Radiocarbon reservoir age of high latitude North Atlantic surface water during the last deglacial

The radiocarbon reservoir age of high latitude North Atlantic Ocean surface water is essential for linking the continental and marine climate records, and is expected to vary according to changes in North Atlantic deep water (NADW) production. Measurements from this region also provide important input and/or tests of oceanic radiocarbon using 3-D global ocean circulation models. Here, we present a surface water radiocarbon reservoir age record of the high latitude western North Atlantic for the deglacial period via the use of fossil cold-water corals growing in waters that are rapidly exchanged with nearby surface waters. The reservoir age of high latitude North Atlantic surface waters was computed from the radiocarbon age difference between our radiocarbon calibration record (http://radiocarbon.LDEO.columbia.edu) and our marine radiocarbon data. ²³⁰Th/²³⁴U/²³⁸U dates provide the absolute coral ages. Our high latitude North Atlantic Ocean reservoir age data combined with recalculated reservoir ages based on published coexisting terrestrial and marine material and Vedde ash radiocarbon dates from central and eastern North Atlantic show modern values (380±140 year, n=14) during the Bolling and Allerod warm period and a 200 year increase in reservoir age (590±130 year, n=10) during the entire Younger Dryas (YD) cold episode. The reservoir age then decreased to 270±20 year (n=2) at the Preboreal/YD transition, although the dates are too sparse for us to be confident in this estimate. We are not able to resolve the timing of the transition to increased reservoir ages from the mid-Allerod to the YD due to the relatively small change and correspondingly large uncertainty in the estimates. The atmospheric Δ¹⁴C record derived from our atmospheric radiocarbon record displays a 40 per mil increase from 12,900 to 12,650 cal years BP, coincident with the shift to high reservoir ages in the early YD cold event. Intrusion of ¹⁴C depleted Antarctic Intermediate Water (AAIW) to the high latitude North Atlantic and reduction of NADW formation are possible causes for the coincident shift to high reservoir ages in the North Atlantic surface ocean and increased atmospheric Δ¹⁴C during the beginning of the YD event.     

High-resolution chronology for the Mesoamerican urban center of Teotihuacan derived from Bayesian statistics of radiocarbon and archaeological data

A high-resolution ¹⁴C chronology for the Teopancazco archaeological site in the Teotihuacan urban center of Mesoamerica was generated by Bayesian analysis of 33 radiocarbon dates and detailed archaeological information related to occupation stratigraphy, pottery and archaeomagnetic dates. The calibrated intervals obtained using the Bayesian model are up to ca. 70% shorter than those obtained with individual calibrations. For some samples, this is a consequence of plateaus in the part of the calibration curve covered by the sample dates (2500 to 1450 ¹⁴C yr BP). Effects of outliers are explored by comparing the results from a Bayesian model that incorporates radiocarbon data for two outlier samples with the same model excluding them. The effect of outliers was more significant than expected. Inclusion of radiocarbon dates from two altered contexts, 500 ¹⁴C yr earlier than those for the first occupational phase, results in ages calculated by the model earlier than the archaeological records. The Bayesian chronology excluding these outliers separates the first two Teopancazco occupational phases and suggests that ending of the Xolalpan phase was around cal AD 550, 100 yr earlier than previously estimated and in accordance with previously reported archaeomagnetic dates from lime plasters for the same site.     

Pitfalls in the AMS radiocarbon-dating of terrestrial macrofossils

The AMS ¹⁴C technique has the advantage that small samples of Late Quaternary age can be dated with high accuracy, and that errors due to reservoir effects can be avoided if specifically determined terrestrial micro- and macrofossils are measured. However, to obtain such high-accuracy measurements, it is important how small samples are handled prior to treatment in the radiocarbon laboratories. Here we present a set of 51 AMS ¹⁴C measurements, of which 31 dates gave expected ages and 20 dates resulted in anomalously young ages, despite the fact that all samples consisted of clearly identified Late Weichselian terrestrial plant macrofossils. To evaluate possible sources of error, we compared these samples in respect to preparation methods, sample storage and sample weight. Our results show that the long-term storage of wet macrofossil samples appears to have a significant effect on the radiocarbon age obtained, even when the samples are kept cool. Fungi or micro-organisms may easily be incorporated into a sample during preparation and identification, and can easily contribute to the contamination of a sample, if stored cool and wet for several months. © 1998 John Wiley & Sons, Ltd.     

Chronologies of sedimentary changes in the south Bohai Sea,China: constraints from luminescence and radiocarbon dating

The alternation of terrestrial and marine deposits is an indicator of past environmental and sea‐level changes. The age of deposition is usually dated by means of radiocarbon. However, radiocarbon dates of molluscan shells from coastal areas may be complicated by various sources of carbon, and problematic for deposits of 40–50 ka or older. Herein, we apply the Optically Stimulated Luminescence (OSL) dating method to date samples from terrestrial and marine/coastal sediments extracted from three cores in the south Bohai Sea, China. Multiple‐ and single‐aliquot regenerative‐dose procedures using OSL signals from fine‐silt (4–11 μm), coarse‐silt (38–63 μm) and fine‐sand (63–90 or 90–125 μm) quartz were employed to determine the equivalent dose (D _e). The results showed that: (i) OSL ages from quartz of different grain sizes and different protocols are consistent with each other; (ii) for Holocene samples, most of the radiocarbon dates agree well with OSL ages; (iii) for pre‐Holocene samples, radiocarbon dates cluster at 40–50 ¹⁴ C ka BP, whereas OSL ages are in stratigraphic order from 11 ka to 176 ka. Because of the self‐consistency of the quartz OSL ages, the stratigraphic agreement in the three cores, and the clustering of the radiocarbon dates, we suggest that the quartz OSL ages are more reliable with respect to dating the samples from the south Bohai Sea. Finally, the four marine strata identified in the south Bohai Sea are likely to have formed during the Holocene, Marine Isotopic Stage (MIS) 3–5, MIS 6 and probably MIS 7, respectively.     

环渤海海岸带14C数据集（Ⅱ）

作为晚更新世与全新世地层年代测定的一种重要手段,¹⁴C测年被广泛应用于地质样品的年代测定。但对于¹⁴C数据的系统校正,迄今未得到应有的重视。文章在环渤海海岸带¹⁴C数据集(Ⅰ)的基础上,对所收集的421个由其他研究者获得的环渤海海岸带¹⁴C数据进行了系统校正。并讨论了百年、千年与万年尺度的¹⁴C数据校正效果。结果表明,直接测定值与系统校正值之间的差值常有数百年至两千年的差别。经统一校正的¹⁴C年龄,最大限度地接近样品太阳历纪年的“真实”年龄,从而有助于更加准确地重建该地区的晚更新世晚期以来的地质年代史,并可与考古纪年及其他测年方法获得的绝对年龄直接对比。     

Radiocarbon deficiencies of US Gulf Coast lakes compromise paleo-hurricane records

Radiocarbon assays of sediments from Lake Shelby, US Gulf Coast, exhibit substantial ¹⁴C deficiencies of 9.3% and 4.7% for the limnic sapropel and associated fresh-water clams Rangia cuneata, respectively. Measured radiocarbon dates from the sapropel and clams require corrections of 785 ± 80 and 365 ± 90 ¹⁴C yr (1σ), respectively, in order to achieve consistency with the radiocarbon time scale. Lake sediments of the US Gulf Coast serve as unique repositories of pre-historic hurricane strikes. Previously unrecognized radiocarbon deficiencies likely render compromised chronologies of the paleo-hurricane records, and erroneous estimates of return period and landfall probability that are derived from the storm chronologies. The recalculated severe hurricane chronologies suggest that the annual landfall probabilities of the last millennium on the US Gulf Coast are equal to, or higher than, the preceding three millennia.     

Associated terrestrial and marine fossils in the late-glacial Presumpscot Formation, southern Maine, USA, and the marine reservoir effect on radiocarbon ages

Excavations in the late-glacial Presumpscot Formation at Portland, Maine, uncovered tree remains and other terrestrial organics associated with marine invertebrate shells in a landslide deposit. Buds of Populus balsamifera (balsam poplar) occurred with twigs of Picea glauca (white spruce) in the Presumpscot clay. Tree rings in Picea logs indicate that the trees all died during winter dormancy in the same year. Ring widths show patterns of variation indicating responses to environmental changes. Fossil mosses and insects represent a variety of species and wet to dry microsites. The late-glacial environment at the site was similar to that of today's Maine coast. Radiocarbon ages of 14 tree samples are 11,907 ± 31 to 11,650 ± 50 ¹⁴C yr BP. Wiggle matching of dated tree-ring segments to radiocarbon calibration data sets dates the landslide occurrence at ca. 13,520 + 95/−20 cal yr BP. Ages of shells juxtaposed with the logs are 12,850 ± 65 ¹⁴C yr BP (Mytilus edulis) and 12,800 ± 55 ¹⁴C yr BP (Balanus sp.), indicating a marine reservoir age of about 1000 yr. Using this value to correct previously published radiocarbon ages reduces the discrepancy between the Maine deglaciation chronology and the varve-based chronology elsewhere in New England.     

Chronology of glacial Lake Agassiz meltwater routed to the Gulf of Mexico

Sediment cores with new radiocarbon dates from the southern outlet of glacial Lake Agassiz indicate that meltwater delivery to the Mississippi valley was disrupted at 10,800 ¹⁴C yr B.P. and the outlet was abandoned by 9400 ¹⁴C yr B.P. These findings confirm the timing of generally accepted terminations of the Lockhart and Emerson Phases of Lake Agassiz. Additionally, the radiocarbon chronology indicates that the spillway was fully formed by 10,800 ¹⁴C yr B.P. and that the occupancy in late-Emerson time was likely short-lived with minimal spillway erosion.     

Reliable Late-Pleistocene Stratigraphic Ages and Shorter Groundwater Travel Times fromC in Fossil Snails from the Southern Great Basin

Both aquatic and land snails are common in the geologic record, but their utility in dating is greatly restricted by their well-documented tendency to yield¹⁴C dates inconsistent with true¹⁴C ages. In this study, we examine the use of¹⁴C ages from (1) small, previously unstudied, terrestrial snails to date hosting spring deposits and from (2) cooccuring aquatic snails to constrain groundwater travel times during the last glacial period. Our study area in the southern Great Basin encompasses Yucca Mountain, site of the proposed high-level nuclear waste repository, where information on the age and extent of past high water tables and on groundwater flow times is crucial to several licensing issues. Our results show that shells of small terrestrial snails belonging toValloniasp. yield¹⁴C dates consistent with¹⁴C ages of associated carbonized wood. These results imply that these taxa can provide reliable¹⁴C age control on the broadly distributed deposits in which they have been described. In contrast, cooccurring aquatic snails from fossil spring deposits yield¹⁴C ages generally greater than the control age. This is because the aquatic shells often formed in spring waters that had an initial¹⁴C deficiency. However, the magnitude of the deficiency is much less than that observed in nearby modern springs, arguing for much higher average¹⁴C contents in late Pleistocene groundwaters in these basins. If representative, this implies shorter groundwater travel times through aquifers in southern Nevada during late-glacial time.     

Comparison of radiocarbon and uranium-series dating methods as applied to marine apatite

A comparison of uranium-series geochronology and radiocarbon dating, the first systematic test of its kind applied to authigenic marine apatite, has been made for nine seafloor phosphate nodules sampled from the Peruvian and Chilean shelves. Radiocarbon ages agree well with the ²³⁰Th ages for all six samples with ²³⁰Th ages younger than the practical dating limit of the ¹⁴C technique for marine samples. Two of three “old” samples contain no significant ¹⁴C activities, as expected. However, one sample with a high concentration of phosphate pellets contains more than 30% of the modern ¹⁴C activity. The discrepancy between the ¹⁴C and U-series age for this sample is thought to be due to post-depositional adsorption of the particle-reactive elements thorium and protactinium onto pellet surfaces.     

Transition from arid to hyper-arid environment in the southern Levant deserts as recorded by early Pleistocene cummulic Aridisols

The time at which deserts established their current arid or hyper-arid conditions remains a fundamental question regarding the history of Earth. Cosmogenic isotope exposure ages of desert pavement and welded, calcic–gypsic–salic Reg soils that developed on relatively flat alluvial surfaces ～2 Ma ago in the Negev Desert indicate long geomorphic stability under extremely dry conditions. Over a short interval during their initial stage of development between 1–2 Ma, these cumulative soils are characterized by calcic soils reaching maximum stage III of carbonate morphology. This interval is the only period when calcic soil horizons formed on stable abandoned alluvial surfaces in the southern Negev Desert. Since ～1 Ma pedogenesis changed toward more arid soil environment and the formation of gypsic–salic soil horizons that were later followed by dust accumulation. The dichotomy of only moderately-developed calcic soil (stages II–III) during a relatively long time interval (10⁵–10⁶ years) indicates an arid environment that does not support continuous development but only occasional calcic soil formation. The very low δ¹⁸O and relatively high δ¹³C values of these early pedogenic carbonates support soil formation under arid climatic conditions. Such an environment was probably characterized by rare and relatively longer duration rainstorms which occasionally allowed deeper infiltration of rainwater and longer retention of soil moisture. This, in turn enabled the growth of sparse vegetation that enhanced deposition of pedogenic carbonate. At ～1 Ma these rare events of slightly wetter conditions ceased and less atmospheric moisture reached the southern Negev Desert leading to deposition of soluble salts and dust deposited in the soils. The combination of long-term hyperaridity, scarcity of vegetation and lack of bioturbation, salts cementation, dust accumulation and tight desert pavement cover, has protected the surfaces from erosion forming one of the most remarkably stable landscapes on Earth, a landscape that essentially has not eroded, but accumulated salt and dust for more than 10⁶ yr.     

Reservoir ages in Baltic Sea sediment—a case study of an isolation sequence from the Litorina Sea stage

In order to quantify the reservoir age in Baltic Sea sediment, one sedimentary sequence from an isostatically isolated basin was subject to high-resolution AMS radiocarbon dates. Diatom analysis confirmed deposition during the Litorina Sea stage and later, in a freshwater lake. Macrofossils from well preserved seeds and other remnants from terrestrial plants were used for AMS datings. It is assumed that these fragile plant remains are not redeposited or affected by internal ages. The ages obtained from the macrofossils range from 6460±125 to 5580±75 ¹⁴C yr BP. By comparing these radiocarbon ages with those obtained by bulk sediment dates, it was obvious that the bulk samples were affected by reservoir ages, resulting in too old ages. The reservoir ages varied within the sediment column; during the most saline phase, the reservoir age was approximately 750 yr, shortly after the isolation ca 400 yr and in the freshwater lake, the age differences between the two series were neglectable.     

Uranium/thorium dating of ferricretes from mid- to late pleistocene glacial sediments,western Tasmania,Australia

The uranium/thorium (U/Th) dating method was applied to pedogenic/diagenic ferricretes developed within glacial drifts from the northern West Coast Ranges of Tasmania. The dates derived from the method are, by definition, minima for the sediments, with the ferricretes being secondary mineral deposits which appear in the form of bands, horizons or nodules comprised of indurated masses of iron oxy(hydr)oxides developed post-depositionally within the host sediment or soil. The absence of such deposits in well-identified drift sediments of the last glaciation suggests the development of ferricrete horizons in glacial drifts occurred during earlier interstadials and interglacials. This has been confirmed by the uranium/thorium dating of ferricrete bands within glacigenic sediments obtained from three drill cores from the Boco Valley. The ages derived were found to be consistent with estimates for the timing of glaciation derived from palaeomagnetic analyses, radiocarbon dating and relative dating techniques. The results show that the uranium/thorium method can be used to successfully date ferricretes obtained from within glacial sediments of ages <350000 yr and provides valuable information regarding the minimum age of the host sediment. © 1997 John Wiley & Sons, Ltd.     

Reinvestigation of the classic late‐glacial Bølling Sø sequence,Denmark: chronology,macrofossils, Cladocera and chydorid ephippia

The late‐glacial Bølling period was first identified by Johs. Iversen on the basis of pollen results from Lake Bølling Sø in Denmark. Because there were no radiocarbon dates from the sequence the Bølling Chronozone (12 000–13 000 ¹⁴C yr BP) was later established on the basis of dates from other sites. A new project is reinvestigating the sediments from the Bølling Sø sequence with AMS radiocarbon dating and multiproxy analyses. Here we present results of AMS radiocarbon dating, macrofossil analyses, cladoceran analyses (Cladocera concentrations and chydorid ephippia) and Pediastrum analyses (concentrations). The AMS dates on land plant remains show that the lower part of the sequence is around 12 500 ¹⁴C yr BP, and thus clearly pre‐dates the Allerød chronozone. However, construction of a chronology for the sequence was problematic, partly because of reworking of macroscopic plant remains. The climate ameliorated after glacial conditions to such an extent that growth of plants could begin at ca. 12 500 ¹⁴C yr BP, but the results of multiproxy analyses show little evidence for a further warming period during the pre‐Allerød part of the sequence. Lake productivity was low, and tree birch rare or maybe absent. This may reflect widespread occurrence of dead ice, unstable soils, heavy in‐wash of minerogenic matter to the lake, resulting in turbid water and rapid sedimentation. The early pioneer vegetation was characterised by Salix polaris and Dryas octopetala, and by herbs. The Allerød Chronozone, and especially its initial part, appears to have been relatively warm but reduced cladoceran concentrations and increased proportion of chydorid ephippia suggest that climate cooled in the middle Allerød and that the late Allerød was colder than the early part. The early Younger Dryas was probably colder than the late Younger Dryas. Clear warming is apparent at the beginning of the Holocene, where the first macrofossil evidence of trees (Betula pubescens, Populus tremula) is found. Copyright © 2004 John Wiley & Sons, Ltd.     

Analysis of the atmospheric 14C record spanning the past 50,000 years derived from high-precision 230Th/234U/238U, 231Pa/235U and 14C dates on fossil corals

Changes in the geomagnetic field intensity, solar variability, and the internal changes of the carbon cycle are believed to be the three controlling factors of past atmospheric radiocarbon (¹⁴C) concentrations (denoted as Δ¹⁴C). Of these three, it is believed that the field intensity is the dominant factor. We analyze an atmospheric Δ¹⁴C record spanning the past 50,000 years based on previously-published ²³⁰Th/²³⁴U/²³⁸U and ¹⁴C dates of fossil corals from Kiritimati, Barbados, Araki and Santo Islands, and identify the role of the Laschamp geomagnetic field excursion on the long term trend of the Δ¹⁴C record. There is a general consistency between the coral Δ¹⁴C record and the Δ¹⁴C output from carbon cycle models based on the global ¹⁴C production estimates. High-precision, high-accuracy ²³⁰Th/²³⁴U/²³⁸U dates and redundant ²³¹Pa/²³⁵U dates anchor the timing of this Δ¹⁴C record. We propose that a significant fraction of the long-term Δ¹⁴C trend may be due to inaccuracies in the generally accepted ¹⁴C decay constant. The uncertainty in estimating the shape of ¹⁴C beta spectrum below 20 keV leads to one of the greatest errors in decay constant estimates. Once the ¹⁴C half-life is validated via redundant techniques, Δ¹⁴C records will provide a better opportunity to examine the roles of carbon cycle and ¹⁴C production influences.     

Soil/landform relationships surrounding the Harappa archaeological site,Pakistan

A soil survey around the archaeological site of Harappa, Pakistan revealed alluvial deposits of five distinct ages based on relative position in the landscape and degree of soil profile development. the youngest deposit (age 1) is in the lowest landscape position and has received flood waters as recently as 1988. Soils there are in an incipient stage of development: only organic carbon and soluble salts have accumulated at the surface of the profile. the age 2 deposit has not undergone significant pedogenic change, but is in a slightly higher landscape position than the youngest deposit. Elevated concentrations of P, and the presence of sand-sized pottery and brick fragments, indicate that this deposit was derived at least partially from archaeological material. the presence of small, soft calcite nodules (Stage II) and some soluble salt translocation are the primary pedogenic changes observed in the age 3 deposit. the age 4 deposit shows evidence of both carbonate and gypsum accumulation. Presence of large gypsum nodules in deep By horizons suggests that a high groundwater table has altered these soils. the oldest deposit, age 5, forms a late Pleistocene stream terrace of the Ravi River. the soil formed in this deposit exhibits considerable carbonate accumulation, with large, dense nodules (Stage II + ) and an argillic horizon. A ¹⁴C date from pedogenic calcite gives an age of 7080 ± 90 years B.P., indicating a minimum age of early Holocene. the soil survey suggests that the ancient city of Harappa was built on an age 5 stream terrace remnant, surrounded by Holocene floodplains and a meandering channel of the Ravi River.     

Deglaciation chronology and glaciomarine successions in the Malangen-Målselv area, northern Norway

The deglaciation history of the Malangen‐Målselv fjord and valley area proximally to the Tromsø‐Lyngen (Younger Dryas) moraine at Bakkejord, Malangen, northern Norway, is reconstructed based on morphostratigraphic, lithostratigraphic and geophysical evidence, and 25 radiocarbon dates from marine shells and foraminifera. The results show that following the Skarpnes event c. 12 200 ¹⁴Cyr BP, and prior to the Younger Dryas readvance, the area was deglaciated at least as far as Sandmo situated 22 km proximally to the Tromsø‐Lyngen moraine. Two moraine ridges crossing the fjord at Sandmo and buried beneath thick glaciomarine sediments are correlated with this period. The area was subsequently deglaciated between 10 300 and 9200 ¹⁴Cyr BP, following the Tromsø‐Lyngen (Younger Dryas) readvance. Five ice‐front accumulations post‐dating the Tromsø‐Lyngen moraine and situated 19, 27, 42, 55 and 77 km behind it are identified and dated based on radiocarbon dates and correlation of marine limits: Målsnes (c. 10 050 ¹⁴Cyr BP), Kjerresnes (c. 10 000 ¹⁴Cyr BP), Solli (c. 9750 ¹⁴Cyr BP), Bardufoss‐Brentmoen‐Storskogmoen (c. 9600–9700 ¹⁴Cyr BP) and Alapmoen (c. 9200 Cyr BP). The largest of these, at Bardufoss‐Storskogmoen, possibly accumulated as a response to an ice advance. Fourteen dates of apparent late Allerød/Younger Dryas age (11 100–10 000 ¹⁴Cyr BP), obtained from fossils in glaciomarine sediments in the Målselv valley up to 77 km proximally to the Tromsø‐Lyngen moraine, are interpreted as postdating rather than predating this moraine. Several of these are considered to be too old because of uncertain reservoir age, carbon‐dating plateaus and/or contamination. This highlights uncertainties associated with radiocarbon‐dating and the profound effect such uncertainties may have on interpreting geological events.     

Age assignment of a diatomaceous ooze deposited in the western Amundsen Sea Embayment after the Last Glacial Maximum

Reliable dating of glaciomarine sediments deposited on the Antarctic shelf since the Last Glacial Maximum (LGM) is challenging because of the rarity of calcareous (micro‐) fossils and the recycling of fossil organic matter. Consequently, radiocarbon (¹⁴C) ages of the acid‐insoluble organic fraction (AIO) of the sediments bear uncertainties that are difficult to quantify. Here we present the results of three different methods to date a sedimentary unit consisting of diatomaceous ooze and diatomaceous mud that was deposited following the last deglaciation at five core sites on the inner shelf in the western Amundsen Sea (West Antarctica). In three cores conventional ¹⁴C dating of the AIO in bulk samples yielded age reversals down‐core, but at all sites the AIO ¹⁴C ages obtained from diatomaceous ooze within the diatom‐rich unit yielded similar uncorrected ¹⁴C ages between 13 517 ± 56 and 11 543 ± 47 years before present (a BP). Correction of these ages by subtracting the core‐top ages, which probably reflect present‐day deposition (as indicated by ²¹⁰Pb dating of the sediment surface at one core site), yielded ages between ca. 10 500 and 8400 cal. a BP. Correction of the AIO ages of the diatomaceous ooze by only subtracting the marine reservoir effect (MRE) of 1300 a indicated deposition of the diatom‐rich sediments between 14 100 and 11 900 cal. a BP. Most of these ages are consistent with age constraints between 13.0 and 8.0 ka for the diatom‐rich unit, which we obtained by correlating the relative palaeomagnetic intensity (RPI) records of three of the sediment cores with global and regional reference curves. As a third dating technique we applied conventional radiocarbon dating of the AIO included in acid‐cleaned diatom hard parts extracted from the diatomaceous ooze. This method yielded uncorrected ¹⁴C ages of only 5111 ± 38 and 5106 ± 38 a BP, respectively. We reject these young ages, because they are likely to be overprinted by the adsorption of modern atmospheric carbon dioxide onto the surfaces of the diatom hard parts prior to sample graphitisation and combustion for ¹⁴C dating. The deposition of the diatom‐rich unit in the western Amundsen Sea suggests deglaciation of the inner shelf before ca. 13 ka BP. The deposition of diatomaceous oozes elsewhere on the Antarctic shelf around the same time, however, seems to be coincidental rather than directly related. Copyright © 2009 John Wiley & Sons, Ltd.     

Comparison of SAR techniques for luminescence dating of sediments derived from volcanic tuff

In this investigation we evaluate several proposed optically stimulated luminescence single-aliquot regeneration (OSL SAR) procedures to determine which technique has the greatest potential to yield accurate ages for samples collected from tuff-derived alluvial sediments within the narrow, sharply incised canyon systems of the Pajarito Plateau of northern New Mexico. The SAR data collection methods evaluated are: infrared-stimulated luminescence (IRSL), post-IR blue-OSL, IRSL with TL annealing cycles on polymineral fine-grains, and blue-OSL on quartz fine sand. A single-grain laser luminescence (SGLL) procedure for quartz sand is also evaluated. Age estimates obtained from these methods are compared with radiocarbon, soil PDI (profile development index), and IRSL multi-aliquot additive dose (MAAD) age constraints. Our results indicate that the modal D_e of quartz sand SGLL dose distributions yield ages that are consistent with radiocarbon and PDI age constraints for the tuff derived sediments in this investigation and appears to be the most promising method for studies in this area. Additionally, two fine-grained polymineral methods, IRSL SAR and traditional IRSL MAAD, produced ages that were generally in agreement with the SGLL ages and with available ¹⁴C and PDI age constraints. At the present stage of research, we advocate using quartz sand SGLL in conjunction with IRSL SAR or even IRSL MAAD for polymineral fine-grains to provide the most robust and reliable luminescence age data sets for tuff-derived sediments.     

AMS Radiocarbon Age of the Upper Mississippi Valley Roxana Silt

Accelerator mass spectrometer radiocarbon ages of the Roxana Silt (loess) along the Upper Mississippi Valley of Wisconsin and Minnesota indicate that loess sedimentation of the Roxana Silt occurred between about 55,000 and 27,000 ¹⁴ C yr B.P. However, due to local environmental controls, the basal age at any given site may range from 55,000 to 35,000 ¹⁴C yr B.P. The radiocarbon ages presented here are in agreement with previous radiocarbon ages for the Roxana Silt in its type area of west-central Illinois, but indicate that long-term sedimentation rates along the bluffline of the Upper Mississippi Valley were very slow (4-8 cm/1000 yr) compared to long-term sedimentation rates along the bluffline of the type area (40-70 cm/1000 yr). Comparison of radiocarbon ages for midcontinent middle Wisconsinan loess deposits indicates that sedimentation along the Mississippi River valley may have preceded loess sedimentation along the Missouri River valley by as much as 20,000 yr or that basal ages for middle Wisconsinan loess along the Missouri Valley are erroneously young. The bracketing ages for the Upper Mississippi Valley Roxana Silt indicate that the Mississippi River valley was receiving outwash sedimentation between 55,000 and 27,000 ¹⁴C yr B.P.