Grain size limit for SD hematite

Grain sizes in the range (10⁻⁴ to 10⁻¹ mm) are common in some rocks. Because thermal and/or chemical remanent magnetization of hematite in this range approaches intensities of single domain (SD) magnetite, careful exploration of this transition, may serve to develop new applications in rock magnetism that relate to magnetic anomaly source identification, and various paleomagnetic and grain size-dependent investigations.Grain size-dependent magnetic behavior of hematite reveals a SD–multidomain (MD) transition at 0.1 mm. This transition is recognized by variation in magnetic coercivity and susceptibility and is related to an anomaly in remanence recovery when cycling through the Morin transition. The coercivity decrease with increasing grain size occurs much more gradually above 0.1 mm than below this value. Magnetic susceptibility of the grains smaller than 0.1 mm has negligible dependence on the amplitude of the applied alternating magnetic field. For the larger grains a new amplitude-dependent susceptibility component is observed. The grain size of 0.1 mm is also associated with loss of most of the remanence when cycling through the Morin transition. This behavior is ascribed to a transition from the metastable SD to the MD magnetic state. The increase in magnetized volume causes the demagnetizing energy to destabilize the SD state, resulting in a transition where the demagnetizing energy is reduced by nucleation of the domain wall for grains larger than 0.1 mm. The 0.1 mm transition has no significant effect on shape of the temperature-dependent coercivity and saturation magnetization.     

Grain size dependent potential for self generation of magnetic anomalies on Mars via thermoremanent magnetic acquisition and magnetic interaction of hematite and magnetite

Early in the history of planetary evolution portions of Martian crust became magnetized by dynamo-generated magnetic field. A lateral distribution of the secondary magnetic field generated by crustal remanent sources containing magnetic carriers of certain grain size and mineralogy is able to produce an ambient magnetic field of larger intensity than preexisting dynamo. This ambient field is capable of magnetizing portions of deeper crust that cools through its blocking temperatures in an absence of dynamo. We consider both magnetite (Fe₃O₄) and hematite (α-Fe₂O₃) as minerals contributing to the overall magnetization. Analysis of magnetization of magnetic minerals of various grain size and concentration reveals that magnetite grains less than 0.01 mm in size, and hematite grains larger than 0.01 mm in size can become effective magnetic source capable of magnetizing magnetic minerals contained in surrounding volume. Preexisting crustal remanence (for example ∼250 A/m relates to 25% of multi-domain hematite) can trigger a self-magnetizing process that can continue in the absence of magnetic dynamo and continue strengthening and/or weakening magnetic anomalies on Mars. Thickness of the primary magnetic layer and concentration of magnetic carriers allow specification of the temperature gradient required to trigger a self-magnetization process.     

Comparative study of top soil magnetic susceptibility variation based on some human activities

An investigation of the effect of some human activities on the magnetic susceptibility and frequency dependent susceptibility was conducted on top soil samples from, a commercial area, a motor park and a school environment in Jalingo, Taraba State, N-E Nigeria. The purpose was to assess the variation of magnetic susceptibility with different land use, detect pollution hotspots using magnetic proxy parameters and evaluate the contribution of superparamagnetic (SP) grain size contribution to the magnetic susceptibility from calculation of the frequency dependence of magnetic susceptibility (MS). The results of the mass specific low frequency magnetic susceptibility measurements showed significant enhancement with values ranging from 67.8 − 495.3 × 10⁻⁸ m³kg⁻¹ with a mean value of 191.61 × 10⁻⁸ × m³kg⁻¹ for the Jalingo College of Education (JCOE) data; 520.1 − 1612.8 × 10⁻⁸ m³kg⁻¹ with a mean value of 901.34 × 10⁻⁸ m³kg⁻¹ for the Jalingo main Market (JMM) and 188.5 − 1203.6 × 10⁻⁸m³kg⁻¹ with an average value of 574 92 × 10⁻⁶ m³kg⁻¹ for the Jalingo Motor Park (JMP). The significant magnetic enhancement indicates high concentration of ferrimagnetic minerals in the soil and hence increased pollution. The magnetic susceptibility of the different land use studied decreased in the order commercial area (market) > motor park > school premises. The results of the percentage frequency dependence susceptibility showed that most of the samples had a mixture of SP and coarse multi domain grains or SP grains < 0.05 µm. The value of χ_fd% range from 2.68 to 13.80% with an average value of 8.67% in the JCOE samples, 0.49 to 10.04% with an a-verage of 5.05% in the JMM samples and 0.56 to 13.04% with an average value of 5.86% in the JMP samples.     

The equivalent dose of different grain size quartz fractions from lakeshore sediments in the arid region of north China

Equivalent dose (D_e) values were measured by using medium aliquots of different grain size quartz fractions of five lakeshore sediments from the arid region of north China. There are two different relationships between D_e values and grain sizes of these five samples. The first relationship is that the D_e values obtained from various grain sizes are in agreement within 1 delta errors. The second relationship is that D_e values are similar to each other for fractions between 125 and 300 μm, while the D_e value of the 63–90 μm fraction is 40～55% smaller than others. For example, the D_e values obtained for sample #3 are 20.15 ± 1.19 Gy, 19.80 ± 0.83 Gy and 20.93 ± 1.06 Gy for fractions of 90–125, 125–150 and 250–300 μm respectively, but are 10.79 ± 0.84 Gy for the 63–90 μm fraction. The second relationship can't be interpreted by previous studies of both dosimetry and heterogeneous bleaching. It is deduced for sample #2, #3 and #6 that fine particles (<90 μm) intruded after the dominant sedimentation. Comparison of OSL ages from different grain size fractions of sample #2 with a radiocarbon age from the same lithologic layer supports that fractions coarser than 125 μm yield more reliable burial ages, while the fraction finer than 90 μm yields underestimated ages for some lakeshore sediments from this arid region.     

Optical dating of the upper 22 m of cored sediments from Daihai Lake,northern China

Daihai Lake is one of the largest lakes in the mid-latitude of northern China. Previous environmental change investigations using the sediments from the lake have been mainly focused on the last 13 ka. In 2006, we drilled an 80-m borehole on the southwest coast of the lake. Here we report the results of initial optical dating of the upper 22-m sediments from the core. Most of the samples allow separation of the 4–11 μm fine-grained and 45–63 μm medium-grained quartz, both of which were used for equivalent dose (D_e) determination. Dose recovery test experiments with the single-aliquot regeneration-dose (SAR) protocol indicate that a preheat at 240 °C for 10 s combined with a cut-heat of 240 °C is suitable for these samples. The D_e values show marked discrepancy between the two grain size fractions with the fine-grained quartz yielding up to over 50% higher D_e values than the medium ones for some samples. We consider the OSL ages for the samples from upper ～10 m to be overestimated. The main cause of the overestimation is attributed to the incomplete bleaching of the sediment grains at deposition. The OSL ages for the lower part of the sequence are considered to be reasonable age estimates which provide useful temporal constrains on the deposition of the sediments for the period of 20–40 ka.     

40Ar / 39Ar geochronology constraints on late miocene weathering rates in Minas Gerais,Brazil

⁴⁰Ar / ³⁹Ar incremental heating ages for twenty one grains of cryptomelane, collected at 0, 42, 45, and 60 m depths in the Cachoeira Mine weathering profile, Minas Gerais, permit calculating long-term (10 Ma time scale) weathering rate (saprolitization rate) in SE Brazil. Pure well-crystallized cryptomelane grains with high K contents (3–5 wt.%) yield reliable geochronological results. The ⁴⁰Ar / ³⁹Ar plateau ages obtained decrease from the top to the bottom of the profile (12.7 ± 0.1 to 7.6 ± 0.1 Ma at surface; 7.6  ± 0.2 to 6.1 ± 0.2 Ma at 42 m; and 7.1 ± 0.2 to 5.9 ± 0.1 Ma at 45 m; 6.6 ± 0.1 to 5.2 ± 0.1 Ma at 60 m), yielding a weathering front propagation rate of 8.9 ± 1.1 m/m.y. From the geochronological results and the mineral transformations implicit by the current mineralogy in the weathering profiles, it is possible to calculate the saprolitization rate for the Cachoeira Mine lithologies and for adjacent weathering profiles developed on granodiorites and schists. The measured weathering front propagation rate yields a saprolitization rate of 24.9 ± 3.1 t/km²/yr. This average long-term (> 10 Ma) saprolitization rate is consistent with mass balance calculations results for present saprolitization rates in weathering watersheds. These results are also consistent with long-term saprolitization rates estimated by combining cosmogenic isotope denudation rates with mass balance calculations.     

Annual variation in neustonic micro- and meso-plastic particles and zooplankton in the Bay of Calvi (Mediterranean–Corsica)

The annual variation in neustonic plastic particles and zooplankton was studied in the Bay of Calvi (Corsica) between 30 August 2011 and 7 August 2012. Plastic particles were classified into three size classes, small microplastics (0.2–2 mm), large microplastics (2–5 mm) and mesoplastics (5–10 mm).74% of the 38 samples contained plastic particles of varying composition: e.g. filaments, polystyrene, thin plastic films. An average concentration of 6.2 particles/100 m² was observed. The highest abundance values (69 particles/100 m²) observed occurred during periods of low offshore wind conditions. These values rose in the same order of magnitude as in previous studies in the North Western Mediterranean.The relationships between the abundance values of the size classes between zooplankton and plastic particles were then examined. The ratio for the intermediate size class (2–5 mm) reached 2.73. This would suggest a potential confusion for predators regarding planktonic prey of this size class.     

Luminescence properties of single grain quartz to determine the history of a sample from the Sahara Desert

In this work we present luminescence analyses of material taken from a Neolithic hearth in the Sahara Desert in Egypt. The sample was taken from a beach sand layer which contained traces of charcoal. The sample was dated using quartz luminescence, and its luminescence properties were investigated to find whether it had been heated by fire. In doing so we established a procedure to distinguish heated and unheated quartz at single grain level.The OSL age estimate of the sample is 10.6 ± 0.4 ka. Luminescence properties were measured using about 40,000 individual grains. Using an approach similar to that used to measure thermal activation characteristics (TAC), we compared the distribution of OSL sensitivity of single grains following different thermal treatments. It was found that higher temperatures and longer treatment times change the sensitivity distributions systematically from that observed using the natural sample. We conclude that the grains examined in our dating study were not heated by fire prior to burial, and that the hearth is not older than the OSL age.     

Residual OSL signals in modern fluvial sediments from the Yellow River (HuangHe) and the implications for dating young sediments

The Yellow River is characterized by its tremendous sediment load. In this study we investigated the residual OSL signals in modern fluvial sand and suspended-sediment samples from the middle reach of the river. The residual equivalent dose (D_e) is found to vary with grain size, mineralogy and the techniques used for the D_e determination. The results indicate that the OSL signals in some grains from these samples were not completely bleached prior to burial, the maximum individual D_e value obtained is up to 56 Gy. The results also show that coarse grains are generally better bleached at deposition than fine grains; the fine-grained quartz from suspended sediments are better bleached than the fine-grained quartz from the fluvial sand deposits. The D_es obtained using quartz TT-OSL signals are up to ～380 Gy for these modern samples.     

Nanoscale porosity in SAFOD core samples (San Andreas Fault)

With transmission electron microscopy (TEM) we observed nanometer-sized pores in four ultracataclastic and fractured core samples recovered from different depths of the main bore hole of the San Andreas Fault Observatory at Depth (SAFOD). Cutting of foils with a focused ion beam technique (FIB) allowed identifying porosity down to the nm scale. Between 40 and 50% of all pores could be identified as in-situ pores without any damage related to sample preparation. The total porosity estimated from TEM micrographs (1–5%) is comparable to the connected fault rock porosity (2.8–6.7%) estimated by pressure-induced injection of mercury. Permeability estimates for cataclastic fault rocks are 10^? 21–10^? 19 m² and 10^? 17 m² for the fractured fault rock. Porosity and permeability are independent of sample depth. TEM images reveal that the porosity is intimately linked to fault rock composition and associated with deformation. The TEM-estimated porosity of the samples increases with increasing clay content. The highest porosity was estimated in the vicinity of an active fault trace. The largest pores with an equivalent radius > 200 nm occur around large quartz and feldspar grains or grain-fragments while the smallest pores (equivalent radius < 50 nm) are typically observed in the extremely fine-grained matrix (grain size < 1 μm). Based on pore morphology we distinguish different pore types varying with fault rock fabric and alteration. The pores were probably filled with formation water and/or hydrothermal fluids at elevated pore fluid pressure, preventing pore collapse. The pore geometry derived from TEM observations and BET (Brunauer, Emmett and Teller) gas adsorption/desorption hysteresis curves indicates pore blocking effects in the fine-grained matrix. Observations of isolated pores in TEM micrographs and high pore body to pore throat ratios inferred from mercury injection suggest elevated pore fluid pressure in the low permeability cataclasites, reducing shear strength of the fault.     

Forsterite to wadsleyite phase transformation under shear stress and consequences for the Earth's mantle transition zone

We have studied the phase transformation of forsterite to wadsleyite under shear stress at the Earth's transition zone pressure and temperature conditions. Two-step experiments were performed using a multi-anvil press. First, we hot pressed iron-free forsterite at 6 or 11 GPa and 1100 °C. Then we deformed a slab of this starting material using a direct simple shear assembly at 16 GPa and 1400 °C for 1, 15, 35, 40, or 60 min. Both the starting material and the deformed samples were characterized using optical and scanning electron microscopy including measurements of crystal preferred orientations (CPO) by electron back scattered diffraction (EBSD), transmission electron microscopy (TEM), and Fourier transform infrared spectroscopy (FTIR). The phase transformation occurs very rapidly, in less than 1 min, and metastable forsterite relics are not observed after deformation. The grain size of wadsleyite is slightly smaller than the forsterite starting material. The water contents obtained from FTIR analyses in forsterite and wadsleyite are 65–124 wt ppm H₂O and 114–736 wt ppm H₂O, respectively, which are well below water solubility at similar conditions in the presence of free water. Wadsleyite aggregates display weak CPO patterns with [1 0 0] axes concentrated at low angle to the shear direction, [0 1 0] axes perpendicular to the shear plane and nearly random [0 0 1] axes. Only a few dislocations were observed in wadsleyite with TEM. This observation is consistent with the assumption that most dislocations formed during the initial high-stress stages of these stress-relaxation experiments, were consumed in the phase transformation, probably enhancing the transformation rate. CPO patterns vary as a function of the water content: with increasing water content the density of [1 0 0] axes parallel to the shear direction decreases, and the density of [0 0 1] axes increases. Viscoplastic self-consistent modeling of CPO evolution using previously reported glide systems for wadsleyite, i.e., [1 0 0]{0 k l} and 1/2 〈1 1 1〉{1 0 1}, cannot reproduce the measured CPO, unless the [0 0 1](0 1 0) system, for which dislocations have not been observed by TEM, is also activated. In addition, wadsleyite grain growth suggests the participation of diffusion-assisted processes in deformation. Calculated anisotropies for P and S-waves using measured CPO are always below 1%. This very low anisotropy is due to both the low finite strain achieved in the experiments, which leads to weak wadsleyite CPO, and to the diluting effect of added majorite. The present experiments emphasize the importance of stress, grain size evolution and water content in the forsterite to wadsleyite phase transformation and subsequent deformation in the transition zone.     

Spatio-temporal variability of size fractionated phytoplankton on the shelf adjacent to the Ebro river (NW Mediterranean)

The mesoscale distribution and seasonal variation of the size structure of phytoplankton biomass, as measured by chlorophyll a (chl a), was studied in the Ebro shelf area (NW Mediterranean) during three different seasons: autumn, winter and summer. In autumn and summer, when the water column was, respectively, slightly or strongly stratified and nutrient concentrations were low at surface, average total chl a values were 0.31 and 0.29 mg m⁻³, respectively. In winter, the intrusion of nutrients into the photic zone by intense vertical mixing and strong riverine inputs, produced an increase of the total autotrophic biomass (0.76 mg m⁻³). In the three seasons, the main contributor to total chl a was the picoplanktonic (<2 μm) size fraction (42% in winter and around 60% in autumn and summer). The nanophytoplankton (2–20 μm) contribution to total chl a showed the lowest variability amongst seasons (between 29% and 39%). The microplanktonic (>20 μm) chl a size fraction was higher in winter (27%) than in the other seasons (less than 13%). The maximum total chl a concentrations were found at surface in winter, at depths of 40 m in autumn and between 50 and 80 m in summer. The relative contribution of the <2 μm size fraction at these levels of the water column tended to be higher than at other depths in autumn and winter and lower in summer. In autumn and winter, nutrient inputs from Ebro river discharge and mixing processes resulted in an increase on the >2 μm contribution to total chl a in the coastal zone near the Ebro Delta area. In summer, the contribution of the <2 and >2 μm chl a size fractions was homogeneously distributed through the sampling area. In autumn and summer, when deep chl a maxima were observed, the total amount of the autotrophic biomass in the superficial waters (down to 10 m) of most offshore stations was less than 10% of the whole integrated chl a (down to 100 m or to the bottom). In winter, this percentage increased until 20% or 40%. The >2 μm chl a increased linearly with total chl a values. However, the <2 μm chl a showed a similar linear relationship only at total chl a values lower than 1 mg m⁻³ (in autumn and summer) or 2 mg m⁻³ (winter). At higher values of total chl a, the contribution of the <2 μm size fraction remained below an upper limit of roughly 0.5 mg m⁻³. Our results indicate that the picoplankton fraction of phytoplankton may show higher seasonal and mesoscale variability than is usually acknowledged.     

Relation between mantle shear zone deformation and metasomatism in spinel peridotite xenoliths of Jeju Island (South Korea): Evidence from olivine CPO and trace elements

This study presents geochemical and fabric analysis of coarse-grained, porphyroclastic and mylonitic spinel peridotite xenoliths derived from the shallow subcontinental lithospheric mantle of Jeju Island (South Korea). Fabric analysis of olivines in the studied peridotites shows activation of the high temperature (0 1 0)[1 0 0] slip system; however, in the porphyroclastic and mylonitic peridotites, activation of (0 k l)[1 0 0] slip system results in a weaker fabric. Formation of porphyroclastic and mylonitic fabrics are thought to form in a shear-dominated environment. The results of the trace element analysis reveal that the smaller the grain size and weaker the fabric, the more enriched in LREE and HFSE are the peridotites, which indicates a strong relationship between metasomatic agents and mantle shear zones.     

Content and distribution of trace metals in surface sediments from the northern Bering Sea,Chukchi Sea and adjacent Arctic areas

Concentrations of trace metals (Zn, Cr, Cu, V, Cd and Pb), total organic carbon (TOC), black carbon (BC) and their granulometry were examined in 25 surface sediment samples from the northern Bering Sea, Chukchi Sea and adjacent areas. Trace metal concentrations in the sediments varied from 21.06–168.21 mg kg⁻¹ for Zn, 8.91–46.94 mg kg⁻¹ for Cr, 2.69–49.39 mg kg⁻¹ for Cu, 32.46–185.54 mg kg⁻¹ for V, 0.09–0.92 mg kg⁻¹ for Cd, and 0.95–15.25 mg kg⁻¹ for Pb. The geoaccumulation index (I_geo) indicated that trace metal contamination (Zn and Cd) existed in some stations of the study area. The distribution of grain size plays an important role in influencing the distribution of trace metals (Zn, Cr, Cu, V, and Pb) in sediments from the Chukchi Sea and adjacent areas.     

Lattice-preferred orientation and microstructure of peridotites from ODP Hole 1274A (15°39′N), Mid-Atlantic Ridge: Testing models of mantle upwelling and tectonic exhumation

Eleven harzburgites and one dunite from Ocean Drilling Program Leg 209 Hole 1274A preserve high-temperature mantle textures. Electron backscatter diffraction (EBSD) analysis shows moderately developed crystal lattice preferred orientations (LPOs) in olivine and orthopyroxene (M-indices ≈ 0.1) indicative of crystal-plastic deformation at ~ 1250 °C. These rocks preserve a protogranular texture with a weak olivine foliation, a very weak or absent orthopyroxene foliation that may be decoupled from the orthopyroxene LPO, and minor interstitial clinopyroxene and spinel. Olivine grain size distributions, along with melt-related microstructures in orthopyroxene, clinopyroxene and spinel suggest that high-temperature deformation textures have been overprinted by pervasive post-deformation melt-rock interaction. Paleomagnetic data constrain the olivine [100] axes to be subhorizontal and oriented at low angle (≤ 28.6° ± 10.6°) to the ridge axis at the onset of serpentinization. This orientation is consistent with either complex 3-D mantle upwelling or 2-D mantle upwelling coupled with complex 3-D tectonic emplacement to the seafloor.     

Optical dating of a Japanese marker tephra using plagioclase

The luminescence characteristics of volcanic plagioclase from an andesitic tephra (Hakone-Tokyo pumice, Hk-TP) from Japan were studied in order to assess if optical dating of plagioclase could be applied to Quaternary tephra. The tephra was shown to contain two kinds of plagioclase grains, labradorite which had a smooth surface and bytownite with a rough surface. The aliquots consisting of smaller grains contained more bytownite; these showed higher luminescence sensitivity and a higher fading rate compared to the larger-grained aliquots containing only labradorite. The fading rates of both OSL and IRSL signals were similar for each grain size. However, the OSL signal showed severe thermal transfer which made it difficult to use for dating. Using the IRSL signal from grains ranging from 150 to 212 μm, an age was obtained in agreement with the independent evidence, once a small fading correction had been applied.     

A conduit-related genesis of the Lengshuiqing intrusive assemblage (Sichuan,SW China)

Lengshuiqing is part of the late Proterozoic igneous province from the western margin of the Yangtze craton. The Lengshuiqing area comprises five ultramafic–mafic intrusions, emplaced in the late Proterozoic Yanbian Group. The intrusions from Lengshuiqing contain cumulate ultramafic zones (peridotite + olivine pyroxenite), with cumulus olivine and Cr-spinel, and intercumulus pyroxenes, hornblende, phlogopite and plagioclase. Ni–Cu ore (pyrrhotite + pentlandite + chalcopyrite) is hosted in the ultramafic zones. Olivine-free diorite–quartz diorite ± gabbro and granite zones commonly occur above the ultramafic rocks. The genesis of the intrusions (conduit-related accumulation or differentiation from stagnant magma) was investigated. The amount of sulphides in the intrusions from Lengshuiqing is one order of magnitude bigger than the sulphides that can be dissolved by a volume of mafic magma similar with the volume of the intrusions. Most intrusions from Lengshuiqing have bulk composition (peridotite ± diorite ± granite) more magnesian (MgO = 21–22%; Mg# > 78) than the deduced composition of their parental magma (MgO = 9–11%; Mg# = 64–67). This indicates the accumulation of sulphide and mafic silicates from a volume of magma much bigger than the volume of the intrusions, which can be explained by the fractionation from magma ascending through the intrusions to shallower depths. A continuous supply and vent of magma is consistent with the lack of chilled margins, the melting of the wall rocks and the generation of high-temperature mineral assemblages (K-feldspar, diopside, and sillimanite) in the Yanbian Group. The intrusions from Lengshuiqing are seen as microchambers on conduits draining olivine-, Cr-spinel-, and sulphide-bearing mafic magma from a larger staging chamber.     

The impact of floods and storms on the acoustic reflectivity of the inner continental shelf: A modeling assessment

Flood deposition and storm reworking of sediments on the inner shelf can change the mixture of grain sizes on the seabed and thus its porosity, bulk density, bulk compressional velocity and reflectivity. Whether these changes are significant enough to be detectable by repeat sub-bottom sonar surveys, however, is uncertain. Here the question is addressed through numerical modeling. Episodic flooding of a large versus small river over the course of a century are modeled with HYDROTREND using the drainage basin characteristics of the Po and Pescara Rivers (respectively). A similarly long stochastic record of storms offshore of both rivers is simulated from the statistics of a long-term mooring recording of waves in the western Adriatic Sea. These time series are then input to the stratigraphic model SEDFLUX2D, which simulates flood deposition and storm reworking on the inner shelf beyond the river mouths. Finally, annual changes in seabed reflectivity across these shelf regions are computed from bulk densities output by SEDFLUX2D and compressional sound speeds computed from mean seafloor grain size using the analytical model of Buckingham [1997. Theory of acoustic attenuation, dispersion, and pulse propagation in unconsolidated granular materials including marine sediments. Journal of the Acoustical Society of America 102, 2579–2596; 1998. Theory of compressional and shear waves in fluidlike marine sediments. Journal of the Acoustical Society of America 103, 288–299; 2000. Wave propagation, stress relaxation, and grain-tograin shearing in saturated, unconsolidated marine sediments. Journal of the Acoustical Society of America 108, 2796–2815]. The modeling predicts reflectivities that change from <12 dB for sands on the innermost shelf to >9 dB for muds farther offshore, values that agree with reflectivity measurements for these sediment types. On local scales of ∼100 m, however, maximum changes in reflectivity are <0.5 dB. So are most annual changes in reflectivity over all water depths modeled (i.e., 0–35 m). Given that signal differences need to be ⩾2–3 dB to be resolved, the results suggest that grain-size induced changes in reflectivity caused by floods and storms will rarely be detectable by most current sub-bottom sonars.     

Extraterrestrial chromite in the resurge deposits of the early Late Ordovician Lockne crater,central Sweden

The distribution of extraterrestrial chromite grains (> 63 μm) has been studied in the resurge deposit of the early Late Ordovician (458 Ma) Lockne impact structure in central Sweden. A 1-kg-sample of resurge sediment from the rim of the crater is extremely rich in extraterrestrial chromite. In total the sample contains > 125 chromium spinel grains kg^− 1, most grains being chromite. Due to post-depositional alterations, the origin of several of the grains is dubious, although it is clear that the major part of the chromites is of extraterrestrial origin (> 75 grains kg^− 1), most likely derived from the impactor. The alterations are primarily due to the hydrothermal system induced by the impactor, with zinc enrichment in the chromites as the most common characteristic. The element chemistry of the least altered chromite grains indicates that the impactor was an ordinary L chondrite. This concurs with a suggested increase in the flux of L chondritic asteroids to Earth, following the disruption of the L chondrite parent body at ca. 470 Ma.More than 170 impact craters are known from around the Earth, but only few of the impactors have been identified, mainly due to the low survival rate of projectile material. Further studies of impact craters will reveal if survival of extraterrestrial chromite is unique for the Lockne structure.     

Suspended microplastics in the surface water of the Yangtze Estuary System,China: First observations on occurrence,distribution

Levels of microplastics (MPs) in China are completely unknown. This study characterizes suspended MPs quantitatively and qualitatively for the Yangtze Estuary and East China Sea. MPs were extracted via a floatation method. MPs were counted and categorized according to shape and size under a stereomicroscope. The MP densities were 4137.3 ± 2461.5 and 0.167 ± 0.138 n/m³, respectively, in the estuarine and the sea samples. Plastic abundances varied significantly in the estuary. Higher densities in three sea trawls confirmed that rivers were the important sources of MP to the marine environment. Plastic particles (>5 mm) were observed with a maximum size of 12.46 mm, but MPs (0.5–5 mm) constituted more than 90% by number of items. The most frequent geometries were fibres, followed by granules and films. Plastic spherules occurred sparsely. Transparent and coloured plastics comprised the majority of the particles. This study provides clues in understanding the fate and potential sources of MPs.