The Bocchigliero Palaeozoic sequence in the context of the Calabrian–Peloritan Hercynian Range (Italy)

The Calabrian–Peloritan Hercynian Range includes three weakly metamorphosed Palaeozoic sequences cropping out in north-eastern Sila (Bocchigliero sequence), southern Sila, Serre and Aspromonte (Stilo sequence), and in the Peloritan Mountains (Peloritan sequence). The work reported here considers the Bocchigliero sequence and comprises part of a geological, petrological and geochemical research programme on the Palaeozoic evolution of the Calabrian–Peloritan Arc. The Bocchigliero sequence constitutes the lower tectonic unit of the Hercynian Caiabrian–Peloritan Range and is overthrusted by the metamorphic Mandatoriccio Unit. The Bocchigliero sequence is a terrigenous–carbonate–volcanic association, is affected byclow grade metamorphism, contains Cambro-Ordovician fossils and extends in age from the Cambrian to the Devonian. The terrigenous material is represented by meta-arenites and metapelites (Cambrian–Devonian); the volcanics include metatuffites (Cambrian and Ordovician), metabasalts (Cambro-Ordovician), metaandesites and metarhyolites (Ordovician and Siluro-Devonian); limestone beds are present in the Devonian. It is believed that the Palaeozoic Bocchigliero basin formed in the Cambrian on a continental crust in which the rocks constituting today's Mandatoriccio Unit were located at 3–8 km depth. The crustal thinning in the Cambro-Ordovician led to fracturing and upwelling of alkaline within-plate basaltic magmas, whereas in the Ordovician the thinning took place under conditions of higher plasticity. In this latter period an increase in temperature resulting from mantle upwelling produced crustal partial melts of andesite and rhyolite composition. In addition, this thermal uprise was responsible for regional metamorphism characterized by low pressures and by the absence of penetrative deformation. The effects of this metamorphism are well developed in the rocks of the Mandatoriccio Unit. In the Silurian and Devonian, progressive closing of the basin took place. The Palaeozoic sequence was then subjected to Variscan low pressure–low temperature metamorphism and Alpine deformation.     

Abiogenic Fischer–Tropsch synthesis of hydrocarbons in alkaline igneous rocks; fluid inclusion, textural and isotopic evidence from the Lovozero complex, N.W. Russia

A detailed fluid inclusion study has been carried out on the hydrocarbon-bearing fluids found in the peralkaline complex, Lovozero. Petrographic, microthermometric, laser Raman and bulk gas data are presented and discussed in context with previously published data from Lovozero and similar hydrocarbon-bearing alkaline complexes in order to further understand the processes which have generated these hydrocarbons. CH₄-dominated inclusions have been identified in all Lovozero samples. They occur predominantly as secondary inclusions trapped along cleavage planes and healed fractures together with rare H₂O-dominant inclusions. They are consistently observed in close association with either arfvedsonite crystals, partially replaced by aegirine, aegirine crystals or areas of zeolitization. The majority of inclusions consist of a low-density fluid with CH₄ homogenisation temperatures between −25 and −120 °C. Those in near-surface hand specimens contain CH₄+H₂ (up to 40 mol%)±higher hydrocarbons. However, inclusions in borehole samples contain CH₄+higher hydrocarbons±H₂ indicating that, at depth, higher hydrocarbons are more likely to form. Estimated entrapment temperatures and pressures for these inclusions are 350 °C and 0.2–0.7 kbar. A population of high-density, liquid, CH₄-dominant inclusions have also been recorded, mainly in the borehole samples, homogenising between −78 and −99 °C. These consist of pure CH₄, trapped between 1.2 and 2.1 kbar and may represent an early CH₄-bearing fluid overprinted by the low-density population. The microthermometric and laser Raman data are in agreement with bulk gas data, which have recorded significant concentrations of H₂ and higher hydrocarbons up to C₆H₁₂ in these samples. These data, combined with published isotopic data for the gases CH₄, C₂H₆, H₂, He and Ar indicate that these hydrocarbons have an abiogenic, crustal origin and were generated during postmagmatic, low temperature, alteration reactions of the mineral assemblage. This would suggest that these data favour a model for formation of hydrocarbons through Fischer–Tropsch type reactions involving an early CO₂-rich fluid and H₂ derived from alteration reactions. This is in contrast to the late-magmatic model suggested for the formation of hydrocarbons in the similar peralkaline intrusion, Ilímaussaq, at temperatures between 400 and 500 °C.     

Reactions and textures in grossular–wollastonite–scapolite calc–silicate granulites from Maligawila, Sri Lanka: evidence for high-temperature isobaric cooling in the meta-sediments of the Highland Complex

Grossular–wollastonite–scapolite calc–silicate granulites from Maligawila in the Buttala klippe, which form part of the overthrusted rocks of the Highland Complex of Sri Lanka, preserve a number of spectacular coronas and replacement textures that could be effectively used to infer their P–T–fluid history. These textures include coronas of garnet, garnet–quartz, and garnet–quartz–calcite at the grain boundaries of wollastonite, scapolite, and calcite as well as calcite–plagioclase and calcite–quartz symplectites or finer grains after scapolite and wollastonite respectively. Other textures include a double rind of coronal scapolite and coronal garnet between matrix garnet and calcite. The reactions that produced these coronas and replacement textures, except those involving clinopyroxene, are modelled in the CaO–Al₂O₃–SiO₂–CO₂ system using the reduced activities. Calculated examples of T–X_CO2 and P–X_CO2 projections indicate that the peak metamorphic temperature of about 900–875 °C at a pressure of 9 kbar and the peak metamorphic fluid composition is constrained to be low in X_CO2 (0.1<X_CO2<0.30). Interpretation of the textural features on the basis of the partial grids revealed that the calc–silicate granulites underwent high-temperature isobaric cooling, from about 900–875 °C to a temperature below 675 °C, following the peak metamorphism. The late-stage cooling was accompanied by an influx of hydrous fluids. The calc–silicate granulites provide evidence for high-temperature isobaric cooling in the meta-sediments of the Highland Complex, earlier considered by some workers to be confined exclusively to the meta-igneous rocks. The coronal scapolite may have formed under open-system metasomatism.     

Late Tertiary–Quaternary tectonics of the Southern Apennines (Italy): New evidences from the Tyrrhenian slope

This paper summarises the results of combined structural and geomorphological investigations we carried out in two key areas, in order to obtain new data on the structure and evolution of the Tyrrhenian slope of the southern Apennines. Analysis by a stress inversion method [Angelier, J., 1994. Fault slip analysis and paleostress reconstruction. In: Continental Deformation. P.L. Hancock Ed., Pergamon Press, Oxford, 53–100] of fault slip data from Mesozoic to Quaternary formations allowed the reconstruction of states of stress at different time intervals. By integrating these data with those deriving from the stratigraphic and morphotectonic records, chronology and timing of the sequence of the deformation events was obtained.The tectonic history of the region can be related to four deformation events. Structures related to the first event, that was dominated by a strike-slip regime with a NW–SE oriented σ1 and was active since Mid–Late Miocene, do not significantly affect the present day landscape, as they were strongly displaced and overprinted by subsequent deformation events and/or deleted by erosion. The second and third events, that may be considered as the main responsible for the morphostructural signature of the region, are comparable with the stretching phases recognised offshore and considered to be responsible for the opening and widening of the Tyrrhenian basin. In particular, the second event (with an E–W oriented σ3), took place in the Late Miocene/earliest Pliocene and was first dominated by a strike-slip regime, that was also responsible for thrusting and folding. Since Late Pliocene, it was dominated by an extensional regime that created large vertical offsets along N–S to NW–SE trending faults. The third event, that was dominated by extension with a NW–SE oriented σ3, started in the Early Pleistocene and was responsible for formation of the horst-and-graben structure with NE–SW trend that characterises the Tyrrhenian margin of the southern Apennines. The fourth deformation event, which is characterised by an extensional regime with a NE–SW trending σ3, started in the late Middle Pleistocene and is currently active.     

Active faulting and seismicity along the Siculo–Calabrian Rift Zone (Southern Italy)

Southern Italy is dominated by extensional tectonics that in the Calabrian arc and Eastern Sicily produced the development of the Siculo–Calabrian Rift Zone (SCRZ). This zone is represented by a ≈ 370 km-long fault belt consisting of 10 to 50 km long distinct fault segments which extend both offshore and on land being also responsible of the crustal seismicity of this region. The geological and morphological observations indicate that the active normal faults of the SCRZ are characterized by throw-rates ranging from 0.7 to 3.1 mm/a. They accommodate an almost uniform horizontal extension-rate of about 3.0 mm/a along a WNW–ESE regional extension direction. Based on our field observations and following empirical relationships between magnitude and surface rupture length connections between large crustal earthquakes and distinct fault segments of the SCRZ have been also tentatively tested. Our data indicate moreover that the magnitudes (M) of the historical and instrumental earthquakes are consistent with the estimated values and that the geometry and kinematics of the fault segments and the related different crustal features of the SCRZ control the different seismic behaviours of adjacent portions of the active rift zone.     

The role of rainfall in the landslide hazard: the case of the Avigliano urban area (Southern Apennines, Italy)

Mass movements varying in type and size, some of which are periodically reactivated, affect the urban area of Avigliano. The disturbed and remoulded masses consist of sandy–silty or silty–clayey plastic material interbedded with stone fragments and conglomerate blocks. Five landslides that were markedly liable to rainfall-associated instability phenomena were selected.

The relationships between landslides and rainfall were investigated using a hydrological and statistical model based on long-term series of daily rainfall data. The model was used to determine the return period of cumulative daily rainfall over 1–180 days. The resulting hydrological and statistical findings are discussed with the aim of identifying the rainfall duration most critical to landslides.

The concept of a precipitation threshold was generalized by defining some probability classes of cumulative rainfall. These classes indicate the thresholds beyond which reactivation is likely to occur. The probability classes are defined according to the return period of the cumulative rainfall concomitant with landslide reactivation.     

The radiolarian assemblages of the Bonarelli Horizon in the Umbria-Marche Apennines and Southern Alps, Italy

The Bonarelli Horizon is an important regional marker level in the Umbria-Marche Apennines. It is characterized by consisting of black bituminous shales that yield a distinctive radiolarian fauna. Black shales referable to the Bonarelli Horizon are also present in the Southern Alps. The horizon is of uniform lithology and contains radiolarian assemblages of late Cenomanian-early Turonian age throughout both the Umbria-Marche Apennines and Southern Alps. Several new radiolarian taxa have been recognised and described from the Bonarelli Horizon of both areas. Two new species are defined in this paper, namelySethocapsa bossoensisandXitus picenus.     

Pervasive assimilation of carbonate and silicate rocks in the Hortavær igneous complex, north-central Norway

The intrusive complex at Hortavær represents a magma transfer zone in which multiple pulses of gabbroic and dioritic magmas evolved along Fe- and alkali-enrichment trends. Extreme alkali enrichment resulted in nepheline-normative and sparse nepheline-bearing monzodioritic and monzonitic rocks. More evolved monzonitic and syenitic rocks are silica saturated and, in some cases, quartz bearing. Previous and current research recognized an abundance of clinopyroxene and other Ca-rich phases, such as scapolite, grossular-rich garnet, and igneous-textured calcite among the mafic and intermediate rocks. Even the most pyroxene-rich samples contain low Sc concentrations, which suggests early, intense fractionation of clinopyroxene. These features and the alkali enrichment are consistent with assimilation of carbonate-rich host rocks. Carbon isotope ratios of the igneous-textured calcite indicate an origin of the carbon from host rocks rich in calcite, consistent with assimilation. However, low _Nd values (−3.4 to −10.2) and moderate initial ⁸⁷Sr/⁸⁶Sr values (0.7052 to 0.7099) indicate the need for assimilation of quartzofeldspathic rocks as well. Models of combined assimilation and fractional crystallization indicate that assimilation of simple end members, either carbonate or silicate, cannot explain the entire data set. Instead, variable proportions of carbonate and silicate materials were assimilated, with the most pronounced assimilation effects in the mafic rocks. The reasons for variable degrees of assimilation are, as yet, uncertain. It is possible that assimilation of calc-silicate rocks with variable carbonate/silicate proportions resulted in the range of observed compositions. However, the importance of carbonate assimilation in mafic rocks compared to felsic ones suggests that assimilation of carbonates was predominant at high temperature and/or mafic magma compositions and assimilation of silicates was predominant at lower temperature and/or felsic magma compositions. We suggest that the ability of the mafic magma to dissolve higher proportions of carbonate contaminants is the result of the magma's ability to form clinopyroxene as a product of assimilation. In any case, extensive carbonate assimilation was possible because CO₂ escaped from the system.     

Cenomanian–Turonian facies succession in the Guerrero–Morelos Basin, Southern Mexico

The Cenomanian–Turonian succession of southern Mexico is characterized by an abrupt change from shallow marine to pelagic facies. The drowning of the platform coincides with the widely documented Cenomanian–Turonian Oceanic Anoxic Event (CTOAE). A proper understanding of the drowning event and the effects of the OAE requires, as an essential first step, the construction of a detailed stratigraphic framework. This has been achieved and utilizes sedimentological data as well as a combination of benthic and planktonic biostratigraphic schemes.

Deposition of the Cenomanian–Turonian sedimentary rocks of the Guerrero–Morelos basin was controlled by tectonic and oceanographic factors resulting in depositional environments ranging from a semi-restricted shelf, ramp, pelagic and prodelta deposits. Facies analysis indicates that shallow marine limestones of the Morelos Formation (lower-upper Cenomanian) were deposited in intertidal–shallow supratidal and subtidal environments in a semi-restricted shelf. Peloidal-bioclastic packstone–wackestones with minor grainstones are the predominant texture of these rocks. Abundant large benthic foraminifers, calcareous algae (dasycladacean) and mollusks (gastropods and rudists) characterize the fossil assemblage.

The Cuautla Formation (uppermost Cenomanian–Turonian) represents sedimentation on a low-energy, wave-dominated, carbonate ramp. The inner ramp accumulated bioclastic banks and shoals composed of peloidal-benthic foraminifer-grainstone, calcareous red and green algae, rudists and minor solitary corals. The middle ramp is represented by nodular packstones with a diverse assemblage of echinoderms, green and red algae, bryozoan, rudists, solitary corals, roveacrinids, calcisphaerulids, and non-keeled planktonic foraminifers. The outer ramp is dominated by argillaceous wackestone–packstone characterized by calcisphaerulids, roveacrinids, and non-keeled planktonic foraminifers. An increase in terrigenous-clastic material towards the eastern part of the area indicates progradation of a deltaic system while the Mexcala Formation (uppermost Cenomanian–Turonian) was deposited in a pelagic setting.

The drowning of the platform is at the contact between the Morelos and Cuautla or Mexcala formations and is dated as latest Cenomanian. The drowning is a hiatus in most sections and it began before the end of the Cenomanian by a minimum of 150 ky if the top of the Morelos is not eroded.     

Experimental study of liquid immiscibility in the fluid-magmatic silicate systems containing Ti,Nb, Sr,REE, and Zr

Aluminosilicate alkaline systems containing Ti, REE (La, Ce), Y, Sr, and Nb were studied experimentally at T = 1200 and 1250°C and P = 2 kbar in the presence of aqueous and alkaline fluid. In the fluid-absent experiments with systems containing the same elements, loparite crystals in a silicate matrix were obtained. These systems in the presence of aqueous and alkaline fluid pressure conditions demonstrate an immiscible splitting into two liquids: (1) aluminosilicate matrix and (2) droplets enriched in Ti, REE (La, Ce), Y, Sr, and Nb, which contain silicate admixture and are compositionally close to loparites. According to approximate estimates, the partition coefficients between the melts of the droplets and aluminosilicate matrix (K = C _dr/C _sil) are more than 5 for TiO₂, < 0.35 for SiO₂, 10–20 for Nb₂O₅, > 15 for REE, and from 2.3 to 7.6 for SrO. Obtained unmixing may be of great significance for explaining the genesis of REE-Nb (loparite) deposits. In addition, the experiments demonstrate that Zr may be accumulated together with Ti and REE due to liquid immiscibility of this type. The partition coefficient of ZrO₂ between the melts of droplets and aluminosilicate matrix (K = C _dr/C _sil) according to approximate estimates varies from ∼ 3.5 to 9.     

Crustal contamination of mafic magmas: evidence from a petrological, geochemical and Sr–Nd–Os–O isotopic study of the Proterozoic Isortoq dike swarm, South Greenland

The mid-Proterozoic Isortoq dike swarm in the Gardar Province, South Greenland, comprises a variety of alkaline rocks ranging from gabbroic to syenitic in composition. Major magmatic mineral phases are olivine, clinopyroxene, Fe–Ti oxides, amphibole, plagioclase and alkali feldspar. Quartz occurs in some samples as a late magmatic phase. Liquidus temperatures of olivine-bearing samples range between 1120 and 1145 °C and solidus temperatures are 850–930 °C. Calculated silica activities are highly variable between 0.53 and unity. Oxygen fugacities vary from −3 to +1 log units relative to the fayalite–magnetite–quartz buffer.

The rocks have MgO contents <6 wt.% with Mg# between 53 and 17. Primitive mantle-normalized trace element patterns show a relative enrichment of LIL elements with Ba peaks and Nb troughs. Clinopyroxenes show a general enrichment in REE relative to chondritic values with variable slightly positive to prominent negative Eu anomalies. Two of the dikes were dated with Sm–Nd three-point isochrons at 1190±44 and 1187±87 Ma, respectively. Initial ⁸⁷Sr/⁸⁶Sr ratios of mafic mineral separates range from 0.70289 to 0.70432 and initial _Nd values vary from +0.3 to −10.7. Whole-rock initial ¹⁸⁷Os/¹⁸⁸Os ratios are highly variable including very radiogenic values of up to 7.967. δ¹⁸O_v-smow values of separated clinopyroxene and amphibole range from +5.2‰ to +6.2‰ and fall within the range of typical mantle-derived rocks, although mixing with a lower crustal component is permitted by the data. Using energy-constrained assimilation-fractional crystallization (EC-AFC) modeling equations, the Sr–Nd isotope data of the more radiogenic samples can successfully be modeled by addition of up to 10% lower crustal granulite-facies Archean gneisses as contaminants. The Os isotopic data also suggest the involvement of old radiogenic crust. In accordance with seismic data, we conclude that a wedge of Archean crust extends from West Greenland further to the south below the present erosion level.     

Velocity and runout simulation of destructive debris flows and debris avalanches in pyroclastic deposits,Campania region,Italy

The Campanian Apennines are characterized by the presence of monocline ridges, mainly formed by limestone. During the periods of volcanic activity of the Somma-Vesuvius and Phlegrean Fields, the ridges were mantled with pyroclastic materials in varying thickness. The pyroclastics have been involved in destructive landslides both in historical time and in the recent past (1997, 1998, 1999). The landslides occur following intense and prolonged rainfalls. In some cases, landslides extended up to 4 km into the surrounding lowlands and reached towns, causing severe destruction and over 200 deaths. Generally, the landslides begin as small debris slides that develop into large, shallow debris avalanches or debris flows involving pyroclastic horizons and colluvial soils (0.5–2 m thick) on steep and vegetated slopes, often at the heads of gullies. During motion, the landslide materials eroded vegetation and soils from the slope, so that the moving material volume tended to increase. Then, proceeding towards and beyond the base of the slopes, the phenomena evolved into hyperconcentrated streamflow due to dilution by incorporating water. The results of motion analyses are described. An empirical rheological relationship was used including two principal terms that depend on the total normal stress and on the flow velocity. On this basis, the model has simulated the velocity and duration of debris avalanches and the distribution of the deposits. The selected areas were those of Sarno/Quindici and Cervinara, where a large amount of data is available both on the material properties and geomorphological setting. It was found that the majority of the cases at the two sites can be simulated successfully with only one specific pair of rheologic parameters. This provides the possibility for first-order predictions to be made of the motion of future landslides. Such predictions will be a valuable tool for outlining potential hazard areas and designing remedial measures.     

Decoupling of paired elements,crossover REE patterns,and mirrored spider diagrams: Fingerprinting liquid immiscibility in the Tapira alkaline–carbonatite complex,SE Brazil

Tapira is an alkaline silicate–carbonatite complex belonging to the kamafugite-carbonatite association in the Late-Cretaceous Alto Paranaíba Igneous Province (APIP). It is dominated by coarse-grained plutonic rocks (bebedourite – a phlogopite-, apatite-, and perovskite-rich clinopyroxenite – with subordinated dunites, wehrlites, carbonatites and phoscorites). The plutonic rocks are crosscut by fine-grained ultramafic alkaline rocks (phlogopite picrites, bebedouritic dikes) and fine-grained carbonatites. Both types of dike-rocks show petrographic evidence of the coexistence of immiscible silicate and carbonatite liquids, such as carbonate ocelli present in the silicate rocks and, more rarely, silicate ocelli within carbonatites. A detailed geochemical study of the rock types in the complex, with emphasis on the fine-grained varieties, showed that whilst some rocks may be related to each other through crystal fractionation (e.g. phlogopite picrites and bebedouritic dikes), others display anomalous trace-element behaviour that cannot be readily explained by the fractionation of a particular phase or combination of phases. We interpret such anomalous geochemical signatures as produced by silicate–carbonate liquid immiscibility, on the basis of available experimental data on partition coefficients between coexisting immiscible liquids. The immiscibility signatures comprise: (a) decoupling of geochemical pairs, such as Nb–Ta and Zr–Hf; (b) rotation of REE patterns, which cross over the patterns of the primitive liquids; and (c) matching and opposite enrichment-depletion trace elements relationships in spider diagrams of conjugate immiscible liquids. We suggest that, once established, such geochemical signatures are very difficult to erase during the subsequent petrogenetic evolution processes, which may result in superimposed conflicting signatures.     

Ordovician igneous and metamorphic units in southeastern Puna: New U–Pb and Sm–Nd data and implications for the evolution of northwestern Argentina

New field, petrological, geochemical, and geochronological data (U–Pb and Sm–Nd) for Ordovician rock units in the southeastern Puna, NW Argentina, indicate two lithostratigraphic units at the eastern–northeastern border of salar Centenario: (1) a bimodal volcanosedimentary sequence affected by low- to medium-grade metamorphism, comprising metasediments associated with basic and felsic metavolcanic rocks, dated 485 ± 5 Ma, and (2) a plutonic unit composed of syenogranites to quartz-rich leucogranites with U–Pb zircon ages between 462 ± 7 and 475 ± 5 Ma. Felsic metavolcanic and plutonic rocks are peraluminous and show similar geochemical differentiation trends. They also have similar Sm–Nd isotopic compositions (T_DM model ages of 1.54–1.78 Ga; ε_Nd(T) values ranging from −3.2 to −7.5) that suggest a common origin and derivation of the original magmas from older (Meso-Paleoproterozoic?) continental crust. Mafic rocks show ε_Nd(T) ranging from +2.3 to +2.5, indicating a depleted mantle source. The data presented here, combined with those in the literature, suggest Ordovician magmatism mainly recycles preexisting crust with minor additions of juvenile mantle-derived material.     

Compositions and Pressure–Temperature Conditions of Metamorphic Fluids Overprinting the Talate VMS Pb–Zn Deposit, Southern Altay, China

The Talate Pb-Zn deposit,located in the east of the NW-SE extending Devonian Kelan volcanic-sedimentary basin of the southern Altaides,occurs in the metamorphic rock series of the upper second lithological section of the lower Devonian lower Kangbutiebao Formation(D_1k_1~2).The Pb-Zn orebodies are stratiform and overprinted by late sulfide—quartz veins.Two distinct mineralization periods were identified:a submarine volcanic sedimentary exhalation period and a metamorphic hydrothermal mineralization period.The metamorphic overprinting period can be further divided into two stages:an early stage characterized by bedding-parallel lentoid quartz veins developed in the chlorite schist and leptite of the ore-bearing horizon,and a late stage represented by pyritechalcopyrite-quartz veins crosscutting chlorite schist and leptite or the massive Pb-Zn ores.Fluid inclusions in the early metamorphic quartz veins are mainly CO_2-H_2O-NaCI and carbonic(CO_2±CH_4±N_2) inclusions with minor aqueous inclusions.The CO_2-H_2O-NaCl inclusions have homogenization temperatures of 294-368℃,T_(m,CO2) of-62.6 to-60.5℃,T_(h,CO2) of 7.7 to 29.6℃(homogenized into liquid),and salinities of 5.5-7.4 wt%NaCl eqv.The carbonic inclusions have T_(m,CO2)of-60.1 to-58.5℃,and T_(h,Co2) of-4.2 to 20.6℃.Fluid inclusions in late sulfide quartz veins are also dominated by CO_2-H_2O-NaCl and CO_2±CH_4 inclusions.The CO_2-H_2O-NaCl inclusions have T_(b,tot) of142 to 360℃,T_(m,CO2)of-66.0 to-56.6℃,T_(h,CO2) of-6.0 to 29.4℃(homogenized into liquid) and salinities of 2.4-16.5 wt%NaCl eqv.The carbonic inclusions have T_(m,Co2)of-61.5 to-57.3℃,and T_(h,CO2) of-27.0to 28.7℃.The aqueous inclusions(L-V) have T_(m,ice) of-9.8 to-1.3℃ and T_(h,tot) of 205 to 412℃.The P-T trapping conditions of CO_2-rich fluid inclusions(100-370 MPa,250-368℃) are comparable with the late- to post-regional metamorphism conditions.The CO_2-rich fluids,possibly derived from regional metamorphism,were involved in the reworking and metal enrichment of the primary ores.Based on these results,the Talate Pb-Zn deposit is classified as a VMS deposit modified by metamorphic fluids.The massive Pb-Zn ores with banded and breccia structures were developed in the early period of submarine volcanic sedimentary exhalation associated with an extensional subduction-related back-arc basin,and the quartz veins bearing polymetallic sulfides were formed in the late period of metamorphic hydrothermal superimposition related to the Permian-Triassic continental collision.     

Seismotectonics of strike–slip earthquakes within the deep crust of southern Italy: Geometry, kinematics, stress field and crustal rheology of the Potenza 1990–1991 seismic sequences (Mmax 5.7)

We present a revision and a seismotectonic interpretation of deep crust strike–slip earthquake sequences that occurred in 1990–1991 in the Southern Apennines (Potenza area). The revision is motivated by: i) the striking similarity to a seismic sequence that occurred in 2002  140 km NNW, in an analogous tectonic context (Molise area), suggesting a common seismotectonic environment of regional importance; ii) the close proximity of such deep strike–slip seismicity with shallow extensional seismicity (Apennine area); and iii) the lack of knowledge about the mechanical properties of the crust that might justify the observed crustal seismicity. A comparison between the revised 1990–1991 earthquakes and the 2002 earthquakes, as well as the integration of seismological data with a rheological analysis offer new constraints on the regional seismotectonic context of crustal seismicity in the Southern Apennines. The seismological revision consists of a relocation of the aftershock sequences based on newly constrained velocity models. New focal mechanisms of the aftershocks are computed and the active state of stress is constrained via the use of a stress inversion technique. The relationships among the observed seismicity, the crustal structure of the Southern Apennines, and the rheological layering are analysed along a crustal section crossing southern Italy, by computing geotherms and two-mechanism (brittle frictional vs. ductile plastic strength) rheological profiles. The 1990–1991 seismicity is concentrated in a well-defined depth range (mostly between 15 and 23 km depths). This depth range corresponds to the upper pat of the middle crust underlying the Apulian sedimentary cover, in the footwall of the easternmost Apennine thrust system. The 3D distribution of the aftershocks, the fault kinematics, and the stress inversion indicate the activation of a right-lateral strike–slip fault striking N100°E under a stress field characterized by a sub-horizontal N142°-trending σ1 and a sub-horizontal N232°-trending σ3, very similar to the known stress field of the Gargano seismic zone in the Apulian foreland. The apparent anomalous depths of the earthquakes (> 15 km) and the confinement within a relatively narrow depth range are explained by the crustal rheology, which consists of a strong brittle layer at mid crustal depths sandwiched between two plastic horizons. This articulated rheological stratification is typical of the central part of the Southern Apennine crust, where the Apulian crust is overthrusted by Apennine units. Both the Potenza 1990–1991 and the Molise 2002 seismic sequences can be interpreted to be due to crustal E–W fault zones within the Apulian crust inherited from previous tectonic phases and overthrusted by Apennine units during the Late Pliocene–Middle Pleistocene. The present strike–slip tectonic regime reactivated these fault zones and caused them to move with an uneven mechanical behaviour; brittle seismogenic faulting is confined to the strong brittle part of the middle crust. This strong brittle layer might also act as a stress guide able to laterally transmit the deviatoric stresses responsible for the strike–slip regime in the Apulian crust and may explain the close proximity (nearly overlapping) of the strike–slip and normal faulting regimes in the Southern Apennines. From a methodological point of view, it seems that rather simple two-mechanism rheological profiles, though affected by uncertainties, are still a useful tool for estimating the rheological properties and likely seismogenic behaviour of the crust.     

Zircon megacrysts from basalts of the Venetian Volcanic Province (NE Italy): U–Pb ages, oxygen isotopes and REE data

Mafic alkaline lavas from the Venetian Volcanic Province (NE Italy) contain orange–brown zircon megacrysts up to 15 mm long, subhedral to subrounded and showing equant morphology, with width-to-length ratios of 1:2–1:2.5. U–Pb ages of zircon (51.1 ± 1.5 to 30.5 ± 0.51 Ma) fit the stratigraphic age of the host lava (Middle Eocene and Oligocene) and their oxygen isotope composition (δ¹⁸O = 5.31–5.51‰) is similar to that of zircon formed in the upper mantle. Cathodoluminescence images and crystal chemical features, e.g. depletion of incompatible elements such as REE, Y, U and Th at constant Hf content, indicate that centre-to-edge zircon zoning is not consistent with evolution of the melt by fractional crystallization. All the above features, together with the fact that zircon and host basalts are coeval, indicate that the studied Zr megacrysts crystallised from a primitive alkaline mafic magma, which later evolved to the less alkaline host magma.