Über den Stoffhaushalt der Donau und ihrer Nebenflüsse

Zusammenfassung Nach einem kurzen überblich über frühere stoffwechseldynamische Untersuchungen im Donauraum nach dem Stand der Monographie werden neuere, teilweise noch unver?ffentlichte Ergebnisse rum?nischer, ungarischer und deutscher Arbeitsgruppen zusammenfassend referiert. Diese neueren Untersuchungen betreffen die Nitrifikationsprozesse im Bistritza-Stausee Bicaz (Rum?nien) sowie Prim?rproduktion und biogene Belüftung der Donau im Bereich von Alsog?d-Budapest (Ungarn) und im Bereich von Kelheim-Jochenstein (BR Deutschland). Dieser Bericht wird erg?nzt durch einige Befunde biochemischer Untersuchungen an anderen grossen Flüssen, und hieraus wird ein Programm für weitere gemeinsame stoffwechseldynamische Forschungen im Donauraum abgeleitet.

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Summary After a short survey on former investigations concerning the dynamic cycle of elements in river Danube, newer, partially unpublished results of Rumanian, Hungarian and German working groups are digested. These newer investigations concern the nitrification processes in the Bistritza dam of Bicaz (Rumania) and primary production as well as biogenic reaeration of river Danube in the region of Alsog?d-Budapest (Hungary) and Kelheim-Jochenstein (German Fed. Rep.). This survey is completed by some results of biochemical investigations at other great rivers and from that a programme for further cooperation concerning the biochemical questions of dynamic cycle of substances in river Danube is derived.

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Dem unvergessenen Donauforscher Prof. Dr. Endre Dudich, Budapest, gewidmet.     

Die Bedeutung der vertikalen Durchmischung für die phytoplanktische Sauerstoffproduktion in einem gestauten Fliessgewässer

Measured oxygen concentrations over the depth in an impounded river showed considerable vertical gradients. Their numerical calculation based on concepts to be found in the literature was yet not possible. For assessing the signification of the mixing over the depth for the phytoplanktic oxygen production a mathematical concept will be developped. This enables the quantification of the influence of the turbulence dependent permanent light-dark changes upon the phytoplanktic production. The results lead to the conclusion that the mixing processes may have a stimulating effect upon the algae which rises their photosynthetic production by a factor from about 2 up to 4.     

Urease-Hemmtest für wirkungsbezogene Untersuchungen der Bindungsformen von Kupfer in Wässern und Bodeneluaten

Urease Inhibition Test for Effect-related Investigations of Copper Speciation in Water and Soil Extracts In 80 different water samples, the inhibition effect of cupric ions was measured by application of a simple urease inhibition test. In relation to the total copper concentration, the inhibition permits an effect-related classification of drinking water, rain water, spring water, surface water, leakage water, wastewater, and soil extracts. Drinking water contains high parts of cupric ions in the free hydrated form. Their copper content results in high urease inhibition and is caused by using copper pipes in house plumbing. In leakage water, wastewater, and soil extracts, cupric ions are mainly complexed by organic compounds in the sample matrix. Hence, the inhibition effects are low. In soil extracts, the urease inhibition increased after an UV-decomposition procedure, but a decreasing effect was observed for a surface and a drinking water sample, respectively. The chemical oxygen demand and UV-absorbance at 255 nm measured before and after the procedure were correlated to the content of organic compounds, i.e., humic acid. In most samples, the organic matrix was not decomposed completely. The oxidizing decomposition apparently forms further complexing agents, which suppress the inhibition effect of cupric ions. In the rain water samples investigated, the content of organic compounds depended on rain intensity. The chemical oxygen demand and UV-absorbance, respectively, were low for rain water collected during strong rain periods and increased with decreasing rain intensity. The rain water trickled over sheet-lead roof showed an increase of urease inhibition compared with the simultaneously collected rain. Consequently, a decomposition of organic matrix could be demonstrated in rain water by use of the urease inhibition test.