A proposed correction to the solar abundances of carbon and oxygen utilizing new and accurate theoretical forbidden transition probabilities

Previously published solar abundances of oxygen and carbon can be corrected to be logN(O) = 8.93 and logN(C) = 8.60 on the hydrogen log-scale when new accurate forbidden electric quadrupole transition probabilities A _Q(s^–1) are used. Such A _Q's, based on the new atomic structure and electron correlation theory, developed recently by Sinanolu and coworkers, are reported for the (¹ S ₀-¹ D ₂) lines of [C i], [N ii, [O i] and [O iii] and the (² P-² D) lines of [N i] and [O ii]. The available experimental values are also given for comparison.Work supported by Grant No. GP-29471 from the U.S. National Science Foundation.     

Experimental and theoretical transition probabilities in singly ionized gold

Absolute transition probabilities have been measured for lines originating from the 5d⁹6d and 5d⁹7s electronic configurations in the spectrum of singly ionized gold (Au  ii ). The laser-induced breakdown spectroscopy has been applied to free gold atoms and ions produced by laser ablation. Absolute transition probabilities have been determined using the branching fraction and the Boltzmann plot methods. Theoretical branching fractions as well as radiative lifetime values have also been obtained by a relativistic Hartree–Fock method taking core polarization and configuration interaction effects into account. The new results are compared with previous results when available.     

Vibrational transition probabilities,\bar r-centroids and morse PE-curves for SiS

Vibrational transition probabilities-namely, Franck-Condon factors and -centroids-have been evaluated using an approximate analytical method for theD-X system of SiS. Morse potential energy curves forD ¹ andX ¹⁺ states of SiS have been constructed using the latest spectroscopic data. The value of -centroids for the band have been found to decrease linearly with the corresponding wavelength.     

Forbidden transition probabilities of astrophysical interest among low-lying states of V III

Electric and magnetic multipole transitions among low-lying states of doubly ionized vanadium were computed using the multi-configuration Hartree-Fock (MCHF) method with Breit-Pauli (BP) corrections to a non-relativistic Hamiltonian. Energy levels were determined up to and including 3d ²(¹ G)4s b ² G _7/2 and computed energies were found to be in good agreement with experiment and other theories. In addition to Einstein A _ki coefficients for some E2 and M1 transitions, lifetime data and selected weighted oscillator strengths are also reported.     

Radiative lifetimes and transition probabilities in Hf I and Hf III

Radiative lifetimes of nine odd levels in Hf III (5d6p z³P_0,1, z¹D₂, z³D_1,2,3, z³F_2,3,4) and of two odd levels in Hf I (5d6s²6p z³D_2,3) have been determined using Time-Resolved Laser-Induced Fluorescence. The investigated levels in Hf I were excited in a single-step process from the ground term (5d²6s² a³F), whereas in Hf III we started from either the ground term 5d² a³F or the low-lying 5d6s a³D term. For all of the investigated levels, the lifetimes have been measured for the first time. A multiconfiguration relativistic Hartree–Fock method, including core-polarization effects, has been used to compute radiative lifetimes of 15 Hf III levels, including those measured in this work. Transition probabilities for 55 transitions in Hf III are also given.     

Calculation of the structure and transition probabilities of low energy levels of Fe and Fe

We use analytical wave functions in intermediate coupling to make a complete relativistic calculation of the structure and transition probabilities for the n = 1, 2, 3 states of Fe⁺²⁴. Data for Fe⁺²⁵ are also given for comparison. The results have a high accuracy and those relating to the n = 3 state are given in detail for the first time here.     

Vibrational transition probabilities,\bar r-centroids and PE-curves for OH and PN

Vibrational transition probabilities namely Franck-Condon factors and -centroids have been evaluated using an approximate analytical method for theA-X systems of OH and PN. KKRV potential energy curves forX ² _i ,X ¹⁺,A ²⁺, andA ¹ states of OH and PN have been constructed using the latest spectroscopic data. The value of -centroids for the band have been found to increase linearly with the corresponding wavelengths. We show results for six new bands and OH and eight new bands of PN in the spectra of astronomical objects.     

Reduced transition probabilities for 4~He radiative capture reactions at astrophysical energies

The reduced transition probabilities from an electric quadrupole B(E2) and reduced transition probabilities from a magnetic dipole B(M1) between the ground state and the first excited state have been calculated for the3He(α,γ)7Be,8Be(α,γ)12C and12C(α,γ)16O radiative capture reactions with the M3Y potential.These reactions are important in stellar evolution.The calculated B(M1) and B(E2) for7Be nuclei are found to be 1.082×10-3e2fm2and 1.921 e2fm4from transitions 3/2-to 1/2-,respectively.The obtained values for reduced transition probabilities B(E2) for the12C and16O nuclei from transitions 0+to 2+are 12.54 e2fm4and 14.18 e2fm4,respectively.The results are in satisfactory agreement with available experimental data.     

Energy spectrum of HeII in a strong magnetic field and bound-bound transition probabilities

The ground state energy of the Heii (singly ionized helium) atom is determined in magnetic fields up to 10¹² G. The 13 lowest excited states and bound-bound transition probabilities are calculated in magnetic fields from 10⁷ to 10⁹ G.     

Investigation of the effects of expectation values for radii on the determination of transition probabilities using WBEPM theory

Transition probabilities for some excited s-p and p-s transition arrays of neutral nitrogen have been calculated using the weakest bound electron potential model theory (WBEPMT) for the investigation of effects of expectation values of radii.We have used both numerical non-relativistic Hartree-Fock (NRHF) wave functions and numerical Coulomb approximation (NCA) wave functions to calculate expectation values of radii. The transition probability results obtained using the parameters determined with two different wave functions agree well with each other and accepted values taken from NIST for low values of transition probability. However, the NRHF wave functions present better results for p-s transitions, while NCA wave functions are better in s-p transitions for large values of transition probability.     

The excitation of the forbidden coronal lines

The excitation of the lowest (3s²3p²) configuration of Fexiii is discussed for the range of density and temperatures experienced in the solar corona. The principal features are the introduction of proton collisions as an important mechanism for exciting the 3p^{2 3}P levels, the use of improved electron collision strengths and a detailed discussion of the influence of the excited configurations. The predicted intensity ratios are shown to be consistent with available observations with the single exception of an eclipse measurement of the ratio of the intensities of the infrared lines.     

Forbidden transition probabilities for ground terms of ions with p or p 5 configurations

Forbidden transition probabilities are listed for ground term transitions of ions in the B I. F I, Al I and Cl I sequences. Some of these transitions remain to be observed in flares.     

The excitation of the forbidden coronal lines

The excitation of the 2s²2p² ground configuration of Caxv is calculated for coronal densities and temperatures. The calculations include electron and proton excitation of the forbidden transitions and electron excitation via the first excited (2s2p³) configuration. It is shown that measurements of the line intensity ratio I( 5694)/I( 5446) are in good agreement with the predictions. The line to continuum observations for limb flares and coronal condensations are discussed. It is suggested that the calcium abundance in condensations is enhanced owing to diffusion processes.Present address: Department of Astronomy, University of Texas, Austin, Texas, U.S.A.     

Measurement of radiative lifetimes and determination of transition probabilities of astrophysical interest in Ho iii

Lifetimes of six levels belonging to the 4f¹⁰6p configuration of Ho  iii have been measured for the first time using the time-resolved laser-induced fluorescence method. They are compared with multiconfigurational pseudo-relativistic Hartree–Fock calculations. A very good agreement is found. Using the experimental lifetimes and theoretical branching fractions, a first set of transition probabilities of astrophysical interest has been obtained for this ion.     

Predicted forbidden line spectrum of NiIV

The spectrum of RR Telescopii in 1954 had a number of strong unidentified lines. To examine the possibility of some of these being due to Niiv we have calculated the energies of the 3d⁷ configuration of this ion. Estimates of the quantum-mechanical parameters have been made by extrapolation from known ions. Transition probabilities have been computed for magnetic dipole and electric quadrupole radiation for all possible transitions within the 3d⁷ configuration.Several predicted forbidden lines are in the region of unidentified lines in RR Telescopii; calculated energies are insufficiently accurate for definitive identifications to be made, but further laboratory work might lead to several identifications.