岩样品的碎屑锆石进行LA-ICP-MS U-Pb年龄测定,获得最年轻的207Pb/206Pb年龄分别为(1732±11)Ma和(1655±22)Ma,说明五佛山群形成时代的下限为古元古代晚期,与华北克拉通南缘熊耳群火山-沉积岩系之后的其他沉积盖层年代相当。五佛山群碎屑锆石207Pb/206Pb年龄范围为2816~1655 Ma,主要集中于2100~1800 Ma之间(约占60%),年龄主峰值为(1.93±0.10)Ga,部分年龄分布于2500~2100 Ma之间(约占24%),说明其沉积物质主要来源于古元古代的地质体,相比华北克拉通其他地区同时代的沉积地层碎屑锆石年代学研究结果,本区来自太古宙的物源极少。五佛山群马鞍山组碎屑锆石的U-Pb年龄反映了嵩山地区在1.93 Ga左右发生过重要的构造-热事件,与华北克拉通古元古代中期发生的变质作用时间(约1.91 Ga)一致。碎屑锆石εHf(t)值为–14.3~4.6,Hf的两阶段模式年龄分布于2363~3672 Ma之间,明显大于其207Pb/206Pb年龄,大部分锆石的Hf同位素组成集中于2.50 Ga和2.80 Ga地壳演化线区域内,揭示了新太古代为华北克拉通南缘重要的陆壳生长期。     

Geochronology and Petrogenesis for the Protolith of Biotite Plagioclase Gneiss at Lianghe, Western Yunnan

In this paper,we report an integrated study of U-Pb age and Hf isotope compositions of zircons from biotite plagioclase gneiss at Lianghe in western Yunnan.The zircons preserved inherited core and rim texture.Igneous zircon grains and rims yielded a weighted mean ~(206)Pb/~(238)U age of 120.4±1.7 Ma,theirε_(Hf)(120 Ma)values were mainly negative ranging from-13.9 to-10.7,with Hf model ages between 1.9 Ga and 2.0 Ga,some zircons had positiveε_(Hf)(120 Ma)values ranging from 0.2 to 2.1.The inherited cores ...     

U–Pb and Hf-isotope analysis of zircons in mafic xenoliths from Fuxian kimberlites: evolution of the lower crust beneath the North China craton

Mafic xenoliths from the Paleozoic Fuxian kimberlites in the North China craton include garnet granulite, and minor pyroxene amphibolite, metagabbro, anorthosite and pyroxenite. The formation conditions of the amphibolites are estimated at 745–820 °C and 7.6–8.8 Kb (25–30 km); the granulites probably are derived from greater depths in the lower crust. LAM-ICPMS U–Pb dating of zircons from four granulites reveals multiple age populations, recording episodes of magmatic intrusion and metamorphic recrystallisation. Concordant ages and upper intercept ages, interpreted as minimum estimates for the time of magmatic crystallisation, range from 2,620 to 2,430 Ma in three granulites, two amphibolites and two metagabbros. Lower intercept ages, represented by near-concordant zircons, are interpreted as reflecting metamorphic recrystallisation, and range from 1,927 to 1,852 Ma. One granulite contains two metamorphic zircon populations, dated at 1,927±55 Ma and 600–700 Ma. Separated minerals from one granulite and one amphibolite yield Sm–Nd isochron ages of 1,619±48 Ma (¹⁴³Nd/¹⁴⁴Nd)i=0.51078), and 1,716±120 Ma (¹⁴³Nd/¹⁴⁴Nd)i=0.51006), respectively. These ages are interpreted as recording cooling following metamorphic resetting; model ages for both samples are in the range 2.40–2.66 Ga. LAM-MC-ICPMS analyses of zircon show a range in ¹⁷⁶Hf/¹⁷⁷Hf from 0.28116 to 0.28214, corresponding to a range of _Hf from –34 to +12. The relationships between ²⁰⁷Pb/²⁰⁶Pb age and _Hf show that: (1) the granulites, amphibolites and metagabbro were derived from a depleted mantle source at 2.6–2.75 Ga; (2) zircons in most samples underwent recrystallisation and Pb loss for 100–200 Ma after magmatic crystallisation, consistent with a residence in the lower crust; (3) metamorphic zircons in several samples represent new zircon growth, incorporating Hf liberated from breakdown of silicates with high Lu/Hf; (4) in other samples metamorphic and magmatic zircons have identical ¹⁷⁶Hf/¹⁷⁷Hf, and the younger ages reflect complete resetting of U–Pb systems in older zircons. The Fuxian mafic xenoliths are interpreted as the products of basaltic underplating, derived from a depleted mantle source in Neoarchean time, an important period of continental growth in the North China craton. Paleoproterozoic metamorphic ages indicate an important tectonic thermal event in the lower crust at 1.8–1.9 Ga, corresponding to the timing of collision between the Eastern and Western Blocks that led to the final assembly of the North China craton. The growth of metamorphic zircon at 600–700 Ma may record an asthenospheric upwelling in Neoproterozoic time, related to uplift and a regional disconformity in the North China craton.     

桂东大瑶山南缘社山花岗闪长岩的锆石U-Pb年龄及Hf同位素特征: 对区内加里东期成岩成矿作用的制约

利用激光剥蚀(MC)-ICP-MS方法对桂东大瑶山南缘的社垌钨钼矿床中的花岗岩类进行研究, 精确限定社山黑云母花岗闪长岩(SD256)中锆石的206Pb/238U加权平均年龄为438.7±3.0 Ma(MSWD=0.22), 侵位于平头背石英砂岩的花岗闪长(斑)岩脉(SD190)形成于438.1±2.6 Ma(MSWD=0.28);花岗岩中新生岩浆锆石的Hf同位素特征较为一致, 176Hf/177Hf比值分布于0.282 406~0.282 518, 对应的ε_Hf(438 Ma)值变化于-3.7~0, 两阶段Hf模式年龄(T_DM2)集中在1 226~1 417 Ma之间.这表明大瑶山地区社山花岗闪长岩类的形成时间在438 Ma左右(加里东期), 成岩成矿作用可能与中元古代新生地壳物质(1.2~1.4 Ga)的部分熔融密切相关.结合区域内已有可靠年龄进行分析, 认为华南加里东期成岩成矿作用应该不是呈简单的北东向分布, 而是呈面状展布, 且该期构造-岩浆-成矿运动可能是引起华南地区在印支期、燕山早期发生大规模的岩浆作用和金属成矿作用的关键原因之一.      

扬子陆块三峡地区莲沱组砂岩中碎屑锆石U-Pb年龄、Hf同位素组成及其地质意义

对扬子陆块三峡地区黄牛岩剖面莲沱组顶部砂岩中的120颗碎屑锆石进行了U-Pb定年和Lu-Hf同位素分析.结果显示,黄牛岩剖面莲沱组中碎屑锆石的年龄谱具有～880～800 Ma、～2000 Ma、～2500 Ma及～2700 Ma的峰值,其中最年轻的碎屑锆石年龄为724±8 Ma.结合前人对该地区莲沱组顶部凝灰岩开展的年...     

U‐Pb Ages and Hf Isotope of Zircons from a Carbonatite Dyke in the Bayan Obo Fe‐REE Deposit in Inner Mongolia: its Geological Significance

Detailed studies on U-Pb ages and Hf isotope have been carried out in zircons from a carbonatite dyke associated with the Bayan Obo giant REE-Nb-Fe deposit, northern margin of the North China Craton(NCC), which provide insights into the plate tectonic in Paleoproterozoic. Analyses of small amounts of zircons extracted from a large sample of the Wu carbonatite dyke have yielded two ages of late Archaean and late Paleoproterozoic(with mean 207 Pb/206 Pb ages of 2521±25 Ma and 1921±14 Ma, respectively). Mineral inclusions in the zircon identified by Raman spectroscopy are all silicate minerals, and none of the zircon grains has the extremely high Th/U characteristic of carbonatite, which are consistent with crystallization of the zircon from silicate, and the zircon is suggested to be derived from trapped basement complex. Hf isotopes in the zircon from the studied carbonatite are different from grain to grain, suggesting the zircons were not all formed in one single process. Majority of εHf(t) values are compatible with ancient crustal sources with limited juvenile component. The Hf data and their TDM2 values also suggest a juvenile continental growth in Paleoproterozoic during the period of 1940–1957 Ma. Our data demonstrate the major crustal growth during the Paleoproterozoic in the northern margin of the NCC, coeval with the assembly of the supercontinent Columbia, and provide insights into the plate tectonic of the NCC in Paleoproterozoic.     

扬子陆块西南缘3.8 Ga碎屑锆石及其地质意义

古老锆石和岩石的发现,是探索地球早期地质演化的关键.为进一步揭示扬子陆块基底物质组成和早期地壳形成演化,采用LA-ICP-MS锆石微区U-Pb测年,对扬子陆块西南缘禄丰地区东川群变质砂岩进行了年代学研究,发现3 822±21 Ma的古老碎屑锆石.这是目前在扬子陆块获得的第2颗>3.8 Ga的古老锆石,也是目前在该地区发现的最老锆石.变质砂岩碎屑物质主要包括4个峰值年龄（~2 320 Ma、~2 162 Ma、~2 036 Ma和~1 915 Ma）,2颗最年轻的锆石年龄基本限定了东川群早期最大沉积时限,与区域上火山岩时代相吻合.另外还包含少量中-晚太古代（2.6~2.9 Ga）和始太古代（3.7~3.8 Ga）的碎屑物质.Hf同位素组成显示这些碎屑锆石具有不同成因,其中2 674~3 822 Ma的碎屑锆石总体具有正的ε_Hf（t）值和2.9~3.9 Ga的两阶段模式年龄,暗示扬子陆块在冥古宙-古太古代时期就有一定规模的新生陆壳分布.古元古代（1.9~2.4 Ga）的岩浆活动除有少量古元古代（2.3~2.4 Ga）新生地壳组分熔融外,大多为太古宙（2.5~3.7 Ga）古老地壳部分熔融.中元古代更多表现为古老地壳的熔融和物质再循环.研究结果为深化扬子陆块早前寒武纪地质演化认识提供了新资料.      

Geochronology and Nd-Sr systematics of Lusatian granitoids: significance for the evolution of the Variscan orogen in east-central Europe

A variety of pre-Variscan granitoids and two Variscan monzogranites occurring in the central and western parts of the Lusatian Granodiorite Complex (LGC), Saxonia were dated by the single zircon evaporation method, complemented by whole rock Nd isotopic data and Rb-Sr whole rock and mineral ages. The virtually undeformed pre-Variscan granitoids constitute a genetically related, mostly peraluminous magmatic suite, ranging in composition from two-mica granodiorite, muscovitebearing biotite quartz diorite (tonalite) and granodiorite to biotite granodiorite and monozogranite. ²⁰⁷Pb/²⁰⁶Pb isotopic ratios derived from the evaporation of single zircons separated from 13 samples representing the above rock types display complex spectra which document significant involvement of late Archaean to late Proterozoic continental crust in the generation of the granitoid melts. Mean ²⁰⁷/Pb/²⁰⁶Pb ages for zircons considered to reflect the time of igneous emplacement range between 542 ± 9 and 587 ± 17 Ma, typical of the Cadomian event elsewhere in Europe, whereas zircon xenocrysts yielded ages between 706 ± 13 and 2932 ± Ma. Detrital zircons from greywackes intruded by the granitoids and found as xenoliths in them provided ages between 1136 ± 22 and 2 574 ± Ma. Rb-Sr whole rock data display good to reasonable linear arrays that, with one exception, correspond to the emplacement ages established for the zircons. Two post-tectonic Variscan monzogranites yielded identical ²⁰⁷/Pb/²⁰⁶Pb single zircon ages of 304 ± 14 Ma and record the end of Variscan granitoid activity in the LGC.The variations in Nd and Sr isotopic data of the Cadomian granitoids are consistent with an origin through the melting and mixing of Archean to early Proterozoic crust with variable proportions of mantle-derived, juvenile magmas. Such mixing may have occurred at the base of an active continental margin or in an intraplate setting through plume-related magmatic underplating. The LGC is interpreted here as a Cadomian (Pan-African) terrane distinct from adjacent Variscan and pre-Variscan domains, the origin of which remains obscure and which probably became involved in Palaeozoic terrane accretion late in the Variscan event.     

Destruction of ancient lower crust through magma underplating beneath Jiaodong Peninsula, North China Craton: U-Pb and Hf isotopic evidence from granulite xenoliths

Zircons from granulite xenoliths entrained in a Late Cretaceous mafic dike in the Jiaodong Peninsula, North China Craton (NCC), show three distinct U-Pb age populations. Part of the old zircon grains yield discordant data that project to ages of about 2.4 to 2.5 Ga, a few grains indicate growth at about 2.0 Ga and a third group yield Cretaceous ages with peaks at 120 and 90 Ma. The oldest zircons give Hf T_DM model ages of 2.6-2.8 Ga. These results demonstrate the existence of original Archean lower crust in the Jiaodong region. Zircons of 2.0 Ga have similar Hf T_DM model ages as the Neoarchean-Paleoproterozoic grains, suggesting that these zircons were products of metamorphic recrystallization due to thermal event without juvenile input. Early Cretaceous zircons yield εHf(t) values of − 21 to − 12 and Late Cretaceous zircons large variable εHf(t) from + 4 to − 50. These data suggest that magmatic underplating occurred in the Neoarchean to Earliest Proterozoic lower crust of the NCC, both in the Early and Late Cretaceous. It is suggested that the Mesozoic magma underplating, which also provided the heat source for the voluminous Mesozoic magmatism in the NCC, significantly modified the composition of the Archean to Paleoproterozoic lower crust of the NCC.     

鄂尔多斯盆地周缘地壳形成与演化历史:来自锆石U-Pb年龄与Hf同位素组成的证据

锆石U-Pb定年及Hf同位素测定结果表明,鄂尔多斯盆地周缘的华北板块北缘、兴蒙造山系及扬子板块-秦岭-大别-苏鲁造山带等构造单元系统具有明显不同的形成与演化历史。华北板块北缘锆石年龄平均值为1 837 Ma,最强烈的岩浆活动出现于2 200~1 800 Ma,该期锆石约占全部的40%;次为强烈的岩浆活动在2 800~2 200 Ma,其众数在全部锆石中约占30%;1 500~1 200 Ma、500~100 Ma这两个阶段形成的锆石在全区所占比例各约为15%。华北板块北缘最突出的特征是基本不含1 000~700 Ma期间形成的锆石,>3 000 Ma的锆石在全区分布极为有限。锆石Hf同位素亏损地幔模式年龄表明华北板块北缘平均值为2.55 Ga,较U-Pb平均年龄老,说明2 200~1 800 Ma期间形成的锆石含有较多的古老地壳再循环组分。Hf亏损地幔模式年龄最强峰值约为2.8 Ga,与全岩Nd亏损地幔模式年龄的峰值相一致,Hf模式年龄为3.0~2.25 Ga的颗粒占全部的近95%,证明华北板块北缘的地壳增生主要在太古宙至古元古代期间。Hf同位素亏损地幔模式年龄>3.0 Ga的锆石颗粒所占比例不到0.1%,另外近5%锆石的模式年龄分布于中元古代。晚古生代-中生代所形成的锆石均是先存地壳组分,尤其是中元古代增生地壳的熔融作用形成。兴蒙造山系中锆石U-Pb年龄平均值为497 Ma,最强峰分布于石炭纪(约320 Ma),石炭纪-二叠纪末(350~250 Ma)形成的锆石所占比例达30%以上。新元古代至早古生代(600~440 Ma)形成的锆石占全部锆石的55%以上,而中元古代末-新元古代期间(1 200~600 Ma)形成的锆石在全区仅占4%。中元古代以前形成的锆石非常有限,说明该区最早形成的地壳组分在兴蒙造山系的形成过程中较充分地参与到后期的岩浆作用过程中。兴蒙造山系中锆石相应的Hf同位素亏损地幔模式年龄平均为1.13 Ga,明显较相应的U-Pb年龄老,最强峰值出现于约0.6 Ga。Hf亏损地幔模式年龄为0.7~0.28 Ga的颗粒在兴蒙造山系所占比例达57%,证明该区最强烈的地壳增生发生于新元古代至古生代期间。Hf同位素亏损地幔模式年龄分布于1.5~0.7 Ga的锆石在全区约占38%,说明此期间也是该区地壳较强烈的增生期。Hf亏损地幔模式年龄大于1.5 Ga的锆石所占比例不到5%,古生代以后兴蒙造山系也基本没有明显的地壳增生。扬子与秦岭-大别-苏鲁造山带构造单元中的锆石U-Pb年龄平均为799 Ma,年龄为1 300~750 Ma的锆石在全部锆石中约占70%。晚古生代-燕山期形成的锆石约占20%。年龄在3 500~2 650 Ma、2 118~1 680 Ma的锆石在该区各约占5%。结合扬子与秦岭-大别-苏鲁造山带平均为1.56 Ga的Nd亏损地幔模式年龄特征,说明1 300~750 Ma期间该区较强烈的岩浆作用事件中有较多的古老地壳组分加入其中。锆石U-Pb年龄及Hf同位素组成均说明鄂尔多斯盆地周缘各构造单元具有不同的形成演化历史。地壳是幕式增长的,但各构造单元每幕发生的时间、强度存在明显差别。因此,由盆地中不同时代地层中碎屑锆石U-Pb年龄及Hf同位素组成及全岩Nd同位素特征的系统研究可反演盆地物源供给与周围构造单元之间的关系。     

粤北大宝山北部九曲岭花岗岩锆石U-Pb年龄和Hf同位素特征

采用LA-MC-ICP-MS锆石U-Pb年龄和Hf同位素测定技术,对大宝山北部九曲岭花岗岩进行测定。结果显示来自九曲岭岩体的三个花岗岩样品的U-Pb谐和年龄分别为169.0±1.9 Ma,171.3±1.4 Ma,450.2±2.9 Ma,表明九曲岭花岗岩体为一复式岩体,主体为燕山期花岗岩,但局部有加里东期花岗岩。锆石Lu-Hf同位素组成测定显示:燕山期岩体的锆石具有低的负εHf(t)值(分别为–12.19~–8.51和–19.47~–8.63),二阶段模式年龄(tDM2)为1.45~1.63 Ga,与华南燕山期花岗岩特征一致,表明其主要是下地壳重熔的产物;加里东期岩体的锆石具有高的εHf(t)值(8.89~12.06),tDM2为0.62~0.78 Ga,表明其源区有新生地壳物质的贡献,暗示早古生代加里东期大宝山区域处于伸展环境。     

Rate of growth of the preserved North American continental crust: Evidence from Hf and O isotopes in Mississippi detrital zircons

Detrital zircons from the Mississippi River have been analyzed for U-Th-Pb, Lu-Hf and O isotopes to constrain the rate of growth of the preserved North American continental crust. One hundred and forty two concordant zircon U/Pb dates on grains mounted in epoxy, obtained by Excimer laser ablation ICP-MS method, resolved six major periods of zircon crystallization: 0-0.25, 0.3-0.6, 0.95-1.25, 1.3-1.5, 1.65-1.95 and 2.5-3.0 Ga. These age ranges match the ages of the recognized lithotectonic units of the North American continent in the hinterland of the Mississippi River. Ninety-six zircons mounted on tape, which show no age zonation and were within 7.5% of concordance, were selected to represent the six U/Pb age time intervals and analyzed for Lu-Hf and O isotope by laser ablation MC-ICP-MS and SHRIMP II, respectively. The δ¹⁸O values of the zircons show a small step increase in the maximum δ¹⁸O values at the Archean-Proterozoic boundary from 7.5‰ in the Archean to 9.5‰, and rarely 13‰, in the Proterozoic and Phanerozoic. However, the average value of δ¹⁸O in zircons changes little with time, showing that the increase in the maximum δ¹⁸O values between 2.5 and 2.0 Ga, which can be attributed to an increase in the sediment content of the source regions of younger granitoids, is largely balanced by an increase in zircons with anomalously low δ¹⁸O, which can be attributed to hydrothermally altered crust in the granitoid source region.εHf_i values for the zircons range from 13.1 to −26.9. Zircons derived from juvenile crust, which we define as having mantle δ¹⁸O (4.5-6.5‰) and lying within error of the Hf depleted mantle growth curve, are rare or absent in the Mississippi basin. The overwhelming majority of zircons crystallized from melted pre-existing continental crust, or mantle-derived magmas that were contaminated by continental crust. The average time difference between primitive crust formation and remelting for each of the recognized lithotectonic time intervals, which is defined as crustal incubation time in this study, is 890 ± 460 Myr. There is also a suggestion that the crustal incubation time increases with decreasing age in the Mississippi basin, which is consistent with the declining role of radioactive heat production in the lower crust with time.The average Hf model age (1.94 Ga), weighted by fraction of zircons in the river load is in reasonable agreement with the Nd model age (1.7 Ga) for the Mississippi River. However, if the zircons are weighted by the area of North America covered by the six recognized periods of zircon crystallization the average model age is 2.35 Ga, which compares favorably with an area weighted Nd model age of 2.36 Ga. Our preferred approach is to use the measured O isotope values to constrain variations in the ¹⁷⁶Lu/¹⁷⁷Hf ratio of the granitic source region from which the zircons crystallized, making the assumption that zircons with mantle-like O isotopic ratios have higher ¹⁷⁶Lu/¹⁷⁷Hf than zircons with higher O isotope values. This method gives an average Hf model age of 2.53 Ga, which is 180 Myr older than the constant ¹⁷⁶Lu/¹⁷⁷Hf calculation.The area weighted zircon Hf model ages show two distinct periods of crust formation for the North American continent, 1.6-2.2 and 2.9-3.4 Ga. At least 50% of the preserved North American continental crust was extracted from the mantle by 2.9 Ga and 90% by 1.6 Ga. Two similar periods of crustal growth are also recognized in Gondwana (Hawkesworth C. J. and Kemp A. I. S. (2006) Using hafnium and oxygen isotopes in zircons to unravel the record of crustal evolution. Chem. Geol.226, 144-162.), suggesting that these may be periods of global continental crustal growth. However, we stress that more data from other continents are required before the hypothesis of episodic global continental growth can be accepted with confidence.     

Zircon trace element characteristics and ages in granulite xenoliths: a key to understanding the age and origin of the lower crust,Arkhangelsk kimberlite province,Russia

Garnet granulite and pyroxenite xenoliths from the Grib kimberlite pipe (Arkhangelsk, NW Russia) represent the lower crust beneath Russian platform in close vicinity to the cratonic region of the north-eastern Baltic (Fennoscandian) Shield. Many of the xenoliths have experienced strong interaction with the kimberlite host, but in others some primary granulite-facies minerals are preserved. Calculated bulk compositions for the granulites suggest that their protoliths were basic to intermediate igneous rocks; pyroxenites were ultrabasic to basic cumulates. A few samples are probably metasedimentary in origin. Zircons are abundant in the xenoliths; they exhibit complex zoning in cathodoluminescence with relic cores and various metamorphic rims. Cores include oscillatory zircon crystallized in magmatic protoliths, and metamorphic and magmatic sector-zoned zircons. Recrystallization of older zircons led to the formation of bright homogeneous rims. In some samples, homogeneous shells are surrounded by darker convoluted overgrowths that were formed by subsolidus growth when a change in mineral association occurred. The source of Zr was a phase consumed during a reaction, which produced garnet. Late-generation zircons in all xenoliths show concordant U–Pb ages of 1.81–1.84 Ga (1,826 ± 11 Ma), interpreted as the age of last granulite-facies metamorphism. This event completely resets most zircon cores. An earlier metamorphic event at 1.96–1.94 Ga is recorded by some rare cores, and a few magmatic oscillatory zircons have retained a Neoarchaean age of 2,719 ± 14 Ma. The assemblage of metaigneous and metasedimentary rocks was probably formed before the event at 1.96 Ga. Inherited magmatic zircons indicate the existence of continental crust by the time of intrusion of magmatic protoliths in the Late Archaean. The U–Pb zircon ages correspond to major events recorded in upper crustal rocks of the region: collisional metamorphism and magmatism 2.7 Ga ago and reworking of Archaean rocks at around 1.95–1.75 Ga. However, formation of the granulitic paragenesis in lower crustal rocks occurred significantly later than the last granulite-facies event seen in the upper crust and correlates instead with retrograde metamorphism and small-volume magmatism in the upper crust.     

Age and nature of 560–520 Ma calc-alkaline granitoids of Biarjmand,northeast Iran: insights into Cadomian arc magmatism in northern Gondwana

ABSTRACT

The Biarjmand granitoids and granitic gneisses in northeast Iran are part of the Torud–Biarjmand metamorphic complex, where previous zircon U–Pb geochronology show ages of ca. 554–530 Ma for orthogneissic rocks. Our new U–Pb zircon ages confirm a Cadomian age and show that the granitic gneiss is ~30 million years older (561.3 ± 4.7 Ma) than intruding granitoids (522.3 ± 4.2 Ma; 537.7 ± 4.7 Ma). Cadomian magmatism in Iran was part of an approximately 100-million-year-long episode of subduction-related arc and back-arc magmatism, which dominated the whole northern Gondwana margin, from Iberia to Turkey and Iran. Major REE and trace element data show that these granitoids have calc-alkaline signatures. Their zircon O (δ¹⁸O = 6.2–8.9‰) and Hf (–7.9 to +5.5; one point with εHf ~ –17.4) as well as bulk rock Nd isotopes (εNd(t) = –3 to –6.2) show that these magmas were generated via mixing of juvenile magmas with an older crust and/or melting of middle continental crust. Whole-rock Nd and zircon Hf model ages (1.3–1.6 Ga) suggest that this older continental crust was likely to have been Mesoproterozoic or even older. Our results, including variable zircon εHf(t) values, inheritance of old zircons and lack of evidence for juvenile Cadomian igneous rocks anywhere in Iran, suggest that the geotectonic setting during late Ediacaran and early Cambrian time was a continental magmatic arc rather than back-arc for the evolution of northeast Iran Cadomian igneous rocks.     

滇西桃花花岗斑岩中新太古代-古元古代锆石年龄信息:对扬子板块西缘基底时代的约束

扬子板块西缘滇西地区是否存在古老基底一直存在争议。本文对滇西桃花地区花岗斑岩进行了岩石学、地球化学和锆石SHRIMP U-Pb年代学研究。形成于晚造山-后碰撞背景的桃花花岗斑岩具岛弧花岗岩地球化学特征,其成因可能与:1)俯冲拆离的洋壳俯冲拆离的洋壳或富集地幔重熔作用;2)加厚的地壳部分熔融。花岗斑岩中的继承锆石有两种类型:一类是发育具有密集振荡环带的岩浆锆石;另一类是次浑圆状锆石。测年结果显示,花岗斑岩的岩浆锆石年龄为36.35±0.35Ma,环带发育的继承锆石年龄介于167~891Ma之间;而次浑圆状继承锆石可以分为两组,其207Pb/206Pb加权平均年龄分别为1851±22Ma与2499±32Ma。新的锆石测年结果表明着滇西桃花地区不仅存在古金沙江洋东向俯冲形成的晚古生代弧岩浆记录,还发现新元古代岩浆活动信息,及早古元古代和新太古代的锆石记录。推测1.8Ga与2.5Ga锆石可能是捕获自地壳或围岩(石鼓片岩),表明滇西地区可能存在古老基底。     

Geologically constraining India in Columbia: The age,isotopic provenance and geochemistry of the protoliths of the Ongole Domain,Southern Eastern Ghats,India

The Ongole Domain in the southern Eastern Ghats Belt of India formed during the final stages of Columbia amalgamation at ca. 1600 Ma. Yet very little is known about the protolith ages, tectonic evolution or geographic affinity of the region. We present new detrital and igneous U–Pb–Hf zircon data and in-situ monazite data to further understand the tectonic evolution of this Columbia-forming orogen.Detrital zircon patterns from the metasedimentary rocks are dominated by major populations of Palaeoproterozoic grains (ca. 2460, 2320, 2260, 2200–2100, 2080–2010, 1980–1920, 1850 and 1750 Ma), and minor Archaean grains (ca. 2850, 2740, 2600 and 2550 Ma). Combined U–Pb ages and Lu–Hf zircon isotopic data suggest that the sedimentary protoliths were not sourced from the adjacent Dharwar Craton. Instead they were likely derived from East Antarctica, possibly the same source as parts of Proterozoic Australia. Magmatism occurred episodically between 1.64 and 1.57 Ga in the Ongole Domain, forming felsic orthopyroxene-bearing granitoids. Isotopically, the granitoids are evolved, producing εHf values between − 2 and − 12. The magmatism is interpreted to have been derived from the reworking of Archaean crust with only a minor juvenile input. Metamorphism between 1.68 and 1.60 Ga resulted in the partial to complete resetting of detrital zircon grains, as well as the growth of new metamorphic zircon at 1.67 and 1.63 Ga. In-situ monazite geochronology indicates metamorphism occurred between 1.68 and 1.59 Ga.The Ongole Domain is interpreted to represent part of an exotic terrane, which was transferred to proto-India in the late Palaeoproterozoic as part of a linear accretionary orogenic belt that may also have included south-west Baltica and south-eastern Laurentia. Given the isotopic, geological and geochemical similarities, the proposed exotic terrane is interpreted to be an extension of the Napier Complex, Antarctica, and may also have been connected to Proterozoic Australia (North Australian Craton and Gawler Craton).