Trace element contamination in the estuarine sediments along Tuticorin coast – Gulf of Mannar,southeast coast of India

Sediment samples were collected from Kallar, Korampallam creek and Punnakayal estuaries of Tuticorin coast for assessing the level of contamination by trace elements in these estuarine sediments. The trace element concentration, calcium carbonate, organic carbon and mercury level were analyzed by Inductively Coupled Plasma Atomic Emission Spectrophotometer, Titrimetric method and SnCl₂ reduction method. The results reveals that the enrichment factor, metal pollution index and geo-accumulation index of these estuarine sediments were predominantly polluted by Cd, As, Zn, Hg and Pb. The factor analysis revealed the source of trace element accumulation in the estuarine sediments particularly Mn and Fe are from riverine inputs and As and Hg from untreated industrial effluents. Among the selected estuaries, Korampallam creek was found to be highly contaminated by trace elements due to the discharge of effluents from thermal power plant, Tuticorin alkali chemicals, copper smelting, Petrochemical industries and shipping activities.     

Assessment of heavy metal contamination in the sur?cial sediments from the lower Meghna River estuary,Noakhali coast,Bangladesh

Sediment samples were collected from ten selected sites of the lower Meghna River estuary, and six heavy metals were analyzed with Atomic Absorption Spectrophotometry(AAS) to assess the contamination level and the metals' association with sediment grain size. The current results revealed that the mean concentrations of the studied metals were ranked in descending order of iron(Fe)(1.29 ? 103 mg/kg) zinc(Zn)(42.41 mg/kg) lead(Pb)(12.48 mg/kg) chromium(Cr)(10.59 mg/kg) copper(Cu)(6.22 mg/kg) cadmium(Cd)(0.28 mg/kg). The geo-accumulation, contamination, and pollution load indexes suggested that the lower Meghna river estuary was not contaminated by Fe, Zn, Pb, Cr, and Cu.The mean size of the sediment ranged from 28.92 to 126.2 mm, and the Pearson correlation coefficient showed a significant association between Fe and Pb(coefficient of determination, r2? 0.836; p 0.05),and no significant correlation was found between individual metals and grain size, indicating no or low influence on the metals distribution.     

Biodiversity reduction on contaminated sediments in the sea: contamination or sediment mobility?

Where contaminants in sediments correlate with biodiversity reductions, the contamination may not be the cause. Other physical factors may be responsible, and should be investigated so that any remedial action is directed properly. Two examples are given where unusual sediment mobility caused biodiversity reductions in sediments with elevated trace contaminants.     

An assessment of an oil spill in Gladstone,Australia – Impacts on intertidal areas at one month post-spill

In January 2006, 25 tonnes of heavy fuel oil spilled into the Port of Gladstone in Queensland, Australia, from the breached hull of a bulk carrier ship. Over the following days, approximately 18 tonnes of the oil was recovered, however a certain amount of oil was deposited in the intertidal areas of Port Curtis leaving a highly visible, viscous residue. The objectives of this research were to assess the immediate impacts on the intertidal habitat and to gain baseline information for future comparative assessments.Sediment PAH and metal concentrations, mangrove communities and intertidal macroinvertebrates were assessed within one month post-spill at oil-impacted sites; adjacent sites which were not visibly impacted; and reference sites which were located outside the recorded distribution of the oil spill. Highest PAH concentrations were found at the impacted sites, with concentrations of some PAHs exceeding Australian and New Zealand Sediment Quality Guidelines (ANZECC/ARMCANZ, 2000). These sites contained very few or no crab holes in the high intertidal area, indicating a low crab density in comparison to reference sites. Little immediate impact was evident on the mangrove and macrobenthic communities, however future surveys may show evidence of longer-term impacts on these communities.     

Chronological reconstruction of metal contamination in the Port of Maó (Minorca, Spain)

In this work we discuss the historical record of metals as derived from a sediment core from the Port of Maó (Minorca, Spain), the second natural largest harbour in Europe. The sedimentation rate derived from radionuclide profiles increased by a factor of five since the 1960s due to the urbanisation of the town waterfront. Metal concentrations showed two different trends: (i) Pb and Sn inputs started during the second half of the 19th century and remained relatively high until mid-20th century; and (ii) Ag, Cd, Ni, Zn, Cu and Cr accumulation began in the 1940s, peaking in the late 1970s. The commissioning of a submarine outfall in 1978 reduced metal concentrations in subsequently deposited sediments since, thereafter, urban and industrial wastes have been dumped out of the estuary. This study also shows that evaluating the quality of sediments on the basis of surface concentrations may be misleading.     

Assessment of urban and industrial contamination levels in the bay of Cádiz,SW Spain

Measuring the amount of pollution is of particular importance in assessing the quality and general condition of an ecosystem. In this paper, some of the results obtained as a consequence of the specific agreement between the Environmental Agency (Consejería de Medio Ambiente, Junta de Andalucía) and the University of Cadiz to assess the environmental condition of the marine bottom and waters are showed. Physical and chemical analyses in water and sediments were undertaken at various sampling sites close to urban and industrial locations. Later on, these results were studied under statistical analysis to reveal any possible relationships between the parameters employed, and to identify any analogous behaviour between the sampling sites. Physical-chemical data revealed that sediments and waters analysed were moderately contaminated and, in addition, no great differences were found between in rising and ebbing tide conditions. Finally, considering only the pollution level, from the cluster analysis of sediments two major groups appear, one of which corresponded to those sites located in the outer bay, and the other to those situated in the inner bay. However, number 6 and 14 sampling sites cannot be associated to those groups due to be related to points with important local discharges.     

Probabilistic ecological risk assessment of heavy metals in sediments from China’s major aquatic bodies

An overall and comparative ecological risk assessment of heavy metals (including Cd, Cr, Cu, Pb, Zn, Hg and As) in surface sediments from China’s eight major aquatic bodies was conducted to better understand their potential risks on a national scale. By applying the joint approach of Hakanson risk index (RI) and Monte Carlo simulation, ecological risk in this work is expressed as probability distribution of RI values instead of single point calculations to reflect the uncertainties in risk assessment process. The results show that the highest ecological risks posed by heavy metals existed in Xiangjiang River and Dianchi Lake. Although only a slim margin of high risk (651.88/600 = 1.08 and 700.61/600 = 1.17) was identified based on average RI values, the probabilities of high risk level derived from Monte Carlo simulation reached as high as 56.7 and 52.9 % in these two aquatic bodies, respectively. And the probability of low risk level was less than 1.6 %. Furthermore, the risk was mainly contributed by Hg and Cd, discharged through local intensive mining and industrial activities. The findings indicate that rigid control and effective management measures to prevent heavy metal pollution are urgently needed in China, especially for the high-risk aquatic bodies. This study shows that the joint approach can be used to identify the high risk water bodies and the major metal pollutants. It may avoid overestimating or underestimating the ecological risk and provide more decision-making support for risk alleviation in the polluted aquatic bodies.     

Evaluation of geochemical behavior and heavy metal distribution of sediments：The case study of the Tirumalairajan river estuary,southeast coast of India

The purpose of this study was to assess the chemical partitioning of selected heavy metals(Fe,Mn,Cu,Zn,Pb,Cr,Co and Ni) in 10 surface sediments at Tirumalairajan River Estuary in the southeastern coast of India.A five-step sequential extraction technique was used to assess the environmental status of heavy metals.Most of metals were considered to be immobile due to the high availability in the residual fraction of heavy metals.The sediments of Tirumalairajan River estuary had not been polluted by heavy metals,and they didn’t pose any high ecological risk.The seasonal variations of heavy metals were slightly higher in summer than in monsoon season.Factor analysis was also carned out to understand the associations of metals in different fractions with sand,silt,clay,organic matter,pH,salinity and other metals.The relationship between the Q-mode and R-mode cluster analyses was useful for identifying the pollution levels in both seasons.It was proved that the enrichment of heavy metals was related with geogenic and anthropogenic sources.The information on total metal concentrations in sediments was not sufficient for assessing the metal behavior in the environment,but the sequential extraction technique was more effective in estimating the environmental impact of contaminated sediments.     

Levels of Po and Pb in mussel and sediments in Candarlı Gulf and the related dose assessment to the coastal population

²¹⁰Po and ²¹⁰Pb in mussel (Mytilus galloprovincialis) and sediment samples collected at Candarl? Gulf during the period of 2010–2012 are presented and discussed. The activity concentrations of ²¹⁰Po and ²¹⁰Pb were measured by means of alpha spectrometry. Activity concentrations of ²¹⁰Po and ²¹⁰Pb in mussels are in the ranged of 332 ± 17–776 ± 23 Bq kg⁻¹ dw and 14 ± 1–40 ± 5 Bq kg⁻¹ dw, for sediments the ranges for 52 ± 5–109 ± 8 Bq kg⁻¹ dw and 38 ± 5–92 ± 9 Bq kg⁻¹ dw, respectively. The estimated consequent annual effective ingestion dose due to ²¹⁰Po and ²¹⁰Pb from mussel consumption in Candarl? Gulf coastal region were calculated. The highest dose due to ²¹⁰Po and ²¹⁰Po were calculated to be 4232 ± 126 μSv and 126 ± 16 μSv, respectively.     

Grain-size normalization as a tool to assess contamination in marine sediments: is the <63 micron fraction fine enough?

A common method for compensating for grain-size differences in suites of sediment samples is to normalize potential contaminants by regression with a particular grain-size fraction, the <63 microm fraction being most often selected. However, this fraction is unlikely to represent accurately the clay content, which represents a major factor in the ability of sediments to adsorb contaminants. Moreover, no reliable estimation of clay content can be made from a coarser grain-size fraction. As a result, regression with coarser-grained fractions can produce spurious interpretations of background values and contamination. Normalization with the clay content or by an alternative grain-size proxy is recommended.     

Changes in daily maximum temperature extremes across India over 1951–2014 and their relation with cereal crop productivity

This study used gridded daily maximum temperature data (1°?×?1°) for 1951–2014 period to analyze the trend in monthly extreme warm days (ExWD) and changes in its probability distribution in each grid. It also analyzed the trend in spatial spread of annual ExWD over the study period at four exceedance levels and further related the number of ExWDs with cereal crop productivity of India. Extreme warm days have increased throughout India but were statistically significant in 42% grids. The increase was consistent over all the months in north-eastern region, southern plateau and both the coastal plains. It also increased significantly over north-western and central India during April to June summer period. The probability distribution of ExWD also changed significantly in many grids, especially in southern plateau and both the coastal plains. The changes indicated increased frequency in the existing levels of extremes and new occurrences of higher frequency of extremes. The analysis of land area affected by different levels of extremes indicated significant increase, with the rate being highest for higher extremes. In terms of extreme warm day temperatures, the study identified southern plateau, east and west coast plains, and north-eastern India as highly vulnerable. Using copula probability model, study showed that increase in ExWD from 20 to 60% may increase the probability of 5% or more yield loss from 17 to 53% for Kharif cereals, 11 to 43% for Rabi cereals and 19 to 63% for wheat crop. The results may be used for devising zone specific adaptation strategies.     

Empirical approaches in prediction of reservoir sediment distribution——An experience of 57 reservoirs in the USA and India

An accurate prediction of sediment distribution may minimize economic losses through proper and timely planning of the functional activities of a reservoir.This study assesses different temporal and spatial factors that affect for sediment deposition in a reservoir and its distribution.This study also focuses on evaluation of two popular distribution prediction methodologies,Area Increment and Empirical Area Reduction,based on experience with sediment distribution in 57 reservoirs in the USA and India.A non-iterative processed empirical distribution model(NPEDM) and a linear regression trend model(LRTM) are proposed to predict sediment distribution.Silt contributing area and inflow entering a reservoir are found to be the most significant factors affecting in reservoir sediment deposition.Compared to the Empirical Area Reduction method,the Area Increment method provided better prediction.The reservoir classification approach and empirical design distribution type curves given by Borland and Miller(1960) are found to be rational.Shape factor values for different periods indicate that reservoir shape(type) changes with time.Thus,long term prediction is not desirable in Type-Ⅱ Ⅲ reservoirs using the Empirical Area Reduction method.Newly developed the NPEDM shows reasonably good prediction of sediment distribution.The NPEDM is very easy to apply and can be used in any reservoir of any size.Extrapolation of the trend of sediment distribution obtained from the LRTM indicates an accurate short term prediction in a few reservoirs as causes of temporal and spatial variations of sediment distribution including the factors of uncertainties of sediment deposition are implicit within the methodology.     

Potential of weight of evidence modelling for gully erosion hazard assessment in Mbire District – Zimbabwe

Gully erosion is an environmental concern particularly in areas where landcover has been modified by human activities. This study assessed the extent to which the potential of gully erosion could be successfully modelled as a function of seven environmental factors (landcover, soil type, distance from river, distance from road, Sediment Transport Index (STI), Stream Power Index (SPI) and Wetness Index (WI)) using a GIS-based Weight of Evidence Modelling (WEM) in the Mbire District of Zimbabwe. Results show that out of the studied seven factors affecting gully erosion, five were significantly correlated (p < 0.05) to gully occurrence, namely; landcover, soil type, distance from river, STI and SPI. Two factors; WI and distance from road were not significantly correlated to gully occurrence (p > 0.05). A gully erosion hazard map showed that 78% of the very high hazard class area is within a distance of 250 m from rivers. Model validation indicated that 70% of the validation set of gullies were in the high hazard and very high hazard class. The resulting map of areas susceptible to gully erosion has a prediction accuracy of 67.8%. The predictive capability of the weight of evidence model in this study suggests that landcover, soil type, distance from river, STI and SPI are useful in creating a gully erosion hazard map but may not be sufficient to produce a valid map of gully erosion hazard.     

Distribution of clay minerals in marine sediments off Chennai,Bay of Bengal,India： Indicators of sediment sources and transport processes

Clay mineralogy, texture size and statistical analyses were carried out on surface sediments from the continental shelf of Chennai, Bay of Bengal, India. The purpose of this study is to characterize the clay mineral distribution and its relation to the hydrodynamics off Chennai to identify the sources and transport pathways of the marine sediments. Characterization of clay minerals in coastal sediments by Fourier Transform Infrared （FTIR） spectroscopy has provided the association of quartz, feldspar, kaolinite, chlorite, illite and iron oxides （magnetite and hematite） derived from river catchments and coastal erosion. Kaolinite, chlorite, illite, iron oxides, and organic matter are the dominant minerals in Cooum, and Adayar region. High quartz and feldspar zones were identified in Marina, which are being confined the sand zone and paralleling the coast. The strong relationships among the wave energy density, sand, quartz and carbonate revealed that wave induced littoral drift system play a dominant role in transportation and deposition of sediments in the Chennai coast. The sediment texture and minerals data are in agreement well with the previous results of hydrodynamics and littoral drift models in this region. Multivariate statistical analyses （correlation, cluster and factor analyses） were carried out and obtained results suggested that clay minerals and organic matter are trapped in silt and clay particles, whereas quartz, feldspar and carbonate are associated with sand particles. Results of sediment sources and transport processes from this study will be useful to predict the fate of the pollutants released from land or the potential change in sediment delivery to coastal areas.     

Source characterization and spatio–temporal evolution of the metal pollution in the sediments of the Basque estuaries (Bay of Biscay)

According to Water Framework Directive requirements, Member States must identify and analyze effects derived from human pressures in aquatic systems. As different kind of pressures can impact water bodies at different scales, analyses of spatio-temporal evolution of water bodies becomes essential in order to understand ecosystem responses. In this investigation, an analysis of spatio-temporal evolution of sedimentary metal pollution (Cd, Cr, Cu, Hg, Ni, Pb, Zn) in 12 Basque estuaries (Bay of Biscay) is presented. Data collected in extensive sampling surveys is the basis for the GIS-based statistical approach used. The implementation of pollution abatement measures is reflected in a long-term decontamination process, mostly evident in estuaries with highest historical sediment pollution levels. Spatial evolution is determined by either naturally occurring or human driven processes. Such spatial processes are more obviously being reflected in estuaries with lower historical sediment pollution levels.     

Optical dating of fluvio-deltaic clastic lake-fill sediments – A feasibility study in the Holocene Rhine delta (western Netherlands)

We test the applicability of quartz optically stimulated luminescence (OSL) dating on clastic lake sediments to investigate whether this dating method can be applied to study the timing and rate of deposition in Holocene fluvio-deltaic lakes. Our study concerns the filling of a lake by the Angstel-Vecht system, part of the Rhine delta in the western Netherlands. Age constraints are provided by radiocarbon dates on the development and abandonment of the fluvial channels debouching into the lake. Results indicate that light exposure prior to deposition and burial was sufficient to reset the OSL signal of the vast majority of the quartz grains. Special attention was given to accurate estimation of the dose rate in the laminated and bedded deposits. The OSL ages obtained are in good agreement with the age constraints, especially for the relatively coarse sediments. OSL results indicate that the filling of the lake took about 700 years, with a sedimentation rate of ～3 mm per year. This study is a demonstration of the use of OSL dating of sand-sized quartz to determine the timing and rate of sedimentation in a Holocene fluvio-deltaic environment.