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1.
The mineralogical and geochemical characteristics of Fe-oxyhydroxide samples from one dredge station (long. 103°54.48′W, lat. 12°42.30′N, water depth 2655 m) on the East Pacific Rise near lat 13°N were analyzed by XRD, ICP-AES, and ICP-MS. Most Fe-oxyhydroxides are amorphous, with a few sphalerite microlites. In comparison with Fe-oxyhydroxides from other fields, the variable ranges in the chemical composition of Fe-oxyhydroxide samples are very narrow; their Fe, Si, and Mn contents were 39.90%, 8.92%, and 1.59%, respectively; they have high Cu (0.88%–1.85%) and Co (65×10−6−704×10−6) contents, and contain Co+Cu+Zn+Ni> 1.01%. The trace-element (As, Co, Ni, Cu, Zn, Ba, Sr) and major-element (Fe, Ca, Al, Mg) contents of these samples are in the range of hydrothermal sulfide from the East Pacific Rise near 13°N, reflecting that this type of Fe-oxyhydroxide constitutes a secondary oxidation product of hydrothermal sulfide. The Fe-oxyhydroxide samples from one dredge station on the East Pacific Rise near 13°N are lower in ΣREE (5.44×10−6–17.01×10−6), with a distinct negative Ce anomaly (0.12–0.28). The Fe-oxyhydroxide samples have similar chondrite-normalized rare-earth-element (REE) patterns to that of seawater, and they are very different from the REE composition characteristics of hydrothermal plume particles and hydrothermal fluids, showing that the REEs of Fe-oxyhydroxide are a major constituent of seawater and that the Fe-oxyhydroxides can become a sink of REE from seawater. The quick settling of hydrothermal plume particles resulted in the lower REE content and higher Mn content of these Fe-oxyhydroxides, which are captured in part of the V and P from seawater by adsorption. The Fe-oxyhydroxides from one dredge station on the East Pacific Rise near 13°N were formed by secondary oxidation in a low temperature, oxygenated environment. In comparison with the elemental (Zn, Cd, Pb, Fe, Co, Cu) average content of hydrothermal sulfide samples from the East Pacific Rise near 13°N, the Zn, Cd, and Pb contents of the Fe-oxyhydroxides are lower, and their Fe, Co, and Cu contents are higher. Supported in part by the Pilot Project of Knowledge Innovation Project, Chinese Academy of Sciences (Grant No. KZCX3-SW-223), and the Special Foundation for the Tenth Five Plan of COMRA (Grant No. DY105-01-03-1)  相似文献   

2.
Thirty-six basalt samples from near East Pacific Rise 13°N are analyzed for major and trace elements. Different types of zoned plagioclase phenocrysts in basalts are also backscatter imaged, and major element profiles scanned and analyzed for microprobe. Basalts dredged from a restricted area have evolved to different extents (MgO=9.38wt%—6.76wt%). High MgO basalts are modeled for crystalliza-tion to MgO of about 7wt%, and resulted in the Ni contents (≈28 ppm) that are generally lower than that in observed basalts (>60 ppm). It suggests that low MgO basalts may have experienced more intensive magma mixing. High MgO (9.38wt%) basalt is modeled for self-"mixing-crystallization", and the high Ni contents in low MgO basalts can be generated in small scale and periodical self-mixing of new magma (high MgO). "Mixing-crystallization" processes that low MgO magmas experienced accord with recent 226Ra/230Th disequilibria studies for magma residence time, in which low MgO magmas have experi-enced more circles of "mixing-crystallization" in relatively longer residence time. Magma mixing is not homogeneous in magma chamber, however, low MgO magmas are closer to stable composition pro-duced by periodical "mixing-crystallization", which is also an important reason for magma diversity in East Pacific Rise. Zoned plagioclase phenocrysts can be divided into two types: with and without high An# cores, both of which have multiple reversed An# zones, suggesting periodical mixing of their host magmas. Cores of zoned plagioclase in low MgO (7.45wt%) basalt differ significantly with their mantle in An#, but are similar in An# with microlite cores (products of equilibrium crystallization) in high MgO (9.38wt%) basalt, which further shows that plagioclase phenocryst cores in low MgO basalts may have formed in their parental magmas before entering into the magma chamber.  相似文献   

3.
The mineralogical,elemental,and isotopic characteristics of a hydrothermal sulfide sample from one dredge station (12°42.30'N,103°54.48'W,water depth 2655 m) on the East Pacific Rise near 13°N were analyzed.The hydrothermal sulfide was composed mainly of sphalerite,chalcopyrite,and pyrite and was a Zn-rich sulfide;in layer ep-s-1,goethite formed by secondary oxidation was found.The concentrations of rare elements,such as Li (0.15×10-6-0.30×10-6),Be (0.01×10-6-0.05×10-6),Zr (73.8×10-9-1344×10-9),Nb (8.14×10-9-64.7×10-9),Hf (2.54×10-9-28.0×10-9),and Ta (0.203×10-9-1.21×10-9),were far lower in the hydrothermal sulfide than in the ocean crust,whereas the content of Au was higher and the contents of Co,Ni,Sr,Cs,Ba,Bi,and U were low.The correlations between Zn and Cr,Cd and Ga,Cu and P,P and In (R2 0.8) were positive,whereas those between Zn and Fe,Cu,and Ba (R2 0.8) were distinctly negative.From low-temperature mineral assemblages to high-temperature mineral assemblages,the spatial distributions of dispersive and rare elements (e.g.In,Li,Cs) in the hydrothermal sulfide displayed corresponding variations.The variations observed in some elements (e.g.,Cd,Cs,P) are controlled by Zn,Fe,and Cu sulfides,respectively.Seafloor weathering accounts for the enrichment of V,Mn,and rare earth elements (REE) in the henna sulfide-oxidation layer that bears the secondary oxide mineral,leading to identical REE patterns for this layer (ep-s-1) and seawater.Seafloor weathering also distinctly affects the correlations between the element ratios of the hydrothermal sulfide.From high-temperature mineral assemblages to low-temperature mineral assemblages,Fe content and δ 34S value of the hydrothermal sulfide increase gradually,and Zn content and lead isotopic ratios decrease gradually on the contrary,which indicate the influences of seawater on elements and the sulfur and lead isotopic compositions enhance gradually during the formation of hydrothermal sulfides.  相似文献   

4.
The interactions of seafloor hydrothermal fluid with igneous rocks can result in leaching elements from the rocks,creating potential ore-forming fluids and influencing the chemical compositions of near-bottom seawater.The hydrothermal alteration of plagioclase microphenocrysts and basaltic glass in the pillow basalts from one dredge station(103°57.62′′W,12°50.55′N,water depth 2480 m)on the East Pacific Rise(EPR)near 13°N were analyzed using a scanning electron microscope(SEM)and energy dispersive X-ray spectrometry(EDS).The results show that the edges of the plagioclase microphenocrysts and the basaltic glass fragments are altered but the pyroxene and olivine microphenocrysts in the interior of the pillow basalts appear to be unaffected by the hydrothermal fluids.In addition,our results show that the chemical alteration at the rims of the plagioclase microphenocrysts and the edges of basaltic glass fragments can be divided into separate types of alteration.The chemical difference in hydrothermal alteration of the plagioclase microphenocrysts and the basaltic glass indicate that different degrees of hydrothermal fluid-solid phase interaction have taken place at the surface of the pillow basalts.If the degree of hydrothermal fluid-solid phase interaction is relatively minor,Si,Al,Ca and Na diffuse from the inside of the solid phase out and as a result these elements have a tendency to accumulate in the edge of the plagioclase microphenocrysts or basaltic glass.If the degree of hydrothermal fluid-solid phase interaction is relatively strong,Si,Al,Ca and Na also diffuse from the inside of solid phase out but these elements will have a relatively low concentration in the edge of the plagioclase microphenocrysts or basaltic glass.Based on the chemical variation observed in the edges of plagioclase microphenocrysts and basaltic glass,we estimate that the content of Si,Al and Fe in the edges of plagioclase microphenocrysts can have a variation of 10.69%,17.59%and 109%,respectively.Similarly,the Si,Al and Fe concentrations in the edges of basaltic glass can have a variation of 9.79%,16.30%and 37.83%,respectively,during the interaction of hydrothermal fluids and seafloor pillow basalt.  相似文献   

5.
Hydrothermal sulfide samples collected in the course of “Alvin” dives at 21°N East Pacific Rise (EPR) have been systematically studied for morphology and composition by means of SEM and electron microprobe analyses.Two categories of samples were available: pyrite-zinc sulfide associations and pyrite-copper-rich sulfide associations. Large-scale variations and small-scale scatter in the stoichiometric composition of the sulfides were caused by the varying composition of deposition and aggregation that exist in the hydrothermal chimneys. Low temperatures of formation can be inferred for the samples based on a comparison with data on the formation of synthetic sulfides.  相似文献   

6.
Under the ANDRA Meuse/Haute Marne underground research laboratory scientific programme, two boreholes (EST204 and EST205) were drilled to a depth of 510 m for the purposes of scientific characterisation. Twenty-nine core samples were taken in borehole EST205 every 3 m between 422 and 504 m depth. Physical property measurements (water content, porosity, density, specific surface), geochemical analyses (major and trace elements, cation exchange capacity [CEC] and surface cation occupancy, leaching anions, redox state, organic matter concentration), and a semi-quantitative mineralogical study were conducted on the samples.As the rocks are in a reduced state, the core samples were stored under nitrogen immediately after drilling. All the steps of the sampling and of the characterisation are done with a research of limitation of the oxidation to obtain representative samples of the in situ conditions.The top of the formation is more carbonate-rich, with interbedded clayey layers and carbonate rock. The formation is more homogeneous in its central section with a clay mineral concentration of 45–50%, which corresponds to a maximum of flooding within the area. In the upper part of this section, micas and mixed-layer illite/smectite R0 dominate, whereas in the lower part of the section we find an abrupt transition to mixed-layer illite/smectite R1 associated with kaolinite.A statistical analysis, including the data of major and trace elements with the semi-quantitative mineralogy, enabled the identification of some mineralogical traps for trace elements. The values of cation occupancy at the surface of the clay minerals provided a good image of the pore water chemistry; pore water is in equilibrium with the clay surfaces. Leaching experiments revealed the pore water salinity and provided profiles of Cl and Br concentrations. Cl/Br values in the centre of the formation are close to the present-day seawater ratio, which could indicate a seawater origin of the pore water. Some measurements of total reduced capacity, provide quantified results of the reduced state of the rock.Processing the data on water content, helium and petroleum pycnometry enabled calculation of total rock porosity and gave an uncertainty range for this value. Finally, the high BET(N2) specific surfaces are consistent with the clayey nature of the rock.  相似文献   

7.
The surface sediments from the eastern Pacific Ocean are mainly composed of biogenetic fossils, silicate detritus, ferromanganese spherolites and clay fractions. Among them, the clay fractions with grain size less than 2 μm (mainly clay minerals) are mostprevalent, especially in the non-calcareous sediments (the content of calcareous fossils is less than 5%), the clay fraction contents often exceed 70%[1―5]. Because of the influences of Antarctic Bottom Water (AABW), equatorial currents, …  相似文献   

8.
Based on structural and mineralogical characteristics of four hydrothermal chimney samples collected by submersible Alvin, growth history and formation environment of hydrothermal chimney at EPR 9-10°N are established. It is shown that there occur two types of hydrothermal chimney with different deposition environments at EPR 9-10°N according to differences in their shape, structure and mineral assemblage: type I chimney forms in an environment with high temperature, low pH and strong reducing hydrothermal focus flow and type II chimney forms in a relatively low temperature, high pH and rich Zn hydrothermal environment. Growth of type I chimney begins with the formation of anhydrite. Subsequently deposition of Cu-Fe-Zn sulphide in various directions of chimneys decides the final structure of this type of chimney. According to observation and analysis of mineral assemblages, the formation process of type I chimney could be divided into three stages from early, middle to late. Changes of temperature and major chemical reaction type in the process of hydrothermal chimney formation are also deduced. Different from type I chimney, quenching crystalline of pyrite and/or crystalline of sphalerite provide the growth foundation of type II chimney in the early stage of chimney forma-tion.  相似文献   

9.
Hydrothermal chimneys with tubular shape were formed in the process of hydrothermal fluids eruption at sea-floor. Their structure and chemical composition are closely related to properties of hydrothermal fluid. There exist great geochemical gradient, thermal gra- dient and mineral assemblage gradient across 1―3- cm-thick wall of chimneys, which includes abundant information of hydrothermal fluid properties and for-mation temperature and also records the growth pro- cess and history of chimne…  相似文献   

10.
Three thousand kilometres of multichannel (MCS) and wide-angle seismic profiles, gravity and magnetic, multibeam bathymetry and backscatter data were recorded in the offshore area of the west coast of Mexico and the Gulf of California during the spring 1996 (CORTES survey). The seismic images obtained off Puerto Vallarta, Mexico, in the Jalisco subduction zone extend from the oceanic domain up to the continental shelf, and significantly improve the knowledge of the internal crustal structure of the subduction zone between the Rivera and North American (NA) Plates. Analyzing the crustal images, we differentiate: (1) An oceanic domain with an important variation in sediment thickness ranging from 2.5 to 1 km southwards; (2) an accretionary prism comprised of highly deformed sediments, extending for a maximum width of 15 km; (3) a deformed forearc basin domain which is 25 km wide in the northern section, and is not seen towards the south where the continental slope connects directly with the accretionary prism and trench, thus suggesting a different deformational process; and (4) a continental domain consisting of a continental slope and a mid slope terrace, with a bottom simulating reflector (BSR) identified in the first second of the MCS profiles. The existence of a developed accretionary prism suggests a subduction–accretion type tectonic regime. Detailed analysis of the seismic reflection data in the oceanic domain reveals high amplitude reflections at around 6 s [two way travel time (twtt)] that clearly define the subduction plane. At 2 s (twtt) depth we identify a strong reflection which we interpret as the Moho discontinuity. We have measured a mean dip angle of 7° ± 1° at the subduction zone where the Rivera Plate begins to subduct, with the dip angle gently increasing towards the south. The oceanic crust has a mean crustal thickness of 6.0–6.5 km. We also find evidence indicating that the Rivera Plate possibly subducts at very low angles beneath the Tres Marias Islands.  相似文献   

11.
We present new analyses of volatile, major, and trace elements for a suite of glasses and melt inclusions from the 85°E segment of the ultra-slow spreading Gakkel Ridge. Samples from this segment include limu o pele and glass shards, proposed to result from CO2-driven explosive activity. The major element and volatile compositions of the melt inclusions are more variable and consistently more primitive than the glass data. CO2 contents in the melt inclusions extend to higher values (167–1596 ppm) than in the co-existing glasses (187–227 ppm), indicating that the melt inclusions were trapped at greater depths. These melt inclusions record the highest CO2 melt concentrations observed for a ridge environment. Based on a vapor saturation model, we estimate that the melt inclusions were trapped between seafloor depths (~ 4 km) and ~ 9 km below the seafloor. However, the glasses are all in equilibrium with their eruption depths, which is inconsistent with the rapid magma ascent rates expected for explosive activity. Melting conditions inferred from thermobarometry suggest relatively deep (25–40 km) and cold (1240°–1325 °C) melting conditions, consistent with a thermal structure calculated for the Gakkel Ridge. The water contents and trace element compositions of the melt inclusions and glasses are remarkably homogeneous; this is an unexpected result for ultra-slow spreading ridges, where magma mixing is generally thought to be less efficient based on the assumption that steady-state crustal magma chambers are absent in these environments. All melts can be described by a single liquid line of descent originating from a pooled melt composition that is consistent with the aggregate melt calculated from a geodynamic model for the Gakkel Ridge. These data suggest a model in which deep, low degree melts are efficiently pooled in the upper mantle (9–20 km depth), after which crystallization commences and continues during ascent and eruption. Based on our melting model and the assumption that CO2 is perfectly incompatible, we show that the highest CO2 concentrations of the melt inclusions (~ 1600 ppm) are consistent with the calculated CO2 concentrations of primary undegassed melts. The highest measured CO2/Nb ratio (443) of Gakkel Ridge melt inclusions predicts a mantle CO2 content of 134 ppm and would result in a global ridge flux of 2.0 × 1012 mol CO2/yr.  相似文献   

12.
13.
The Turpan-Hami basin (as the Tu-Ha basin here-after) and the Santanghu basin, as the late Paleozoic– Mesozoic-Cenozoic reworked and superimposed sedi-mentary basins with the similar evolution history 1, 2), are located in between the Tianshan and the Altay moun-tains in northeastern Xinjiang. As the major oil-and gas-bearing basins in Xinjiang, study of both the ba-sins through their complicated tectonic evolution his-tory is scientifically significant for exploring conti-nental geology …  相似文献   

14.
Succeeding to multiply collisions of different blocks in Late Paleozoic[1―5], complex intracontinental structural deformation occurred in the Tianshan area during Mesozoic-Cenozoic[6―16], which controlled coeval basin-range evolution and resulted in intensive modi- fication and adjustment of the Paleozoic oil-gas reser- voirs[17―19]. The Kuqa Depression is a secendary struc- tural unit of the Tarim basin, in which Mesozoic- Ce- nozoic deposits occur in thickness of 6000―7000 m. The Kuq…  相似文献   

15.
~~Underplating in the middle-lower Yangtze Valley and model of geodynamic evolution:Constraints from geophysical data1)East China petroleum Administration,1988(unpublished data). 1)Measurements of regional rock densities and magnetic parameters of Anhui Province(research report),Annul Geological and Mineral Bureau,1987(unpublished). 1)In this paper South China Block(SCB)includes the Yangtze block and Cathaysian block.In the Neoproterozoic the Yangtze block had been sutured to th…  相似文献   

16.
Summary According to the terrane model used for the interpretation of the heterogeneities in the Lower Palaeozoic development along the southwestern border of the East European platform (Baltica) several suspect terranes have been accreted to the passive platform margin during the closure of the postulated Tornquist Sea in Ordovician and Silurian times. Their final docking and partly overthrusting onto the platform are of Scandian (Early Devonian) age. A matter of dispute is the provenance of the various terranes. There are lithofacies, structural, palaeobiogeographical and palaeomagnetic constraints for relations both to Baltica and East Avalonia. Specific similarities can be observed between the Southern Jylland, Pomerania, ysogóry (including Radom-Krasik), and Rawa Russkaja terranes. After their accretion and amalgamation they may form a more or less continuous Caledonian marginal thrust belt along the platform border. On the other hand, more significant differences exist between the latter and the so far recognized Southern North Sea, Maopolska, Cracovides, Upper Silesian, Sudeten, Kochanowka, and Dobrogean terranes. The position of any Tornquist Sea suture zone(s) is still completely enigmatic.  相似文献   

17.
DSDP Leg 82 sampled the oceanic crust, at 9 sites, west of the MAR between 33°N and 38°N, i.e., from the Azores “mantle plume” to south of the Hayes Fracture Zone. A specific aim of this DSDP Leg was to determine if the origin, and spatial and temporal evolution of oceanic mantle heterogeneity in the vicinity was related in a predictable manner to the “mantle plume”. Our approach in evaluating this question has been to select samples on the basis of trace element characteristics and age, for radiogenic isotope determinations.Isotopic and trace element heterogeneity occur both within between sites. While there is a crude correlation between trace element and isotopic characteristics, it is difficult to establish a detailed set of guidelines which would describe either trace element-isotope interrelationships. This difficulty is highlighted by the occurrence of basalts in one hole (H558) with trace element characteristics ranging from enriched to depleted, which can have identical or different isotopic characteristics.The origin, and spatial and temporal distribution of the heterogeneity cannot be reconciled with any simple models. A complicated scenario, involving mantle plums or blobs, recent local heterogeneity and complex mixing models, is required.  相似文献   

18.
Global climate during the Jurassic has been commonly described as a uniform greenhouse climate for a long time.However,the climate scenario of a cool episode during the Callovian-Oxfordian transition following by a warming trend during the Oxfordian(163.53 to157.4 Ma) is documented in many localities of the western Tethys.It is still unclear if a correlatable climate scenario also occurred in the eastern Tethys during the same time interval.In this study,a detailed geochemical analysis on the 1060 m thick successions(the Xiali and Suowa formations) from the Yanshiping section of the Qiangtang Basin,located in the eastern Tethys margin during the Callovian-Oxfordian periods,was performed.To reveal the climate evolution of the basin,carbonate content and soluble salt concentrations(SO_4~(2-),Cl~-) were chosen as climatic indices.The results show that the overall climate patterns during the deposition of the Xiali and Suowa formations can be divided into three stages:relatively humid(~164.0 to 160.9 Ma),dry(~160.9 to159.6 Ma),semi-dry(~159.6 to 156.8 Ma).A similar warming climate scenario also occurred in eastern Tethys during the Callovian-Oxfordian transition(~160.9 to159.6 Ma).Besides,we clarify that the Jurassic True polar wander(TPW),the motion of the lithosphere and mantle with respect to Earth's spin axis,inducing climatic shifts were responsible for the aridification of the Qiangtang Basin during the Callovian-Oxfordian transition with a review of the paleolatitude of the Xiali formation(19.7+2.8/-2.6° N) and the Suowa formation(20.7+4.1/-3.7° N).It is because the TPW rotations shifted the East Asia blocks(the North and South China,Qiangtang,and Qaidam blocks) from the humid zone to the tropical/subtropical arid zone and triggered the remarkable aridification during the Middle-Late Jurassic(ca.165-155 Ma).  相似文献   

19.
The present study is based on a suite of surface samples from exposures of eroded laterite, considered to be Tertiary in age, and nearby soils in the Sahelian region of SW Niger and Burkina Faso. X‐ray fluorescence, X‐ray diffraction, computer‐controlled scanning electron microscopy, energy‐dispersive X‐ray spectroscopy, diffuse UV–visible reflectance spectroscopy and a suite of magnetic measurements have been used to shed light on the origin of the soils and their possible derivation from the adjacent, eroded laterite outcrops. On the basis of the wide range of data obtained, we conclude that the mineralogy and magnetic properties of the soils preclude direct derivation from the laterites without further weathering and modification. Nor does the evidence support the view that the soils have evolved entirely independently, uninfluenced by input from the laterites. The only conclusion that is consistent with all the lines of evidence is that the erosion of the laterites provided at least a significant part of the material upon which soil formation took place. This must have occurred at a time early enough to permit a long period of subsequent soil development during which the iron oxides, specifically haematite and ferrimagnetic minerals, were significantly modified. From this, we infer that eroded material from discontinuous laterite exposures has contributed significantly to the remotely sensed, distinctive reflectance characteristics of the Sahel surfaces. The magnetic properties of the soils provide evidence for the in situ neo‐formation of fine, secondary, pedogenic magnetite/maghemite grains typical of those found in many soils across the Sahel region and elsewhere in both temperate and tropical environments. Copyright © 2017 John Wiley & Sons, Ltd.  相似文献   

20.
The rock magnetic properties of the samples of dredged rocks composing the submarine volcanic edifices within the Sea-of-Okhotsk slope of the northern part of the Kuril Island Arc are studied. The measurements of the standard rock magnetic parameters, thermomagnetic analysis, petrographical studies, and microprobe investigations have been carried out. The magnetization of the studied rocks is mainly carried by the pseudo-single domain and multidomain titanomagnetite and low-Ti titanomagnetite grains. The high values of the natural remanent magnetization are due to the pseudo-single-domain structure of the titanomagnetite grains, whereas the high values of magnetic susceptibility are associated with the high concentration of ferrimagnetic grains. The highest Curie points are observed in the titanomagnetite grains of the igneous rocks composing the edifices of the Smirnov, Edelshtein, and 1.4 submarine volcanoes.  相似文献   

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