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1.
Emergent Pleistocene sea level indicators in the northern Bahamas include: a bioerosional notch at +5.3 to 5.9 m; sea caves, notches, and marine terraces at about +4.3 m; and lithified coral rubble and reef deposits between 0 and 3 m. Thorium 230 dates of the fossil corals, which were deposited as these features were being produced, span the age range from 100 to 145 thousand years BP with a majority falling between 115 and 130 thousand years BP. The notch at about +5.6 m is interpreted to be the product of a sea level stand 125 thousand years BP, while the features at +4.3 m are believed to be formed sometime later as sea level fell from the higher position. Part of the age span is inherent in the dating technique and possible sample alteration. Another cause of the spread may be mixing of corals of different ages into a single deposit. 相似文献
2.
Deep-sea sediments from a basin in the Southeast Pacific are described, in which strong carbonate dissolution and strong diagenetic migration of metals can be observed. Clay minerals of smectite type are formed in large quantities during the early diagenesis of this sediment, in a first stage as an X-ray amorphous phase, which later crystallizes to smectite. Rb, Sc, Na and K become enriched during the process of clay-mineral formation, probably due to uptake of these elements from sea-water to interlayer positions of smectite. The unsolved question is what sort of mechanism connects the calcite dissolution with the formation of smectite? The source of the Al, necessary for the formation of smectite is also unknown. 相似文献
3.
T.R.S. Wilson J. Thomson S. Colley D.J. Hydes N.C. Higgs J. Sørensen 《Geochimica et cosmochimica acta》1985,49(3):811-822
Porewater and solid phase geochemical data at two contrasting NE Atlantic stations are reported. Station 10552, on the Cape Verde abyssal plain, is a site of slow pelagic accumulation (ca. 0.4 cm kyr?1). Molecular oxygen is present in the sediment column to at least 2 m, and probably much deeper, labile organic-carbon is almost totally consumed in the upper few centimetres of the sediment. By contrast, at station 10554 on the Madeira abyssal plain, the pelagic sequence has been interrupted by the occasional deposition of organic-rich turbidites. Porewater oxygen and nitrate profiles show that subsurface organic metabolism of the organic-carbon associated with the uppermost turbidite layer is a significant fraction of the overall metabolism in the sediment column. This metabolism occurs at a relatively thin reaction front which progresses deeper into the turbidite with time. This phenomenon exerts a controlling influence on the present nutrient profile and redox succession.In a less extreme form, substrate distributions of this latter type are not uncommon in Atlantic sediments. A model has been developed which is controlled by both oxygen and nitrate data. This model permits a vertical profile of metabolic activity to be derived, and also gives estimates of the reaction rate constants and solid phase mixing rates at these two contrasting stations. About 30% of the total activity at station 10554 is located within the turbidite at the deepening reaction front; this is a non-steady-state condition. In fact, it is found that the integrated metabolic activity at the two stations is not dissimilar (ca. ). The striking differences in redox profile are therefore primarily attributable to differences in the distribution of metabolic activity within the column. 相似文献
4.
Pleistocene speleothems of Mallorca: implications for palaeoclimate and carbonate diagenesis in mixing zones 总被引:1,自引:0,他引:1
The Pleistocene speleothems of Sa Bassa Blanca cave, Mallorca, are excellent indicators of palaeoclimate variations, and are samples that allow evaluation of the products and processes of mixing‐zone diagenesis in an open‐water cave system. Integrated stratigraphic, petrographic and geochemical data from a horizontal core of speleothem identified two main origins for speleothem precipitates: meteoric‐marine mixing zone and meteoric‐vadose zone. Mixing‐zone precipitates formed at and just below the water–air interface of cave pools during interglacial times, when the cave was flooded as a result of highstand sea‐level. Mixing‐zone precipitates include bladed and dendritic high‐Mg calcite, microporous‐bladed calcite with variable Mg content, and acicular aragonite; their presence suggests that calcium‐carbonate cementation is significant in the studied mixing‐zone system. Fluid inclusion salinities, δ13C and δ18O compositions of the mixing‐zone precipitates suggest that mixing ratio was not the primary control on whether precipitation or dissolution occurred, rather, the proximity to the water table and degassing of CO2 at the interface, were the major controls on precipitation. Thus, simple two‐end‐member mixing models may apply only in mixing zones well below the water table. Meteoric‐vadose speleothems include calcite and high‐Mg calcite with columnar and bladed morphologies. Vadose speleothems precipitated during glacial stages when sea level was lower than present. Progressive increase in δ13C and δ18O of the vadose speleothems resulted from cooling temperatures and more positive seawater δ18O associated with glacial buildup. Such covariation could be considered as a valid alternative to models predicting invariant δ18O and highly variable δ13C in meteoric calcite. Glacio‐eustatic oscillations of sea‐level are recorded as alternating vadose and mixing‐zone speleothems. Short‐term climatic variations are recorded as alternating aragonite and calcite speleothems precipitated in the mixing zone. Fluid‐inclusion and stable‐isotope data suggest that aragonite, as opposed to calcite, precipitated during times of reduced meteoric recharge. 相似文献
5.
Liu Jian Ye Zhizheng Han Chunrui Liu Xinbo Qu Gaosheng 《Journal of Asian Earth Sciences》1997,15(6):465
This paper focuses on a borehole, Xichen-1 well, drilled on the Chenhang Island, Xisha Islands in the South China Sea. Mineralogical, petrographic, stable isotopic and minor-element data from the Holocene to Pleistocene interval (0–179 m ) in the Xichen-1 well are discussed in detail. The 400-m-long core is divisible into four mineralogical facies: a high-Mg calcitic aragonite facies (0–16.91 m, Holocene), an aragonitic low- Mg calcite facies (16.91–30.60 m, Late Pleistocene), a low- Mg calcitic facies (30.60–179 m, Middle-Early Pleistocene) and a low- Mg calcitic and dolomitic facies (179–400 m, Early Pleistocene–Late Miocene). The Holocene section has much higher whole-rock δ18O and δ13C values and Mg and Sr content than the non-dolomitized Pleistocene limestones (16.91–179 m). The 16.91–165 m interval is characterized by a relatively invariant oxygen isotopic composition and very heterogeneous carbon isotopic composition. Between 165 and 179 m, there is a positively correlated increase of whole-rock δ18O and δ18C with depth, and Mg content also shows a gradual increase with depth. Petrographic data demonstrate that the Pleistocene reef sequence has been extensively affected by meteoric waters. We conclude that the Late Pleistocene section (16.91–30.60 m) and the Middle-Early Pleistocene section (30.60–165 m) have suffered incomplete and complete meteoric diagenesis, respectively, and that the Early Pleistocene interval (165–179 m) was diagenetically altered in a meteoric–marine mixing environment. 相似文献
6.
The stable isotope geochemistry of Miocene sediments from the leeward margin of the Great Bahama Bank was examined to investigate burial diagenetic processes in periplatform carbonates. Data indicate that, in addition to differences in bulk proportions of neritic and pelagic carbonate along the slope, rhythmic variation in primary carbonate content has controlled patterns of burial diagenesis and associated geochemical signatures throughout much of the succession examined. The present study focuses on Ocean Drilling Program Sites 1006 and 1007, the most distal of five sites drilled from marginal to deep basin environments during Leg 166. These Miocene sections are characterized by their cyclic appearance, manifest as decimetre‐ to metre‐scale alternations between light‐coloured ooze/chalk/limestone and dark‐coloured marl/marlstone. The section at Site 1006 contains a high proportion of pelagic carbonate and is unlithified to a subbottom depth of ~675 m. Fluctuations in δ18O and δ13C values at this site are independent of lithological variation and reflect primary conditions. At Site 1007, located at the toe‐of‐slope and composed of a mixture of bank‐derived and pelagic carbonate, limestones are densely cemented, show little evidence of compaction and have δ18O values up to 2‰ higher than coeval sediments at Site 1006. Marlstones at Site 1007 are poorly cemented, exhibit an increase in compaction‐related features with depth and have lower and more variable δ18O values that are similar to those of coeval sediments at Site 1006. Isotopic and petrographic characteristics of limestone interbeds result from cement precipitation from cold sea water during the first ~100 m of burial. Higher proportions of insoluble materials and pelagic carbonate seem to have inhibited diagenetic alteration in adjacent marlstones; in spite of significant compaction and pressure solution during burial, original isotopic compositions appear to be best preserved in these intervals at Site 1007. The documented contrasts in petrographic and isotopic patterns illustrate the role of primary sediment composition in controlling lithification processes in periplatform carbonates and stress the importance of considering such factors when interpreting geochemical data from ancient shelf and slope limestones. 相似文献
7.
8.
Anaerobic diagenesis within Recent, Pleistocene, and Eocene marine carbonate frameworks 总被引:2,自引:0,他引:2
FRANCIS J. SANSONE† GORDON W. TRIBBLE ‡ CHRISTINE C. ANDREWS† JEFFREY P. CHANTON§ 《Sedimentology》1990,37(6):997-1009
Porewaters from a variety of Recent, Pleistocene, and Eocene lithified marine carbonate frameworks displayed similar chemical characteristics: highly depleted concentrations of dissolved oxygen (>20 μM), elevated levels of dissolved methane (25-5000 nM), and near-seawater sulphate levels. These porewaters also had low pH values (7·5-7·9), and contained elevated concentrations of sulphide (4–10 μM), dissolved inorganic carbon (2·05–2·46 mM), and inorganic nutrients. Hydrocarbon composition data indicate that the methane is biogenic, whereas the methane δ13C values (–47·4 ± 2·7%0) suggest that it has been subject to oxidation. The porewater dissolved inorganic carbon δ13C values varied from –0·6 to –39%0, suggesting input of carbon dioxide from organic matter oxidation. We conclude that anaerobic diagenesis involving bacterial degradation of organic matter is a common process in lithified marine carbonates and hypothesize that it may be an important factor controlling their carbonate geochemistry. 相似文献
9.
Pleistocene fluctuations of sea level have left marine and aeolian limestones intercalated with glacial red soils on the Bermuda Carbonate Platform (Atlantic, 64°50W, 32°20N). Successive eustatic highstands of similar amplitude drowned the tectonically stable platform and piled up similar sets of sediments. Up to three Pleistocene beaches are stacked in shorelines sections. Post-depositional diagenetic histories of these beaches can be linked to repeated changes in sea level and pore waters.This paper presents field evidence and petrographic results (microscope, X-ray, cathodoluminescence, SEMEDAX) for the diagenetic histories of two superimposed Pleistocene beaches in Whalebone Bay, Bermuda North Shore. The younger beach was deposited during isotopic stage 5e, about 120 ka ago. The age of the older beach may be isotopic stage 9 or older.Diagenesis drastically altered the older beach before the stage 5e transgression. Primary high-Mg calcite (HMC) and aragonite were no longer present. Marine skeletal grains were instead leached or recrystallized to low-Mg calcite (LMC). Primary and secondary pore space were largely reduced by LMC cement. Lines of needle relics reminiscent of marine aragonite cement occur as inclusions within syntaxial rim cements around echinoderm grains, indicating that a marine influence had at least once interrupted this period of freshwater alteration. Finally, before the rocks became buried by the sediments of the younger beach, a crust of marine, bladed HMC cement was precipitated throughout the pore space.The younger beach consists of skeletal grains that are, apart from the effects of non-selective dissolution, essentially unaltered. The sediments are only weakly lithified by cryptocrystalline LMC showing an alveolar texture, tangential fibres and other features characteristic of calichification. A younger post-depositional marine influence is not recorded.These results suggest that, under favourable conditions, diagenetic processes can document sea-level fluctuations. The recorded fluctuations, however, are difficult to assess because even major sea-level highstands may not produce a diagenetic imprint.
Correspondence to: R. Vollbrecht 相似文献
10.
Samir Mefteh Mounir Medhioub Elhoucine Essefi Fakher Jamoussi 《Journal of the Geological Society of India》2014,83(2):198-210
This study aims to follow the effect of the diagenetic transformations on the clayey fraction and the organic matter of the Tunisian southern sub-surface. 61 samples from oil well named NWA-1 were recuperated for series of analyses. This study follows a comparative approach between the mineralogical, geochemical and petrographic studies. To discuss results from a statistical viewpoint, the Principal Component Analysis (PCA) was applied in order to find out any correlation between different components. The associated minerals quartz, feldspar, calcite, pyrite, anhydrite, gypsum, dolomite and olivine are also detected. These associated minerals remove by-products by the illitization reaction. The Index of Crystallinity (IC) of illite shows that, except some anomalies, the studied samples are between the epizone and the anchizone. Downward, samples show the effect of diagenetic processes and weak signs of low-grade metamorphism. As regards to the organic matter, values of Tmax range between 333°C and 463°C. On the other hand, potential hydrocarbon compounds (S2) show low values compared to those of (S1); but they maintain a similar variability from 0.63 to 21.12. SEM observations and X-ray microanalyses supported the formation of authigenic micro-quartz. The PCA of clay minerals, chemical components, and the depth shows three different populations. Feldspar, chlorite and quartz make up a population positively correlated with the depth. The second population seems to be indifferent to depth variation; it is made up of two sub-populations: the population of illite, gypsum and anhydrite, which is obtained by a counter clock rotation of depth population; and the population of pyrite, kaolinite, olivine phyllosilicate, which is obtained by an anticlockwise rotation of depth population. Third, the population of smectite, calcite and dolomite is inversely proportional to the depth variation. On the other hand, the PCA of TOC, Tmax, HI, S1, S2 and the depth make up a homogenous statistical population following the depth evolution. 相似文献
11.
Hydrochemical data for meteoric waters of the uplifted carbonate platform of northern Guam show that, contrary to recent models of lowstand diagenesis, phreatic dissolution is active beneath a 60–180 m thick vadose zone. Overland flow during high intensity rainfall events is focussed into surface detention ponds, which drain very rapidly via the epikarst and vertical fissures to the freshwater lens. We estimate that these waters contribute 13% of dissolved calcium in samples from pumping wells but may also deliver aggressive and/or organic-rich waters to the lens. Fast-flow vadose waters mix with lens-top waters to form fresher cap that discharges rapidly coastwards via cavernous porosity. Slower vadose percolation, sampled as cave drips, equilibrates with bedrock within the upper 30 m of the vadose zone, accounting for some 46% of dissolved calcium in the lens waters. The remaining 41% calcium is generated by net dissolution within the lens. 相似文献
12.
ANN-MARIE ROBERTSSON KARIN GARCíA AMBROSIANI 《Boreas: An International Journal of Quaternary Research》1988,17(1):1-14
Till-covered sand and silt sediments with organic material from Boliden, northern Sweden, have been resampled and reinvestigated. Texture and petrographic analyses demonstrated one till bed overlying, and one underlying the sandy sediments. Low frequencies of diatoms were noted, representing freshwater, halophilous and brackish water taxa. The diatoms may be allochthonous or autochthonous, or redeposited from older deposits. Pollen analysis revealed a new picture of the composition of the vegetation, as compared with earlier investigations. The flora consisted of an arctic-subarctic treeless shrub and herb vegetation dominated by Salix, Betula nana , Gramineae and Cyperaceae. Artemisia and several arctic-alpine herbs were important elements. The identification of Salix wood as well as fruits and fruit scales of Betula nana and Betula cf. humilis is in agreement with the pollen-analytical results, as is the occurrence of Nordicboreal species of Coleoptera. Two radiocarbon datings resulted in an age of c. 45,000 B. P. and >40,000 B.P. The Boliden till-covered sediments were most probably deposited during an Early or Middle Weichselian interstadial, but the initial or final stage of an interglacial (Eemian) is also possible. 相似文献
13.
We compare the diagenetic evolution of deeply buried Rotliegend (Permian) red bed sandstones at the southern and northern
margin of the Central European Basin (CEB) in Germany. Main target is to evaluate the influence of maturation products from
hydrocarbon (HC) source rocks during red bed diagenesis. At the southern margin of the CEB, thick coal-bearing Carboniferous
source rocks are omnipresent beneath the Rotliegend. They contain dominantly gas-prone terrigenous organic material and some
oil source rocks. Hydrocarbons were generated from Late Carboniferous onwards throughout most of basin subsidence. At the
northern margin of the CEB, source rocks are almost absent due to deep erosion of Carboniferous rocks and a low TOC of local
Lower Carboniferous relics. Early diagenetic processes are comparable at both basin margins. Significant differences in burial
diagenetic evolution are spatially correlated to the occurrence of hydrocarbon source rocks. Burial diagenesis at the southern
margin of the CEB is characterized especially by bleaching of red beds, major dissolution events, pervasive illite formation,
impregnation of pore surfaces with bitumen, and formation of late Fe-rich cements. Almost none of these features were detected
at the northern basin margin. Instead, relatively early cements are preserved down to maximum burial depths. This suggests
that major diagenetic mineral reactions in deeply buried red bed sandstones are controlled by the presence or absence of maturing
hydrocarbon source rocks. 相似文献
14.
Marine diatomaceous siliceous sediments in Neogene sections of northern Japan contrast with the Monterey Shale of California in containing many intercalations of acidic volcaniclastic sediments. Diagenesis of these sediments from deep boreholes and surface sections was investigated. Three diagenetic zones—biogenic opal, opal-CT and quartz zones—are recognized in siliceous sediments, corresponding roughly to amorphous silica, low cristobalite and quartz zones in acidic vitric volcaniclastic sediments. Opal-CT consists almost exclusively of silica and water, while low cristobalite contains appreciable amounts of A1, Ca, Na and K. In subsurface sections, values of d(101) spacing of opal-CT decrease progressively with increasing burial depth. The progressive ordering is not associated with additional silica cementation. In surface sections, the behaviour of d(101) spacing is complicated owing to the modification of the progressive ordering developed during burial diagenesis by later silica cementation during uplift. The cementing opal-CT is probably precipitated from percolating groundwater which dissolves siliceous skeletons in porous diatomaceous mudstones overlying the opal-CT porcellanite. Opaline cherts that form during burial diagenesis are designated as early opaline chert, while those which form during uplift are later opaline chert. The later opaline chert contains two groups of opal-CT; one is progressively ordered opal-CT and the other is additionally cemented opal-CT with higher d(101) spacing than that in the host porcellanite. In diatomaceous siliceous sediments, early opaline chert is scarce. Most, if not all, opaline cherts in surface sections are of later origin. 相似文献
15.
Equilibrium-line-altitude (ELA) reconstructions using the toe-to-headwall-altitude ratio method for paleoglaciers in the Cordilleras Blanca and Oriental, northern Peruvian Andes (7–10°S; 77°20'–77°35'W), indicate that ELAs during the last glacial maximum (LGM; marine isotope stage 2) were c . 4300 m in the Cordillera Blanca, c . 3900–3600 m on the west side of the Cordillera Oriental, and c . 3200 m on the east (Amazon Basin) side of the Cordillera Oriental. Comparison with estimated modern ELAs and glaciation thresholds indicate that ELA depression ranged from c . 700 m in the Cordillera Blanca to c . 1200 m on the east side of the Cordillera Oriental. This augments data from many mountain ranges in middle- and low-latitude regions that indicate that ELAs during the LGM were depressed by c . 1000 m. Published palynological evidence for drier conditions during the LGM in the tropical Andes suggests that ELA depression of this amount involved a temperature reduction (> 5–6°C) that greatly exceeded the tropical sea-surface temperature depression estimates of CLIMAP (< 2°C). The west to east increase in ELA depression during the LGM indicates that the steep modern precipitation gradients may have been even steeper during the LGM. 相似文献
16.
V. I. Astakhov 《Doklady Earth Sciences》2017,476(2):1200-1202
This is an overview of the latest data on the age of topographically expressed glacigenic formations of the Polar Urals obtained by international geological teams by modern dating techniques including optical luminescence, radiocarbon and cosmogenic beryllium in exposed boulders. The new dates combined with the results of geological mapping and remote sensing data is a basis for rejecting the concept of the Quaternary Uralian ice caps in favor of small alpine glaciers which developed south of the Kara ice sheet. 相似文献
17.
《Quaternary Science Reviews》2007,26(22-24):2883-2896
In the El Minia district of northern Upper Egypt, the Pleistocene deposits of the Nile Valley include (?)Early Pleistocene conglomerates of the Armant Formation and (?)Middle Pleistocene sands of the Qena Formation. These sediments are exposed along both sides of the valley in terraces at different heights, unconformably overlying Eocene limestones. Field observations suggest that the conglomerate facies of the Armant Formation was deposited in proximal and mid-alluvial fans. The sands of the Qena Formation are differentiated into two facies: a cross-bedded sandstone, representative of alluvial fan—braided stream environments, and a facies of sand interbedded with mud that may have been deposited by a meandering river. The heavy minerals of the Armant Formation are markedly different from those of the Qena Formation, suggesting derivation from different sources. Surface textures of quartz grains from the Qena sands, observed by SEM, exhibit chemical features, attributed to a fluviatile origin. Sand from the Armant Formation is characterized by mechanical and chemical surface textural features that suggest original aeolian derivation followed by later fluvial sedimentation. 相似文献
18.
AXEL MUNNECKE HILDEGARD WESTPHAL† JOHN J. G. REIJMER† CHRISTIAN SAMTLEBEN 《Sedimentology》1997,44(6):977-990
Comparison of ultrastructures in Pliocene periplatform carbonates from the Bahamas with Silurian limestones from Gotland (Sweden) reveals that despite the differences in primary sediment composition and age, they reflect a similar mechanism of lithification. In both sequences calcite microspar was formed as a primary cement at an early stage of marine burial diagenesis. Neither significant compression nor meteoric influence are necessary for the formation of calcite microspar. A model is proposed for the process of microsparitic cementation of fine-grained aragonite needle muds comprising four stages: (1) unconsolidated, aragonite-dominated carbonate mud; (2) precipitation of microspar that engulfs aragonite needles; (3) dissolution of aragonite, resulting in pitted surfaces of the microspar crystals; and (4) slight recrystallization. Our results contradict the widespread opinion that microspar necessarily is a product of secondary recrystallization of a previously lithified micrite. 相似文献
19.
Palaeodunes were examined on the eastern margin of the Rio Branco–Rupununi savanna, northeast Amazonia. Optical dating suggests that the onset of aeolian activity was between 17 000 and 15 000 yr ago, just after the Last Glacial Maximum. Both the palaeodune axes and modern dominant wind directions have northeast to east‐northeast directions, implying no significant shift in atmospheric circulation patterns over northeast Amazonia during the Late Pleistocene to Holocene. Major regional climate change events, such as the Younger Dryas, do not appear to have had any effect on the rates of aeolian deposition at the study site. Aeolian activity appears to have continued to the present day, showing a remarkably constant deposition rate of around 0.13 m kyr?1 initially, increasing smoothly to the present. Until more palaeodunes in northern Amazonia are dated, it is impossible to determine if this record of gradual aeolian deposition is a reliable regional palaeoclimate indicator, rather than being the result of local bioclimatic and geomorphological effects. Copyright © 2004 John Wiley & Sons, Ltd. 相似文献
20.
The uplifted Pleistocene terraces along the coast of southern Sinai exhibit a well developed reef system formed during isotope stage 9, and a younger one formed during isotope stage 5. An intermediate reef corresponding to isotope stage 7 occurs only as an erosional relic in the study area. The sediments comprise reefal framestones, peri-reefal facies, coral rubble, and siliciclastic-dominated beach and aeolian facies. The compositional and textural complexity of the sediments leads to a highly variable spatial distribution of diagenetic features. However, the geometric relationships and elemental analyses allow a reconstruction of the general diagenetic evolution: during the major eustatic sea-level highstand of isotope stage 9, the Older Reef was constructed and cemented with aragonite and high-Mg calcite. Climate was probably semiarid with some rainy periods which permitted the installation of ephemeral freshwater lenses, especially during the minor sea-level lowstand within isotope stage 9. In these lenses, and during the subsequent major sea-level lowstand, some freshwater dissolution occurred. The highstand during isotope stage 7 led to the construction of the Intermediate Reef. In the Older Reef, some high-Mg calcite precipitated at that time. Dolomite cement formed either in marine interstitial waters modified by some freshwater input, or in a hypersaline context. Phreatic-meteoric low-Mg calcite cement covers, and partly replaces, previous marine cements and dolomite, but is still attributed to the major highstand of isotope stage 7 when freshwater lenses could develop during minor sea-level lowstands. The subsequent major sea-level lowstand was dominated by an arid climate, and only a little freshwater corrosion occurred. The Younger Reef formed during the major highstand of isotope stage 5. Aragonite and high-Mg calcite cements, as well as some dolomite, are common within the reef, whereas freshwater cements are limited to beach and aeolian facies. Due to tectonic uplift, only the lower part of the Older Reef was reflooded during isotope stage 5, and only some aragonite crystals precipitated on top of dolomite or low-Mg calcite. The interrelationships between tectonics, sea-level variations of different orders, and climatic changes thus had a profound impact on the diagenetic history of these reef systems. 相似文献