脆韧性剪切带变碳酸盐岩CO2的释放能力：—以郯廊断裂系南段双山断裂为例

为求算经受动力变质作用岩石释放CO2的能力，特选择变碳酸岩区的一条脆韧性断层岩，对其进行构造蚀变岩石矿物学和地球化学分析，求得每100克碳酸质母岩在蚀变反应过程中可释放33．90克CO2气体分子，其质量占母岩质量的1／3；流体在岩石动力蚀变中起重要作用。     

郯庐断裂带南段晚期韧性剪切带涡度分析及其构造意义

天然剪切带通常都是简单剪切和纯剪切叠加的一般剪切的产物。通过测量韧性剪切带的运动学涡度，可以很好地解决剪切带变形过程中究竟是简单剪切占优势还是纯剪切占优势的问题。本次研究中利用石英C轴组构与主应变比值的方法以及石英C轴组构与斜列颗粒形态的方法，测量了郯庐断裂带南段晚期韧性剪切带的运动学涡度。获得的运动学涡度主要介于0．80～0．95之间，明显大于0．75且小于1，指示郯庐晚期左旋走滑韧性剪切带的变形以简单剪切为主的同时，还存在一个纯剪切分量。根据本次研究获得的涡度值、断层产状以及断裂带的运动学特征综合分析，可以认为郯庐晚期韧性剪切带是一个具有压扭性质的走滑构造。并且，本次工作中获得的运动学涡度支持伊佐奈崎板块与欧亚板块的边界为典型的汇聚型板块边界的现有成果。     

郯庐断裂带南段桴槎山韧性剪切带糜棱岩的变形条件和组分迁移系

本文对郯庐断裂带南段主干断裂典型的韧性剪切带进行了系统的剖析。从糜棱岩塑性变形的亚颗粒化、动态重结晶和矿物成分特征及岩石组分迁移变化等入手进行系统的研究工作,计算了岩石形成的温度、压力和流动应力和流变速率参数;模拟计算了岩石在剪切变形作用下的体积亏损及组分迁移的量值,探讨了变形－变质及流体的相关关系     

郯庐断裂带渤南段构造特征及其控盆作用

渤南地区郯庐断裂带具有很好的油气勘探前景,但由于其构造特征复杂,目前对渤南地区油气成藏条件、主控因素及富集规律的认识尚不明晰.通过对三维地震和地质资料的分析解释,结合前人研究成果,探讨了渤南地区郯庐断裂带构造特征的时空差异及其对盆地结构的控制作用.研究表明,渤南地区郯庐断裂带具有3组分支断裂,每组分支断裂由2~4条断裂构成,均表现出了明显的走滑特征,整体由东向西、由深至浅走滑程度逐渐减弱.新生代古新世-早始新世郯庐断裂带渤南段左旋走滑,东部分带活动明显、强度大,中带和西带不活动或活动较弱,渤南地区中生代发育的NWW向伸展断裂系统复活,形成北断南超的复式半地堑或南北双断式结构;中始新世以来,渤南地区郯庐断裂带转为右旋走滑,3组分支断裂均开始活动,表现为强烈的走滑兼伸展运动,强度由东向西逐渐减弱,中带分支断裂形成的中央构造脊将黄河口凹陷分割成东、西两个次洼,并开始逐渐发育一系列次级断层,与主断裂构成帚状断裂组合;新近纪-第四纪郯庐断裂渤南段表现为右旋走滑兼挤压,主走滑断裂不连续,代之以大量规模较小的次级断裂系统.太平洋区板块俯冲方向、俯冲速率的变化以及深部动力背景的变迁共同造成了渤南地区郯庐断裂不同分支构造发育演化及其控盆作用的差异性,由于右旋走滑位移量小于先期的左旋走滑,现今渤南地区构造单元分布仍具左旋特征.      

郯庐断裂带肥东韧性剪切带的变形规律同位素年龄及其构造意义

郯庐断裂带肥东韧性剪切带的几何学形态为一正花状左行平移断裂带，目前出露的为该韧性剪切带的根部，具有典型的深层次左行走滑变形特征，肥东韧性剪切带中糜棱岩，超糜棱岩测得的^40Ar/^39Ar全岩年龄分别为120.48Ma和118.75Ma，说明郯庐断裂带的大规模左行平移时代为早白垩世，对该带构造变形和构造叠加的研究表明，肥东浮槎山一带是被郯庐断裂带截切，牵引，叠加，改造的印支期大别一胶南造山带的残块，郯庐断裂带与大别-胶南造山带是不同时期，不同构造系统的产物，前者属于滨太平洋构造系统，后者属于特提斯构造系统。     

接触变质条件下变碳酸岩CO2释放与定量计算——以郯庐断裂南段肥东县双山为例

为了探讨接触变质带内变碳酸盐岩变质过程CO₂释放的数量和排放CO₂的物理、化学及地质条件,根据递进变质反应和时间积分流体通量模型,定量分析和定量计算了双山地区变碳酸盐岩在接触变质作用中释放CO₂的通量。计算结果得到CO₂的通量值为0.729×104~2.446×104 mol/cm2,CO₂的来源以接触变质反应释放为主;CO₂的生成释放与变质程度呈正相关关系。自白云石带至方解石带变质流体中X_CO2不断升高,但钙铝榴石带由于岩浆水影响,流体通量最高而X_CO2急剧下降。      

郯庐断裂带南段并无巨大平移—来自安徽境内的证据

本文根据新近1：5万地质填图和构造调查所获资料，依据郯庐断裂带两侧标志地质体（西冷岩组火山岩，宿松岩群和肥东岩群中磷矿层，大别岩群和阚集岩群）的构造型式和错位情况，拉伸线理的性质和动向，以及郯庐断裂带两侧的次级断裂带特征等，都不能判定郯庐断裂带存在巨大左行平移，故认为大别－苏鲁造山带呈弧形展布，基本代表了原始构造方位，郯庐断裂带是多期构造变动形成的负向构造带，综合造就的一种假位错效应。     

郯庐断裂带中-南段新生代火山活动与深部过程

郯庐断裂带中南段新生代火山活动主要发生在古近纪、中新世和更新世3个阶段,前者出现在断裂带的伸展活动中,后两者出现在挤压活动中。随着时代变新,玄武岩碱性逐渐增强,轻、重稀土元素分离程度及不相容元素富集程度也逐渐增强。Sr、Nd同位素显示,源区地幔具有轻微富集型(EMⅠ)→洋岛型→洋中脊型的演化规律。断裂带所影响的地幔发生了地幔剪切变形及显著的交代作用,两者相互促进。断裂带在新生代演化中切割深度不断加大,火山源区不断加深,现今已切穿了整个岩石圈。断裂带在新生代软流圈上隆的背景下,经过地幔剪切、减压、地幔交代及部分熔融等深部过程,从而出现了大规模的玄武岩喷发。     

郯庐断裂带中-南段中生代岩浆活动的构造背景与深部过程

郯庐断裂带内岩浆岩及糜棱岩的年龄及野外研究表明以中-酸性为主的岩浆活动主要发生在早白垩世走滑运动的晚期,岩石化学以富钾、富碱为特征;稀土元素以轻稀土富集、重稀土亏损为特征;微量元素表现出富集大离子亲石元素,尤其是强不相容元素;同位素组成显示岩浆来源于壳幔过渡带.带内岩浆活动明显受断裂带控制,走滑晚期的岩浆活动起源于地幔底侵、壳幔相互作用下的壳幔过渡带,在伊泽奈崎板块斜向俯冲、中国东部遭受区域性剪切-挤压的背景下出现.在此背景下中国东部发生了岩石圈减薄,同时出现了一系列北东-北北东向已深切至壳幔边界的左行平移断裂系,从而诱发了大规模的岩浆活动.     

郯庐断裂带肥东桃源韧性剪切带构造分析及时限探究

郯庐断裂带在肥东桃源地区为一混合杂岩带,温压数据显示区域内变形变质环境为中下地壳构造环境。本文对剪切带的应变大小、应变速率、涡度以及应力场等构造特征进行分析测量,结果显示该剪切带所受应力方向为170°左右,夹角为40°～50°,并以简单剪切为主,其变形矿物被拉长。此外,带内发育的长英质糜棱岩流体以及伟晶岩流体均发生同构造变形,本文结合前期年代学研究结果,整合出了3种不同流体之间的关系,并有效限定出带内韧性剪切活动发生在140～124 Ma之间。同时,通过对郯庐断裂带中南段年代学数据统计,发现郯庐断裂带肥东段主要记录了早白垩世的剪切活动,而大别造山带东缘、苏鲁西缘分别记录了同造山年代学数据,断裂带中南段在年代学分布上呈现出明显的空间差异性,反映出郯庐断裂带递进变形的特征。     

Calculation of the CO2 Degassing during Contact Metamorphism and Its Geological Significance: The Model and Example from the Shuanshan Area of the South Tan–Lu Fault Belt

The paper studies CO2 degassing and controlling factors under the condition of contact metamorphism in the Shuangshan area, southern Tan-Lu fault belt and the method of calculating the amount of CO2 degassing. The results show that the amount of CO2 degassing is controlled by the characteristics of the country rocks, including the thermal conductivity, penetrability, porosity and connectivity. Compositions, size and depth of intrusive rock also have an important influence on CO2 degassing, i.e., they generated numerous cracks in the country rocks, and thus allowed the easy flow and accumulation of fluids. The amount of CO2 flux in contact metamorphism is calculated quantitatively based on the metamorphic reaction and time-integrated fluid flux. The value （0.729- 2.446×10^4 mol/cm^2） of CO2 flux suggests that CO2 was provided mainly by the contact metamorphic reaction. The generation and releasing of CO2 are positively correlated with the degree of metamorphism, and XCO2 in fluids gradually increases from dolomite zone to calcite zone, but in the zone of grossular, fluid flux is the largest and XCO2 sharply decreases due to involvement of magmatic water. This study presents evidence that a large amount of industrial-scale CO2 can be produced during contact metamorphism. On the basis of theoretical and practical studies, a cone model has been proposed to response CO2 degassing for the contact metamorphism, and it can be used to explore CO2 accumulations beyond the oil-gas basins. This model can also be applied to the study of inorganic genesis of CO2 accumulations.     

Calculation of the CO2 Degassing during Contact Metamorphism and Its Geological Significance: The Model and Example from the Shuanshan Area of the South Tan-Lu Fault Belt

The paper studies CO2 degassing and controlling factors under the condition of contact metamorphism in the Shuangshan area, southern Tan-Lu fault belt and the method of calculating the amount of CO2 degassing. The results show that the amount of CO2 degassing is controlled by the characteristics of the country rocks, including the thermal conductivity, penetrability, porosity and connectivity. Compositions, size and depth of intrusive rock also have an important influence on CO2 degassing, i.e., they generated numerous cracks in the country rocks, and thus allowed the easy flow and accumulation of fluids. The amount of CO2 flux in contact metamorphism is calculated quantitatively based on the metamorphic reaction and time--integrated fluid flux. The value (0.729- 2.446×104 mol/cm2) of CO2 flux suggests that CO2 was provided mainly by the contact metamorphic reaction. The generation and releasing of CO2 are positively correlated with the degree of metamorphism, and XCO2 in fluids gradually increases from dolomite zone to calcite zone, but in the zone of grossular, fluid flux is the largest and XCO2 sharply decreases due to involvement of magmatic water. This study presents evidence that a large amount of industrial-scale CO2 can be produced during contact metamorphism. On the basis of theoretical and practical studies, a cone model has been proposed to response CO2 degassing for the contact metamorphism, and it can be used to explore CO2 accumulations beyond the oil-gas basins. This model can also be applied to the study of inorganic genesis of CO2 accumulations.     

Excess and Radiogenic Argon in High-Pressure Mylonites of the Tan-Lu Fault Zone, Eastern China

Bulk separates of porphyroclastic phengite, neoformed phengite and their mixtures from the Tan-Lu HP mylonites overprinted on the Sulu UHP rocks were analyzed with the 40Ar/39Ar step heating method. Two samples of the neoformed phengite from ultramylonite give 40Ar/39Ar plateau ages of 209.9±1.8 Ma and 214.3±1.8 Ma, which are interpreted as representing cooling times of the TanLu sinistral faulting, and provide geochronological evidence for the syn-orogenic faulting of the Tan-Lu fault zone. The results show that the phengite formed during the retrograde eclogite-facies mylonitization was not contaminated with excess argon and can be used for dating the deformation. Argon closure in previous K-bearing minerals with excess argon under a retrograde HP dry condition is considered to be the reason for lack of excess argon incorporation in the neoformed phengite. Five porphyroclastic phengite samples yield 40Ar/39Ar plateau ages ranging from 666±12 Ma to 307.1±3.3 Ma, which are interpreted as being contaminated with excess argon. Two mixture samples with plateau ages of 239.4±2.1 Ma and 239.3±2.0 Ma show upward-convex age spectra caused by the mixture of older porphyroclastic phengite with excess argon incorporation and younger neoformed phengite without excess argon incorporation. It is demonstrated that excess argon introduced from the previous UHP metamorphism is still preserved in the pre-existing phengite after the Tan-Lu eclogite-facies mylonitization. The intense deformation under HT and HP conditions cannot erase excess argon in the previous phengite totally due to restricted fluid activities. These porphyroclastic phengite previously contaminated with excess argon cannot be used for dating the later HP deformation. This indicates that deformation under a HP dry condition does not play an important role in removing previous 40Are in phengite.     

郯庐断裂带莒县地区早白垩世中酸性火山岩成因及其地质意义

莒县早白垩世火山岩沿郯庐断裂带分布,由粗安岩、粗面岩和流纹岩组成,属高钾钙碱性-钾玄岩系列.岩石富集Rb、K、Ba等大离子亲石元素和轻稀土元素,相对亏损Nb、Ta、Ti等高场强元素和重稀土元素,Sr-Nd同位素组成((87Sr/86Sr)t=0.7082～0.7095,ENd(t)=-16.4～-19.8)与区内基性岩的相类似,而Pb同位素组成((206pb/204Pb)t=16.523～17.038,(207pb/204Pb)t=15.414～15.468,(208pb/204Pb)t=37.058～37.427)类似于EM1型富集地幔.(87Sr/86Sr)t和εNd(t)与SiO2没有明显的相关性,且较高的Th/U、Ce/Pb值和较低的Nb/La、Nb/U值均暗示岩浆在上升过程中未遭受明显的地壳混染.粗安岩具有高的Cr、Ni、MgO含量及Mg#值和古老Nd同位素模式年龄,暗示其起源于富集的岩石圈地幔.粗面岩与粗安岩的主要氧化物、微量元素与SiO2呈明显的相关性,这暗示可能为同源岩浆结晶分异而来.研究表明,莒县地区中酸性火山岩形成于岩石圈伸展减薄背景下,由曾遭受俯冲扬子陆壳熔体改造的华北岩石圈地幔部分熔融形成的岩浆分离结晶作用而成.郯庐断裂带的伸展活动控制着火山岩的分布,为岩浆的形成和运移提供了有利的场所,在华北克拉通破坏中可能起到了重要的作用.     

郯庐断裂带对鲁西隆升过程的影响:磷灰石裂变径迹证据

郯庐断裂带(TLFZ)是一条贯穿华北的NNE向巨型断裂带。新生代以来,在郯庐断裂带的两侧及其内部发生了显著的伸展构造变形,形成了泰安-莱芜-蒙阴NW向断陷盆地群,并使鲁西块体发生了急剧的陆内伸展隆升。本文在前人研究的基础上,分别在鲁西沂山、徂徕山和蒙山三处进行了大量的样品采集,总计完成了25个样品的测试,获得了一系列新的磷灰石裂变径迹(AFT)年代学结果。结合前人已发表的裂变径迹结果,对鲁西地区新生代与伸展变形有关的剥露-隆升作用的时空分布特征、隆升剥露模式及隆升幅度进行分析,并揭示郯庐断裂带在鲁西新生代热隆升过程中的影响。主要认识有:1)新生代以来,鲁西主要经历了始新世-早渐新世和新近纪以来两期快速剥露-隆升阶段。2)始新世-早渐新世主要表现为幕式差异性快速剥露-隆升,鲁西南受NW向断层控制形成向北、向东的掀斜抬升作用,鲁西北受NE向断裂控制,形成向北、向西的掀斜抬升作用。新近纪以来,进入相对低速区域性剥露-隆升阶段。3)AFT模拟显示,与始新世-早渐新世的幕式快速剥露-隆升相比,中新世以来,鲁西剥露-隆升速率相对减小,但剥蚀量剥露-抬升量较大。故鲁西整体抬升于中新世以来。4)结合前人研究成果,新生代以来,鲁西宏观上受郯庐断裂带伸展活动影响,越靠近郯庐断裂带剥蚀量越大,局部受NW或NE向断裂控制。     

南大巴山前陆冲断带中带构造样式及变形机制

南大巴山前陆冲断带自北向南发育了根带、中带和锋带三条构造带。通过对处于中带的木瓜口-明月乡、城口-龙田乡两段剖面地质考察,结果表明该剖面叠瓦断层带经历了七期运动:三期NE-SW向的前展式逆冲运动,一期SE-NW右旋剪切运动,一期EW逆冲右旋运动,一期NE-SW向的左旋走滑运动及NE-SW向的正断运动,同时受到NW-SE的右旋剪切作用。结合前人年代学研究结果,初步探讨了剖面的变形机制,研究结果对南大巴山前陆褶断带的构造格架、矿产形成及油气分布远景研究均有一定的指导作用。     

Characteristics of Compositional Migration in Mylonites from the Ductile Shear Zones of the Southern Tancheng-Lujiang Fault Belt, Eastern Anhui Province

On the basis of field geology, three typical ductile shear zones in the southern part of the Tancheng-Lujiang fault belt have been chosen for a detailed study. Altogether ten samples of the tectonites have been collected for this study. The paper is focused on a comprehensive study of the tectonites in the medium-lower horizons of the ductile shear zones. The mineral compositions of the rocks are analyzed with EPMA and some typical whole-rock samples analyzed by chemical and ICP methods. Based on the comprehensive study of the characteristics of the deformation, the mineral assemblages and the changes of chemical composition of the bulk rocks, this paper presents a discussion on the relationship between the volume loss, the fluid flow and compositional changes during mylonitization of the ductile shear zones in this region. Our study shows that there are a large amount of fluids flowing through the shear zones during the process of mylonization, accompanied by the loss of rock volume and migration of el     

郯庐断裂新生代构造演化及其对烃源岩生排烃的影响:以辽东湾坳陷辽中凹陷为例

郯庐断裂带是渤海海域重要的活动断裂带,控制着该地区油气成藏的生储盖运圈保条件。以辽东湾坳陷辽中凹陷为研究对象,利用三维地震资料、平衡剖面分析对郯庐断裂几何学特征、演化特征进行研究;在此基础上,分析郯庐断裂走滑活动对烃源岩发育、分布、演化及生排烃的影响。辽东湾坳陷新生代构造演化分为为五个构造演化阶段、三个构造演化旋回。郯庐断裂走滑活动可错开先期、同期发育的烃源岩,改变烃源岩位置及生烃潜力的空间分布,有利于形成局部水体更深的还原环境,发育生烃潜力更大的烃源岩。走滑活动使断裂带附近地温梯度和大地热流升高,有利于降低生烃门限。郯庐断裂不同时期不同部位具有不同的活动性质,对油气运移起封闭或者运移通道作用。东营组沉积期晚期和明化镇组下段沉积期至今的断裂走滑活动与烃源岩大量生排烃期、油气成藏时期具有良好的匹配关系,提出郯庐断裂走滑活动可形成"拖曳"生排烃现象,使与走滑断层相关的圈闭中即使烃源岩条件较差亦可能具有勘探价值,从而突破了传统的油气勘探思路。     

冕宁-德昌稀土成矿带碳酸岩流体研究

通过对四川冕宁-德昌稀土矿带主要矿物中包裹体岩相学、显微测温分析与包裹体成分分析,指出由岩浆碳酸岩分异出的成矿流体为富含高密度CO2、K、Na、SO42-和多种成矿元素的超临界流体,流体以高温、高压、超高盐度、富CO2为特征,从早期到晚期流体中CO2含量增加。结合前人对碳酸岩流体、稀土矿带周边新生代盆地中无机成因CO2气藏、富钾卤水、稳定同位素和隋性气体同位素研究成果,从碳酸岩流体的性质、流体体系、碳、氦同位素组成,初步探讨了碳酸岩流体与周边新生代盆地中CO2气藏、富钾卤水的成因联系。