A regional-scale study of chromium and nickel in soils of northern California, USA

A soil geochemical survey was conducted in a 27,000-km² study area of northern California that includes the Sierra Nevada Mountains, the Sacramento Valley, and the northern Coast Range. The results show that soil geochemistry in the Sacramento Valley is controlled primarily by the transport and weathering of parent material from the Coast Range to the west and the Sierra Nevada to the east. Chemically and mineralogically distinctive ultramafic (UM) rocks (e.g. serpentinite) outcrop extensively in the Coast Range and Sierra Nevada. These rocks and the soils derived from them have elevated concentrations of Cr and Ni. Surface soil samples derived from UM rocks of the Sierra Nevada and Coast Range contain 1700–10,000 mg/kg Cr and 1300–3900 mg/kg Ni. Valley soils west of the Sacramento River contain 80–1420 mg/kg Cr and 65–224 mg/kg Ni, reflecting significant contributions from UM sources in the Coast Range. Valley soils on the east side contain 30–370 mg/kg Cr and 16–110 mg/kg Ni. Lower Cr and Ni concentrations on the east side of the valley are the result of greater dilution by granitic sources of the Sierra Nevada.Chromium occurs naturally in the Cr(III) and Cr(VI) oxidation states. Trivalent Cr is a non-toxic micronutrient, but Cr(VI) is a highly soluble toxin and carcinogen. X-ray diffraction and scanning electron microscopy of soils with an UM parent show Cr primarily occurs within chromite and other mixed-composition spinels (Al, Mg, Fe, Cr). Chromite contains Cr(III) and is highly refractory with respect to weathering. Comparison of a 4-acid digestion (HNO₃, HCl, HF, HClO₄), which only partially dissolves chromite, and total digestion by lithium metaborate (LiBO₃) fusion, indicates a lower proportion of chromite-bound Cr in valley soils relative to UM source soils. Groundwater on the west side of the Sacramento Valley has particularly high concentrations of dissolved Cr ranging up to 50 μg L⁻¹ and averaging 16.4 μg L⁻¹. This suggests redistribution of Cr during weathering and oxidation of Cr(III)-bearing minerals. It is concluded that regional-scale transport and weathering of ultramafic-derived constituents have resulted in enrichment of Cr and Ni in the Sacramento Valley and a partial change in the residence of Cr.     

Regional variations in water quality and relationships to soil and bedrock weathering in the southern Sacramento Valley, California, USA

Regional patterns in ground- and surface-water chemistry of the southern Sacramento Valley in California were evaluated using publicly available geochemical data from the US Geological Survey’s National Water Information System (NWIS). Within the boundaries of the study area, more than 2300 ground-water analyses and more than 20,000 surface-water analyses were available. Ground-waters from the west side of the Sacramento Valley contain greater concentrations of Na, Ca, Mg, B, Cl and SO₄, while the east-side ground-waters contain greater concentrations of silica and K. These differences result from variations in surface-water chemistry as well as from chemical reactions between water and aquifer materials. Sediments that fill the Sacramento Valley were derived from highlands to the west (the Coast Ranges) and east (the Sierra Nevada Mountains), the former having an oceanic provenance and the latter continental. These geologic differences are at least in part responsible for the observed patterns in ground-water chemistry. Thermal springs that are common along the west side of the Sacramento Valley appear to have an effect on surface-water chemistry, which in turn may affect the ground-water chemistry.     

The age and origin of a thick mafic–ultramafic keel from beneath the Sierra Nevada batholith

We present evidence for a thick (∼100 km) sequence of cogenetic rocks which make up the root of the Sierra Nevada batholith of California. The Sierran magmatism produced tonalitic and granodioritic magmas which reside in the Sierra Nevada upper- to mid-crust, as well as deep eclogite facies crust/upper mantle mafic–ultramafic cumulates. Samples of the mafic–ultramafic sequence are preserved as xenoliths in Miocene volcanic rocks which erupted through the central part of the batholith. We have performed Rb-Sr and Sm-Nd mineral geochronologic analyses on seven fresh, cumulate textured, olivine-free mafic–ultramafic xenoliths with large grainsize, one garnet peridotite, and one high pressure metasedimentary rock. The garnet peridotite, which equilibrated at ∼130 km beneath the batholith, yields a Miocene (10 Ma) Nd age, indicating that in this sample, the Nd isotopes were maintained in equilibrium up to the time of entrainment. All other samples equilibrated between ∼35 and 100 km beneath the batholith and yield Sm-Nd mineral ages between 80 and 120 Ma, broadly coincident with the previously established period of most voluminous batholithic magmatism in the Sierra Nevada. The Rb-Sr ages are generally consistent with the Sm-Nd ages, but are more scattered. The ⁸⁷Sr/⁸⁶Sr and ¹⁴³Nd/¹⁴⁴Nd intercepts of the igneous-textured xenoliths are similar to the ratios published for rocks outcroping in the central Sierra Nevada. We interpret the mafic/ultramafic xenoliths to be magmatically related to the upper- and mid-crustal granitoids as cumulates and/or restites. This more complete view of the vertical dimension in a batholith indicates that there is a large mass of mafic–ultramafic rocks at depth which complement the granitic batholiths, as predicted by mass balance calculations and experimental studies. The Sierran magmatism was a large scale process responsible for segregating a column of ∼30 km thick granitoids from at least ∼70 km of mainly olivine free mafic–ultramafic residues/cumulates. These rocks have resided under the batholith as granulite and eclogite facies rocks for at least 70 million years. The presence of this thick mafic–ultramafic keel also calls into question the existence of a “flat” (i.e., shallowly subducted) slab at Central California latitudes during Late Cretaceous–Early Cenozoic, in contrast to the southernmost Sierra Nevada and Mojave regions. Received: 27 December 1997 / Accepted: 11 June 1998     

Cluster analysis of a regional-scale soil geochemical dataset in northern California

A regional-scale soil geochemical study was conducted within a 22,000 km² area in northern California including the Sierra Nevada, Sacramento Valley, and northern Coast Range. Over 1300 soil samples were chemically analyzed for 42 elements. The distribution of distinct groups of elements demonstrates the interplay of geologic, hydrologic, geomorphologic and anthropogenic factors; however, it is difficult to fully appreciate the complexity of geochemical transport and weathering processes on a landscape-scale in an area of very complex geology with such a large dataset containing more than 40 variables. To examine the data from a perspective of multi-element groupings, cluster analyses were applied to the dataset. The analysis identified several groups of elements whose spatial patterns could be related to specific geologic sources.     

Experimental and geochemical evidence for derivation of the El Capitan Granite,California, by partial melting of hydrous gabbroic lower crust

Partial melting of mafic intrusions recently emplaced into the lower crust can produce voluminous silicic magmas with isotopic ratios similar to their mafic sources. Low-temperature (825 and 850°C) partial melts synthesized at 700 MPa in biotite-hornblende gabbros from the central Sierra Nevada batholith (Sisson et al. in Contrib Mineral Petrol 148:635–661, 2005) have major-element and modeled trace-element (REE, Rb, Ba, Sr, Th, U) compositions matching those of the Cretaceous El Capitan Granite, a prominent granite and silicic granodiorite pluton in the central part of the Sierra Nevada batholith (Yosemite, CA, USA) locally mingled with coeval, isotopically similar quartz diorite through gabbro intrusions (Ratajeski et al. in Geol Soc Am Bull 113:1486–1502, 2001). These results are evidence that the El Capitan Granite, and perhaps similar intrusions in the Sierra Nevada batholith with lithospheric-mantle-like isotopic values, were extracted from LILE-enriched, hydrous (hornblende-bearing) gabbroic rocks in the Sierran lower crust. Granitic partial melts derived by this process may also be silicic end members for mixing events leading to large-volume intermediate composition Sierran plutons such as the Cretaceous Lamarck Granodiorite. Voluminous gabbroic residues of partial melting may be lost to the mantle by their conversion to garnet-pyroxene assemblages during batholithic magmatic crustal thickening.     

Soil geochemical signature of urbanization and industrialization – Chicago, Illinois, USA

The concentrations of 45 elements in ambient (not obviously disturbed) surface soils were determined for 57 sites distributed throughout the city of Chicago, Illinois in the upper Midwestern United States. These concentrations were compared to soils from 105 sites from a largely agricultural region within a 500-km radius surrounding the city and to soils collected from 90 sites across the state of Illinois. Although the bulk composition of the Chicago urban soils reflects largely natural sources, the soils are significantly enriched in many trace elements, apparently from anthropogenic sources. The median concentration of Pb in Chicago soils is 198 mg/kg, a 13-fold enrichment compared to regional concentrations. Zinc (median 235 mg/kg), Cu (59 mg/kg), and Ni (31 mg/kg) are also enriched from 2- to 4-fold in Chicago soils and all four elements show strong mutual correlations. These elevated concentrations are most likely related to vehicular and roadway sources and represent uneven distribution across the city as airborne material. Other airborne particulate material from a combination of fossil fuel combustion, waste incineration, and steel production may contribute to apparent elevated concentrations in Chicago soil of Fe (median 2.9%), Mo (5 mg/kg), V (82 mg/kg) and S (0.09%). Chicago soils are enriched from about 1.6- to 3-fold in these elements. Enrichments in P and Se may be caused by direct addition of phosphate fertilizer to parklands, lawns and gardens. The density of the sampling (1 site per 10 km²) is inadequate to define the distribution of the observed enrichments within the city or to predict soil compositions for most of the areas between sample sites, but does provide a statistically significant signature of the history of urban and industrial activity within the city in contrast to the surrounding agricultural lands.     

Hornblende gabbro sill complex at Onion Valley,California, and a mixing origin for the Sierra Nevada batholith

 The steep crest of the Sierra Nevada, California, near Onion Valley, exposes natural cross sections through a mafic intrusive complex that formed as part of the Mesozoic Sierra Nevada batholith. Sheeted sills of hornblende gabbro to hornblende diorite, individually as thick as 1.5 m, form the upper 200 to 300 m of the complex. Thicker, multiply-injected sills, as well as mafic stocks, lie underneath at elevations below 3600 m. Lens-shaped cumulate bodies, as thick as 200 m and more than 700 m broad, lie near the base of the sheeted sill suite. Cumulates are flat-lying, modally layered hornblende gabbro with subsidiary ultramafic olivine hornblendite, plagioclase hornblendite, and late-mobile hornblende-plagioclase pegmatite. Fine grain size, scarce phenocrysts and xenocrysts, and quench mineral textures are evidence that hornblende gabbro sills injected in a largely liquid state and preserve basaltic melt compositions. Most sills reached volatile saturation, as shown by tiny miarolitic cavities that are also widespread in cumulates. Although some sills chilled directly against others, most chilled against septa, millimeters to a few centimeters thick, of medium-grained diorite to granodiorite. Mutually crosscutting relations, as well as chilling, show that the septa were partly molten at the time the sills injected and likely formed the lower portions of an overlying more silicic magma chamber that has since been removed by erosion. Sill compositions range from evolved high-alumina basalt to aluminous andesite with major and trace element abundances similar to those of modern arc magmas. Experimental phase equilibria indicate dissolved water contents near 6 wt% (Sisson and Grove 1993a). The sills show unequivocally that hydrous arc basaltic magmas reached shallow levels in the crust during formation of the largely granodioritic Sierra Nevada batholith. The basaltic magmas appear to have been produced from an enriched mantle source with ⁸⁷Sr/⁸⁶Sr ∼0.7065, ɛNd ∼−4.3, ²⁰⁶Pb/²⁰⁴Pb ∼18.6, ²⁰⁷Pb/²⁰⁴Pb ∼15.6, ²⁰⁸Pb/²⁰⁴Pb ∼38.6. Although crystal fractionation contributed to forming the sill suite and the associated cumulates, nearly constant concentrations of Na₂O, P₂O₅, Nb, Zr, and light rare earth elements in the sills indicate that mixing between sill basaltic and more evolved septa magmas was important for producing sills with andesitic compositions. Average Sierran granodiorite major and trace element concentrations are readily reproduced by a simple mixture of average basaltic sill from Onion Valley and average Sierran low-silica granite. This result supports the inference that Sierran granitoids formed chiefly by mixing between crustal and mantle-derived magmas, although in some cases these crustal melts may have been derived by refusion of earlier mafic intrusions near the base of the crust. The common mafic inclusions (enclaves) in Sierran granodiorites bear a superficial resemblance to Onion Valley mafic sills; however, high concentrations of lithophile elements in the inclusions point to extensive chemical exchange between inclusions and their host magmas. The prevalence of hornblende-rich mafic intrusive rocks at Onion Valley, elsewhere in the Sierra Nevada, and in other shallow subduction batholiths stems from two effects of high melt water concentrations (∼4–6 wt% H₂O). The hydrous parent basaltic and basaltic andesite magmas had low liquidus temperatures, compared to nearly dry basaltic melts, and thus were chilled less during ascent through the crust and were more capable of ascent as liquids. More importantly, their high water concentrations led to low melt densities, higher than granitoid liquids, but comparable to or less dense than partly solidified granitoid magmas. Thus, the hydrous basaltic and basaltic andesite magmas were neutrally or positively buoyant and were capable of penetrating and rising through partly crystallized granitoids and their partly molten source regions to reach upper crustal emplacement levels. Drier basaltic magmas were probably abundant at depth and contributed heat and mass to granite generation, but were insufficiently buoyant to ascend to shallow levels. Received: 2 August 1995 / Accepted: 26 June 1996     

Late Pleistocene Glaciations in the Northwestern Sierra Nevada, California

Pleistocene fluvial landforms and riparian ecosystems in central California responded to climate changes in the Sierra Nevada, yet the glacial history of the western Sierra remains largely unknown. Three glacial stages in the northwestern Sierra Nevada are documented by field mapping and cosmogenic radionuclide surface-exposure (CRSE) ages. Two CRSE ages of erratic boulders on an isolated till above Bear Valley provide a limiting minimum age of 76,400±3800 ¹⁰Be yr. Another boulder age provides a limiting minimum age of 48,800±3200 ¹⁰Be yr for a broad-crested moraine ridge within Bear Valley. Three CRSE ages producing an average age of 18,600±1180 yr were drawn from two boulders near a sharp-crested bouldery lateral moraine that represents an extensive Tioga glaciation in Bear Valley. Nine CRSE ages from striated bedrock along a steep valley transect average 14,100±1500 yr and suggest rapid late-glacial ice retreat from lower Fordyce Canyon with no subsequent extensive glaciations. These ages are generally consistent with glacial and pluvial records in east-central California and Nevada.     

Mesozoic transpression,transtension, subduction and metallogenesis in northern and central California

Middle Paleozoic to Middle Jurassic terrane assemblies in the Klamaths and Sierran Foothills consist of mafic–ultramafic complexes + fine‐grained terrigenous strata derived from previously accreted continental‐margin belts. Sutured oceanic terranes reflect c. 230 Myr of margin‐parallel slip involving chiefly transtension and transpression. Quartzofeldspathic clastic rocks and blueschists ± eclogites are very rare. Little devolatilization occurred at magmagenic depths; hence, coeval hydrothermal ore deposits and granitoids are uncommon. In contrast, nearly head‐on Cretaceous subduction of the Farallon plate generated the massive Klamath–Sierra Nevada volcanic–plutonic arc, reflecting dewatering of the eastward descending oceanic lithosphere in the magmagenic zone. Immature Great Valley forearc and Franciscan trench deposits shed from the arc record c. 70 Myr. of rapid crustal growth. Au‐bearing solutions rising from magmagenic depths, exsolved from plutons, and expelled from heated wall rocks were mobilized attending arc construction. Precipitation of gold‐bearing quartz veins occurred where H₂O + CO₂‐bearing fluids encountered major geochemical discontinuities in the wall rocks.     

Geomorphological analysis of neotectonic deformation,northern Owens Valley,California

At the western edge of the Basin and Range Province, the Owens Valley is the site of active seismicity and deformation. Morphometric analyses of three geomorphological features are used to determine the patterns and rates of neotectonic deformation: (l) a network of Pleistocene channels cut on top of the Bishop Tuff; (2) uplifted terraces of the Owens River; and (3) alluvial fans of the White Mountain front.In the Owens Valley, the three analyses are consistent with the same solution: net eastward tilt of the Owens Valley block at a rate of between 3.5 and 6.1°/Ma. Given the dip on the basement determined from geophysical data and extrapolating the rate of tilt in the Owens Valley back in time, it is inferred that the break-up of the Sierra Nevada and the northern Owens Valley occurred in the Pliocene, between around 2 and 4 Ma ago. The pattern of deformation in the northern Owens Valley matches anticlinal flexure on the Coyote warp, near the front of the Sierra Nevada, and faulting across the Volcanic Tableland is consistent with flexural extension. It is proposed that the Coyote warp is an expression of the tectonic hinge between westward rotation of the Sierra Nevada and eastward rotation of the Owens Valley since the Pliocene.     

Distribution of elements in biotite-hornblende pairs and in an orthopyroxene-clinopyroxene pair from zoned plutons,northern Sierra Nevada,California

Distribution of major and minor elements has been determined for five hornblende-biotite pairs from hornblende-biotite quartz diorite and monzotonalite and for a clinopyroxene-orthopyroxene pair from pyroxene diorite collected from the border zones and centers of zoned plutons in the northern Sierra Nevada, California. The distribution coefficients K _d [Mg/Fe] for biotite/hornblende are of the same magnitude (0.61–0.67) for both the mafic border zone and the silicic center.For comparison, K _D [Mg/Fe] values for biotite/hornblende from plutonic rocks of the central Sierra Nevada and the southern California batholith were calculated from data published by others. Rocks of the oldest age group (ca. 150 m.y.) in the central Sierra Nevada have an average distribution coefficient, K _D , of 0.64, close to the average K _D in the study area, where K-Ar dates are 143 to 129 m.y. The intermediate age group has an average K _D =0.81, and the youngest group has K _D =0.77. K _D [Mg/Fe] for biotite/hornblende from the southern California batholith is 0.83, close to the average of the intermediate age group in the central Sierra Nevada. The calculated difference in pressure of crystallization between rocks of the Feather River area and the southern California batholith is 1 kb; the rocks of the Feather River area being crystallized at a higher pressure. This is in good agreement with the low-pressure contact metamorphism in the south (pyroxene hornfels facies), as compared with a medium-pressure metamorphism around the northern plutons, where andalusitesillimanite-cordierite and andalusite-staurolite subfacies of the amphibolite facies indicate pressures of about 4 kb.Trace elements Cr, V, Ni, Co, Ga are distributed equally between biotite and hornblende, whereas Ba and possibly Cu are concentrated in biotite and Sr and Sc and possibly Zr in hornblende.Publication authorized by the Director, U.S. Geological Survey.     

Late Cretaceous-Paleocene Extensional Collapse and Disaggregation of the Southernmost Sierra Nevada Batholith

Geobarometric studies have documented that most of the metasedimentary wall rocks and plutons presently exposed in the southernmost Sierra Nevada batholith south of the Lake Isabella area were metamorphosed and emplaced at crustal levels significantly deeper (～15 to 30 km) than the batholithic rocks exposed to the north (depths of ～3 to 15 km). Field and geophysical studies have suggested that much of the southernmost part of the batholith is underlain along low-angle faults by the Rand Schist. The schist is composed mostly of metagraywacke that has been metamorphosed at relatively high pressures and moderate temperatures. NNW-trending compositional, age, and isotopic boundaries in the plutonic rocks of the central Sierra Nevada appear to be deflected westward in the southernmost part of the batholith. Based on these observations, in conjunction with the implicit assumption that the Sierra Nevada batholith formerly continued unbroken south of the Garlock fault, previous studies have inferred that the batholith was tectonically disrupted following its emplacement during the Cretaceous. Hypotheses to account for this disruption include intraplate oroctinal bending, W-vergent overthrusting, and gravitational collapse of overthickened crust. In this paper, new geologic data from the eastern Tehachapi Mountains, located adjacent to and north of the Garlock fault in the southernmost Sierra Nevada, are integrated with data from previous geologic studies in the region into a new view of the Late Cretaceous-Paleocene tectonic evolution of the region. The thesis of this paper is that part of the southernmost Sierra Nevada batholith was unroofed by extensional faulting in Late Cretaceous-Paleocene time. Unroofing occurred along a regional system of low-angle detachment faults. Remnants of the upper-plate rocks today are scattered across the southern Sierra Nevada region, from the Rand Mountains west to the San Emigdio Mountains, and across the San Andreas fault to the northern Salinian block.

Batholithic rocks in the upper plates of the Blackburn Canyon fault of the eastern Tehachapi Mountains, low-angle faults in the Rand Mountains and southeastern Sierra Nevada, and the Pastoria fault of the western Tehachapi Mountains are inferred to have been removed from a position structurally above rocks exposed in the southeastern Sierra Nevada and transported to their present locations along low-angle detachment faults. Some of the granitic and metamorphic rocks in the northern part of the Salinian block are suggested to have originated from a position structurally above deep-level rocks of the southwestern Sierra Nevada. The Paleocene-lower Eocene Goler Formation of the El Paso Mountains and the post-Late Cretaceous to pre-lower Miocene Witnet Formation in the southernmost Sierra Nevada are hypothesized to have been deposited in supradetachment basins that formed adjacent to some of the detachment faults.

Regional age constraints for this inferred tectonic unroofing and disaggregation of the southern Sierra Nevada batholith suggest that it occurred between ～90 to 85 Ma and ～55 to 50 Ma. Upper-plate rocks of the detachment system appear to have been rotated clockwise by as much as 90° based on differences in the orientation of foliation and contacts between inferred correlative hanging-wall and footwall rocks. Transport of the upper-plate rocks is proposed to have occurred in two stages. First, the upper crust in the southern Sierra Nevada extended in a south to southeast direction, and second, the allochthonous rocks were carried westward at the latitude of the Mojave Desert by a mechanism that may include W-vergent faulting and/or oroclinal bending. The Late Cretaceous NNW extension of the upper crust in the southernmost Sierra Nevada postulated in this study is similar to Late Cretaceous, generally NW-directed, crustal extension that has been recognized to the northeast in the Funeral, Panamint, and Inyo mountains by others. Extensional collapse of the upper crust in the southern Sierra Nevada batholith may be closely linked to the emplacement of Rand Schist beneath the batholith during Late Cretaceous time, as has been suggested in previous studies.     

Chronology of glaciations in the Sierra Nevada,California, from 10Be surface exposure dating

We use ¹⁰Be surface exposure dating to construct a high-resolution chronology of glacial fluctuations in the Sierra Nevada, California. Most previous studies focused on individual glaciated valleys, whereas our study compares chronologies developed throughout the range to identify regional patterns in the timing of glacier response to major climate changes. Sites throughout the range indicate Last Glacial Maximum retreat at 18.8 ± 1.9 ka (2σ) that suggests rather consistent changes in atmospheric variables, e.g., temperature and precipitation, throughout the range. The penultimate glacial retreat occurred at ca 145 ka. Our data suggest that the Sierra Nevada landscape is dominated by glacial features deposited during marine isotope stage (MIS) 2 and MIS 6. Deposits of previously recognized glaciations between circa 25 and 140 ka, e.g., MIS 4, Tenaya, early Tahoe, cannot be unequivocally identified. The timing of Sierra Nevada glacial retreat correlates well with other regional paleoclimate proxies in the Sierra Nevada, but differs significantly from paleoclimate proxies in other regions. Our dating results indicate that the onset of LGM retreat occurred several thousand years earlier in the Sierra Nevada than some glacial records in the western US.     

The occurrence and distribution of tin with particular reference to marine environments

Concentrations of tin in sea water decreased from estuarine and shelf (0.02-0.04 μg/kg) to surface Atlantic waters (0.009 μg/kg). Mean contents (ppm) in other materials included: ultramafic rocks, 0.8; basalts, 1.7; silicic rocks, 2.5; red clays, 3.4; amphibolites, 1.2. Oceanic ferromanganese deposits contained from 0.2 to 5.8 ppm; tin and cobalt contents were correlated.     

Exposure of a late cretaceous layered mafic-felsic magma system in the central Sierra Nevada batholith,California

New U-Pb zircon ages for the Lamarck Granodiorite, associated synplutonic gabbro and diorite plutons, and two large mafic intrusive complexes that underlie them in the Sierra Nevada batholith are 92±1 Ma. These ages establish the Late Cretaceous as a period of extensive mafic-felsic magmatism in the central part of the batholith, and confirm the significance of mafic magmatism in the evolution of the voluminous silicic plutions in the Sierran arc. The lack of significant zircon inheritance in any of the units analyzed supports isotopic evidence that the Lamarck and other Late Cretaceous Sierran plutons were derived predominantly from young crust. Recognition of an extensive mafic-felsic magma system in the Sierra Nevada batholith emphasizes the importance of basaltic liquids in the evolution of continental crust in arc settings.     

Salinia revisited: a crystalline nappe sequence lying above the Nacimiento fault and dispersed along the San Andreas fault system,central California

Salinia, as originally defined, is a fault-bounded terrane in westcentral California. As defined, Salinia lies between the Nacimiento fault on the west, and the Northern San Andreas fault (NSAF) and the main trace of the dextral SAF system on the east. This allochthonous terrane was translated from the southern part of the Sierra Nevada batholith and adjacent western Mojave Desert region by Neogene-Quaternary displacement along the SAF system. The Salina crystalline basement formed a westward promontory in the SW Cordilleran Cretaceous batholithic belt, relative to the Sierra Nevada batholith to the north and the Peninsular Ranges batholith to the south, making Salinia batholithic rocks susceptible to capture by the Pacific plate when the San Andreas transform system developed. Proper restoration of offsets on all branches of the San Andreas system is a critical factor in understanding the Salinia problem. When cumulative dextral slip of 171 km (106 mi) along the Hosgri–San Simeon–San Gregorio–Pilarcitos fault zone (S–N), or dextral slip of 200 km (124 mi) along the Hosgri–San Simeon–San Gregorio–Pilarcitos–northern San Andreas fault system, is added to the cumulative dextral slip of 315–322 km (196–200 mi) along the main trace of the SAF north of the San Emigdio–Tehachapi mountains, central California, there is a minimum amount of cumulative dextral slip of 486 km (302 mi) or a maximum amount of cumulative dextral slip of 522 km (324 mi) along the entire SAF system north of the Tehachapi Mountains. When these sums are compared with the offset distance (610–675 km or 379–420 mi) between the batholithic rocks associated with the Navarro structural discontinuity (NSD) in northern California, and those in the ‘tail’ of the southern Sierra Nevada granitic rocks in the San Emigdio–Tehachapi mountains, central California, a minimum deficit of from ～100 km (～62 mi) to a maximum deficit of ～189 km (～118 mi) is needed to restore the crystalline rocks associated with the NSD with the crystalline terranes within the San Emigdio and Tehachapi mountains – the enigma of Salinia. Two principal geologic models compete to explain the enigma (i.e. the discrepancy between measured dextral slip along traces of the SAF system and the amount of separation between the Sierra Nevada batholithic rocks near Point Arena in northern California and the Mesozoic and older crystalline rocks in the San Emigdio and Tehachapi mountains in southern California). (i) One model proposes pre-Neogene (>23 Ma), Late Cretaceous or Maastrichtian (<ca. 71 Ma) to early Palaeocene or Danian (ca. 66 Ma) sinistral slip of 500–600 km (311–373 mi) along the Nacimiento fault and of the western flank of Salinia from the eastern flank of the Peninsular Ranges (sinistral slip but in the opposite sense to later Neogene (<23 Ma) dextral slip along and within the SAF system. (ii) A second model proposes that the crystalline rocks of Salinia comprise a series of 100 km- (60 mi-) scale allochthonous (extensional) nappes that rode southwestward above the Rand schist–Sierra de Salinas (SdS) shear zone subduction extrusion channels. The allochthonous nappes are from NW–SE: (i) Farallon Islands–Santa Cruz Mountains–Montara Mountain, and adjacent batholithic fragments that appear to have been derived from the top of the deep-level Sierra Nevada batholith of the western San Emigdio–Tehachapi mountains; (ii) the Logan Quarry–Loma Prieta Peak fragments that appear to have been derived from the top of a buried detachment fault that forms the basement surface beneath the Maricopa sub-basin of the southernmost Great Valley; (iii) The Pastoria plate–Gabilan Range massif that appears to have been derived from the top of the deep-level SE Sierra Nevada batholith; and (iv) the Santa Lucia–SdS massif, which appears to be lower batholithic crust and underlying extruded schist that were breached westwards from the central to western Mojave Desert region. In this model, lower crustal batholithic blocks underwent ductile stretching above the extrusion channel schists, while mid- to upper-crustal level rocks rode southwestwards and westwards along trenchward dipping detachment faults. Salinian basement rocks of the Santa Lucia Range and the Big Sur area record the most complete geologic history of the displaced terrane. The oldest rocks consist of screens of Palaeozoic marine metasedimentary rocks (the Sur Series), including biotite gneiss and schist, quartzite, granulite gneiss, granofels, and marble. The Sur Series was intruded during Cretaceous high-flux batholithic magmatism by granodiorite, diorite, quartz diorite, and at deepest levels, charnockitic tonalite. Local nonconformable remnants of Campanian–Maastrichtian marine strata lie on the deep-level Salinia basement, and record deposition in an extensional setting. These Cretaceous strata are correlated with the middle to upper Campanian Pigeon Point (PiP) Formation south of San Francisco. The Upper Cretaceous strata, belonging to the Great Valley Sequence, include clasts of the basement rocks and felsic volcanic clasts that in Late Cretaceous time were brought to a coastal region by streams and rivers from Mesozoic felsic volcanic rocks in the Mojave Desert. The Rand and SdS schists of southern California were underplated beneath the southern Sierra Nevada batholith and the adjacent Salinia-Mojave region along a shallow segment of the subducting Farallon plate during Late Cretaceous time. The subduction trajectory of these schists concluded with an abrupt extrusion phase. During extrusion, the schists were transported to the SW from deep- to shallow-crustal levels as the low-angle subduction megathrust surface was transformed into a mylonitic low-angle normal fault system (i.e. Rand fault and Salinas shear zone). The upper batholithic plate(s) was(ere) partially coupled to the extrusion flow pattern, which resulted in 100 km-scale westward displacements of the upper plate(s). Structural stacking, temporal and metamorphic facies relations suggest that the Nacimiento (subduction megathrust) fault formed beneath the Rand-SdS extrusion channel. Metamorphic and structural relations in lower plate Franciscan rocks beneath the Nacimiento fault suggest a terminal phase of extrusion as well, during which the overlying Salinia underwent extension and subsidence to marine conditions. Westward extrusion of the subduction-underplated rocks and their upper batholithic plates rendered these Salinia rocks susceptible to subsequent capture by the SAF system. Evidence supporting the conclusion that the Nacimiento fault is principally a megathrust includes: (i) shear planes of the Nacimiento fault zone in the westcentral Coast Ranges locally dip NE at low angles. (ii) Klippen and/or faulted klippen are locally present along the trace of the Nacimiento fault zone from the Big Creek–Vicente Creek region south of Point Sur near Monterey, to east of San Simeon near San Luis Obispo in central California. Allochthonous detachment sheets and windows into their underplated schists comprise a composite Salinia terrane. The nappe complex forming the allochthon of Salinia was translated westward and northwestward ～100 km (～62 mi) above the Nacimiento megathrust or Franciscan subduction megathrust from SE California between ca. 66 and ca. 61 Ma (i.e. latest Cretaceous–earliest Palaeocene time). Much, or all, of the westward breaching of the Salinia batholithic rocks likely occurred above the extrusion channels of the Rand-SdS schists; following this event, the Franciscan Sur-Obispo terrane was thrust beneath the schists, perhaps during the final stages of extrusion in the upper channel. Later, the Sur-Obispo terrane was partially extruded from beneath the Salinia nappe terrane, during which time the upper plate(s) underwent extension and subsidence to marine conditions. Attenuation of the Salinia nappe sequence during the extrusion of the Franciscan Complex thinned the upper crust, making the upper plates susceptible to erosion from the top of the Franciscan Complex near San Simeon, where it is now exposed. In the San Emigdio Mountains, the relatively thin structural thickness of the upper batholithic plates made them susceptible to late Cenozoic flexural folding and disruption by high-angle dip–slip faults. The ～100 km (～62 mi) of westward and northwestward breaching of the Salinia batholithic rocks above the Rand-SdS channels, and the underlying Nacimiento fault followed by ～510 km (～320 mi) of dextral slip from ～23 Ma to Holocene time along the SAF system, allow for the palinspastic restoration of Salinia with the crystalline rocks of the San Emigdio–Tehachapi mountains and the Mojave terrane, resolving the enigma of Salinia.     

The persistence of lead from past gasoline emissions and mining drainage in a large riparian system: Evidence from lead isotopes in the Sacramento River, California

Lead concentrations and isotope ratios measured in river water colloids and streambed sediment samples along 426 km of the Sacramento River, California reveal that the influence of lead from the historical mining of massive sulfide deposits in the West Shasta Cu-mining district (at the headwaters of the Sacramento River) is confined to a 60 km stretch of river immediately downstream of that mining region, whereas inputs from past leaded gasoline emissions and historical hydraulic Au-mining in the Sierra Nevadan foothills are the dominant lead sources in the remaining 370 km of the river. Binary mixing calculations suggest that more than 50% of the lead in the Sacramento River outside of the region of influence of the West Shasta Cu-mining district is derived from past depositions of leaded gasoline emissions. This predominance is the first direct documentation of the geographic extent of gasoline lead persistence throughout a large riparian system (>160,000 km²) and corroborates previous observations based on samples taken at the mouth of the Sacramento River. In addition, new analyses of sediment samples from the hydraulic gold mines of the Sierra Nevada foothills confirm the present-day fluxes into the Sacramento River of contaminant metals derived from historical hydraulic Au-mining that occurred during the latter half of the 19th and early part of the 20th centuries. These fluxes occur predominantly during periods of elevated river discharge associated with heavy winter precipitation in northern California. In the broadest context, the study demonstrates the potential for altered precipitation patterns resulting from climate change to affect the mobility and transport of soil-bound contaminants in the surface environment.     

Magma accumulation rates and thermal histories of plutons of the Sierra Nevada batholith,CA

Zircon U–Pb geochronology results indicate that the John Muir Intrusive Suite of the central Sierra Nevada batholith, California, was assembled over a period of at least 12 Ma between 96 and 84 Ma. Bulk mineral thermochronology (U–Pb zircon and titanite, ⁴⁰Ar/³⁹Ar hornblende and biotite) of rocks from multiple plutons comprising the Muir suite indicates rapid cooling through titanite and hornblende closure following intrusion and subsequent slow cooling through biotite closure. Assembly of intrusive suites in the Sierra Nevada and elsewhere over millions of years favors growth by incremental intrusion. Estimated long-term pluton assembly rates for the John Muir Intrusive Suite are on the order of 0.001 km³ a⁻¹ which is inconsistent with the rapid magma fluxes that are necessary to form large-volume magma chambers capable of producing caldera-forming eruptions. If large shallow crustal magma chambers do not typically develop during assembly of large zoned intrusive suites, it is doubtful that the intrusive suites represent cumulates left behind following caldera-forming eruptions.     

Pb and Sr systematics of ultrapotassic and basaltic rocks from the central Sierra Nevada,California

This study presents Sr and Pb isotopic ratios and Rb, Sr, U, Th, and Pb concentrations of an ultrapotassic basaltic suite and related rocks from the central Sierra Nevada, California. The ultrapotassic suite yields a narrow range of Sr and Pb isotopic compositions (⁸⁷Sr/⁸⁶Sr=0.70597–0.70653; ²⁰⁶Pb/ ²⁰⁴Pb=18.862–19.018; ²⁰⁷Pb/²⁰⁴Pb=15.640–15.686; ²⁰⁸Pb/ ²⁰⁴Pb=38.833–38.950). Associated basalts containing ultramafic nodules have less radiogenic Sr (⁸⁷Sr/⁸⁶=0.70430–0.70521) and generally higher Rb/Sr ratios than the ultrapotassic suite. Leucitites from Deep Springs Valley, California, contain high ⁸⁷Sr/⁸⁶Sr (71141–0.71240) and low ²⁰⁶Pb/²⁰⁴Pb (17.169–17.234) ratios, reflecting contamination by crustal granulite.The isotopic relationships support an origin of the ultrapotassic basaltic suite by partial melting of an enriched upper mantle source. Dehydration of a gently inclined oceanic slab beneath the Sierra Nevada may have provided Ba, K, Rb, Sr, and H₂O, which migrated into the overlying upper mantle lithosphere. The end of subduction 10 m.y. ago allowed increased asthenospheric heat flow into the upper mantle lithosphere. The increased heat flow enhanced fluid movement in the upper mantle and contributed towards isotopic homogenization of the upper mantle source areas. Continued heating of the enriched upper mantle caused partial melting and subsequent eruption of the ultrapotassic lavas.