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1.
Following the recent mass spectrometric observations of the ambient stratospheric positive and negative ions we have carried out co-ordinated laboratory experiments using a selected ion flow tube apparatus and a flowing afterglow apparatus for the following purposes: (i) to consider whether CH3CN is a viable candidate molecule for the species X in the observed stratospheric ion series H+ (H2On (X)m and (ii) to determine the binary mutual neutralization rate coefficients αi for the reactions ofH+ (H2O4 and H+(H2O)(CH3CN)3 with several of the negative ion species observed in the stratosphere. We conclude from (i) that CH3CN is indeed a viable candidate for X and from (ii) that the αi for stratospheric ions are within the limited range (5–6) × 10?8 cm3 s?1.  相似文献   

2.
The calculation of number densities of CO2, H2O and N2 photolysis products was carried out for the Martian atmosphere at heights up to 60 km. The ozone distributed in the atmosphere as a layer of 10 km width with [O3] max = 2.5 × 109 cm3 at height of 35 km which agree well with the results of u.v. observations on the evening terminator from the Mars-5 satellite. The calculated densities of O2, CO and H2O are also in good agreement with the measured data. The eddy diffusion coefficient is equal to 3 × 106 in the troposphere (h ? 30 km) and 108 cm2 s?1 above 40 km. The dependence of the total ozone content on water vapour amount in the atmosphere is considered; the hypothesis about the influence of water ice aerosol on the ozone formation is proposed to explain the high concentrations of ozone in the morning.  相似文献   

3.
In an updating of energy characteristics of lightnings on Venus obtained from Venera-9 and -10 optical observations, the flash energy is given as 8 × 108 J and the mean energy release of lightnings is 1 erg cm?2 s which is 25 times as high as that on the Earth. Lightnings were observed in the cloud layer. The stroke rate in the near-surface atmosphere is less than 5 s?1 over the entire planet if the light energy of the stroke exceeds 4 × 105 J and less than 15 s?1 for (1–4) × 105 J.The average NO production due to lightnings equals 5 × 108 cm?2 s?1, the atomic nitrogen production is equal to 7 × 109 cm?2s?1,the N flux toward the nightside is 3.2 × 109 cm?2s?1, the number densities [N] = 3 × 107cm?3 and [NO] = 1.8 × 106cm?3 at 135 km. Almost all NO molecules in the upper atmosphere vanish interacting with N and the resulting NO flux at 90-80 km equals 5 × 105cm?2s?1, which is negligibly small as compared with lightning production. If the predissociation at 80–90 km is regarded as the single sink of NO, its mixing ratio, fNO, is 4 × 10?8, for the case of a surface sink fNO = 0.8 × 10?9 at 50 km. Excess amounts, fNO ? 4 × 10?8, may exist in the thunderstorm region.  相似文献   

4.
The u.v. spectrometer polarimeter on the Solar Maximum Mission has been utilized to measure mesospheric ozone vs altitude profiles by the technique of solar occultation. Sunset data are presented for 1980, during the fall equinoctal period within ± 20° of the geographic equator. Mean O3, concentrations are 4.0 × 1010 cm?3at 50 km, 1.6 × 1010 cm?3 at 55 km. 5.5 × 109 cm?3 at 60 km and 1.5 × 109 cm?3 at 65 km. Som profiles exhibit altitude structure which is wavelike. The mean ozone profile is fit best with the results of a time-dependent model if the assumed water vapor mixing ratio employed varies from 6 ppm at 50 km to 2–4 ppm at 65 km.  相似文献   

5.
The nitrogen isotope ratio of middle atmosphere nitrogen oxide is predicted as a function of altitude. Nitrogen oxides originate photochemically either from stratospheric nitrous oxide reacting with O(1D) or in the mesosphere and thermosphere from direct dissociation of N2 and ionization-initiated reactions involving O2 and N2. During its formation process, N2O acquires a nitrogen isotopic composition of N isotopes different than N2. Photodissociation within the stratosphere also modifies the proportion of isotopes. Reaction of stratospheric NO with O3 produces NO2, which when photodissociated yields NO depleted in 15N relative to NO2 in laboratory air. The value of δ15NO in the stratosphere is −100‰. In the altitude region between 50 and 65 km, NO is transformed into NO2 and then returned to NO by reaction of NO2 with O and by NO2 photodissociation. These reactions determine the isotopic makeup of NO. Above 65 km, nitric oxide is produced by local ionization processes and gas phase photochemical reactions involving N2 and excited O2. These processes determine the isotopic composition of NO in the upper mesosphere and thermosphere. Here δ15NO is 0‰. Air transported into the mesosphere above 65 km will reflect the NO isotopic values of the region below, while mesospheric NO transported below 65 km will not be distinguishable from NO originating in the stratosphere.  相似文献   

6.
Simultaneous measurements of NO and NO2 in the stratosphere leading to an NOx determination have been performed by means of i.r. absorption spectrometry using the Sun as a source in the 5·2 μm band of NO and in the 6·2 μm band of NO2. The observed abundance of NOP peaks at 26 km where it is equal to (4·2 ± 1) × 109 cm?3. The volume mixing ratio of NOp was observed to vary from 1·3 × 10?9 at 20 km to 1·3 × 10?8 at 34 km.  相似文献   

7.
Altitude profiles for the number densities of NO, NO2, NO3, N2O5, HNO2, CH3O, CH3O2, H2CO, OH, and HO2 are calculated as a function of time of day with a steady-state photochemical model in which the altitude profiles for the number densities of H2O, CH4, H2, CO, O3, and the sum of NO and NO2 are fixed at values appropriate to a summer latitude of 34°. Average daily profiles are calculated for the long-lived species, HNO3, H2O2, and CH3O2H.The major nitrogen compound HNO3 may have a number density approaching 5 × 1011 molecules cm?3 at the surface, although an effective loss path due to collisions with particulates could greatly reduce this value.The number density of OH remains relatively unchanged in the first 6 km and reaches 1 × 107 molecules cm?3 at noon, while the number density of HO2 decreases throughout the lower troposphere from its noontime value of 8 × 108 molecules cm?3 at the surface.H2O2 and H2CO both have number densities in the ppb range in the lower troposphere.Owing to decreasing temperature and water concentration, the production of radicals and their steady-state number densities decrease with altitude, reaching a noontime minimum of 1 × 108 molecules cm?3 for OH and 3 × 107 molecules cm?3 for HO2 at the tropopause. The related minor species show even sharper decreases with increasing altitude.The primary path for interconverting OH and HO2 serves as the major sink for CO and leads to a tropospheric lifetime for CO of ~0.1 yr.Another reaction cycle, the oxidation of CH4, is quite important in the lower troposphere and leads to the production of H2CO along with the destruction of CH4 for which a tropospheric lifetime of ~2 yr is estimated.The destruction of H2CO that was produced in the CH4 oxidation cycle provides the major source of CO and H2 in the atmosphere.  相似文献   

8.
Nitric oxide is formed in the atmosphere through the ionization and dissociation of molecular nitrogen by galactic cosmic rays. One NO molecule is formed for each ion pair produced by cosmic ray ionization.The height-integrated input (day and night) to the lower stratosphere is of the order of 6 × 107 NO molecules cm?2/sec in the auroral zone (geomagnetic latitude Φ ? 60°) during the minimum of the sunspot cycle and 4 × 107 NO molecules cm?2/sec in the subauroral belt and auroral region (Φ? 45°) at the maximum of solar activity. The tropical production is less than 10?7 NO molecules cm?2/sec above 17 km and at the equator the production is only 3 × 106NO molecules cm?2/sec.  相似文献   

9.
Models are developed for the photochemistry of a CO2H2ON2 atmosphere on Mars and estimates are given for the concentrations of N, NO, NO2, NO3, N2O5, HNO2, HNO3, and N2O as a function of altitude. Nitric oxide is the most abundant form of odd nitrogen, present with a mixing ratio relative to CO2 of order 10?8. Deposition rates for nitrite and nitrate minerals could be as large as 3× 105 N equivalent atoms cm?2 sec?1 under present conditions and may have been higher in the past.  相似文献   

10.
Previous modeling by Banaszkiewicz et al. (2000a,b) showed that the CH4 thermospheric mixing ratio on Titan could vary as much as 35-40% due to ion-neutral chemical reactions. A new vertical methane profile has been computed by simultaneously modifying the stratospheric methane mixing ratio and the K(z) previously considered by Lara et al. (1996) and Banaszkiewicz et al. (2000a,b). A satisfactory fit of the methane thermospheric abundance and stratospheric mixing ratio of other minor constituents is achieved by placing the homopause at ∼1000 km and increasing the methane stratospheric mixing ratio (qCH4) up to 3.8%. The new proposed eddy diffusion coefficient steadily rises from 1×107 cm2 s−1 at 700 km to 1×1010 cm2 s−1 at 1500 km, whereas the stratospheric values are in the range (4-20)×103 cm2 s−1. Other likely ionization sources that can influence the methane distribution are (i) a metallic ion layer produced by micrometeoroid infall and (ii) frequent X-rays solar flares. Analysis of the effects of these ionization sources on the methane distribution indicates that, unlike previously assumed, CH4 can suffer considerable variations. These variations, although proved in this work, must be cautiously regarded since several assumptions have to be made on the rate of N2 and CH4 ionization by the processes previously mentioned. Hence, these results are only indicative of methane sensitivity to ionospheric chemistry.  相似文献   

11.
Yuk L. Yung  W.B. Demore 《Icarus》1982,51(2):199-247
The photochemistry of the stratosphere of Venus was modeled using an updated and expanded chemical scheme, combined with the results of recent observations and laboratory studies. We examined three models, with H2 mixing ratio equal to 2 × 10?5, 5 × 10?7, and 1 × 10?13, respectively. All models satisfactorily account for the observations of CO, O2, O2(1Δ), and SO2 in the stratosphere, but only the last one may be able to account for the diurnal behavior of mesospheric CO and the uv albedo. Oxygen, derived from CO2 photolysis, is primarily consumed by CO2 recombination and oxidation of SO2 to H2SO4. Photolysis of HCl in the upper stratosphere provides a major source of odd hydrogen and free chlorine radicals, essential for the catalytic oxidation of CO. Oxidation of SO2 by O occurs in the lower stratosphere. In the high-H2 model (model A) the OO bond is broken mainly by S + O2 and SO + HO2. In the low-H2 models additional reactions for breaking the OO bond must be invoked: NO + HO2 in model B and ClCO + O2 in model C. It is shown that lightning in the lower atmosphere could provide as much as 30 ppb of NOx in the stratosphere. Our modeling reveals a number of intriguing similarities, previously unsuspected, between the chemistry of the stratosphere of Venus and that of the Earth. Photochemistry may have played a major role in the evolution of the atmosphere. The current atmosphere, as described by our preferred model, is characterized by an extreme deficiency of hydrogen species, having probably lost the equivalent of 102–103 times the present hydrogen content.  相似文献   

12.
The Mariner 9 infrared spectrometer obtained data over a large part of Mars for almost a year beginning late in 1971. Mars' infrared emission spectrum was measured from 200 to 2000 cm?1 with an apodized resolution of 2.4 cm?1. No significant deviation from terrestrial ratios of carbon (12C/13C) or oxygen (16O/18O; 16O/17O) isotopes was observed on Mars. The 12C/13C isotopic ratio was found to be terrestrial with an uncertainty of 15%. Upper limits have been calculated for several minor constituents. With an effective noise equivalent radiance of 1.2 × 10?9 W cm?2 sr?1/cm?1, new upper limits in centimeter-atmospheres of 2 × 10?5 for C2H2, 4 × 10?3 for C2H4, 3 × 10?3 for C2H6, 2 × 10?4 for CH4, 1 × 10?3 for N2O, 1 × 10?4 for NO2, 4 × 10?5 for NH3, 1 × 10?3 for PH3, 7 × 10?4 for SO2, and 1 × 10?4 for OCS have been derived.  相似文献   

13.
Vertical distributions and spectral characteristics of Titan’s photochemical aerosol and stratospheric ices are determined between 20 and 560 cm?1 (500–18 μm) from the Cassini Composite Infrared Spectrometer (CIRS). Results are obtained for latitudes of 15°N, 15°S, and 58°S, where accurate temperature profiles can be independently determined.In addition, estimates of aerosol and ice abundances at 62°N relative to those at 15°S are derived. Aerosol abundances are comparable at the two latitudes, but stratospheric ices are ~3 times more abundant at 62°N than at 15°S. Generally, nitrile ice clouds (probably HCN and HC3N), as inferred from a composite emission feature at ~160 cm?1, appear to be located over a narrow altitude range in the stratosphere centered at ~90 km. Although most abundant at high northern latitudes, these nitrile ice clouds extend down through low latitudes and into mid southern latitudes, at least as far as 58°S.There is some evidence of a second ice cloud layer at ~60 km altitude at 58°S associated with an emission feature at ~80 cm?1. We speculate that the identify of this cloud may be due to C2H6 ice, which in the vapor phase is the most abundant hydrocarbon (next to CH4) in the stratosphere of Titan.Unlike the highly restricted range of altitudes (50–100 km) associated with organic condensate clouds, Titan’s photochemical aerosol appears to be well-mixed from the surface to the top of the stratosphere near an altitude of 300 km, and the spectral shape does not appear to change between 15°N and 58°S latitude. The ratio of aerosol-to-gas scale heights range from 1.3–2.4 at about 160 km to 1.1–1.4 at 300 km, although there is considerable variability with latitude. The aerosol exhibits a very broad emission feature peaking at ~140 cm?1. Due to its extreme breadth and low wavenumber, we speculate that this feature may be caused by low-energy vibrations of two-dimensional lattice structures of large molecules. Examples of such molecules include polycyclic aromatic hydrocarbons (PAHs) and nitrogenated aromatics.Finally, volume extinction coefficients NχE derived from 15°S CIRS data at a wavelength of λ = 62.5 μm are compared with those derived from the 10°S Huygens Descent Imager/Spectral Radiometer (DISR) data at 1.583 μm. This comparison yields volume extinction coefficient ratios NχE(1.583 μm)/NχE(62.5 μm) of roughly 70 and 20, respectively, for Titan’s aerosol and stratospheric ices. The inferred particle cross-section ratios χE(1.583 μm)/χE(62.5 μm) appear to be consistent with sub-micron size aerosol particles, and effective radii of only a few microns for stratospheric ice cloud particles.  相似文献   

14.
The methane abundance in the lower Jovian stratosphere is measured using Galilean satellite eclipse light curves. Spectrally selective observations in and between absorption bands are compared. An average mixing ratio at the locations measured is [CH4]/[H2] ~ 1.3 × 10?3, larger than the value 0.9 × 10?3 expected for a solar abundance of carbon. Some zenographic variation of the mixing ratio may occur. Observationally compatible values are 1.3–2.0 × 10?3 in the STZ, 1.3– 2.6 × 10?3 on the GRS/STrZ edge, and 0.7–1.3 × 10?3 in the GRS.  相似文献   

15.
It is shown that Titan's surface and plausible atmospheric thermal opacity sources—gaseous N2, CH4, and H2, CH4 cloud, and organic haze—are sufficient to match available Earth-based and Voyager observations of Titan's thermal emission spectrum. Dominant sources of thermal emission are the surface for wavelenghts λ ? 1 cm, atmospheric N2 for 1 cm ? λ ? 200 μm,, condensed and gaseous CH4 for 200 μm ? λ ? 20 μm, and molecular bands and organic haze for λ ? 20 μm. Matching computed spectra to the observed Voyager IRIS spectra at 7.3 and 52.7° emission angles yields the following abundances and locations of opacity sources: CH4 clouds: 0.1 g cm? at a planetocentric radius of 2610–2625 km, 0.3 g cm?2 at 2590–2610 km, total 0.4 ± 0.1 g cm–2 above 2590 km; organic haze: 4 ± 2 × 10?6, g cm, ?2 above 2750 km; tropospheric H2: 0.3 ± 0.1 mol%. This is the first quantitative estimate of the column density of condensed methane (or CH4/C2H6) on Titan. Maximum transparency in the middle to far IR occurs at 19 μm where the atmospheric vertical absorption optical depth is ?0.6 A particle radius r ? 2 μm in the upper portion of the CH4 cloud is indicated by the apparent absence of scattering effects.  相似文献   

16.
Aircraft measurements of O2(1Δg) emission made over a 10-yr period provide information on the variation of ozone with latitude and season in the altitude region 50–90 km. Between 50 and 70 km there appears to be little variation (< ± 25%) whereas the abundance between 80 and 90 km exhibits a large seasonal change north of 30°N and much less at lower latitude. At mid and high latitude the column abundance above ~ 80 km changes from ? 1 × 1014 cm?2 in summer to about 3 × 1014 cm?2 in winter. There are occasional enhancements in both the day and twilight airglow which almost always occur in association with auroral activity or, at least, where such activity is statistically most likely. These enhancements appear to reflect a corresponding increase in the ozone mixing ratio in the upper stratosphere. While the gradient in ozone mixing ratio with latitude is generally small at altitudes between 50 and 90km there are occasions when a temporary latitude structure can be seen, particularly above 80 km.  相似文献   

17.
The ozone height profile in the Arctic, at the end of the winter, has been measured up to an altitude of 100 km using a combined solar occultation and 1.27 μ oxygen emission technique. The typical two layer structure has been observed with a high altitude minimum near 80 km and a maximum at 86 km. The measured concentration in this ozone bulge was 5.1 × 107cm?3, typical of that measured at 52°N for the summer months. It is suggested that this reduced ozone concentration may have been associated with a stratospheric warming event that was in progress at the time of the measurement.  相似文献   

18.
Stellar occultation data from the 2460 Å and 2980 Å channels of the OAO-2 stellar photometers have been used to derive the nighttime ozone number density distribution in the low latitude mesosphere. The nighttime ozone distribution obtained from both channels are similar indicating a maximum in the ozone distribution near 80km of 2–3 × 103cm?3.  相似文献   

19.
Two coherently related radio signals transmitted from Voyager 1 at wavelengths of 13 cm (S-band) and 3.6 cm (X-band) were used to probe the equatorial atmosphere of Titan. The measurements were conducted during the occultation of the spacecraft by the satellite on November 12, 1980. An analysis of the differential dispersive frequency measurements did not reveal any ionization layers in the upper atmosphere of Titan. The resolution was approximately 3 × 103 and 5 × 103 electrons/cm3 near the evening and morning terminators, respectively. Abrupt signal changes observed at ingress and egress indicated a surface radius of 2575.0 ± 0.5 km, leading to a mean density of 1.881 ± 0.002 g cm?3 for the satellite. The nondispersive data were used to derive profiles in height of the gas refractivity and microwave absorption in Titan's troposphere and stratosphere. No absorption was detected; the resolution was about 0.01 dB/km at the 13-cm wavelength. The gas refractivity data, which extend from the surface to about 200 km altitude, were interpreted in two different ways. In the first, it is assumed that N2 makes up essentially all of the atmosphere, but with very small amounts of CH4 and other hydrocarbons also present. This approach yielded a temperature and pressure at the surface of 94.0 ± 0.7°K and 1496 ± 20 mbar, respectively. The tropopause, which was detected near 42 km altitude, had a temperature of 71.4 ± 0.5°K and a pressure of about 130 mbar. Above the tropopause, the temperature increased with height, reaching 170 ± 15°K near the 200-km level. The maximum temperature lapse rate observed near the surface (1.38 ± 0.10°K/km) corresponds to the adiabatic value expected for a dry N2 atmosphere—indicating that methane saturation did not occur in tbis region. Above the 3.5-km altitude level the lapse rate dropped abruptly to 0.9 ± 0.1°K/km and then decreased slowly with increasing altitude, crossing zero at the tropopause. For the N2 atmospheric model, the lapse rate transition at the 3.5-km level appears to mark the boundary between a convective region near the surface having the dry adiabatic lapse rate, and a higher stable region in radiative equilibrium. In the second interpretation of the refractivity data, it is assumed, instead, that the 3.5 km altitude level corresponds to the bottom of a CH4 cloud layer, and that N2 and CH4 are perfectly mixed below this level. These assumptions lead to an atmospheric model which below the clouds contains about 10% CH4 by number density. The temperature near the surface is about 95°K. Arguments concerning the temperature lapse rates computed from the radio measurements appear to favor models in which methane forms at most a limited haze layer high in the troposphere.  相似文献   

20.
A strong, broad spectral emission feature at 85° N latitude centered at 221 cm−1 remains unidentified after candidate ices of H2O and pure crystalline CH3CH2CN are unambiguously ruled out. A much shallower weak emission feature starts at 160 cm−1 and blends into the strong feature at ∼190 cm−1. This feature is consistent with one formed by an HCN ice cloud composed of ?5 μm radius particles that resides in the lower stratosphere somewhere below an altitude of 160 km. Titan's stratospheric aerosol appears to have a spectral emission feature at about 148 cm−1. The aerosol abundance at 85° N is about a factor 2.2 greater than at 55° S.  相似文献   

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