A geochemical record of environmental changes in sediments from Sishili Bay,northern Yellow Sea,China: Anthropogenic influence on organic matter sources and composition over the last 100 years

Total organic carbon (TOC), total nitrogen (TN), δ¹³C and δ¹⁵N were measured in sediment cores at three sites in Sishili Bay, China, to track the impacts of anthropogenic activities on the coastal environment over the last 100 years. The increased TOC and TN in the upper section of sediment cores indicated a eutrophic process since 1975. In comparison, the TOC and TN in the sediment core near to a scallop aquaculture area displayed a much slower increase, indicating the contribution of scallop aquaculture in mitigating eutrophication. Combined information from δ¹³C, δ¹⁵N and TOC:TN indicated an increased terrestrial signal, although organic matter sources in Sishili Bay featured a mixture of terrestrial and marine sources, with phytoplankton being dominant. Increased fertilizer use since 1970s contributed to the eutrophic process in Sishili Bay since 1975, and increased sewage discharge from 1990s has added to this process.     

水平井开采南海神狐海域天然气水合物数值模拟

2007年5月,南海北部神狐海域的实地钻探结果表明该区域海底存在大量天然气水合物,其作为未来我国潜在的可开发能源的调查和资源评价工作正在展开.本文以SH7站位的钻探、测井数据为基础,建立了实际水合物藏分层地质模型,主要包括上盖层、水合物层和下盖层,其中上下盖层均为可渗透的沉积物.本文利用新型的开采井设计方式,进行了单一...     

The response of benthic macrofauna to anthropogenic stress in Narragansett Bay, Rhode Island: a review of human stressors and assessment of community conditions

The present state of knowledge regarding the input of anthropogenic pollutants into Narragansett Bay, Rhode Island was reviewed and benthic infaunal communities present at four depositional environments within the upper Bay were characterized. Inter-station differences in species composition and abundance of these assemblages were examined in relation to established pollution gradients.Using diversity curves and multivariate statistics, evidence of significant anthropogenic impact on the structure of benthic macrofaunal communities in Narragansett Bay was identified. The magnitude of this impact was greatest at stations closest to the Bay’s urban centers, where exposure to multiple stressors had resulted in communities of opportunistic taxa which persisted in a state of low faunal diversity characteristic of early stages of species succession. As was expected based on historic models of faunal succession; the apparent maturity of benthic assemblages in Narragansett Bay increased along the north-south gradient of decreasing anthropogenic stress.     

Short-term,linear, and non-linear local effects of the tides on the surface dynamics in a new,high-resolution model of the Mediterranean Sea circulation

Ocean Dynamics - The tides in the Mediterranean Sea are generally weaker than in other regions of the world ocean, but are locally intensified in passages with complex bathymetry, such as the...     

Estimation of mean water transit time on a steep hillslope in South Korea using soil moisture measurements and deuterium excess

A method for estimating daily mean transit time (DMTT) within a soil layer was proposed using field measurements of soil moisture. Vertical profiles of soil moisture time series were used for storage estimation. Water fluxes were evaluated through matrix and bypass flow. Variations in soil moisture and soil thickness were used to evaluate matrix flow. Exponential decay in depth of macropores was also used for bypass flow approximation. DMTT evaluation was compared to results obtained from a stable water isotope model using two years of data acquired on a steep granite hillslope in the Sulmachun watershed, South Korea. Various uncertainties in transit time evaluation such as model structure, non‐stationary assumption and data acquisition of existing approaches can be accounted for in the proposed methodology, and the flowpath contribution can be further configured in conjunction with hydrometric measurements. Probability density functions of isotope analyses were partially explained by transit time distributions that were based on soil moisture measurements. Supplementary sensitivity analyses for uncertainty configurations indicate that matrix flow is the primary process in determining transit time distribution while the impact of bypass flow is minor. The feasibility of a DMTT approach over isotope‐based methodologies highlights not only the strength of this proposed method, both in cost and time, but also its further application potential for existing soil moisture measurements. Copyright © 2013 John Wiley & Sons, Ltd.     

Numerical modeling of a long-term in situ chemical osmosis experiment in the Pierre Shale,South Dakota

We have numerically modeled evolving fluid pressures and concentrations from a nine-year in situ osmosis experiment in the Pierre Shale, South Dakota. These data were obtained and recently interpreted by one of us (C.E.N.) as indicating a potentially significant role for chemical osmosis in media like the Pierre Shale. That analysis considered only the final pressure differentials among boreholes that were assumed to represent osmotic equilibrium. For this study, the system evolution was modeled using a recently developed transient model for membrane transport. The model simulates hydraulically and chemically driven fluid and solute transport. The results yield an estimate of the thickness of the water film between the clay platelets b of 40 Å, which corresponds to an osmotic efficiency σ of 0.21 for the ambient pore water salinity of 3.5 g/l TDS. These values largely confirm the results of the earlier equilibrium analysis. However, the new model analysis provides additional constraints suggesting that intrinsic permeability k = 1.4 × 10⁻¹⁹ m², specific storage S_s = 1.7 × 10⁻⁵ m⁻¹, and diffusion coefficient D* = 6 × 10⁻¹¹ m²/s. The k value is larger than certain independent estimates which range from 10⁻²¹ to 10⁻²⁰; it may indicate opening of microcracks during the experiments. The fact that the complex transient pressure and concentration behavior for the individual wells could be reproduced quite accurately, and the inferred parameter values appear to be realistic for the Pierre Shale, suggests that the new model is a useful tool for modeling transient coupled flows in groundwater systems.     

Temporal trends of brominated flame retardants in coastal waters of Japan and South China: Retrospective monitoring study using archived samples from es-Bank, Ehime University, Japan

The present paper is a summary of studies conducted at the Center for Marine Environmental Studies, Ehime University, on temporal trends of brominated flame retardants (BFRs) in coastal waters of Japan and South China. Archived marine mammal fat tissues and dated sediment cores were used to evaluate temporal trends of polybrominated diphenyl ethers (PBDEs) and hexabromocyclododecanes (HBCDs) in relation to their usage in the region. The results indicate that environmental concentrations of these BFRs in Japan and South China increased significantly during the last several decades. Temporal trends in the contaminant concentrations were consistent with historical consumption of the corresponding BFRs. PBDE levels in marine mammals and sediments from Japan, after showing peak concentrations in the 1990s, appear to be leveling off in recent years, in accordance with the discontinued usage of Tetra- and Octa-BDEs in Japan from the 1990s. The change in concentration levels was also accompanied by changes in PBDE congener profiles, i.e. shift towards increased proportion of higher brominated BDEs. Furthermore, in recent years HBCD concentrations in marine mammals from Japan appear to exceed those of PBDEs, presumably reflecting increasing usage of HBCDs over PBDEs. In finless porpoises from the South China Sea, PBDE levels were much higher than HBCD concentrations both in the past and recent years, implying consumption of HBCDs was not as high as that of PBDEs in China. In dated sediment cores from Tokyo Bay, concentrations increased exponentially with doubling times of 4.6–7.9 years, 6.1–12 years and 7.1–12 years for BDE-209, ΣPBDEs and HBCDs, respectively.     

Simulated changes due to global warming in the variability of precipitation, and their interpretation using a gamma-distributed stochastic model

The interannual variability of monthly mean January and July precipitation and its possible change due to global warming are assessed using a five-member ensemble of climate for the period 1871–2100, simulated by the CSIRO Mark 2 global coupled atmosphere–ocean model. In the 1961–1990 climate, for much of the middle to high latitudes the standard deviation of precipitation for both months is roughly proportional to the mean, with the coefficient of variation (C) typically 0.3–0.5. The variability there is shown to be largely consistent with that from a first-order Markov chain model of the daily rainfall occurrence, with the distribution of wet-day amounts approximated by a gamma distribution. Global distributions of Mark 2-based parameters of this stochastic model, commonly used in weather generators, are presented. In low latitudes, however, the variability from the coupled model is typically double that anticipated by the stochastic model, as quantified by an ‘overdispersion ratio’. C often exceeds one at subtropical locations, where rain is less frequent, but sometimes relatively heavy.The standard deviation of monthly mean precipitation S generally increases as the global model warms, with the global mean S in 2071–2100 in January (July) being 9.0% (11.5%) larger than in 1961–1990. Decreases in some subtropical locations occur, particularly where mean precipitation decreases. The global pattern of overdispersion is largely unchanged, however, and the changes in S can be related to those in the stochastic model parameters. Much of the increase in S is associated with increases in the scale parameter of the gamma distribution of wet-day amounts. Changes in C, which is unaffected by this parameter, are generally small. Increases in C in several subtropical bands and over northern midlatitude land in July are related to a decreased frequency of precipitation, and (to a lesser degree) changes in the gamma shape parameter. Some potential applications of the results to downscaling are discussed, and illustrated using observed rainfall from southeast Australia.