The Sr, Nd and O isotopic studies of the 1991–1995 eruption at Unzen, Japan

The magma generation at Unzen volcano may be considered as the product of crustal material mixed with mantle magma accompanied by fractional crystallization (AFC). The magma in the Unzen volcano is estimated to consist of about 50–80% of residual magma (F) and about 30–70% assimilated crustal material (A) relative to the original magma. Concerning the 1991–1995 eruption, it is estimated that the magma formed as the result of mixing of about 50–60% crustal material and about 55–65% of residual magma. An alternative magma eruption model for the 1991–1995 eruption is proposed here. In the early stage, the isotopic characteristics of 1991 eruption are defined by AFC process in the deeper magma chamber. Later, the magma ascended through the conduit and quiescently stayed for a long time in a shallow reservoir before eruption. The minerals continuously crystallized as phenocrysts especially at the chilled top and outer margin in the shallow chamber. The crystallized phenocryst mush was reworked into the central part of the magma chamber by means of magma convection and rapid magma ascent. Therefore, the reaction between phenocrysts and melt occurs only in internal chemical disequilibrium in the magma chamber. In contrast, the isotopic compositions of the original magma shall be little influenced by the above processes throughout its eruptive history. The 1991–1995 eruptive rocks of the Unzen volcano show their characteristics in Sr and Nd isotopic values independent of their two previous eruptions. However, the isotopic values of early eruptive product could represent the original magma value. This result also supports the previous work of Chen et al. (1993) [Chen, C.H., DePaolo, D.J., Nakada, S., Shieh, Y.N., 1993. Relationship between eruption volume and neodymium isotopic composition at Unzen volcano. Nature 362, 831–834], that suggested the Nd of early or precursory eruptive products could be a qualitative indicator of the maximum size of a continuing or impending eruption.     

Magnetic petrology of the 1991–1995 dacite lava of Unzen volcano,Japan: Degree of oxidation and implications for the growth of lava domes

To understand the oxidation state and process of oxidation of lava domes, we carried out magnetic petrological analyses of lava samples obtained from domes and block-and-ash-flow deposits associated with the 1991–1995 eruption of Unzen volcano, Japan. As a result, we recognize three different types of magnetic petrology, each related to deuteric high-temperature oxidation during initial cooling. Type A oxides are characterized by homogenous titanomagnetite and titanohematite, indicating a low oxidation state and high titanomagnetite concentrations. Type B oxides are weakly exsolved and contain titanohematite laths and rutile lenses, indicating a higher oxidation state. Type C oxides, which represent the highest oxidation state, are completely exsolved and composed of Ti-poor titanomagnetite, titanohematite, rutile, and pseudobrookite, indicating high hematite concentrations. Some grains in Types A and B show indications of reduction, which was related to interaction with volcanic gases subsequent to high-temperature oxidation. In terms of geological occurrence, the oxidation processes probably differed for endogenous and exogenous domes. Endogenous dome lavas are oxidized concentrically and are classified into the three types according to their location within the dome: samples from the surface are strongly oxidized and classified as Type C, while the inner part is unoxidized and classified as Type A. Exogenous dome lavas are unoxidized and assigned to Type A. Some samples show signs of reduction, which may have occurred around fumaroles. We propose that location within the dome and the process of dome growth are the factors that control oxidation.     

Overview of the 1990–1995 eruption at Unzen Volcano

Following 198 years of dormancy, a small phreatic eruption started at the summit of Unzen Volcano (Mt. Fugen) in November 1990. A swarm of volcano-tectonic (VT) earthquakes had begun below the western flank of the volcano a year before this eruption, and isolated tremor occurred below the summit shortly before it. The focus of VT events had migrated eastward to the summit and became shallower. Following a period of phreatic activity, phreatomagmatic eruptions began in February 1991, became larger with time, and developed into a dacite dome eruption in May 1991 that lasted approximately 4 years. The emergence of the dome followed inflation, demagnetization and a swarm of high-frequency (HF) earthquakes in the crater area. After the dome appeared, activity of the VT earthquakes and the summit HF events was replaced largely by low-frequency (LF) earthquakes. Magma was discharged nearly continuously through the period of dome growth, and the rate decreased roughly with time. The lava dome grew in an unstable form on the shoulder of Mt. Fugen, with repeating partial collapses. The growth was exogenous when the lava effusion rate was high, and endogenous when low. A total of 13 lobes grew as a result of exogenous growth. Vigorous swarms of LF earthquakes occurred just prior to each lobe extrusion. Endogenous growth was accompanied by strong deformation of the crater floor and HF and LF earthquakes. By repeated exogenous and endogenous growth, a large dome was formed over the crater. Pyroclastic flows frequently descended to the northeast, east, and southeast, and their deposits extensively covered the eastern slope and flank of Mt. Fugen. Major pyroclastic flows took place when the lava effusion rate was high. Small vulcanian explosions were limited in the initial stage of dome growth. One of them occurred following collapse of the dome. The total volume of magma erupted was 2.1×10⁸ m³ (dense-rock-equivalent); about a half of this volume remained as a lava dome at the summit (1.2 km long, 0.8 km wide and 230–540 m high). The eruption finished with extrusion of a spine at the endogenous dome top. Several monitoring results convinced us that the eruption had come to an end: the minimal levels of both seismicity and rockfalls, no discharge of magma, the minimal SO₂ flux, and cessation of subsidence of the western flank of the volcano. The dome started slow deformation and cooling after the halt of magma effusion in February 1995.     

Generation of block and ash flows during the 1990–1995 eruption of Unzen Volcano, Japan

Processes generating block and ash flows by gravitational dome collapse (Merapi-type pyroclastic flow) were observed in detail during the 1990–1995 eruption of Unzen volcano, Japan. Two different types were identified by analysis of video records and observations during helicopter flights. Most of the block and ash flows erupted during the 1991–1993 exogenous dome growth stage initially involved crack propagation due to cooling and flowage of the dome lava lobes. The mass around the crack became unstable, locally decreasing in tensile strength. Finally, a slab separated from the lobe front, fragmented progressively from the base to the top within a few seconds, and became a block and ash flow. Rock falls immediately followed, in response to local instability of the lobe front. Clasts in these rock falls fragmented and merged with the preceding flow. In contrast, block and ash flows during the endogenous dome growth stage in 1994 were generated due to local bulge of the dome. Unstable lava blocks collapsed and subsequently fragmented to produce block and ash flows.     

Petrology and Fe–Ti oxide reequilibration of the 1991 Mount Unzen mixed magma

A dacitic magma (64.5 wt.% SiO₂), a mixture of phenocryst-rich rhyodacite and an aphyric mafic magma, was erupted during the recent 1991–1995 Mount Unzen eruptive cycle. The experimental and analytical results of this study reveal additional details about conditions in the premixing and postmixing magmas, and the nature of the mixing process. The preeruption rhyodacitic magma was at a temperature of 790±20°C according to Fe–Ti oxide phenocryst cores, and at a depth of 6 to 7 km (160 MPa) according to Al-in-hornblende geobarometry. The mafic magma that mixed with the rhyodacite is found as andesitic (54 to 62 wt.% SiO₂) enclaves in the erupted magma and was essentially aphyric when intruded. Phase equilibria indicate that an aphyric andesite at 160 MPa is >1030°C (H₂O-saturated) and possibly as high as 1130°C (2 wt.% H₂O). The composition of the rhyodacite which was mixed with the andesite is estimated to lie between 67 and 69 wt.% SiO₂. Using these compositions and temperatures, the temperature of the Unzen magma after mixing is estimated to be at least 850° to 870°C. The groundmass Fe–Ti oxide microphenocrysts and those in pargasite-bearing reaction zones around biotite phenocrysts both give 890±20°C temperatures; the oxide–oxide contacts give temperatures of 910±20°C. The 900±30°C postmixing temperatures are consistent with phase-equilibria experiments which show that the magma was not above 930°C at 160 MPa. Our Fe–Ti oxide reequilibration experiments suggest that the mixing of the two magmas began within a few weeks of the eruption, which is a shorter time than is calculated using available diffusion data. There is also evidence that some mixing took place much closer to the time of extrusion based on the presence of unrimmed biotite phenocrysts in the magma.     

Petrologic investigations of the 1995 and 1996 eruptions of Ruapehu volcano, New Zealand: formation of discrete and small magma pockets and their intermittent discharge

 Ruapehu volcano erupted intermittently between September and November 1995, and June and July 1996, producing juvenile andesitic scoria and bombs. The volcanic activity was characterized by small, sequential phreatomagmatic and strombolian eruptions. The petrography and geochemistry of dated samples from 1995 (initial magmatic eruption of 18 September 1995, and two larger events on 23 September and 11 October), and from 1996 (initial and larger eruptions on 17–18 June) suggest that episodes of magma mixing occurred in separate magma pockets within the upper part of the magma plumbing system, producing juvenile andesitic magma by mixing between relatively high (1000–1200  °C)- and low (∼1000  °C)- temperature (T) end members. Oscillatory zoning in pyroxene phenocrysts suggests that repeated mixing events occurred prior to and during the 1995 and 1996 eruptions. Although the 1995 and 1996 andesitic magmas are products of similar mixing processes, they display chronological variations in phenocryst clinopyroxene, matrix glass, and whole-rock compositions. A comparison of the chemistry of magnesian clinopyroxene in the four tephras indicates that, from 18 September through June 1996, the tephras were derived from at least two discrete high-temperature (high-T) batches of magma. Crystals of magnesian clinopyroxene in the 23 September and 11 October tephras appear to be derived from different high-T magma batches. Whole-rock and matrix-glass compositions of all tephras are consistent with their derivation from distinct mixed melts. We propose that, prior to 1995 there was a shallow low-temperature (low-T) magma storage system comprising crystal-rich mush and remnant magma from preceding eruptive episodes. Crystal clots and gabbroic inclusions in the tephras attest to the existence of relict crystal mush. At least two discrete high-T magmas were then repeatedly injected into the mush zone, forming discrete and mixed magma pockets within the shallow system. The intermittent 1995 and 1996 eruptions sequentially tapped these magma pockets. Received: 1 April 1998 / Accepted: 22 December 1998     

Radionuclides and sulfur content in Mount Etna plume in 1983–1995: new constraints on the magma feeding system

Radionuclide activities (²¹⁰Pb, ²¹⁰Bi, ²¹⁰Po) were investigated in Mount Etna plume from 1983 to 1995. At SE crater the long-term observation (12 years) of the ²¹⁰Po/²¹⁰Pb ratio shows that it can behave as a degassing vent not directly related to the main magma reservoir depending on the magma level inside the volcano. Since 1992, the simultaneous determination of radionuclides and sulfur in the main plume results in new constraints on the degassing model of Lambert et al. (Earth Planet. Sci. Lett., 76 (1986) 185). The ²¹⁰Po/SO₂ and ²¹⁰Pb/SO₂ ratios enable us to identify two sources of ²¹⁰Po in the plume: one is magmatic, correlated with SO₂, the other one is an additional component issued from the decay of ²¹⁰Pb in the shallow degassing cell, and depends directly on the residence time of the gases before their emission. Estimations of the volume of degassing magma, the residence time of the gases and the proportion of undegassed magma renewing the shallow degassing cell are given for the period 1992–1995. During the 1992 eruption, the rate of degassing magma volume is estimated to have been as high as 5×10⁶ m³/day, and the volume of the shallow degassing magma reservoir about 0.5 km³. In 1994 and 1995 the rate of non-erupted degassing magma volume was estimated to have been about 0.18 km³/year. During the entire 1983–1995 period, only 15–20% of the degassed magma was erupted.     

Some regularity in the process of re-awakening of andesite and dacite volcanoes: specific features of the 1982 El Chichón volcano,México reactivation

El Chichón volcano is an andesite stratovolcano in southern México. It erupted in March 1982, after about 550 years of quiescence. The 1982 eruption of El Chichón has not been followed by the growth of a lava dome within the newly formed crater. This is rather anomalous since the construction of a new dome after the destruction of an old one is a common process during the eruptions at andesite and dacite volcanoes. To discuss this anomalous aspect of the El Chichón eruption, some regularity in the process of re-awakening of dormant (here defined as a period of quiescence of more than 100 years) andesite and dacite volcanoes are studied based on the seismic activity recorded at the volcanoes Bezymianny, Mount St. Helens, El Chichón, Unzen, Pinatubo and Soufrière Hills. Three stages were identified in the re-awakening activity of these volcanoes: (1) preliminary seismic activity, leading up to the first phreatic explosion; (2) activity between the first and the largest explosions; (3) post-explosion dome-building process. The eruptions were divided into two groups: low-VEI (Volcanic Explosivity Index) and the long duration stage-1 events (Unzen, 1991 and Soufrière Hills volcano, 1995) and high-VEI and the short duration stage-1 events (Bezymianny, 1956; Mount St. Helens, 1980; El Chichón, 1982 and Pinatubo, 1992). The comparative analysis of the seismo-eruptive activity of two eruptions of the second group, the 1980 of Mt. St. Helens and the 1982 of El Chichón, produced an explanation the absence of new dome building during the 1982 eruption of El Chichón volcano. It may be explained in terms of the unusually rapid emission of gas and water from the magmatic and hydrothermal system beneath the volcano during a relatively short sequence of large explosions that could have sharply increased the viscosity of the magma making impossible its exit to the surface.     

Erratum to Compositional variations and magma mixing in the 1991 eruptions of Hudson volcano,Chile

The August 1991 eruptions of Hudson volcano produced ~2.7 km³ (dense rock equivalent, DRE) of basaltic to trachyandesitic pyroclastic deposits, making it one of the largest historical eruptions in South America. Phase 1 of the eruption (P1, April 8) involved both lava flows and a phreatomagmatic eruption from a fissure located in the NW corner of the caldera. The paroxysmal phase (P2) began several days later (April 12) with a Plinian-style eruption from a different vent 4 km to the south-southeast. Tephra from the 1991 eruption ranges in composition from basalt (phase 1) to trachyandesite (phase 2), with a distinct gap between the two erupted phases from 54–60 wt% SiO₂. A trend of decreasing SiO₂ is evident from the earliest part of the phase 2 eruption (unit A, 63–65 wt% SiO₂) to the end (unit D, 60–63 wt% SiO₂). Melt inclusion data and textures suggest that mixing occurred in magmas from both eruptive phases. The basaltic and trachyandesitic magmas can be genetically related through both magma mixing and fractional crystallization processes. A combination of observed phase assemblages, inferred water content, crystallinity, and geothermometry estimates suggest pre-eruptive storage of the phase 2 trachyandesite at pressures between ~50–100 megapascal (MPa) at 972 ± 26°C under water-saturated conditions (log fO₂ –10.33 (±0.2)). It is proposed that rising P1 basaltic magma intersected the lower part of the P2 magma storage region between 2 and 3 km depth. Subsequent mixing between the two magmas preferentially hybridized the lower part of the chamber. Basaltic magma continued advancing towards the surface as a dyke to eventually be erupted in the northwestern part of the Hudson caldera. The presence of tachylite in the P1 products suggests that some of the magma was stalled close to the surface (<0.5 km) prior to eruption. Seismicity related to magma movement and the P1 eruption, combined with chamber overpressure associated with basalt injection, may have created a pathway to the surface for the trachyandesite magma and subsequent P2 eruption at a different vent 4 km to the south-southeast. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

Chemical composition of fumarolic gases and spring discharges from El Chichòn volcano, Mexico: causes and implications of the changes detected over the period 1998–2000

Since the March–April 1982 eruption of El Chichòn volcano, intense hydrothermal activity has characterised the 1-km-wide summit crater. This mainly consists of mud and boiling pools, fumaroles, which are mainly located in the northwestern bank of the crater lake. During the period 1998–2000, hot springs and fumaroles discharging inside the crater and from the southeastern outer flank (Agua Caliente) were collected for chemical analyses. The observed chemical fluctuations suggest that the physico-chemical boundary conditions regulating the thermodynamic equilibria of the deep rock/fluid interactions have changed with time. The chemical composition of the lake water, characterised in the period 1983–1997 by high Na⁺, Cl⁻, Ca²⁺ and SO₄²⁻ contents, experienced a dramatic change in 1998–1999, turning from a Na⁺–Cl⁻- to a Ca²⁺–SO₄²⁻-rich composition. In June 2000, a relatively sharp increase in Na⁺ and Cl⁻ contents was observed. At the same time, SO₂/H₂S ratios and H₂ and CO contents in most gas discharges increased with respect to the previous two years of observations, suggesting either a new input of deep-seated fluids or local variations of the more surficial hydrothermal system. Migration of gas manifestations, enhanced number of emission spots and variations in both gas discharge flux and outlet temperatures of the main fluid manifestations were also recorded. The magmatic-hydrothermal system of El Chichòn is probably related to interaction processes between a deep magmatic source and a surficial cold aquifer; an important role may also be played by the interaction of the deep fluids with the volcanic rocks and the sedimentary (limestone and evaporites) basement. The chemical and physical changes recorded in 1998–2000 were possibly due to variations in the permeability of the conduit system feeding the fluid discharges at surface, as testified by the migration of gas and water emanations. Two different scenarios can be put forward for the volcanic evolution of El Chichòn: (1) build-up of an infra-crater dome that may imply a future eruption in terms of tens to hundreds of years; (2) minor phreatic–phreatomagmatic events whose prediction and timing is more difficult to constrain. This suggests that, unlike the diminished volcanic activity at El Chichòn after the 1982 paroxistic event, the volcano-hydrothermal fluid discharges need to be more constantly monitored with regular and more frequent geochemical sampling and, at the same time, a permanent network of seismic stations should be installed.     

Petrogenetic modeling of rock variety in the Khalkhab–Neshveh pluton,NW of Saveh,Iran

The Khalkhab–Neshveh (KN) pluton is a part of Urumieh–Dokhtar Magmatic Arc and was intruded into a covering of basalt and andesite of Eocene to early Miocene age. It is a medium to high‐K, metaluminous and I‐type pluton ranging in composition from quartz monzogabbro, through quartz monzodiorite, granodiorite, and granite. The KN rocks show subtle differentiation trends strongly controlled by clinopyroxene, plagioclase, hornblende, apatite, and titanite, where most major elements (except K₂O) are negatively correlated with SiO₂; and Al₂O₃, Na₂O, Sr, Eu, and Y define curvilinear trends. Considering three processes of magmatic differentiation including mixing and/or mingling between basaltic and dacitic magmas, gravitational fractional crystallization and in situ crystallization revealed that the latter is the most likely process for the evolution of KN magma. This is supported by the occurrence of all rock types at the same level, the lack of mafic enclaves in the granitoid rocks, the curvilinear trends of Na₂O, Sr, and Eu, and the constant ratios of (⁸⁷Sr/⁸⁶Sr)_i from quartz monzodiorite to granite (0.70475 and 0.70471, respectively). In situ crystallization took place via accumulation of plagioclase and clinopyroxene phenocrysts and concentration of these phases in the quartz monzogabbro and quartz monzodiorite at the margins of the intrusion at T ≥ 1050°C, and by filter pressing and fractionation of hornblende, plagioclase, and later biotite in the granitoids at T = ～880°C.     

Chemical evolution and volcanic activity of the active crater lake of Poás volcano, Costa Rica, 1993–1997

Concentrations of chloride and sulfate and pH in the hot crater lake (Laguna Caliente) at Poás volcano and in acid rain varied over the period 1993–1997. These parameters are related to changes in lake volume and temperature, and changes in summit seismicity and fumarole activity beneath the active crater. During this period, lake level increased from near zero to its highest level since 1953, lake temperature declined from a maximum value of 70°C to a minimum value of 25°C, and pH of the lake water increased from near zero to 1.8. In May 1993 when the lake was nearly dry, chloride and sulfate concentrations in the lake water reached 85,400 and 91,000 mg l⁻¹, respectively. Minimum concentrations of chloride and sulfate after the lake refilled to its maximum volume were 2630 and 4060 mg l⁻¹, respectively. Between January 1993 and May 1995, most fumarolic activity was focused through the bottom of the lake. After May 1995, fumarolic discharge through the bottom of the lake declined and reappeared outside the lake within the main crater area. The appearance of new fumaroles on the composite pyroclastic cone coincided with a dramatic decrease in type B seismicity after January 1996. Between May 1995 and December 1997, enhanced periods of type A seismicity and episodes of harmonic tremor were associated with an increase in the number of fumaroles and the intensity of degassing on the composite pyroclastic cone adjacent to the crater lake. Increases in summit seismic activity (type A, B and harmonic tremor) and in the height of eruption plumes through the lake bottom are associated with a period of enhanced volcanic activity during April–September 1994. At this time, visual observations and remote fumarole temperature measurements suggest an increase in the flux of heat and gases discharged through the bottom of the crater lake, possibly related to renewed magma ascent beneath the active crater. A similar period of enhanced seismic activity that occurred between August 1995 and January 1996, apparently caused fracturing of sealed fumarole conduits beneath the composite pyroclastic cone allowing the focus of fumarolic degassing to migrate from beneath the lake back to the 1953–1955 cone. Changes in the chemistry of summit acid rain are correlated changes in volcanic activity regardless of whether fumaroles are discharging into the lake or are discharging directly into the atmosphere.     

Three magmatic components in the 1973 eruption of Eldfell volcano,Iceland: Evidence from plagioclase crystal size distribution (CSD) and geochemistry

The 1973 eruption of Eldfell volcano, Iceland, appears to have been a short, simple event, but textural and geochemical evidence suggest that it may have had three different magmatic components. The first-erupted fissure magmas were chemically evolved, rich in plagioclase (∼ 18%) and had shallow, straight crystal size distribution (CSD) curves. The early lavas were less evolved chemically, had lower plagioclase contents (∼ 13%) and steeper, slightly concave up CSDs. The late lavas were chemically similar to the early lavas, but even richer in plagioclase than the initial magmas (∼ 24%) and had the steepest CSDs. There was no chemical evidence for plagioclase fractionation, but compositional diversity could be produced by clinopyroxene fractionation which must have occurred at depth. We propose that the eruption started with old, coarsened (Ostwald ripened) magma left over from a previous eruption, possibly that which produced Surtsey Island ten years earlier. The early flows may be mixtures of small amounts of this old magma with a new, low crystallinity, uncoarsened magma or a completely new magma. The late flows are another new magma from depth, chemically similar to the early flows, but which has grown plagioclase under increasing saturation (undercooling) perhaps during its ascent. All three magmatic components may have originated from the same parent, but had varying degrees of clinopyroxene fractionation, plagioclase nucleation and growth, and coarsening.     

Airborne measurements of particle and gas emissions from the December 1994–January 1995 eruption of Popocatépetl volcano (Mexico)

Airborne and ground-based (correlation spectrometer, cascade impactor, and photoelectric counter together with intake filter probes) measurements are described for the volcanic emissions from Popocatépetl volcano (Mexico) from December 23, 1994 to January 28, 1995. Measurements of SO₂ restarted 48 h after the eruption onset of December 21, 1994. Maximum sulfur dioxide (4560 t d⁻¹) plus 3.8×10⁴ t d⁻¹ of particulate matter were ejected on December 24, 1994. The maximum rate of ejection occurred coincidentally with the maximum amplitude of harmonic tremor and the maximum number of seismic type B events. Sulfur dioxide emission rates ranged from 1790 to 2070 t d⁻¹ (December 23–24, 1994). Afterwards, sulfur dioxide emission rates clearly indicated a consistent decline. However, frequent gas and ash emission puffs exhibited SO₂ fluxes reaching values as high as 3060 t d⁻¹. The emission SO₂ baseline for the period of study (February 1994–January 1995) was about 1000 t d⁻¹. Ejection velocity of particulate matter was approximately 270 m s⁻¹ reaching a height of about 2.5 km over the summit. The immediate aerosol dispersion area was estimated at 6.0×10⁴ km² maximum. The microscopic structure of particles (aerosol and tephra) showed a fragile material, probably coming from weathered crustal layers. X-ray fluorescence and neutron-activation analysis from the impactor samples found the following elements: Si, Al, Ca, S, P, Cl, K, Ni, Fe, Ti, Sc, Cu, Zn, Mn, Sr, Cr, Co, Y, Br, Se, Ga, Rb, Hg and Pb. Morphological analysis shows that ash samples might be from pulverized basaltic rock indicating that the Popocatépetl eruption of December 21, 1994 was at low temperature. The microscopic structure of puff material showed substance aggregates consisted of fragile rock, water and adsorbed SO₂. These aggregates were observed within water droplets of approximately 1 mm and even larger. Sulfur transformations in the droplets occurred intensively. Volcanic ash contained 5–6% of sulfur during the first expulsion hours. Elemental relative concentrations with respect to Al show that both Si and S have relative concentrations >1, i.e., 13.73 and 2.17, respectively in agreement with the photoelectric counter and COSPEC measurements.     

Sulfur and chlorine degassing from primitive arc magmas: temporal changes during the 1982–1983 eruptions of Galunggung (West Java, Indonesia)

The 1982–1983 eruptions of Galunggung represent a nine-month period of intermittent volcanic activity with significant changes in explosivity and emission of volatiles. Eruptions started with Vulcanian explosions but changed gradually to Strombolian activity. Compositions of juvenile material changed from basaltic andesite to high-Mg basalt, which are among the most primitive rock types known in the Indonesian arc system. Although bulk compositions suggest a single evolution trend, we infer from the compositions of melt inclusions in olivine phenocrysts that the magmas represent derivatives of a complex spectrum of primary melts. Primitive inclusions in olivine phenocrysts from magma erupted during the Strombolian phase contain up to 2000 ppm sulfur, but concentrations decrease rapidly with increasing SiO₂ down to matrix glass values (50–100 ppm). ‘Vulcanian’ inclusions appear to be degassed before eruption (200 ppm S). Chlorine concentrations increase from 750 to 2200 ppm in Strombolian, and from 800 to 1500 in Vulcanian magmas, whereas matrix glass contains about 1000 ppm in both cases. Ash leachates show two cycles of decreasing S/Cl ratios: from 9.7 to 5.6 at the start of the activity, and from 12.2 to 2.0 after four months. As the second cycle follows upon increased seismic activity at shallow depth, it probably reflects degassing of fresh sulfur-rich magma arriving in the shallow Galunggung reservoir. In contrast to the degassed state of Vulcanian magma, the significant amounts of adsorbed sulfur on the ashes point to an excess source of sulfur, which was most likely derived from intruding Strombolian magma. Hence, the observed sulfur flux of 2 Mt is not in accordance with a petrologic estimate of 0.09 Mt. Using a published value of 550 Mt of erupted material about 0.34 km³ fresh undegassed magma is needed to account for the observed sulfur flux. This is close to the erupted volume of Vulcanian magma (0.26 km³), which presumably was replaced completely by Strombolian magma during the eruption. Using the petrologic method, we calculate a total release of 0.3 Mt chlorine, which agrees well with an output of 0.47 Mt estimated independently from S/Cl ratios of the ash leachates and TOMS sulfur yields. Ash leachates show that about 35% of the sulfur and 30% of the chlorine was scavenged from the eruption plumes. Our results suggest that sulfur and chlorine were largely decoupled during degassing, which resulted in considerable variations in S/Cl ratios during the Galunggung eruptions. We infer that sulfur degassing reflects the arrival of fresh magma at shallow depth, whereas chlorine is largely derived from simultaneously erupted material. As a consequence, the petrologic estimates are more consistent with observed emissions for chlorine than for sulfur.     

Structural features of Panarea volcano in the frame of the Aeolian Arc (Italy): Implications for the 2002–2003 unrest

Panarea, characterized by gas unrest in 2002–2003, is the volcanic island with the least constrained structure in the eastern-central Aeolian Arc (Italy). Based on structural measurements, we define here its deformation pattern relative to the Arc. The main deformations are subvertical extension fractures (63% of data), normal faults (25%) and dikes (12%). The mean orientation of the extension fractures and faults is N38°E, with a mean opening direction of N135° ± 8°, implying extension with a moderate component of dextral shear. These data, matched with those available for Stromboli volcano (pure opening) and Vulcano, Lipari and Salina volcanoes (predominant dextral motions) along the eastern-central Arc, suggest a progressive westward rotation of the extension direction and an increase in the dextral shear. The dextral shear turns into compression in the western arc. The recent unrest at Panarea, coeval to that of nearby Stromboli, may also be explained by the structural context, as both volcanoes lie along the portion of the Arc subject to extension.     

The droughts of 1996–1997 and 2004–2005 in Amazonia: hydrological response in the river main‐stem

Severe hydrological droughts in the Amazon have generally been associated with strong El Niño events. More than 100 years of stage record at Manaus harbour confirms that minimum water levels generally coincide with intense warming in the tropical Pacific sea waters. During 2005, however, the Amazon experienced a severe drought which was not associated with an El Niño event. Unless what usually occurs during strong El Niño events, when negative rainfall anomalies usually affect central and eastern Amazon drainage basin; rainfall deficiencies in the drought of 2005 were spatially constrained to the west and southwest of the basin. In spite of this, discharge stations at the main‐stem recorded minimum water levels as low as those observed during the basin‐wide 1996–1997 El Niño‐related drought. The analysis of river discharges along the main‐stem and major tributaries during the drought of 2004–2005 revealed that the recession on major tributaries began almost simultaneously. This was not the case in the 1996–1997 drought, when above‐normal contribution of some tributaries for a short period during high water was crucial to partially counterbalance high discharge deficits of the other tributaries. Since time‐lagged contributions of major tributaries are fundamental to damp the extremes in the main‐stem, an almost coincident recession in almost all tributaries caused a rapid decrease in water discharges during the 2005 event. Copyright © 2010 John Wiley & Sons, Ltd.     

Subduction-related episodes of K-alkaline magmatism (15–0.1 Ma) and geodynamic implications in the north Tyrrhenian — central Italy region: a review

In the north Tyrrhenian region and adjoining shores of Alpine Corsica and central Italy, four magmatic phases (15–14; 8–6; 5–2; and 1.3–0.1 Ma) are present which consist prevailingly of either old acidic and lamproitic rocks or young (1.3–0.1 Ma) basic volcanics with potassic–ultrapotassic affinity (the rocks of the K and HK series of the Roman province, and the kamafugitic rocks). Composition, age and location of the igneous phases reveal a geochemical polarity oriented from west to east. The episodes of magmatic activity reflect the evolution of the geodynamic environment (ensialic plate convergence): backarc stretching and attenuation of an Alpine orogenic wedge were accompanied by the eastward roll-back and progressive steepening of the descending Adria plate. The latter process led to enhanced metasomatic modifications of the mantle wedge composition and to eruption of the large volumes of KS and HKS volcanic rocks in central Italy (0.6–0.1 Ma).     

Geochemistry of fluids associated with the 1995–1996 eruption of Mt. Ruapehu, New Zealand: signatures and processes in the magmatic-hydrothermal system

The 1995–1996 eruption of Mt. Ruapehu has provided a number of insights into the geochemical processes operating within the magmatic-hydrothermal system of this volcano. Both pre-eruption degassing of the rising magma and its eventual intrusion into the convective zone of the hydrothermal system beneath the lake were clearly reflected in lake water compositions. The eruptions of September–October 1995 expelled the lake, and provided the first-ever opportunity to characterise gas discharges from this volcano. The fumarolic discharges revealed compositions typical of andesite volcanoes and strong interaction with the enclosing meteoric and hydrothermal system fluids. Some 1.1 MT of SO₂ gas was released from the volcano between September 1995 and December 1996, whereas ca. twice this amount (2.2 MT equivalent SO₂) was erupted as soluble (i.e. leachable) oxyanions of sulphur. Significantly more sulphur was released from the volcano over this period than can be accounted for from the magma volume actually erupted. The evidence suggests that a sizable component of the evolved sulphur was remobilised from the long-lived hydrothermal system within the volcano during the 1995–1996 activity.     

A new scenario for the last magmatic eruption of La Soufrière of Guadeloupe (Lesser Antilles) in 1530 A.D. Evidence from stratigraphy radiocarbon dating and magmatic evolution of erupted products

La Soufrière of Guadeloupe is a dangerous volcano characterized over the last decade by moderate seismic and fumarolic unrest. In the last 15,000 years it has experienced phreatic and magmatic eruptions and unusually numerous flank collapse events sometimes associated with a magmatic eruption. We propose a new age of 1530 A.D. and a new eruptive scenario for the last magmatic eruption on the basis of a novel statistical analysis of radiocarbon age dates, and new field and geochemical data. This eruption is the only magmatic eruption likely to have occurred in Guadeloupe during the last 1400 years. The eruption mainly involved an andesitic magma which, in the first phase of the eruption, partially mixed with a slightly more differentiated magma stored in a small and shallow magma chamber. Ascent of magma to the surface generated a partial collapse of the hydrothermally altered edifice that increased the magma discharge and led to a sub-plinian phase with scoria fallout and column-collapse pyroclastic flows followed by near-vent pyroclastic scoria fountains. The eruption ended with growth of a lava dome. Our revised interpretation of the last magmatic eruption of La Soufrière constitutes the most likely key to a future magmatic eruption scenario for this volcano which displays strong evidence of unrest since 1992.