Nitrate sources and sinks in Elkhorn Slough,California: Results from long-term continuous in situ nitrate analyzers

Nitrate and water quality parameters (temperature, salinity, dissolved oxygen, turbidity, and depth) were measured continuously with in situ NO₃ analyzers and water quality sondes at two sites in Elkhorn Slough in Central California. The Main Channel site near the mouth of Elkhorn Slough was sampled from February to September 2001. Azevedo Pond, a shallow tidal pond bordering agricultural fields further inland, was sampled from December 1999 to July 2001. Nitrate concentrations were recorded hourly while salinity, temperature, depth, oxygen, and turbidity were recorded every 30 min. Nitrate concentrations at the Main Channel site ranged from 5 to 65 μM. The propagation of an internal wave carrying water from ≈100 m depth up the Monterey Submarine Canyon and into the lower section of Elkhorn Slough on every rising tide was a major source of nitrate, accounting for 80–90% of the nitrogen load during the dry summer period. Nitrate concentrations in Azevedo Pond ranged from 0–20 μM during the dry summer months. Nitrate in Azevedo Pond increased to over 450 μM during a heavy winter precipitation event, and interannual variability driven by differences in precipitation was observed. At both sites, tidal cycling was the dominant forcing, often changing nitrate concentrations by 5-fold or more within a few hours. Water volume flux estimates were combined with observed nitrate concentrations to obtain nitrate fluxes. Nitrate flux calculations indicated a loss of 4 mmol NO₃ m^?2 d^?1 for the entire Elkhorn Slough and 1 mmol NO₃ m^?2 d^?1 at Azevedo Pond. These results suggested that the waters of Elkhorn Slough were not a major source of nitrate to Monterey Bay but actually a nitrate sink during the dry season. The limited winter data at the Main Channel site suggest that nitrate was exported from Elkhorn Slough during the wet season. Export of ammonium or dissolved organic nitrogen, which we did not monitor, may balance some or all of the NO₃ flux.     

The influence of topography and land use on water quality of Xiangxi River in Three Gorges Reservoir region

A self-organizing map (SOM) was used to cluster the water quality data of Xiangxi River in the Three Gorges Reservoir region. The results showed that 81 sampling sites could be divided into several groups representing different land use types. The forest dominated region had low concentrations of most nutrient variables except COD, whereas the agricultural region had high concentrations of NO₃N, TN, Alkalinity, and Hardness. The sites downstream of an urban area were high in NH₃N, NO₂N, PO₄P and TP. Redundancy analysis was used to identify the individual effects of topography and land use on river water quality. The results revealed that the watershed factors accounted for 61.7% variations of water quality in the Xiangxi River. Specifically, topographical characteristics explained 26.0% variations of water quality, land use explained 10.2%, and topography and land use together explained 25.5%. More than 50% of the variation in most water quality variables was explained by watershed characteristics. However, water quality variables which are strongly influenced by urban and industrial point source pollution (NH₃N, NO₂N, PO₄P and TP) were not as well correlated with watershed characteristics.     

Temporal and spatial patterns in abundance and diversity of fish assemblages in Elkhorn Slough,California

Assemblages of ichthyofauna of shallow inshore habitats along Californía’s central coast are described in terms of species composition, abundance, and life-style categories. A total of 22,334 fishes from 65 species and 27 families was collected with otter trawls at six sites in the main channel and tidal creeks of Elkhorn Slough, a tidal embayment and seasonal estuary, and two nearshore ocean stations in Monterey Bay during 44 months between August 1974 and June 1980. Greater than 90% of the catch comprised 10 species. The four dominant species,Cymatogaster aggregata, Leptocottus armatus, Phanerodon furcatus, andEmbiotoca jacksoni, occurred during most or all seasons and were classified as residents or partial residents. Several abundant species were marine immigrants that seasonally use the slough as spawning and nursery grounds; this resulted in higher abundance and species richness during summer. Species collected during winter largely were slough residents. Species compsosition and richness varied with distance from the slough entrance. The ocean assemblage was most different, and its similarity to other stations decreased progressively with distance inland and into the tidal creeks. During our study, 5,074 fishes were collected by beach seine in Bennett Slough, a remote shallow marsh basin adjacent to the entrance of Elkhorn Slough. Species richness was relatively low and three euryhaline species accounted for >80% of the total catch. The species assemblage was most similar to those at the tidal creek and most shallow stations of Elkhorn Slough. Resident species numerically dominated assemblages in Bennett Slough and the most inland areas of Elkhorn Slough. The high relative abundance of marine-related fishes (classified as marine, marine immigrant, and partial resident), entering Elkhorn Slough early in life or as spawning adults indicates the importance of this habitat to nearshore fish assemblages.     

Spatial variability of soil properties in relation to land use and topography in a typical small watershed of the black soil region,northeastern China

Soil degradation resulted from unreasonable land use and erosion has been a serious problem in the black soil region of northeastern China. This paper seeks to understand the relationships between topsoil properties and topography and land use for land management targeting at improving soil quality in this region. A total of 292 soil samples and 81 volumetric rings were taken from a typical small watershed of the region in June 2005 for examining total carbon (TC), total nitrogen (TN), soil texture (classified into gravel, sand, silt, and clay), and bulk density (ρ _b), respectively. Spatial variability of these soil properties was evaluated with classical statistics and geostatistics methods. The results of classical statistics indicated that TC, TN, sand, silt, clay content, and ρ _b were moderate variables while gravel had great variability. Soil properties were mainly correlated to slope position, elevation and land types. Geostatistical analyses showed that the spatial autocorrelation for TC, TN, and silt was weak, strong for clay and moderate for and ρ _b sand, respectively. The spatial variations of soil properties are affected comprehensively by topographic factors, land use, erosion, and erosion control in this watershed. Past erosion, however, is the most important component to induce change of soil properties. In this small watershed, current soil and water conservation measures play an important role in controlling soil loss. But the restoration of soil properties was unsatisfactory. Comparing with untilled soil of this region, TC, TN, silt content are excessively low; whereas ρ _b, sand and clay content are excessively high; gravel appears at most sampling locations. It is necessary for improving soil properties to protect forest and grassland and change cultivation system of farmlands.     

Groundwater depletion and quality deterioration due to environmental impacts in Maheshwaram watershed of R.R. district,AP (India)

Maheshwaram watershed is situated in Ranga Reddy district of Andhra Pradesh at a distance of about 30 km south of Hyderabad, capital of Andhra Pradesh. The watershed has an area of 60 km² and has hard rock aquifers with semi-arid climate. The study area has been expanding at a fast pace and now has the distinction of being one of the fastest growing urban centers facing the problem of groundwater depletion and quality deterioration due to the absence of perennial source of surface water and also due to over exploitation. Human activities involving industrial and agricultural development and the inadequate management of land and water resources have, directly or indirectly resulted in the degradation of environment viz. water and soil. In the present study chemical analysis of groundwater samples of the study area, collected during pre- and post-monsoon seasons of 2007–2008 has been carried out. The analyzed data are utilized to characterize the hydro chemical process dominant in the area. Various classification methods such as Piper, Back and Hanshaw, Wilcox, USA. Salinity Laboratory are employed to critically study the geochemical characteristics of groundwater of the study area. Finally, principal component analysis (PCA) is also employed to the chemical variables of groundwater to characterize the hydro chemical process that is dominant in the area. In the analysis four principal components emerged as significant contributors to the groundwater quality. The total contribution of these four components is about 85–87%. The contribution of the first component is about 49–50% and has significant positive loadings of Ca²⁺, Mg²⁺, Na⁺, and Cl⁻ ions. The second, third, and fourth principal components have significant positive loadings of F⁻, NO₃ ⁻, SO₄ ²⁺, and HCO₃ ⁻ ions.     

Chemistry of perennial springs of Bhetagad watershed: a case study from central Himalayas,India

A field study was conducted to assess the location and the seasonal variation in physicochemical parameters of springs (outlets of underground water channels) of Bhetagad watershed of Uttaranchal hills, India. Traditionally, spring water is used for multiple purposes in this region. The average population density of the watershed is 366 persons km^?2, distributed within an altitudinal range of 1,090–2,060 m a.m.s.l. and 23.52 km² area. Twelve springs, in three different land uses e.g. pine forest, rainfed agriculture near settlements and irrigated agriculture near settlements were monitored in the winter (January), summer (June) and monsoon (August) during 1998 and 1999. The water quality parameters selected, in the present study are pH, EC, TDS, DO, free CO₂, total hardness, Ca²⁺, Mg²⁺, CO₃^2?, HCO₃^?, Cl^-, NO₃^? and SO₄^2? ions. Some springs in pine forests exhibit lower pH values than the permissible limit. Springs, with their location in agriculture and settlement, show slightly higher EC than the springs in pine forests. All the springs, near the irrigated agricultural land recorded higher nitrate ion concentration.     

Tidal and Nontidal Oscillations in Elkhorn Slough,CA

Elkhorn Slough is a shallow, tidally forced estuary that is directly connected to Monterey Bay. It is ebb-dominated and, due to continued erosion, the tidal prism has tripled over the past 40 years. Water level measurements at four locations are used to examine tidal and nontidal oscillations in Elkhorn Slough. The tidal response of Elkhorn Slough differs from that of Monterey Bay primarily due to the generation of a relatively large number of shallow-water tidal constituents that are due to tidal distortion caused by friction along the bottom and lateral boundaries, intertidal storage, and nonlinear advection. The shallow-water constituents range from 3 to almost 15 cycles per day (cpd) and include a rich variety of overtides and compound tides, whose amplitudes generally increase toward the head of the slough. The tidal harmonics are seasonally dependent, with lower amplitudes during the fall and winter and higher amplitudes in summer. The tidal constituents were examined using two types of spectral decomposition, the conventional power spectrum and the more recent Hilbert spectrum. Unlike the power spectrum, the Hilbert spectrum does not reveal any harmonic structure in the data. Energy associated with tidal distortion in this case appears to be broadly distributed across the spectral continuum. At least four nontidal oscillations occur in Elkhorn Slough with frequencies of 26.0, 39.7, 52.7, and 66.9 cpd. The Hilbert spectrum reveals maxima at 26, 39.7, and 66.9 cpd, but not at 52.7 cpd, suggesting that it is harmonically related to the oscillation at 26.0 cpd. The nontidal oscillations fall into the range of frequencies associated with the natural oscillations of Monterey Bay. However, evolutionary power spectra indicate that they appear to be permanent features of the system and thus are not necessarily consistent with seiche-like oscillations that are often transient and subject to damping. These oscillations could be caused by several factors including edge waves along the coast of Monterey Bay, long-period surface waves of atmospheric origin that enter the bay from offshore, or breaking internal waves in and around the Monterey Submarine Canyon. In conclusion, detailed hydrodynamic models are needed to provide a better understanding of how tidal harmonics are generated and preserved in Elkhorn Slough, and to determine the origin of the natural oscillations in Monterey Bay.     

Effects of Hypoxia on Fish Survival and Oyster Growth in a Highly Eutrophic Estuary

Human land use activities around estuaries can result in high levels of eutrophication. At Elkhorn Slough estuary, a highly eutrophic California estuary, we investigated the effects of impaired water quality on two stress-tolerant estuarine species, a common fish, the staghorn sculpin, Leptocottus armatus and a foundational invertebrate, the Olympia oyster, Ostrea lurida. We caged the two indicator species at six wetlands with different levels of water quality impairment, four of which had restricted tidal flow. We also recorded water quality parameters simultaneously at all sites using YSI sondes, and sampled nutrients and chlorophyll-a monthly, building on the National Estuarine Research Reserve System-wide Monitoring Program. We found that the monitored environmental variables predicted ecological responses by the indicator species. In particular, we found that the duration and severity of hypoxia were negatively correlated with fish survival and oyster growth. Further, our results corroborate previous studies that artificial tidal restriction leads to increased hypoxia stress. We conclude that large diurnal fluctuations in dissolved oxygen and extended nighttime hypoxia can have lethal and sub-lethal effects even on stress-tolerant organisms in the estuary. While laboratory experiments have often shown such effects, it is relatively rare to demonstrate negative effects of oxygen variation with in situ experiments, which provide stakeholders with concrete evidence for impaired water quality at local wetlands. Tidally restricted sites, which experience the largest fluctuations in dissolved oxygen and longest periods of hypoxia, harbor conditions harmful to vertebrates and invertebrates in the estuary. Reversing the anthropogenically induced low oxygen levels, by restoring more natural tidal exchange and by decreasing agricultural runoff, could improve the survival and growth of important estuarine organisms.     

Prospective scenarios for water quality and ecological status in Lake Sete Cidades (Portugal): The integration of mathematical modelling in decision processes

The design of alternative strategies for water and ecological quality protection at the Lake Verde of Sete Cidades should be coupled with the assessment of future trophic states. Therefore, a mathematical model was developed to make prospective scenarios to reduce the risk of environmental degradation of the lake, and a modified Psenner scheme was used to characterize P distribution in the sediments. The model was able to describe thermal stratification, nutrient cycling (P, NH₄ and NO₃), dissolved O₂, and phytoplankton dynamics in the water column and adjacent sediment layers. Internal P recycling, resulting from thermal stratification and sediment anoxia, was identified as the main cause for the increase of P concentration in the hypolimnion followed by slow transfer to the epilimnion (about 20 μg/L annual average). Cyanobacteria blooms during spring were explained by the availability of P and increased water temperature verified during this season. The most sensitive model parameter was sediment porosity. This parameter has a direct effect in dissolved O₂ and P profiles and also in phytoplankton biomass. Finally, different water quality restoration scenarios were identified and their effectiveness assessed. Without the adoption of remediation measures (scenario control), Lake Verde water quality would deteriorate with annual average concentrations of total P and phytoplankton biomass (dry matter) reaching 34 μg/L and 2 mg/L, respectively, after 10 years of simulation. The reduction of P loads (scenario PORAL) into the lake would improve water quality comparatively to the scenario control, reducing the annual average concentrations of total P from 34 μg/L to 26 μg/L and of phytoplankton from 2 mg/L down to 1.4 mg/L after 10 years of simulation. In scenario sediments, corresponding to a decrease in the organic content of the sediments, a reduction in the concentrations of total P and phytoplankton is expected in the first two years of simulation, but this effect, would be attenuated throughout the years due to organic matter sedimentation. The best strategy is obtained by combining external and internal measures for P remediation. Finally, it is recommended that the model be used to integrate the results of water quality monitoring and watershed management plans.     

Effects of Local Watershed Land Use on Water Quality in Mid-Atlantic Coastal Bays and Subestuaries of the Chesapeake Bay

Nutrient inputs have degraded estuaries worldwide. We investigated the sources and effects of nutrient inputs by comparing water quality at shallow (< 2m deep) nearshore (within 200 m) locations in a total of 49 Chesapeake subestuaries and Mid-Atlantic coastal bays with differing local watershed land use. During July–October, concentrations of total nitrogen (TN), dissolved ammonium, dissolved inorganic N (DIN), and chlorophyll a were positively correlated with the percentages of cropland and developed land in the local watersheds. TN, DIN, and nitrate were positively correlated with the ratio of watershed area to subestuary area. Total phosphorus (TP) and dissolved phosphate increased with cropland but were not affected by developed land. The relationships among N, P, chlorophyll a, and land use suggest N limitation of chlorophyll a production from July–October. We compared our measurements inside the subestuaries to measurements by the Chesapeake Bay Program in adjacent estuarine waters outside the subestuaries. TP and dissolved inorganic P concentrations inside the subestuaries correlated with concentrations outside the subestuaries. However, water quality inside the subestuaries generally differed from that in adjacent estuarine waters. The concentration of nitrate was lower inside the subestuaries, while the concentrations of other forms of N, TP, and chlorophyll a were higher. This suggests that shallow nearshore waters inside the subestuaries import nitrate while exporting other forms of N as well as TP and chlorophyll a. The importance of local land use and the distinct biogeochemistry of shallow waters should be considered in managing coastal systems.     

Nitrate pollution of ground waters from shallow basaltic aquifers,Deccan Trap Hydrologic Province,India

Analyses of groundwater samples collected from several locations in a small watershed of the Deccan Trap Hydrologic Province, indicated anomalously higher values of nitrate than the background. However, the NO₃ concentrations in water from dug wells under pastureland where the subsurface material consisted of stony waste were minimum. The maximum values were reported for water from dug wells where the principal land use was agricultural. Lowering of NO₃ values under shallow water-table conditions suggests denitrification. Higher concentrations of nitrate determined for samples collected from the wells with a deeper water-table indicate that denitrification process is inactive. The high values of nitrate coinciding with agricultural land use indicate fertilizers as the main source of nitrate pollution of ground-water. Decrease in Cl/NO₃ ratio for agricultural land use confirms this inference.     

基于WEAP模型的西苕溪流域水质安全保障方案

针对西苕溪流域水质安全问题,基于WEAP建模平台,构建了西苕溪流域水资源评估与规划模型。在模型验证基础上,分析了西苕溪流域2001～2020年河道水功能目标满足度及水供需关系,识别了流域水资源利用存在的问题,并探讨了水源地和中下游区水质安全保障措施及其改善水质的效用,在此基础上提出了西苕溪流域水质安全保障方案。研究表明:TN是影响水源地供水安全的限制性因素,TN、TP是影响河道水功能的重要指标。通过综合实施废水处理厂、节水型设备、退耕还林等水资源管理措施能起到较好地削减TN产出的效果,水源地河道TN浓度降低,基本上能保证全年实现河道Ⅲ类水功能目标,中下游河道TP、TN浓度亦能达到Ⅲ类水功能要求。     

A combined statistical approach for evaluation of the effects of land use,agricultural and urban activities on stream water chemistry in small tile-drained catchments of south Bohemia,Czech Republic

This work evaluates the changes of nitrate-nitrogen (NO₃-N), ammonium-nitrogen (NH₄-N), total phosphorus (P) and chemical oxygen demand (COD) concentrations in stream waters as related to the land use/land cover (LULC) alterations within eight small (5–39 km²) tile-drained catchments in the southern part of The Czech Republic in the period 1993–2010, when massive grassing of arable land took place. The robust tools of seasonal Mann–Kendall trend test and LOcally WEighted Scatterplot Smoothing methods were employed to reveal trends of the monitored parameters with adjustment to hydrology. Using principal component analysis and multiple regressions, statistically significant factors with highest impacts on the assessed water quality parameters were identified. Besides indicators of LULC changes in the catchments and their various zones, information of built tile drainage systems were used along with factors reflecting point pollution sources such as the population number, sewerage type and proximity to a watercourse, effectiveness of wastewater treatment, and number of livestock units. The change in LULC was essential only for NO₃-N concentrations, when grassing of arable land, presence of water ponds, areas of permanent cultures and also areas of drained land explained up to 90.6 % NO₃-N variability and nitrate-nitrogen concentrations showed a significantly decreasing trend in all monitored catchments during the evaluated period. LULC changes within infiltration vulnerable zones were discovered as less important for the assessed water quality parameters compared to LULC changes in the whole catchment area. However, for NH₄-N, P and COD, the results did not enable a definite quantification of the effects of LULC changes. The influence of non-point pollution sources on these parameters was revealed as uncertain and was heavily overshadowed by point sources, in particular by wastewater management, and livestock numbers, although the proportion of arable land in tile drainage subcatchments was discovered fundamental in case of the COD. The increasing numbers of livestock, population, and changes in sewage treatment led in some catchments to significant worsening of water quality. Achieved findings may be critical for supporting water quality policy and management decisions.     

Aluminium in Lake Cuicocha,Ecuador, an Andean Crater Lake: Filterable,Gelatinous and Microcrystal Al Occurrence

In Lake Cuicocha watershed, a young caldera lake, soils consist of volcanic deposits with a high SiO₂ and Al₂O₃ content; these andisols are in an early stage of development; and in drainage water from the watershed, aluminium concentrations reach 15.0 μmol L⁻¹. Total aluminium concentrations in Lake Cuicocha water raises up to 7.2 μmol L⁻¹, with nearly 70% occurring as filterable Al at neutral to weak alkaline conditions. Al polymerization to gelatinous aggregates of a few hundred micrometres in diameter as well as the occurrence of Al microcrystals like gibbsite as an ageing product of gelatinous Al polymers was noted in the lake water. The gelatinous Al leads to the formation of larger aggregates resulting in flocs of bacteria, algae, microorganisms and detritus.     

Fortnightly Tidal Modulations Affect Net Community Production in a Mesotidal Estuary

Optical in situ chemical sensors enable sampling intervals and durations that rival acoustic techniques used for measuring currents. Coupling these high-frequency biogeochemical and physical measurements in estuaries to address ecosystem-scale questions, however, is still comparatively novel. This study investigated how tides affect ecosystem metabolism in a mesotidal estuary in central California (Elkhorn Slough). Dissolved oxygen measurements were used to estimate the terms in a control volume budget for a tidal creek/marsh complex at tidal timescales over several weeks. Respiration rates were 1.6 to 7.3 g O₂ m^?2 day^?1; net community production approached 20 g O₂ m^?2 day^?1. We found that aquatic NCP integrated throughout the creek complex varied significantly over the spring-neap cycle. The intertidal contribution to aquatic metabolism was net heterotrophic during spring tides and generally in balance during neap tides because spring-tide marsh inundation was limited to nighttime, and therefore the marsh could not contribute any primary production to the water column. At the estuary scale, the fortnightly export of oxygen from the main channel to the intertidal was largely balanced by an advective flux up-estuary.     

Assessment of groundwater quality for drinking and irrigation purposes: a case study of Peddavanka watershed, Anantapur District, Andhra Pradesh, India

In India, the quantity and quality of water available for irrigation is variable from place to place. Assessment of water quality has been carried out to determine the sources of dissolved ions in groundwater. Quality of groundwater in a 398 km² Peddavanka watershed of a semi-arid region of south India is evaluated for its suitability for drinking and irrigation purposes. The middle Proterozoic Cuddapah Supergroup and Kurnool Group of rocks underlie most of the watershed. The main lithologic units consist chiefly of quartzite, limestone, and shale. Seventy-six water samples were collected from open-wells and bore-holes. Water samples were collected representative of the post-monsoon (winter) and pre-monsoon (summer). The quality assessment is made through the estimation of Ca²⁺, Mg²⁺, Na⁺, K⁺, Cl⁻, SO₄²⁻, CO₃²⁻, HCO₃⁻, total hardness as CaCO₃, TDS, EC, and pH. Based on these analyses, parameters like sodium adsorption ratio, % sodium, residual sodium carbonate, non-carbonate hardness, potential salinity, Kelley’s ratio, magnesium ratio, index of base exchange and permeability index were calculated. According to Gibbs‘ ratio samples in both seasons fall in the rock dominance field. The overall quality of waters in the study area in post-monsoon season is high for all constituents ruling out pollution from extraneous sources.     

The role of hydrologic regimes on dissolved organic carbon composition in an agricultural watershed

Willow Slough, a seasonally irrigated agricultural watershed in the Sacramento River valley, California, was sampled weekly in 2006 in order to investigate seasonal concentrations and compositions of dissolved organic carbon (DOC). Average DOC concentrations nearly doubled from winter baseflow (2.75 mg L⁻¹) to summer irrigation (5.14 mg L⁻¹), while a concomitant increase in carbon-normalized vanillyl phenols (0.11 mg 100 mg OC⁻¹ increasing to 0.31 mg 100 mg OC⁻¹, on average) indicates that this additional carbon is likely vascular plant-derived. A strong linear relationship between lignin concentration and total suspended sediments (r² = 0.79) demonstrates that agricultural management practices that mobilize sediments will likely have a direct and significant impact on DOC composition. The original source of vascular plant-derived DOC to Willow Slough appears to be the same throughout the year as evidenced by similar syringyl to vanillyl and cinnamyl to vanillyl ratios. However, differing diagenetic pathways during winter baseflow as compared to the rest of the year are evident in acid to aldehyde ratios of both vanillyl and syringyl phenols. The chromophoric dissolved organic matter (CDOM) absorption coefficient at 350 nm showed a strong correlation with lignin concentration (r² = 0.83). Other CDOM measurements related to aromaticity and molecular weight also showed correlations with carbon-normalized yields (e.g. specific UV absorbance at 254 nm (r² = 0.57) and spectral slope (r² = 0.54)). Our overall findings suggest that irrigated agricultural watersheds like Willow Slough can potentially have a significant impact on mainstem DOC concentration and composition when scaled to the entire watershed of the main tributary.     

Sources of nutrient inputs to the Patuxent River estuary

We quantified annual nutrient inputs to the Patuxent River estuary from point and nonpoint sources and from direct atmospheric deposition. We also compared nonpoint source (NPS) discharges from Piedmont and Coastal Plain regions and from agricultural and developed lands. Using continuous automated-sampling, we measured discharges of water, nitrogen, phosphorus, organic carbon (C), and suspended solids from a total of 23 watersheds selected to represent various proportions of developed land and cropland in the Patuxent River basin and the neighboring Rhode River basin. The sampling period spanned two years that differed in annual precipitation by a factor of 1.7. Water discharge from the watershed to the Patuxent River estuary was 3.4 times higher in the wet year than in the dry year. Annual water discharges from the study watersheds increased as the proportion of developed land increased. As the proportion of cropland increased, there were increases in the annual flow-weighted mean concentrations of nitrate (NO₃ ^?), total nitrogen (TN), dissolved silicate (Si), total phosphate (TPO₄ ^3?), total organic phosphorus (TOP), total P (TP), and total suspended solids (TSS) in NPS discharges. The effect of cropland on the concentrations of NO₃ ^? and TN was stronger for Piedmont watersheds than for Coastal Plain watersheds. As the proportion of developed land increased, there were increases in annual mean concentrations of NO₃ ^?, total ammonium (TNH₄ ⁺), total organic N (TON), TN, total organic C (TOC), TPO₄ ^3?, TOP, TP, and TSS and decreases in concentrations of Si. Annual mean concentrations of TON, TOC, forms of P, and TSS were highest in the wet year. Annual mean concentrations of NO₃ ^?, TNH₄ ⁺, TN, and Si did not differ significantly between years. We directly measured NPS discharges from about half of the Patuxent River basin and estimated discharges from the other half of the basin using statistical models that related annual water flow and material concentrations to land cover and physiographic province. We compared NPS discharges to public data on point source (PS) discharges. We estimated direct atmospheric deposition of forms of N, P, and organic C to the Patuxent River estuary based on analysis of bulk deposition near the Rhode River. During the wet year, most of the total terrestrial and atmospheric inputs of forms of N and P came from NPS discharges. During the dry year, 53% of the TNH₄ ⁺ input was from atmospheric deposition and 58% of the NO₃ ^? input was from PS discharges; NPS and PS discharges were about equally important in the total inputs of TN and TPO₄ ^3?. During the entire 2-yr period, the Coastal Plain portion of the Patuxent basin delivered about 80% of the NPS water discharges to the estuary and delivered similar proportions of the NPS TNH₄ ⁺, TN, TOP, and TSS. The Coastal Plain delivered greater proportions of the NPS TON, TOC, Si, and TP (89%, 90%, 93%, and 95%, respectively) than of water, and supplied nearly all of the NPS TPO₄ ^3? (99%). The Piedmont delivered 33% of the NPS NO₃ ^? while delivering only 20% of the NPS water to the stuary. We used statistical models to infer the percentages of NPS discharges supplied by croplands, developed lands, and other lands. Although cropland covers only 10% of the Patuxent River basin, it was the most important source of most materials in NPS discharge, supplying about 84% of the total NPS discharge of NO₃ ^?; about three quarters of the TPO₄ ^3?, TOP, TP, and TSS; and about half of the TNH₄ ⁺ and TN. Compared to developed land, cropland supplied a significantly higher percentage of the NPS discharges of NO₃ ^?, TN, TPO₄ ^3?, TOP, TP, and TSS, despite the fact development land covered 12% of the basin.     

Continuous Monitoring Reveals Drivers of Dissolved Oxygen Variability in a Small California Estuary

Estuarine ecosystem diversity and function can be degraded by low oxygen concentrations. Understanding the spatial and temporal patterns of dissolved oxygen (DO) variation and the factors that predict decreases in DO is thus essential to inform estuarine management. We investigated DO variability and its drivers in Elkhorn Slough, a shallow, well-mixed estuary affected by high nutrient loading and with serious eutrophication problems. Long-term (2001–2012), high-resolution (15 min) time series of DO, water level, winds, and solar radiation from two fully tidal sites in the estuary showed that hypoxia events close to the bottom are common in the summer at the more upstream estuarine station. These events can occur in any lunar phase (spring to neap), at any time of the day, and both on sunny or cloudy days. They are, however, short-lived (lasting in average 40 min) and mainly driven by momentary low turbulent diffusion around slack tides (both at high and low water). Tidal advective transport explains up to 52.1% of the daily DO variability, and the water volume (or DO reservoir) contained in the estuary was not sufficient to avoid hypoxia in the estuary. Solar radiation was responsible for a positively correlated DO daily cycle but caused a decreased in the averaged DO in the summer at the inner station. Wind-driven upwelling reduced the average DO at the more oceanic station during spring. The approach we employed, using robust techniques to remove suspect data due to sensor drift combined with an array of statistical techniques, including spectral, harmonic, and coherence spectrum analysis, can serve as a model for analyses of long-term water quality datasets in other systems. Investigations such as ours can inform coastal management by identifying key drivers of hypoxia in estuaries.     

Impervious surface impact on water quality in the process of rapid urbanization in Shenzhen, China

Urbanization has accelerated rapidly over the last century, which has caused surfaces in natural ecosystems to shift to impervious surfaces. As a result, urban watershed ecosystems show altered physical, chemical and ecological process. As an important part of watershed management, urbanization has become one of the key issues involved in the deterioration of water quality. Impervious surface area (ISA) has been recognized as a key indicator of the effects of non-point runoff and water quality within a particular watershed. Numerous case studies have been conducted to investigate the relationship between urbanization and water quality in different study areas. However, there is still a lack of understanding regarding quantitative analysis of the threshold between urbanization and water quality indicators. This study was conducted to improve the understanding of how to quantify a threshold between urbanization and water quality, taking the rapid urbanization zone of Shenzhen, China as a case study. To accomplish this, ISA was extracted from the Landsat? image using a linear spectral mixture method to quantify the urbanization. The relationship between water quality indicators and ISA was then analyzed by nonlinear regression, and the threshold between ISA and the chemical indicators of water quality was investigated using the statistical segment approach method. The results indicate that the water quality indicators and ISA are significantly correlated, and that, with the exception of Zn, Pb, and CN, the water quality indicators had R ² values greater than 0.45. Furthermore, with the exception of Zn, F^?, Pb and oils, water quality indicators were found to have an ISA threshold of 36.9–52.9 %, indicating that it is important to control the ISA below 36.9 % in urbanization watersheds to enable effective urban watershed management.