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1.
Stable carbon and oxygen isotope data from mollusc aragonite extracted from sediment cores provide new information on the origin and history of sedimentation in the southwestern area of the central basin of Lake Erie. Sediments infilling the Sandusky subbasin consist of three lithologic units overlying glacial deposits. The lowest of these is a soft gray mud overlain by a shell hash layer containing Sphaerium striatinum fragments. A fluid mud unit caps the shell hash layer and extends upwards to the sediment-water interface. New stable isotope data suggest that the soft gray mud unit is of postglacial, rather than proglacial, origin. These data also suggest that the shell hash layer was derived from erosional winnowing of the underlying soft gray mud layer. This winnowing event may have occurred as a result of the Nipissing flood.The Pelee-Lorain moraine, which forms the eastern boundary of the Sandusky subbasin, is an elevated area of till capped by a sand deposit that originated as a beach. The presence of both the shell hash layer and relict beach deposit strengthens the interpretation that the Nipissing flood was a critical event in the development of the southwestern area of the central basin of Lake Erie. This event, which returned drainage from the upper lakes to the Lake Erie basin, was a dominant influence on regional stratigraphy, bathymetry, and depositional setting.  相似文献   

2.
Isotopic records of aquatic cellulose are becoming increasingly important for palaeohydrological reconstructions, but widespread application of this climate proxy is hampered by minerogenic contamination that affects oxygen isotope measures in cellulose. Few records of isotopes in aquatic cellulose are available from palaeoclimate archives in the Southern Hemisphere. In this study, we used a new bulk cellulose extraction method and determined the oxygen (δ18O) and carbon (δ13C) isotope values in cellulose from a Holocene lake sediment core segment (7.2–1.1 cal ka BP) from Lake Pupuke, Auckland, New Zealand. Isotope values from modern, potential sources of sedimentary cellulose revealed the aquatic origin of the cellulose extracted from the core, and hence enabled inference of past lake water δ18O values from the δ18O of measured cellulose in the core. A shift to a more positive water balance in the lake was identified around 2.8 cal ka BP by a decrease in inferred lake water δ18O values. At that time, greater epilimnetic primary productivity is indicated by the higher δ13C values of sedimentary cellulose. Greater divergence between the δ13C values of cellulose and bulk organic matter suggests stronger stratification of the lake, likely caused by greater freshwater input. We discuss a possible link to a solar minimum that occurred at that time.  相似文献   

3.
Annually laminated sediments in Lake Xiaolongwan, northeast China, contain a suite of n-alkanes (C17–C33) with a strong odd over even carbon number predominance. Biomarker n-alkane proxies (average chain length, Paq ratio, grass/tree ratio, carbon preference index and compound-specific δ13C values) were used to reconstruct climate changes that occurred over the last millennium. Compound-specific δ13C values show large differences between the distinctive chain length groups of n-alkanes that originate from algae, aquatic macrophytes and terrestrial plants. Long-chain n-alkanes (C27–C33) are predominantly derived from leaf wax lipids in the forest. Variations in long-chain n-alkane δ13C values may mainly record water-use efficiency, inasmuch as the contribution from C4 plants is negligible in the Lake Xiaolongwan catchment. Short- and middle-chain n-alkanes are mainly from algae and aquatic plants. They are strongly depleted in 13C. This feature may be linked to a methane-derived, negative δ13C pool and lake overturn, which regulates dinoflagellate blooms. Parallel fluctuations are observed in δ13C27–31 values, Paq, and the grass/tree ratio throughout the record. Variations in δ13C27–31 values and Paq are in agreement with historical documents on summer and winter climate conditions. They support earlier suggestions that δ13C values in the long-chain n-alkanes and Paq may be useful indicators of effective precipitation or drought stress in this forested area. The δ13C27–31 index and Paq show distinct decadal variations. Periods with high δ13C27–31 values and a low Paq index correspond with the warm phases of the Pacific Decadal Oscillation (PDO). Values are reversed during PDO cool phases. At the decadal timescale, summer monsoon rainfall in northeast China over the last millennium may have been regulated mainly by the PDO.  相似文献   

4.
5.
Journal of Paleolimnology - We report organic carbon (OC) accumulation rates in three freshwater ecosystems in southern Brazil, along the largest shallow coastal lagoon ecosystem in the world, the...  相似文献   

6.
The apparent isotope enrichment factor εmacrophyte of submerged plants (εmacrophyte–DIC = δ13Cmacrophyte − δ13CDIC) is indicative of dissolved inorganic carbon (DIC) supply in neutral to alkaline waters and is related to variations in aquatic productivity (Papadimitriou et al. in Limnol Oceanogr 50:1084–1095, 2005). This paper aims to evaluate the usage of εmacrophyte inferred from isotopic analyses of submerged plant fossils in addition to analyses of lake carbonate as a palaeolimnological proxy for former HCO3 concentrations. Stable carbon isotopic analysis of modern Potamogeton pectinatus leaves and its host water DIC from the Tibetan Plateau and Central Yakutia (Russia) yielded values between −23.3 and +0.4‰ and between +14.0 and +6.5‰, respectively. Values of ε Potamogeton–DIC (range −15.4 to +1.1‰) from these lakes are significantly correlated with host water HCO3 concentration (range 78–2,200 mg/l) (r = −0.86; P < 0.001), thus allowing for the development of a transfer function. Palaeo-ε Potamogeton–ostracods values from Luanhaizi Lake on the NE Tibetan Plateau, as inferred from the stable carbon isotope measurement of fossil Potamogeton pectinatus seeds (range −24 to +2.8‰) and ostracods (range −7.8 to +7.5%) range between −14.8 and 1.6‰. Phases of assumed disequilibrium between δ13CDIC and δ13Costracods known to occur in charophyte swards (as indicated by the deposition of charophyte fossils) were excluded from the analysis of palaeo-ε. The application of the ε Potamogeton–DIC-HCO3 transfer function yielded a median palaeo-HCO3 -concentration of 290 mg/l. Variations in the dissolved organic carbon supply compare well with aquatic plant productivity changes and lake level variability as inferred from a multiproxy study of the same record including analyses of plant macrofossils, ostracods, carbonate and organic content.  相似文献   

7.
Stable isotope measures in organic matter are frequently used as indicators of past climate change. Although such analyses can provide valuable information, there is considerable uncertainty associated with studies of organic-rich sediments, especially those from Arctic lakes and bogs. We studied stable isotopes of carbon and nitrogen, and magnetic properties in a sediment core from a small alkaline lake with a high sedimentation rate, Lake Nattmålsvatn, Norway. There is good correspondence among the different sediment variables during the late glacial, and they seemingly reflect major climate variations such as the Allerød Interstade and the Younger Dryas, as well as the transition into the current interglacial. During the early Holocene, however, these relationships are more complex and δ13C and δ15N values do not stabilize until ~7,500 cal year BP. A significant excursion in all variables occurs between 6,850 and 6,500 cal year BP and is interpreted to represent climate deterioration. Holocene δ13C values vary little and indicate that isotopically-depleted dissolved inorganic carbon (DIC) in the lake, possibly influenced by methanotrophy and high pCO2, dominated the lake’s carbon cycle. Holocene δ15N is similarly muted, likely due to the availability of abundant dissolved nitrogen. Bulk organic matter is probably dominated by phytoplankton remains produced beneath the ice cover in late spring and during ice breakup when isotopically-depleted DIC, pCO2 and ammonium availability were maximal. Thus, use of δ13C and δ15N as indicators of Holocene paleoclimate and paleoproductivity variation can be challenging in a lake such as Nattmålsvatn, where ice cover isolates the basin for large parts of the year, allowing dissolved respiratory gases to accumulate in the water column. In contrast, magnetic variables appear to better track climate variations. In particular, runoff-driven influx of minerogenic sediments shows high variability that can be attributed to regional changes in Holocene winter precipitation. The most striking shifts occur between 4,000 and 2,300 cal year BP.  相似文献   

8.
9.
The oxygen isotope ratios of diatoms (δ18Odiatom), and the oxygen and hydrogen isotope ratios of lake water (δW) of lakes in south Alaska provide insight into past changes in atmospheric circulation. Lake water was collected from 31 lakes along an elevation transect and diatoms were isolated from lake sediment from one lake (Mica Lake) in south Alaska. In general, δW values from coastal lakes overlap the global meteoric water line (GMWL). δW values from interior lakes do not lie on the GMWL; they fall on a local evaporation line trajectory suggesting source isotopes are depleted with respect to maritime lakes. Sediment cores were recovered from 58 m depth in Mica Lake (60.96° N, 148.15° W; 100 m asl), an evaporation-insensitive lake in the western Prince William Sound. Thirteen calibrated 14C ages on terrestrial macrofossil samples were used to construct an age-depth model for core MC-2, which spans 9910 cal years. Diatoms from 46, 0.5-cm-thick samples were isolated and analyzed for their oxygen isotope ratios. The analyses employed a newly designed, stepwise fluorination technique, which uses a CO2 laser-ablation system, coupled to a mass spectrometer, and has an external reproducibility of ±0.2‰. δ18Odiatom values from Mica Lake sediment range between 25.2 and 29.8‰. δ18Odiatom values are relatively uniform between 9.6 and 2.6 ka, but exhibit a four-fold increase in variability since 2.6 ka. High-resolution sampling and analyses of the top 100 cm of our lake cores suggest large climate variability during the last 2000 years. The 20th century shows a +4.0‰ increase of δ18Odiatom values. Shifts of δ18Odiatom values are likely not related to changes in diatom taxa or dissolution effects. Late Holocene excursions to lower δ18Odiatom values suggest a reduction of south-to-north storm trajectories delivered by meridional flow, which likely corresponds to prolonged intervals when the Aleutian Low pressure system weakened. Comparisons with isotope records of precipitation (δP) from the region support the storm-track hypothesis, and add to evidence for variability in North Pacific atmospheric circulation during the Holocene.
Zachary SharpEmail:
  相似文献   

10.
We use Cladocera remains in the sediments to reconstruct the longterm history of Lake Orta, a lake which experienced severe pollution from copper and ammonium sulphate, and started to recover during the last 15 years. Both human and natural impacts were detected over almost 400 years. Pollution was manifested by a dramatic decrease in the number of remains, in the planktonic/littoral (P/L) ratio, and in chydorid species diversity. Most species, even those most tolerant to stress, disappeared. The recolonization of biota was initially sustained by one species of chydorid,Chydorus sphaericus, which had a three-fold increase at the beginning of the 1980s, when studies on plankton recorded the development of a pelagic population. This fact, and the appearance in the sediments ofAlona quadrangularis, attest to the development of filamentous algae which was reported in studies on the plankton. The colonization of the lake by pelagic species came only in the last twelve years and was manifested also as a stabilization of the P/L ratio. Two other periods of disturbance were detected in the sediments: the first, at the end of the 19th century, was related to the introduction of exotic fish species; the second occurred during the second half of the 17th century. This event probably cannot be ascribed to human impact, but may be related to a decrease in temperature in that period (the Maunder Minimum).  相似文献   

11.
Based on the geochemical elements Rb and Sr in sediments with three different grain size fractions from profile H3 on the northern lacustrine bottomland 13 m above the Huangqihai Lake surface in 1986, the paper investigates the record of palaeolake stand state, sedimentary environmental evolution, and winter monsoon change. First, these samples are separated into three different grain size fractions, i.e., total sediments, 77–20 μm and <20 μm. Second, the chemical elements—Rb and Sr—of the grain size separation were tested and analyzed systematically in this paper. Then the elements compositions of these samples are measured using VP-320 mode fluorescence spectrum instrument, respectively. The magnetic susceptibility of these samples is measured using Kappabridge KLY-3 mode instrument made in Czech AGICO Company. The results showed the elements and the ratios varied regularly with the grain size. But the ratio of Rb/Sr in the sediments <20 μm correlates positively with the magnetic susceptibility of these samples. Therefore, the ratio of Rb/Sr in the fraction <20 μm from the lake sediments reflected the strengthening of the weathering in the deposition sites. It is a good indicator of the summer monsoon-induced weathering and pedogenesis fluctuations and can be used to reconstruct the conditions of the paleoclimate and paleoen-vironment.  相似文献   

12.
内蒙古黄旗海不同粒级湖泊沉积物Rb、Sr组成与环境变化   总被引:2,自引:0,他引:2  
Based on the geochemical elements Rb and Sr in sediments with three different grain size fractions from profile H3 on the northern lacustrine bottomland 13 m above the Huangqihai Lake surface in 1986,the paper investigates the record of palaeolake stand state, sedimentary environmental evolution,and winter monsoon change.First,these samples are separated into three different grain size fractions,i.e.,total sediments,77-20μm and〈20μm. Second,the chemical elements-Rb and Sr-of the grain size separation were tested and analyzed systematically in this paper.Then the elements compositions of these samples are measured using VP-320 mode fluorescence spectrum instrument,respectively.The magnetic susceptibility of these samples is measured using Kappabridge KLY-3 mode instrument made in Czech AGICO Company.The results showed the elements and the ratios varied regularly with the grain size.But the ratio of Rb/Sr in the sediments〈20μm correlates positively with the magnetic susceptibility of these samples.Therefore,the ratio of Rb/Sr in the fraction〈20 μm from the lake sediments reflected the strengthening of the weathering in the deposition sites.It is a good indicator of the summer monsoon-induced weathering and pedogenesis fluctuations and can be used to reconstruct the conditions of the paleoclimate and paleoenvironment.  相似文献   

13.
青藏高原对全球气候变暖响应敏感,研究青藏高原近千年来环境演化过程、规律与驱动机制对预测其未来气候变化有重要意义。本文通过位于青藏高原东部的苦海沉积物总有机质相关指标(总有机碳(TOC)、总氮(TN)、总有机碳与总氮比值(TOC/TN)和总有机碳同位素(δ13Corg)的研究重建了该区域过去840年来环境演化过程。结果表明,苦海沉积物中的有机质主要来自于内源水生植物。由于暖期(冷期)时黄河上游径流量较高(低),苦海水位随之升高(降低),湖泊水动力增强(减弱),浅水区沉水植物对研究岩芯中的有机质贡献率提高(降低),导致沉积物TOC、TN、TOC/TN升高,δ13Corg值正(负)偏。人类活动导致的青藏高原近50年气候异常变暖可能是~1950 AD之后δ13Corg反映的黄河上游径流量变化与重建的中国温度记录之间的关系发生转变的原因。苦海沉积物δ13Corg记录与万象洞石笋δ18O记录和太阳总辐射强度记录变化特征的相似性说明青藏高原东部地区气候变化的控制因素为太阳辐射驱动下的季风降雨量变化。  相似文献   

14.
Recent improvements in understanding glacial extents and chronologies in the Wasatch and Uinta Mountains and other mountain ranges in the western U.S. call for a more detailed approach to using glacier reconstructions to infer paleoclimates than commonly applied AAR-ELA-ÄT methods. A coupled 2-D mass balance and ice-flow numerical modeling approach developed by [Plummer, M.A., Phillips, F.M., 2003. A 2-D numerical model of snow/ice energy balance and ice flow for paleoclimatic interpretation of glacial geomorphic features. Quaternary Science Reviews 22, 1389–1406] allows exploration of the combined effects of temperature, precipitation, shortwave radiation and many secondary parameters on past ice extents in alpine settings. We apply this approach to the Little Cottonwood Canyon in the Wasatch Mountains and the Lake Fork and Yellowstone Canyons in the south-central Uinta Mountains. Results of modeling experiments indicate that the Little Cottonwood glacier required more precipitation during the local Last Glacial Maximum (LGM) than glaciers in the Uinta Mountains, assuming lapse rates were similar to modern. Model results suggest that if temperatures in the Wasatch Mountains and Uinta Mountains were  6 °C to 7 °C colder than modern, corresponding precipitation changes were  3 to 2× modern in Little Cottonwood Canyon and  2 to 1× modern in Lake Fork and Yellowstone Canyons. Greater amounts of precipitation in the Little Cottonwood Canyon likely reflect moisture derived from the surface of Lake Bonneville, and the lake may have also affected the mass balance of glaciers in the Uinta Mountains.  相似文献   

15.
We used statistical analyses to determine which subset of 36 environmental variables best explained variations in surface sediment δ13C and δ15N from 50 lakes in western Ireland that span a human-impact gradient. The factors controlling lake sediment δ13C and δ15N depended on whether organics in the lake sediment were mostly derived from the lake catchment (allochthonous) or from productivity within the lake (autochthonous). Lake sediments with a dominantly allochthonous organic source (high C:N ratio sediments) produced δ13C and δ15N measurements similar to values from catchment vegetation. δ13C and δ15N measurements from lake sediments with a dominantly autochthonous organic source (low C:N ratio sediments) were influenced by fractionation in the lake and catchment leading up to assimilation of carbon and nitrogen by lacustrine biota. δ13C values from lake sediment samples in agricultural catchments were more negative than δ13C values from lake sediment samples in non-impacted, bogland catchments. Hypolimnetic oxygen concentrations and methane production had a greater influence on δ13C values than fractionation due to algal productivity. δ15N from lake sediment samples in agricultural catchments were more positive than δ15N in non-impacted bogland catchments. Lower δ15N values from non-impacted lake catchments reflected δ15N values of catchment vegetation, while higher δ15N values in agricultural catchments reflected the high δ15N values of cattle manure and inorganic fertilisers. The influence of changing nitrogen sources and lake/catchment fractionation processes were more important than early diagenesis for lake sediment δ15N values in this dataset. The results from this study suggest a possible influence of bound inorganic nitrogen on the bulk sediment δ15N values. We recommend using a suitable method to control for bound inorganic nitrogen in lake sediments, especially when working with clay-rich sediments. This study confirms the usefulness of δ13C and δ15N from bulk lake sediments, as long as we are mindful of the multiple factors that can influence these values. This study also highlights how stable isotope datasets from lake surface sediments can complement site-specific isotope source/process studies and help identify key processes controlling lake sediment δ13C and δ15N in a study area.  相似文献   

16.
We studied the potential for using stable carbon and nitrogen isotope ratios in sediment profiles to trace external nutrient sources and eutrophication at four coastal sites in the Baltic Sea. The sites are characterized by various present and past activities in their catchments, including residential development, sugar processing, agriculture and fish farming. Radiometrically dated sediment cores were analysed for nutrient isotope ratios, organic carbon and total nitrogen. Background information was collected from historical sources, literature and water monitoring data. Despite the multiple organic enrichment sources, it was possible to identify individual sources and processes in the sediment profiles using stable isotope analysis of bulk sediment. The largest changes in δ15N values were seen at sites receiving urban wastewaters. The site that received effluents from a sugar cane (C4-plant) refinery in the past showed a clear effect on δ13C values compared to the site that received wastewater from a sugar beet (C3-plant) factory. Fish farming produced detectable, albeit minor changes in the sediment profile. Slightly lower δ13C values reflected the influence of fish feed and fish metabolism, and higher δ15N values likely indicated the influence of increased sediment denitrification. The land-sea connection via river discharge was observable in the overall δ13C levels of the sediment cores. Our results suggest that temporal changes in sources of organic matter enrichment can be detected in well-dated coastal sediment cores using nutrient stable isotope analyses, even at sites subjected to multiple impacts. There is not, however, a simple relationship between sediment stable isotope profiles and the eutrophication history of our study sites.  相似文献   

17.
Abundant ostracode valves (Cyprinotus cingalensis) and caryopses of Urochloa paspaloides, a terrestrial grass, were well preserved in the lacustrine sediments of the Cattle Pond on Dongdao Island, South China Sea. Oxygen and carbon isotopes, and elements (Ca, Mg) were analyzed on ostracode valves and plant caryopses in this study. The δ18Oostracode and δ13Costracode exhibited a positive and statistically significant correlation, and showed a decreasing trend toward the top of sediment sequence with some fluctuations, indicating a gradual increase in effective moisture. The Mg/Ca ratios in the ostracode shells, generally used as a proxy for salinity changes in lake water, showed a trend toward lower values in the upper samples, reflecting a gradual decrease of salinity in the lake. The δ13Corg values in the plant caryopses of the upper 14 cm of sediment have lower values than those in the bottom sediments, suggesting less water and salinity stress. These results indicate increasing effective moisture and rainfall intensity over the past ∼1,100 years on Dongdao Island.  相似文献   

18.
Comparing the organic matter (OM) composition of modern and past lake sediments contributes to the understanding of changes in lacustrine environments over time. We investigate modern plant and lake-water samples as well as modern and ancient sediment samples from the Tswaing Crater in South Africa using biomarker and stable carbon isotope analyses on bulk OM and specific biomarker compounds. The characteristic molecular markers for higher land plants (predominantly C3-type deciduous angiosperms) in Lake Tswaing are long-chain n-alkanes (n-C27−33), n-alkanols (n-C28+30), stigmasterol, β-sitosterol, β-amyrin, α-amyrin and lupeol. The C17 n-alkane, tetrahymanol, gammaceran-3-one and C29 sterols dominate the lipid fraction of autochthonously produced OM. By comparing stable carbon isotope analyses on bulk OM and the characteristic biomarkers, we follow the modern carbon cycle in the crater environment and find indications for methanotrophic activity in the lake from isotopically depleted moretene. A comparative study of core sediments reveals changes in the terrestrial (C3 versus C4) and aquatic bioproductivity and allows insights into the variability of the carbon cycle under the influence of changing climatic conditions for the time from the end of the last glacial (Termination I) to the late Holocene, ca. 14,000–2,000 calibrated years before present (years BP). The most pronounced changes occur in the aquatic realm after ca. 10,000 years BP when our results imply climate swings from more humid to more arid and after 7,500 years BP to gradually more humid conditions again, which can be related to a shift in the position of the Inter-Tropical Convergence Zone or to changes in the tropical atmosphere–ocean interaction. Long-chain alkenones (LCAs) have been identified in ancient lake sediments from Africa for the first time. They occur in samples older than 7,500 years BP and their distribution (dominance of C38 and of tri- over tetra-unsaturated LCAs) is distinctly different from other published records suggesting a to date unknown source organism.  相似文献   

19.
Glacial striae and other ice movement indicators such as roche moutonées, glacial erratics, till fabric and glaciotectonic deformation have been used to reconstruct the Late Weichselian ice movements in the region of eastern Svalbard and the northern Barents Sea. The ice movement pattern may be divided into three main phases: (1) a maximum phase when ice flowed out of a centre east or southeast of Kong Karls Land. At this time the southern part of Spitsbergen was overrun by glacial ice from the Barents Sea; (2) the phase of deglaciation of the Barents Sea Ice Sheet, when an ice cap was centred between Kong Karls Land and Nordaustlandet. At the same time ice flowed southwards along Storfjorden; and (3) the last phase of the Late Weichselian glaciation in eastern Svalbard is represented by local ice caps on Spitsbergen, Nordaustlandet, Barentsoya and Edgeøya.
The reconstructed ice flow pattern during maximum glaciation is compatible with a centre of uplift in the northern Barents Sea as shown by isobase reconstructions and suggested by isostatic modelling.  相似文献   

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