Metallogenetic systems associated with granitoid magmatism in the Amazonian Craton: An overview of the present level of understanding and exploration significance

The Amazonian Craton hosts world-class metallogenic provinces with a wide range of styles of primary precious, rare, base metal, and placer deposits. This paper provides a synthesis of the geological database with regard to granitoid magmatic suites, spatio temporal distribution, tectonic settings, and the nature of selected mineral deposits. The Archean Carajás Mineral Province comprises greenstone belts (3.04–2.97 Ga), metavolcanic-sedimentary units (2.76–2.74 Ga), granitoids (3.07–2.84 Ga) formed in a magmatic arc and syn-collisional setting, post-orogenic A₂-type granites as well as gabbros (ca. 2.74 Ga), and anorogenic granites (1.88 Ga). Archean iron oxide-Cu-Au (IOCG) deposits were synchronous or later than bimodal magmatism (2.74–2.70 Ga). Paleoproterozoic IOCG deposits, emplaced at shallow-crustal levels, are enriched with Nb–Y–Sn–Be–U. The latter, as well as Sn–W and Au-EGP deposits are coeval with ca. 1.88 Ga A₂-type granites. The Tapajós Mineral Province includes a low-grade meta-volcano-sedimentary sequence (2.01 Ga), tonalites to granites (2.0–1.87 Ga), two calc-alkaline volcanic sequences (2.0–1.95 Ga to 1.89–1.87 Ga) and A-type rhyolites and granites (1.88 Ga). The calc-alkaline volcanic rocks host epithermal Au and base metal mineralization, whereas Cu–Au and Cu–Mo ± Au porphyry-type mineralization is associated with sub-volcanic felsic rocks, formed in two continental magmatic arcs related to an accretionary event, resulting from an Andean-type northwards subduction. The Alta Floresta Gold Province consists of Paleoproterozoic plutono-volcanic sequences (1.98–1.75 Ga), generated in ocean–ocean orogenies. Disseminated and vein-type Au ± Cu and Au + base metal deposits are hosted by calc-alkaline I-type granitic intrusions (1.98 Ga, 1.90 Ga, and 1.87 Ga) and quartz-feldspar porphyries (ca. 1.77 Ga). Timing of the gold deposits has been constrained between 1.78 Ga and 1.77 Ga and linked to post-collisional Juruena arc felsic magmatism (e.g., Colíder and Teles Pires suites). The Transamazonas Province corresponds to a N–S-trending orogenic belt, consolidated during the Transamazonian cycle (2.26–1.95 Ga), comprising the Lourenço, Amapá, Carecuru, Bacajá, and Santana do Araguaia tectonic domains. They show a protracted tectonic evolution, and are host to the pre-, syn-, and post-orogenic to anorogenic granitic magmatism. Gold mineralization associated with magmatic events is still unclear. Greisen and pegmatite Sn–Nb–Ta deposits are related to 1.84 to 1.75 Ga late-orogenic to anorogenic A-type granites. The Pitinga Tin Province includes the Madeira Sn–Nb–Ta–F deposit, Sn-greisens and Sn-episyenites. These are associated with A-type granites of the Madeira Suite (1.84–1.82 Ga), which occur within a cauldron complex (Iricoumé Group). The A-type magmatism evolved from a post-collisional extension, towards a within-plate setting. The hydrothermal processes (400 °C–100 °C) resulted in albitization and formation of disseminated cryolite, pyrochlore columbitization, and formation of a massive cryolite deposit in the core of the Madeira deposit. The Rondônia Tin Province hosts rare-metal (Ta, Nb, Be) and Sn–W mineralization, which is associated with the São Lourenço-Caripunas (1.31–1.30 Ga), related to the post-collisional stage of the Rondônia San Ignácio Province (1.56–1.30 Ga), and to the Santa Clara (1.08–1.07 Ga) and Younger Granites of Rondônia (0.99–0.97 Ga) A-type granites. The latter are linked to the evolution of the Sunsás-Aguapeí Province (1.20–0.95 Ga). Rare-metal polymetallic deposits are associated with late stage peraluminous granites, mainly as greisen, quartz vein, and pegmatite types.     

A Paleoproterozoic orogeny recorded in a long-lived cratonic remnant (Wuyishan terrane), eastern Cathaysia Block, China

The Precambrian basement of northern Wuyishan (southern Zhejiang Province, eastern Cathaysia Block, South China), consists mainly of Paleoproterozoic granites and metamorphic rocks of the Badu Complex, which are the oldest rocks found in the Cathaysia Block. LA-ICPMS zircon U–Pb ages for a gneiss and five gneissic granites from the Tianhou, Danzhu, Xiaji and Lizhuang plutons indicate that magmatism and metamorphism took place between 1888 and 1855 Ma. The Xiaji (1888 ± 7 Ma) and Lizhuang (1875 ± 9 Ma) granites have high SiO₂, K₂O and Rb contents, high A/CNK (1.09–1.40) and Rb/Sr, and low contents of Sr, REE and mafic components (Mg, Fe, Ti, Mn and other transition metals). They have the geochemical signature of S-type granites, and a sedimentary protolith is confirmed by the presence of abundant inherited zircons with a range of ages and Hf-isotope compositions. The Tianhou and Danzhu granites are metaluminous to weakly peraluminous (A/CNK = 0.80–1.07), and have low SiO₂ contents, high Ga/Al and FeO/(FeO + MgO) ratios, and Zn and HFSE concentrations typical of A-type granites. They also record high crystallization temperatures (885–920 °C), consistent with A-type granites. High Y/Nb ratios (>1.4) indicate that they belong to the A₂ subgroup, suggesting that they probably formed in a post-orogenic tectonic setting. Their ages range from 1867 to 1855 Ma, slightly later than the syn-collisional Lizhuang and Xiaji S-type granites. These granitic rocks and the metamorphic rocks of the Badu Complex define a late Paleoproterozoic orogenic cycle in the area. All the 1.86–1.90 Ga zircons, whether derived from S- or A-type granites, show similar Hf-isotopic compositions, with Hf model ages clustering at 2.8 Ga. These model ages, and inherited zircons (ca. 2.5–2.7 Ga) found in some rocks, indicate that the late Paleoproterozoic magmatism and tectonism of the eastern Cathaysia Block represent an overprint on an Archaean basement. This Paleoproterozoic orogeny in the Wuyishan terrane coincides with the assembly of the supercontinent Columbia, suggesting that the Wuyishan terrane was the part of this supercontinent.Zircon ages also record an early Mesozoic (Triassic) tectonothermal overprint that was very intensive in the northern Wuyishan area, leading to high-grade metamorphism of Paleoproterozoic basement, Pb loss from Paleoproterozoic zircons and overgrowth of new zircon. The central and southern parts of Wuyishan and the Chencai area (northern Zhejiang Province) also experienced strong reworking in Neoproterozoic and early Paleozoic times. The Wuyishan terrane (especially in the north) represents a long-lived remnant of the old craton, which has survived for at least one billion years. The compositions of the basement rocks, the Paleoproterozoic orogeny and the Triassic tectonothermal imprint in the Wuyishan terrane are similar to those recognized in the Yeongnam massif of South Korea, suggesting that the two terranes may have been connected from Paleoproterozoic to Triassic time.     

Geochemistry,U–Pb geochronology,Sm–Nd and O isotopes of ca. 50 Ma long Ediacaran High-K Syn-Collisional Magmatism in the Pernambuco Alagoas Domain,Borborema Province,NE Brazil

The Pernambuco Alagoas (PEAL) domain shows the major occurrence of granitic batholiths of the Borborema Province, NE Brazil, with Archean to Neoproterozoic range of Nd T_DM model ages, giving clues on the role of granites during the Brasiliano orogeny. SHRIMP U/Pb zircon geochronological data for seven granitic intrusions of the PEAL domain divide the studied granitoids into three groups: 1) early-to syn-collision granitoids with crystallization ages ca. 635 Ma (Serra do Catú pluton), 2) syn-collision granitoids with crystallization ages 610–618 Ma (Santana do Ipanema, Água Branca, Mata Grande and Correntes plutons) and 3) late-to post-collision granitoids with ages of ca. 590 Ma (Águas Belas, and Cachoeirinha plutons). The intrusions of group 1 and 2, except the Mata Grande and Correntes plutons, show Nd T_DM model ages ranging from 1.2 to 1.5 Ga, while the granitoids from group 3, and Mata Grande Pluton and Correntes plutons have Nd T_DM model ages ranging from 1.7 to 2.2 Ga. The studied granitoids with ages <600 Ma are high-K, calc-alkaline, shoshonitic and those with ages <600 Ma are transitional high-K calc-alkaline to alkaline. The volcanic arc signatures associated with the Paleoproterozoic Nd T_DM model ages are interpreted as inherited from the source rocks. The oldest ages and lower Nd T_DM model ages are recorded from granitoids intruded in the southwest part of the PEAL domain, suggesting that these intrusions are associated with slab-tearing during convergence between the PEAL and the Sergipano domains. Zircon oxygen isotopic data in some of the studied plutons, together with the available Nd isotopic data suggest that the Brasiliano orogeny strongly reworked older crust, of either Paleoproterozoic or Tonian ages. The studied granitoids are coeval with calc-alkaline granitoids of the Transversal Zone and Sergipano domains and rare high-K calc-alkaline granitoids from the Transversal Zone domain. Such large volumes of high-K granitoids with crystallization ages older than 600 Ma are not recorded in the Transversal Zone domains, suggesting that at least between 600 and 650 Ma, the granitic magmatism of these two areas were distinct. However, the studied granitoids (630–580 Ma) located in the north part of the PEAL domain, north of the Palmares shear zone are coeval with granitoids of similar geochemical compositions in the Transversal Zone domain. It suggests that the southeastern part of the Transversal Zone and the northern part of the PEAL domains belonged to the same crustal block during the Brasiliano/Pan-African orogeny.     

Geochemical Characterization of Granites of Distinctly Different Ages in the Alto Pajeu Terrane,Borborema Province,Northeast Brazil

This work presents geochemical data for granitic plutons that intruded the Alto Pajeu terrane, Borborema Province, northeastern Brazil, during several distinct tectonic cycles. The Alto Pajeu terrane is represented in the study area by metasedimentary (São Caetano Formation) and metavolcanosedimentary (Irajai Formation) sequences overlying a gneissic-migmatitic basement. Several granitic plutons of different ages, mineralogical proportions, and chemical compositions have invaded the supracrustal and basement rocks. Two deformational events, one tangential (older) and the other transcurrent (younger), were identified. The metamorphic grade determined for the metasedimentary rocks varies from amphibolite to high amphibolite facies, with temperatures ranging from 600 to 680°C and pressures from 6.0 to 7.5 kbar. Three magmatic events with distinct ages were identified for the tectonic evolution of the Alto Pajeu terrane in the study area. The older magmatic event is related to the Transamazonico orogenic cycle (～ 2.0 Ga), the intermediary magmatic event to the Cariris Velhos cycle (～0.97 Ga), and the younger magmatic event to the Brasiliano orogenic cycle (～0.55 Ga). The Cariris Velhos- and Brasiliano-age granites are geochemically classified as peraluminous, subalkalic granites of the calc-alkalic series, whereas the Transamazônico-age granite is metaluminous and alkaline. Geochemical data presented and discussed here suggest that the magmatism related to the three tectonic events had distinctly different sources and petrogenetic evolutions.     

Isotopic signatures of Paleoproterozoic granitoids from the southern São Francisco Craton and implications for the evolution of the Transamazonian Orogeny

The southern São Francisco Craton, northeastern Brazil, consists of an Archean block surrounded by a Paleoproterozoic belt related to the Transamazonian Orogeny (ca. 2.0 Ga). A calc-alkaline plutonic arc developed within the belt and the granitoid plutons comprise two distinct groups. One group displays Archean T_DM ages (3.07–2.62 Ga), ε_Nd(t) values between −11.0 and −3.8 and high initial ⁸⁷Sr/⁸⁶Sr values, and it consists mainly of peraluminous granites. T_DM ages for the other group are Paleoproterozoic (2.43–2.27 Ga), and ε_Nd(t) values range between −2.8 and +1.3; the plutons are metaluminous tonalites (trondhjemites) to granodiorites. The Transamazonian granitoids can be related to contrasting source-regions, from mantle- to crust-derived ones. A number of them are probably derived from mixing of Paleoproterozoic juvenile material and variable proportions of Archean crust material. Magmatism related to deep faulting, during the compressional stages of the Transamazonian Orogeny, is a plausible model for granitoid generation. The contribution of mantle-derived material to the granitoid sources supports the idea that a significant episode of new crust formation occurred during the Transamazonian Orogeny.     

Timing of Proterozoic magmatism in the Sunsas belt,Bolivian Precambrian Shield,SW Amazonian Craton

We present new U-Pb zircon and monazite ages from the Sunsas belt granitic magmatism in Bolivia,SW Amazonian Craton.The geochronological results revealed four major magmatic events recorded along the Sunsas belt domains.The older igneous event formed a granitic basement coeval to the Rio Apa Terrane(1.95-1.85 Ga)in the southern domain.The second magmatic episode is represented by 1.68 Ga granites associated to the Paraguá Terrane(1.69-1.66 Ga)in the northern domain.The 1.37-1.34 Ga granites related to San Ignacio orogeny represent the third and more pervasive magmatic event,recorded throughout the Sunsas belt.Moreover,magmatic ages of～1.42 Ga revealed that the granitogenesis asso-ciated to the Santa Helena orogeny also affected the Sunsas belt,indicating that it was not restricted to the Jauru Terrane.Lastly,the 1.10-1.04 Ga youngest magmatism was developed during the Sunsas oro-geny and represents the final magmatic evolution related to Rodinia assembly.Likewise,the 1.95-1.85 and 1.68 Ga inherited zircon cores obtained in the～1.3 Ga and 1.0 Ga granite samples suggest strong par-tial melting of the Paleoproterozoic sources.The 1079±14 Ma and 1018±6 Ma monazite crystallization ages can be correlated to the collisional tectono-thermal event of the Sunsas orogeny,associated to reac-tions of medium-to high-grade metamorphism.Thus,the Sunsas belt was built by heterogeneous 1.95-1.85 Ga and 1.68 Ga crustal fragments that were reworked at 1.37-1.34 Ga and 1.10-1.04 Ga related to orogenic collages.Furthermore,the 1.01 Ga monazite age suggests that granites previously dated by zir-con can bear evidence of a younger thermal history.Therefore,the geochronological evolution of the Sunsas belt may have been more complex than previously thought.     

U/Pb and Sm/Nd geochronologic studies of the eastern Borborema Province, Northeastern Brazil: initial conclusions

The Borborema Province of NE Brasil comprises the central part of a wide Pan-African-Brasiliano orogenetic belt that formed as a consequence of late Neoproterozoic convergence and collision of the São Luis-West Africa craton and the São Francisco-Congo-Kasai cratons. New Sm/Nd and U/Pb results from the eastern part of this province help to define the basic internal architecture and pre-collisional history of this province, with particular emphasis on delineating older cratonic terranes, their fragmentation during the Mesoproterozoic, and their assembly into West Gondwana during the Pan African-Brasiliano orogeny at ca. 600 Ma.The region can be divided into three major geotectonic domains: a) Rio Piranhas-Caldas Brandão massif, with overlying Paleoproterozoic to Neoproterozoic supracrustal rocks, north of the Patos Lineament; b) the Archean to Paleoproterozoic São Francisco craton (SFC) to the south; and c) a complex domain of Paleoproterozoic to Archean basement blocks with several intervening Mesoproterozoic to Neoproterozoic fold belts in the center (south of Patos Lineament and north of SFC). The northern and central domains comprise the Borborema Province.Archean basement gneiss and Transamazonian granulite of northern SFC are exposed in the southern part of the central domain, underlying southern parts of the Sergipano fold belt. Basement in the Rio Piranhas massif appears to consist mostly of Transamazonian (2.1 to 2.2 Ga) gneissic rocks; Nd model ages (T_DM) of ca. 2.6 Ga for 2.15 Ga gneisses indicate a substantial Archean component in the protoliths to these gneisses. The Caldas Brandão massif to the east yields both Transamazonian and Archean U/Pb zircon and Nd (T_DM) ages, indicating a complex architecture. Metasedimentary rocks of the Jucurutu Formation yield detrital zircons with original crystallization ages as young as 1.8 Ga, indicating that these rocks may be late Paleoproterozoic and correlate with other ca. 1.8 Ga cratonic supracrustal rocks in Brazil such as the Roraima Group and Espinhaço Group.Most metavolcanic and pre-Brasiliano granitic units of the Sergipano (SDS), Pajeú-Paraíba (SPP), Riacho Pontal (SRP), and Piancó-Alto Brígida (SPAB) fold belts in the central domain formed ˜ 1.0 ± 0.1 Ga, based on U/Pb ages of zircons. Nd model ages (T_DM) for these same rocks, as well as Brasiliano granites intruded into them and large parts of the Pernambuco-Alagoas massif, are commonly 1.3–1.7 Ga, indicating that rocks of the fold belts were not wholly derived from either older (> 2.1 Ga) or juvenile (ca. 1.0 Ga) crust, but include mixtures of both components. A simple interpretation of Brasiliano granite genesis and the Nd data implies that there is no Transamazonian or Archean basement underlying large parts of these fold belts or of the Pernambuco-Alagoas massif. An exception is a belt of syenitic Brasiliano plutons (Syenitoid Line) and host gneisses between SPAB and SPP that clearly has a Transamazonian (or older) source. In addition, there are several smaller blocks of Archean to Transamazonian gneiss that can be defined within and among these fold belts. These blocks do not appear to constitute a continuous basement complex, but appear to be isolated older crustal fragments.Our data support a model in which ca. 1.0 Ga rifting was an important tectonic and crust-forming event along the northern edge of the São Francisco craton. Our data also show that significant parts of the Borborema Province are not remobilized Transamazonian to Archean crust, but that Mesoproterozoic crust is a major feature of the Province. There are several small remnants of older crust within the area dominated by Mesoproterozoic crust, suggesting that the rifting event created several small continental fragments that were later incorporated into the Brasiliano collisional orogen. We cannot at present determine if the Rio Piranhas-Caldas Brandão massifs and the older crustal blocks of the central domain were originally part of the São Francisco craton or whether some (or all) of them came from more exotic parts of the Proterozoic Earth. Finally, our data have not yet revealed any juvenile terranes of either Transamazonian or Brasiliano age.     

Paleoproterozoic granitoids from the northern limit of the Archean Amapá block (Brazil), southeastern Guyana Shield: Pb–Pb evaporation in zircons and Sm–Nd geochronology

Central Amapá, northern Brazil is located at the boundary between: (a) a northern Paleoproterozoic domain, consisting mainly of granite-greenstones terrains and (b) a southern Archean continental block (Amapá block), including an Archean basement reworked during the Transamazonian orogeny (2.26–1.95 Ga). Field investigations, Pb–Pb zircon and Sm–Nd whole rock geochronology supported by geochemical data on granitoids brought further constraints on Paleoproterozoic crustal growth in the southeastern Guyana Shield. A first magmatic episode, dated at 2.26 Ga, is marked by the crystallization of metaluminous low-K tholeiitic tonalites and quartz-diorites, which geochemical affinity with volcanic arc and association with T-MORB amphibolites suggest that they formed in a back-arc basin – island arc system. This event is coeval to the oceanic stage registered in French Guyana during the Eorhyacian (2.26–2.02 Ga). A second magmatic episode is represented by peraluminous, medium- to high-K calc-alkaline tonalite and granodiorite, which revealed some similarities with Mesorhyacian TTG rocks of French Guyana. For granitoids of both episodes, T_DM and ε_Nd values indicate the contribution of some Archean crustal component, probably by assimilation or contamination. This second magmatic episode occurred at 2.10 Ga, indicating that the period of successive calc-alkaline magmatic arcs formation may have extended until the Neorhyacian. Meanwhile, during this time, tectonic accretion by collision of the newly formed continental landmass was the prevailing process in French Guyana. The latter magmatic episode, even though poorly constrained, was registered around 2.08–2.02 Ga in central Amapá. It corresponds to the emplacement and solidification of high-K collisional granitoids, produced by partial melting of the Archean continental crust, as testified by the Archean T_DM, inherited Pb–Pb zircon ages and strongly negative ε_Nd values. Our results point toward the existence of a protracted episode of crustal growth during the Neorhyacian in the southeastern Guyana Shield. This episode has been predominantly driven by magmatic arc accretion during, at least, 160 My, along the period of 2.26–2.10 Ga. This cycle ended with diachronic closure of the oceanic basins and arc–continent collision.     

Origin of the Alxa Block,western China: New evidence from zircon U–Pb geochronology and Hf isotopes of the Longshoushan Complex

The NW–SE trending Longshoushan is in the southwestern margin of the Alxa Block, which was traditionally considered the westernmost part of the North China Craton (NCC). Precambrian crystalline basement exposed in the Longshoushan area was termed the “Longshoushan Complex”. This complex's formation and metamorphism are significant to understand the geotectonics and early Precambrian crustal evolution of the western NCC. In this study, field geology, petrology, and zircon U–Pb and Lu–Hf isotopes of representative orthogneisses and paragneisses in the Longshoushan Complex were investigated. U–Pb datings reveal three Paleoproterozoic magmatic episodes (ca. 2.33, ca. 2.17 and ca. 2.04 Ga) and two subsequent regional metamorphic events (ca. 1.95–1.90 Ga and ca. 1.85 Ga) for metamorphic granitic rocks in the Longshoushan Complex. U–Pb dating of the detrital magmatic zircons from two paragneisses yields concordant ²⁰⁷Pb/²⁰⁶Pb ages between 2.2 Ga and 2.0 Ga, and a small number of metamorphic zircon rims provide a ca. 1.95 Ga metamorphic age, suggesting that the depositional time of the protolith was between 2.0 and 1.95 Ga and that the sedimentary detritus was most likely derived from the granitic rocks in the Longshoushan Complex itself. Zircon Lu–Hf isotopic analyses indicate that nearly all magmatic zircons from ca. 2.0 Ga to ca. 2.17 Ga orthogneisses have positive εHf(t) values with two-stage Hf model ages (T_DMC) ranging from 2.45 to 2.65 Ga (peak at ca. 2.5 Ga), indicating that these Paleoproterozoic granitic rocks were derived from the reworking of the latest Neoarchean–early Paleoproterozoic juvenile crust. Detrital magmatic zircons from two paragneisses yield scattered ¹⁷⁶Hf/¹⁷⁷Hf ratios, εHf(t) and T_DMC values, further indicating that the sedimentary detritus was not only derived from these plutonic rocks but also from other unreported or denuded Paleoproterozoic igneous rocks. The ca. 2.15 Ga detrital magmatic zircons from one paragneiss have negative εHf(t) values with T_DMC ranging from 2.76 to 3.04 Ga, indicating another important crustal growth period in the Longshoushan region. These data indicate that the Longshoushan Complex experienced Neoarchean–Early Paleoproterozoic crustal growth, approximately ca. 2.3–2.0 Ga experienced multiphase magmatic events, and approximately ca. 1.95–1.90 Ga and ca. 1.85 Ga experienced high-grade metamorphic events. The sequence of tectonothermal events is notably similar to that of the main NCC. Together with the datasets from an adjacent area, we suggest that the western Alxa Block was most likely an integrated component of the NCC from the Neoarchean to the Paleoproterozoic.     

Late Triassic post-collisional granites related to Paleotethyan evolution in northwestern Lao PDR: Geochronological and geochemical evidence

The late Paleozoic to early Mesozoic granites exposed in northwestern Lao PDR provide important constraints on the tectonic evolution of the Eastern Paleotethyan Ocean and regional correlation with the giant granitic belt in Southeast Asia. New geochronological data show that the granites have Late Triassic zircon U–Pb ages of 231–220 Ma. They are dominated by monzogranite and biotite granite with an I-type geochemical affinity. These granites are enriched in LREEs and LILEs and depleted in HFSEs. The geochemical variations for these granites indicate the fractional crystallization of plagioclase, K-feldspar, biotite, apatite, and Fe–Ti oxides. Their initial ⁸⁷Sr/⁸⁶Sr ratios range from 0.7021 to 0.7105 and ε_Nd (t) values from −1.6 to −7.3. Zircon in-situ ε_Hf (t) values are in range of −6.0–+5.3 (peaks at −2.8 and +2.5, respectively), Hf model ages of 0.67–1.64 Ga (peaks at 0.83 Ga and 1.45 Ga, respectively), and δ¹⁸O values of 6.6‰–8.0‰, similar to the Late Triassic granitoids from the Eastern Province in Southeast Asia. These granites originated from a mixed source of ancient metamorphic rocks with juvenile mafic crust. The Late Triassic granites in northwestern Lao PDR formed in a post-collisional setting in response to the thickened crustal collapse during the assembly of the Sibumasu with Indochina blocks. These granites can southerly link with the Eastern granite province of the Eastern Paleotethyan Domain in Southeast Asia.     

Precambrian history of the Zona Transversal of the Borborema Province,NE Brazil: Insights from Sm–Nd and U–Pb geochronology

The Borborema Province has three major subprovinces. The northern subprovince lies north of the Patos shear zone and is comprised of Paleoproterozoic cratonic basement with Archean nuclei, plus overlying Neoproterozoic supracrustal rocks and Brasiliano plutonic rocks. The central subprovince occurs between the Patos and Pernambuco shear zones and is mainly comprised of the Zona Transversal. The southern subprovince occurs between the Pernamabuco shear zone and the São Francisco craton and is comprised of a tectonic collage of various blocks, terranes, or domains ranging in age from Archean to Neoproterozoic. This report focuses on the Zona Transversal, especially on Brasiliano rocks for which we have the most new information.Paleoproterozoic gneisses with ages of 2.0–2.2 Ga occur discontinuously throughout the Zona Transversal. The Cariris Velhos suite consists of metavolcanic, metasedimentary, and metaplutonic rocks yielding U–Pb zircon ages of 995–960 Ma. This suite is mainly confined to a 100 km wide belt that extends for more than 700 km within the Alto Pajeú terrane. Sm–Nd model ages in metaigneous rocks cluster about 1.3–1.6 Ga, indicating that older crust was involved in genesis of their magmas. Brasiliano supracrustal rocks dominate the Piancó-Alto Brígida terrane, and they probably also constitute significant parts of the Alto Pajeú and Rio Capibaribe terranes. They are only slightly older than early stages of Brasiliano plutonism, with detrital zircon ages at least as young as 620 Ma; most T_DM ages range from 1.2 to 1.6 Ga.Brasiliano plutons range from ca. 640 to 540 Ma, and their T_DM ages range from 1.2 to 2.5 Ga. Previous workers have shown significant correlations among U–Pb ages, Sm–Nd model ages, petrology, and geochemistry, and we are able to reinforce and extend these correlations. Stage I plutons formed 640–610 Ma and have T_DM ages less than 1.5 Ga. Stage II (610–590 Ma) contains few plutons, but coincides with the peak of compressional deformation, metamorphism, and formation of migmatites. Stage III plutons (590 to ca. 575 Ma) have older T_DM ages (ca. 1.8–2.0 Ga), as do Stage IV plutons (575 to ca. 550 Ma; T_DM from 1.9 to 2.4 Ga). Stage III plutons formed during the transition from compressional to transcurrent deformation, while Stage IV plutons are mainly post-tectonic. Stage V plutons (550–530 Ma) are commonly undeformed (except along younger shear zones) and have A-type geochemistry. The five stages have distinct geochemical properties, which suggest that the tectonic settings evolved from early, arc-related magma-genesis (Stage I) to within-plate magma-genesis (Stage V), with perhaps some intermediate phases of extensional environments.     

First evidence for Cambrian rift-related magmatism in the West African Craton margin: The Derraman Peralkaline Felsic Complex

West of the southern, Archean, part of the Reguibat Rise of the West African Craton the Oulad Dlim Massif consists of metamorphic nappes stacked during the Mauritanides (Variscan) orogeny. In the Derraman region, about 12 km west of the nappes, we have found strongly deformed hypersolvus aegirine-riebeckite A1-type granites with SHRIMP zircon U–Pb ages of ca. 525 ± 3 Ma, ε(Nd)_525Ma (− 5.2 to − 6.8.) and Nd model ages T_CR ≈ 1.85 Ga. These granites define two km-sized bodies and a few smaller satellites. One body is emplaced within a 3.12 Ga leucocratic gneiss. The other body and its satellites are emplaced within an Archean low-grade metasedimentary sequence with detrital zircons that have ages that peak at 2.84 Ga, 2.91 Ga, and 3.15 Ga. These Archean gneisses and metapelite rocks define a tectonic unit, hereafter called the Derraman-Bulautad-Leglat (DBL) unit, which was formed from the Reguibat basement at the very margin of the WAC. The ~ 525 Ma Derraman granites are the oldest post-Archean rocks in this unit and were generated in an intraplate rifting environment from melting of crustal fenites during the ubiquitous Cambrian rifting event that affected this part of northern Gondwana. At the present level of knowledge, however, we cannot decide whether the “old” Nd isotope signature of Derraman granites resulted from melting of an old (Paleoproterozoic) fenite source or reflects the signature of the mantle-derived metasomatising fluids. The just-discovered Derraman granites are strikingly similar to other rift-related Cambrian–Ordovician hypersolvus aegirine–riebeckite granites widespread in North Gondwana. Understanding the potential connections between them would help to understand the Cambrian–Ordovician breakdown of northern Gondwana.     

The formation and rejuvenation of continental crust in the central North China Craton: Evidence from zircon U–Pb geochronology and Hf isotope

The Trans-North China Orogen (TNCO) along the central part of the North China Craton (NCC) is considered as a Paleoproterozoic suture along which the Eastern and Western Blocks of the NCC were amalgamated. Here we investigate the Precambrian crustal evolution history in the Fuping segment of the TNCO and the subsequent reactivation associated with extensive craton destruction during Mesozoic. We present zircon LA-ICP-MS U–Pb and Lu–Hf data on TTG (tonalite–trondhjemite–granodiorite) gneiss, felsic orthogneiss, amphibolite and granite from the Paleoproterozoic suite which show magmatic ages in the range of 2450–1900 Ma suggesting a long-lived convergent margin. The ε_Hf(t) values of these zircons range from −11.9 to 12 and their model ages suggest magma derivation from both juvenile components and reworked Archean crust. The Mesozoic magmatic units in the Fuping area includes granite, diorite and mafic microgranular enclaves, the zircons from which define a tight range of 120–130 Ma ages suggesting a prominent Early Cretaceous magmatic event. However, the ε_Hf(t) values of these zircons show wide a range from −30.3 to 0.2, indicating that the magmatic activity involved extensive rejuvenation of the older continental crust.     

Rhyacian (2.23–2.20 Ga) juvenile accretion in the southern São Francisco craton,Brazil: Geochemical and isotopic evidence from the Serrinha magmatic suite,Mineiro belt

The Serrinha magmatic suite (Mineiro belt) crops out in the southern edge of the São Francisco craton, comprising the Brito quartz-diorite, Brumado de Cima and Brumado de Baixo granodiorites, granophyres and felsic sub-volcanic and volcanic rocks, part of which intruded into the Nazareno greenstone belt. The suite rocks have petrographic features that are consistent with magma supercooling due to the low water content combined with volatile loss, leading to crystallization of quartz and alkaline feldspar at the rims of plagioclase phenocrysts (granophyric intergrowth). The investigated rocks are sub-alkaline, calc-alkaline and show low content in rare earth elements. The U–Pb zircon crystallization ages for the Brumado de Cima granodiorite [2227 ± 22 (23) Ma] and a coeval granophyre [2211 ± 22 (23) Ma], coupled with available single-zircon Pb evaporation ages for the Brito and Brumado de Baixo plutons, are significantly older than the “Minas orogeny” (ca. 2100–2050 Ga) of Quadrilátero Ferrífero area, eastward from the Serrinha suite. Our data establish an early Rhyacian event tectonically linked with the evolution of the Mineiro belt. The bulk Nd isotopic signature [low negative to positive ε_Nd(t) values] of the Serrinha samples are consistent with the important role of Paleoproterozoic mantle components in the magma genesis. The integrated geologic, geochemical and isotopic information suggests that Paleoproterozoic evolution of the Mineiro belt initiated in a passive continental margin basin with deposition of the Minas Supergroup at ca. 2500 Ma. This stage was succeeded by outboard rupture of the oceanic lithosphere with development and coalescence of progressively younger magmatic arcs during Rhyacian time. One of the earliest arcs formed the Serrinha suite. The tectonic collage of the Serrinha and Ritápolis (2190–2120 Ma) arcs produced the NE–SW Lenheiro shear zone, resulting in mylonitization and recrystallization of both the granitoid intrusions and host rocks. As a matter of fact juxtaposition of distinct magmatic units in age and origin took place along the Lenheiros structure in this sector of the Mineiro belt.     

Sources of granite magmatism in the Embu Terrane (Ribeira Belt,Brazil): Neoproterozoic crust recycling constrained by elemental and isotope (Sr-Nd-Pb) geochemistry

Whole rock elemental and Sr–Nd isotope geochemistry and in situ K-feldspar Pb isotope geochemistry were used to identify the sources involved in the genesis of Neoproterozoic granites from the Embu Terrane, Ribeira Belt, SE Brazil. Granite magmatism spanned over 200 Ma (810–580 Ma), and is dominated by crust-derived relatively low-T (850–750 °C, zircon saturation) biotite granites to biotite-muscovite granites. Two Cryogenian plutons show the least negative εNd_t (−8 to −10) and highest mg# (30–40) of the whole set. Their compositions are strongly contrasted, implying distinct sources for the peraluminous (ASI ∼ 1.2) ∼660 Ma Serra do Quebra-Cangalha batholith (metasedimentary rocks from relatively young upper crust with high Rb/Sr and low Th/U) and the metaluminous (ASI = 0.96–1.00) ∼ 630 Ma Santa Catarina Granite. Although not typical, the geochemical signature of these granites may reflect a continental margin arc environment, and they could be products of a prolonged period of oceanic plate consumption started at ∼810 Ma. The predominant Ediacaran (595–580 Ma) plutons have a spread of compositions from biotite granites with SiO₂ as low as ∼65% (e.g., Itapeti, Mauá, Sabaúna and Lagoinha granites) to fractionated muscovite granites (Mogi das Cruzes, Santa Branca and Guacuri granites; up to ∼75% SiO₂). εNd_T are characteristically negative (−12 to −18), with corresponding Nd T_DM indicating sources with Paleoproterozoic mean crustal ages (2.0–2.5 Ga). The Guacuri and Santa Branca muscovite granites have the more negative εNd_t, highest ⁸⁷Sr/⁸⁶Sr_t (0.714–0.717) and lowest ²⁰⁸Pb/²⁰⁶Pb and ²⁰⁷Pb/²⁰⁶Pb, consistent with an old metasedimentary source with low time-integrated Rb/Sr. However, a positive Nd–Sr isotope correlation is suggested by data from the other granites, and would be consistent with mixing between an older source predominant in the Mauá granite and a younger, high Rb/Sr source that is more abundant in the Lagoinha granite sample. The Ediacaran granites are coeval with profuse granite magmatism attributed to continental arc magmatism in northern Ribeira and Araçuaí belts. However, their evolved compositions with low mg# and dominantly peraluminous character are unlike those of magmatic arc granites, and they are more likely products of post-collisional magmatism or correspond to an inner belt of crust-derived granites.     

The Cariris Velhos tectonic event in Northeast Brazil

The Borborema Province in northeastern South America is a typical Brasiliano-Pan-African branching system of Neoproterozoic orogens that forms part of the Western Gondwana assembly. The province is positioned between the São Luis-West Africa craton to the north and the São Francisco (Congo-Kasai) craton to the south. For this province the main characteristics are (a) its subdivision into five major tectonic domains, bounded mostly by long shear zones, as follows: Médio Coreaú, Ceará Central, Rio Grande do Norte, Transversal, and Southern; (b) the alternation of supracrustal belts with reworked basement inliers (Archean nuclei + Paleoproterozoic belts); and (c) the diversity of granitic plutonism, from Neoproterozoic to Early Cambrian ages, that affect supracrustal rocks as well as basement inliers. Recently, orogenic rock assemblages of early Tonian (1000–920 Ma) orogenic evolution have been recognized, which are restricted to the Transversal and Southern domains of the Province.Within the Transversal Zone, the Alto Pajeú terrane locally includes some remnants of oceanic crust along with island arc and continental arc rock assemblages, but the dominant supracrustal rocks are mature and immature pelitic metasedimentary and metavolcaniclastic rocks. Contiguous and parallel to the Alto Pajeú terrane, the Riacho Gravatá subterrane consists mainly of low-grade metamorphic successions of metarhythmites, some of which are clearly turbiditic in origin, metaconglomerates, and sporadic marbles, along with interbedded metarhyolitic and metadacitic volcanic or metavolcaniclastic rocks. Both terrane and subterrane are cut by syn-contractional intrusive sheets of dominantly peraluminous high-K calc-alkaline, granititic to granodioritic metaplutonic rocks. The geochemical patterns of both supracrustal and intrusive rocks show similarities with associations of mature continental arc volcano-sedimentary sequences, but some subordinate intra-plate characteristics are also found.In both the Alto Pajeú and Riacho Gravatá terranes, TIMS and SHRIMP U–Pb isotopic data from zircons from both metavolcanic and metaplutonic rocks yield ages between 1.0 and 0.92 Ga, which define the time span for an event of orogenic character, the Cariris Velhos event. Less extensive occurrences of rocks of Cariris Velhos age are recognized mainly in the southernmost domains of the Province, as for example in the Poço Redondo-Marancó terrane, where arc-affinity migmatite-granitic and meta-volcano-sedimentary rocks show U–Pb ages (SHRIMP data) around 0.98–0.97 Ga. For all these domains, Sm–Nd data exhibit T_DM model ages between 1.9 and 1.1 Ga with corresponding slightly negative to slightly positive ε_Nd(t) values. These domains, along with the Borborema Province as a whole, were significantly affected by tectonic and magmatic events of the Brasiliano Cycle (0.7–0.5 Ga), so that it is possible that there are some other early Tonian rock assemblages which were completely masked and hidden by these later Brasiliano events.Cariris Velhos processes are younger than the majority of orogenic systems at the end of Mesoproterozoic Era and beginning of Neoproterozoic throughout the world, e.g. Irumide belt, Kibaride belt and Namaqua-Natal belt, and considerably younger than those of the youngest orogenic process (Ottawan) in the Grenvillian System. Therefore, they were probably not associated with the proposed assembly of Rodinia. We suggest, instead, that Cariris Velhos magmatism and tectonism could have been related to a continental margin magmatic arc, with possible back-arc associations, and that this margin may have been a short-lived (<100 m.y.) leading edge of the newly assembled Rodinia supercontinent.     

Geochronology and geochemical characteristics of the Dongping ore-bearing granite,North China: Sources and implications for its tectonic setting

The Dongping gold deposit, located in Chongli County (Hebei Province) about 200 km northwest of Beijing, is one of the largest gold-producing areas along the northern margin of the North China Craton. It is located in the of Shuiquangou alkaline igneous complex of Middle Devonian age (394.3 ± 3.2 Ma), composed chiefly of highly alkaline syentite and quartz syenites. This study reveals the age of the Carboniferous in the deposit at 351.7 ± 2.8 Ma (MSWD = 1.9). The Dongping deposit is locally hosted in Cretaceous (~143 ± 1 Ma) alkali granites that intruded the older and the gold mineralization is closely associated genetically with this event. Hydrothermal zircons in the alkali granites have Th/U ratios mostly ranging between 0.01 and 0.7 indicating oscillatory zoning. A few grains with high Th/U ratios (1.31–2.07) may be from metamorphic domains. Negative εHf(t) values of the zircon mainly range between −19.75 and −16.93, suggesting that they originated principally by the melting of recycled continental crust. Less abundant zircons with εHf(t) ranging from −25.76 to −23.46, with Hf model ages (T_DM2) of 2.54 to 2.67 Ga, (mainly 2.2 to 2.3 Ga) suggest that recycled Neoarchean basement was also present in the source region. The Devonian syenites and quartz syenites have T_DM1 ages ranging from 1.96 to 2.08 Ga. Zircons from these rocks have εHf(t) values of −11.9 to −18.9. Certain zircons from the gold-bearing granite of Paleozoic age have an initial ¹⁷⁶Hf/¹⁷⁷Hf ratio of 0.281816 to 0.282058 and 0.282147 to 0.282348, reflecting a homogenous distribution of hafnium isotopes typical of magmatic sources. The T_DM1 and T_DM2 of the latest intrusion varying 1.33 to 1.59 Ga and 1.72 to 2.11 Ga respectively, indicating that the Neoproterozoic to Mesoproterozoic rocks of this area are an important source for the younger magma which are important to forming ore deposits. The TDM₂ indicate that the magma may be derived from a very old crustal basement (~2.67 Ga) in the northern margin of North China Craton by partial melting.     

Geochronology and isotope analysis of the Late Paleozoic to Mesozoic granitoids from northeastern Vietnam and implications for the evolution of the South China block

In northeastern Vietnam, Late Paleozoic and Permo-Triassic granitic plutons are widespread, but their tectonic significance is controversial. In order to understand the regional magmatism and crustal evolution processes of the South China block (SCB), this study reports integrated in situ U–Pb, Hf–O and Sr–Nd isotope analyses of granitic rocks from five plutons in northeastern Vietnam. Zircon SIMS U–Pb ages of six granitic samples cluster around in two groups 255–228 Ma and 90 Ma. Bulk-rock ε_Nd (t) ranges from −11 to −9.7, suggesting that continental crust materials were involved in their granitic genesis. In situ zircon Hf–O isotopic measurements for the granitic samples yield a mixing trend between the mantle- and supracrustal-derived melts. It is suggested that the granitic rocks were formed by re-melting of the continental crust. These new data are compared with the Paleozoic and Mesozoic granitic rocks of South China. We argue that northeastern Vietnam belongs to the South China block. Though still speculated, an ophiolitic suture between NE Vietnam and South China, so-called Babu ophiolite, appears unlikely. The Late Paleozoic to Mesozoic magmatism in the research area provides new insights for the magmatic evolution of the South China block.     

The unique Katugin rare-metal deposit (southern Siberia): Constraints on age and genesis

We report new geological, mineralogical, geochemical and geochronological data about the Katugin Ta-Nb-Y-Zr (REE) deposit, which is located in the Kalar Ridge of Eastern Siberia (the southern part of the Siberian Craton). All these data support a magmatic origin of the Katugin rare-metal deposit rather than the previously proposed metasomatic fault-related origin. Our research has proved the genetic relation between ores of the Katugin deposit and granites of the Katugin complex. We have studied granites of the eastern segment of the Eastern Katugin massif, including arfvedsonite, aegirine-arfvedsonite and aegirine granites. These granites belong to the peralkaline type. They are characterized by high alkali content (up to 11.8 wt% Na₂O + K₂O), extremely high iron content (FeO¹/(FeO¹ + MgO) = 0.96–1.00), very high content of most incompatible elements – Rb, Y, Zr, Hf, Ta, Nb, Th, U, REEs (except for Eu) and F, and low concentrations of CaO, MgO, P₂O₅, Ba, and Sr. They demonstrate negative and CHUR-close εNd(t) values of 0.0…−1.9. We suggest that basaltic magmas of OIB type (possibly with some the crustal contamination) represent a dominant part of the granitic source. Moreover, the fluorine-enriched fluid phases could provide an additional source of the fluorine. We conclude that most of the mineralization of the Katugin ore deposit occurred during the magmatic stage of the alkaline granitic source melt. The results of detailed mineralogical studies suggest three major types of ores in the Katugin deposit: Zr mineralization, Ta-Nb-REE mineralization and aluminum fluoride mineralization. Most of the ore minerals crystallized from the silicate melt during the magmatic stage. The accessory cryolites in granites crystallized from the magmatic silicate melt enriched in fluorine. However, cryolites in large veins and lens-like bodies crystallized in the latest stage from the fluorine enriched melt. The zircons from the ores in the aegirine-arfvedsonite granite have been dated at 2055 ± 7 Ma. This age is close to the previously published 2066 ± 6 Ma zircon age of the aegirine-arfvedsonite granites, suggesting that the formation of the Katugin rare-metal deposit is genetically related to the formation of peralkaline granites. We conclude that Katugin rare-metal granites are anorogenic. They can be related to a Paleoproterozoic (∼2.05 Ga) mantle plume. As there is no evidence of the 2.05 Ga mantle plume in other areas of southern Siberia, we suggest that the Katugin mineralization occurred on the distant allochtonous terrane, which has been accreted to Siberian Craton later.     

Intrusive rocks and tectono-metamorphic evolution of the Mako Paleoproterozoic belt (Eastern Senegal,West Africa)

The Kedougou Kenieba Inlier (KKI) (Paleoproterozoic of Eastern Senegal) is a portion of the West African Craton (WAC) containing a granite-greenstone terrain that experienced three distinct periods of magmatic activity, peaking at 2200, 2160–2130 and 2100–2070 Ma. In the Inlier, Paleoproterozoic granitoids and large-scale transcurrent shear zones are spatially associated, suggesting a genetic link between magma bodies and shear zones. Granitic intrusions are associated with all the volcanic episodes and phases of deformation, and have been used to constrain the age of many of these events. Our structural data and deformation sequence indicate that the Mako Greenstone Belt and the adjacent granitoid complexes have undergone a multi-phase evolutionary history that is spread over a prolonged period. The available geochronological data and field studies allowed classification of the granitoids of the KKI into four generations GI, GII, GIII and GIV.The current data suggest that the oldest rocks in the KKI, the Badon granites (2198 ± 2 Ma) and the tonalitic gneisses from Tonkouto (2200–2198 Ma) (GI), could be correlated with an early Birimian magmatic event. The gneisses, crystallized at depth, record the earliest deformation and in contrast to other tonalites, do not appear to have intruded volcanic rocks. The second manifestation of magmatism was intrusion of mafic diorite – the Gabbro Sandikounda Layered Igneous Complex type (GII) and development of the Laminia Kaourou Plutonic Complex (LKPC) (2160–2130 Ma). These bodies pre-date or are sometimes synchronous with a major deformational episode, and may, therefore, have formed very early in convergent Birimian orogenesis.The third major peak of magmatic activity occurred after the above major episode with the development of the oval shaped Diombalou and Bouroumbourou plutons (GIII). The orientation of these plutons parallel to the regional strike of the schistosity indicates structural control on granite emplacement. Eburnean magmatism was terminated in the Mako Belt following compressional Eburnean deformation, with the emplacement of the Tinkoto, Mamakono plutons (GIV) in the east of the complex and continued in the Dialé–Daléma supergroup with the syntectonic emplacement of the Saraya batholith. Garnitiferous granites of crustal derivation were emplaced in the final period of extensional activity around 2080 Ma.Field observations suggest the early plutons of the complex granitic (Kakadian) batholith intruded during convergent deformation whereas later igneous activity accompanied regional orogen-parallel extension, followed by exhumation. In the Mako Belt, thickening of the crust was proposed to have caused heating and the ‘apparent diapiric rise’ of the Diombalou and Bouroumbourou plutons.