首页 | 本学科首页   官方微博 | 高级检索  
相似文献
 共查询到20条相似文献,搜索用时 109 毫秒
1.
The paper concerns the complex study of pedogenic and magnetic characteristics of unpolluted soil profiles from Ukraine (3 profiles, of which two represent chernozem and one kastanozem) and Poland (1 profile of chernozem), all with loess parent material. Two of the profiles were situated further south than the other two. The “southern” zone is characterized by lower precipitation rate and higher annual temperatures than the “northern” zone. Depth variations of magnetic properties obtained with various methods were compared with pedogenic characteristics. The common characteristic of all profiles is enhancement of susceptibility in their upper parts related to the presence of superparamagnetic/ single-domain grains of maghemite/oxidized magnetite of pedogenic origin. However, variations of magnetic characteristics measured down depth profiles differ between profiles probably due to differences in climatic conditions and, perhaps, parent loess.  相似文献   

2.
The magnetic susceptibility (MS) of Chinese loess showing a general proportional relationship to pedogenic grade has been widely recognized and used for reconstruction of paleoclimate by Quaternary scientists. The in-situ pedogenic enhancement of ferrimagnetic content is normally believed to be the main reason for the increase of susceptibility in soil units. However, this pattern of high magnetic susceptibility in palaeosols, and low values in loess, are not replicated in some loess deposits. Siberian loess deposits display a completely opposite susceptibility behavior: high values in loess and low values in palaeosols. This inverse relationship has been explained by the idea that magnetic susceptibility is reflecting the magnitude of an aeolian ferrimagnetic component of consistent mineralogy, the grain size of which is related to average wind velocity. Our magnetic study of Siberian samples in this paper suggests that there are notable differences in magnetic properties between Siberian loess and developed palaeosols, not only in magnetic grain-size and concentration but also in magnetic mineralogy. This evidence is difficult to explain fully through variation in wind strength alone, but implies that the low magnetic susceptibility values in the Siberian paleosol units are a reflection, at least in part, of the alteration of the ferrimagnetic content by post-depositional processes. The Loess Plateau is a very arid area where potential evaporation is always higher than precipitation; pedogenesis occurs under dry oxidising conditions. The Siberian Kurtak region is located on the edge of the tundra where it is always wet and saturation during interglacials will lead to a reducing pedogenic environment. Ferrimagnetic minerals under this condition will be destroyed, resulting in lower magnetic susceptibility. Therefore, great care should be taken when using susceptibility values for paleoclimatic reconstruction.  相似文献   

3.
Our study concerned magnetic properties of soil profiles taken from polluted regions of Eastern Ukraine around the industrial centres Krivyj Rig, Mariupol and Komsomolsk. Soils represent chernozem and podzoluvisol. The low-field magnetic susceptibility shows enhancement in the topsoil caused by contamination by coarse-grain magnetite connected with industrial pollution. Magnetic mineralogy was determined by means of thermal demagnetisation of SIRM, monitoring of susceptibility changes during warming from ?196°C to room temperature and heating to 700°C, and Mössbauer analysis. Granulometry of magnetic particles was investigated by determination of hysteresis parameters, susceptibility, M s , SIRM and ARM ratios and frequency dependence of susceptibility. The chemical parameters, namely pH, organic carbon and iron content in different pedogenic and lithogenic minerals, measured for particular horizons determined pedogenic characteristic of soil profiles. Our study showed that differences in magnetic parameters of non-polluted and polluted soil profiles are not limited to the topsoil, but reach deep layers of the parent material. Industrial pollution promotes formation of the so-called “pedogenic” SP and SD particles in these layers.  相似文献   

4.
In most Chinese loess–paleosol sequences, high magnetic susceptibility values are found in the soil horizons, with low values in the loess layers. The susceptibility signal has been widely used as a proxy climatic indicator. However, both the causes and mechanisms which control susceptibility still remain controversial. Our recent studies challenge some earlier interpretations of the magnetic susceptibility signal in Chinese wind-blown sediments. First, the prevailing hypothesis of pedogenic origin cannot totally account for the susceptibility variations in many sections. Second, in some cases, the principal carrier of the magnetization seems not to be the ultrafine pedogenic minerals, rather coarse lithogenic magnetic minerals derived from local sources can also contribute significantly to the susceptibility signal. Finally, not all the Chinese soils have higher susceptibility values than that of loess or sand layers, opposite relationships do exist. It is concluded that the source and causes of susceptibility may be different from site to site or even at different times at a given site. Any single hypothesis cannot completely account for the susceptibility variations in the Chinese Loess Plateau and its surrounding regions. Besides the previous explanations of carbonate leaching, pedogenic processes and organic decomposition, the contribution of source materials to magnetic susceptibility must also be taken into account.  相似文献   

5.
The study on magnetic properties of the red clay indicates that the red clay and loess- paleosol sequence have a common magnetic mineralogy, with magnetite, maghemite, hematite (and possibly goethite) contributing to the magnetic behavior. The red clay magnetic susceptibility is also found to have a positive relation with extrafine superparamagnetic grains. This suggests that, like the Quaternary loess-paleosols, an ultrafine ferrimagnetic component produced during pe-dogenesis in the red clay under humid conditions also plays an important role in susceptibility enhancement in the soil units. This is supported by the correlation between Rb/Sr ratio and magnetic susceptibility. This signifies that, like the above loess-paleosol sequence, the magnetic susceptibility of the red clay can be used as a general proxy paleoclimatic indicator, although whether its susceptibility in the red clay is comparable to pedogenesis intensity and requires further investigation. Magnetic susceptibility variation in the red clay thus also provides an eo-lian/pedogenic record of paleoclimatic evolution. Study of the background susceptibility indicates that, on average, the absolute scale of the paleoclimatic shift from red clay development to Quaternary loess deposition is similar to the climatic shift from stage 5 (S1) to stage 2-4 (L1). This may suggest that during the Quaternary there is an evident strengthening of the absolute wind intensity to bring more (about double) coarser and less weathered (non-SP fraction) eolian magnetic input from the source regions to the Loess Plateau than during the Pliocene. The presence of eolian red clay since 7.5 Ma BP in central-northern China implies an important envi-ronmental change from the underlying Cretaceous red sandstone. The red clay development was closely related to global drying and climate cooling since the Cretaceous and closely associated with the abrupt uplift of the Qinghai-Xizang Plateau at about that time. This uplift of the plateau intensified the East Asia monsoon system and started red clay deposition.  相似文献   

6.
The study on magnetic properties of the red clay indicates that the red clay and loesspaleosol sequence have a common magnetic mineralogy, with magnetite, maghemite, hematite (and possibly goethite) contributing to the magnetic behavior. The red clay magnetic susceptibility is also found to have a positive relation with extrafine superparamagnetic grains. This suggests that, like the Quaternary loess-paleosols, an ultrafine ferrimagnetic component produced during pedogenesis in the red clay under humid conditions also plays an important role in susceptibility enhancement in the soil units. This is supported by the correlation between Rb/Sr ratio and magnetic susceptibility. This signifies that, like the above loess-paleosol sequence, the magnetic susceptibility of the red clay can be used as a general proxy paleoclimatic indicator, although whether its susceptibility in the red clay is comparable to pedogenesis intensity and requires further investigation. Magnetic susceptibility variation in the red clay thus also provides an eolian/pedogenic record of paleoclimatic evolution. Study of the background susceptibility indicates that, on average, the absolute scale of the paleoclimatic shift from red clay development to Quaternary loess deposition is similar to the climatic shift from stage 5 (S1) to stage 2–4 (L1). This may suggest that during the Quaternary there is an evident strengthening of the absolute wind intensity to bring more (about double) coarser and less weathered (non-SP fraction) eolian magnetic input from the source regions to the Loess Plateau than during the Pliocene. The presence of eolian red clay since 7.5 Ma BP in central-northern China implies an important environmental change from the underlying Cretaceous red sandstone. The red clay development was closely related to global drying and climate cooling since the Cretaceous and closely associated with the abrupt uplift of the Qinghai-Xizang Plateau at about that time. This uplift of the plateau intensified the East Asia monsoon system and started red clay deposition.  相似文献   

7.
Magnetic measurements of soils are an effective research tool in assessing soil erosion. This approach is based on detecting layers showing different magnetic properties in vertical soil profiles and lateral catenas. The objective of this research is to compile data on magnetic susceptibility (MS) of soils in Eastern Ukraine to assess the soil erosion rates. The chernozems of Tcherkascy Tishki (Kharkov Region, Ukraine) have undergone a field crop rotation without proper soil conservation technologies being applied. We conducted an intrinsic element grouping of the magnetic susceptibility values and demonstrated that they can be used as MS cartograms in soil erosion mapping. The study showed a strong correlation between the MS values and the erosion index. MS and the erosion index were found to correlate with the humus content. Magnetic mineralogical analyses suggest the presence of highly magnetic minerals (magnetite and maghemite) as well as weakly magnetic goethite, ferrihydrite, and hematite. Stable pseudosingle-domain (PSD), single-domain (SD), and superparamagnetic (SP) grains of pedogenic origin dominate in the studied chernozems. Being an effective, quick and low cost alternative, magnetic methods can be successfully used in the soil erosion investigations.  相似文献   

8.
杭州城区土壤的磁性与磁性矿物学及其环境意义   总被引:18,自引:0,他引:18       下载免费PDF全文
对杭州城区四个不同功能区块土壤进行了系统的环境磁学测定,结果表明城市土壤的磁化率平均值为128×10-8m3·kg-1,频率磁化率平均值3.6%(样品数=182),城市土壤呈现明显的磁性增强. 城市土壤的磁化率与频率磁化率呈极显著指数负相关,表明城市土壤磁性增强明显区别于自然成土过程引起的以超顺磁性(SP)颗粒为主的表土磁性增强机理. 统计分析表明,城市土壤磁化率与软剩磁和饱和等温剩磁(SIRM)呈显著直线正相关,说明亚铁磁性矿物是城市土壤剩余磁性的主要载体. 综合等温剩磁获得曲线、热磁曲线、磁滞回线等岩石磁学测定和SEM/EDX分析,城市土壤的磁性矿物以磁铁矿和赤铁矿为主,磁性矿物以假单畴-多畴(PSD-MD)颗粒存在,粒度明显大于成土过程形成的磁性颗粒,这些磁性颗粒主要来自燃料燃烧、汽车尾气等环境污染物. 因此,城市土壤磁测可作为城市土壤污染监测、污染空间分布和污染物来源判断的新手段.  相似文献   

9.
陕西交道全新世黄土-黑垆土磁化率的CBD研究   总被引:16,自引:7,他引:9  
根据黄士高原中部交道剖面全新世黄土-黑垆土剖面的非磁滞磁化率和CBD提取前后的磁化率、频率磁化率以及热磁分析结果,分析了磁性矿物的种类和磁畴状态,讨论了古土壤的磁化率增强,指出CBD技术强有力的支持古土壤磁化率增强的土壤成因观点.虽然CBD能非常有效地溶解土壤成因的磁赤铁矿,但并不是完全选择性地溶解土壤成因的磁铁矿颗粒.此外,通过对样品CBD处理前后磁化率数据的分析,从土壤化学角度为黄土的风成说提供了新证据。  相似文献   

10.
中国东部红土的磁性及其环境意义   总被引:22,自引:2,他引:20       下载免费PDF全文
通过中国东部红土剖面的环境磁学参数(磁化率、频率磁化率、非磁滞剩磁、饱和等温剩磁等)测量,获得了红土剖面磁性矿物浓度、粒度和类型等特性随深度的变化曲线以及红土经连二亚硫酸钠一柠檬酸钠一重碳酸钠溶液(DCB)处理后的磁性参数变化.根据红土剖面环境磁学参数及其磁参数比值的变化可将红土分为3个层段,各层段的磁性矿物特征存在明显的差异.证实了红土剖面中的磁性载体主要是磁赤铁矿、赤铁矿和针铁矿,并分离出了球粒状磁颗粒.认为红土磁性矿物的数量、粒度、类型等的变异指示了其形成时的环境特征,其频率磁化率和DCB处理的磁化率损失量指示了红土成壤化作用的强弱,可作为在红壤区研究过去全球变化的一种新途径.  相似文献   

11.
Summary Magnetic property variations in marine, lacustrine and loess-paleosol sequences have proved to be useful proxies in climate change studies. However in order to correctly interpret the record of the magnetic property variations it is absolutely necessary to have a good understanding of the cause of the observed variations. Most of the ambiguity in loess-paleosol studies is in distinguishing the role of pedogenesis from other climatic factors. Studying the mineral magnetic properties of the protected cave sediments which have not undergone pedogenesis allows us to determine the degree to which detrital input is climatically driven. These results will help us better understand the variations observed in the surficial loess-paleosol sequences. This study reports mineral magnetic data collected from entrance facies sediments deposited during the early Wurmian glacial stage in the Kůlna Cave. The entrance facies sediments consist of loess-like silts with varying amount of talus. The magnetic susceptibility record from these sediments shows higher values in layers originating in colder climates which is different to that commonly observed in surficial loess deposits. Higher values of magnetic susceptibility in Kůlna sediments are probably due to higher concentrations of ferromagnetic minerals (magnetite and maghemite) and due to an increased proportion of superparamagnetic grains. The magnetic mineralogy and the grainsize distribution (grains larger than superparamagnetic) appear not to change throughout the studied profiles. Higher magnetic susceptibility accompanied by an increase in the superparamagnetic fraction observed in the sediments deposited during colder periods can be explained by an increased input from a pedogenic source when the vegetation cover was reduced and the erosion rate increased.  相似文献   

12.
Measurements of topsoil magnetic susceptibility are often used for quick assessment of soil contamination of anthropogenic origin, with heavy metals or other pollutants. However, because of complicated correlations between low-field magnetic susceptibility (shortened to magnetic susceptibility) of topsoil and soil pollution, the outcome of a field magnetometry survey can not be related directly to soil pollution. For each case study, the results should be interpreted on their own taking into account not only the type of pollution but also pedogenic, biogenic and environmental factors. In practice, it is very difficult to measure and consider all these factors. Here we illustrate the merit of geostatistical methods, which are focused on the spatial variability of a phenomenon, in the interpretation of soil magnetometry results. This article presents the analysis of spatial variability of top soil layers magnetic susceptibility-within the Upper Silesia Industrial Region (USIR)-using semivariance analysis. It also explains how to adjust the sampling density of field magnetometry measurements to spatial variability of the soil pollution as well as to the spatial scale of the investigated area. For this purpose, the values of magnetic susceptibility have been measured by using various sampling densities at areas of different size located within USIR. This enabled to determine the main scales of magnetic susceptibility spatial variability of soils within USIR using semivariance. A few distinct scales of variability were found from the site scale to a more regional scale. Variability ranges of 30 km, 12 km, and 5 km refer to the large regional scale, whereas smaller ranges of few hundreds down to a few tens of meters, can be attributed to the local (site) scale. In addition, the precision of the measuring campaigns, performed within USIR with different sampling densities, was compared through the analysis of the spatial variability of the soil magnetic susceptibility signal by using ordinary kriging. jarek97@yahoo.com, piotr.fabijanczyk@is.pw.edu.pl  相似文献   

13.
The soil in the Rif, Morocco, is at serious risk because increasing anthropogenic pressures are gradually transforming large natural areas into farmland. The distribution of magnetic minerals within the soil profile can be used to assess soil development and degradation. The soils in the study area are severely eroded because of a combination of highly erodible soils, intense rainstorms and scarce vegetation cover. To sample of representative soil profiles, lithology, slope gradient and land use were considered. The ranges of magnetic susceptibility in the soil profiles distinguished between two primary soil groups. Magnetic susceptibility varied in the soil profile and along the soil toposequence, and the variations were related to the differences in the original magnetic composition and the influence of main erosion factors. Lithology is the main factor contributing to the variation in magnetic susceptibility. The magnetic susceptibility values in soils on Tertiary marls (χ = 13·5 × 10?8 m3 kg?1) differed significantly from those on Quaternary terraces (χ = 122·1 × 10?8 m3 kg?1). Slope affected the distribution of magnetic susceptibility because of the continuous loss of topsoil in some parts of the slope and the deposition of eroded soil in others. Elimination of the natural vegetation cover and a shift to cultivated land for cereals has had a negative impact on soil development and, on similar slopes and substrates, magnetic susceptibility decreased significantly in cultivated soils. The soils on steep slopes that had natural vegetation cover retained the magnetic minerals better than did those on gentler slopes that were under cultivation. Grazing, clearing and, especially, tilling has weakened the soil and made it much more vulnerable to erosion. An analysis of the main factors causing erosion will help to promote rational use of the land and to establish conservation strategies in such fragile agroecosystems. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献   

14.
15.
Mineral magnetic properties of soils and parent materials have been interpreted in terms of paleoclimate and rates of soil formation but it is important to understand which minerals contribute to the mineral magnetic signal. Citrate-bicarbonate-dithionite (CBD) treatment has been used to determine the amounts of fine-grained, often pedogenic, ferrimagnetic minerals relative to coarse-grained, often inherited, magnetic minerals. However, questions have been raised about the effect of particle size on the efficacy of CBD in dissolving magnetite and maghemite grains. In this paper we use magnetic susceptibility and its frequency dependence, and the low-temperature behavior of a saturation isothermal remanent magnetization, to track the dissolution of carefully sized magnetite grains. We found that the standard CBD procedure dissolves fine magnetite particles (ca. < 1 μm) but leaves larger particles (ca. > 1 μm) essentially intact. Thin oxidized coatings, presumably maghemite, are also dissolved by the CBD procedure. These results support previous interpretations that the CBD procedure can be used to distinguish between pedogenic and lithogenic magnetic grains, assuming that most pedogenic magnetic grains are sufficiently small (ca. < 1 μm) and most lithogenic magnetic grains are sufficiently large (ca. > 1 μm). These results also show that the standard procedure is too harsh to differentiate between 1 μm grains of magnetite and maghemite. A modified CBD extraction that uses half as much dithionite reduces the magnetic susceptibility of 1 μm magnetite grains by only 10%. This method may be useful in distinguishing between magnetite and maghemite grains in this size range.  相似文献   

16.
Pitambar  Gautam  Ulrich  Blaha  Erwin  Appel 《Island Arc》2005,14(4):424-435
Abstract Soil profiles of the Kathmandu urban area exhibit significant variations in magnetic susceptibility (χ) and saturation isothermal remanence (SIRM), which can be used to discriminate environmental pollution. Magnetic susceptibility can be used to delineate soil intervals by depth into normal (< 10?7 m3/kg), moderately enhanced (10?7–< 10?6 m3/kg) and highly enhanced (≥ 10?6 m3/kg). Soils far from roads and industrial sites commonly fall into the ‘normal’ category. Close to a road corridor, soils at depths of several centimeters have the highest χ, which remains high within the upper 20 cm interval, and decreases with depth through ‘moderately magnetic’ to ‘normal’ at approximately 30–40 cm. Soils in the upper parts of profiles in urban recreational parks have moderate χ. Soil SIRM has three components of distinct median acquisition fields (B1/2): soft (30–50 mT, magnetite‐like phase), intermediate (120–180 mT, probably maghemite or soft coercivity hematite) and hard (550–600 mT, hematite). Close to the daylight surface, SIRM is dominated by a soft component, implying that urban pollution results in enrichment by a magnetite‐like phase. Atomic absorption spectrometry of soils from several profiles for heavy metals reveals remarkable variability (ratio of maximum to minimum contents) of Cu (16.3), Zn (14.8) and Pb (9.3). At Rani Pokhari, several metals are well correlated with χ, as shown by a linear relationship between the logarithmic values. At Ratna Park, however, both χ and SIRM show significant positive correlation with Zn, Pb and Cu, but poor and even negative correlation with Fe (Mn), Cr, Ni and Co. Such differences result from a variety of geogenic, pedogenic, biogenic and man‐made factors, which vary in time and space. Nevertheless, for soil profiles affected by pollution (basically traffic‐related), χ exhibits a significant linear relationship with a pollution index based on the contents of some urban elements (Cu, Pb, Zn), and therefore it serves as an effective parameter for quantifying the urban pollution.  相似文献   

17.
To understand the origin of the ultrafine pedogenic components responsible for the magnetic susceptibility (MS) enhancement remains a major challenging problem in linking magnetic signal with paleoclimate. Here we examine the effect of the natural fires on the MS signal of both plants and modern soils and in particular the MS difference between C3 and C4 plant ashes and their influence on magnetic susceptibility. We also proved the influence of the different floral root systems on the MS signal of modern soils. We find that the C3 and C4 plants are different in their ability to enhance MS signal of modern soils. Increased MS signal of modern soils by C4 plants was much greater than that by C3 plants.  相似文献   

18.
Summary Magnetic susceptibility of more than 160 modern silty soil samples in China was measured to assess the relationship between the magnetic susceptibility and modern climatic parameters. Correlation between magnetic susceptibility and mean annual temperature (MAT) or mean annual precipitation (MAP), shows a complex picture and no single function can be found to fit all the data on the national scale. In East China, where East Asian monsoon plays an important role for the climate conditions, magnetic susceptibility increases with the increase of MAT or MAP in temperate semi-arid regions of the Loess Plateau and surrounding areas. This can be attributed to increasing intensity of pedogenesis which would favor the formation of strongly magnetic minerals and/or reduce depositional rate of eolian dust. Magnetic susceptibility tends to decrease with the increase of temperature and precipitation in the tropical and subtropical warm and humid regions of the vast areas south of the Yangtze River. This may be explained by pedogenic transformation of iron-bearing minerals to weakly magnetic minerals. Between these two different correlation patterns, 15°C of MAT and/or 1200 mm of MAP seem to be the thresholds. In West China, the correlation becomes quite complex in the great mountains and vast sedimentary basins in the north-west. This may be due to the prevailing continental climate in this region and topographic contrast within short distance. The correlation for the Qinghai-Xizang (Tibetan) Plateau is not clear because very few samples were collected. Fluctuations of paleo-temperature and paleo-precipitation at Luochuan for the last 130 ka were estimated using the climofunction obtained from this study.  相似文献   

19.
Several events of anthropogenic impacts on the floodplain river sediments of the Danube along a section near the town of Oryakhovo (NW Bulgaria) have been detected using magnetic technique. In the field, magnetic susceptibility was measured using three susceptibility meters – MS2D, KT-5 and SM30. The differences in the surface susceptibility values measured with the different instruments are ascribed to the various penetration depths which depend on several parameters like sensor diameter, frequency and field strength. This is supported by the detailed laboratory study on penetration depth and sensitivity of the new SM30 susceptibility meter and the comparison with the already existing data for the other two sensors. Boundaries between different flooding events are clearly linked with significant variability of the measured susceptibility values corresponding to one and the same level. Sediment cores, taken at different distances from the water level, show the history of depositional events and corresponding degree of anthropogenic pollution. Identification of the magnetic phases responsible for the signal was carried out by means of thermomagnetic (T) curves. The main carrier is magnetite with Tc of 580°C or oxidized magnetite with Tc of 600°C. A second kink at about 300°C is better expressed for samples with lower susceptibilities. It may correspond to several minerals, e.g. maghemite, pyrrothite, titanomagnetite, as well as different mineral transformations of paramagnetic minerals (decomposition, dehydroxilation, etc. for example siderite, lepidocrocite). The samples showing strong magnetic enhancement are characterized by the predominance of magnetite. Optical microscopy on magnetic extracts shows the presence of small spherical particles, typical for the anthropogenic magnetic phases from high-temperature technological processes. Well expressed susceptibility variations along the cores suggest the presence of several stages of different degree of pollution, covering an estimated period of about 30 years.  相似文献   

20.
Limited information is available about the use of magnetic susceptibility property to determine soil redistribution in hilly areas of the semi-arid regions. This study was conducted to evaluate the use of magnetic properties to determine soil redistribution along a hill slope following deforestation. The study area is located in the Quaternary hilly region of Lordegan district in west Iran. Ten transects were established in two land uses that included natural Querqus forested and cultivated lands. Soil samples were collected at different positions along the slope and magnetic properties (χlf, χhf, SIRM, ARM, and χfd) and selected physico-chemical properties were determined. The results (based on the χfd, SIRM/ARM) showed that the magnetic susceptibly in the calcareous materials is pre-dominantly derived during the pedogenic processes and the superparamagnetic particles which were transported to lower positions of hill slope following deforestation. The results confirmed that this methodology could be applied for monitoring soil redistribution along the slope in calcareous hilly areas in the semi-arid regions.  相似文献   

设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号