Geochemical constraints on the provenance of Oligocene–Miocene siliciclastic deposits (Zivah Formation) of NW Iran: implications for the tectonic evolution of the Caucasus

In this study, the whole-rock geochemistry of 35 Oligocene–Miocene sandstone and shale samples from the Zivah Formation, Moghan area (NW Iran) were collected and analyzed for evaluation of their provenance, tectonic setting and the intensity of paleo-weathering. Low to moderate values of the chemical index of alteration (mean CIA?=?53/68 for sandstones/shales) and relatively high values of index of compositional variability (mean ICV?=?1.23/1.08 for sandstones/shales) suggest weak chemical weathering and an immature source. These results support for the semi-arid and semi-humid paleoclimate conditions in the source area. The geochemistry results reveal that the sediments were deposited in a basin related to the island arc and active continental margin tectonic settings, probably indicating the time of initial collision between Arabia and Eurasia. The enrichment of Cr, Ni and V in the sandstone and shales are consistent with mafic input from the source area. However, La/Th vs. Hf and La/Sc vs. Co/Th plots reveal mixed source of felsic and intermediate volcanic rocks. The data indicate that the sediments most likely originated from a mixture of mafic, intermediate and felsic igneous source areas, possibly as the erosional products of localized topography of the Talysh and the Lesser Caucasus mountains (south to southwest), created by compression in the Moghan region during the syn-collisional development of the Caucasus.     

Relationships between seep-carbonates,mud volcanism and basin geometry in the Late Miocene of the northern Apennines of Italy: the Montardone mélange

The Montardone mélange (Mm) is a chaotic, block-in-matrix unit outcropping in the Montebaranzone syncline in the northern Apennines. The Mm occurs in the uppermost part of the Termina Fm, the Middle–Late Miocene interval of a succession deposited in a wedge-top slope basin (Epiligurian succession). The Mm is closely associated with bodies of authigenic carbonates, characterized by negative values of δ¹³C (from ?18.22 to ?39.05 ‰ PDB) and chemosynthetic benthic fauna (lucinid and vesicomyid bivalves). In this paper, we propose that the Mm is a mud volcano originated by the post-depositional reactivation and rising of a stratigraphically lower mud-rich mass transport body (Canossa–Val Tiepido sedimentary mélange or olistostrome) triggered by fluid overpressure. We base our conclusion on (1) the Mm pierces the entire Termina Fm and older Epiligurian units and represents the direct continuation of the underlying Canossa–Val Tiepido mélange; (2) the geometry and facies distribution of the Montebaranzone sandstone body, which are compatible with a confined basin controlled by the rising of the Mm; (3) the systematic presence of large-scale (lateral extension 300–400 m) seep-carbonates associated with the mélange, suggesting a persistent gas-enriched fluid vent from the ascending overpressured mud; (4) blocks and clasts sourced from the Mm, hosted by the authigenic carbonates, conveyed by ascending mud and gas-enriched fluids. The Mm represents one of the few fossil examples of reactivation of a basin-scale sedimentary mélange (olistostrome); a three-stage model showing mechanisms of Mm raising is proposed.     

The Corsica–Sardinia Massif as source area for the early northern Apennines foredeep system: evidence from debris flows in the "Macigno costiero" (Late Oligocene, Italy)

Large isolated gravity flows (debrites) are widely present in the stratigraphic record of the northern Apennines foreland-basin system. These strata may be useful for provenance signals and dispersal pathways during foreland evolution. This paper examines a cohesive debris flow bed interbedded with turbidite strata of the Macigno Formation (Late Oligocene, Tuscany, Italy), in order to obtain new data on the provenance of the clastic material. Clasts in the debris flow are predominantly plutonic (granodiorite, tonalite, and S-granite) and subordinately metamorphic (gneiss and schist) and sedimentary calcareous clasts. The composition of the clasts within the debris flow is similar to the clastic composition of the interbedded turbidite sandstones of the "Macigno costiero." The depositional features of the debris flow suggest that it traveled for a short distance within the basin before it was deposited not far from the slope. The absence of a high-pressure/low-temperature (HP/LT) paragenesis in the plutonic and metamorphic clasts of the debris flow indicates a provenance from a crystalline basement not involved in the high-pressure phases of the Alpine Orogenesis. Previous studies have indicated the Central-Western Alps as potential source areas for the Macigno Formation sediments. The lack of HP/LT metamorphic signatures in our studied samples excludes the Pennidic and Austroalpine nappes of the Western Alps as possible sources for the debris flows of the "Macigno costiero." These new data (sedimentological, petrographical, and microstructural) suggest that the Corsica-Sardinia Hercynian basement, lacking a HP/LT paragenesis, is the more accredited source area of the debris flow and of the related turbidite sandstones of the "Macigno costiero" succession. These foredeep-feeding sediments were probably before deposited within an episutural basin developed close to the northern Apennines orogenic wedge.     

Asbestos fibre identification vs. evaluation of asbestos hazard in ophiolitic rock mélanges,a case study from the Ligurian Alps (Italy)

In recent years, the high incidence of harmful health effects through inhalation of airborne asbestos from amphibole-bearing rock mélanges has been thoroughly documented. Here, we present a field-based, multi-scale geological approach aimed at illustrating the occurrence of amphibole fibrous mineralisation in an ophiolitic suite from the Ligurian Alps (Italy) and discussing the implication on in situ determination of the asbestos hazard. The rock mélange is composed of plurimetre-sized blocks of different lithotypes (metagabbro, serpentinite, chloritoschist) juxtaposed by the meaning of tectonic structures. The geological-structural survey revealed that the fibrous mineralisation is localised in specific structural sites of the rock volume, including veins and schistosity. Both micro-chemical and crystal structure analyses on selected fibrous samples revealed that actinolite fibres grow in veins within the metagabbro and in chloritoschists, while fibrous tremolite occurs in serpentinite schistosity. The morphological features of these amphibole fibres have been analysed in TEM images and used for classifying them as “asbestiform” or “non-asbestiform”. The results show that the asbestos hazard determination is not unequivocally identified when different procedures for asbestos fibre identification and classification are applied. This may have impact on normatives and regulations in defining environmental hazards due to asbestos occurrence.     

Upper crust “boudinage” during post-collisional Miocene extension in Tuscany: Insights from the southern part of the Larderello geothermal area (Northern Apennines,Italy)

A geological study carried out in the southern part of the Larderello geothermal area (Northern Apennines) provides new information on the development mechanism and timing of the earlier extensional structures that formed during the Miocene post-collisional tectonics which affected the orogen. Staircase low-angle normal faults (LANFs) affected a multilayered thickened upper crust after the collisional stage, producing the lateral segmentation of the Tuscan Nappe, the deeper non-metamorphic tectonic unit of the Northern Apennines in the Tuscan area. The tectonic history recorded in two Tuscan Nappe discontinuous bodies revealed that the LANFs took place during the Middle–Late Miocene, displacing collisional structures developed from the Late Oligocene. These Tuscan Nappe bodies are delimited by detachment faults located at the base, within the Tuscan evaporites, and at the top within the Ligurian Units. Their western and eastern margins coincide with east-dipping ramps. These structures and the Tuscan Nappe bodies were later dissected by Pliocene–Quaternary high-angle normal faults. The reconstructed deformation history implies that the Tuscan Nappe bodies are extensional horses developed through an earlier asymmetrical east-dipping extensional duplex system, involved in block faulting during the later, Pliocene-Quaternary, stage of extension.     

Oligocene-to-Early Miocene depositional and structural evolution of the Calabria–Peloritani Arc southern terrane (Italy) and geodynamic correlations with the Spain Betics and Morocco Rif

The Calabria–Peloritani Arc southern terrane is a stack of crystalline basement nappes, some of them provided with a widely outcropping Alpine sedimentary cover, sealed by clastics of the Stilo–Capo d’Orlando Formation (SCOF). New field observations in the Stilo area lead to define a Pignolo Formation as a sedimentary cycle predating the emplacement of the uppermost nappe (Stilo Unit) of the tectonic pile. It includes the well-known Lithothamnium and larger foraminifers bearing calcarenites, previously interpreted as a basal member of the SCOF. The biostratigraphic revision of both formations, together with recently published data about other preorogenic deposits, point to a stacking of the whole terrane between the Aquitanian and the middle–late Burdigalian. A comparison between the sedimentary cycles characterising the Calabria–Peloritani southern terrane during the Oligocene–Early Miocene and those almost coeval of the Betic–Rifian internal units highlights their quite similar evolution. Thus it is reliable that both the orogenic belts originated from contiguous paleogeographic realms. These considerations confirm that the present western Mediterranean Chains were originally segments of a continuous orogenic belt disrupted by the opening of the Balearic and Tyrrhenian basins.     

Jurassic and Cretaceous radiolarian assemblages from the Bornova mélange in northern Karaburun Peninsula (western Turkey) and its connection to the İzmir–Ankara mélanges

Two large blocks of red bedded chert identified within the Late Cretaceous–Paleocene Bornova mélange in northern Karaburun Peninsula yielded Jurassic (late Bathonian–early Oxfordian) and Cretaceous (middle–late Albian) radiolarian assemblages. These new data confirm the correlation of the Bornova mélange with the Bornova Flysch Zone (BFZ) and the ?zmir–Ankara mélanges. A review of all previously obtained ages in chert blocks of the BFZ and the ?zmir–Ankara mélanges is provided in order to strengthen this correlation.     

Evidence for Late Miocene to Recent contamination of arc andesites by crustal melts in the Chilean Andes (25–26°S) and its geodynamic implications

Chemical and isotopic data from 12 volcanic centers of the southern Central Volcanic Zone (CVZ) in Chile, whose ages of 20, 16, 11, 8, 5, 2 and <1 Ma bracket the peak of shortening and crustal thickening in the mid-Miocene, show systematic differences with age. The composition of andesites erupted before and after crustal thickening are similar in terms of most major and trace elements, but the post-Miocene andesites show enrichments in Th, U, Cs and Rb, as well as high ⁸⁷Sr/⁸⁶Sr and ²⁰⁶Pb/²⁰⁴Pb ratios coupled with low εNd values which indicate greater crustal contamination compared with the older equivalents. Comparison of contamination indicators with age shows that contamination was low from 20 Ma to 8 Ma, increased sharply between 8 and 5 Ma, and remained at a high level into the Quaternary. Constant ratios of fluid-mobile vs immobile elements (Cs/Th or Ba/Zr) in even the most contaminated rocks indicate that fluid interaction was negligible. The contaminated andesites display disequilibrium textures and contain phenocrysts with a mixed population of melt inclusions. We suggest that the main process of crustal contamination was mixing with crustal melts. This is supported by geophysical evidence for a zone of partial melting in the mid and lower crust under the magmatic arc and by the presence of late Miocene to Pliocene crustal-derived felsic ignimbrites in the CVZ.     

Metamorphic P–T–t–d evolution of (U)HP metabasites from the South Tianshan accretionary complex (NW China) — Implications for rock deformation during exhumation in a subduction channel

The late Carboniferous accretionary system of the South Tianshan orogen (North-Western China) underwent complex structural and polymetamorphic evolution. Combined petrological, geochronological and microstructural analysis of (ultra)high-pressure (UHP) metabasites (eclogites and blueschists) enclosed in metapelites show a relict coarse-grained eclogitic fabric S2 surrounded by a dominant fine-grained eclogite and blueschist facies retrograde fabric S2. The S2 fabric is reworked by upright folds F3 that are responsible for a major shortening of the whole accretionary system. For both the eclogite and blueschist, peak and retrograde P–T conditions have been thermodynamically constrained at 25–26 kbar and 425–500 °C and 10–13 kbar and 500−550 °C respectively, suggesting a shared exhumation history. The garnet-whole rock-amphibole isochron in the blueschist yielded Lu–Hf and Sm–Nd ages of 326.0 ± 2.9 Ma and 318.4 ± 3.9 Ma respectively, interpreted to date the prograde to peak metamorphic assemblage. The retrograde path of the eclogite is characterized by heterogeneous omphacite recrystallization into a mylonitic fine-grained matrix and crystallization of blue amphibole. Microstructures in both pristine porphyroclastic and recrystallized fine-grained domains in the eclogite indicate a gradual evolution from constriction-dominated (L>S-type) to flattening-dominated (S>L-type) type of deformation, increase of fabric intensity reflected by gradually growing M-indexes and the development of lattice preferred orientation (LPO) typical for dislocation creep under slightly hydrated conditions. Recrystallization of the matrix in the blueschist is homogeneous, which indicates a matrix dominated channel flow during exhumation. These LPOs evolutions suggest a significant mechanical coupling with the upper plate concomitant with oroclinal bending of the Kazakh orocline. Lock up of Kazakh orocline is responsible for further stress increase resulting in horizontal shortening of South Tianshan accretionary wedge and development of D3 upright folding and steepening of the whole sequence.     

Boninite volcanic rocks from the mélange of NW Dinaric-Vardar ophiolite zone (Mt. Medvednica,Croatia) – record of Middle to Late Jurassic arc-forearc system in the Tethyan subduction factory

Mineralogy and Petrology - In the Late Jurassic to Early Cretaceous ophiolite mélange from the Mt. Medvednica (Vardar Ocean) blocks of boninite rocks have been documented. They emerge as...     

Use of the 87Sr/86Sr isotopic ratio as an environmental tracer: an example of the application to the Fossil Forest of the Dunarobba (FFD) sedimentary system near Aviglano Umbro (Terni—Central Italy)

A recent discovery of Pliocene tree trunks (Taxodium, Glyptostrobus or Sequoia) perfectly preserved in the fluvial lacustrine sediments deposited in the old Tiberin Lake (near the town of Dunarobba, Central Italy) has led to the study of the conditions responsible for the trunks preservation. The present work has applied Sr isotope techniques to examine and confirm fluid migration in the different sediment types which cross the entire fluvial-lacustrine sequence. Based on the ⁸⁷Sr/⁸⁶Sr ratios measured in carbonate and in silicate fractions of samples collected from a bore hole (from 0 to 120 m) it is concluded that each sedimentary level has limited communication between zones and is characterised by different isotope values. This suggests that the intrinsic properties of these clays make them a good material for isolating waste, both for direct use and for a better buffer in other formations, possibly less secure, such as salt or granite. The results obtained in the present work have demonstrated some of the potential uses of the ⁸⁷Sr/⁸⁶Sr isotopic ratio as an environmental tracer for confirming results from some of the geotechnical (such as permeability) and geochemical parameters of these host sediments.     

Sandstone provenance and tectonic evolution of the Xiukang Mélange from Neotethyan subduction to India–Asia collision (Yarlung-Zangbo suture,south Tibet)

The Xiukang Mélange of the Yarlung-Zangbo suture zone in south Tibet documents low efficiency of accretion along the southern active margin of Asia during Cretaceous Neotethyan subduction, followed by final development during the early Paleogene stages of the India–Asia collision. Here we present integrated petrologic, U–Pb detrital-zircon geochronology and Hf isotope data on different types of sandstone blocks in the Xiukang Mélange. Three groups of sandstone blocks with different provenance and depositional setting are distinguished by their petrographic, geochronological and isotopic fingerprints. Blocks of turbiditic quartzarenite originally sourced from the Indian continent were deposited in pre-Cretaceous time on the northernmost edge of the Indian passive margin and eventually involved into the mélange at the early stage of the India–Asia collision. Two distinct groups of volcaniclastic-sandstone blocks were derived from the central Lhasa block and Gangdese magmatic arc. One group was deposited in the trench and/or on the trench slope of the Asian margin during the early Late Cretaceous, and the other group in a syn-collisional basin just after the onset of the India–Asia collision in the Early Eocene. The largely erosional character of the Asian active margin in the Late Cretaceous is indicated by the scarcity of off-scraped trench-fill deposits and the relatively small subduction complex developed during limited episodes of accretion. The Xiukang Mélange was finally structured in the Late Paleocene/Eocene, when sandstone blocks of both Indian and Asian origin were progressively incorporated tectonically in the suture zone of the nascent Himalayan Orogen.